JPS6314706A - Oil-in-water type emulsion cosmetic - Google Patents
Oil-in-water type emulsion cosmeticInfo
- Publication number
- JPS6314706A JPS6314706A JP15949386A JP15949386A JPS6314706A JP S6314706 A JPS6314706 A JP S6314706A JP 15949386 A JP15949386 A JP 15949386A JP 15949386 A JP15949386 A JP 15949386A JP S6314706 A JPS6314706 A JP S6314706A
- Authority
- JP
- Japan
- Prior art keywords
- water
- oil
- combination
- soluble polyhydric
- salt
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 25
- 239000002537 cosmetic Substances 0.000 title claims abstract description 21
- 239000000839 emulsion Substances 0.000 title claims abstract description 9
- 239000000203 mixture Substances 0.000 claims abstract description 21
- 150000005846 sugar alcohols Polymers 0.000 claims abstract description 20
- 150000003839 salts Chemical class 0.000 claims abstract description 12
- XOAAWQZATWQOTB-UHFFFAOYSA-N taurine Chemical compound NCCS(O)(=O)=O XOAAWQZATWQOTB-UHFFFAOYSA-N 0.000 claims description 21
- 150000003904 phospholipids Chemical class 0.000 claims description 14
- 239000007764 o/w emulsion Substances 0.000 claims description 13
- 229940104261 taurate Drugs 0.000 claims description 3
- 239000004094 surface-active agent Substances 0.000 abstract description 7
- 238000002156 mixing Methods 0.000 abstract description 6
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 abstract description 4
- 239000003995 emulsifying agent Substances 0.000 abstract description 4
- IIZPXYDJLKNOIY-JXPKJXOSSA-N 1-palmitoyl-2-arachidonoyl-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCC\C=C/C\C=C/C\C=C/C\C=C/CCCCC IIZPXYDJLKNOIY-JXPKJXOSSA-N 0.000 abstract description 3
- 239000000787 lecithin Substances 0.000 abstract description 3
- 229940067606 lecithin Drugs 0.000 abstract description 3
- 235000010445 lecithin Nutrition 0.000 abstract description 3
- 229940058015 1,3-butylene glycol Drugs 0.000 abstract description 2
- 239000002253 acid Substances 0.000 abstract description 2
- 235000019437 butane-1,3-diol Nutrition 0.000 abstract description 2
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 abstract description 2
- 230000001976 improved effect Effects 0.000 abstract description 2
- 229940057995 liquid paraffin Drugs 0.000 abstract description 2
- URACZAGMGOMSLF-UHFFFAOYSA-N 2-(2-oxononadecylamino)ethanesulfonic acid Chemical compound CCCCCCCCCCCCCCCCCC(=O)CNCCS(O)(=O)=O URACZAGMGOMSLF-UHFFFAOYSA-N 0.000 abstract 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract 1
- 229910052708 sodium Inorganic materials 0.000 abstract 1
- 239000011734 sodium Substances 0.000 abstract 1
- -1 acyl methyl taurine salt Chemical class 0.000 description 9
- 239000003921 oil Substances 0.000 description 9
- 235000019198 oils Nutrition 0.000 description 9
- 239000012071 phase Substances 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 8
- 239000006071 cream Substances 0.000 description 8
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 6
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 239000002563 ionic surfactant Substances 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 235000014113 dietary fatty acids Nutrition 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 239000000194 fatty acid Substances 0.000 description 5
- 229930195729 fatty acid Natural products 0.000 description 5
- 150000004665 fatty acids Chemical class 0.000 description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- 238000011156 evaluation Methods 0.000 description 4
- 235000011187 glycerol Nutrition 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 229960003080 taurine Drugs 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 150000001413 amino acids Chemical class 0.000 description 3
- 230000001804 emulsifying effect Effects 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- AHLPHDHHMVZTML-BYPYZUCNSA-N L-Ornithine Chemical compound NCCC[C@H](N)C(O)=O AHLPHDHHMVZTML-BYPYZUCNSA-N 0.000 description 2
- HNDVDQJCIGZPNO-YFKPBYRVSA-N L-histidine Chemical compound OC(=O)[C@@H](N)CC1=CN=CN1 HNDVDQJCIGZPNO-YFKPBYRVSA-N 0.000 description 2
- 241001465754 Metazoa Species 0.000 description 2
- SUZRRICLUFMAQD-UHFFFAOYSA-N N-Methyltaurine Chemical compound CNCCS(O)(=O)=O SUZRRICLUFMAQD-UHFFFAOYSA-N 0.000 description 2
- AHLPHDHHMVZTML-UHFFFAOYSA-N Orn-delta-NH2 Natural products NCCCC(N)C(O)=O AHLPHDHHMVZTML-UHFFFAOYSA-N 0.000 description 2
- UTJLXEIPEHZYQJ-UHFFFAOYSA-N Ornithine Natural products OC(=O)C(C)CCCN UTJLXEIPEHZYQJ-UHFFFAOYSA-N 0.000 description 2
- 229920002472 Starch Polymers 0.000 description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- NOPFSRXAKWQILS-UHFFFAOYSA-N docosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCO NOPFSRXAKWQILS-UHFFFAOYSA-N 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 230000002500 effect on skin Effects 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- 239000003205 fragrance Substances 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- HNDVDQJCIGZPNO-UHFFFAOYSA-N histidine Natural products OC(=O)C(N)CC1=CN=CN1 HNDVDQJCIGZPNO-UHFFFAOYSA-N 0.000 description 2
- 239000008309 hydrophilic cream Substances 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 2
- 229960003104 ornithine Drugs 0.000 description 2
- 235000019271 petrolatum Nutrition 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 239000003755 preservative agent Substances 0.000 description 2
- 230000001953 sensory effect Effects 0.000 description 2
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N squalane Chemical compound CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 2
- 235000019698 starch Nutrition 0.000 description 2
- 239000008107 starch Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 239000001993 wax Substances 0.000 description 2
- 239000002023 wood Substances 0.000 description 2
- PORPENFLTBBHSG-MGBGTMOVSA-N 1,2-dihexadecanoyl-sn-glycerol-3-phosphate Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP(O)(O)=O)OC(=O)CCCCCCCCCCCCCCC PORPENFLTBBHSG-MGBGTMOVSA-N 0.000 description 1
- TZCPCKNHXULUIY-RGULYWFUSA-N 1,2-distearoyl-sn-glycero-3-phosphoserine Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@H](COP(O)(=O)OC[C@H](N)C(O)=O)OC(=O)CCCCCCCCCCCCCCCCC TZCPCKNHXULUIY-RGULYWFUSA-N 0.000 description 1
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
- MFGOFGRYDNHJTA-UHFFFAOYSA-N 2-amino-1-(2-fluorophenyl)ethanol Chemical compound NCC(O)C1=CC=CC=C1F MFGOFGRYDNHJTA-UHFFFAOYSA-N 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- 244000105624 Arachis hypogaea Species 0.000 description 1
- 239000004475 Arginine Substances 0.000 description 1
- 241000283690 Bos taurus Species 0.000 description 1
- 240000002791 Brassica napus Species 0.000 description 1
- 235000004977 Brassica sinapistrum Nutrition 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 241000588724 Escherichia coli Species 0.000 description 1
- JZNWSCPGTDBMEW-UHFFFAOYSA-N Glycerophosphorylethanolamin Natural products NCCOP(O)(=O)OCC(O)CO JZNWSCPGTDBMEW-UHFFFAOYSA-N 0.000 description 1
- ZWZWYGMENQVNFU-UHFFFAOYSA-N Glycerophosphorylserin Natural products OC(=O)C(N)COP(O)(=O)OCC(O)CO ZWZWYGMENQVNFU-UHFFFAOYSA-N 0.000 description 1
- 244000068988 Glycine max Species 0.000 description 1
- 235000010469 Glycine max Nutrition 0.000 description 1
- ODKSFYDXXFIFQN-BYPYZUCNSA-P L-argininium(2+) Chemical compound NC(=[NH2+])NCCC[C@H]([NH3+])C(O)=O ODKSFYDXXFIFQN-BYPYZUCNSA-P 0.000 description 1
- KDXKERNSBIXSRK-YFKPBYRVSA-N L-lysine Chemical compound NCCCC[C@H](N)C(O)=O KDXKERNSBIXSRK-YFKPBYRVSA-N 0.000 description 1
- 239000004166 Lanolin Substances 0.000 description 1
- 239000005639 Lauric acid Substances 0.000 description 1
- 239000004472 Lysine Substances 0.000 description 1
- KDXKERNSBIXSRK-UHFFFAOYSA-N Lysine Natural products NCCCCC(N)C(O)=O KDXKERNSBIXSRK-UHFFFAOYSA-N 0.000 description 1
- 108010038807 Oligopeptides Proteins 0.000 description 1
- 102000015636 Oligopeptides Human genes 0.000 description 1
- 235000021314 Palmitic acid Nutrition 0.000 description 1
- 239000004264 Petrolatum Substances 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 1
- WBWWGRHZICKQGZ-UHFFFAOYSA-N Taurocholic acid Natural products OC1CC2CC(O)CCC2(C)C2C1C1CCC(C(CCC(=O)NCCS(O)(=O)=O)C)C1(C)C(O)C2 WBWWGRHZICKQGZ-UHFFFAOYSA-N 0.000 description 1
- 241000209140 Triticum Species 0.000 description 1
- 235000021307 Triticum Nutrition 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000000908 ammonium hydroxide Substances 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- ODKSFYDXXFIFQN-UHFFFAOYSA-N arginine Natural products OC(=O)C(N)CCCNC(N)=N ODKSFYDXXFIFQN-UHFFFAOYSA-N 0.000 description 1
- 108010062796 arginyllysine Proteins 0.000 description 1
- 230000003796 beauty Effects 0.000 description 1
- 235000013871 bee wax Nutrition 0.000 description 1
- 239000012166 beeswax Substances 0.000 description 1
- 210000000941 bile Anatomy 0.000 description 1
- HUCVOHYBFXVBRW-UHFFFAOYSA-M caesium hydroxide Inorganic materials [OH-].[Cs+] HUCVOHYBFXVBRW-UHFFFAOYSA-M 0.000 description 1
- 239000004204 candelilla wax Substances 0.000 description 1
- 235000013868 candelilla wax Nutrition 0.000 description 1
- 229940073532 candelilla wax Drugs 0.000 description 1
- 150000001720 carbohydrates Chemical class 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 229960000541 cetyl alcohol Drugs 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- 235000005822 corn Nutrition 0.000 description 1
- 238000012937 correction Methods 0.000 description 1
- 229960002887 deanol Drugs 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 238000007033 dehydrochlorination reaction Methods 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 229940105990 diglycerin Drugs 0.000 description 1
- GPLRAVKSCUXZTP-UHFFFAOYSA-N diglycerol Chemical compound OCC(O)COCC(O)CO GPLRAVKSCUXZTP-UHFFFAOYSA-N 0.000 description 1
- 239000012972 dimethylethanolamine Substances 0.000 description 1
- 229960000735 docosanol Drugs 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 235000013345 egg yolk Nutrition 0.000 description 1
- 210000002969 egg yolk Anatomy 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 239000010696 ester oil Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000003349 gelling agent Substances 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 150000002314 glycerols Chemical class 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- IUJAMGNYPWYUPM-UHFFFAOYSA-N hentriacontane Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCC IUJAMGNYPWYUPM-UHFFFAOYSA-N 0.000 description 1
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 1
- 239000003906 humectant Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 238000001727 in vivo Methods 0.000 description 1
- 150000007529 inorganic bases Chemical class 0.000 description 1
- 239000000832 lactitol Substances 0.000 description 1
- 229960003451 lactitol Drugs 0.000 description 1
- 235000019388 lanolin Nutrition 0.000 description 1
- 229940039717 lanolin Drugs 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000005923 long-lasting effect Effects 0.000 description 1
- 239000000845 maltitol Substances 0.000 description 1
- 229940035436 maltitol Drugs 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- JXTPJDDICSTXJX-UHFFFAOYSA-N n-Triacontane Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCC JXTPJDDICSTXJX-UHFFFAOYSA-N 0.000 description 1
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
- 235000008390 olive oil Nutrition 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 235000020232 peanut Nutrition 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 229940066842 petrolatum Drugs 0.000 description 1
- WTJKGGKOPKCXLL-RRHRGVEJSA-N phosphatidylcholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCCCCCCC=CCCCCCCCC WTJKGGKOPKCXLL-RRHRGVEJSA-N 0.000 description 1
- 150000008104 phosphatidylethanolamines Chemical class 0.000 description 1
- 150000003905 phosphatidylinositols Chemical class 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 239000008213 purified water Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000001568 sexual effect Effects 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 230000036548 skin texture Effects 0.000 description 1
- RYYKJJJTJZKILX-UHFFFAOYSA-M sodium octadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC([O-])=O RYYKJJJTJZKILX-UHFFFAOYSA-M 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 229940032094 squalane Drugs 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- WBWWGRHZICKQGZ-GIHLXUJPSA-N taurocholic acid Chemical compound C([C@@H]1C[C@H]2O)[C@@H](O)CC[C@]1(C)[C@@H]1[C@@H]2[C@@H]2CC[C@@H]([C@@H](CCC(=O)NCCS(O)(=O)=O)C)[C@@]2(C)[C@H](O)C1 WBWWGRHZICKQGZ-GIHLXUJPSA-N 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 238000009834 vaporization Methods 0.000 description 1
- 230000008016 vaporization Effects 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/06—Emulsions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
- A61K8/466—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfonic acid derivatives; Salts
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Dermatology (AREA)
- Cosmetics (AREA)
Abstract
Description
【発明の詳細な説明】
［産業上の利用分野１
本発明は、安全性の高いイオン性界面活性剤による乳化
性にすぐれた安定な水中油型乳化化粧料であって、翌朝
までしっとり感が持続する肌効果に優れた水中油型乳化
化粧料に関する。[Detailed Description of the Invention] [Industrial Application Field 1] The present invention is a stable oil-in-water emulsion cosmetic with excellent emulsifying properties using a highly safe ionic surfactant, which provides a moist feeling until the next morning. This invention relates to an oil-in-water emulsion cosmetic with excellent long-lasting skin effects.
［従来の技術］
従来、イオン性界面活性剤を油の増粘・ゲル化剤及び乳
化剤として使用する試みがなされており、例えばイオン
性界面活性剤と多価アルコールと油相成分とを混合し、
安定な多価アルコール中油型非水エマルションを得た後
、これに水を添加してなる水中油型エマルションが知ら
れている（特開昭５７−７２３５号公報）。また、イオ
ン性界面活性剤と分子内に２個以上の水酸基を有する水
溶性多価アルコールと油相成分とを含む乳化組成物と、
炭素数がｌＯ〜３０の高級アルコールを含む水とを混合
して得られる水中油型乳化組成物も知られている（４＋
ｆ開閉５９−Ｅｉ９３８号公報）。[Prior Art] Previously, attempts have been made to use ionic surfactants as oil thickeners, gelling agents, and emulsifiers. ,
An oil-in-water emulsion is known, which is obtained by adding water to a stable oil-in-polyhydric alcohol non-aqueous emulsion (Japanese Patent Application Laid-open No. 7235/1983). Further, an emulsified composition containing an ionic surfactant, a water-soluble polyhydric alcohol having two or more hydroxyl groups in the molecule, and an oil phase component;
An oil-in-water emulsion composition obtained by mixing a higher alcohol with a carbon number of 10 to 30 with water is also known (4+
f opening/closing 59-Ei938).
［発明が解決しようとする問題点］
しかしながら、化粧料等に応用する場合、人体に対して
安全性の高いものが要望されており、イオン性界面活性
剤のなかには一般消費者の間で安全性に不安を抱くもの
も少なくなく、また、使用後の肌に対する効果も期待で
きないものが多かった。[Problems to be solved by the invention] However, when applied to cosmetics, etc., there is a demand for products that are highly safe for the human body, and some ionic surfactants are not considered safe among general consumers. Many people were concerned about this, and many products were not expected to have any effect on the skin after use.
［問題点を解決するための手段］
本発明者等は係る点に鑑み、イオン性界面活性剤を利用
した水中油型乳化化粧料につき、安全性ならびに安定化
方法について鋭意研究の結果、イオン性界面活性剤とし
てＮ−長鎖アシルメチルタウリン塩と、溶解パラメータ
ーが１２．５〜１８の水溶性多価アルコールとの組み合
わせが特に有効であることを見い出し、本発明を完成さ
せた。また、木組み合わせに於いて、イオン性界面活性
剤として、Ｎ−長鎖アシルメチルタウリン塩とレシチン
とを組み合わせて使用することが、更に安定性を向」ニ
させることを見い出した。なお、本発明の水中油型乳化
化粧料は。[Means for Solving the Problems] In view of the above points, the present inventors conducted extensive research on the safety and stabilization method of oil-in-water emulsion cosmetics using ionic surfactants, and found that The present invention was completed based on the discovery that a combination of an N-long chain acylmethyl taurine salt and a water-soluble polyhydric alcohol having a solubility parameter of 12.5 to 18 is particularly effective as a surfactant. It has also been found that the combination of N-long chain acylmethyl taurate salt and lecithin as ionic surfactants in wood combinations further improves the stability. In addition, the oil-in-water emulsion cosmetic of the present invention is as follows.
Ｎ−長鎖アシルメチルタウリン塩の作用により、翌朝ま
でしっとり感が持続する肌効果に優れたものでもあった
。Due to the action of the N-long chain acyl methyl taurine salt, the skin had an excellent effect of keeping the skin moist until the next morning.
すなわち本発明は、Ｎ−長鎖アシルメチルタウリンＩＩ
Ｍと、水溶性多価アルコールから選ばれる１種もしくは
２種以」−の組み合わせまたはこれらと水との組み合わ
せであって溶解パラメーターが１２．５〜１８である成
分と、油相成分とを含む乳化組成物と、水とを含有する
ことを特徴とする水中油型乳化化ｖｌ料、及び−に配水
中油型乳化化か［祠に於いて、乳化組成物を得るに際し
て、Ｎ−長鎖アシルメチルタウリン１ムにリン脂質及び
／またはその塩を併用することを特徴とする水中油型乳
化化粧料である。That is, the present invention provides N-long chain acylmethyltaurine II
M and one or more selected from water-soluble polyhydric alcohols, or a combination of these and water with a solubility parameter of 12.5 to 18, and an oil phase component. An oil-in-water emulsification agent characterized by containing an emulsifying composition and water; This is an oil-in-water emulsion cosmetic characterized by using methyl taurine in combination with phospholipids and/or their salts.
特にＮ−長鎖アシルメチルタウリン塩は、洗浄剤として
は応用されてはいるものの、乳化剤としてはその特性を
生かした応用は見られなかったものである。今回、乳化
剤として水中油型乳化化粧料へ適用することにより、そ
の効果が著大であることを見い出したものである。In particular, N-long chain acylmethyl taurine salts have been used as detergents, but have not been used as emulsifiers to take advantage of their properties. This time, we have discovered that when applied as an emulsifier to oil-in-water emulsified cosmetics, the effect is significant.
以下に本発明の構成について述べる。The configuration of the present invention will be described below.
本発明に使用するＮ−長鎖アシルメチルタウリン塩は、
脂肪酸とＮ−メチルタウリン塩との縮合物で、アミドス
ルホネート型アニオン界面活性剤であり、人や動物の胆
汁中に存在する生体内界面活性剤であるタウロコール酸
と類似した構造を持っている安全性の高いものである。The N-long chain acylmethyl taurine salt used in the present invention is
It is a condensation product of fatty acid and N-methyltaurine salt, and is an amide sulfonate type anionic surfactant.It is safe because it has a structure similar to taurocholic acid, which is an in-vivo surfactant that exists in human and animal bile. It is highly sexual.
Ｎ−長鎖アシルメチルタウリン塩の製造法に関しては、
（Ｔ） 脂肪酸クロライドとＮ−メチルタウリン塩と
のアルカリ存在下に於ける脱塩酸反応■ 脂肪酸とＮ−
メチルタウリン塩との脱水反応
■ 脂肪酸インプロペニルエステルとＮ−メチルタウリ
ン塩との脱アセトン反応
等がある。Regarding the production method of N-long chain acyl methyl taurate salt, (T) Dehydrochlorination reaction between fatty acid chloride and N-methyl taurate salt in the presence of an alkali■ Fatty acid and N-
Dehydration reaction with methyl taurate ■ Deacetonization reaction between fatty acid impropenyl ester and N-methyl taurate, etc.
また、脂肪酸は炭素数が１２〜２６のものであり、特に
好ましくは、ラウリン酸、ミリスチン酸、パルミチン酸
、ステアリン酸である。Further, the fatty acid has 12 to 26 carbon atoms, and particularly preferably lauric acid, myristic acid, palmitic acid, and stearic acid.
川を生成する塩基としては、例えば、トリエタノールア
ミン・水酸化ナトリウム・水酸化カリウム・アルギニン
会リジン・ヒスチジン・オルニチン・オキシリジン等を
挙げることができる。また、このうちで塩基性アミノ酸
は、Ｄ一体・Ｌ一体・ＤＬ一体の別を問わず使用できる
。また、塩基は単独で用いてもよく、あるいは複数の組
み合わせで用いてもよい。Examples of the base that generates a river include triethanolamine, sodium hydroxide, potassium hydroxide, arginine lysine, histidine, ornithine, and oxylysine. Moreover, among these, basic amino acids can be used regardless of whether they are D-integrated, L-integrated, or DL-integrated. Further, the bases may be used alone or in combination.
溶解パラメーターは、例えば、ポリマーハンドブック（
Ｐｏｌｙｍｅｒ ｈａｎｄ ｂｏｏｋ； Ｅ、Ｈ，Ｉｍ
ｍｅｒｇｕｔ。Solubility parameters can be found, for example, in the Polymer Handbook (
Polymer hand book; E, H, Im
mergut.
Ｉｎｔｅｒｓｃｉｅｎｃｅ Ｐｕｂｌｉｓｈｅｒｓ）に
記載されているもので、溶媒の熱力学的性質を示し、相
溶性（親和性）を測定するために用いられるものであり
、二種の溶媒がほぼ同一な値を持てばその溶媒は互いに
混和するとされている。溶解パラメーターの計算方法は
、蒸発熱から求める方法、ファンデル・ワールス・ガス
定数から求める方法、臨界圧から求める方法、表面張力
から求める方法があるが、本発明においては次式に従い
蒸発熱から求めたものを使用した。Interscience Publishers), it indicates the thermodynamic properties of a solvent and is used to measure compatibility (affinity), and if two solvents have almost the same value, they are Solvents are said to be miscible with each other. The solubility parameter can be calculated from the heat of vaporization, from the van der Waals gas constant, from the critical pressure, or from the surface tension. I used something similar.
δ ＝ （ΔＥ／Ｖ）１／２ ・・
・・・・・・・（１）ΔＥ ＝ΔＨ−ＲＴ
・・・・・・・・・（２）ΔＨ＝ ２３
．７Ｔ ｂ ＋ ０．２０Ｔ ｂ −２！１１５
０・・・・・・・・・（３）δ：溶解パラメーター
ΔＥ：蒸発エネルギー
■＝分子容
ΔＨ：蒸発熱
Ｔｂ：情意（°Ｋ）
補正：アルコールの場合計算値に １．４を加える。δ = (ΔE/V)1/2...
・・・・・・・・・(1) ΔE = ΔH−RT
・・・・・・・・・(2) ΔH= 23
．． 7T b + 0.20T b -2!115
0・・・・・・・・・(3) δ: Solubility parameter ΔE: Evaporation energy ■=Molecular volume ΔH: Heat of evaporation Tb: Passion (°K) Correction: In the case of alcohol, add 1.4 to the calculated value.
以−にの方法によって測定した水溶性多価アルコール、
水の溶解パラメーターは表１の如くである。本発明で使
用できるものは、水溶性多価アルコールから選ばれる１
種もしくは２挿具−ヒの組み合わせまたはこれらと水と
の組み合わせであって溶解パラメーターが１２．５〜１
Ｂであるものである。以下、本発明の水溶性多価アルコ
ール類と呼ぶものとする。Water-soluble polyhydric alcohol measured by the method below,
The water solubility parameters are as shown in Table 1. What can be used in the present invention is 1 selected from water-soluble polyhydric alcohols.
A combination of seeds or two twigs and water or a combination of these and water with a solubility parameter of 12.5 to 1.
B. Hereinafter, it shall be referred to as the water-soluble polyhydric alcohol of the present invention.
混合物の溶解パラメーターは次式により求められる（２
種の混合物の場合）。The solubility parameter of the mixture is determined by the following formula (2
(for seed mixtures).
ｘｌＶｌ δ１ ＋ｘ２ Ｖ２ δ２ｘｌ Ｖ
Ｉ ＋ｘ２ Ｖ２
Ｘｌ、Ｘ２：それぞれのモル分率
Ｖｔ 、ｖ２ ：それぞれの分子容δ１ 、δ２
：それぞれの溶解パラメーターここで、モル分率は次式
により求められる。xlVl δ1 +x2 V2 δ2xl V
I +x2 V2 Xl, X2: respective molar fractions Vt, v2: respective molecular volumes δ1, δ2
:Each solubility parameter Here, the mole fraction is determined by the following formula.
Ｗｌ
Ｘ２＝１−ＸＩ
Ｗｌ 、Ｗ２ ：それぞれの配合重量Ｍ１ 、
Ｍ２ ：それぞれの分子量参考のために１表１に分子量
と分子容をも示した。Wl
M2: Each molecular weight The molecular weight and molecular volume are also shown in Table 1 for reference.
（以下余白）
表 １
本発明に使用可能な水溶性多価アルコール類は、例えば
、プロピレングリコール・１．３−ブチレングリコール
φジプロピレングリコール・エチレングリコール・ポリ
エチレングリコール等のグリコール類、グリセリン・ジ
グリセリン・ポリグリセリン等のグリセロール類、ソル
ビトール−マルチトール・ショ糖番でんぷん糖・還元で
んぷん糖φラクチトール等の糖類、ペンタエリスリトー
ルから選ばれる１種もしくは２種以上の組み合わせまた
はこれらと水との組み合わせであって溶解パラメーター
が１２．５〜！８であるものである。(Left below) Table 1 Examples of water-soluble polyhydric alcohols that can be used in the present invention include glycols such as propylene glycol, 1,3-butylene glycol, dipropylene glycol, ethylene glycol, and polyethylene glycol, glycerin, and diglycerin. - One or more combinations selected from glycerols such as polyglycerin, sorbitol-maltitol, saccharides such as sucrose, starch sugar, reduced starch sugar φ-lactitol, and pentaerythritol, or a combination of these and water. The solubility parameter is 12.5~! 8.
次に油相成分としては、通常化粧品の分野で使用され、
人体に対して安全とされているものが用い得る。例えば
、オリーブ油・ヒマシ油等の植物油、ミツロウΦラノリ
ンφキャンデリラワックス・木ロウ等のワックス類、流
動ノぐラフイン・スクワラン・ワセリンΦパラフィンワ
ックス等の炭化水素、セタノールφステアリルアルコー
ル・ベヘニルアルコール等の高級アルコ−ル、その他の
エステル油、シリコン油等を挙げることができる。Next, as an oil phase component, it is usually used in the field of cosmetics.
Any material that is considered safe for the human body can be used. For example, vegetable oils such as olive oil and castor oil, waxes such as beeswax Φ lanolin φ candelilla wax and wood wax, hydrocarbons such as liquid graphite, squalane, petrolatum Φ paraffin wax, and high-grade products such as cetanol φ stearyl alcohol and behenyl alcohol. Examples include alcohol, other ester oils, and silicone oils.
本発明に使用するリン脂質は、大豆・トウモロコシ・落
花生−ナタネΦ麦等の植物、卵黄・牛等の動物、大腸菌
等の微生物から抽出されるリン脂質であり、ホスファチ
ジン酸・ホスファチジルグリセリン・ホスファチジルイ
ノシトール・ホスファチジルエタノールアミン・ホスフ
ァチジルモノメチルエタノールアミン・ホスファチジル
ジメチルエタノールアミン・ホスファチジルコリン（レ
シチン）・ホスファチジルセリン・ビスホスファチジン
酸・ジホスファチジルグリセリン（カルシオリピン）等
のグリ七ロリン脂質、スフィンゴミエリン等のスフィン
ゴリン脂質を挙げることができ、さらに、これらを水素
添加処理したものも挙げることができる。特に、水素添
加処理したリン脂質は、非常に安定性が高く好ましい。The phospholipids used in the present invention are phospholipids extracted from plants such as soybeans, corn, peanuts, rapeseed and wheat, animals such as egg yolks and cows, and microorganisms such as Escherichia coli, and include phosphatidic acid, phosphatidylglycerin, and phosphatidylinositol.・Glycerol phospholipids such as phosphatidylethanolamine, phosphatidyl monomethylethanolamine, phosphatidyl dimethylethanolamine, phosphatidylcholine (lecithin), phosphatidylserine, bisphosphatidic acid, diphosphatidylglycerin (calciolipin), and sphingophospholipids such as sphingomyelin. In addition, those obtained by hydrogenation treatment can also be mentioned. In particular, hydrogenated phospholipids are highly stable and preferred.
これらは単独で用いてもよく、あるいは複数の組み合わ
せで用いてもよい。These may be used alone or in combination.
リン脂質を塩として利用する場合、塩を形成する物質と
しては、水酸化リチウム・水酸化ナトリウム・水酸化カ
リウム・水酸化セシウム・水酸化アンモニウム等の無機
塩基、アルギニン・リジン・ヒスチジン・オルニチン等
の塩基性アミノ酸、１ム基性アミノ酸を残基として有す
る塩基性オリゴペプチド、モノエタノールアミン・ジェ
タノールアミン・トリエタノールアミン等の塩基性アミ
ンを挙げることができる。リン脂質のＩｎも単独で用い
てもよく、あるいは複数の組み合わせで用いてもよい。When using phospholipids as salts, salt-forming substances include inorganic bases such as lithium hydroxide, sodium hydroxide, potassium hydroxide, cesium hydroxide, and ammonium hydroxide, and arginine, lysine, histidine, ornithine, etc. Examples include basic amino acids, basic oligopeptides having a basic amino acid as a residue, and basic amines such as monoethanolamine, jetanolamine, and triethanolamine. The phospholipid In may be used alone or in combination.
本発明に於ける乳化組成物に於いて、Ｎ−長鎖アシルメ
チルタウリン塩と、溶解パラメーターが１２．５〜１８
である本発明の水溶性多価アルコール類との配合量は、
重量比１：１ ”１：３０の範囲である。油相成分の配
合量は、Ｎ−長鎖アシルメチルタウリンｆｆｉと溶解パ
ラメーターが１２．５〜１８である本発明の水溶性多価
アルコール類との合計量の３００重量倍以下の範囲であ
る。In the emulsion composition of the present invention, the N-long chain acylmethyl taurine salt and the solubility parameter are 12.5 to 18.
The amount of the water-soluble polyhydric alcohol of the present invention is:
The weight ratio is in the range of 1:1" to 1:30. The blending amount of the oil phase components is N-long chain acylmethyl taurine ffi and the water-soluble polyhydric alcohol of the present invention having a solubility parameter of 12.5 to 18. The range is 300 times the total amount by weight or less.
上記範囲内に於いて、均一な乳化組成物が得られ、次い
で水を加えることによって安定な水中油型乳化化粧料を
得ることができる。Within the above range, a uniform emulsified composition can be obtained, and then by adding water, a stable oil-in-water emulsified cosmetic can be obtained.
また、本発明に係る他の水中油型乳化化粧料は、上記乳
化組成物を得るに際して、Ｎ−長鎖アシルメチルタウリ
ン塩にリン脂質及び／またはその塩を併用することを特
徴とするものである。Ｎ−長鎖アシルメチルタウリン塩
と、リン脂質及び／またはその塩との配合割合は、重量
比ｌ：９〜９：ｌの範囲である。溶解パラメーターが１
２．５〜１８である本発明の水溶性多価アルコール類の
配合量は、Ｎ−長鎖アシルメチルタウリン塩と、リン脂
質及び／またはその塩との合計量の１〜２０重量倍の範
囲である。この場合の油相成分の配合量は、Ｎ−長鎖ア
シルメチルタウリン塩と、リン脂質及び／またはその塩
と、溶解パラメーターが１２．５〜１８である本発明の
水溶性多価アルコール類との合計量の３００重量倍以下
の範囲である。上記範囲内に於いて、均一な乳化組成物
が得られ、次いで水を加えることによって安定な水中油
型乳化化粧料を得ることができる。リン脂質及び／また
はその塩の併用により、混合界面活性剤系のＨＬＢ値を
下げることによってより良好な乳化性をもたらしており
、更に、Ｎ−長鎖アシルメチルタウリン１ｎの溶解性を
高め、析出等を防止するので、より安定性を高めている
。Further, another oil-in-water emulsified cosmetic according to the present invention is characterized in that, when obtaining the above-mentioned emulsified composition, a phospholipid and/or a salt thereof is used in combination with an N-long chain acylmethyl taurine salt. be. The mixing ratio of the N-long chain acylmethyl taurine salt and the phospholipid and/or its salt is in the range of 1:9 to 9:1 by weight. solubility parameter is 1
The amount of the water-soluble polyhydric alcohol of the present invention having a molecular weight of 2.5 to 18 is in the range of 1 to 20 times the total amount of the N-long chain acylmethyl taurine salt and the phospholipid and/or its salt. It is. In this case, the blending amounts of the oil phase components are: N-long chain acylmethyl taurine salt, phospholipid and/or its salt, and the water-soluble polyhydric alcohol of the present invention having a solubility parameter of 12.5 to 18. The range is 300 times the total amount by weight or less. Within the above range, a uniform emulsified composition can be obtained, and then by adding water, a stable oil-in-water emulsified cosmetic can be obtained. The combined use of phospholipids and/or their salts lowers the HLB value of the mixed surfactant system, resulting in better emulsifying properties, and also increases the solubility of N-long chain acylmethyl taurine 1n, resulting in improved precipitation. etc., thereby increasing stability.
なお、乳化組成物を得るに際して、Ｎ−長鎖アシルメチ
ルタウリン塩と、本発明の水溶性多価アルコール類と、
場合によっては、リン脂質及び／またはその塩を加えて
、先ず均一なゲルを調製後、油相成分を加えて乳化組成
物を得る方法を採用しても良いし、これら成分を一度に
加えて混合して、均一な乳化組成物を得る方法を採用し
てもかまわない。In addition, when obtaining the emulsified composition, the N-long chain acylmethyl taurine salt, the water-soluble polyhydric alcohol of the present invention,
In some cases, a method may be adopted in which a phospholipid and/or its salt is added to first prepare a homogeneous gel, and then an oil phase component is added to obtain an emulsified composition, or a method may be adopted in which an emulsified composition is obtained by adding these components at once. A method of obtaining a uniform emulsion composition by mixing may be adopted.
本発明の水中油型乳化化粧料には、前記必須成分に加え
て更に、化粧品に一般に使用される薬剤・粉体・一般界
面活性剤・色素−香料−アルコール・保湿剤−防腐剤・
美容剤・酸化防止剤・紫外線吸収剤・水溶性高分子等を
適宜配合することができる。In addition to the above-mentioned essential ingredients, the oil-in-water emulsion cosmetic of the present invention further contains drugs commonly used in cosmetics, powders, general surfactants, pigments, fragrances, alcohol, humectants, preservatives,
Beauty agents, antioxidants, ultraviolet absorbers, water-soluble polymers, etc. can be blended as appropriate.
［実施例１
次に本発明について実施例を挙げてさらに説明する。こ
れらは本発明を何ら限定するものではない。[Example 1] Next, the present invention will be further described with reference to Examples. These do not limit the present invention in any way.
実施例 ［１］〜［２１、比較例 ［１］〜［３１表２
及び表３に示す如く、Ｎ−長鎖アシルメチルタウリン１
１！、水溶性多価アルコール類、油相成分を７０°Ｃに
てホモミクサー処理して乳化組成物を得た後、７０°Ｃ
に加熱した水相成分を加えて水中油型のクリームを得た
。Examples [1] to [21] Comparative examples [1] to [31 Table 2
and as shown in Table 3, N-long chain acylmethyl taurine 1
1! , water-soluble polyhydric alcohols, and oil phase components were treated with a homomixer at 70°C to obtain an emulsified composition, and then heated at 70°C.
An oil-in-water cream was obtained by adding heated aqueous phase ingredients to the mixture.
実施例 ［３］、比較例 ［４］〜［５］表４に示す如
く、Ｎ−長鎖アシルメチルタウリン１１ｘ、リン脂質、
水溶性多価アルコール類を７０°Ｃにてホモミクサー処
理してゲルを調製後、７０°Ｃに加熱した油相成分を加
えて乳化組成物を得、更に７０°Ｃに加熱した水相成分
を加えて水中油型のクリームを得た。Example [3], Comparative Examples [4] to [5] As shown in Table 4, N-long chain acylmethyl taurine 11x, phospholipid,
After preparing a gel by treating water-soluble polyhydric alcohols with a homomixer at 70°C, add the oil phase component heated to 70°C to obtain an emulsified composition, and then add the water phase component heated to 70°C. In addition, an oil-in-water cream was obtained.
（以下余白）
表 ２
表 ３
表４
［発明の効果１
本発明の水中油型乳化化粧料の安定性の良さを確認する
為に、実施例 ［１１〜［３１につき、比較例 ［１］
〜［５］ と共に、４０°Ｃに於ける１力月後の状態を
観察した。結果は表２〜４に示す。実施例 ［１］〜［
３１のクリームは、それぞれ均一なエマルジョンであっ
て、製造時と何ら変わることなく、良好な安定性を示し
た。一方、比較例［３］ 、 ［５］ のクリームは
分離しており、また。(The following are blank spaces) Table 2 Table 3 Table 4 [Effect of the invention 1 In order to confirm the stability of the oil-in-water emulsion cosmetic of the present invention, Examples [11 to [31], Comparative examples [1]
~[5] Together with the above, the state after one month at 40°C was observed. The results are shown in Tables 2-4. Examples [1] to [
Cream No. 31 was a uniform emulsion, showing no change from the time of manufacture and exhibiting good stability. On the other hand, the creams of Comparative Examples [3] and [5] were separated;
比較例［１］ 、 ［２］ 、 ［４］のクリームは、
Ｎ−長鎖アシルメチルタウリン塩と思われる固体の析出
が見られ、安定性に劣るものであった。The creams of Comparative Examples [1], [2], and [4] are
Precipitation of a solid believed to be an N-long chain acylmethyl taurine salt was observed, and the stability was poor.
また、本発明の水中油型乳化化粧料の翌朝までしっとり
感が持続する肌効果について、その効果を確認する為に
、実施例Ｉｌｌのクリームにつき、比較例［６］のクリ
ーム（以下に示す）と共に、官能検査を行なった。In addition, in order to confirm the effect of the oil-in-water emulsion cosmetic of the present invention on keeping the skin moisturized until the next morning, we used the cream of Example Ill and the cream of Comparative Example [6] (shown below). At the same time, a sensory test was conducted.
比較例［６］
（処方） （重量％）１、
ステアリン酸ナトリウム ０．５２、グリセリ
ン １０．０３、流動パラフィン
２０．０４、 セタノール
５．０５、香料
０．２ｅ、 １．３−ブチレングリコール
１０．０７、防腐剤 適量
８、精製水 残量（製造方法
）
実施例［１１の製造方法に準する。Comparative example [6] (Formulation) (Weight%) 1,
Sodium stearate 0.52, glycerin 10.03, liquid paraffin
20.04, Setanol
5.05, fragrance
0.2e, 1.3-butylene glycol
10.07, Preservative appropriate amount 8, Purified water remaining amount (manufacturing method) According to the manufacturing method of Example [11].
（官能検査）
１０名の女性パネルにて洗顔後、就寝前に試料クリーム
を左右の頬部にそれぞれ０．０５ｇずつ塗布し、翌朝２
５℃の恒温室内で、下記の評価項目にて相対評価を行な
った。(Sensory test) A panel of 10 women applied 0.05g of the sample cream to each of their left and right cheeks after washing their faces and before going to bed.
Relative evaluation was performed using the following evaluation items in a constant temperature room at 5°C.
（評価項目） １、肌ざわりの良さ ２、肌の柔らかさ ３、肌のなめらかさ ４、肌のしっとり感 ５、肌のツヤ （評価基準） ５段階の一対比較法により２種のサンプルを比較した。(Evaluation item) 1. Good texture 2.Skin softness 3.Smooth skin 4. Moist skin feeling 5. Skin glow (Evaluation criteria) The two samples were compared using a five-step paired comparison method.
結果は表５に人数で示す。The results are shown in Table 5 in terms of number of participants.
表 ５
表５の結果より明らかな如く、実施例［１］のクリーム
は、比較例［８］のクリームに比較して、翌朝の肌効果
に於いて、肌ざわりの良さ、肌のなめらかさの点で優れ
ていた。また、肌の柔らかさ、肌のなめらかさの点でも
優れている傾向がみられた。Table 5 As is clear from the results in Table 5, the cream of Example [1] had better skin texture and smoother skin the next morning than the cream of Comparative Example [8]. It was excellent. Additionally, there was a tendency for the skin to be superior in terms of skin softness and smoothness.
以」二の如く、本発明の水中油型乳化化粧料は、安全性
−安定性の高い、翌朝までしっとり感が持続する肌効果
に優れた水中油型乳化化粧料である。As described above, the oil-in-water emulsion cosmetic of the present invention is highly safe and stable, and has excellent skin effects that keep the skin feeling moist until the next morning.
以 上that's all
Claims (2)
アルコールから選ばれる１種もしくは２種以上の組み合
わせまたはこれらと水との組み合わせであって溶解パラ
メーターが１２．５〜１８である成分と、油相成分とを
含む乳化組成物と、水とを含有することを特徴とする水
中油型乳化化粧料。(1) A component that is a combination of N-long chain acylmethyl taurate and one or more selected from water-soluble polyhydric alcohols, or a combination of these and water, and has a solubility parameter of 12.5 to 18. An oil-in-water emulsion cosmetic comprising: an emulsion composition containing an oil phase component; and water.
び／またはその塩と、水溶性多価アルコールから選ばれ
る１種もしくは２種以上の組み合わせまたはこれらと水
との組み合わせであって溶解パラメーターが１２．５〜
１８である成分と、油相成分とを含む乳化組成物と、水
とを含有することを特徴とする水中油型乳化化粧料。(2) A combination of one or more selected from N-long chain acylmethyl taurine salt, phospholipid and/or its salt, and water-soluble polyhydric alcohol, or a combination of these and water, with solubility parameters is 12.5~
An oil-in-water emulsion cosmetic comprising an emulsion composition containing the component No. 18, an oil phase component, and water.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61159493A JPH0753648B2 (en) | 1986-07-07 | 1986-07-07 | Oil-in-water emulsion cosmetic |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61159493A JPH0753648B2 (en) | 1986-07-07 | 1986-07-07 | Oil-in-water emulsion cosmetic |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6314706A true JPS6314706A (en) | 1988-01-21 |
| JPH0753648B2 JPH0753648B2 (en) | 1995-06-07 |
Family
ID=15694970
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP61159493A Expired - Fee Related JPH0753648B2 (en) | 1986-07-07 | 1986-07-07 | Oil-in-water emulsion cosmetic |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0753648B2 (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5075113A (en) * | 1988-04-22 | 1991-12-24 | Jacques Dubois | Products comprising an emulsion of water and oily paraffinic hydrocarbons with added extracts of lecithin and processes for production |
| JP2003267818A (en) * | 2002-03-15 | 2003-09-25 | Kose Corp | Whitening cosmetic |
| WO2006018149A1 (en) * | 2004-08-13 | 2006-02-23 | Henkel Kommanditgesellschaft Auf Aktien | Cosmetic compositions for treating stressed skin containing taurine and long-chained fatty alcohols |
| WO2015034046A1 (en) * | 2013-09-06 | 2015-03-12 | サントリーホールディングス株式会社 | Emulsion and production method therefor |
| JP2016044181A (en) * | 2014-08-19 | 2016-04-04 | 株式会社コーセー | Oil in water emulsion composition |
| JP2016079183A (en) * | 2014-10-15 | 2016-05-16 | 株式会社コーセー | Oil-in-water emulsion composition |
| JP2017114804A (en) * | 2015-12-24 | 2017-06-29 | 花王株式会社 | Oil-in-water type liquid bathing agent and manufacturing method thereof |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5351376B2 (en) * | 2006-05-24 | 2013-11-27 | 株式会社 資生堂 | Oil-in-water emulsified cosmetic |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62226921A (en) * | 1986-03-28 | 1987-10-05 | Lion Corp | Skin detergent composition |
-
1986
- 1986-07-07 JP JP61159493A patent/JPH0753648B2/en not_active Expired - Fee Related
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62226921A (en) * | 1986-03-28 | 1987-10-05 | Lion Corp | Skin detergent composition |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5075113A (en) * | 1988-04-22 | 1991-12-24 | Jacques Dubois | Products comprising an emulsion of water and oily paraffinic hydrocarbons with added extracts of lecithin and processes for production |
| JP2003267818A (en) * | 2002-03-15 | 2003-09-25 | Kose Corp | Whitening cosmetic |
| WO2006018149A1 (en) * | 2004-08-13 | 2006-02-23 | Henkel Kommanditgesellschaft Auf Aktien | Cosmetic compositions for treating stressed skin containing taurine and long-chained fatty alcohols |
| WO2015034046A1 (en) * | 2013-09-06 | 2015-03-12 | サントリーホールディングス株式会社 | Emulsion and production method therefor |
| JPWO2015034046A1 (en) * | 2013-09-06 | 2017-03-02 | サントリーホールディングス株式会社 | Emulsion and production method thereof |
| JP2016044181A (en) * | 2014-08-19 | 2016-04-04 | 株式会社コーセー | Oil in water emulsion composition |
| JP2016079183A (en) * | 2014-10-15 | 2016-05-16 | 株式会社コーセー | Oil-in-water emulsion composition |
| JP2017114804A (en) * | 2015-12-24 | 2017-06-29 | 花王株式会社 | Oil-in-water type liquid bathing agent and manufacturing method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0753648B2 (en) | 1995-06-07 |
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