JPS63132813A - Semi-transparent cosmetic - Google Patents
Semi-transparent cosmeticInfo
- Publication number
- JPS63132813A JPS63132813A JP27949586A JP27949586A JPS63132813A JP S63132813 A JPS63132813 A JP S63132813A JP 27949586 A JP27949586 A JP 27949586A JP 27949586 A JP27949586 A JP 27949586A JP S63132813 A JPS63132813 A JP S63132813A
- Authority
- JP
- Japan
- Prior art keywords
- alcohol
- water
- transparency
- oil
- poe
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000002537 cosmetic Substances 0.000 title claims abstract description 19
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 67
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 26
- 239000004094 surface-active agent Substances 0.000 claims abstract description 14
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 9
- ZORQXIQZAOLNGE-UHFFFAOYSA-N 1,1-difluorocyclohexane Chemical compound FC1(F)CCCCC1 ZORQXIQZAOLNGE-UHFFFAOYSA-N 0.000 abstract description 5
- 239000001593 sorbitan monooleate Substances 0.000 abstract description 5
- 235000011069 sorbitan monooleate Nutrition 0.000 abstract description 5
- 229940035049 sorbitan monooleate Drugs 0.000 abstract description 5
- LEACJMVNYZDSKR-UHFFFAOYSA-N 2-octyldodecan-1-ol Chemical compound CCCCCCCCCCC(CO)CCCCCCCC LEACJMVNYZDSKR-UHFFFAOYSA-N 0.000 abstract description 3
- 238000013329 compounding Methods 0.000 abstract 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 18
- 239000012071 phase Substances 0.000 description 16
- 239000003921 oil Substances 0.000 description 14
- 235000019198 oils Nutrition 0.000 description 14
- 239000006210 lotion Substances 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 7
- -1 polyoxyethylene Polymers 0.000 description 7
- 239000003755 preservative agent Substances 0.000 description 7
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 6
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 6
- 239000003205 fragrance Substances 0.000 description 6
- 239000008346 aqueous phase Substances 0.000 description 5
- 239000004359 castor oil Chemical class 0.000 description 5
- 235000019438 castor oil Nutrition 0.000 description 5
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Chemical class CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- 230000002335 preservative effect Effects 0.000 description 5
- 238000003756 stirring Methods 0.000 description 5
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 4
- POJWUDADGALRAB-UHFFFAOYSA-N allantoin Chemical compound NC(=O)NC1NC(=O)NC1=O POJWUDADGALRAB-UHFFFAOYSA-N 0.000 description 4
- GPLRAVKSCUXZTP-UHFFFAOYSA-N diglycerol Chemical compound OCC(O)COCC(O)CO GPLRAVKSCUXZTP-UHFFFAOYSA-N 0.000 description 4
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N squalane Chemical compound CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 4
- QYIXCDOBOSTCEI-QCYZZNICSA-N (5alpha)-cholestan-3beta-ol Chemical compound C([C@@H]1CC2)[C@@H](O)CC[C@]1(C)[C@@H]1[C@@H]2[C@@H]2CC[C@H]([C@H](C)CCCC(C)C)[C@@]2(C)CC1 QYIXCDOBOSTCEI-QCYZZNICSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- NCHJGQKLPRTMAO-XWVZOOPGSA-N [(2R)-2-[(2R,3R,4S)-3,4-dihydroxyoxolan-2-yl]-2-hydroxyethyl] 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O NCHJGQKLPRTMAO-XWVZOOPGSA-N 0.000 description 3
- QYIXCDOBOSTCEI-UHFFFAOYSA-N alpha-cholestanol Natural products C1CC2CC(O)CCC2(C)C2C1C1CCC(C(C)CCCC(C)C)C1(C)CC2 QYIXCDOBOSTCEI-UHFFFAOYSA-N 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 235000014113 dietary fatty acids Nutrition 0.000 description 3
- 239000000194 fatty acid Substances 0.000 description 3
- 229930195729 fatty acid Natural products 0.000 description 3
- 235000011187 glycerol Nutrition 0.000 description 3
- 238000005342 ion exchange Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical compound OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 2
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 description 2
- FFJCNSLCJOQHKM-CLFAGFIQSA-N (z)-1-[(z)-octadec-9-enoxy]octadec-9-ene Chemical compound CCCCCCCC\C=C/CCCCCCCCOCCCCCCCC\C=C/CCCCCCCC FFJCNSLCJOQHKM-CLFAGFIQSA-N 0.000 description 2
- 229940058015 1,3-butylene glycol Drugs 0.000 description 2
- CAYHVMBQBLYQMT-UHFFFAOYSA-N 2-decyltetradecan-1-ol Chemical compound CCCCCCCCCCCCC(CO)CCCCCCCCCC CAYHVMBQBLYQMT-UHFFFAOYSA-N 0.000 description 2
- IZHVBANLECCAGF-UHFFFAOYSA-N 2-hydroxy-3-(octadecanoyloxy)propyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)COC(=O)CCCCCCCCCCCCCCCCC IZHVBANLECCAGF-UHFFFAOYSA-N 0.000 description 2
- HIQIXEFWDLTDED-UHFFFAOYSA-N 4-hydroxy-1-piperidin-4-ylpyrrolidin-2-one Chemical compound O=C1CC(O)CN1C1CCNCC1 HIQIXEFWDLTDED-UHFFFAOYSA-N 0.000 description 2
- POJWUDADGALRAB-PVQJCKRUSA-N Allantoin Natural products NC(=O)N[C@@H]1NC(=O)NC1=O POJWUDADGALRAB-PVQJCKRUSA-N 0.000 description 2
- 239000004475 Arginine Substances 0.000 description 2
- CKLJMWTZIZZHCS-REOHCLBHSA-N L-aspartic acid Chemical compound OC(=O)[C@@H](N)CC(O)=O CKLJMWTZIZZHCS-REOHCLBHSA-N 0.000 description 2
- 229920001214 Polysorbate 60 Polymers 0.000 description 2
- 235000019774 Rice Bran oil Nutrition 0.000 description 2
- LDDUCKDUDZVHLN-UHFFFAOYSA-N [2-hydroxy-3-[2-hydroxy-3-(16-methylheptadecanoyloxy)propoxy]propyl] 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OCC(O)COCC(O)COC(=O)CCCCCCCCCCCCCCC(C)C LDDUCKDUDZVHLN-UHFFFAOYSA-N 0.000 description 2
- DRRMRHKHTQRWMB-UHFFFAOYSA-N [3-(2-ethylhexanoyloxy)-2,2-bis(2-ethylhexanoyloxymethyl)propyl] 2-ethylhexanoate Chemical compound CCCCC(CC)C(=O)OCC(COC(=O)C(CC)CCCC)(COC(=O)C(CC)CCCC)COC(=O)C(CC)CCCC DRRMRHKHTQRWMB-UHFFFAOYSA-N 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 150000005215 alkyl ethers Chemical class 0.000 description 2
- 229960000458 allantoin Drugs 0.000 description 2
- 235000003704 aspartic acid Nutrition 0.000 description 2
- OQFSQFPPLPISGP-UHFFFAOYSA-N beta-carboxyaspartic acid Natural products OC(=O)C(N)C(C(O)=O)C(O)=O OQFSQFPPLPISGP-UHFFFAOYSA-N 0.000 description 2
- 235000019437 butane-1,3-diol Nutrition 0.000 description 2
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 2
- 235000008524 evening primrose extract Nutrition 0.000 description 2
- 239000010475 evening primrose oil Substances 0.000 description 2
- 229940089020 evening primrose oil Drugs 0.000 description 2
- 239000003906 humectant Substances 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- JXTPJDDICSTXJX-UHFFFAOYSA-N n-Triacontane Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCC JXTPJDDICSTXJX-UHFFFAOYSA-N 0.000 description 2
- 229940055577 oleyl alcohol Drugs 0.000 description 2
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 description 2
- 239000004006 olive oil Substances 0.000 description 2
- 235000008390 olive oil Nutrition 0.000 description 2
- 239000008165 rice bran oil Substances 0.000 description 2
- 229940032094 squalane Drugs 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- CUNWUEBNSZSNRX-RKGWDQTMSA-N (2r,3r,4r,5s)-hexane-1,2,3,4,5,6-hexol;(z)-octadec-9-enoic acid Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO.OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO.CCCCCCCC\C=C/CCCCCCCC(O)=O.CCCCCCCC\C=C/CCCCCCCC(O)=O.CCCCCCCC\C=C/CCCCCCCC(O)=O CUNWUEBNSZSNRX-RKGWDQTMSA-N 0.000 description 1
- FDCJDKXCCYFOCV-UHFFFAOYSA-N 1-hexadecoxyhexadecane Chemical compound CCCCCCCCCCCCCCCCOCCCCCCCCCCCCCCCC FDCJDKXCCYFOCV-UHFFFAOYSA-N 0.000 description 1
- 239000000263 2,3-dihydroxypropyl (Z)-octadec-9-enoate Substances 0.000 description 1
- RZRNAYUHWVFMIP-GDCKJWNLSA-N 3-oleoyl-sn-glycerol Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@H](O)CO RZRNAYUHWVFMIP-GDCKJWNLSA-N 0.000 description 1
- CYDQOEWLBCCFJZ-UHFFFAOYSA-N 4-(4-fluorophenyl)oxane-4-carboxylic acid Chemical compound C=1C=C(F)C=CC=1C1(C(=O)O)CCOCC1 CYDQOEWLBCCFJZ-UHFFFAOYSA-N 0.000 description 1
- DCXYFEDJOCDNAF-UHFFFAOYSA-N Asparagine Natural products OC(=O)C(N)CC(N)=O DCXYFEDJOCDNAF-UHFFFAOYSA-N 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- ZAKOWWREFLAJOT-CEFNRUSXSA-N D-alpha-tocopherylacetate Chemical compound CC(=O)OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C ZAKOWWREFLAJOT-CEFNRUSXSA-N 0.000 description 1
- DCXYFEDJOCDNAF-REOHCLBHSA-N L-asparagine Chemical compound OC(=O)[C@@H](N)CC(N)=O DCXYFEDJOCDNAF-REOHCLBHSA-N 0.000 description 1
- ILRKKHJEINIICQ-OOFFSTKBSA-N Monoammonium glycyrrhizinate Chemical compound N.O([C@@H]1[C@@H](O)[C@H](O)[C@H](O[C@@H]1O[C@H]1CC[C@]2(C)[C@H]3C(=O)C=C4[C@@H]5C[C@](C)(CC[C@@]5(CC[C@@]4(C)[C@]3(C)CC[C@H]2C1(C)C)C)C(O)=O)C(O)=O)[C@@H]1O[C@H](C(O)=O)[C@@H](O)[C@H](O)[C@H]1O ILRKKHJEINIICQ-OOFFSTKBSA-N 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 239000004147 Sorbitan trioleate Substances 0.000 description 1
- PRXRUNOAOLTIEF-ADSICKODSA-N Sorbitan trioleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@@H](OC(=O)CCCCCCC\C=C/CCCCCCCC)[C@H]1OC[C@H](O)[C@H]1OC(=O)CCCCCCC\C=C/CCCCCCCC PRXRUNOAOLTIEF-ADSICKODSA-N 0.000 description 1
- AZPFEYANVWPOHJ-CLFAGFIQSA-N [2-hydroxy-3-[2-hydroxy-3-[(Z)-octadec-9-enoyl]oxypropoxy]propyl] (Z)-octadec-9-enoate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC(O)COCC(O)COC(=O)CCCCCCC\C=C/CCCCCCCC AZPFEYANVWPOHJ-CLFAGFIQSA-N 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 235000009582 asparagine Nutrition 0.000 description 1
- 229960001230 asparagine Drugs 0.000 description 1
- 235000015278 beef Nutrition 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 238000004581 coalescence Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- ZAKOWWREFLAJOT-UHFFFAOYSA-N d-alpha-Tocopheryl acetate Natural products CC(=O)OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C ZAKOWWREFLAJOT-UHFFFAOYSA-N 0.000 description 1
- 229940105990 diglycerin Drugs 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000010696 ester oil Substances 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 235000019197 fats Nutrition 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 229940074045 glyceryl distearate Drugs 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 210000003127 knee Anatomy 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229940057995 liquid paraffin Drugs 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- LAQFLZHBVPULPL-UHFFFAOYSA-N methyl(phenyl)silicon Chemical compound C[Si]C1=CC=CC=C1 LAQFLZHBVPULPL-UHFFFAOYSA-N 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 239000001788 mono and diglycerides of fatty acids Substances 0.000 description 1
- RZRNAYUHWVFMIP-UHFFFAOYSA-N monoelaidin Natural products CCCCCCCCC=CCCCCCCCC(=O)OCC(O)CO RZRNAYUHWVFMIP-UHFFFAOYSA-N 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
- 239000001540 sodium lactate Substances 0.000 description 1
- 229940005581 sodium lactate Drugs 0.000 description 1
- 235000011088 sodium lactate Nutrition 0.000 description 1
- 229940045920 sodium pyrrolidone carboxylate Drugs 0.000 description 1
- HYRLWUFWDYFEES-UHFFFAOYSA-M sodium;2-oxopyrrolidine-1-carboxylate Chemical compound [Na+].[O-]C(=O)N1CCCC1=O HYRLWUFWDYFEES-UHFFFAOYSA-M 0.000 description 1
- 229960005078 sorbitan sesquioleate Drugs 0.000 description 1
- 235000019337 sorbitan trioleate Nutrition 0.000 description 1
- 229960000391 sorbitan trioleate Drugs 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 229940042585 tocopherol acetate Drugs 0.000 description 1
- 235000019871 vegetable fat Nutrition 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
Landscapes
- Cosmetics (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は、外観上半透明を呈する化粧料、更に詳しくは
、アルコール／（水＋アルコール）の−足枕の系におい
て、ＨＬＢ ７以下の親油性界面活性剤とＨＬＢ １０
以上のポリオキシエチレン（以下、ＰＯＥと略す）付加
型非イオン界面活性剤と油分を適正配合することにより
得られる化粧料で、半透明度の程度が調節可能でかつ広
い温度範囲にわたる長期保存においても半透明度が変化
することのない半透明化粧料に関する。[Detailed Description of the Invention] [Industrial Application Field] The present invention is directed to cosmetics having a translucent appearance, more specifically, to cosmetics having an HLB of 7 or less in an alcohol/(water+alcohol) foot pillow system. Lipophilic surfactant and HLB 10
This cosmetic is obtained by appropriately blending the polyoxyethylene (hereinafter abbreviated as POE) addition type nonionic surfactant and oil, and the degree of translucency can be adjusted and it can be stored for long periods over a wide temperature range. This invention relates to a translucent cosmetic whose translucency does not change.
従来、水、アルコール、保湿剤などからなる水・アルコ
ール系化粧料は化粧水、整髪剤、シェービングローショ
ンなどに多（利用されているが、その殆どは外観上透明
なものである。Conventionally, water/alcohol-based cosmetics consisting of water, alcohol, humectants, etc. have been widely used in lotions, hair conditioners, shaving lotions, etc., but most of them are transparent in appearance.
僅少例ではあるが非透明系のものがあり、これは静置時
に２相（油相と水相など）の状態にあるものを使用時に
置場して一時的に白濁させるものである。Although there are only a few examples, there are non-transparent types, which are in a two-phase state (such as an oil phase and an aqueous phase) when left standing, and which temporarily become cloudy when used.
透明な水・アルコール系化粧料は汎用の各種ポリオキシ
エチレン付加親水性界面活性剤を使用することによって
得ることができるが、これらの界面活性剤を使用して安
定な半透明の水・アルコール系化粧料を得ることは困難
である。というのは、使用する界面活性剤によっては高
温域で合点現象による白濁を生じたり、逆に高温域で透
明性が上昇して透明になってしまったり、また、低温域
で界は面活性剤の析出を生じたりするために、充分に安
定な半透明化粧料は得られなかったからである。Transparent water/alcohol-based cosmetics can be obtained by using various general-purpose polyoxyethylene-added hydrophilic surfactants. Cosmetics are difficult to obtain. This is because depending on the surfactant used, it may become cloudy due to the coalescence phenomenon at high temperatures, or conversely, the transparency may increase and become transparent at high temperatures, or the surface active agent may become transparent at low temperatures. This is because a sufficiently stable translucent cosmetic material could not be obtained because of the precipitation of .
本発明者は、このような状況にかんがみ、広い温度領域
で長期保存しても半透明度が一定しており、かつ、透明
性が調節可能な半透明化粧料を開発すべく鋭意検討を重
ねた結果、本発明を完成した。In view of this situation, the present inventor has conducted extensive research to develop a translucent cosmetic that maintains a constant translucency even after long-term storage over a wide temperature range, and whose transparency can be adjusted. As a result, the present invention was completed.
すなわち、本発明は、アルコール／（水＋アルコール）
の重量比が０．Ｏ１〜０．４である水・アルコール系に
おいてＨＬＢ ７以下の親油性活性剤とＨＬＢ１０以上
のＰＯＥ付加型非イオン界面活性剤及び油分を含有して
なる半透明化粧料である。That is, the present invention provides alcohol/(water+alcohol)
The weight ratio of 0. This is a translucent cosmetic containing a lipophilic active agent with an HLB of 7 or less, a POE-added nonionic surfactant with an HLB of 10 or more, and an oil in a water/alcohol system with an O of 1 to 0.4.
以下、本発明について詳述する。The present invention will be explained in detail below.
本発明において水・アルコール系を構成するアルコール
は、例えばエタノールであり、アルコール／（水＋アル
コール）Ｏｉｔ比は０．０１〜０．４である。数比がｏ
、ｏｉ未溝の場合は、界面活性剤の溶解が困難であり、
０．４を越える場合は高温域において良好な半透明度を
維持する事が難しく透明となってしまう場合がある。よ
って、この比の好ましい範囲は０．０３〜０．３である
。In the present invention, the alcohol constituting the water/alcohol system is, for example, ethanol, and the alcohol/(water+alcohol) Oit ratio is 0.01 to 0.4. The number ratio is o
, if the oi is not grooved, it is difficult to dissolve the surfactant,
If it exceeds 0.4, it may be difficult to maintain good translucency in a high temperature range and the film may become transparent. Therefore, the preferred range of this ratio is 0.03 to 0.3.
本発明で用いられるＨＬＢ ７以下の親油性界面活性剤
としては、ソルビタンモノオレート、ソルビタンセスキ
オレート、ソルビタントリオレエート、ソルビタンモノ
イソステアレート、ソルビタンセスキイソステアレート
等のソルビタン脂肪酸エステル、グリセリルジステアレ
ート、グリセリルモノオレート、ジグリセリンモノオレ
エート、ジグリセリンジオレエート、デカグリセリンペ
ンクオレエート、デカグリセリンペンタイソステアレー
ト、ジグリセリンジイソステアレート、デカグリセリン
デカイソステアレート、デカグリセリンペンタイソステ
アレート等のグリセリン及びポリグリセリン脂肪酸エス
テル、ＰＯＥ（２）モノオレエート等のポリエチレング
リコール脂肪酸エステル、ＰＯＥ（３〜１０モル）のヒ
マシ油誘導体等を挙げることが出来る。The lipophilic surfactants with an HLB of 7 or less used in the present invention include sorbitan fatty acid esters such as sorbitan monooleate, sorbitan sesquioleate, sorbitan trioleate, sorbitan monoisostearate, and sorbitan sesquiisostearate, and glyceryl distearate. , glyceryl monooleate, diglycerin monooleate, diglycerin dioleate, decaglycerin penqueoleate, decaglycerin pentysostearate, diglycerin diisostearate, decaglycerin decaisostearate, decaglycerin pentysostearate Examples include glycerin and polyglycerin fatty acid esters such as, polyethylene glycol fatty acid esters such as POE (2) monooleate, and castor oil derivatives of POE (3 to 10 mol).
親油性界面活性剤の配合量は、ＨＬＢ １０以上のＰＯ
Ｅ付加型非イオン界面活性剤との比において０．０２：
１から１：１好ましくはｏ、ｏｓ： １〜０．５ ：
１であり、当該比未溝の配合量においては、経時にて透
明化する傾向（特にアルコールの多い系）にあり、また
当該比を越えて配合した場合、経時にて半透明度が上昇
し濁りの原因となる。上記親油性界面活性剤は単独でも
また２種以上を併用して用いる事も可能である。The blending amount of lipophilic surfactant is PO with HLB 10 or more.
Ratio to E-addition type nonionic surfactant: 0.02:
1 to 1:1 preferably o, os: 1 to 0.5:
1, and at the blending ratio of the ratio, there is a tendency to become transparent over time (particularly in systems containing a lot of alcohol), and when blended in excess of the ratio, the translucency increases over time and the product becomes cloudy. It causes. The above lipophilic surfactants can be used alone or in combination of two or more.
本発明で用いるＰＯＥ付加型非イオン界面活性剤として
はＰＯＥ分岐アルキルエーテル型であるＰＯＥ２オクチ
ルドデシルアルコール（ＥＯ付加１０〜２５モル）やＰ
ＯＥ ２デシルテトラデシルアルコール（ＥＯ付加１０
〜３０モル） 、ＰＯＥアルキルエーテル型であるＰＯ
Ｅオレイルエーテル（Ｆ、Ｏ付加１０〜５０モル）やＰ
ＯＥ セチルｘ−チル（ＥＯ付加１０〜３０モル）、Ｐ
ＯＥソルビタンエステル型であるＰＯＥソルビタンモノ
オレート（ＥＯ付加２０〜３０モル） 、ＰＯＥソルビ
タンモノイソステアレート（ＥＯ付加１０〜３０モル）
およびＰＯＥジヒドロコレステロールエーテル（ＥＯ付
加１０〜３０モル）あるいはＰＯＥヒマシ油誘油体導体
Ｏ付加２０〜６０モル）等を挙げることができる。Examples of the POE-added nonionic surfactant used in the present invention include POE2-octyldodecyl alcohol (10 to 25 moles of EO added), which is a POE branched alkyl ether type, and POE
OE 2-decyltetradecyl alcohol (EO addition 10
~30 mol), POE alkyl ether type PO
E oleyl ether (F, O addition 10-50 mol) and P
OE cetyl x-tyl (EO addition 10-30 moles), P
OE sorbitan ester type POE sorbitan monooleate (20 to 30 moles of EO added), POE sorbitan monoisostearate (10 to 30 moles of EO added)
and POE dihydrocholesterol ether (10 to 30 moles of EO added) or POE castor oil-derived oil conductor (20 to 60 moles of O added).
ＰＯｔＥ付加型非イオン界面活性剤の配合量は、０゜１
〜５重量％であり、０．１重量％未満では良好な半透明
領域を得る事が難しく、また、５Ｍ量％を越えて配合し
た場合安全性上の問題が生じる。The amount of POtE-added nonionic surfactant is 0°1
-5% by weight, and if it is less than 0.1% by weight, it is difficult to obtain a good translucent area, and if it is blended in an amount exceeding 5M%, safety problems will occur.
上記ＰＯＥ付加型非イオン界面活性剤は単独で用いるこ
ともまた２種以上を併用して用いる事も可能である。The above POE-added nonionic surfactants can be used alone or in combination of two or more.
本発明で用いられる油分は、牛゛脂、スクヮラン、オリ
ーブ油、月見草油、コメヌカ油などの動植物油脂及び炭
化水素、流動パラフィンなどの鉱物油、イソプロピルミ
リステート、ペンタエリスリトールテトラ２エチルヘキ
サノエートなどのエステル油、メチルフェニルシリコン
、ジメチルシリコンなどのシリコン油、合成アルコール
である２オクチルドデカノル、２デシルテトラデカノー
ル、天然アルコールであるオレイルアルコール等の化粧
品、医薬品、食品等の業界で一般に利用されている油分
のなかで常温において液状を呈するものを挙げる事が出
来る。The oils used in the present invention include animal and vegetable fats and fats and hydrocarbons such as beef tallow, squalane, olive oil, evening primrose oil, and rice bran oil, mineral oils such as liquid paraffin, isopropyl myristate, pentaerythritol tetra-2-ethylhexanoate, etc. Ester oil, silicone oils such as methylphenyl silicone and dimethyl silicone, synthetic alcohols such as 2-octyldodecanol and 2-decyltetradecanol, and natural alcohols such as oleyl alcohol, which are commonly used in the cosmetics, pharmaceutical, and food industries. Among the oils present, there are those that are liquid at room temperature.
油分を被可溶化物と考えた場合、非極性の油分は極性油
分と比べて可溶化しにくい。本発明に用いる油分も好ま
しく極性油分でありＩＯＢ （Ｉｎｏｒｇａｎｉｃ
ａｎｄ ０ｒａｎｉｃ Ｂａ１ａｎｃｅｉ下記注−１）
を指標として考えた場合、０．１以上さらに好ましくは
０．２以上である。When considering oil as a substance to be solubilized, non-polar oil is more difficult to solubilize than polar oil. The oil used in the present invention is also preferably a polar oil and IOB (Inorganic
and Oranic BalanceiNote-1 below)
When considered as an index, it is 0.1 or more, more preferably 0.2 or more.
（注−１）
１０Ｂ 、 ｒ化学の領域」第１１巻、第１０号、第７
１９頁〜７２５頁、１９５７年に示されている膝用によ
る計算方法に従って算出した無機性及び有機性の値の比
。(Note-1) 10B, r Area of Chemistry, Volume 11, No. 10, No. 7
Ratios of inorganic and organic values calculated according to the calculation method by Knee, pp. 19-725, 1957.
油分の配合量は化粧水全量中のｏ、ｏｉ〜３重量％、好
ましくは０．０１〜２重量％である。３重量％を越えて
油分を配合した場合は、良好な半透明領域を得るために
、大量の界面活性剤を配合しなければならず、安全性、
使用性の観点から好ましくない。The blending amount of the oil component is from o, oi to 3% by weight, preferably from 0.01 to 2% by weight, based on the total amount of lotion. If more than 3% by weight of oil is added, a large amount of surfactant must be added to obtain a good translucent area, resulting in safety issues and
Unfavorable from the viewpoint of usability.
本発明で用いる油分は単独で用いるまた２種以上を併用
することもある。The oil components used in the present invention may be used alone or in combination of two or more.
本発明において半透明とは水の透明度を１００としたと
き透明度２０〜９５の領域のものを指す。一般的に透明
化粧料といわれるものは透明度９６以上、牛乳様に白濁
したエマルジョンは透明度１５以下である。In the present invention, "semi-transparent" refers to a material having a transparency range of 20 to 95 when the transparency of water is 100. Generally speaking, transparent cosmetics have a transparency of 96 or higher, and milk-like cloudy emulsions have a transparency of 15 or lower.
また、透明度の測定に関して本発明者らはスガ試験機株
式会社製のデジタル測色色差計算機を用い、コントロー
ルとして蒸留水の透明度を１００として測定している。Further, regarding the measurement of transparency, the present inventors used a digital colorimetric color difference calculator manufactured by Suga Test Instruments Co., Ltd., and measured the transparency of distilled water as a control at 100.
本発明の半透明化粧料には、目的に反さない限度で、必
要に応じ他の成分、例えば、香料、着色料、保湿剤、防
腐剤、水溶性高分子物質などを配合することができる。The translucent cosmetic of the present invention may contain other ingredients as necessary, such as fragrances, colorants, humectants, preservatives, water-soluble polymer substances, etc., as long as they do not contradict the purpose. .
〔実施例］ 以下、本発明を実施例によって説明する。〔Example] Hereinafter, the present invention will be explained by examples.
実施例１〜４
表１内に示したようにＰＯＥ （６０モル）硬化ヒマ
シ油誘導体とジグリセリンジイソステアレートの比が１
：０．１の実施例１では、透明度の経時変化は観察され
ず。試作直後透明度８５のものが１力月後、各条件にお
いても変化が少なく良好であった。Examples 1-4 As shown in Table 1, the ratio of POE (60 mol) hydrogenated castor oil derivative to diglycerine diisostearate was 1.
:0.1 in Example 1, no change in transparency over time was observed. Immediately after trial production, the transparency was 85, and after one month, there was little change under each condition and it was good.
それに対し、界面活性剤比が該比以下の比較例１では、
高温域において透明度の上昇が観察され、また、該比以
上の比較例２では室温及び低温域にて透明度の低下し濁
る傾向にある。また、比較例３に示す如くアルコール量
が多く領域では、高温にて一定の透明性を維持する事が
困難であり透明度の上昇が観察された。On the other hand, in Comparative Example 1 where the surfactant ratio was less than this ratio,
An increase in transparency was observed in the high temperature range, and in Comparative Example 2 where the ratio was higher than this, the transparency tended to decrease and become cloudy at room temperature and low temperature range. Furthermore, as shown in Comparative Example 3, in a region where the amount of alcohol is large, it is difficult to maintain a certain level of transparency at high temperatures, and an increase in transparency was observed.
実施例２．３．４については経時にて透明性の変化は少
なく安定性良好なものであった。Examples 2.3.4 exhibited good stability with little change in transparency over time.
実施例５
重量％
■イオン交換水 残部■エタノ
ール １０■１，３ブチレン
グリコール ５■プロピレングリコール
５■ＰＯＥ （３０モル）モノオレイ
ン酸ソルビタン ０．８■
ＰＯＥ （１５モル）ジヒドロコレステロールエーテ
ル ０．２■ソルビタンモ
ノオレエート０．３
■コメヌカ油 １．０■ピ
ロリドンカルボン酸ナトリウム ０．５［相］メチ
ルセルロース １．０■アスパラギ
ンｔｌＩｏ、ｏｓ
＠クエン酸ナトリウム ０．１００
防腐剤 ０．２■香 料
０．３（製法）
■のイオン交換水に■■■［相］■＠を添加し均一ン容
解した後、これに■のエタノールに■■■■＠■を添加
し均一溶解して得たアルコール相を添加、攪拌混合し、
半透明化粧料を得た。本島の透明度は５０で経時にて透
明性の変化は少なく良好なものであった。Example 5 Weight % ■Ion-exchanged water Balance ■Ethanol 10■1,3-butylene glycol 5■Propylene glycol
5 ■ POE (30 mol) Sorbitan monooleate 0.8 ■
POE (15 mol) Dihydrocholesterol ether 0.2 ■ Sorbitan monooleate 0.3 ■ Rice bran oil 1.0 ■ Sodium pyrrolidone carboxylate 0.5 [Phase] Methyl cellulose 1.0 ■ Asparagine tlIo, os @ sodium citrate 0 .100
Preservative 0.2 ■Fragrance 0.3 (manufacturing method) ■■■[Phase]■@ is added to the ion-exchanged water of ■, homogeneously dissolved, and then added to the ethanol of ■■■■■@■ Add the alcohol phase obtained by adding and uniformly dissolving, stir and mix,
A translucent cosmetic was obtained. The transparency of the main island was 50, which was good with little change in transparency over time.
実施例６
重量％
■イオン交換水 残部■エタノ
ール １０■ＰＯＥ （２
０モル）２−オクチルドデシルアルコール
０．５０ジグリセリンジイソステア、レ
ート ０．１■ソルビタンセスキイソステアレート
０．１■ペンタエリスリトールテトラ−２−
エチルヘキサノエート ０．３０アラン
トイン ０．２■アルチトー
ル ５■アスパラギン酸
０．０４［相］し一アルギニン
ｏ、ｉｏ防腐剤
０．１０香 料
０．２（製法）
■のイオン交換水に■■■［相］を添加し均一溶解して
得た水相に、■のエタノールに■■■■０＠を添加し均
一熔解して得たアルコール相を添加攪拌混合し、半透明
化粧水を得た。本島の透明性は８８で、経時にて変化は
少なく安定性良好であった。Example 6 Weight % ■Ion exchange water Balance ■Ethanol 10■POE (2
0 mol) 2-octyldodecyl alcohol
0.50 Diglycerin diisostearate, rate 0.1 ■ Sorbitan sesquiisostearate 0.1 ■ Pentaerythritol tetra-2-ethylhexanoate 0.30 Allantoin 0.2 ■ Altitol 5 ■ Aspartic acid
0.04 [phase] mono-arginine
o, io preservative
0.10 fragrance
0.2 (Production method) ■■■■[Phase] was added to the ion-exchanged water of ■ and uniformly dissolved. To the aqueous phase obtained, ■■■■0@ was added to the ethanol of ■ and uniformly dissolved. The alcohol phase was added and mixed with stirring to obtain a translucent lotion. The transparency of the main island was 88, with little change over time and good stability.
実施例７
重量％
■イオン交換水 残部■エタノ
ール ■５■ジプロピレング
リコール ５■ＰＯＥ （２０モル）オ
レイルエーテル ０．３■デカグリセリンペンタイ
ソステアレート０．１■ビタミンＥアセテート
０．２０イソプロピルミリステート
０．１■香 料 ０．
１■クエン酸 ０．０
２［相］クエン酸ナトリウム ０．
０６■防腐剤 ｏ、ｉ（
製法）
■のイオン交換水に■■［相］を添加、攪拌し均一とし
た後これに、■のエタノールに■■■■■■及び■を均
一溶解して得たアルコール相を添加、攪拌混合して半透
明化粧水を得た。本島の透明度は９２であり、経時にて
変化は少なく良好なものであった。Example 7 Weight % ■Ion-exchanged water Balance ■Ethanol ■5■Dipropylene glycol 5■POE (20 mol) Oleyl ether 0.3■Decaglycerin pentysostearate 0.1■Vitamin E acetate
0.20 isopropyl myristate
0.1■Fragrance 0.
1 ■ Citric acid 0.0
2 [Phase] Sodium citrate 0.
06■Preservatives o, i(
Manufacturing method) Add ■■ [phase] to the ion-exchanged water from ■ and stir to make it homogeneous. To this, add the alcohol phase obtained by homogeneously dissolving ■■■■■■ and ■ in the ethanol from ■ and stir. A translucent lotion was obtained by mixing. The transparency of the main island was 92, which was good with little change over time.
実施例８
重量％
■イオン交換水 残部■エタノ
ール ３０■グリセリン
５■ジプロピレングリコール
１０■ＰＯＥ （２５モル）セチルエー
テル ３■ソルビタンモノイソステアレート０，
５■オレイルアルコール ３■乳
酸 ０．０２■乳酸ナト
リウム ０．１０［相］グリチ
ルリチン酸モノアンモニウム ０．１０防腐剤
０．１０色 素
通量（製法）
■のエタノールに■■■及び■を添加し均一溶解した後
、これを■に■■■■［相］及び＠を添加し均一溶解し
た水相に添加、攪拌混合して半透明化粧水を得た。本品
の透明度は５ｏ経時にて透明度の変化は少なく良好であ
った。Example 8 Weight % ■Ion exchange water Balance ■Ethanol 30■Glycerin
5 ■ Dipropylene glycol
10 ■ POE (25 mol) Cetyl ether 3 ■ Sorbitan monoisostearate 0,
5 ■ Oleyl alcohol 3 ■ Milk
Acid 0.02 Sodium lactate 0.10 [Phase] Monoammonium glycyrrhizinate 0.10 Preservative
0.10 dye
Total amount (manufacturing method) Add ■■■ and ■ to the ethanol of ■ and uniformly dissolve it, then add this to the aqueous phase in which ■■■■ [phase] and @ were added to ■ and uniformly dissolve, and mix by stirring. I got a translucent lotion. The transparency of this product was good with little change in transparency over time of 5o.
実施例９
重量％
■イオン交換水 残部■エタノ
ール ５■ソルビトール
５■１，３−ブチレングリコー
ル １０■ＰＯＥ （５０モル）硬化ヒマ
シ油誘導体 ０．５■ジグリセリンジイソステアレー
ト ０．１０オリーブ油
０．１■スクワラン ０
．１■アスパラギン酸 ０．０
５＠ｌＬ−アルギニン ０．３
０カルボキシビニルポリマー ０．２０アラ
ントイン ０．２０防腐剤
０．１［相］香 料
０．１（製法）
■のイオン交換水に■■■■＠を添加し均一に溶解し水
相を調整した後これに■のエタノールに■■■■Ｏｏを
添加し均一熔解して得たアルコール相を添加、攪拌、混
合し、最後に［相］を添加増粘し、粘稠半透明化粧料を
得た。本品の透明度は８０で経時にて透明度の変化は少
なく良好なものであった。Example 9 Weight% ■Ion-exchanged water Balance ■Ethanol 5■Sorbitol
5 ■ 1,3-butylene glycol 10 ■ POE (50 mol) hydrogenated castor oil derivative 0.5 ■ diglycerine diisostearate 0.10 olive oil
0.1 ■ Squalane 0
．． 1 ■ Aspartic acid 0.0
5@lL-Arginine 0.3
0 Carboxyvinyl polymer 0.20 Allantoin 0.20 Preservative
0.1 [phase] fragrance
0.1 (Production method) After adding ■■■■@ to the ion-exchanged water of (■) and uniformly dissolving it to adjust the aqueous phase, to this, ■■■■Oo was added to the ethanol of (■) and uniformly melted. The alcohol phase was added, stirred and mixed, and finally the [phase] was added and thickened to obtain a viscous translucent cosmetic. The transparency of this product was 80, which was good with little change in transparency over time.
実施例１０
重量％
■イオン交換水 残部■グリセ
リン ７■エタノール
５■ＰＯＥ硬化ヒマシ油誘導体
く６０モル）０．５■ＰＯＥジヒドロコレステロールエ
ーテル ０．２■ジグリセリンジイソステアレート
０．１５０月見草油 ０
．１■防腐剤 ０．２■
香 料 ０．０５（製法）
■のエタノールに■〜■を均一溶解した後、■、■を均
一に混合した水相に添加、攪拌して半透明化粧水を得た
。本品の透明度は８０であり、経時にて透明度の変化は
少なく良好なものであった。Example 10 Weight % ■Ion exchange water Balance ■Glycerin 7■Ethanol
5■POE hydrogenated castor oil derivative (60 moles) 0.5■POE dihydrocholesterol ether 0.2■Diglycerine diisostearate
0.150 Evening Primrose Oil 0
．． 1■ Preservative 0.2■
Fragrance 0.05 (Manufacturing method) After uniformly dissolving ■ to ■ in the ethanol of step (1), it was added to the aqueous phase in which ■ and ■ were uniformly mixed, and the mixture was stirred to obtain a translucent lotion. The transparency of this product was 80, which was good with little change in transparency over time.
Claims (1)
０．４である水・アルコール系において、ＨＬＢ７以下
の親油性界面活性剤とＨＬＢ１０以上のポリオキシエチ
レン付加型非イオン界面活性剤及び油分を含有すること
を特徴とする半透明化粧料。The weight ratio of alcohol/(water + alcohol) is 0.01~
A translucent cosmetic comprising a lipophilic surfactant with an HLB of 7 or less, a polyoxyethylene-adducted nonionic surfactant with an HLB of 10 or more, and an oil component in a water/alcohol system with an HLB of 0.4.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61279495A JPH0699271B2 (en) | 1986-11-22 | 1986-11-22 | Translucent cosmetics |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61279495A JPH0699271B2 (en) | 1986-11-22 | 1986-11-22 | Translucent cosmetics |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS63132813A true JPS63132813A (en) | 1988-06-04 |
| JPH0699271B2 JPH0699271B2 (en) | 1994-12-07 |
Family
ID=17611843
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP61279495A Expired - Lifetime JPH0699271B2 (en) | 1986-11-22 | 1986-11-22 | Translucent cosmetics |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0699271B2 (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004315410A (en) * | 2003-04-15 | 2004-11-11 | Asutaa Biyo:Kk | Method for simultaneously performing curly hair correction and hair dyeing |
| JP2006117643A (en) * | 2004-09-22 | 2006-05-11 | Kao Corp | Microemulsion |
| JP2006298788A (en) * | 2005-04-18 | 2006-11-02 | Shiseido Co Ltd | Method for producing translucent cosmetics |
| JP2007254405A (en) * | 2006-03-24 | 2007-10-04 | Shiseido Co Ltd | Method of producing oil-in-water emulsion whitely turbid cosmetic |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS56145211A (en) * | 1980-04-14 | 1981-11-11 | Pola Chem Ind Inc | Aqueous cosmetic |
| JPS5770808A (en) * | 1980-10-20 | 1982-05-01 | Nonogawa Shoji:Kk | Production of emulsion for cosmetic |
| JPS6112603A (en) * | 1984-06-28 | 1986-01-21 | Shiseido Co Ltd | Semi-transparent cosmetic |
| JPS6191112A (en) * | 1984-10-08 | 1986-05-09 | Kobayashi Kooc:Kk | Whitening cosmetic |
| JPS61167609A (en) * | 1985-01-18 | 1986-07-29 | Shiseido Co Ltd | Face lotion |
-
1986
- 1986-11-22 JP JP61279495A patent/JPH0699271B2/en not_active Expired - Lifetime
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS56145211A (en) * | 1980-04-14 | 1981-11-11 | Pola Chem Ind Inc | Aqueous cosmetic |
| JPS5770808A (en) * | 1980-10-20 | 1982-05-01 | Nonogawa Shoji:Kk | Production of emulsion for cosmetic |
| JPS6112603A (en) * | 1984-06-28 | 1986-01-21 | Shiseido Co Ltd | Semi-transparent cosmetic |
| JPS6191112A (en) * | 1984-10-08 | 1986-05-09 | Kobayashi Kooc:Kk | Whitening cosmetic |
| JPS61167609A (en) * | 1985-01-18 | 1986-07-29 | Shiseido Co Ltd | Face lotion |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004315410A (en) * | 2003-04-15 | 2004-11-11 | Asutaa Biyo:Kk | Method for simultaneously performing curly hair correction and hair dyeing |
| JP2006117643A (en) * | 2004-09-22 | 2006-05-11 | Kao Corp | Microemulsion |
| JP2006298788A (en) * | 2005-04-18 | 2006-11-02 | Shiseido Co Ltd | Method for producing translucent cosmetics |
| JP2007254405A (en) * | 2006-03-24 | 2007-10-04 | Shiseido Co Ltd | Method of producing oil-in-water emulsion whitely turbid cosmetic |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0699271B2 (en) | 1994-12-07 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US4767625A (en) | Lamella type single phase liquid crystal composition and oil-base cosmetic compositions using the same | |
| US4275055A (en) | Hair conditioner having a stabilized, pearlescent effect | |
| JPS63225312A (en) | Transparent or semitransparent jelly-like cosmetic | |
| JPH10513179A (en) | Roll-on antiperspirant composition | |
| JPH0525843B2 (en) | ||
| CZ174994A3 (en) | Oil-based transparent gels and process for preparing thereof | |
| EP0227012A1 (en) | Gel-like emulsion and O/W emulsions obtained from the gel-like emulsion | |
| KR100732728B1 (en) | Emulsion cosmetic composite of low viscocity | |
| US5362418A (en) | Gel-like emulsion and O/W emulsion obtained from the gel-like emulsion | |
| JPH04149112A (en) | Transparent cosmetic for skin | |
| JPS63126543A (en) | Microemulsion | |
| WO2024083001A1 (en) | Steady-state double-layer toner and preparation method therefor | |
| JPS63132813A (en) | Semi-transparent cosmetic | |
| JP4073539B2 (en) | Cosmetics | |
| JPH0816047B2 (en) | Translucent liquid cosmetics | |
| KR20070089302A (en) | Transparent oil in water type emulsified cosmetic compositions | |
| JPH0267247A (en) | Solubilization of fatty ester sparingly soluble in water | |
| JP2724852B2 (en) | Microemulsion | |
| JPS6260364B2 (en) | ||
| JPS6112603A (en) | Semi-transparent cosmetic | |
| JP3656209B2 (en) | Cloudy liquid cosmetic | |
| JP3000396B2 (en) | Translucent cosmetics | |
| JP6685692B2 (en) | Topical skin | |
| JP3725328B2 (en) | Cloudy cosmetic | |
| JPH03115208A (en) | Oily cosmetic |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EXPY | Cancellation because of completion of term |