JPS63157881A - Stainless product decorated with ceramic - Google Patents
Stainless product decorated with ceramicInfo
- Publication number
- JPS63157881A JPS63157881A JP30606886A JP30606886A JPS63157881A JP S63157881 A JPS63157881 A JP S63157881A JP 30606886 A JP30606886 A JP 30606886A JP 30606886 A JP30606886 A JP 30606886A JP S63157881 A JPS63157881 A JP S63157881A
- Authority
- JP
- Japan
- Prior art keywords
- stainless steel
- glaze
- adhesive
- metal powder
- base
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000919 ceramic Substances 0.000 title claims abstract description 18
- 229910001220 stainless steel Inorganic materials 0.000 claims abstract description 39
- 239000010935 stainless steel Substances 0.000 claims abstract description 39
- 239000000853 adhesive Substances 0.000 claims abstract description 35
- 230000001070 adhesive effect Effects 0.000 claims abstract description 35
- 229910052751 metal Inorganic materials 0.000 claims abstract description 21
- 239000002184 metal Substances 0.000 claims abstract description 21
- 239000000843 powder Substances 0.000 claims abstract description 19
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims abstract description 15
- GIOZLVMCHDGNNZ-UHFFFAOYSA-N magnesium;oxido-(oxido(dioxo)chromio)oxy-dioxochromium Chemical compound [Mg+2].[O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O GIOZLVMCHDGNNZ-UHFFFAOYSA-N 0.000 claims abstract description 4
- 235000011007 phosphoric acid Nutrition 0.000 claims description 7
- 229910019142 PO4 Inorganic materials 0.000 claims description 4
- 239000010452 phosphate Substances 0.000 claims description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 4
- 150000002681 magnesium compounds Chemical class 0.000 claims description 3
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims 1
- 239000002585 base Substances 0.000 abstract description 18
- 210000003298 dental enamel Anatomy 0.000 abstract description 16
- 229910052910 alkali metal silicate Inorganic materials 0.000 abstract description 6
- 238000005034 decoration Methods 0.000 abstract description 6
- 229910052725 zinc Inorganic materials 0.000 abstract description 6
- 229910052782 aluminium Inorganic materials 0.000 abstract description 5
- 229910000831 Steel Inorganic materials 0.000 abstract description 4
- 238000010438 heat treatment Methods 0.000 abstract description 4
- 239000010959 steel Substances 0.000 abstract description 4
- 239000011248 coating agent Substances 0.000 abstract description 3
- 238000000576 coating method Methods 0.000 abstract description 3
- 230000035939 shock Effects 0.000 abstract 1
- 235000019353 potassium silicate Nutrition 0.000 description 8
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 8
- 239000010953 base metal Substances 0.000 description 7
- 238000010304 firing Methods 0.000 description 7
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 5
- 229910052802 copper Inorganic materials 0.000 description 5
- 239000010949 copper Substances 0.000 description 5
- 239000011701 zinc Substances 0.000 description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 4
- 235000012239 silicon dioxide Nutrition 0.000 description 4
- ILRRQNADMUWWFW-UHFFFAOYSA-K aluminium phosphate Chemical compound O1[Al]2OP1(=O)O2 ILRRQNADMUWWFW-UHFFFAOYSA-K 0.000 description 3
- 239000001506 calcium phosphate Substances 0.000 description 3
- 229910000389 calcium phosphate Inorganic materials 0.000 description 3
- 235000011010 calcium phosphates Nutrition 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- GVALZJMUIHGIMD-UHFFFAOYSA-H magnesium phosphate Chemical compound [Mg+2].[Mg+2].[Mg+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O GVALZJMUIHGIMD-UHFFFAOYSA-H 0.000 description 3
- 239000004137 magnesium phosphate Substances 0.000 description 3
- 229910000157 magnesium phosphate Inorganic materials 0.000 description 3
- 229960002261 magnesium phosphate Drugs 0.000 description 3
- 235000010994 magnesium phosphates Nutrition 0.000 description 3
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 238000005238 degreasing Methods 0.000 description 2
- -1 magnesium Chemical class 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 238000005554 pickling Methods 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 239000004111 Potassium silicate Substances 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000002313 adhesive film Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 238000005422 blasting Methods 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 235000013365 dairy product Nutrition 0.000 description 1
- CMMUKUYEPRGBFB-UHFFFAOYSA-L dichromic acid Chemical compound O[Cr](=O)(=O)O[Cr](O)(=O)=O CMMUKUYEPRGBFB-UHFFFAOYSA-L 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000002320 enamel (paints) Substances 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000001056 green pigment Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- PAZHGORSDKKUPI-UHFFFAOYSA-N lithium metasilicate Chemical compound [Li+].[Li+].[O-][Si]([O-])=O PAZHGORSDKKUPI-UHFFFAOYSA-N 0.000 description 1
- 229910052912 lithium silicate Inorganic materials 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- QQFLQYOOQVLGTQ-UHFFFAOYSA-L magnesium;dihydrogen phosphate Chemical compound [Mg+2].OP(O)([O-])=O.OP(O)([O-])=O QQFLQYOOQVLGTQ-UHFFFAOYSA-L 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 150000004712 monophosphates Chemical class 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 229910052913 potassium silicate Inorganic materials 0.000 description 1
- NNHHDJVEYQHLHG-UHFFFAOYSA-N potassium silicate Chemical compound [K+].[K+].[O-][Si]([O-])=O NNHHDJVEYQHLHG-UHFFFAOYSA-N 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 238000005488 sandblasting Methods 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
Landscapes
- Other Surface Treatments For Metallic Materials (AREA)
Abstract
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明は、ステンレス鋼の表面にセラミックスを加飾し
た製品に関するものである。DETAILED DESCRIPTION OF THE INVENTION (Field of Industrial Application) The present invention relates to a product in which the surface of stainless steel is decorated with ceramics.
（発明が解決しようとする問題点）
従来、金属製品の加飾にはその金属板の種類に応じて、
夫々に対応した加飾方法がある。(Problem to be solved by the invention) Conventionally, decoration of metal products involves the following methods depending on the type of metal plate:
There are decoration methods for each type.
即ち、銅を主とした七宝は、成形後、油焼きした上に直
接七宝釉をかけ或いは薬品による酸洗い後に七宝釉をか
けて焼成を繰り返すことで製品化している。That is, cloisonné, which is mainly made of copper, is produced by molding, firing in oil, and directly applying cloisonné glaze, or by pickling with chemicals, applying cloisonné glaze, and repeating firing.
また、アルミニウムホーローは、アルカリ又は酸性脱脂
後に空焼きしてホーロー釉をかけ焼成して得る。Moreover, aluminum enamel is obtained by dry firing after alkali or acid degreasing, applying an enamel glaze, and firing.
鉄ホーローは、アルカリ脱脂や酸洗いを主とした前処理
後、下地軸をかけて仮焼し、さらに上釉をかけて焼成し
て得るのである。Iron enamel is obtained by pre-treating it mainly by alkaline degreasing and pickling, then applying a base shaft and calcining it, then applying a top glaze and firing it.
このような構成をステンレス鋼に施しても釉薬が融着し
ないため、従来のステンレスホーローの前処理としてサ
ンドブラストやショツトブラストでステンレス鋼表面を
物理的に粗くした後、ホーローかけをして密着性を向」
ニさせていたのであるしかしながら、これによると複雑
な形状の製品及び一部分だけに加飾することが困難であ
り、またステンレス鋼の表面を粗面化する前処理を必要
として面倒であり且つ使用中に剥離し易かった。Even if such a structure is applied to stainless steel, the glaze will not fuse. Therefore, as a pretreatment for conventional stainless steel enamel, the stainless steel surface is physically roughened by sandblasting or shot blasting, and then enameled to improve adhesion. "Toward"
However, this method makes it difficult to decorate only a part of a product with a complex shape, and requires pre-treatment to roughen the surface of the stainless steel, which is troublesome and difficult to decorate during use. It was easy to peel off.
そこで本発明は、従来困難であったステンレス鋼の表面
にセラミックス釉薬を密着できてセラミックス加飾の耐
衝撃性、耐摩耗性、耐剥離性を良好とするステンレス製
品を提供することを目的としている。Therefore, an object of the present invention is to provide a stainless steel product in which a ceramic glaze can be adhered to the surface of stainless steel, which has been difficult to do in the past, and the ceramic decoration has good impact resistance, abrasion resistance, and peeling resistance. .
（問題点を解決するための手段）
このため本発明は、金属粉を加えた珪酸アルカリ接着剤
、金属粉を加えたリン酸塩系無機接着剤、オルトリン酪
液中に金属粉と重クロム酸マグネシウム等のマグネシウ
ム化合物を混合したオルトリン酸系接着剤の一種もしく
は二種以上を混合して成る耐熱性の下地用接着剤を用い
、これをステンレス鋼に接着すると共にその上にセラミ
ックス釉薬を被着して加熱し、或いは該下地用接着剤を
セラミックス釉薬に混合してステンレス鋼に付着し加熱
して成ることを構成としている。(Means for Solving the Problems) Therefore, the present invention provides an alkali silicate adhesive containing metal powder, a phosphate-based inorganic adhesive containing metal powder, and a metal powder and dichromic acid in ortholine dairy liquid. Using a heat-resistant base adhesive made of one or more orthophosphoric acid adhesives mixed with magnesium compounds such as magnesium, this is bonded to stainless steel and a ceramic glaze is applied on top of it. Alternatively, the base adhesive may be mixed with a ceramic glaze and applied to stainless steel and then heated.
（イ）ここで金属粉を加えた珪酸アルカリ接着剤とは、
珪酸カリ、珪酸ソーダ、珪酸リチウム等の珪酸アルカリ
の何れか一種もしくは二種以上が混合された珪酸アルカ
リ系接着剤にアルミニウム、亜鉛、銅、鉄、カルシウム
、マグネシウム、バリウム等２価又は３価の金属もしく
はその酸化物の一種もしくは二種以上を珪酸アルカリ中
の珪酸に対して０．１〜２．０モル加えて構成する。(b) Here, what is an alkali silicate adhesive with metal powder added?
Divalent or trivalent adhesives such as aluminum, zinc, copper, iron, calcium, magnesium, barium, etc. are added to an alkali silicate adhesive that is a mixture of one or more alkali silicates such as potassium silicate, sodium silicate, and lithium silicate. It is constituted by adding 0.1 to 2.0 moles of one or more metals or their oxides to the silicic acid in the alkali silicate.
（σ）またリン酸塩系無機質接着剤は、例えば、リン酸
アルミニウム、リン酸マグネシウム、リン酸カルシウム
等、リン酸塩に２価もしくは３価の金属粉を含有して成
るものでその一種もしくは二種以上の混合物である。こ
こで金属粉の添加量は０゜１〜２．０モル加えるのがよ
い。(σ) Phosphate-based inorganic adhesives include one or two types of phosphate containing divalent or trivalent metal powder, such as aluminum phosphate, magnesium phosphate, and calcium phosphate. It is a mixture of the above. The amount of metal powder to be added is preferably 0.1 to 2.0 moles.
（ハ）さらに、オルトリン酸系接着剤は、オルトリン酸
水溶液に重クロム酸マグネシウム、醇化マグネシウム、
モノリン酸マグネシウム等のマグネシウム化合物を混合
し、さらにアルミニウム、亜鉛、銅等のいずれか一種も
しくは二種以上の金属粉末を加えて成るものである。こ
こで金属粉の添加量は０．１〜２．０モル加えるのがよ
い。(c) Furthermore, orthophosphoric acid adhesives include magnesium dichromate, magnesium chloride, etc. in an orthophosphoric acid aqueous solution.
It is made by mixing a magnesium compound such as magnesium monophosphate, and further adding one or more metal powders such as aluminum, zinc, copper, etc. Here, the amount of metal powder added is preferably 0.1 to 2.0 moles.
（ニ）そして、成形したステンレス鋼地金に該下地用接
着剤を塗布した後、陶磁器軸、ホーロー釉。(d) Then, after applying the base adhesive to the formed stainless steel base metal, the ceramic shaft and enamel glaze were applied.
七宝釉等のセラミックス釉を適宜に接着剤五に施釉し焼
成してステンレス製品を得るのである。A stainless steel product is obtained by applying a ceramic glaze such as cloisonné glaze to an appropriate adhesive and firing it.
或いｌ±、加飾源であるセラミックス釉薬中に、釉薬重
量（風乾重量）の１０％以下の該下地接着剤を混合して
成形したステンレス鋼地金に施釉し焼成してステンレス
製品を得るのである。Alternatively, a stainless steel base metal is formed by mixing the base adhesive in an amount of 10% or less of the weight of the glaze (air-dried weight) into a ceramic glaze that is a decoration source, and then glazing and firing to obtain a stainless steel product. It is.
以下、本発明の実施例について説明する。Examples of the present invention will be described below.
なお、いずれもステンレス鋼地金は１８−８ステンレス
鋼板を予め７００°Ｃ出焼き、表面の油分、有機分を除
去し、１／１ ＯＮ硫酸で酸洗いし、水洗い後、次いで
１／ＩＯＮアンモニア水で中和、水洗いの後乾燥させた
ものを用いた。In each case, the stainless steel base metal is an 18-8 stainless steel plate that is baked at 700°C to remove surface oil and organic content, pickled with 1/1 ON sulfuric acid, washed with water, and then soaked in 1/ION ammonia. It was neutralized with water, washed with water, and then dried.
（実施例１）
３号水ガラスにその含まれる珪酸に対して１モ塗の亜鉛
粉を混合して成る下地用接着剤をステンレス鋼地金に塗
布した後、１８−８ステンレスの膨張係数９．５Ｘ１（
１６に近いＫＮａＯ２０重量％、ＣａＦ２５重量％、Ａ
ｌ２０３５重量％。(Example 1) After applying a base adhesive made of No. 3 water glass mixed with 1 mo coating of zinc powder to the silicic acid contained in the stainless steel base metal, the expansion coefficient of 18-8 stainless steel was 9. .5X1(
KNaO 20% by weight, CaF 25% by weight, A
l2035% by weight.
Ｂ２０３１５重量％、５ｉ０２５５重量％）配合物に対
し Ｃａ３０ａ ２．３０重量％、酸化ニッケルー酸
化クロム−重クロム酸カリ系緑色顔料３％を加えて成る
釉泥漿を該接着剤上に塗布し、９００′Ｃに加熱して良
好なステンレスホーロー、１１ＨＷｊ品を得た。A glaze slurry made by adding 2.30% by weight of Ca30a and 3% of a nickel oxide-chromium oxide-potassium dichromate green pigment to the mixture (B20315% by weight, 5i0255% by weight) was applied onto the adhesive, and 900' C. to obtain a good stainless steel enamel, 11HWj product.
水加飾品のステンレス鋼と釉との接着面における引っ張
り強さは７４０ ｋｇ／ ｃｍ２ であった。The tensile strength of the water-decorated product at the adhesive surface between the stainless steel and the glaze was 740 kg/cm2.
また、５００ｇのスチールポールを加飾重上１ｍから落
とした落下試験結果は、釉面が貝殻状に破壊したものの
破壊面におけるステンレス地金は全く見えない程釉薬と
鋼板との接着は強固であった。なお、下地用接着剤とし
て１号水力ラス、２号水ガラスを使用しても３号水ガラ
ス同様の効果を呈し２、水ガラスの種類によるステンレ
ス釉薬への接着性、耐熱性への変化は認められなかった
。In addition, a drop test result in which a 500g steel pole was dropped from 1m above a decorative weight showed that although the glaze surface broke in a shell-like manner, the adhesion between the glaze and the steel plate was so strong that no stainless steel was visible on the broken surface. Ta. Furthermore, even if No. 1 water glass or No. 2 water glass is used as the base adhesive, it will have the same effect as No. 3 water glass. 2 The adhesion to stainless steel glaze and heat resistance will change depending on the type of water glass. I was not able to admit.
また、亜鉛に替えて銅、鉄の金属粉を水ガラス中の珪酸
に対して１モル加えた下地用接着剤としてステンレス鋼
地金に塗布し、ついで七宝用フリット釉薬を塗布し７０
０ ’Ｏに加熱して得たものも本例と同様にステンレス
地金並びに釉薬との接着性等の性質は良好であった。In addition, instead of zinc, metal powders of copper and iron were added to 1 mole of silicic acid in water glass and applied to the stainless steel base metal as a base adhesive, and then a frit glaze for cloisonné was applied.
The material obtained by heating to 0'O also had good properties such as adhesion to the stainless steel base metal and glaze, similar to this example.
（実施例２）
リン酸アルミニウム、リン酸マグネシウム、リン酸カル
シウムを３：２：５の割合で混合して成る下地用接着剤
をステンレス地金に塗布し、その上へホーロー釉薬を塗
布した後、８００℃に加熱してステンレスホーロー加飾
品を得た。(Example 2) A base adhesive made of a mixture of aluminum phosphate, magnesium phosphate, and calcium phosphate in a ratio of 3:2:5 was applied to a stainless steel base metal, and after applying enamel glaze on top of it, 800 It was heated to ℃ to obtain a stainless steel enamel decorated product.
しかし、このホーロー塗膜は、金属粉を加えた水ガラス
塗膜よりやや衝撃強度に劣ったが、実用的には、使用上
問題がなかった。However, although this enamel coating was slightly inferior in impact strength to the water glass coating coated with metal powder, there were no problems in practical use.
なおリン酸アルミニウム、リン酸マグネシウム、リン酸
カルシウムの一種もしくは二種以上の任意割合に混合し
て下地用接着剤を用いても同様であった。Note that the same results were obtained when one or more of aluminum phosphate, magnesium phosphate, and calcium phosphate were mixed in arbitrary proportions to form the base adhesive.
（実施例３）
オルトリン酸水溶液に、重クロム酸マグネシウム、酸化
マグネシウム、モノリン酸マクネンウムを３：２：５の
割合でオルトリン酸水溶液の７０％容量まで混合し、さ
らにアルミニウム ０．２モル、亜鉛 ０．５モル、銅
０．３モルを混合して成る下地用接着剤をステンレス
鋼板に塗布し、この上−＼七宝釉を盛り付けて７００
’（！乃至８５０ ’Ｏに加熱してステンレス上に強固
に接着した下地釉薬を得た。(Example 3) Magnesium dichromate, magnesium oxide, and macanenium monophosphate were mixed into an aqueous orthophosphoric acid solution in a ratio of 3:2:5 to a volume of 70% of the aqueous orthophosphoric acid solution, and further 0.2 mol of aluminum and 0 mol of zinc were added. A base adhesive consisting of a mixture of 0.5 mol and 0.3 mol of copper was applied to a stainless steel plate, and a cloisonné glaze was applied on top of it.
'(! to 850 'O) to obtain a base glaze that firmly adhered to the stainless steel.
（実施例４）
ステンレス鋼に、実施例（＋）と実施例（２）との接着
剤を１：１の重量比に混合して成る下地用接着剤を塗布
し、その上へホーロー釉を吹き付けて波箔させた後、８
５０℃に加熱してステンレス鋼にホーロー釉が強固に融
着したホーロー加飾品を得た。(Example 4) A base adhesive made by mixing the adhesives of Example (+) and Example (2) at a weight ratio of 1:1 was applied to stainless steel, and enamel glaze was applied on top of it. After spraying and making corrugated foil, 8
By heating to 50° C., an enamel decorated product in which the enamel glaze was firmly fused to the stainless steel was obtained.
なお、実施例（１）〜（４）において、多色化した模様
を得るには、ホーロー、七宝の夫々の加飾技法を用いる
ことはもちろんである。In addition, in Examples (1) to (4), in order to obtain multicolored patterns, it goes without saying that the decoration techniques of enamel and cloisonné are used.
また、ホーロー釉の代わりに８００℃〜１１００′Ｃの
低温で溶ける陶磁器釉をステンレスに重ねて塗布しても
強固な陶磁器釉の加飾されたステンレス製品が得られた
。Further, instead of the enamel glaze, a ceramic glaze that melts at a low temperature of 800°C to 1100'C was applied over the stainless steel, and a strong stainless steel product decorated with a ceramic glaze could be obtained.
（実施例５）
３号ガラスに、その含まれる珪酸に対し１モルの金属亜
鉛を混合した下地用接着剤とホーロー釉薬とを１：５０
比に混合して成る混在物を、充分洗浄したステンレス鋼
に吹き付けて付着させた後、８５０°Ｃに加熱してステ
ンレス鋼のホーロー加飾品を得た。(Example 5) A base adhesive prepared by mixing 1 mole of metallic zinc with respect to the silicic acid contained in No. 3 glass and enamel glaze at a ratio of 1:50.
The mixed substance was sprayed onto thoroughly cleaned stainless steel to make it adhere to the mixture, and then heated to 850°C to obtain a stainless steel enamel decorated product.
耐衝撃性等の耐久性は実施例（１）と同等であった。Durability such as impact resistance was equivalent to Example (1).
なお、各実施例共、金属粉の添加量を０．１〜２モルの
範囲で変化させて実験したがいずれも充分な耐久性に耐
える加飾面を得た。好ましくはそれが１モル付近添加し
たものが最も強固な接着被膜となったのである。In each of the examples, experiments were conducted by varying the amount of metal powder added in the range of 0.1 to 2 moles, and in all cases a decorated surface with sufficient durability was obtained. Preferably, the strongest adhesive film was obtained when approximately 1 mol of it was added.
Claims (1)
えたリン酸塩系無機接着剤、オルトリン酸液中に金属粉
と重クロム酸マグネシウム等のマグネシウム化合物を混
合したオルトリン酸系接着剤の一種もしくは二種以上を
混合して成る耐熱性の下地用接着剤を用い、これをステ
ンレス鋼に接着すると共にその上にセラミックス釉薬を
被着して加熱し、或いは該下地用接着剤をセラミックス
釉薬に混合してステンレス鋼に付着し加熱して成るセラ
ミックスを加飾したステンレス製品。(1) Alkaline silicate adhesive with metal powder added, phosphate-based inorganic adhesive with metal powder added, orthophosphoric acid adhesive with metal powder and magnesium compound such as magnesium dichromate mixed in orthophosphoric acid solution A heat-resistant base adhesive consisting of one or more of the above is used, and this is bonded to stainless steel, and a ceramic glaze is applied and heated, or the base adhesive is coated with a ceramic glaze. Stainless steel products decorated with ceramics that are mixed with glaze, attached to stainless steel, and heated.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP30606886A JPS63157881A (en) | 1986-12-22 | 1986-12-22 | Stainless product decorated with ceramic |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP30606886A JPS63157881A (en) | 1986-12-22 | 1986-12-22 | Stainless product decorated with ceramic |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS63157881A true JPS63157881A (en) | 1988-06-30 |
Family
ID=17952658
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP30606886A Pending JPS63157881A (en) | 1986-12-22 | 1986-12-22 | Stainless product decorated with ceramic |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS63157881A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH08302486A (en) * | 1995-05-10 | 1996-11-19 | Nippon Fueroo Kk | Enamel glaze for stainless steel |
-
1986
- 1986-12-22 JP JP30606886A patent/JPS63157881A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH08302486A (en) * | 1995-05-10 | 1996-11-19 | Nippon Fueroo Kk | Enamel glaze for stainless steel |
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