JPS63158559A - Electrophotographic sensitive body - Google Patents
Electrophotographic sensitive bodyInfo
- Publication number
- JPS63158559A JPS63158559A JP30687886A JP30687886A JPS63158559A JP S63158559 A JPS63158559 A JP S63158559A JP 30687886 A JP30687886 A JP 30687886A JP 30687886 A JP30687886 A JP 30687886A JP S63158559 A JPS63158559 A JP S63158559A
- Authority
- JP
- Japan
- Prior art keywords
- group
- charge
- photoreceptor
- layer
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- -1 cyano, nitro, amino Chemical group 0.000 claims abstract description 19
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 6
- 125000003118 aryl group Chemical group 0.000 claims abstract description 6
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 claims abstract description 3
- 125000003545 alkoxy group Chemical group 0.000 claims abstract description 3
- 125000003282 alkyl amino group Chemical group 0.000 claims abstract description 3
- 125000001769 aryl amino group Chemical group 0.000 claims abstract description 3
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims abstract 2
- 108091008695 photoreceptors Proteins 0.000 claims description 49
- 239000000126 substance Substances 0.000 claims description 32
- 239000005977 Ethylene Substances 0.000 claims description 16
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 4
- 125000003277 amino group Chemical group 0.000 claims description 2
- 125000004093 cyano group Chemical group *C#N 0.000 claims description 2
- 125000004185 ester group Chemical group 0.000 claims description 2
- 125000005843 halogen group Chemical group 0.000 claims description 2
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims 1
- 239000000463 material Substances 0.000 abstract description 14
- 239000000758 substrate Substances 0.000 abstract description 14
- 150000001875 compounds Chemical class 0.000 abstract description 11
- 230000035945 sensitivity Effects 0.000 abstract description 6
- 150000002148 esters Chemical class 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 150000002367 halogens Chemical class 0.000 abstract 1
- 239000010410 layer Substances 0.000 description 52
- 239000011347 resin Substances 0.000 description 13
- 229920005989 resin Polymers 0.000 description 13
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 12
- 239000011230 binding agent Substances 0.000 description 12
- 239000011248 coating agent Substances 0.000 description 11
- 238000000576 coating method Methods 0.000 description 11
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical class N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 11
- 239000000243 solution Substances 0.000 description 10
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 9
- 238000001035 drying Methods 0.000 description 8
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 7
- 239000011247 coating layer Substances 0.000 description 7
- 238000000034 method Methods 0.000 description 6
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 6
- 239000002904 solvent Substances 0.000 description 6
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 6
- 239000011368 organic material Substances 0.000 description 5
- 239000004926 polymethyl methacrylate Substances 0.000 description 5
- 239000000203 mixture Substances 0.000 description 4
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical class C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 3
- 239000004952 Polyamide Substances 0.000 description 3
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 238000000151 deposition Methods 0.000 description 3
- 125000000664 diazo group Chemical group [N-]=[N+]=[*] 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 229910010272 inorganic material Inorganic materials 0.000 description 3
- 239000011147 inorganic material Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 229920002647 polyamide Polymers 0.000 description 3
- 229920001225 polyester resin Polymers 0.000 description 3
- 239000004645 polyester resin Substances 0.000 description 3
- 229910052711 selenium Inorganic materials 0.000 description 3
- 239000011669 selenium Substances 0.000 description 3
- AZQWKYJCGOJGHM-UHFFFAOYSA-N 1,4-benzoquinone Chemical compound O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 description 2
- 239000004593 Epoxy Substances 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- MWPLVEDNUUSJAV-UHFFFAOYSA-N anthracene Chemical compound C1=CC=CC2=CC3=CC=CC=C3C=C21 MWPLVEDNUUSJAV-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000005684 electric field Effects 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 238000004898 kneading Methods 0.000 description 2
- 230000031700 light absorption Effects 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 229910044991 metal oxide Inorganic materials 0.000 description 2
- 150000004706 metal oxides Chemical class 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 125000005397 methacrylic acid ester group Chemical group 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 229920000515 polycarbonate Polymers 0.000 description 2
- 239000004417 polycarbonate Substances 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 229920006267 polyester film Polymers 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 229920002635 polyurethane Polymers 0.000 description 2
- 239000004814 polyurethane Substances 0.000 description 2
- 229920002050 silicone resin Polymers 0.000 description 2
- 239000002356 single layer Substances 0.000 description 2
- 230000003068 static effect Effects 0.000 description 2
- 238000001771 vacuum deposition Methods 0.000 description 2
- VDFKURANQKCOAI-UHFFFAOYSA-N 1-nitrofluoren-9-one Chemical compound C12=CC=CC=C2C(=O)C2=C1C=CC=C2[N+](=O)[O-] VDFKURANQKCOAI-UHFFFAOYSA-N 0.000 description 1
- WUPHOULIZUERAE-UHFFFAOYSA-N 3-(oxolan-2-yl)propanoic acid Chemical compound OC(=O)CCC1CCCO1 WUPHOULIZUERAE-UHFFFAOYSA-N 0.000 description 1
- 235000000177 Indigofera tinctoria Nutrition 0.000 description 1
- 239000004419 Panlite Substances 0.000 description 1
- 206010034972 Photosensitivity reaction Diseases 0.000 description 1
- 229910001370 Se alloy Inorganic materials 0.000 description 1
- 239000004809 Teflon Substances 0.000 description 1
- 229920006362 Teflon® Polymers 0.000 description 1
- 235000010724 Wisteria floribunda Nutrition 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 230000004397 blinking Effects 0.000 description 1
- 229910052980 cadmium sulfide Inorganic materials 0.000 description 1
- 229910052681 coesite Inorganic materials 0.000 description 1
- 229940125904 compound 1 Drugs 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 229910052906 cristobalite Inorganic materials 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000005496 eutectics Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229940097275 indigo Drugs 0.000 description 1
- COHYTHOBJLSHDF-UHFFFAOYSA-N indigo powder Natural products N1C2=CC=CC=C2C(=O)C1=C1C(=O)C2=CC=CC=C2N1 COHYTHOBJLSHDF-UHFFFAOYSA-N 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 229920003145 methacrylic acid copolymer Polymers 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- SJHHDDDGXWOYOE-UHFFFAOYSA-N oxytitamium phthalocyanine Chemical compound [Ti+2]=O.C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 SJHHDDDGXWOYOE-UHFFFAOYSA-N 0.000 description 1
- 230000036211 photosensitivity Effects 0.000 description 1
- 229920003227 poly(N-vinyl carbazole) Polymers 0.000 description 1
- 229920003217 poly(methylsilsesquioxane) Polymers 0.000 description 1
- 229920005668 polycarbonate resin Polymers 0.000 description 1
- 239000004431 polycarbonate resin Substances 0.000 description 1
- 229920006149 polyester-amide block copolymer Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 229940065287 selenium compound Drugs 0.000 description 1
- 150000003343 selenium compounds Chemical class 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 229920005573 silicon-containing polymer Polymers 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 238000004544 sputter deposition Methods 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 229910052682 stishovite Inorganic materials 0.000 description 1
- 238000001308 synthesis method Methods 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
- 238000001132 ultrasonic dispersion Methods 0.000 description 1
- 238000007740 vapor deposition Methods 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G5/00—Recording members for original recording by exposure, e.g. to light, to heat, to electrons; Manufacture thereof; Selection of materials therefor
- G03G5/02—Charge-receiving layers
- G03G5/04—Photoconductive layers; Charge-generation layers or charge-transporting layers; Additives therefor; Binders therefor
- G03G5/06—Photoconductive layers; Charge-generation layers or charge-transporting layers; Additives therefor; Binders therefor characterised by the photoconductive material being organic
- G03G5/0622—Heterocyclic compounds
- G03G5/0644—Heterocyclic compounds containing two or more hetero rings
- G03G5/0661—Heterocyclic compounds containing two or more hetero rings in different ring systems, each system containing at least one hetero ring
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Photoreceptors In Electrophotography (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は電子写真用感光体に関し、詳しくは導電性基体
上に形成せしめた感光層の中に、前記一般式（Ｉ）で示
されるエチレン化合物を含有する事を特徴とする電子写
真用感光体に関する。DETAILED DESCRIPTION OF THE INVENTION [Industrial Application Field] The present invention relates to an electrophotographic photoreceptor, and more specifically, the present invention relates to an electrophotographic photoreceptor, and more specifically, an ethylene compound represented by the general formula (I) is contained in a photosensitive layer formed on a conductive substrate. The present invention relates to an electrophotographic photoreceptor characterized by containing a compound.
従来より電子写真用感光体く以下感光体とも称する）の
感光材料としてはセレンまたはセレン合金などの無機光
導電性物質、酸化亜鉛あるいは硫化カドミウムなどの無
機光導電性物質を樹脂結着剤中に分散させたもの、ポＩ
ＪＮ−ビニールカルバゾールまたはポリビニールアント
ラセンなどの有機光導電性物質、フタロシアニン化合物
あるいはビスアゾ化合物などの有機光導電性物質または
、これら光導電性物質を樹脂納置中に分散させたものな
どが利用されている。Conventionally, photosensitive materials for electrophotographic photoreceptors (hereinafter also referred to as photoreceptors) have been made using inorganic photoconductive substances such as selenium or selenium alloys, or inorganic photoconductive substances such as zinc oxide or cadmium sulfide in a resin binder. Dispersed, Po I
Organic photoconductive substances such as JN-vinyl carbazole or polyvinyl anthracene, organic photoconductive substances such as phthalocyanine compounds or bisazo compounds, or these photoconductive substances dispersed in resin are used. There is.
また感光体には暗所で表面電荷を保持する機能、光を受
容して電荷を発生する機能、同じく光を受容して電荷を
輸送する機能とが必要であるが、一つの層でこれらの機
能をあわ仕もったいわゆる単層型感光体と、主として電
荷発生に寄与する層と暗所での表面電荷と光受容時の電
荷輸送に寄与する層とに機能分離した層を積層したいわ
ゆる積層型感光体がある。これらの感光体を用いた電子
写真法による画像形成には、例えばカールソン方式が適
用される。゛この方式での画像形成は暗所での感光体へ
のコロナ放電による帯電、帯電された感光体表面上への
原稿の文字や絵などの静電潜像の形成、形成された静電
潜像のトナーによる現像、現像されたトナー像の紙など
の支持体への定着により行われ、トナー像転写後の感光
体は除電、残留トナーの除去、光除電などを行った後、
再使用に供される。In addition, a photoreceptor must have the function of retaining surface charge in the dark, the function of receiving light and generating charge, and the function of receiving light and transporting charge, but these functions can be achieved in one layer. A so-called multi-layered photoreceptor is a so-called single-layer type photoreceptor with multiple functions, and a laminated layer with functionally separated layers: a layer that mainly contributes to charge generation, a layer that contributes to surface charge in the dark, and a layer that contributes to charge transport during light reception. There is a type photoreceptor. For example, the Carlson method is applied to image formation by electrophotography using these photoreceptors.゛Image formation using this method involves charging the photoconductor in a dark place by corona discharge, forming an electrostatic latent image of the original text or picture on the surface of the charged photoconductor, and This is done by developing the image with toner and fixing the developed toner image on a support such as paper, and after the toner image has been transferred, the photoreceptor is subjected to static neutralization, removal of residual toner, photostatic static elimination, etc.
Subject to reuse.
近年、可とう性、熱安定性、膜形成性などの利点により
、有機材料を用いた電子写真用感光体が実用化されてき
ている。例えば、ポリ−Ｎ−ビニールカルバゾールと２
．４．１−ｚニトロフルオレン−９−オンとからなる感
光体（米国特許第３４８４２３７号明細書に記載）、有
機顔料を主成分とする感光体く特開昭４７−３７５４３
号公報に記載）、染料と樹脂とからなる共晶錯体を主成
分とする感光体（特開昭４７−１０７３５号公報に記載
）などである。In recent years, electrophotographic photoreceptors using organic materials have been put into practical use due to their advantages such as flexibility, thermal stability, and film-forming properties. For example, poly-N-vinyl carbazole and 2
．． 4. Photoreceptor consisting of 1-z nitrofluoren-9-one (described in U.S. Pat. No. 3,484,237), photoreceptor containing organic pigment as a main component JP-A-47-37543
(described in Japanese Unexamined Patent Publication No. 10735/1983), and a photoreceptor whose main component is a eutectic complex consisting of a dye and a resin (described in Japanese Patent Application Laid-Open No. 10735/1983).
さらに、新規ヒドラゾン化合物も数多く実用化されてい
る。Furthermore, many new hydrazone compounds have also been put into practical use.
しかしながら、有機材料は無機材料にない多くの長所を
持つが、電子写真用感光体に要求されるすべての特性を
充分に満足するものはまだ得られていないのが現状であ
り、特に光感度および繰り返し連続使用時の特性に問題
があった。However, although organic materials have many advantages that inorganic materials do not have, it is currently not possible to obtain a material that satisfactorily satisfies all the characteristics required of an electrophotographic photoreceptor, especially in terms of photosensitivity and There were problems with the characteristics when used repeatedly and continuously.
本発明は、上述の点に鑑みてなされたものであって、感
光層に電荷輸送性物質として今まで用いられたことのな
い新しい有機材料を用いることにより、高感度で繰り返
し特性の優れた複写機用およびプリンタ用の電子写真用
感光体を提供することを目的とする。The present invention has been made in view of the above points, and by using a new organic material that has never been used as a charge transporting substance in the photosensitive layer, copying with high sensitivity and excellent repeatability can be achieved. The purpose of the present invention is to provide electrophotographic photoreceptors for machines and printers.
上記目的を達成するために、本発明によれば、下記一般
式（Ｉ）で示されるエチレン化合物のうちの少なくとも
一種類を含む感光層を有する電子写真用感光体とする。In order to achieve the above object, the present invention provides an electrophotographic photoreceptor having a photosensitive layer containing at least one type of ethylene compound represented by the following general formula (I).
（式（Ｉ）中、ｎ、ｍはそれぞれ０〜５の整数、Ｒ３−
Ｒ１はそれぞれ水素原子、ハロゲン原子、ヒドロキン基
、アルキル基、アルコキシ基、アリル基。(In formula (I), n and m are each integers of 0 to 5, R3-
R1 is a hydrogen atom, a halogen atom, a hydroquine group, an alkyl group, an alkoxy group, or an allyl group, respectively.
カルボキンル基、エステル基、アリール基、シアノ基、
ニトロ基、アミノ基、アルキルアミノ基。Carboquine group, ester group, aryl group, cyano group,
Nitro group, amino group, alkylamino group.
またはアリールアミノ基を表す。ＲＩＳ、 Ｒ１６は水
素原子、低級アルキル基、またはアリール基を表す。）
〔作用〕
本発明に用いられる前記一般式（Ｉ）のエチレン化合物
は、その合成法については文献に述べられている。しか
しながら、これらエチレン化合物を感光層に用いた例は
知られていない。本発明者らは、前記目的を達成するた
めに各種有機材料について鋭意検討を進めるなかで、こ
れらエチレン化合物について数多くの実験を行った結果
、その技術的解明はまだ充分なされてはいないが、この
よ１１前記一般式（Ｉ）で示されるエチレン化合物を電
荷輸送性物質として感光層に用いることにより、高感度
で繰り返し特性の優れた感光体が得られることを見出し
たのである。Or represents an arylamino group. RIS, R16 represents a hydrogen atom, a lower alkyl group, or an aryl group. ) [Function] The synthesis method of the ethylene compound of the general formula (I) used in the present invention is described in the literature. However, there are no known examples of using these ethylene compounds in photosensitive layers. In order to achieve the above objective, the present inventors conducted numerous experiments on these ethylene compounds while conducting intensive studies on various organic materials. It has been discovered that by using the ethylene compound represented by the general formula (I) in the photosensitive layer as a charge transporting substance, a photoreceptor with high sensitivity and excellent repeatability can be obtained.
本発明に用いる前記一般式（Ｉ）で表されるエチレン化
合物の具体例を例示すると次の通りである。Specific examples of the ethylene compound represented by the general formula (I) used in the present invention are as follows.
化合物
化合物
化合物Ｎα２３
Ｎα２４
Ｎｏ、２５
Ｎｏ、２６
Ｎｏ、２７
Ｎｏ、２８
化合物Ｎα２９
Ｎα３Ｏ
Ｎα３１
Ｎα３２
Ｎα３４
本発明の感光体は前述のエチレン化合物を感光層中に含
有させたものであるが、これらエチレン化合物の応用の
仕方によって、第１図、第２図、あるいは第３図に示し
たごとくに用いることができる。Compound Compound Compound Nα23 Nα24 No, 25 No, 26 No, 27 No, 28 Compound Nα29 Nα3O Nα31 Nα32 Nα34 The photoreceptor of the present invention contains the above-mentioned ethylene compound in the photosensitive layer. Depending on the application, it can be used as shown in FIG. 1, FIG. 2, or FIG. 3.
第１図〜第３図は本発明の感光体のそれぞれ異なる実施
例の概念的断面図、１は導電性基体、２０゜２１、２２
は感光層、３は電荷発生質、４は電荷発生層、５は電荷
輸送性物質、６は電荷輸送層、７は被覆層である。1 to 3 are conceptual cross-sectional views of different embodiments of the photoreceptor of the present invention, 1 is a conductive substrate, 20° 21, 22
3 is a photosensitive layer, 3 is a charge-generating material, 4 is a charge-generating layer, 5 is a charge-transporting material, 6 is a charge-transporting layer, and 7 is a coating layer.
第１図は、導電性基体ｌ上に電荷発生物質３と電荷輸送
性物質５であるエチレン化合物を枝（脂バインダー結着
剤中に分散した感光層２０（通常単層型感光体と称せら
れる構成）が設けられたものである。FIG. 1 shows a photosensitive layer 20 (usually called a single-layer photoreceptor) in which a charge-generating substance 3 and an ethylene compound as a charge-transporting substance 5 are dispersed in a fat binder binder on a conductive substrate l. configuration) is provided.
第２図は、導電性基体１上に電荷発生物質３を主体とす
る電荷発生層４と、電荷輸送性物質５であるエチレン化
合物を含有する電荷輸送層６との積層からなる感光層２
１（通常積層型感光体と称せられる構成）が設けられた
ものである。FIG. 2 shows a photosensitive layer 2 formed by laminating a charge generation layer 4 mainly containing a charge generation substance 3 and a charge transport layer 6 containing an ethylene compound as a charge transport substance 5 on a conductive substrate 1.
1 (a configuration commonly referred to as a laminated photoreceptor).
第３図は、第２図の逆の層構成のものである。FIG. 3 shows an inverse layer configuration to that in FIG.
この場合、電荷発生層４を保護するために被覆層７が設
けられるのが一般的である。In this case, a covering layer 7 is generally provided to protect the charge generation layer 4.
第２図および第３図に示す二種類の１構成とする理由と
して、感光体は正帯電方式または負帯電方式で用いられ
るが、負帯電方式として第２図の層構成が通常用いられ
る。第２図の層構成で正帯電方式で用いようとしても、
これに適合する電荷輸送性物質が見つかっていないのが
現状であり、したがって、正帯電方式の感光体として本
発明者らがすでに提案したように、第３図に示す層構成
が有効なものとして挙げられるのである。The reason for the two types of configurations shown in FIGS. 2 and 3 is that the photoreceptor is used in a positive charging system or a negative charging system, and the layer configuration shown in FIG. 2 is usually used in the negative charging system. Even if you try to use the positive charging method with the layer configuration shown in Figure 2,
At present, no charge-transporting substance has been found that meets this requirement. Therefore, as the present inventors have already proposed, the layer structure shown in Figure 3 is considered to be effective as a positive charging type photoreceptor. It can be mentioned.
第１図の感光体は、電荷発生物質を電荷輸送性物質およ
び樹脂バインダーを溶解した溶液中に分散せしめ、この
分散液を導電性基体上に塗布することによって作製でき
る。The photoreceptor shown in FIG. 1 can be produced by dispersing a charge generating substance in a solution containing a charge transporting substance and a resin binder, and applying this dispersion onto a conductive substrate.
第２図の感光体は、導電性基体上に電荷発生物質を真空
蒸着するか、あるいは電荷発生物質の粒子を溶剤または
樹脂バインダー中に分散して得た分散液を塗布、乾燥し
、その上に電荷輸送物質および樹脂バインダーを溶解し
た溶液を塗布、乾燥することにより作製できる。The photoreceptor shown in Figure 2 is produced by vacuum-depositing a charge-generating substance on a conductive substrate, or by coating and drying a dispersion obtained by dispersing particles of a charge-generating substance in a solvent or resin binder, and then It can be produced by applying a solution containing a charge transporting substance and a resin binder to the surface of the substrate and drying the solution.
第３図の感光体は、電荷輸送性物質および樹脂バインダ
ーを溶解した溶液を導電性基体上に塗布、乾燥し、その
上に電荷発生物質を真空蒸着するか、あるいは電荷発生
物質の粒子を溶剤または樹脂バインダー中に分散して得
た分散液を塗布、乾燥することにより作製できる。The photoreceptor shown in Figure 3 is produced by coating a conductive substrate with a solution containing a charge-transporting substance and a resin binder and drying it, and then vacuum-depositing a charge-generating substance thereon, or by depositing particles of the charge-generating substance in a solvent. Alternatively, it can be produced by coating and drying a dispersion obtained by dispersing in a resin binder.
導電性基体１は感光体の電極としての役目と同時に他の
各層の支持体となっており、円筒状、板状、フィルム状
のいずれでも良く、材質的にはアルミニウム、ステンレ
ス鋼、ニッケルなどの金属、あるいはガラス、樹脂など
の上に導電処理をほどこしたものでも良い。The conductive substrate 1 serves as an electrode for the photoreceptor and at the same time serves as a support for the other layers, and may be cylindrical, plate-shaped, or film-shaped, and may be made of aluminum, stainless steel, nickel, etc. It may also be made of metal, glass, resin, or the like, which has been subjected to conductive treatment.
電荷発生層４は、前記したように電荷発生物質３の粒子
を樹脂バインダー中に分散させた材料を塗布するか、あ
るいは、真空蒸着などの方法により形成され、光を受容
して電荷を発生する。また、その電荷発生効率が高いこ
とと同時に発生した電荷の電荷輸送層６および被覆層７
への注入性が重要で、電場依存性が少なく低電場でも注
入の良いことが望ましい。電荷発生物質としては、無金
属フタロシアニン、チタニルフタロシアニンなどのフタ
ロシアニン化合物、各種アゾ、キノン、インジゴ顔料あ
るいは、セレンまたはセレン化合物などが用いられ、画
像形成に使用される露光光源の光波長領域に応じて好適
な物質を選ぶことができる。電荷発生層は電荷発生機能
を有すればよいので、その膜厚は電荷発生物質の光吸収
係数より決まり一般的には５μｍ以下であり、好適には
１μｍ以下である。電荷発生層は電荷発生物質を主体と
してこれに電荷輸送性物質などを添加して使用すること
も可能である。樹脂バインダーとしては、ポリカーボネ
ート、ポリエステル、ポリアミド、ポリウレタン、エポ
キシ、シリコン樹脂、メタクリル酸エステルの重合体お
よび共重合体などを適宜組み合わせして使用することが
可能である。The charge generation layer 4 is formed by applying a material in which particles of the charge generation substance 3 are dispersed in a resin binder as described above, or by a method such as vacuum deposition, and generates charges by receiving light. . In addition, the charge transport layer 6 and the coating layer 7 for the generated charges at the same time have a high charge generation efficiency.
It is important to have good injection properties even in low electric fields with little dependence on electric fields. As the charge generating substance, phthalocyanine compounds such as metal-free phthalocyanine and titanyl phthalocyanine, various azo, quinone, and indigo pigments, or selenium or selenium compounds are used, depending on the light wavelength range of the exposure light source used for image formation. A suitable material can be selected. Since the charge generation layer only needs to have a charge generation function, its thickness is determined by the light absorption coefficient of the charge generation substance and is generally 5 μm or less, preferably 1 μm or less. The charge generation layer is mainly composed of a charge generation substance, and a charge transporting substance can also be added thereto. As the resin binder, polycarbonate, polyester, polyamide, polyurethane, epoxy, silicone resin, polymers and copolymers of methacrylic acid ester, etc. can be used in appropriate combinations.
電荷輸送層６は樹脂バインダー中に有機電荷輸送性物質
として前記一般式（Ｉ）で示されるエチレン化合物を分
散させた塗膜であり、暗所では絶縁体層として感光体の
電荷を保持し、光受容時には電荷発生層から注入される
電荷を輸送する機能を発揮する。樹脂バインダーとして
は、ポリカーボネート、ポリエステル、ポリアミド、ポ
リウレタン、エポキシ、シリコン樹脂、メタクリル酸エ
ステルの重合体および共重合第などを用いることができ
る。The charge transport layer 6 is a coating film in which an ethylene compound represented by the general formula (I) as an organic charge transport substance is dispersed in a resin binder, and serves as an insulating layer in the dark to retain the charge on the photoreceptor. During light reception, it functions to transport charges injected from the charge generation layer. As the resin binder, polycarbonate, polyester, polyamide, polyurethane, epoxy, silicone resin, methacrylic acid ester polymers and copolymers, etc. can be used.
被覆層７は暗所ではコロナ放電の電荷を受容して保持す
る機能を有しており、かつ電荷発生層が感応する光を透
過する性能を有し、露光時に光を透過し、電荷発生層に
到達させ、発生した電荷の注入を受けて表面電荷を中和
消滅されることが必要である。被覆材料としては、ポリ
エステル、ポリアミドなどの有機絶縁性皮膜形成材料が
適用できる。また、これら有機材料とガラス樹脂、Ｓｉ
Ｏ□などの無機材料さらには金属、金属酸化物などの電
気抵抗を低減せしめる材料とを混合して用いることもで
きる。被覆材料としては有機絶縁性皮膜形成材料に限定
されることはな（Ｓｉ０２などの無機材料さらには金属
、金属酸化物などを蒸着、スパッタリングなどの方法に
より形成することも可能である。被覆材料は前述の通り
電荷発生物質の光の吸収極大の波長領域においてできる
だけ透明であることが望ましい。The coating layer 7 has the function of receiving and retaining the charge of corona discharge in a dark place, and has the ability to transmit the light to which the charge generation layer is sensitive, and transmits the light upon exposure, and the charge generation layer It is necessary for the surface charge to be neutralized and annihilated by the injection of the generated charge. As the coating material, organic insulating film-forming materials such as polyester and polyamide can be used. In addition, these organic materials, glass resin, Si
It is also possible to use a mixture of inorganic materials such as O□ and materials that reduce electrical resistance such as metals and metal oxides. The coating material is not limited to organic insulating film forming materials (inorganic materials such as Si02, metals, metal oxides, etc. can also be formed by methods such as vapor deposition and sputtering.The coating material is As described above, it is desirable that the charge generating material be as transparent as possible in the wavelength region where the light absorption is maximum.
被覆層自体の膜厚は被覆層の配合組成にも依存するが、
繰り返し連続使用したとき残留電位が増大するなどの悪
影響が出ない範囲で任意に設定できる。The thickness of the coating layer itself depends on the composition of the coating layer, but
It can be set arbitrarily within a range that does not cause adverse effects such as an increase in residual potential when used repeatedly and continuously.
以下、本発明の具体的な実施例について説明する。Hereinafter, specific examples of the present invention will be described.
実施例１
ボールミルで１５０時間粉砕した無金属フタロシアニン
（東京化成製）５０重量部と前記化合物Ｎｏ、 １で示
されるエチレン化合物１００重量部をポリエステル樹脂
（バイロン：東洋紡製）１００重量部とテトラヒドロフ
ラン（ＴＨＦ）溶剤とともに３時間混合機により混練し
て塗布液を調整し、導電性基体であるアルミ蒸着ポリエ
ステルフィルム（＾β−ＰＥＴ）上に、ワイヤーバー法
にて塗布して、乾燥後の膜厚が１５μｍになるように感
光層を形成して感光体を作製した。Example 1 50 parts by weight of metal-free phthalocyanine (manufactured by Tokyo Kasei Co., Ltd.) ground for 150 hours in a ball mill and 100 parts by weight of the ethylene compound represented by Compound No. ) A coating solution was prepared by kneading it with a solvent in a mixer for 3 hours, and it was applied onto a conductive substrate, aluminum-deposited polyester film (^β-PET), using a wire bar method, and the film thickness after drying was determined. A photoreceptor was prepared by forming a photosensitive layer to have a thickness of 15 μm.
実施例２
まず、α型無金属フタロシアニンを出発原料とし、２つ
のリニアモーターを対向して配置した間にα型無金属フ
タロンアニンと作用小片としてテフロンピースを内蔵し
た非磁性縮体をおいて粉砕するＬ Ｉ ＭＭＡ Ｃ（Ｌ
ｉｎｅａｒ １ｎｄｃｔｉｏｎ Ｍｏｔｏｒ Ｍ＋ｘ−
ｉｎｇ ａｎｄ Ｃｒａｓｈｉｎｇ ：富士電機製）処
理を２０分間行い微粉末化した。この微粉末化された試
料１重量部とＤＭＦ （Ｎ、Ｎ−ジメチルホルムアミド
）溶剤５０重量部とを超音波分散処理を行った。その後
、試料とＤ Ｍ Ｆとを分離濾過し、乾燥して無金嘱フ
タロシアニンの処理を行った。Example 2 First, α-type metal-free phthalocyanine is used as a starting material, and while two linear motors are placed facing each other, α-type metal-free phthalocyanine and a non-magnetic condensed body containing a Teflon piece as a working piece are placed and pulverized. L I MMA C(L
inear 1ndction Motor M+x-
ing and crushing (manufactured by Fuji Electric) for 20 minutes to form a fine powder. 1 part by weight of this finely powdered sample and 50 parts by weight of DMF (N,N-dimethylformamide) solvent were subjected to ultrasonic dispersion treatment. Thereafter, the sample and DMF were separated and filtered, dried, and processed into gold-free phthalocyanine.
次に、前記化合物Ｎｏ、 １で示されるエチレン化合物
１００重量部をテトラヒドロフラン（ＴＨ’Ｆ）７００
リ
！置部に溶かした液とポリメタタル酸メチルポリマー（
ＰＭＭＡ：東京化成）１００重量部をトルエン７００重
量部に溶かした液とを混合してできた塗液をアルミ蒸着
ポリエステルフィルム基体上にワイヤーバーにて塗布し
、乾燥後の膜厚が１５μｍになるように電荷輸送層を形
成した。このようにして得られた電荷輸送層上に上記の
処理をされた無金属フタロシアニン５０重量部、ポリエ
ステル樹脂（商品名バイロン２００：東洋紡製）５０重
量部、ＰＭＭＡ５０重量部とＴＨＦ溶剤とともに３時間
混合機により混練して塗布液を調整し、ワイヤーバーに
て塗布し、乾燥後の膜厚が１μｍになるように電荷発生
層を形成し感光体を作製した。Next, 100 parts by weight of the ethylene compound represented by Compound No. 1 was added to 700 parts by weight of tetrahydrofuran (TH'F).
Ri! The solution and polymethyl metatalate polymer (
A coating solution prepared by mixing 100 parts by weight of PMMA (Tokyo Kasei) dissolved in 700 parts by weight of toluene is applied onto an aluminum-deposited polyester film substrate using a wire bar, and the film thickness after drying becomes 15 μm. A charge transport layer was formed in this manner. On the thus obtained charge transport layer, 50 parts by weight of the above-treated metal-free phthalocyanine, 50 parts by weight of polyester resin (trade name: Vylon 200, manufactured by Toyobo Co., Ltd.), 50 parts by weight of PMMA and THF solvent were mixed for 3 hours. A coating solution was prepared by kneading with a machine, and applied with a wire bar to form a charge generation layer such that the film thickness after drying was 1 μm, thereby producing a photoreceptor.
実施例３
実施例１の感光層の組成を、無金属フタロシアニン５０
重量部、化合物Ｎ（Ｌ １で示されるエチレン化合物１
００重量部、ポリエステル樹脂（商品名バイロン２００
：東洋紡製）５０重量部、ＰＭＭＡ５０重量部とに変更
して実施例１と同様に感光層を形成し感光体を作製した
。Example 3 The composition of the photosensitive layer of Example 1 was changed to 50% metal-free phthalocyanine.
Parts by weight, compound N (ethylene compound 1 represented by L 1
00 parts by weight, polyester resin (trade name Byron 200
: manufactured by Toyobo) and 50 parts by weight of PMMA, a photosensitive layer was formed in the same manner as in Example 1, and a photoreceptor was produced.
実施例４
実施例３において、無金属フタロシアニンに変えて例え
ば特開昭４７−３７５４３に示されるようなビスアゾ顔
料であるクロログイアンブル−を用い実施例１と同様に
感光層を形成し感光体を作製した。Example 4 In Example 3, a photosensitive layer was formed in the same manner as in Example 1 using chlorodiambre, which is a bisazo pigment as disclosed in JP-A-47-37543, instead of metal-free phthalocyanine, and a photoreceptor was formed. Created.
このようにして得られた感光体の電子写真特性を川口電
機製静電記録紙試験装置ｒ Ｓ Ｐ−４２８Ｊを用いて
測定した。The electrophotographic properties of the photoreceptor thus obtained were measured using an electrostatic recording paper tester RSP-428J manufactured by Kawaguchi Electric.
感光体の表面電位ＶＳ （ボルト）は暗所で＋６．０ｋ
Ｖのコロナ放電を１０秒間行って感光体表面を正帯電せ
しめたときの初期の表面電位であり、続いてコロナ放電
を中止した状態で２秒間暗所保持したときの表面電位Ｖ
バボルト）を測定し、さらに続いて感光体表面に照度２
ルツクスの白色光を照射してＶ−が半分になるまでの時
間（秒）を求め半減衰露光ｆｉＥ＋／＊（ルックス・秒
）とした。また、照度２ルツクスの白色光を１０秒間照
射したときの表面電位を残留電位Ｖ、（ボルト）とした
。また、フタロシアニン化合物を電荷発生物質とした場
合、長波長光での高感度が期待できるので、波長７８０
ｎｍの単色光をもちいたときの電子写真特性も同時に測
定した。すなわち、Ｖｄ までは同様に測定し、次に白
色光の替わりに１μＷの単色光（７８００ｍ）を照射し
て半減衰露光量（μＪ／ａｍ）を求め、また、この光を
１０秒間感光体表面に照射したときの残留電位Ｖ、（ボ
ルト）を測定した。測定結果を第１表に示す。The surface potential VS (volts) of the photoreceptor is +6.0k in the dark.
This is the initial surface potential when corona discharge of V is performed for 10 seconds to positively charge the surface of the photoreceptor, and then the surface potential is V when held in the dark for 2 seconds with corona discharge stopped.
Babolt), and then the illuminance 2 on the surface of the photoreceptor.
The time (seconds) required for V- to be halved after irradiation with lux white light was determined and was defined as half-attenuation exposure fiE+/* (lux seconds). Further, the surface potential when white light with an illuminance of 2 lux was irradiated for 10 seconds was defined as the residual potential V (volt). In addition, when a phthalocyanine compound is used as a charge generating substance, high sensitivity with long wavelength light can be expected.
At the same time, electrophotographic properties were measured using monochromatic light of nm wavelength. That is, measurements are made in the same manner up to Vd, then 1 μW monochromatic light (7800 m) is irradiated instead of white light to determine the half-attenuation exposure amount (μJ/am), and this light is applied to the photoreceptor surface for 10 seconds. The residual potential V, (volt) was measured when irradiated with . The measurement results are shown in Table 1.
第 １ 表
第１表に見られるように、実施例１．２．３．４は半減
衰露光量、残留電位ともに良好であった。Table 1 As seen in Table 1, Examples 1.2.3.4 had good half-attenuation exposure and residual potential.
実施例５
厚さ５００μｍのアルミニウム板上に、セレンを厚さ１
．５μｍに真空蒸着し電荷発生層を形成し、次に、化合
物に２で示されるエチレン化合物１００重量部をテトラ
ヒドロフラン（ＴＨＦ）７圓重景部に溶かした液とポリ
メタク莱し酸メチルポリマー（ＰＭＭＡ：東京化成）１
００重量部をトルエン７００重量部に溶かした液とを混
合してできた塗液をワイヤーバーにて塗布し、乾燥後の
膜厚が２０μｍになるように電荷輸送層を形成した。こ
の感光体に−６，ＯｋＶのコロナ帯電を０．２秒間行い
、実施例４に準じて特性ヲ？１ｌｌｌ 定Ｌ タト、：
、 ロ、Ｖ、＝−８１０Ｖ、 Ｖｒ＝−７０Ｖ。Example 5 Selenium was deposited to a thickness of 1 on a 500 μm thick aluminum plate.
．． A charge generating layer was formed by vacuum deposition to a thickness of 5 μm, and then a solution prepared by dissolving 100 parts by weight of an ethylene compound represented by 2 in 7 μm of tetrahydrofuran (THF) and polymethyl methacrylate polymer (PMMA: Tokyo Kasei) 1
00 parts by weight dissolved in 700 parts by weight of toluene was applied using a wire bar to form a charge transport layer such that the film thickness after drying was 20 μm. This photoreceptor was corona charged at -6, OkV for 0.2 seconds, and the characteristics were determined according to Example 4. 1llll Constant L Tato:
, V, = -810V, Vr = -70V.
Ｅ 、、２ ＝３．９ルツクス・秒と良好な結果が得ら
れた。A good result was obtained with E,,2=3.9 lux·sec.
実施例６
実施例１で処理された無金属フタロシアニン５０重量部
、ポリエステル樹脂（商品名バイロン２００：東洋紡製
）５０重量部、ＰＭＭＡ５０重量部とＴＨＦ溶剤ととも
に３時間混合機により混練して塗布液を調整し、アルミ
ニウム支持体上に約１μｍになるように塗布し、電荷発
生層を形成した。次に、化合物Ｎα３で示されるエチレ
ン化合物１００重量部、ポリカーボネート樹脂（パンラ
イトＬ −１２５０） １００重量部、シリコンオイル
０．１重量部をＴ ＨＦ７００重量部とトルエン７００
重量部で混合し、電荷発生層の上に約１５μｍとなるよ
うに塗布し、電荷輸送層を形成し感光体を作製した。Example 6 50 parts by weight of the metal-free phthalocyanine treated in Example 1, 50 parts by weight of polyester resin (trade name Byron 200 manufactured by Toyobo), 50 parts by weight of PMMA and THF solvent were kneaded in a mixer for 3 hours to form a coating solution. The mixture was adjusted and coated on an aluminum support to a thickness of about 1 μm to form a charge generation layer. Next, 100 parts by weight of an ethylene compound represented by compound Nα3, 100 parts by weight of polycarbonate resin (Panlite L-1250), and 0.1 part by weight of silicone oil were mixed with 700 parts by weight of THF and 700 parts by weight of toluene.
The components were mixed in parts by weight and coated on the charge generation layer to a thickness of about 15 μm to form a charge transport layer to produce a photoreceptor.
このようにして得られた感光体に実施例５と同様にして
、−６，０ｋＶのコロナ帯電を０．２秒間行い、特性を
測定したところ、Ｖ、 ＝−８５０Ｖ、 Ｅ ｌ／２
＝４．１ルツクス・秒と良好な結果が得られた。The thus obtained photoreceptor was corona charged at -6.0 kV for 0.2 seconds in the same manner as in Example 5, and its characteristics were measured. V, = -850 V, E l/2
= 4.1 lux·sec, a good result was obtained.
実施例７
化合物Ｎα４〜３５それぞれについて実施例４と同様、
感光層を形成し感光体を作製しｒ Ｓ Ｐ−４２８Ｊを
用いて特性を測定した結果を第２表に示す。Example 7 Same as Example 4 for each of compounds Nα4 to 35,
A photoreceptor was prepared by forming a photosensitive layer, and its characteristics were measured using rSP-428J. The results are shown in Table 2.
暗所で＋６．０ｋＶのコロナ放電を１０秒間行い正帯電
せしめ、照度２ルツクスの白色光を照射した場合の半減
衰露光ＩＥ１／２（ルックス・秒）で示した。A corona discharge of +6.0 kV was performed for 10 seconds in a dark place to positively charge the sample, and the half-attenuation exposure IE1/2 (lux seconds) was shown when white light with an illuminance of 2 lux was irradiated.
第２表に見られるように、化合物Ｎα４〜３５を用いた
感光体にふいても良好な半減衰露光量が得られることが
判る。As seen in Table 2, it can be seen that a good half-attenuation exposure amount can be obtained even when the photoreceptor using compounds Nα4-35 is wiped.
第 ２ 表（その１）
第 ２ 表（その２）
〔発明の効果〕
本発明によれば、導電性基体上に設ける感光層の電荷輸
送性物質として前記一般式（Ｉ）で示されるエチレン化
合物を用いる事としたため、正帯電および負帯電におい
ても高感度でしかも繰り返し特性の優れた感光体を得る
事ができる。また、電荷発生物質は露光光源の種類に対
応して好適な物質を選ぶことができ、−例をあげると７
タロンアニン化合物およびある種のビスアゾ化合物を用
いれば半導体レーザブリンク−に使用可能な感光体を得
ることができる。さらに、必要に応じて表面に被覆層を
設置して耐久性を向上することが可能である。Table 2 (Part 1) Table 2 (Part 2) [Effects of the Invention] According to the present invention, the ethylene compound represented by the above general formula (I) is used as a charge transporting substance in the photosensitive layer provided on the conductive substrate. By using the photoreceptor, it is possible to obtain a photoreceptor with high sensitivity and excellent repeatability even in positive and negative charging. In addition, a suitable charge-generating substance can be selected depending on the type of exposure light source; for example, 7
By using talonanine compounds and certain bisazo compounds, it is possible to obtain photoreceptors that can be used for semiconductor laser blinking. Furthermore, if necessary, it is possible to provide a coating layer on the surface to improve durability.
第１．２．３図は本発明の感光体のそれぞれ異なる実施
例を示す概念的断面図である。
■ 導電性基体、３ 電荷発生物質、・１ 電荷発生層
、５ 電荷輸送性物質、６ 電荷輸送層、７ 被覆層、
２０．２１．２２ 感光層。1.2.3 are conceptual sectional views showing different embodiments of the photoreceptor of the present invention. ■ Conductive substrate, 3 charge-generating substance, 1 charge-generating layer, 5 charge-transporting substance, 6 charge-transporting layer, 7 coating layer,
20.21.22 Photosensitive layer.
Claims (1)
ちの少なくとも一種類を含む感光層を有することを特徴
とする電子写真用感光体。 ▲数式、化学式、表等があります▼・・・（ I ） （式（ I ）中、ｎ、ｍはそれぞれ０〜５の整数、Ｒ＿
１〜Ｒ＿１＿４はそれぞれ水素原子、ハロゲン原子、ヒ
ドロキシ基、アルキル基、アルコキシ基、アリル基、カ
ルボキシル基、エステル基、アリール基、シアノ基、ニ
トロ基、アミノ基、アルキルアミノ基、またはアリール
アミノ基を表す。Ｒ＿１＿５、Ｒ＿１＿６は水素原子、
低級アルキル基、またはアリール基を表す。）[Scope of Claims] 1) An electrophotographic photoreceptor characterized by having a photosensitive layer containing at least one kind of ethylene compound represented by the following general formula (I). ▲There are mathematical formulas, chemical formulas, tables, etc.▼...(I) (In formula (I), n and m are each integers from 0 to 5, R_
1 to R_1_4 each represent a hydrogen atom, a halogen atom, a hydroxy group, an alkyl group, an alkoxy group, an allyl group, a carboxyl group, an ester group, an aryl group, a cyano group, a nitro group, an amino group, an alkylamino group, or an arylamino group. represent. R_1_5 and R_1_6 are hydrogen atoms,
Represents a lower alkyl group or an aryl group. )
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP30687886A JPS63158559A (en) | 1986-12-23 | 1986-12-23 | Electrophotographic sensitive body |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP30687886A JPS63158559A (en) | 1986-12-23 | 1986-12-23 | Electrophotographic sensitive body |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS63158559A true JPS63158559A (en) | 1988-07-01 |
Family
ID=17962334
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP30687886A Pending JPS63158559A (en) | 1986-12-23 | 1986-12-23 | Electrophotographic sensitive body |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS63158559A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0466094A2 (en) * | 1990-07-10 | 1992-01-15 | Canon Kabushiki Kaisha | Electrophotographic photosensitive member |
-
1986
- 1986-12-23 JP JP30687886A patent/JPS63158559A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0466094A2 (en) * | 1990-07-10 | 1992-01-15 | Canon Kabushiki Kaisha | Electrophotographic photosensitive member |
| EP0757292A1 (en) * | 1990-07-10 | 1997-02-05 | Canon Kabushiki Kaisha | Electrophotographic photosensitive member |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JPH0279855A (en) | Electrophotographic sensitive body | |
| JPH01102469A (en) | Electrophotographic sensitive body | |
| JPS63158560A (en) | Electrophotographic sensitive body | |
| JPH032760A (en) | Electrophotographic sensitive body | |
| JPH0194349A (en) | Electrophotographic sensitive body | |
| JPS63158556A (en) | Electrophotographic sensitive body | |
| JPS63158559A (en) | Electrophotographic sensitive body | |
| JPH01273049A (en) | Electrophotographic sensitive body | |
| JPS63157159A (en) | Electrophotographic sensitive body | |
| JPS63158557A (en) | Electrophotographic sensitive body | |
| JPH0524505B2 (en) | ||
| JPS63158555A (en) | Electrophotographic sensitive body | |
| JPH01172965A (en) | Electrophotographic sensitive body | |
| JPH01107262A (en) | Electrophotographic sensitive body | |
| JPS63157161A (en) | Electrophotographic sensitive body | |
| JPS63157160A (en) | Electrophotographic sensitive body | |
| JPH01107263A (en) | Electrophotographic sensitive body | |
| JPH01152466A (en) | Electrophotographic sensitive body | |
| JPH01170945A (en) | Electrophotographic sensitive body | |
| JPS63192050A (en) | Electrophotographic sensitive body | |
| JPH01152463A (en) | Electrophotographic sensitive body | |
| JPS63192049A (en) | Electrophotographic sensitive body | |
| JPS63188146A (en) | Electrophotographic sensitive body | |
| JPS63183448A (en) | Electrophotographic sensitive body | |
| JPS63167370A (en) | Electrophotographic sensitive body |