JPS63149651A - Multicolor proofing sheet - Google Patents
Multicolor proofing sheetInfo
- Publication number
- JPS63149651A JPS63149651A JP29833786A JP29833786A JPS63149651A JP S63149651 A JPS63149651 A JP S63149651A JP 29833786 A JP29833786 A JP 29833786A JP 29833786 A JP29833786 A JP 29833786A JP S63149651 A JPS63149651 A JP S63149651A
- Authority
- JP
- Japan
- Prior art keywords
- paper
- image
- film
- white
- color
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000012546 transfer Methods 0.000 abstract description 13
- 229920000728 polyester Polymers 0.000 abstract description 4
- 230000008602 contraction Effects 0.000 abstract description 2
- 239000000123 paper Substances 0.000 description 44
- 239000010410 layer Substances 0.000 description 33
- 239000000463 material Substances 0.000 description 16
- 239000000203 mixture Substances 0.000 description 16
- -1 polyethylene Polymers 0.000 description 10
- 239000003086 colorant Substances 0.000 description 8
- 229920001577 copolymer Polymers 0.000 description 8
- 239000000049 pigment Substances 0.000 description 7
- 229920005989 resin Polymers 0.000 description 7
- 239000011347 resin Substances 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- 238000000034 method Methods 0.000 description 6
- 229920000139 polyethylene terephthalate Polymers 0.000 description 5
- 239000005020 polyethylene terephthalate Substances 0.000 description 5
- VVBLNCFGVYUYGU-UHFFFAOYSA-N 4,4'-Bis(dimethylamino)benzophenone Chemical compound C1=CC(N(C)C)=CC=C1C(=O)C1=CC=C(N(C)C)C=C1 VVBLNCFGVYUYGU-UHFFFAOYSA-N 0.000 description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- 239000012790 adhesive layer Substances 0.000 description 4
- 239000011230 binding agent Substances 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 239000000975 dye Substances 0.000 description 4
- 229920006267 polyester film Polymers 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 3
- 239000004952 Polyamide Substances 0.000 description 3
- 239000000853 adhesive Substances 0.000 description 3
- 230000001070 adhesive effect Effects 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 239000006229 carbon black Substances 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 229920003986 novolac Polymers 0.000 description 3
- 239000002985 plastic film Substances 0.000 description 3
- 229920002647 polyamide Polymers 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- OSNILPMOSNGHLC-UHFFFAOYSA-N 1-[4-methoxy-3-(piperidin-1-ylmethyl)phenyl]ethanone Chemical compound COC1=CC=C(C(C)=O)C=C1CN1CCCCC1 OSNILPMOSNGHLC-UHFFFAOYSA-N 0.000 description 2
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 2
- 229910052753 mercury Inorganic materials 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- NWVVVBRKAWDGAB-UHFFFAOYSA-N p-methoxyphenol Chemical compound COC1=CC=C(O)C=C1 NWVVVBRKAWDGAB-UHFFFAOYSA-N 0.000 description 2
- 108091008695 photoreceptors Proteins 0.000 description 2
- 239000003504 photosensitizing agent Substances 0.000 description 2
- 229920006255 plastic film Polymers 0.000 description 2
- 239000004014 plasticizer Substances 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 229910052913 potassium silicate Inorganic materials 0.000 description 2
- 235000019353 potassium silicate Nutrition 0.000 description 2
- YKYONYBAUNKHLG-UHFFFAOYSA-N propyl acetate Chemical compound CCCOC(C)=O YKYONYBAUNKHLG-UHFFFAOYSA-N 0.000 description 2
- WQGWDDDVZFFDIG-UHFFFAOYSA-N pyrogallol Chemical compound OC1=CC=CC(O)=C1O WQGWDDDVZFFDIG-UHFFFAOYSA-N 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- MYWOJODOMFBVCB-UHFFFAOYSA-N 1,2,6-trimethylphenanthrene Chemical compound CC1=CC=C2C3=CC(C)=CC=C3C=CC2=C1C MYWOJODOMFBVCB-UHFFFAOYSA-N 0.000 description 1
- MVPFPGOWZLIWRV-UHFFFAOYSA-N 1-azido-4-[[3-[(4-azidophenyl)methylidene]cyclohexylidene]methyl]benzene Chemical compound C1=CC(N=[N+]=[N-])=CC=C1C=C(CCC1)CC1=CC1=CC=C(N=[N+]=[N-])C=C1 MVPFPGOWZLIWRV-UHFFFAOYSA-N 0.000 description 1
- ZEYKLMDPUOVUCR-UHFFFAOYSA-N 2-chloro-5-(trifluoromethyl)benzenesulfonyl chloride Chemical compound FC(F)(F)C1=CC=C(Cl)C(S(Cl)(=O)=O)=C1 ZEYKLMDPUOVUCR-UHFFFAOYSA-N 0.000 description 1
- CBECDWUDYQOTSW-UHFFFAOYSA-N 2-ethylbut-3-enal Chemical compound CCC(C=C)C=O CBECDWUDYQOTSW-UHFFFAOYSA-N 0.000 description 1
- QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 description 1
- WTQZSMDDRMKJRI-UHFFFAOYSA-N 4-diazoniophenolate Chemical compound [O-]C1=CC=C([N+]#N)C=C1 WTQZSMDDRMKJRI-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 229920002799 BoPET Polymers 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 229920000089 Cyclic olefin copolymer Polymers 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- 239000000020 Nitrocellulose Substances 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- DAKWPKUUDNSNPN-UHFFFAOYSA-N Trimethylolpropane triacrylate Chemical compound C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 125000004036 acetal group Chemical group 0.000 description 1
- 150000008065 acid anhydrides Chemical class 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 150000001540 azides Chemical class 0.000 description 1
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 1
- 239000012965 benzophenone Substances 0.000 description 1
- AOJOEFVRHOZDFN-UHFFFAOYSA-N benzyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC1=CC=CC=C1 AOJOEFVRHOZDFN-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 1
- 235000012730 carminic acid Nutrition 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- XCJYREBRNVKWGJ-UHFFFAOYSA-N copper(II) phthalocyanine Chemical compound [Cu+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 XCJYREBRNVKWGJ-UHFFFAOYSA-N 0.000 description 1
- 238000012937 correction Methods 0.000 description 1
- 229930003836 cresol Natural products 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 239000012954 diazonium Substances 0.000 description 1
- 150000001989 diazonium salts Chemical class 0.000 description 1
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical group [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 125000004185 ester group Chemical group 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- VANNPISTIUFMLH-UHFFFAOYSA-N glutaric anhydride Chemical compound O=C1CCCC(=O)O1 VANNPISTIUFMLH-UHFFFAOYSA-N 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 239000002655 kraft paper Substances 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229920003145 methacrylic acid copolymer Polymers 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- JTHNLKXLWOXOQK-UHFFFAOYSA-N n-propyl vinyl ketone Natural products CCCC(=O)C=C JTHNLKXLWOXOQK-UHFFFAOYSA-N 0.000 description 1
- 229920001220 nitrocellulos Polymers 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 239000011087 paperboard Substances 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical class OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 229940079877 pyrogallol Drugs 0.000 description 1
- 239000001397 quillaja saponaria molina bark Substances 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 239000011342 resin composition Substances 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 229930182490 saponin Natural products 0.000 description 1
- 150000007949 saponins Chemical class 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 229920002050 silicone resin Polymers 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- ANRHNWWPFJCPAZ-UHFFFAOYSA-M thionine Chemical compound [Cl-].C1=CC(N)=CC2=[S+]C3=CC(N)=CC=C3N=C21 ANRHNWWPFJCPAZ-UHFFFAOYSA-M 0.000 description 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F3/00—Colour separation; Correction of tonal value
- G03F3/10—Checking the colour or tonal value of separation negatives or positives
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Duplication Or Marking (AREA)
Abstract
Description
【発明の詳細な説明】 〔産業上の利用分野〕 本発明は、多色カラープルーフィングシートに関する。[Detailed description of the invention] [Industrial application field] The present invention relates to a multicolor proofing sheet.
多色刷り印刷における本印刷の前工程として校正刷りに
より色校正を行うことが一般的である。In multicolor printing, it is common to perform color proofing by proof printing as a pre-process of main printing.
この場合、一般的には、たとえば怒光性転写シートにそ
れぞれ各色のフォトポリマー色像をつくり、たとえばピ
ンシステムによって見当合せしながら、アート紙、コー
ト紙、合成紙、白色プラスチックシート等の受像面に、
各色像を順次重ねて転写して色校正を得るようにしてい
る。In this case, generally, photopolymer color images of each color are created on a phototransfer sheet, for example, and are registered on an image receiving surface of art paper, coated paper, synthetic paper, white plastic sheet, etc., using a pin system, for example. To,
Color correction is obtained by sequentially overlapping and transferring each color image.
しかし、上記のような白色紙では、実際の印刷用紙では
ないので、実際の印刷物と画質や質感が異なる。したが
って、実際の印刷用紙に着色画像を転写すればよいが、
このままでは、転写時の熱や圧力等により紙が伸縮し、
あるいは画質が劣化し、所望の製品が得られないでいた
。However, since the above white paper is not actual printing paper, the image quality and texture differ from actual printed matter. Therefore, all you have to do is transfer the colored image to the actual printing paper, but
If left as is, the paper will expand and contract due to heat and pressure during transfer.
Alternatively, the image quality deteriorated and a desired product could not be obtained.
そこで、本発明の主たる目的は、画像品質が優れかつ通
常の印刷で得られた印刷物の画像品質とほぼ同じである
多色カラープルーフィングシートを提供することにある
。Therefore, the main object of the present invention is to provide a multicolor proofing sheet that has excellent image quality and is almost the same as the image quality of printed matter obtained by ordinary printing.
上記目的は、着色画像に白色紙を転写することにより得
られる多色カラープルーフィングシートにおいて、前記
白色紙の片面にそれより伸縮性の小さいフィルムを設け
たことで達成される。The above object is achieved by providing a multicolored color proofing sheet obtained by transferring a colored image onto a white paper, by providing a film having a smaller stretch on one side of the white paper.
本発明では、被転写紙としての白色紙の片面にそれより
伸縮性の小さいフィルムを設けたので、転写時における
熱や圧力による伸縮および変形が小さく、画像品質の劣
化がほとんどない。しかも、白色紙の伸縮や変形がない
ところから、その白色紙として、実際印刷が行なわれる
当該印刷用紙を使用できるので、実際の印刷物と同様の
画像品質および質感を得ることができる。In the present invention, a film with less elasticity is provided on one side of the white paper used as the transfer paper, so that there is less expansion, contraction and deformation due to heat and pressure during transfer, and there is almost no deterioration in image quality. Moreover, because white paper does not expand, contract, or deform, the printing paper on which actual printing is performed can be used as the white paper, so that image quality and texture similar to those of actual printed matter can be obtained.
以下本発明をさらに詳説する。 The present invention will be explained in more detail below.
本発明では、白色紙の片面にそれより伸縮性の小さいフ
ィルムが設けられる。In the present invention, a film with less stretch is provided on one side of the white paper.
この白色紙としては、カラープルーフィング後の印刷時
に用いる白色印刷用紙が好ましくは用いられるが、印刷
物と異なる用紙であってもよい。As this white paper, white printing paper used during printing after color proofing is preferably used, but a paper different from that of printed matter may be used.
ただ、カラープルーフィングシートと実際の印刷物との
間において質感で異なる場合があるので、あまり好まし
いものではない。However, this is not very desirable since there may be a difference in texture between the color proofing sheet and the actual printed matter.
上記の白色紙としては、上質紙、中質紙、下級紙、コー
ト紙、両更祇、クラフト紙、板紙等を挙げることができ
る。Examples of the above-mentioned white paper include high-quality paper, medium-quality paper, low-grade paper, coated paper, ryosegi paper, kraft paper, paperboard, and the like.
この白色紙の片面に対して、それより伸縮性の小さいフ
ィルムが設けられる。このフィルムを形成する材料とし
ては、金属箔、合成紙、プラスチックフィルム等を用い
ることができるが、プラスチックフィルムが望ましく、
特にポリエステル、ポリエチレン、ポリプロピレンフィ
ルムが好ましい。フィルム厚としては、１０〜４００μ
ｍ１特に４０〜１００μｍが好ましい。フィルムは、全
面に設ける必要はなく、たとえば格子状とすることもで
きる。また、異種フィルムを積層させたものであっても
よい。A less stretchable film is provided on one side of the white paper. Metal foil, synthetic paper, plastic film, etc. can be used as the material for forming this film, but plastic film is preferable.
Particularly preferred are polyester, polyethylene, and polypropylene films. Film thickness is 10~400μ
m1 is particularly preferably 40 to 100 μm. The film does not need to be provided over the entire surface, and may be provided in a lattice shape, for example. Alternatively, it may be one in which different types of films are laminated.
また、白色紙にフィルムを設ける手法として、接着材を
用いたり、熱圧着によるなどの方法を採用できる。Further, as a method of providing the film on the white paper, methods such as using an adhesive or thermocompression bonding can be adopted.
さらに本発明は、第１図のように白色紙１の片面にフィ
ルム２を設ける場合のほか、白色紙ＩＡ。Furthermore, the present invention applies not only to the case where a film 2 is provided on one side of a white paper 1 as shown in FIG. 1, but also to a white paper IA.
ＩＢの片面にフィルム２を挟むようにして設けた場合も
含まれる。This also includes a case where the film 2 is provided on one side of the IB so as to be sandwiched therebetween.
本発明における着色画像はたとえば次のようにして形成
できる。すなわち、第３図に示すように、透明支持体３
上に透明熱融着層４およびキノンジアジド化合物等の感
光性組成物を有する着色記録層５が積層された着色画像
形成材料を用意する。The colored image in the present invention can be formed, for example, as follows. That is, as shown in FIG.
A colored image forming material is prepared, on which a transparent heat-adhesive layer 4 and a colored recording layer 5 having a photosensitive composition such as a quinonediazide compound are laminated.
また、着色記録層としては、第４図のように、熱融着層
４がわに着色剤を含有しない感光性組成物を有する無着
色記録層５Ａを積層し、さらにその上に着色剤を含む着
色記録層５Ｂを積層した２層の着色記録層であってもよ
い。In addition, as a colored recording layer, as shown in FIG. 4, an uncolored recording layer 5A having a photosensitive composition containing no colorant is laminated on the thermal adhesive layer 4, and a colorant is further applied thereon. It may be a two-layer colored recording layer in which the colored recording layer 5B containing the color recording layer 5B is laminated.
本発明に使用される着色画像形成材料の透明支持体とし
ては、ポリエステルフィルム、特に二軸延伸ポリエチレ
ンテレフタレートフィルムが水、熱に対する寸法安定性
の点で好ましいが、アセテートフィルム、ポリ塩化ビニ
ルフィルム、ポリスチレンフィルム、ポリプロピレンフ
ィルム、ポリエチレンフィルムも使用し得る。更にこれ
らの支持体をそのまま使ってもよいが、画像形成後の画
像の転写性を良くするためにシリコーン樹脂、フッ素樹
脂あるいはフッ素系界面活性剤等の適当な撥油性物質に
よる離型処理を施したり、または厚さ１μｍ程度のアル
コール可溶性ポリアミド、アルコール可溶性ナイロン、
スチレン／無水マレイン酸共重合体の部分エステル化物
あるいはポリビニルアルコール等の下引き層を設けても
よい。As the transparent support for the colored image-forming material used in the present invention, a polyester film, particularly a biaxially oriented polyethylene terephthalate film, is preferable in terms of dimensional stability against water and heat, but acetate film, polyvinyl chloride film, polystyrene film, etc. Films, polypropylene films, polyethylene films may also be used. Furthermore, these supports may be used as they are, but in order to improve the transferability of the image after image formation, they may be subjected to mold release treatment using a suitable oil-repellent substance such as silicone resin, fluororesin or fluorosurfactant. or alcohol-soluble polyamide, alcohol-soluble nylon, or alcohol-soluble polyamide with a thickness of about 1 μm,
A subbing layer such as a partially esterified styrene/maleic anhydride copolymer or polyvinyl alcohol may be provided.
前記の熱融着性層は、透明であり且つ室温では非粘着性
であるが、８０℃〜１６０℃の温度範囲で熱融着可能な
ものが好適である。The heat-fusible layer is transparent and non-adhesive at room temperature, but is preferably heat-fusible in a temperature range of 80°C to 160°C.
これには、次に挙げるような７０℃〜１４０℃の軟化点
を有する皮膜形成性の熱可塑性樹脂が用いられる。例え
ば、オレフィンく共）重合体、塩化ビニル（共）重合体
、塩化ビニリデン（共）重合体、酢酸ビニル（共）重合
体、（メタ）アクリル酸エステル（共）重合体、スチレ
ン／（メタ）アクリル酸エステル共重合体、ポリエステ
ル、ビニルブチラール樹脂、塩化ゴム、セルロース誘導
体、好ましくは、スチレン／（メタ）アクリル酸エステ
ル共重合体、ポリエステル等であり、これらは単独もし
くは混合して用いられ、更には他の樹脂類あるいは可塑
剤等を混合して用いてもよい。For this purpose, the following film-forming thermoplastic resins having a softening point of 70°C to 140°C are used. For example, olefin copolymers, vinyl chloride (co)polymers, vinylidene chloride (co)polymers, vinyl acetate (co)polymers, (meth)acrylate ester (co)polymers, styrene/(meth)polymers Acrylic ester copolymers, polyesters, vinyl butyral resins, chlorinated rubber, cellulose derivatives, preferably styrene/(meth)acrylic ester copolymers, polyesters, etc., which may be used alone or in combination; may be used in combination with other resins or plasticizers.
熱融着性層の厚さは、１〜２０μｍの範囲が適当であり
、特に好ましくは２〜８μｍの範囲である。熱融着性層
の厚さは、後述の着色記録層あるいは着色（記録）層と
無着色記録層とを合せた厚さと同等またはそれ以上にし
た方が、熱融着性層上に形成された着色画像を受像材料
表面に加熱、加圧、転写する際、微細な非画線部、つま
り大きな加線部に囲まれた狭い領域の熱融着性層までも
が効果的に受像材料表面に融着し、均−且つ良好な転写
画像を得ることができる。The thickness of the heat-fusible layer is suitably in the range of 1 to 20 μm, particularly preferably in the range of 2 to 8 μm. The thickness of the heat-fusible layer formed on the heat-fusible layer should be equal to or greater than the thickness of the colored recording layer or the combined thickness of the colored (recording) layer and the non-colored recording layer, which will be described later. When a colored image is heated, pressed, and transferred onto the surface of an image-receiving material, even minute non-image areas, that is, narrow areas of the heat-fusible layer surrounded by large line areas, are effectively transferred to the surface of the image-receiving material. It is possible to obtain a uniform and good transferred image.
上記の感光性組成物としては、種々のものを使用できる
が、実質的に水に不溶で、アルカリ現像可能な感光性組
成物を用いるのが好ましい。具体的には、ネガティブワ
ーキング型の感光性組成物としては、例えば２．６−ジ
（４′−アジドベンザル）シクロヘキサンのようなアジ
ド系感光剤とフェノールノボラック樹脂をブレンドした
組成物、さらにベンジルメタアクリレートとメタクリル
酸（例えばモル比７：３）の共重合体をバインダーとし
てトリメチロールプロパントリアクリレートのごとき多
官能性モノマーとミヒラーケトンのごとき光重合開始剤
をブレンドした光重合型感光性組成物が用いられる。ま
た、ポジティブワーキング型としては、例えば（ｉ）ｏ
−キノンジアジドを感光剤、フェノールノボラック樹脂
をバインダーとする感光性樹脂組成物があり、さらには
（ｉｉ ）ジアゾニウム塩、有機ハロゲン化物のような
活性光線の照射により酸を発生゛し得る化合物、アセタ
ール基、ケタール基、オルトカルボン酸エステル基、シ
リルエーテル基のような酸により分解し得る結合を少な
くとも１個有する化合物、および２または３種類の異な
るフェノール類を含むノボラック樹脂を含有する感光性
樹脂組成物を用いることもできる。Although various kinds of photosensitive compositions can be used as the above-mentioned photosensitive composition, it is preferable to use a photosensitive composition that is substantially insoluble in water and can be developed with an alkali. Specifically, negative working type photosensitive compositions include compositions that are a blend of an azide photosensitizer such as 2,6-di(4'-azidobenzal)cyclohexane and a phenol novolak resin, and benzyl methacrylate. A photopolymerizable photosensitive composition is used in which a copolymer of methacrylic acid and methacrylic acid (e.g., molar ratio 7:3) is blended with a polyfunctional monomer such as trimethylolpropane triacrylate and a photopolymerization initiator such as Michler's ketone. . In addition, as a positive working type, for example, (i) o
- There are photosensitive resin compositions that use quinonediazide as a photosensitizer and phenol novolak resin as a binder, and (ii) compounds that can generate acid upon irradiation with actinic rays, such as diazonium salts and organic halides, and acetal groups. , a compound having at least one acid-decomposable bond such as a ketal group, an orthocarboxylic acid ester group, or a silyl ether group, and a novolac resin containing two or three different types of phenols. You can also use
ここに記したところを含めて、感光性組成物に関しては
、さらにＪ、ＫＯ５ＡＲ著“Ｌｉｇｈｔ ５ｅｎｓｉｔ
ｉｖｅＳｙｓ ｔｅｍ″（Ｗｉｌｅｙ ＆ ５ｏｎｓ、
Ｎｅｗ Ｙｏｒｋ、１９６５）および色材協会誌第４４
巻（１９７１）第１）６〜１３７頁の記載にしたがうこ
とができる。Regarding photosensitive compositions, including those described here, please refer to “Light 5ensit” by J. KO5AR.
iveSystem'' (Wiley & 5ons,
New York, 1965) and Color Materials Association Magazine No. 44
(1971) No. 1), pages 6 to 137.
着色感光性層中には着色物質として染料、顔料が添加さ
れる。特に、色校正に使用する場合、そこに要求される
常色即ち、イエロー、マゼンタ、シアン、ブラックと一
致した色調の顔料、染料が必要となるが、その他金属粉
、白色顔料、螢光顔料なども使われる。これらは、単独
であるいは２種以上の併用で用いることもできる。Dyes and pigments are added as coloring substances to the colored photosensitive layer. In particular, when used for color proofing, pigments and dyes with a tone matching the usual colors required for that purpose, such as yellow, magenta, cyan, and black, are required, but other materials such as metal powders, white pigments, fluorescent pigments, etc. is also used. These can be used alone or in combination of two or more.
本発明に用いる着色感光性層の着色剤／結合剤、着色剤
以外の組成物の比率は、目標とする光学濃度と着色感光
性層の現像液に対する除去性を考慮して同業者に公知の
方法により定めることができる。例えば、染料の場合、
その含有量は重量で５％〜７５％、顔料の場合、その含
有量は重量で５％〜９０％が適当である。The ratio of the colorant/binder and components other than the colorant in the colored photosensitive layer used in the present invention is determined based on the ratio known to those skilled in the art, taking into account the target optical density and the removability of the colored photosensitive layer to the developer. It can be determined by the method. For example, in the case of dyes,
The appropriate content is 5% to 75% by weight, and in the case of pigments, the content is 5% to 90% by weight.
また、着色感光性層の膜厚は目標とする光学濃度、着色
感光性層に用いられる着色剤の種類（染料、顔料、カー
ボンブラック）およびその含有率により当業者に公知の
方法により定めることができるが、許容範囲内であれば
着色感光性層の膜厚はできるだけ薄い方が解像度は高く
なり、画像品質は良好である。従って、該膜厚は、１μ
ｍ〜１０μｍ、特に１〜４μｍの範囲で使用されるのが
好適である。In addition, the thickness of the colored photosensitive layer can be determined by a method known to those skilled in the art based on the target optical density, the type of colorant (dye, pigment, carbon black) used in the colored photosensitive layer, and its content. However, within the allowable range, the thinner the colored photosensitive layer is, the higher the resolution and the better the image quality. Therefore, the film thickness is 1μ
It is preferable to use it in the range of m to 10 μm, particularly 1 to 4 μm.
上記、着色記録剤からなる着色記録剤中には、その他種
々の目的に応じて、各種の添加剤を加えることができる
。Various additives may be added to the above-mentioned colored recording agent according to various purposes.
例えば塗布性を向上させるために、セルロースアルキル
エーテル、フッ素界面活性剤、シリコーン系化合物等の
界面活性剤、増感剤として酸無水物、例えば無水グルタ
ル酸、無水フタル酸等、また、塗膜の物性改良剤として
リン酸エステル、フタル酸エステル等の可塑剤等を添加
して用いることができる。For example, to improve coating properties, surfactants such as cellulose alkyl ethers, fluorine surfactants, and silicone compounds, acid anhydrides such as glutaric anhydride, phthalic anhydride, etc. are used as sensitizers, and Plasticizers such as phosphate esters and phthalate esters can be added as physical property improvers.
上記の着色画像形成材料は、たとえば次のような画像形
成法に好適に用いられる。The above-mentioned colored image forming material is suitably used, for example, in the following image forming method.
すなわち、まず上記着色画像形成材料の透明支持体３表
面あるいは反対側表面上に分解マスクを配し、その上か
ら活性光線を照射し画像露光する。That is, first, a decomposition mask is placed on the surface of the transparent support 3 or the opposite surface of the colored image-forming material, and actinic rays are irradiated from above for imagewise exposure.
これを、他の３色についても行う。次いで、各露光済材
料について、現像液により液体現像し、水洗、乾燥した
ものの第１色目を画像受容材料の被転写面と重ね合せ、
画像受容材料がわに画像転写した後、その透明支持体を
剥離して第１色目の転写画像を得る。これに残り３色の
画像を一致させ積層しながら同様に残り３回の転写を行
い最終のカラープルーフィングシートとする。Repeat this for the other three colors as well. Next, each exposed material is liquid developed with a developer, washed with water, and dried, and the first color is superimposed on the transferred surface of the image-receiving material.
After the image is transferred to the image-receiving material, the transparent support is peeled off to obtain a first color transferred image. The images of the remaining three colors are matched and stacked, and the remaining three transfers are performed in the same manner to form the final color proofing sheet.
次に実施例により、本発明を明らかにする。 Next, the present invention will be clarified by examples.
（実施例１）
５０ミクロンの厚さのポリエステルフィルムを支持体と
してその片面に、シュラツクのイソプロピルアルコール
溶液（１０％）を塗布、乾燥して２．５μの厚さの色像
裏打ち層を形成し、ついでゼラチン４０ｇ、シュウ酸第
二鉄アンモン１２．６ｇ。(Example 1) Schlag's isopropyl alcohol solution (10%) was applied to one side of a 50 micron thick polyester film as a support and dried to form a 2.5 micron thick color image backing layer. , followed by 40 g of gelatin and 12.6 g of ferric ammonium oxalate.
グリセリン３ｇ、サポニン０．４ｇ、水８００ｇの溶液
に、グル−１０ｇ１ベンジジンエロー１０ｇ１水９０ｇ
をボールミルで処理して作った分散液を、添加してつく
った感光液を色像裏打ち層の上に塗り重ね、乾燥して２
ミクロンの厚さの感光層を作り費用の熱転写シートとし
た。In a solution of 3 g of glycerin, 0.4 g of saponin, and 800 g of water, add 10 g of glue, 10 g of benzidine yellow, and 90 g of water.
A photosensitive liquid made by adding a dispersion prepared by processing with a ball mill is coated on the color image backing layer, and dried.
A photosensitive layer with a thickness of microns was made and used as an inexpensive thermal transfer sheet.
上記ベンジジンエローの代りにブリリアントカーミノ６
Ｂ、フタロシアニンブルー及びカーボンブラックとニグ
ロシンの混合物をそれぞれ用いてマゼンタ、シアンおよ
び黒用の熱転写シートを同様にして作った。Brilliant Carmino 6 instead of Benzidine Yellow above
B, thermal transfer sheets for magenta, cyan, and black were similarly made using phthalocyanine blue and a mixture of carbon black and nigrosine, respectively.
まず費用熱転写シートを費用分解網ネガと密着させ３０
アンペア−のアーク灯から６０ａａの距離を置いて３分
間露光し、ついで１％過酸化水素水溶液に約１分間浸漬
して露光域感光層を充分に水不溶化となし、次に３５℃
の水を流しかけて、感光層の未硬化部分を溶解除去し、
乾燥して黄色ポジ像を作った。First, put the cost thermal transfer sheet in close contact with the cost resolution net negative for 30 minutes.
The exposed area was exposed to light for 3 minutes at a distance of 60 AA from a 60 AA arc lamp, then immersed in a 1% hydrogen peroxide aqueous solution for about 1 minute to make the exposed area photosensitive layer sufficiently water insoluble, and then heated to 35°C.
water to dissolve and remove the uncured portion of the photosensitive layer.
After drying, a yellow positive image was created.
これを印刷用上質紙にポリエステルフィルムを接着剤に
より積層した校正用紙の上質紙面上に重ね、１００℃の
熱ローラーで押圧してから支持体すなわちポリエステル
フィルムを剥離すると、色像が色像裏打ち層と共にアー
ト紙面に融着し転写された。This is layered on the high-quality paper side of proofing paper, which is made by laminating a polyester film on high-quality printing paper with an adhesive, and is pressed with a heated roller at 100°C. When the support, that is, the polyester film is peeled off, the color image is transferred to the color image backing layer. It was also fused and transferred onto the art paper.
マゼンタ、シアンそして黒用の熱転写シートも夫々対応
する色分解網ネガを通して露光し、先の黄色ポジ像を転
写したアート紙上に順次同様に、熱転写し色のポジ像を
得た。The thermal transfer sheets for magenta, cyan, and black were also exposed through the corresponding color separation net negatives, and then thermally transferred in the same manner onto the art paper onto which the previous yellow positive image had been transferred to obtain color positive images.
この画像品質は優れ、かつその後実際の印刷を行っても
のと対比して質感は同様であった。The image quality was excellent, and the texture was similar to that of actual printing.
（実施例２）
特開昭５９−９７１４０号公報における実施例１と同様
の方式によりカラープルーフィングシートを得た。ただ
、その場合の白色アート紙の代りに、実施例１と同じ校
正用紙を用いたところ、画像品質に優れたカラープルー
フィングシートを得た。(Example 2) A color proofing sheet was obtained in the same manner as in Example 1 in JP-A-59-97140. However, when the same proofing paper as in Example 1 was used instead of the white art paper in that case, a color proofing sheet with excellent image quality was obtained.
（実施例３）
下記組成の下塗液を厚さ１００８ｍの２軸延伸ポリエチ
レンテレフタレートフイルム上に、コーティングロッド
（Ｕ、Ｓ、Ａ ％ Ｒ，Ｄ、５ｐｅｃｉａｌｔｉｅｓ）
を用いて、乾燥膜厚０．３μｍになるように塗布、乾燥
し、離型性表面を有する支持体を作成した。(Example 3) A coating rod (U, S, A % R, D, 5 specialties) was applied to a biaxially stretched polyethylene terephthalate film with a thickness of 1008 m using an undercoating liquid with the following composition.
was applied to a dry film thickness of 0.3 μm and dried to prepare a support having a releasable surface.
アルコール可溶性ポリアミド ８．５ｇ（東し社
製ＣＭ８０００）
ニトロセルロースＲＳＩ／２ ０．０５ｇ（３
０％ ＩＰＡ 混綿）
メタノール ４００ｇメチルセロソ
ルブ １００ｇ次に、下記組成の４色の着
色感光検層分散液を調整し、乾燥膜厚が２μｍになるよ
うに塗布した。Alcohol-soluble polyamide 8.5g (Toshisha CM8000) Nitrocellulose RSI/2 0.05g (3
0% IPA (mixed cotton) Methanol 400g Methyl Cellosolve 100g Next, four colored photosensitive logging dispersions having the following composition were prepared and coated to give a dry film thickness of 2 μm.
ピロガロール・アセトン縮合樹脂と
１．２−ナフトキノンジアジド−５−
スルホニルクロライドのエステル化
物〔感光体１） ２ｇフェノー
ルとｍ−、ｐ−混合クレゾ
ールとホルムアルデヒドとの共重縮
合樹脂〔バインダー樹脂Ｉ） ８ｇ顔料
３ｇ
セイ力ファーストイエローＨ−７０５５（大日精化■製
）
セイ力ファーストカーミン１４８３
（大日精化■製）
シアニンブルー４９２０
（大日精化■製）
三菱カーボンブラックＭＡ−１００
（三菱化成■製）
メチルセロソルブ １００ｇ更に、下記組成
の感光性層塗布液を感光膜厚２μｍになるように塗布、
乾燥した。Esterified product of pyrogallol/acetone condensation resin and 1,2-naphthoquinonediazide-5-sulfonyl chloride [Photoreceptor 1) 2g Copolycondensation resin of phenol, m-, p-mixed cresol, and formaldehyde [Binder resin I) 8g pigment
3g Seiryoku First Yellow H-7055 (manufactured by Dainichiseika) Seiryoku First Carmine 1483 (manufactured by Dainichiseika) Cyanine Blue 4920 (manufactured by Dainichiseika) Mitsubishi Carbon Black MA-100 (manufactured by Mitsubishi Kasei) Methyl Cellosolve 100g Furthermore, apply a photosensitive layer coating solution with the following composition to a photosensitive film thickness of 2 μm.
Dry.
〔感光体Ｉ） ２ｇ〔バインダ
ー樹脂Ｉ） ８ｇ酢酸ｎ−プロピル
７０ｇシクロヘキサノン
３０ｇかくして得られた４色の着色画像形成材料の２
組について夫々をレジスタービンを用いて相応する色分
解ポジマスクと正確な位置に重ね合わせ、さらに感度測
定、現像ラチチュード評価用コントロールウェッジ（Ｉ
ＪＧＲＡ ＰＣＷ ８２ 、連続調ウェッジ・・・濃
度差量０．１５ずつで１３段階のグレースケール、スモ
ールドツトバッチ・・・１５０ ｖＡ／ １ｎｃｈ。[Photoreceptor I) 2g [Binder resin I] 8g n-propyl acetate
70g cyclohexanone
30g of the four colored image forming materials thus obtained
For each set, each set was overlaid in a precise position with the corresponding color separation positive mask using a resistor bin, and then a control wedge (I) was used for sensitivity measurement and development latitude evaluation.
JGRA PCW 82, continuous tone wedge... 13 levels of gray scale with density difference of 0.15 each, small dot batch... 150 vA/1 nch.
０．５．１，２．３．４．５％網点チャート〕を密着さ
せて、２に−の超音圧水銀灯Ｊｅｔ、 Ｌｉｇｈｔ ２
０００（オーク製作断裂）で５０ｃｍの距離から、現像
後の連続調ウェッジの３段が完全に現像除去される画像
露光を行ない、１組はメタケイ酸カリウム２％水溶液、
１組は３％メタケイ酸カリウム水溶液で２５℃にて３０
秒間現像した。0.5.1, 2.3.4.5% halftone chart] and 2 - supersonic pressure mercury lamp Jet, Light 2
000 (oak fabrication fracture) from a distance of 50 cm, image exposure was performed in which three stages of continuous tone wedges after development were completely removed, one set was a 2% potassium metasilicate aqueous solution,
One set is 30% potassium metasilicate aqueous solution at 25℃.
Developed for seconds.
このようにして色分解マスクを忠実に再現した４色の画
像形成着色材料が２組得られた。In this way, two sets of four-color image-forming colored materials that faithfully reproduced the color separation masks were obtained.
一方、別の１００μｍ２軸延伸ポリエチレンテレフタレ
ートフイルム上に下記の処方からなる光重合性画像受容
層溶液をコーティングロッドを用いて塗布し、１００℃
で２分乾燥して光重合性画像受容層シートを作成した。On the other hand, a photopolymerizable image-receiving layer solution having the following formulation was applied onto another 100 μm biaxially stretched polyethylene terephthalate film using a coating rod, and the temperature was increased to 100°C.
The mixture was dried for 2 minutes to prepare a photopolymerizable image-receiving layer sheet.
乾燥膜厚は２８μｍであった。The dry film thickness was 28 μm.
塩化ビニル・酢酸ビニルアルコール共重合体（セキスイ
社製、エスレフクＡ） ９０ｇペンタエリスリトール
テトラアクリ
レート ５４ｇミヒラ
ーズケトン ０．５１ｇベンゾフェ
ノン ３．１８ ｇパラメトキシ
フェノール ０．０９ｇメチルエチルケトン
２２０ｇ次に、先に得た１組のイエロ
ー色画像を画像受容シートとレジスターピンで正確に密
着し、１００℃に加熱されている１対のニップロール間
を通過させ色画像を画像受容シートに転写し、画像側の
ポリエチレンテレフタレートフィルムを剥離した。Vinyl chloride/vinyl acetate alcohol copolymer (manufactured by Sekisui Co., Ltd., S-Refuku A) 90 g Pentaerythritol tetraacrylate 54 g Michler's ketone 0.51 g Benzophenone 3.18 g Paramethoxyphenol 0.09 g Methyl ethyl ketone 220 g Next, the previously obtained set of The yellow image was accurately brought into contact with the image-receiving sheet using register pins, passed between a pair of nip rolls heated to 100°C, the color image was transferred to the image-receiving sheet, and the polyethylene terephthalate film on the image side was peeled off. .
引き続きマゼンタ、シアン、ブラックの順に色画像の転
写を同様に行い、画像受容シートの画像面側を被転写紙
に密着させ、１００℃に加熱されている１対のニップロ
ール間を通過させることにより、多色画像が形成された
画像受容層を被転写紙に融着させた。Subsequently, the color images are transferred in the same manner in the order of magenta, cyan, and black, and the image side of the image-receiving sheet is brought into close contact with the transfer paper, and the sheet is passed between a pair of nip rolls heated to 100°C. The image-receiving layer with the multicolor image formed thereon was fused to the receiving paper.
ここで、被転写紙としては、印刷用紙の片面（印刷する
と反対の面）に厚さ６０μｍの「プロテクトテープ＃６
２２ＣＪ （種水化学工業社製）を加熱ローラで、１
００℃×０．２秒の条件で熱圧着したものを用いた。Here, as the paper to be transferred, a 60 μm thick "protect tape #6" is used on one side of the printing paper (the opposite side when printing).
22CJ (manufactured by Tanemizu Chemical Industry Co., Ltd.) with a heating roller, 1
The material was thermocompressed under the conditions of 00° C. x 0.2 seconds.
その後、接着層側のポリエチレンテレフタレートフィル
ムを通して２ｋＷ超音圧水銀灯Ｊｅｔ、 Ｌｉｇｈｔ２
０００ （オーク製作断裂）で５０Ｃ１）の距離から９
秒間全面露光を施し、接着層側のポリエチレンテレフタ
レートフィルムを剥離し、被転写紙上に多色カラープル
ーフィングシートが得られた。他の組も同様にして行っ
た。After that, a 2kW ultrasonic mercury lamp Jet, Light2 was passed through the polyethylene terephthalate film on the adhesive layer side.
9 from a distance of 50C1) at 000 (oak fabrication rupture)
The entire surface was exposed to light for seconds, and the polyethylene terephthalate film on the adhesive layer side was peeled off to obtain a multicolor proofing sheet on the transfer paper. The other groups did the same.
２組の得られたカラープルーフは被転写紙上に強固に保
持され、いずれも印刷物に極めて近い良好なものであっ
た。The two sets of color proofs obtained held strongly on the receiving paper and were both very close to the printed matter.
以上の通り、本発明によれば、画像品質に優れ、かつ実
際の印刷物と同じ質感のカラープルーフィングシートを
得ることができる。As described above, according to the present invention, it is possible to obtain a color proofing sheet that has excellent image quality and has the same texture as an actual printed matter.
第１図および第２図はカラープルーフィングシートの被
転写紙の断面図、第３図および第４図は着色画像形成材
料の層構成例図である。
１．１Ａ、ＩＢ・・・白色紙、２・・・フィルム。
特許出願人 小西六写真工業株式会社三菱化成工業株
式会社1 and 2 are cross-sectional views of a transfer paper of a color proofing sheet, and FIGS. 3 and 4 are illustrations of an example of the layer structure of a colored image forming material. 1.1A, IB...white paper, 2...film. Patent applicant Roku Konishi Photo Industry Co., Ltd. Mitsubishi Chemical Industries, Ltd.
Claims (1)
多色カラープルーフィングシートにおいて、前記白色紙
の片面にそれより伸縮性の小さいフィルムを設けたこと
を特徴とする多色カラープルーフィングシート。(1) A multicolor proofing sheet obtained by transferring a colored image onto white paper, characterized in that a film with less elasticity is provided on one side of the white paper. .
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61298337A JP2645414B2 (en) | 1986-12-15 | 1986-12-15 | Multicolor color proofing sheet |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61298337A JP2645414B2 (en) | 1986-12-15 | 1986-12-15 | Multicolor color proofing sheet |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS63149651A true JPS63149651A (en) | 1988-06-22 |
| JP2645414B2 JP2645414B2 (en) | 1997-08-25 |
Family
ID=17858360
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP61298337A Expired - Fee Related JP2645414B2 (en) | 1986-12-15 | 1986-12-15 | Multicolor color proofing sheet |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2645414B2 (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0365359A2 (en) * | 1988-10-21 | 1990-04-25 | Hoechst Celanese Corporation | A method for forming a colored image on a degradable sheet material |
| JPH0333746A (en) * | 1989-06-29 | 1991-02-14 | Konica Corp | Multicolor proofing sheet |
| EP0616257A2 (en) * | 1993-03-18 | 1994-09-21 | Toyo Ink Manufacturing Co., Ltd. | Image transfer method and material |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS515101A (en) * | 1974-05-29 | 1976-01-16 | Hoechst Co American |
-
1986
- 1986-12-15 JP JP61298337A patent/JP2645414B2/en not_active Expired - Fee Related
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS515101A (en) * | 1974-05-29 | 1976-01-16 | Hoechst Co American |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0365359A2 (en) * | 1988-10-21 | 1990-04-25 | Hoechst Celanese Corporation | A method for forming a colored image on a degradable sheet material |
| EP0365359A3 (en) * | 1988-10-21 | 1992-03-04 | Hoechst Celanese Corporation | A method for forming a colored image on a degradable sheet material |
| JPH0333746A (en) * | 1989-06-29 | 1991-02-14 | Konica Corp | Multicolor proofing sheet |
| EP0616257A2 (en) * | 1993-03-18 | 1994-09-21 | Toyo Ink Manufacturing Co., Ltd. | Image transfer method and material |
| EP0616257A3 (en) * | 1993-03-18 | 1995-04-26 | Toyo Ink Mfg Co | Image transfer method and material. |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2645414B2 (en) | 1997-08-25 |
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