JPS63156574A - Method for coating polyphenylene oxide resin - Google Patents
Method for coating polyphenylene oxide resinInfo
- Publication number
- JPS63156574A JPS63156574A JP61302778A JP30277886A JPS63156574A JP S63156574 A JPS63156574 A JP S63156574A JP 61302778 A JP61302778 A JP 61302778A JP 30277886 A JP30277886 A JP 30277886A JP S63156574 A JPS63156574 A JP S63156574A
- Authority
- JP
- Japan
- Prior art keywords
- parts
- resistance
- resin
- coating
- polyphenylene oxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000004721 Polyphenylene oxide Substances 0.000 title claims abstract description 20
- 229920006380 polyphenylene oxide Polymers 0.000 title claims abstract description 20
- 229920005989 resin Polymers 0.000 title claims abstract description 20
- 239000011347 resin Substances 0.000 title claims abstract description 20
- 239000011248 coating agent Substances 0.000 title claims abstract description 13
- 238000000576 coating method Methods 0.000 title claims abstract description 13
- 238000000034 method Methods 0.000 title claims abstract description 6
- 239000003973 paint Substances 0.000 claims abstract description 17
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims abstract description 9
- 239000012948 isocyanate Substances 0.000 claims abstract description 8
- 150000002513 isocyanates Chemical class 0.000 claims abstract description 8
- 229920005862 polyol Polymers 0.000 claims abstract description 8
- 150000003077 polyols Chemical class 0.000 claims abstract description 8
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims abstract description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 9
- 239000003513 alkali Substances 0.000 abstract description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 abstract 1
- 238000012360 testing method Methods 0.000 description 15
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 12
- 230000000052 comparative effect Effects 0.000 description 11
- 229920001225 polyester resin Polymers 0.000 description 10
- 239000004645 polyester resin Substances 0.000 description 10
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 8
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 8
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 8
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 6
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 6
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 5
- 239000008096 xylene Substances 0.000 description 5
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
- 239000001361 adipic acid Substances 0.000 description 4
- 235000011037 adipic acid Nutrition 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 4
- SVONRAPFKPVNKG-UHFFFAOYSA-N 2-ethoxyethyl acetate Chemical compound CCOCCOC(C)=O SVONRAPFKPVNKG-UHFFFAOYSA-N 0.000 description 3
- 239000004593 Epoxy Substances 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 3
- 238000009833 condensation Methods 0.000 description 3
- 230000005494 condensation Effects 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 238000000935 solvent evaporation Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 2
- 238000010422 painting Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000002253 acid Substances 0.000 description 1
- 239000002390 adhesive tape Substances 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 238000006482 condensation reaction Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 229920006351 engineering plastic Polymers 0.000 description 1
- 125000003700 epoxy group Chemical group 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 229920006122 polyamide resin Polymers 0.000 description 1
- -1 polyamide resin Chemical class 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
Landscapes
- Application Of Or Painting With Fluid Materials (AREA)
- Coating Of Shaped Articles Made Of Macromolecular Substances (AREA)
Abstract
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明はポリフェニレンオキサイド（ＰＰＯ）樹脂への
塗装方法に関するものである。DETAILED DESCRIPTION OF THE INVENTION (Industrial Field of Application) The present invention relates to a method for coating polyphenylene oxide (PPO) resin.
（従来の技術）
ｐｐｏ樹脂は機械的強度、電気的特性、耐熱性、耐水性
等の緒特性にすぐれているため、自動車分野をはじめと
し電気、通信分野等広範囲の用途に用いられている。こ
のようなＰＰＯ樹脂に塗装を施す場合には、通常次に示
す塗料が用いられている。(Prior Art) PPO resin has excellent properties such as mechanical strength, electrical properties, heat resistance, and water resistance, so it is used in a wide range of applications including the automobile field, electricity, and communication fields. When painting such PPO resin, the following paints are usually used.
ｉ）溶剤蒸発型塗料
有機溶剤が蒸発するだけで塗膜を形成する塗料で、この
ために樹脂自体は初めから分子量の相当高いものが用い
られている。i) Solvent evaporation type paint A paint that forms a coating film simply by evaporation of an organic solvent, and for this reason, the resin itself used has a fairly high molecular weight from the beginning.
１ｉ）２液エポキシ塗料
エポキシ樹脂（個々の分子中に２個以上のエポキシ基を
もつ樹脂）のもつ硬化機能を発揮させるため、アミン、
ポリアミド樹脂など活性水素をもつ物質を、使用直前に
添加するものである。1i) Two-component epoxy paint In order to exhibit the curing function of epoxy resin (resin with two or more epoxy groups in each molecule), amine,
A substance containing active hydrogen, such as polyamide resin, is added immediately before use.
（発明が解決しようとする問題点）
しかしながら上記溶剤蒸発型塗料および２液エポキシ塗
料を用いるｐｐｏ樹脂への塗装方法にあっては、溶剤蒸
発型塗料の場合は該塗料が耐薬品性、耐傷付性および耐
候性が悪いため、これ等の特性が要求される場合には使
用することかてりきない。また２液エポキシ塗料の場合
も、耐候性が悪いため自動車外装部品等の厳しい性能が
要求される場合には更に上塗り塗料を塗布する必要があ
り、塗装工程が増加するという問８点がある。(Problems to be Solved by the Invention) However, in the method of coating PPO resin using the above-mentioned solvent evaporation paint and two-component epoxy paint, in the case of a solvent evaporation paint, the paint has chemical resistance and scratch resistance. Because of its poor durability and weather resistance, it cannot be used when these properties are required. In addition, two-component epoxy paints also have poor weather resistance, so when severe performance is required, such as in automobile exterior parts, it is necessary to apply an additional top coat, which increases the number of painting steps.
（問題点を解決するための手段）
本発明者は、上記問題点を解決すべく種々研究の結果、
水酸基価２０〜６０ＫＯ）１■／ｇ、分子Ｍ３゜５００
〜５，０００のポリオールとイソシアネートから成る２
液ウレタン塗料をポリフェニレンオキサイド（ＰＰＯ）
樹脂の被塗装面に塗装する場合に、塗膜とｐｐｏ樹脂と
の密着性が著しく良好であると共に上記問題点が解決さ
れることを確かめた。(Means for Solving the Problems) As a result of various studies to solve the above problems, the present inventor has found that
Hydroxyl value 20-60KO) 1■/g, molecule M3゜500
~5,000 polyols and isocyanates2
Polyphenylene oxide (PPO) liquid urethane paint
When coating a resin surface, it was confirmed that the adhesion between the coating film and the PPO resin was extremely good and the above problems were solved.
（作 用）
上記２液ウレタン塗料において、ポリオールの水酸基価
が２０より小さくなると塗料の粘着性、耐溶剤性が悪（
なり、一方６０を越えるとｐｐｏ樹脂素材との密着性が
低下して好ましくない。(Function) In the above two-component urethane paint, if the hydroxyl value of the polyol is less than 20, the adhesiveness and solvent resistance of the paint will be poor (
On the other hand, if it exceeds 60, the adhesion to the PPO resin material decreases, which is not preferable.
またポリオールの分子量が３．５００より小さくなると
粘着性が生じ、５，０００を越えると塗装作業性が悪く
なり好ましくない。Moreover, if the molecular weight of the polyol is less than 3.500, stickiness will occur, and if it exceeds 5,000, coating workability will deteriorate, which is not preferable.
上記ポリオールとしては２７〜３０重量％の無水フタル
酸を含むポリエステル樹脂を用いるのが好ましい。無水
フタル酸を２７〜３０重量％とするのは速乾性をもたせ
、ＰＰＯ素材に密着性のよいラーカータイプに近づける
ためである。As the polyol, it is preferable to use a polyester resin containing 27 to 30% by weight of phthalic anhydride. The reason why the phthalic anhydride content is 27 to 30% by weight is to provide quick-drying properties and to approximate a lurker type with good adhesion to the PPO material.
（実験例） 次に本発明を実施例および比較例により更に説明する。(Experiment example) Next, the present invention will be further explained with reference to Examples and Comparative Examples.
尚実施例および比較例における「部」及び「％」は特記
しない限り重量による。Note that "parts" and "%" in Examples and Comparative Examples are by weight unless otherwise specified.
止較貫上
脱水縮合反応が可能なデカンタ−／還流冷却器を備えた
２１のフラスコに１００部のキシレンを供給した後無水
フタル酸１９７部、アジピン酸３９５部、エチレングリ
コール５５部、トリメチロールプロパン３０６部を１６
０〜２１０°Ｃの温度に加熱して生成する縮合水を連続
的に除去しながら６時間反応を行ないセロソルブアセテ
ートで希釈して分子量３，０００、水酸基価６０ＫＯ１
ｌ ｍｇ／ｇのポリエステル樹脂を得た。このポリエス
テル樹脂（不発渾分６０％） ６０部に酸化チタン３５
部、酢酸ブチル５部を加え、イソシアネート（住友バイ
エルウレタン（株）製、「スミジュールＮ７５Ｊ）を１
５部加え、酢酸ブチル／トルエン＝１７１のシンナー３
０部で希釈し、７０Ｘ１５０ ｗａのｐｐｏ樹脂（エン
ジニアリング・プラスチック （株）製ＥＢＮ９００１
）板に塗装した。このようにして塗膜厚３５μｌの試験
片を得た。After supplying 100 parts of xylene to 21 flasks equipped with a decanter/reflux condenser capable of a dehydration condensation reaction, 197 parts of phthalic anhydride, 395 parts of adipic acid, 55 parts of ethylene glycol, and trimethylolpropane were added. 306 copies to 16
The reaction was carried out for 6 hours while heating to a temperature of 0 to 210°C and condensation water produced was continuously removed, and diluted with cellosolve acetate to give a molecular weight of 3,000 and a hydroxyl value of 60 KO1.
1 mg/g of polyester resin was obtained. 60 parts of this polyester resin (60% unexploded content) and 35 parts of titanium oxide
1 part of butyl acetate, and 1 part of isocyanate ("Sumidur N75J" manufactured by Sumitomo Bayer Urethane Co., Ltd.).
Add 5 parts of butyl acetate/toluene = 171 thinner 3
Dilute with 0 parts and use 70 x 150 wa of PPO resin (EBN9001 manufactured by Engineering Plastics Co., Ltd.).
) painted on the board. In this way, a test piece with a coating thickness of 35 μl was obtained.
１指貫上
比較例１と同様なフラスコに１００部のキシレンを供給
した後、無水フタル酸２５３部、アジピン酸２５４部、
ネオペンチルグリコール１００部およびトリメチロール
プロパン３０５部を１５０〜１９０°Ｃに加熱して生成
する縮合水を連続的に除去しながら５時間反応を行ない
セロソルブアセテートで希釈して分子量４，５００ 、
水酸基価３５ＫＯＨｍｇ／ｇのポリエステル樹脂を得た
。このポリエステル樹脂（不揮発分６０％）６０部に、
酸化チタン３５部、酢酸ブチル５部を加え、イソシアネ
ート、「スミジュールＮ７５」を１０部加え、酢酸ブチ
ル／トルエン＝１７１のシンナー３０部で希釈し、比較
例１と同様にしてｐｐｏ樹脂板に塗布し試験片を得た。After feeding 100 parts of xylene into a flask similar to Comparative Example 1, 253 parts of phthalic anhydride, 254 parts of adipic acid,
100 parts of neopentyl glycol and 305 parts of trimethylolpropane were heated to 150 to 190°C, the reaction was carried out for 5 hours while continuously removing the water of condensation produced, and the mixture was diluted with cellosolve acetate to give a molecular weight of 4,500.
A polyester resin having a hydroxyl value of 35 KOHmg/g was obtained. To 60 parts of this polyester resin (60% non-volatile content),
Add 35 parts of titanium oxide and 5 parts of butyl acetate, add 10 parts of isocyanate "Sumidur N75", dilute with 30 parts of butyl acetate/toluene = 171 thinner, and apply to a PPO resin board in the same manner as Comparative Example 1. A test piece was obtained.
実ｍ％
比較例１と同様なフラスコに１００部のキシレンを供給
した後無水フタル酸３０４部、アジピン酸２８０部を１
５０〜１９０°Ｃの温度に加熱して生成する縮合水を連
続的に除去しながら反応を行ない、セロソルブアセテー
トで希釈して分子量５．０００ 、水酸基価２０ Ｋ
０１１■／ｇのポリエステル樹脂（不揮発分６０％）を
得た。このポリエステル樹脂６０部に酸化チタン３５部
、酢酸ブチル５部を加え、更にイソシアネート「スミジ
ュールＮ７５」を４部加え、酢酸ブチル／トルエン＝１
７１のシンナー３０部で希釈し、比較例１と同様にして
ＰＰＯ樹脂板に塗布し試験片を得た。Actual m% After feeding 100 parts of xylene into a flask similar to Comparative Example 1, 304 parts of phthalic anhydride and 280 parts of adipic acid were added to 1
The reaction is carried out while continuously removing the condensed water produced by heating to a temperature of 50 to 190°C, and diluted with cellosolve acetate to give a molecular weight of 5.000 and a hydroxyl value of 20 K.
A polyester resin (non-volatile content: 60%) with a weight of 0.011 cm/g was obtained. To 60 parts of this polyester resin, 35 parts of titanium oxide and 5 parts of butyl acetate were added, and 4 parts of isocyanate "Sumidur N75" were added, and butyl acetate/toluene = 1
The mixture was diluted with 30 parts of No. 71 thinner and applied to a PPO resin plate in the same manner as in Comparative Example 1 to obtain a test piece.
尖膳拠主
比較例１と同様なフラスコに１００部のキシレンを供給
した後、アジピン酸３２３部、無水フタル酸３２５部、
トリメチロールプロパン４２０ 部ヲ１６０〜２００°
Ｃの温度で加熱して生成する縮合水を連続的に除去しな
がら６時間反応を行ない、セロソルブアセテートで希釈
して分子ｆｆ１３，５００、水酸基価３ｏｘｏｏ ｍｇ
／ｇのポリエステル樹脂（不揮発分６０％）を得た。こ
のポリエステル樹脂６０部に酸化チタン３５部、酢酸ブ
チル５部を加え、更にイソシアネート［スミジュールＮ
７５」を８部加え、酢酸ブチル／トルエン＝１７１のシ
ンナー３０部で希釈し、比較例１と同様にしてｐｐｏ樹
脂板に塗装して試験片を作製した。After feeding 100 parts of xylene into a flask similar to Comparative Example 1, 323 parts of adipic acid, 325 parts of phthalic anhydride,
Trimethylolpropane 420 parts 160-200°
The reaction was carried out for 6 hours while continuously removing condensation water produced by heating at a temperature of
/g of polyester resin (non-volatile content: 60%) was obtained. To 60 parts of this polyester resin, 35 parts of titanium oxide and 5 parts of butyl acetate were added, and furthermore, isocyanate [Sumidur N
75'' was added, diluted with 30 parts of butyl acetate/toluene=171 thinner, and painted on a PPO resin board in the same manner as in Comparative Example 1 to prepare a test piece.
ル較斑Ｉ
比較例１と同様なフラスコに１００部のキシレンを供給
した後、ポリエステル樹脂としてデスモフェン０６７０
（分子量２０００、水酸基価１４３、住友バイエルウ
レタン（株）製）３５部とイソシアネート「スミジュー
ルＮ７５Ｊ２５部と、酸化チタン３５部を加え、酢酸ブ
チル／トルエン＝１７１のシンナー３５部で希釈し、比
較例１と同様にしてｐｐｏ樹脂板に塗装して試験片を作
製した。Comparison I After feeding 100 parts of xylene into a flask similar to Comparative Example 1, Desmophene 0670 was added as a polyester resin.
Comparative Example A test piece was prepared by coating a PPO resin plate in the same manner as in 1.
上記実施例１〜３および比較例１〜２の試験片につき塗
膜性能を次の測定方法により評価し、得た結果を表１に
示す。The coating film performance of the test pieces of Examples 1 to 3 and Comparative Examples 1 to 2 was evaluated by the following measuring method, and the obtained results are shown in Table 1.
（イ）初期密着性
試験片の塗膜面にマルチクロスカッタを用い素地に軽く
達する等間隔ＩＩＷの平行線をたがいに直交させて引き
、１１ｕ１１平方の正方形を２５個つくる。この状態で
幅に余裕のある粘着テープを密着させ上方に一気に引き
はがし塗面のはがれの生じない正方形の数を調べ、Ｏ：
２５／２５ 、Ｘ ： ０／２５として評価する。(a) Initial adhesion On the coated surface of the test piece, use a multi-cross cutter to draw parallel lines at equal intervals IIW that lightly reach the substrate, orthogonal to each other, to create 25 11x11 squares. In this state, adhere a piece of adhesive tape that has enough width and peel it upwards at once to check the number of squares that will not peel off the painted surface.O:
25/25, X: Evaluated as 0/25.
（ロ）耐温水性
ＪＩＳに５４００７．２に準拠し、試験片を４０°Ｃの
温水中に２４０時間浸漬して測定する。(b) Hot water resistance Measurement is performed by immersing a test piece in 40°C warm water for 240 hours in accordance with JIS 54007.2.
（ハ）耐湿性
温度、湿度とも調整可能な密閉箱を使用し、試験片を温
度５０″Ｃ１相対湿度９５％に調整した密閉箱に水平に
おき、２４時間ごとにふくれの発生およびその変化の状
態を調べ２４０時間まで行う。(c) Moisture resistance Use a sealed box in which both temperature and humidity can be adjusted. Place the test piece horizontally in the sealed box adjusted to a temperature of 50" C1 and relative humidity of 95%, and check the occurrence of blistering and its changes every 24 hours. Check the condition and continue for up to 240 hours.
（ニ）耐ガソリン性
ＪＩＳに５４００７．７に準拠し、試験片を室温でガソ
リン中に３０分浸漬して測定する。(d) Gasoline resistance Measured according to JIS 54007.7 by immersing a test piece in gasoline at room temperature for 30 minutes.
（ホ）耐酸性
ＪＩＳ Ｋ５４００７．５に準拠し、試験片を室温で１
％）１２５０．溶液中に４時間浸漬して測定する。(E) Acid resistance In accordance with JIS K54007.5, test the test piece at room temperature.
%) 1250. Measurement is performed by immersing the sample in the solution for 4 hours.
（へ）耐アルカリ性
ＪＩＳに５４００７．４に準拠し、試験片を室温で５％
ＮａＯＨ溶液中に４時間浸漬して測定する。(f) Alkali resistance In accordance with JIS 54007.4, the test piece is 5% at room temperature.
Measurement is performed by immersing in NaOH solution for 4 hours.
（ト）耐候性
サンシャインウエザオメータ（スガ試験機（株）製、５
Ｍカラーコンピューター）により測定する。(G) Weather-resistant Sunshine Weather-Ometer (manufactured by Suga Test Instruments Co., Ltd., 5)
Measured using M color computer).
光沢保持率＝試験後の光沢／初期光沢
ΔＥ−色差
表１
（発明の効果）
以上説明してきたように、この発明においては、ｐｐｏ
樹脂の被塗装面に水酸基価２０〜６０ＫＯＨｍｇ／ｇで
分子量３，５００〜５，０００のポリオールとイソシア
ネ′−トから成る２液ウレタン塗料を用いて塗装を行な
う構成としたことにより、表１からも明らかなように該
塗料がｐｐｏ樹脂素材に対して優れた塗膜性能を有する
ため自動車外装部品のような厳しい性能が要求される場
所にも使用できる。Gloss retention rate = Gloss after test / Initial gloss ΔE - Color difference table 1 (Effects of the invention) As explained above, in this invention, ppo
By using a two-component urethane paint consisting of polyol and isocyanate with a hydroxyl value of 20 to 60 KOHmg/g and a molecular weight of 3,500 to 5,000 to the resin surface to be coated, Table 1 shows that As is clear, this paint has excellent coating performance against PPO resin materials, so it can be used in places where strict performance is required, such as automobile exterior parts.
また、従来のようにブライマーを必要としないので、工
程削減もできるという効果が得られる。Furthermore, unlike the conventional method, there is no need for a brimer, so it is possible to reduce the number of steps.
Claims (1)
基価２０〜６０ＫＯＨ ｍｇ／ｇでかつ分子量３，５０
０〜５，０００のポリオールとイソシアネートから成る
２液ウレタン塗料を塗布することを特徴とするポリフェ
ニレンオキサイド樹脂への塗装方法。1. Apply polyphenylene oxide resin to the surface to be coated with a hydroxyl value of 20 to 60 KOH mg/g and a molecular weight of 3.50.
A method for coating polyphenylene oxide resin, which comprises applying a two-component urethane paint consisting of 0 to 5,000 polyol and isocyanate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61302778A JPS63156574A (en) | 1986-12-20 | 1986-12-20 | Method for coating polyphenylene oxide resin |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61302778A JPS63156574A (en) | 1986-12-20 | 1986-12-20 | Method for coating polyphenylene oxide resin |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS63156574A true JPS63156574A (en) | 1988-06-29 |
Family
ID=17913005
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP61302778A Pending JPS63156574A (en) | 1986-12-20 | 1986-12-20 | Method for coating polyphenylene oxide resin |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS63156574A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104017476A (en) * | 2014-05-30 | 2014-09-03 | 百川化工(如皋)有限公司 | Production method of 180-level polyurethane wire enamel |
-
1986
- 1986-12-20 JP JP61302778A patent/JPS63156574A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104017476A (en) * | 2014-05-30 | 2014-09-03 | 百川化工(如皋)有限公司 | Production method of 180-level polyurethane wire enamel |
| CN104017476B (en) * | 2014-05-30 | 2016-02-24 | 百川化工(如皋)有限公司 | A kind of production method of 180 level polyurethane enamelled wire paints |
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