JPS6312767A - Carpet backing composition - Google Patents
Carpet backing compositionInfo
- Publication number
- JPS6312767A JPS6312767A JP62056370A JP5637087A JPS6312767A JP S6312767 A JPS6312767 A JP S6312767A JP 62056370 A JP62056370 A JP 62056370A JP 5637087 A JP5637087 A JP 5637087A JP S6312767 A JPS6312767 A JP S6312767A
- Authority
- JP
- Japan
- Prior art keywords
- weight
- parts
- polyisocyanate
- composition
- blocked polyisocyanate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims description 48
- 239000005056 polyisocyanate Substances 0.000 claims description 64
- 229920001228 polyisocyanate Polymers 0.000 claims description 64
- 239000006185 dispersion Substances 0.000 claims description 27
- 229920000877 Melamine resin Polymers 0.000 claims description 22
- 239000004640 Melamine resin Substances 0.000 claims description 21
- 239000003795 chemical substances by application Substances 0.000 claims description 21
- 229920006158 high molecular weight polymer Polymers 0.000 claims description 20
- 239000007787 solid Substances 0.000 claims description 10
- 239000002981 blocking agent Substances 0.000 description 28
- 229920000126 latex Polymers 0.000 description 20
- 239000004816 latex Substances 0.000 description 18
- 238000005406 washing Methods 0.000 description 17
- 229920005989 resin Polymers 0.000 description 16
- 239000011347 resin Substances 0.000 description 16
- 150000001875 compounds Chemical class 0.000 description 15
- -1 2-hydroxypropyl Chemical group 0.000 description 14
- 238000002156 mixing Methods 0.000 description 12
- 229920000642 polymer Polymers 0.000 description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- 239000004593 Epoxy Substances 0.000 description 8
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 8
- 238000000034 method Methods 0.000 description 8
- 239000002904 solvent Substances 0.000 description 8
- 229910052739 hydrogen Inorganic materials 0.000 description 7
- 239000001257 hydrogen Substances 0.000 description 7
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 6
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 6
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 5
- 239000003054 catalyst Substances 0.000 description 5
- 125000005442 diisocyanate group Chemical group 0.000 description 5
- 125000000524 functional group Chemical group 0.000 description 5
- 239000012948 isocyanate Substances 0.000 description 5
- 239000011593 sulfur Substances 0.000 description 5
- 229910052717 sulfur Inorganic materials 0.000 description 5
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- 229920000459 Nitrile rubber Polymers 0.000 description 4
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 4
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 4
- MBHRHUJRKGNOKX-UHFFFAOYSA-N [(4,6-diamino-1,3,5-triazin-2-yl)amino]methanol Chemical compound NC1=NC(N)=NC(NCO)=N1 MBHRHUJRKGNOKX-UHFFFAOYSA-N 0.000 description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 4
- 230000000903 blocking effect Effects 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 239000002270 dispersing agent Substances 0.000 description 4
- 239000000178 monomer Substances 0.000 description 4
- 229920005862 polyol Polymers 0.000 description 4
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 description 4
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 4
- 238000004073 vulcanization Methods 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 3
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000004202 carbamide Substances 0.000 description 3
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 3
- 239000000084 colloidal system Substances 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 239000000945 filler Substances 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 3
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 3
- 150000002513 isocyanates Chemical class 0.000 description 3
- 150000003077 polyols Chemical class 0.000 description 3
- 230000001681 protective effect Effects 0.000 description 3
- 229920003048 styrene butadiene rubber Polymers 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- 239000002562 thickening agent Substances 0.000 description 3
- RMVRSNDYEFQCLF-UHFFFAOYSA-N thiophenol Chemical compound SC1=CC=CC=C1 RMVRSNDYEFQCLF-UHFFFAOYSA-N 0.000 description 3
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 2
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
- UJOBWOGCFQCDNV-UHFFFAOYSA-N 9H-carbazole Chemical compound C1=CC=C2C3=CC=CC=C3NC2=C1 UJOBWOGCFQCDNV-UHFFFAOYSA-N 0.000 description 2
- DLFVBJFMPXGRIB-UHFFFAOYSA-N Acetamide Chemical compound CC(N)=O DLFVBJFMPXGRIB-UHFFFAOYSA-N 0.000 description 2
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 2
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 2
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 2
- ZRALSGWEFCBTJO-UHFFFAOYSA-N Guanidine Chemical compound NC(N)=N ZRALSGWEFCBTJO-UHFFFAOYSA-N 0.000 description 2
- 244000043261 Hevea brasiliensis Species 0.000 description 2
- FZERHIULMFGESH-UHFFFAOYSA-N N-phenylacetamide Chemical compound CC(=O)NC1=CC=CC=C1 FZERHIULMFGESH-UHFFFAOYSA-N 0.000 description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 description 2
- YRKCREAYFQTBPV-UHFFFAOYSA-N acetylacetone Chemical compound CC(=O)CC(C)=O YRKCREAYFQTBPV-UHFFFAOYSA-N 0.000 description 2
- 238000007259 addition reaction Methods 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical class C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 2
- WQAQPCDUOCURKW-UHFFFAOYSA-N butanethiol Chemical compound CCCCS WQAQPCDUOCURKW-UHFFFAOYSA-N 0.000 description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 description 2
- 239000007809 chemical reaction catalyst Substances 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 238000007334 copolymerization reaction Methods 0.000 description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
- VEZUQRBDRNJBJY-UHFFFAOYSA-N cyclohexanone oxime Chemical compound ON=C1CCCCC1 VEZUQRBDRNJBJY-UHFFFAOYSA-N 0.000 description 2
- SWXVUIWOUIDPGS-UHFFFAOYSA-N diacetone alcohol Chemical compound CC(=O)CC(C)(C)O SWXVUIWOUIDPGS-UHFFFAOYSA-N 0.000 description 2
- 150000001991 dicarboxylic acids Chemical class 0.000 description 2
- DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical compound C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 description 2
- 239000004815 dispersion polymer Substances 0.000 description 2
- 238000010494 dissociation reaction Methods 0.000 description 2
- 230000005593 dissociations Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000001804 emulsifying effect Effects 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 239000001530 fumaric acid Substances 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- TZMQHOJDDMFGQX-UHFFFAOYSA-N hexane-1,1,1-triol Chemical compound CCCCCC(O)(O)O TZMQHOJDDMFGQX-UHFFFAOYSA-N 0.000 description 2
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 150000002605 large molecules Chemical class 0.000 description 2
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 2
- 239000011976 maleic acid Substances 0.000 description 2
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 2
- 150000002763 monocarboxylic acids Chemical class 0.000 description 2
- 229920003052 natural elastomer Polymers 0.000 description 2
- 229920001194 natural rubber Polymers 0.000 description 2
- 150000002902 organometallic compounds Chemical class 0.000 description 2
- 150000002923 oximes Chemical class 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 2
- 150000003384 small molecules Chemical class 0.000 description 2
- 239000000600 sorbitol Substances 0.000 description 2
- KZNICNPSHKQLFF-UHFFFAOYSA-N succinimide Chemical compound O=C1CCC(=O)N1 KZNICNPSHKQLFF-UHFFFAOYSA-N 0.000 description 2
- KUAZQDVKQLNFPE-UHFFFAOYSA-N thiram Chemical compound CN(C)C(=S)SSC(=S)N(C)C KUAZQDVKQLNFPE-UHFFFAOYSA-N 0.000 description 2
- 229960002447 thiram Drugs 0.000 description 2
- 239000013638 trimer Substances 0.000 description 2
- 239000011787 zinc oxide Substances 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- FZENGILVLUJGJX-NSCUHMNNSA-N (E)-acetaldehyde oxime Chemical compound C\C=N\O FZENGILVLUJGJX-NSCUHMNNSA-N 0.000 description 1
- ZTNJGMFHJYGMDR-UHFFFAOYSA-N 1,2-diisocyanatoethane Chemical compound O=C=NCCN=C=O ZTNJGMFHJYGMDR-UHFFFAOYSA-N 0.000 description 1
- PQDIQKXGPYOGDI-UHFFFAOYSA-N 1,3,5-triisocyanatobenzene Chemical compound O=C=NC1=CC(N=C=O)=CC(N=C=O)=C1 PQDIQKXGPYOGDI-UHFFFAOYSA-N 0.000 description 1
- AGJCSCSSMFRMFQ-UHFFFAOYSA-N 1,4-bis(2-isocyanatopropan-2-yl)benzene Chemical compound O=C=NC(C)(C)C1=CC=C(C(C)(C)N=C=O)C=C1 AGJCSCSSMFRMFQ-UHFFFAOYSA-N 0.000 description 1
- OHLKMGYGBHFODF-UHFFFAOYSA-N 1,4-bis(isocyanatomethyl)benzene Chemical compound O=C=NCC1=CC=C(CN=C=O)C=C1 OHLKMGYGBHFODF-UHFFFAOYSA-N 0.000 description 1
- ROHUXHMNZLHBSF-UHFFFAOYSA-N 1,4-bis(isocyanatomethyl)cyclohexane Chemical compound O=C=NCC1CCC(CN=C=O)CC1 ROHUXHMNZLHBSF-UHFFFAOYSA-N 0.000 description 1
- OVBFMUAFNIIQAL-UHFFFAOYSA-N 1,4-diisocyanatobutane Chemical compound O=C=NCCCCN=C=O OVBFMUAFNIIQAL-UHFFFAOYSA-N 0.000 description 1
- CDMDQYCEEKCBGR-UHFFFAOYSA-N 1,4-diisocyanatocyclohexane Chemical compound O=C=NC1CCC(N=C=O)CC1 CDMDQYCEEKCBGR-UHFFFAOYSA-N 0.000 description 1
- ATOUXIOKEJWULN-UHFFFAOYSA-N 1,6-diisocyanato-2,2,4-trimethylhexane Chemical compound O=C=NCCC(C)CC(C)(C)CN=C=O ATOUXIOKEJWULN-UHFFFAOYSA-N 0.000 description 1
- TZBAIMGBDFXZMO-UHFFFAOYSA-N 1-isocyanatomethyl-1,3,3-trimethylcyclohexane Chemical compound CC1(C)CCCC(C)(CN=C=O)C1 TZBAIMGBDFXZMO-UHFFFAOYSA-N 0.000 description 1
- LTMRRSWNXVJMBA-UHFFFAOYSA-L 2,2-diethylpropanedioate Chemical compound CCC(CC)(C([O-])=O)C([O-])=O LTMRRSWNXVJMBA-UHFFFAOYSA-L 0.000 description 1
- YAJYJWXEWKRTPO-UHFFFAOYSA-N 2,3,3,4,4,5-hexamethylhexane-2-thiol Chemical compound CC(C)C(C)(C)C(C)(C)C(C)(C)S YAJYJWXEWKRTPO-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- IZXIZTKNFFYFOF-UHFFFAOYSA-N 2-Oxazolidone Chemical compound O=C1NCCO1 IZXIZTKNFFYFOF-UHFFFAOYSA-N 0.000 description 1
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 1
- SVONRAPFKPVNKG-UHFFFAOYSA-N 2-ethoxyethyl acetate Chemical compound CCOCCOC(C)=O SVONRAPFKPVNKG-UHFFFAOYSA-N 0.000 description 1
- PQAMFDRRWURCFQ-UHFFFAOYSA-N 2-ethyl-1h-imidazole Chemical compound CCC1=NC=CN1 PQAMFDRRWURCFQ-UHFFFAOYSA-N 0.000 description 1
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 description 1
- QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- IGFHQQFPSIBGKE-UHFFFAOYSA-N 4-nonylphenol Chemical compound CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 229930185605 Bisphenol Natural products 0.000 description 1
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- PDQAZBWRQCGBEV-UHFFFAOYSA-N Ethylenethiourea Chemical compound S=C1NCCN1 PDQAZBWRQCGBEV-UHFFFAOYSA-N 0.000 description 1
- 239000005057 Hexamethylene diisocyanate Substances 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 1
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- WRQNANDWMGAFTP-UHFFFAOYSA-N Methylacetoacetic acid Chemical compound COC(=O)CC(C)=O WRQNANDWMGAFTP-UHFFFAOYSA-N 0.000 description 1
- CHJJGSNFBQVOTG-UHFFFAOYSA-N N-methyl-guanidine Natural products CNC(N)=N CHJJGSNFBQVOTG-UHFFFAOYSA-N 0.000 description 1
- 206010028980 Neoplasm Diseases 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000005062 Polybutadiene Substances 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 229920000265 Polyparaphenylene Polymers 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- FZWLAAWBMGSTSO-UHFFFAOYSA-N Thiazole Chemical compound C1=CSC=N1 FZWLAAWBMGSTSO-UHFFFAOYSA-N 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 229920002978 Vinylon Polymers 0.000 description 1
- FMRLDPWIRHBCCC-UHFFFAOYSA-L Zinc carbonate Chemical compound [Zn+2].[O-]C([O-])=O FMRLDPWIRHBCCC-UHFFFAOYSA-L 0.000 description 1
- XMUZQOKACOLCSS-UHFFFAOYSA-N [2-(hydroxymethyl)phenyl]methanol Chemical compound OCC1=CC=CC=C1CO XMUZQOKACOLCSS-UHFFFAOYSA-N 0.000 description 1
- 229960001413 acetanilide Drugs 0.000 description 1
- PXAJQJMDEXJWFB-UHFFFAOYSA-N acetone oxime Chemical compound CC(C)=NO PXAJQJMDEXJWFB-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 125000002723 alicyclic group Chemical group 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- 125000003368 amide group Chemical group 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000003849 aromatic solvent Substances 0.000 description 1
- 125000004069 aziridinyl group Chemical group 0.000 description 1
- 238000010009 beating Methods 0.000 description 1
- DQXBYHZEEUGOBF-UHFFFAOYSA-N but-3-enoic acid;ethene Chemical compound C=C.OC(=O)CC=C DQXBYHZEEUGOBF-UHFFFAOYSA-N 0.000 description 1
- KLIYQWXIWMRMGR-UHFFFAOYSA-N buta-1,3-diene;methyl 2-methylprop-2-enoate Chemical compound C=CC=C.COC(=O)C(C)=C KLIYQWXIWMRMGR-UHFFFAOYSA-N 0.000 description 1
- 201000011510 cancer Diseases 0.000 description 1
- DKVNPHBNOWQYFE-UHFFFAOYSA-N carbamodithioic acid Chemical compound NC(S)=S DKVNPHBNOWQYFE-UHFFFAOYSA-N 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229930003836 cresol Natural products 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 description 1
- 239000011353 cycloaliphatic epoxy resin Substances 0.000 description 1
- PDXRQENMIVHKPI-UHFFFAOYSA-N cyclohexane-1,1-diol Chemical compound OC1(O)CCCCC1 PDXRQENMIVHKPI-UHFFFAOYSA-N 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- FSEUPUDHEBLWJY-HWKANZROSA-N diacetylmonoxime Chemical compound CC(=O)C(\C)=N\O FSEUPUDHEBLWJY-HWKANZROSA-N 0.000 description 1
- KORSJDCBLAPZEQ-UHFFFAOYSA-N dicyclohexylmethane-4,4'-diisocyanate Chemical compound C1CC(N=C=O)CCC1CC1CCC(N=C=O)CC1 KORSJDCBLAPZEQ-UHFFFAOYSA-N 0.000 description 1
- SWSQBOPZIKWTGO-UHFFFAOYSA-N dimethylaminoamidine Natural products CN(C)C(N)=N SWSQBOPZIKWTGO-UHFFFAOYSA-N 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 239000012990 dithiocarbamate Substances 0.000 description 1
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 125000003700 epoxy group Chemical group 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- RAHHITDKGXOSCO-UHFFFAOYSA-N ethene;hydrochloride Chemical compound Cl.C=C RAHHITDKGXOSCO-UHFFFAOYSA-N 0.000 description 1
- ZOOODBUHSVUZEM-UHFFFAOYSA-N ethoxymethanedithioic acid Chemical compound CCOC(S)=S ZOOODBUHSVUZEM-UHFFFAOYSA-N 0.000 description 1
- 239000005038 ethylene vinyl acetate Substances 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 description 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 1
- ACCCMOQWYVYDOT-UHFFFAOYSA-N hexane-1,1-diol Chemical compound CCCCCC(O)O ACCCMOQWYVYDOT-UHFFFAOYSA-N 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-M hexanoate Chemical compound CCCCCC([O-])=O FUZZWVXGSFPDMH-UHFFFAOYSA-M 0.000 description 1
- 150000005165 hydroxybenzoic acids Chemical class 0.000 description 1
- 150000003949 imides Chemical class 0.000 description 1
- YDNLNVZZTACNJX-UHFFFAOYSA-N isocyanatomethylbenzene Chemical compound O=C=NCC1=CC=CC=C1 YDNLNVZZTACNJX-UHFFFAOYSA-N 0.000 description 1
- DUDXQIXWPJMPRQ-UHFFFAOYSA-N isocyanatomethylcyclohexane Chemical compound O=C=NCC1CCCCC1 DUDXQIXWPJMPRQ-UHFFFAOYSA-N 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 150000003951 lactams Chemical class 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 150000003903 lactic acid esters Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- AYLRODJJLADBOB-UHFFFAOYSA-N methyl 2,6-diisocyanatohexanoate Chemical compound COC(=O)C(N=C=O)CCCCN=C=O AYLRODJJLADBOB-UHFFFAOYSA-N 0.000 description 1
- OJURWUUOVGOHJZ-UHFFFAOYSA-N methyl 2-[(2-acetyloxyphenyl)methyl-[2-[(2-acetyloxyphenyl)methyl-(2-methoxy-2-oxoethyl)amino]ethyl]amino]acetate Chemical compound C=1C=CC=C(OC(C)=O)C=1CN(CC(=O)OC)CCN(CC(=O)OC)CC1=CC=CC=C1OC(C)=O OJURWUUOVGOHJZ-UHFFFAOYSA-N 0.000 description 1
- 125000000325 methylidene group Chemical group [H]C([H])=* 0.000 description 1
- XONPDZSGENTBNJ-UHFFFAOYSA-N molecular hydrogen;sodium Chemical compound [Na].[H][H] XONPDZSGENTBNJ-UHFFFAOYSA-N 0.000 description 1
- DNYZBFWKVMKMRM-UHFFFAOYSA-N n-benzhydrylidenehydroxylamine Chemical compound C=1C=CC=CC=1C(=NO)C1=CC=CC=C1 DNYZBFWKVMKMRM-UHFFFAOYSA-N 0.000 description 1
- WHIVNJATOVLWBW-UHFFFAOYSA-N n-butan-2-ylidenehydroxylamine Chemical compound CCC(C)=NO WHIVNJATOVLWBW-UHFFFAOYSA-N 0.000 description 1
- SQDFHQJTAWCFIB-UHFFFAOYSA-N n-methylidenehydroxylamine Chemical compound ON=C SQDFHQJTAWCFIB-UHFFFAOYSA-N 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- KZCOBXFFBQJQHH-UHFFFAOYSA-N octane-1-thiol Chemical compound CCCCCCCCS KZCOBXFFBQJQHH-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- XVNKRRXASPPECQ-UHFFFAOYSA-N phenyl n-phenylcarbamate Chemical compound C=1C=CC=CC=1OC(=O)NC1=CC=CC=C1 XVNKRRXASPPECQ-UHFFFAOYSA-N 0.000 description 1
- WVDDGKGOMKODPV-ZQBYOMGUSA-N phenyl(114C)methanol Chemical compound O[14CH2]C1=CC=CC=C1 WVDDGKGOMKODPV-ZQBYOMGUSA-N 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- XKJCHHZQLQNZHY-UHFFFAOYSA-N phthalimide Chemical compound C1=CC=C2C(=O)NC(=O)C2=C1 XKJCHHZQLQNZHY-UHFFFAOYSA-N 0.000 description 1
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920005906 polyester polyol Polymers 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920001021 polysulfide Polymers 0.000 description 1
- 239000005077 polysulfide Substances 0.000 description 1
- 150000008117 polysulfides Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- DJEHXEMURTVAOE-UHFFFAOYSA-M potassium bisulfite Chemical compound [K+].OS([O-])=O DJEHXEMURTVAOE-UHFFFAOYSA-M 0.000 description 1
- 235000010259 potassium hydrogen sulphite Nutrition 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 229960002317 succinimide Drugs 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 125000000542 sulfonic acid group Chemical group 0.000 description 1
- 229940052367 sulfur,colloidal Drugs 0.000 description 1
- 229920006174 synthetic rubber latex Polymers 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- QXJQHYBHAIHNGG-UHFFFAOYSA-N trimethylolethane Chemical compound OCC(C)(CO)CO QXJQHYBHAIHNGG-UHFFFAOYSA-N 0.000 description 1
- 239000012991 xanthate Substances 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 239000011667 zinc carbonate Substances 0.000 description 1
- 229910000010 zinc carbonate Inorganic materials 0.000 description 1
- 235000004416 zinc carbonate Nutrition 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
Landscapes
- Adhesives Or Adhesive Processes (AREA)
- Manufacturing Of Multi-Layer Textile Fabrics (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.
Description
【発明の詳細な説明】
崖ｍ冴υ牛氷駈
本発明は、耐洗濯性にすぐれたカーペット裏打ち用組成
物に関する。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a carpet backing composition with excellent washing resistance.
従来■及±
現在の代表的なカーペットであるタフテッドカーペット
においては、−次基布にナイロン、アクリル、ビニロン
等のパイルを植え込むと共に、このパイルが脱落するの
を防止するために、裏打ち処理が施されている。この裏
打ち処理には、合成ゴムラテックス等の高分子重合体の
水性分散液に必要に応じて充填剤、分散剤、増粘剤等を
添加してなる水性分散組成物が使用されている。Conventional ■ and ± In tufted carpets, which are the current typical carpet, piles of nylon, acrylic, vinylon, etc. are planted in the base fabric, and a backing treatment is applied to prevent the piles from falling off. It has been subjected. For this lining treatment, an aqueous dispersion composition is used, which is prepared by adding fillers, dispersants, thickeners, etc. as necessary to an aqueous dispersion of a high molecular weight polymer such as synthetic rubber latex.
近年、このようなカーペットに耐洗濯性が強く求められ
るに至っており、特に、所謂ダストコントロールマット
においては、多数回の洗濯後にも、マットの寸法変化、
例えば収縮が少ないこと、カーリング（曲がり）現象が
ないこと、パイルや裏打ち樹脂の脱落が少ないこと等、
過酷な耐洗濯性が要求されている。In recent years, there has been a strong demand for such carpets to have washing resistance, and in particular, so-called dust control mats do not change their dimensions even after being washed many times.
For example, there is little shrinkage, there is no curling phenomenon, and there is little shedding of the pile or lining resin, etc.
Severe washing resistance is required.
かかる耐洗濯性を確保するために、既に、種々の水性分
散組成物が提案されている。例えば、特開昭５９−１５
４６５号公報には、スチレン−ブタジェン共重合体ゴム
ラテックスにエポキシ化合物とアジリジン環を有する化
合物を配合してなる水性分散組成物が記載されている。In order to ensure such washing resistance, various aqueous dispersion compositions have already been proposed. For example, JP-A-59-15
No. 465 describes an aqueous dispersion composition comprising a styrene-butadiene copolymer rubber latex mixed with an epoxy compound and a compound having an aziridine ring.
また、ゴムラテックスにメチロールメラミン等の熱硬化
性樹脂や加硫剤を単独にて、又は併用して配合してなる
組成物も知られているが、洗濯後のマットの寸法変化や
、裏打ち樹脂の脱落等に関して、尚、改良の必要が認め
られる。Compositions made by blending rubber latex with a thermosetting resin such as methylol melamine or a vulcanizing agent singly or in combination are also known; There is still a need for improvement in regards to the falling off etc.
発明が解決しようとする問題点
本発明者らは、従来のカーペット裏打ち用組成物におけ
る上記した問題を解決するために鋭意研究した結果、高
分子重合体の水性分散液にブロック化ポリイソシアネー
トと共に、メラミン樹脂及び加硫剤のうちの少なくとも
１種を配合することによって、従来の同種の組成物に比
べて海かにすくれた耐洗濯性を有し、前記した過酷な要
求に応え得るカーペット裏打ち用組成物を得ることがで
きることを見出して、本発明に至ったものである。Problems to be Solved by the Invention As a result of intensive research to solve the above-mentioned problems in conventional carpet lining compositions, the present inventors have developed an aqueous dispersion of a high molecular weight polymer together with a blocked polyisocyanate. By blending at least one of a melamine resin and a vulcanizing agent, the carpet backing has superior washing resistance compared to conventional compositions of the same type and can meet the above-mentioned severe demands. The inventors have discovered that it is possible to obtain a composition for use in the treatment of cancer, leading to the present invention.
朋上目乱ε肩」Ｕ−４だ叉ｊどＥ成
木発明によるカーペット裏打ち用組成物の第１は、高分
子重合体の水性分散液の固形分１００重量部当りブロッ
ク化ポリイソシアネート０．５〜３０重量部及び゛メラ
ミン樹脂１〜１０重量部を含有することを特徴とし、第
２は、高分子重合体の水性分散液の固形分１００重量部
当りブロック化ポリイソシアネート０．５〜３０重量部
及び加硫剤０゜５〜１０重量部を含有することを特徴と
し、また、第３は、高分子重合体の水性分散液の固形分
１００重量部当りブロック化ポリイソシアネート０．５
〜３０重量部、メラミン樹脂１〜１０重量部及び加硫剤
０．５〜１０重量部を含有することを特徴とする。The first carpet backing composition according to the present invention comprises 0.00% of the blocked polyisocyanate per 100 parts by weight of the solids of the aqueous dispersion of the high molecular weight polymer. 5 to 30 parts by weight and 1 to 10 parts by weight of melamine resin; Parts by weight and 0.5 to 10 parts by weight of a vulcanizing agent, and the third is 0.5 parts by weight of blocked polyisocyanate per 100 parts by weight of solid content of the aqueous dispersion of the polymer.
~30 parts by weight, 1 to 10 parts by weight of melamine resin, and 0.5 to 10 parts by weight of vulcanizing agent.
本発明において用いられる高分子重合体の水性分散液と
しては、スチレン−ブタジェンゴム（ＳＢＲ）ラテック
ス、メチルメタクリレート−ブタジェンゴム（Ｍ Ｂ
Ｒ）ラテックス、アクリロニトリル−ブタジェンゴム（
ＮＢＲ）ラテックス、天然ゴム（ＮＲ）ラテックス、塩
化ビニル系重合体ラテックス、メチルメタクリレート−
スチレン−ブタジェンゴム（ＭＳＢＲ）ラテックス、エ
チレン−酢酸ビニルラテックス、アクリルラテックス等
、従来より知られている高分子重合体のラテックスが用
いられる。これらのラテックスにおける高分子重合体は
、カルボキシル基、水酸基、アミド基、グリシジル基、
スルホン酸基等の官能基を有していてもよい。特に、本
発明においては、カルボキシル基及び／又は水酸基を有
する高分子重合体のラテックスが好ましく用いられる。Examples of the aqueous dispersion of the polymer used in the present invention include styrene-butadiene rubber (SBR) latex, methyl methacrylate-butadiene rubber (M B
R) Latex, acrylonitrile-butadiene rubber (
NBR) latex, natural rubber (NR) latex, vinyl chloride polymer latex, methyl methacrylate
Conventionally known polymer latexes such as styrene-butadiene rubber (MSBR) latex, ethylene-vinyl acetate latex, and acrylic latex are used. The polymers in these latexes include carboxyl groups, hydroxyl groups, amide groups, glycidyl groups,
It may have a functional group such as a sulfonic acid group. In particular, in the present invention, latexes of high molecular weight polymers having carboxyl groups and/or hydroxyl groups are preferably used.
これらの官能基がラテックス中の高分子重合体に含まれ
る態様は何ら限定されるものではないが、代表的には、
主ポリマーを構成する単量体成分と共に、分子内に上記
官能基を側鎖に有する単量体成分を共重合させることに
よって得ることができる。There are no limitations to the manner in which these functional groups are contained in the polymer in the latex, but typically,
It can be obtained by copolymerizing a monomer component having the above-mentioned functional group in its side chain in the molecule together with the monomer component constituting the main polymer.
例えば、ラテックスにカルボキシル基を導入するには、
上記共重合における単量体成分として、アクリル酸、メ
タクリル酸、クロトン酸等のエチレン性不飽和モノカル
ボン酸や、フマル酸、マレイン酸、イタコン酸等のエチ
レン性不飽和ジカルボン酸又はこれらエチレン性不飽和
ジカルボン酸の半エステル等を用いればよい。また、ラ
テックスに水酸基を導入するには、上記共重合における
単量体成分と已て、２−ヒドロキシエチル（メタ）アク
リレート、２−ヒドロキシプロピル（メタ）アクリレー
ト、２，３−ジヒドロキシプロピル（メタ）アクリレー
ト、Ｎ−メチロール（メタ）アクリルアミド等を用いれ
ばよい。For example, to introduce carboxyl groups into latex,
As monomer components in the above copolymerization, ethylenically unsaturated monocarboxylic acids such as acrylic acid, methacrylic acid, and crotonic acid, ethylenically unsaturated dicarboxylic acids such as fumaric acid, maleic acid, and itaconic acid, or these ethylenically unsaturated monocarboxylic acids, such as fumaric acid, maleic acid, and itaconic acid, and A half ester of saturated dicarboxylic acid or the like may be used. In addition, in order to introduce hydroxyl groups into latex, in addition to the monomer components in the above copolymerization, 2-hydroxyethyl (meth)acrylate, 2-hydroxypropyl (meth)acrylate, 2,3-dihydroxypropyl (meth) Acrylate, N-methylol (meth)acrylamide, etc. may be used.
更に、このようにして得られるこれら官能基を有する重
合性高分子化合物を共重合させたり、これらの官能基を
有する高分子化合物を高分子重合体の保護コロイドとし
て、重合反応中に用いたり、或いは重合反応後に添加す
ることもできる。Furthermore, the polymerizable polymer compounds having these functional groups obtained in this way can be copolymerized, or the polymer compounds having these functional groups can be used as a protective colloid for the polymer during the polymerization reaction. Alternatively, it can be added after the polymerization reaction.
本発明で用いられるブロック化ポリイソシアネートとは
、ポリイソシアネートの有する遊離イソシアネートＭに
付加反応して、これを不活性化させるが、加熱及び／又
は触媒によって容易に解離して、再び遊離イソシアネー
ト基をもつポリイソシアネートを再生する結合を形成す
る化合物（以下、ブロック化剤という。）とポリイソシ
アネートとの付加反応生成物をいう。かかるブロック化
ポリイソシアネートは既に知られており、例えば、特開
昭６０−２０３６８５号公報に記載されている。The blocked polyisocyanate used in the present invention is an addition reaction to free isocyanate M contained in the polyisocyanate to inactivate it, but it is easily dissociated by heating and/or a catalyst to generate free isocyanate groups again. Refers to the addition reaction product between polyisocyanate and a compound that forms a bond that regenerates the polyisocyanate (hereinafter referred to as a blocking agent). Such blocked polyisocyanates are already known and are described, for example, in JP-A-60-203685.
上記ブロック化ポリイソシアネート化合物のためのポリ
イソシアネートとしては、従来より知られている任意の
ポリイソシアネートが用いられる。Any conventionally known polyisocyanate can be used as the polyisocyanate for the blocked polyisocyanate compound.
従って、かかるポリイソシアネートとして、例えば、エ
チレンジイソシアネート、テトラメチレンジイソシアネ
ート、ヘキサメチレンジイソシアネート、２，４．４−
又は２，２．４− トリメチルへキサメチレンジイソシ
アネート、２．６−ジイソシアナトカプロン酸メチル等
の脂肪族ジイソシアネート、３−イソシアナトメチル−
３，５，５−トリメチルシクロヘキサン、１，３−又は
１，４−ビス（イソシアナトメチル）シクロヘキサン、
メチルシクロヘキサン−２，４−又は２．６−ジイソシ
アネート、ジシクロへキシルメタン−４，４゛−ジイソ
シアネート、１，３−又は１，４−ジイソシアナトシク
ロヘキサン等の脂環族ジイソシアネート、ｍ−又はｐ−
フェニレンジイソシアネート、ジフェニルメタン−４，
４゛−ジイソシアネ−１・、２．４−又は２．６−１−
リレンジイソシアネート等の芳香族ジイソシアネート、
１．３−又は１，４−ビス（イソシアナトメチル）ベン
ゼン、■、３−又は１，４−ビス（α−イソシアナトイ
ソプロピル）ベンゼン等の芳香脂肪族ジイソシアネート
のようなジイソシアネートを挙げることができる。Therefore, such polyisocyanates include, for example, ethylene diisocyanate, tetramethylene diisocyanate, hexamethylene diisocyanate, 2,4.4-
or 2,2.4-trimethylhexamethylene diisocyanate, aliphatic diisocyanate such as methyl 2,6-diisocyanatocaproate, 3-isocyanatomethyl-
3,5,5-trimethylcyclohexane, 1,3- or 1,4-bis(isocyanatomethyl)cyclohexane,
Alicyclic diisocyanates such as methylcyclohexane-2,4- or 2,6-diisocyanate, dicyclohexylmethane-4,4'-diisocyanate, 1,3- or 1,4-diisocyanatocyclohexane, m- or p-
Phenyl diisocyanate, diphenylmethane-4,
4'-Diisocyane-1, 2.4- or 2.6-1-
Aromatic diisocyanates such as lylene diisocyanate,
Mention may be made of diisocyanates such as araliphatic diisocyanates such as 1.3- or 1,4-bis(isocyanatomethyl)benzene, ■, 3- or 1,4-bis(α-isocyanatoisopropyl)benzene, etc. .
また、トリイソシアネートとして、トリフェニルメタン
−４，４，４”−）ジイソシアネート、１．３．５−ト
リイソシアナトベンゼン、Ｌ３，５−１−リス（イソシ
アナトメチル）シクロヘキサン、１，３．５− ）リス
（イソシアナトメチル）ベンゼン、２，６−ジイツシア
ナ１−カプロン酸−２−イソシアナトエチル等を挙げる
ことができる。In addition, as the triisocyanate, triphenylmethane-4,4,4''-) diisocyanate, 1,3,5-triisocyanatobenzene, L3,5-1-lis(isocyanatomethyl)cyclohexane, 1,3.5 -) Lis(isocyanatomethyl)benzene, 2-isocyanatoethyl 2,6-dicyana-1-caproate, and the like.
更に、本発明において用い得るポリイソシアネートとし
て、例えば、ジイソシアネートの三量体や三量体等の重
合ポリイソシアネート、ポリメチレンポリフェニレンポ
リイソシアネートや、上記イソシアネート化合物の過剰
と、例えば、エチレングリコール、プロピレングリコー
ル、ジプロピレングリコール、ジエチレングリコール、
トリエチレングリコール、２．２．４−１−リフチル−
１，３−ベンタンジオール、ネオペンチルグリコール、
ヘキサンジオール、シクロヘキサンジメタツール、シク
ロヘキサンジオール、水添ビスフェノールＡ１キシリレ
ングリコール、グリセリン、トリメチロールエタン、ト
リメチロールプロパン、ヘキサントリオール、ペンタエ
リスリトール、ソルビトール、ソルビット、シュクロー
ズ、ヒマシ油、エチレンジアミン、ヘキサメチレンジア
ミン、エタノールアミン、ジェタノールアミン、トリエ
タノールアミン、水、アンモニア、尿素等の活性水素含
有低分子量化合物、又は種々のポリエーテルポリオール
、ポリエステルポリオール、ポリウレタンポリオール、
アクリルポリオール、エポキシポリオール等の活性水素
含有高分子量化合物とを反応させて得られるポリイソシ
アネート、或いはこれらのアロファネート化ポリイソシ
アネート、ビウレット化ポリイソシアネート等を挙げる
ことができる。Further, as the polyisocyanate that can be used in the present invention, for example, polymerized polyisocyanates such as trimers and trimers of diisocyanates, polymethylene polyphenylene polyisocyanates, and excess of the above isocyanate compounds, such as ethylene glycol, propylene glycol, dipropylene glycol, diethylene glycol,
Triethylene glycol, 2.2.4-1-rifutyl-
1,3-bentanediol, neopentyl glycol,
Hexanediol, cyclohexane dimetatool, cyclohexanediol, hydrogenated bisphenol A1 xylylene glycol, glycerin, trimethylolethane, trimethylolpropane, hexanetriol, pentaerythritol, sorbitol, sorbitol, sucrose, castor oil, ethylenediamine, hexamethylenediamine , ethanolamine, jetanolamine, triethanolamine, water, ammonia, active hydrogen-containing low molecular weight compounds such as urea, or various polyether polyols, polyester polyols, polyurethane polyols,
Examples include polyisocyanates obtained by reacting with active hydrogen-containing high molecular weight compounds such as acrylic polyols and epoxy polyols, and allophanated polyisocyanates and biuret-formed polyisocyanates thereof.
上記イソシアネート化合物は単独にて、又は２種以上の
混合物として用いられる。The above isocyanate compounds may be used alone or as a mixture of two or more.
前記ブロック化剤としては、従来より知られている任意
のブロック化剤が用いられる。かかるブロック化剤と′
しては、例えば、フェノール、クレゾール、ｐ−ノニル
フェノール、ヒドロキシ安息香酸エステル等のフェノー
ル系ブロック化剤、ε−カプロラクタム、Ｔ−ブチロラ
クタム等のラクタム系ブロック化剤、マロン酸ジエチル
、アセト酢酸メチル、アセチルアセトン等の活性メチレ
ン系ブロック化剤、エタノール、イソプロピルアルコー
ル、ｔ−ブチルアルコール、ラウリルアルコール、エチ
レングリコールモノエチルエーテル、ベンジルアルコー
ル、グリコール酸、グリコール酸エステル、乳酸、乳酸
エステル、ジアセトンアルコール、エチレンクロルヒド
リン等のアルコール系ブロック化剤、ブチルメルカプタ
ン、オクチルメルカプタン、ｔ−ドデシルメルカプタン
、２−メルカプトヘンジチアゾール、チオフェノール等
のメルカプカン系ブロック化剤、アセトアニリド、酢酸
アミド、アクリルアミド、ヘンズアミド等の酸アミド系
ブロック化剤、コハク酸イミド、フタルイミド等のイミ
ド系ブロック化剤、ジフェニルアミン、カルバソ゛−ル
、アニリン、シフ゛チルアミン等のアミン系ブロック化
剤、イミダゾール、２−エチルイミダゾール等のイミダ
ゾール系ブロック化剤、尿素、チオ尿素、エチレンチオ
尿素等の尿素系ブロック化剤、２−オキサゾリドン、Ｎ
−フェニルカルバミン酸フェニル等のカルバミン酸エス
テル系ブロック化剤、ホルムアルドキシム、アセトアル
ドキシム、アセトキシム、メチルエチルケトキシム、ジ
アセチルモノオキシム、シクロへキサノンオキシム、ベ
ンゾフェノンオキシム等のオキシム系ブロック化剤、或
いは亜硫酸水素ナトリウム、亜硫酸水素カリウム等の亜
硫酸塩系ブロック化剤等を挙げることができる。これら
ブロック化剤は、単独で用いてもよく、また、２種以上
を併用してもよいが、本発明においては、特にオキシム
系ブロック化剤が、反応性、安全性等の点から好ましい
。As the blocking agent, any conventionally known blocking agent can be used. Such a blocking agent and
Examples include phenol blocking agents such as phenol, cresol, p-nonylphenol, and hydroxybenzoic acid esters, lactam blocking agents such as ε-caprolactam and T-butyrolactam, diethyl malonate, methyl acetoacetate, and acetylacetone. Active methylene blocking agents such as ethanol, isopropyl alcohol, t-butyl alcohol, lauryl alcohol, ethylene glycol monoethyl ether, benzyl alcohol, glycolic acid, glycolic acid ester, lactic acid, lactic acid ester, diacetone alcohol, ethylene chlorhydride Alcohol-based blocking agents such as phosphorus, mercapcan-based blocking agents such as butyl mercaptan, octyl mercaptan, t-dodecyl mercaptan, 2-mercaptohendithiazole, and thiophenol, and acid amide-based blocks such as acetanilide, acetamide, acrylamide, and henzamide. imide blocking agents such as succinimide and phthalimide, amine blocking agents such as diphenylamine, carbazole, aniline, and cyphthylamine, imidazole blocking agents such as imidazole and 2-ethylimidazole, urea, Urea-based blocking agents such as thiourea and ethylene thiourea, 2-oxazolidone, N
- Carbamate ester blocking agents such as phenyl phenylcarbamate, oxime blocking agents such as formaldoxime, acetaldoxime, acetoxime, methyl ethyl ketoxime, diacetylmonoxime, cyclohexanone oxime, benzophenone oxime, or sulfurous acid Examples include sulfite-based blocking agents such as sodium hydrogen and potassium hydrogen sulfite. These blocking agents may be used alone or in combination of two or more types, but in the present invention, oxime-based blocking agents are particularly preferred in terms of reactivity, safety, and the like.
ブロック化ポリイソシアネートは、前述し、たように、
ポリイソシアネートとブロック化剤とを常法にて反応さ
せることによって得ることができる。Blocked polyisocyanate, as mentioned above,
It can be obtained by reacting a polyisocyanate and a blocking agent in a conventional manner.
この反応は、活性水素をもたない溶剤中でも、また、無
溶剤量でも行なうことができる。活性水素をもたない溶
剤としては、例えば、酢酸エチル、酢酸ブチル、セロソ
ルブアセテート、カルピトールアセテート、二塩基酸の
ジメチルエステル等のエステル系、メチルエチルケトン
、メチルイソブチルケトン、シクロヘキサノン等のケト
ン系、トルエン、キシレン、ツルペッツ＃１００、ツル
ペッツ＃１５０等の芳香族系溶剤が挙げられる。This reaction can be carried out in a solvent without active hydrogen and also in a solvent-free amount. Examples of solvents without active hydrogen include esters such as ethyl acetate, butyl acetate, cellosolve acetate, carpitol acetate, dimethyl ester of dibasic acids, ketones such as methyl ethyl ketone, methyl isobutyl ketone, and cyclohexanone, toluene, Aromatic solvents such as xylene, Tsurupetz #100, Tsurupetz #150 and the like can be mentioned.
また、ブロック化剤として亜硫酸塩系ブロック化剤を用
いる場合は、水を溶剤として用いることが好適である場
合が多い。Moreover, when using a sulfite-based blocking agent as a blocking agent, it is often preferable to use water as a solvent.
ポリイソシアネートのブロック化反応は、前述したよう
に、常法によればよいが、より具体的には例えば、ポリ
イソシアナートブロック化剤とをＮＧＯ／ブロック化剤
（当量比）を約０．９〜１．１、好ましくは約０．９５
〜１．０として反応させる方法、ポリイソシアネートと
ブロック化剤とをＮＧＯ／ブロック化剤（当量比）を約
１．１〜３，０、好ましくは約１．２〜２．０として反
応させた後、これに前述した活性水素含有低分子量化合
物及び／又は活性水素含有高分子量化合物を反応させる
方法、ポリイソシアネートと活性水素含有低分子量化合
物及び／又は活性水素含有高分子量化合物をＮＣＯ／活
性水素（当量比）を約１．５〜１０．０、好ましくは約
２．０〜７．０として反応させた後、必要に応じてポリ
イソシアネートを除去してから、これにブロック化剤を
反応させる方法等が挙げられる。As mentioned above, the blocking reaction of polyisocyanate may be carried out by a conventional method, but more specifically, for example, the polyisocyanate blocking agent and NGO/blocking agent (equivalent ratio) are about 0.9. ~1.1, preferably about 0.95
The polyisocyanate and the blocking agent were reacted at a ratio of NGO/blocking agent (equivalent ratio) of about 1.1 to 3.0, preferably about 1.2 to 2.0. Thereafter, the polyisocyanate and the active hydrogen-containing low-molecular-weight compound and/or the active-hydrogen-containing high-molecular-weight compound are reacted with NCO/active hydrogen ( A method in which the polyisocyanate is reacted with an equivalent ratio of about 1.5 to 10.0, preferably about 2.0 to 7.0, and then the polyisocyanate is removed as necessary, and then the blocking agent is reacted with the polyisocyanate. etc.
しかし、これらに限定されるものではない。尚、ポリイ
ソシアネートのブロック化反応に際して、例えば、第３
級アミン、有機金属化合物等の従来より知られている触
媒を使用してもよい。However, it is not limited to these. In addition, in the blocking reaction of polyisocyanate, for example, the third
Conventionally known catalysts such as grade amines and organometallic compounds may also be used.
このようにして得られるブロック化ポリイソシアネート
は、通常、水乳化液、水分散液又は水溶液等の水系混合
物として、前記高分子重合体の水性分散液に配合するの
が好適である。このように、ブロック化ポリイソシアネ
ートを水系混合物とするためには、従来より知られてい
る任意の方法によることができるが、例えば、ブロック
化ポリイソシアネートを機械的に微粒子化して水に分散
させ、必要に応じて、界面活性剤、保護コロイド、分散
剤等社よって分散液を安定化する方法、界面活性剤、保
護コロイド等を用いて乳化する方法、ブロック化ポリイ
ソシアネートの一部に塩形成性の基を導入して、これを
塩形成させるか、或いはブロック化ポリイソシアネート
自体に親水性基を導入して、自己乳化或いは水溶化させ
る方法、親水性のブロック化剤を用いて、得られるブロ
ック化ポリイソシアネートに自己乳化性或いは水溶性を
与える方法等が挙げられる。また、これらの方法の２種
以上を組合わせた方法も可能である。The thus obtained blocked polyisocyanate is usually preferably blended into the aqueous dispersion of the high molecular weight polymer as an aqueous mixture such as an aqueous emulsion, an aqueous dispersion, or an aqueous solution. In this way, in order to form the blocked polyisocyanate into an aqueous mixture, any conventionally known method can be used. For example, the blocked polyisocyanate is mechanically made into fine particles and dispersed in water, If necessary, methods for stabilizing the dispersion using surfactants, protective colloids, dispersants, etc., methods for emulsifying using surfactants, protective colloids, etc., salt-forming methods for some of the blocked polyisocyanates, etc. The block obtained by introducing a group of and forming a salt, or by introducing a hydrophilic group into the blocked polyisocyanate itself to make it self-emulsifying or water-soluble, or by using a hydrophilic blocking agent. Examples include a method of imparting self-emulsifying properties or water solubility to the chemically modified polyisocyanate. Furthermore, a combination of two or more of these methods is also possible.
ブロック化ポリイソシアネートを製造する際に溶剤を用
いる場合には、溶剤を含有したまま水中への乳化、分散
、溶解等の処理を行なってもよく、また、予め溶剤を除
去した後に処理してもよい。When a solvent is used to produce blocked polyisocyanate, processing such as emulsification, dispersion, and dissolution in water may be carried out while the solvent is still contained, or processing may be carried out after the solvent is removed in advance. good.
溶剤を含んだまま、水中への乳化、分散、溶解等の処理
をしたものは、この後に蒸発、分液等の方法によって溶
剤を除去することも可能である。また、ブロック化ポリ
イソシアネートに第３級アミン、有機金属化合物等の従
来より知られているイソシアネート反応触媒、ブロック
化ポリイソシアネートの解離触媒等を添加した後、上記
水系混合物とすることは、本発明のブロック化ポリイソ
シアネートの効果を増大させるのに有効な場合が多い。If the product is treated by emulsifying, dispersing, dissolving, etc. in water while still containing the solvent, the solvent can be removed by methods such as evaporation, liquid separation, etc. In addition, the present invention allows the addition of conventionally known isocyanate reaction catalysts such as tertiary amines and organometallic compounds, dissociation catalysts for blocked polyisocyanates, etc. to the blocked polyisocyanate, and then forms the above-mentioned aqueous mixture. are often effective in increasing the effectiveness of blocked polyisocyanates.
本発明による組成物において、前記高分子重合体の水性
分散液とブロック化ポリイソシアネートとの配合割合は
、組成物から形成される裏打ち樹脂に要求される性能と
各成分の性質にもよるが、通常、高分子重合体の水性分
散液の固形分１００重量部に対し、ブロック化ポリイソ
シアネートの配合量は、固形分にて０．５〜３０重世部
の範囲にある。組成物において、ブロック化ポリイソシ
アネートの配合量が０．５重量部よりも少ない場合には
、前述したような耐洗濯性が十分でな（、他方、３０重
量部よりも多い場合は、組成物から形成される裏打ち樹
脂が硬く、脆くなって、樹脂のひび割れや脱落等を生じ
やすい。更に、通常、ブロック化ポリイソシアネートは
高分子重合体の水性分散液に比べて高価であるので、必
要な性能が得られる看取上にこれを配合することは、経
済性の点からも不利モある。以上から、組成物における
ブロック化ポリイソシアネートの配合量は、特に、１〜
２０重量部の範囲が好ましい。In the composition according to the present invention, the blending ratio of the aqueous dispersion of the high molecular weight polymer and the blocked polyisocyanate depends on the performance required of the backing resin formed from the composition and the properties of each component. Usually, the amount of blocked polyisocyanate to be blended is in the range of 0.5 to 30 parts by weight based on 100 parts by weight of the solid content of the aqueous dispersion of the high molecular weight polymer. If the amount of blocked polyisocyanate in the composition is less than 0.5 parts by weight, the wash resistance as described above may not be sufficient (on the other hand, if it is more than 30 parts by weight, the composition The backing resin formed from the polyisocyanate becomes hard and brittle, and the resin is likely to crack or fall off.Furthermore, blocked polyisocyanates are usually more expensive than aqueous dispersions of high molecular weight polymers. It is also disadvantageous from an economical point of view to blend this at the end of the day when performance is obtained.From the above, the amount of blocked polyisocyanate in the composition is particularly from 1 to 1.
A range of 20 parts by weight is preferred.
高分子重合体の分散液とブロック化ポリイソシアネート
の混合物を得るには、通常、これらをそのまま混合すれ
ばよいが、必要に応じて、界面活性剤、分散剤、増粘剤
の添加、又はｐＨ８１１整等によって、一層安定な混合
物とすることも可能である。To obtain a mixture of a polymer dispersion and a blocked polyisocyanate, it is usually sufficient to mix them as they are, but if necessary, a surfactant, a dispersant, a thickener may be added, or a pH of 811 It is also possible to obtain a more stable mixture by adjusting the mixture.
本発明において、上記ブロック化ポリイソシアネートは
、一部エポキシ化合物にて置換することができる。本発
明において好ましく用い得るエポキシ化合物は、平均し
て１分子当たり２個以上のエポキシ基を有するビスフェ
ノール型、レゾルシノール型、脂環式エポキシ樹脂のほ
か、エチレングリコール、プロピレングリコール、グリ
セリン、ヘキサントリオール、トリメチロールプロパン
、ポリエチレングリコール等の脂肪族多価アルコールと
エピクロルヒドリンとの反応生成物を挙げることができ
る。これらエポキシ化合物は、水溶性であっても、水不
溶性であってもよく、水への溶解性に応じて、水溶液と
して、又は乳化分散して、高分子重合体の水性分散液に
配合される。In the present invention, the blocked polyisocyanate can be partially substituted with an epoxy compound. Epoxy compounds that can be preferably used in the present invention include bisphenol type, resorcinol type, and alicyclic epoxy resins having an average of two or more epoxy groups per molecule, as well as ethylene glycol, propylene glycol, glycerin, hexanetriol, and cycloaliphatic epoxy resins. Examples include reaction products of aliphatic polyhydric alcohols such as methylolpropane and polyethylene glycol and epichlorohydrin. These epoxy compounds may be water-soluble or water-insoluble, and depending on their solubility in water, they are blended into the aqueous dispersion of the polymer as an aqueous solution or emulsified. .
高分子重合体の水性分散液にブロック化ポリイソシアネ
ートと共にエポキシ化合物を配合するときは、可使時間
の短縮を伴うものの、カーペットの洗濯後の収縮やカー
リング、樹脂の脱落等が小さく、また、耐洗濯性が改善
された裏打ち樹脂が形成される。しかし、エポキシ化合
物を多量に配合することは、可使時間を極端に短縮する
ので、性能及び使用性のバランスの観点から、本発明の
組成物において、エポキシ化合物の配合量は、高分子重
合体の水性分散液の固形分１００重量部に対し、固形分
にて１０重量部以下である。When an epoxy compound is blended with a blocked polyisocyanate in an aqueous dispersion of a polymer, the pot life is shortened, but shrinkage and curling of the carpet after washing, and shedding of the resin are small, and the resistance is increased. A backing resin with improved washability is formed. However, blending a large amount of an epoxy compound will extremely shorten the pot life, so from the viewpoint of the balance between performance and usability, in the composition of the present invention, the blending amount of the epoxy compound is The solid content is 10 parts by weight or less per 100 parts by weight of the aqueous dispersion.
本発明による組成物は、前記ブロック化ポリイソシアネ
ートと共に、メラミン樹脂及び加硫剤のうちの少なくと
も１種を含有し、好ましくは、これらを共に含有する。The composition according to the invention contains, together with the blocked polyisocyanate, at least one of a melamine resin and a vulcanizing agent, preferably both.
本発明において用いるメラミン樹脂としては、よく知ら
れているように、塩基性条件下にメラミンとホルムアノ
’ｖデヒドとを反応させて得られるメチロールメラミン
や、これに更にメタノールやブタノールを反応させて得
られるメチル化又はブチル化メチロールメラミンを挙げ
ることができる。As is well known, the melamine resin used in the present invention includes methylolmelamine obtained by reacting melamine and formano'vdehyde under basic conditions, and methylolmelamine obtained by further reacting this with methanol or butanol. Mention may be made of methylated or butylated methylolmelamine.
前記高分子重合体の水性分散液への配合に際しては、メ
ラミン樹脂が水溶性であるときは、そのまま上記水系混
合物と混合すればよいが、水不溶性であるときは、前記
ブロック化ポリイソシアネートと同様に、水乳化液や分
散液等として配合すればよい。When blending the high molecular weight polymer into the aqueous dispersion, if the melamine resin is water-soluble, it may be mixed as is with the aqueous mixture, but if it is water-insoluble, it may be mixed with the above-mentioned blocked polyisocyanate. It may be blended into a water emulsion, dispersion, or the like.
本発明による組成物において、メラミン樹脂の配合量は
、前記高分子重合体の水性分散液の固形分１００重量部
当たり１〜１０重量部の範囲である。特に、性能のバラ
ンスの点からは、２〜７重量部の範囲が好ましい。In the composition according to the present invention, the blending amount of the melamine resin is in the range of 1 to 10 parts by weight per 100 parts by weight of the solid content of the aqueous dispersion of the high molecular weight polymer. In particular, from the viewpoint of performance balance, the range of 2 to 7 parts by weight is preferable.
組成物がかかるメラミン樹脂を含有するときは、組成物
をカーペットの裏面に塗布し、乾燥させた後、加熱する
ことによって、前記ブロック化ポリイソシアネートから
ブロック化剤が遊離して、遊離のイソシアネート基を有
するポリイソシアネートが再生され、このポリイソシア
ネートが高分子重合体及びメラミン樹脂それぞれに反応
して３次元架橋構造を形成し、カーペット裏打ち樹脂と
してすぐれた耐洗濯性を発現する。When the composition contains such a melamine resin, the composition is applied to the back side of the carpet, dried, and then heated to liberate the blocking agent from the blocked polyisocyanate and form free isocyanate groups. This polyisocyanate reacts with the high molecular weight polymer and the melamine resin to form a three-dimensional crosslinked structure, and exhibits excellent washing resistance as a carpet lining resin.
本発明において用いる加硫剤は、イオウ又は加熱によっ
てイオウを放出する化合物のほか、酸化亜鉛のような金
属酸化物を含む。イオウとしては、結晶性又は非結晶性
の粉末イオウ、コロイドイオウ等を挙げることができる
。また、加熱によってイオウを放出する化合物としては
、例えば、多硫化チウラム、ジチオカルバミン、千オプ
ラスト等を挙げることができる。この加硫剤は、通常、
高分子分散液１００重量部当たりに０．５〜１０重量部
の範囲で配合される。組成物が特にすぐれた耐洗濯性や
耐ブロッキング性を有する゛裏打ち樹脂を形成するため
には、１〜５重量部の範囲が好ましい。The vulcanizing agent used in the present invention includes sulfur or a compound that releases sulfur upon heating, as well as metal oxides such as zinc oxide. Examples of sulfur include crystalline or non-crystalline powder sulfur, colloidal sulfur, and the like. Furthermore, examples of compounds that release sulfur upon heating include thiuram polysulfide, dithiocarbamine, and oplast. This vulcanizing agent is usually
It is blended in an amount of 0.5 to 10 parts by weight per 100 parts by weight of the polymer dispersion. In order to form a backing resin in which the composition has particularly excellent washing resistance and anti-blocking properties, the amount is preferably in the range of 1 to 5 parts by weight.
本発明において、加硫剤は、加硫促進剤や加硫促進助剤
等と併用されることが望ましい。かかる加硫促進剤とし
ては、例えば、ジチオカルバミン酸塩系、チ茅尿素、グ
アニジン系、キサンテート系、チウラム系、アルデヒド
アミン系、チアゾール系等を挙げることができ、また、
加硫促進助剤として、例えば、酸化亜鉛、炭酸亜鉛、ス
テアリン酸亜鉛、ステアリン酸、オレイン酸等を挙げる
ことができる。In the present invention, the vulcanizing agent is preferably used in combination with a vulcanization accelerator, a vulcanization accelerating aid, or the like. Examples of such vulcanization accelerators include dithiocarbamate-based, thiourea-based, guanidine-based, xanthate-based, thiuram-based, aldehydeamine-based, thiazole-based, and the like.
Examples of the vulcanization accelerator include zinc oxide, zinc carbonate, zinc stearate, stearic acid, and oleic acid.
組成物がかかる加硫剤を含有するときは、前述したよう
に、遊離のイソシアネート基を有するポリイソシアネー
トが再生されるとき、このポリイソシア皐−トが高分子
重合体と架橋反応するのみならず、加硫剤が高分子重合
体を架橋して、３次元架橋構造を形成するので、形成さ
れる樹脂は、カーペットｉ打ち樹脂としてすぐれた耐洗
濯性を発現する。When the composition contains such a vulcanizing agent, as mentioned above, when the polyisocyanate having free isocyanate groups is regenerated, this polyisocyanate not only undergoes a crosslinking reaction with the high molecular weight polymer; Since the vulcanizing agent crosslinks the high molecular weight polymer to form a three-dimensional crosslinked structure, the resulting resin exhibits excellent washing resistance as a carpet i-beating resin.
組成物がメラミン樹脂と共に加硫剤を含有するときは、
上記したメラミン樹脂と加硫剤による効果が合わされて
、形成される樹脂は、総合的にバランスがよく、特にす
ぐれた耐洗濯性を有する。When the composition contains a vulcanizing agent along with a melamine resin,
The resin formed by combining the effects of the melamine resin and the vulcanizing agent described above has a good overall balance and particularly excellent washing resistance.
本発明によるカーペット裏打ち用組成物は、必要に応じ
て、上記各成分以外に充填剤、分散剤、酸化防止剤、増
粘剤、着色剤等の通常の配合剤や、ブロック化ポリイソ
シアネートの解離触媒、イソシアネートの反応触媒、メ
ラミン樹脂の硬化触媒等を含有していてもよい。充填剤
としては、通常、例えば、炭酸カルシウム、水酸化アル
ミニウム、クレー、タルク等が用いられる。その配合量
は、高分子重合体の水性分散液の固形分１００重量部に
ついて、通常、１００重量部以下である。１００重量部
を越えて多量に配合するときは、耐洗濯性が低下するお
それがあるので、好ましくない。The carpet lining composition according to the present invention may optionally contain conventional compounding agents such as fillers, dispersants, antioxidants, thickeners, colorants, etc. in addition to the above-mentioned components, and dissociation of blocked polyisocyanate. It may contain a catalyst, an isocyanate reaction catalyst, a melamine resin curing catalyst, and the like. As the filler, for example, calcium carbonate, aluminum hydroxide, clay, talc, etc. are usually used. The amount incorporated is usually 100 parts by weight or less per 100 parts by weight of the solid content of the aqueous dispersion of the high molecular weight polymer. When blending in a large amount exceeding 100 parts by weight, it is not preferable because there is a risk that the washing resistance will decrease.
本発明による組成物は、カーペットの裏面に塗布し、乾
燥した後、１１０〜２００℃程度の温度に加熱すれば、
耐洗濯性にすぐれた裏打ち樹脂を形成する。The composition according to the present invention can be applied to the back side of a carpet, dried, and then heated to a temperature of about 110 to 200°C.
Forms a backing resin with excellent washing resistance.
本発明によるカーペット裏打ち用組成物は、クツテッド
カーペット、編みカーペット、フックカーペット等、裏
面に高分子重合体の分散液が施されるすべてのカーペッ
トに用いることができる。The carpet backing composition according to the invention can be used in all carpets, such as tucked carpets, knitted carpets, hooked carpets, etc., which have a dispersion of a high molecular weight polymer applied to the back side.
（発明の効果）
本発明によるカーペットｉ打ち用水性組成物は、高分子
重合体°の水性分散液にブロック化ポリイソシアネート
と共に、メラミン樹脂樹脂及び／又は加硫剤を含有し、
従来の同種の組成物に比較して、ポット・ライフが著し
く長く、組成物の製造から使用に至るまで、長期間が経
過しても何ら問題が生じない。更に、前述したように、
形成される裏打ち樹脂においては、高分子重合体及びポ
リイソシアネートがメラミン樹脂及び／又は加硫剤にて
架橋されて強靭であるので、かかる裏打ち樹脂を有する
カーペットは、前述したような苛酷な耐洗濯性を有する
。(Effects of the Invention) The aqueous carpet composition according to the present invention contains a melamine resin and/or a vulcanizing agent together with a blocked polyisocyanate in an aqueous dispersion of a high molecular weight polymer.
Compared to conventional compositions of the same type, the pot life is significantly longer, and no problems occur even after a long period of time from manufacture to use of the composition. Furthermore, as mentioned above,
In the formed backing resin, the high molecular weight polymer and polyisocyanate are cross-linked with melamine resin and/or a vulcanizing agent, making it strong, so carpets with such backing resin can withstand harsh washing as described above. have sex.
以下に実施例を比較例と共に挙げて本発明を説明するが
、本発明はこれら実施例により何ら限定されるものでは
ない。The present invention will be described below with reference to Examples and Comparative Examples, but the present invention is not limited to these Examples in any way.
去範斑
アクリロニトリル−ブタジェンゴム（ＮＢＲ）ラテック
ス又はアクリルラテックスの固形分１００重量部に第１
表に示す配合量にてブロック化ポリイソシアネート、水
溶性メラミン樹脂及び／又は加硫剤、重質炭酸カルシウ
ムを添加し、カルボキシメチルセルロースにて粘度を１
００００±１０００ｃｐｓに調整してなる組成物を調製
した。The first compound is added to 100 parts by weight of the solid content of acrylonitrile-butadiene rubber (NBR) latex or acrylic latex.
Blocked polyisocyanate, water-soluble melamine resin and/or vulcanizing agent, and heavy calcium carbonate are added in the amounts shown in the table, and the viscosity is reduced to 1 with carboxymethyl cellulose.
0000±1000 cps was prepared.
この組成物を基布がポリエステルであり、パイルがポリ
アミドであるタフテッドカーペットの裏面に１．０ｋｇ
／ｍの割合にて均一に塗布し、１２０℃で１５分間予備
乾燥し、次いで、１５０℃にて１０分間熱風乾燥した。Apply 1.0 kg of this composition to the back side of a tufted carpet whose base fabric is polyester and whose pile is polyamide.
/m, pre-dried at 120°C for 15 minutes, and then hot air-dried at 150°C for 10 minutes.
このようにして得られたタフテッドカーペットを洗濯機
にて浴比１：３０、洗剤濃度０．１４％、洗濯水温４０
℃にて７分間洗濯し、冷永を１０分間オーバーフローさ
せて濯ぎをした後、温度１００℃にて完全乾燥すること
を１サイクルとして、洗濯を３０サイクルした後、カー
ペットの寸法変化を測定すると共に、カーペットの裏面
とカーリング状態を観察した。The thus obtained tufted carpet was washed in a washing machine at a bath ratio of 1:30, a detergent concentration of 0.14%, and a washing water temperature of 40%.
℃ for 7 minutes, rinsed with cold overflow for 10 minutes, and completely dried at a temperature of 100℃. After 30 washing cycles, the dimensional change of the carpet was measured. , the back side of the carpet and the curling condition were observed.
結果を第１表に示す。先ず、比較例１及び３にみられる
ように、ラテックスにメラミン樹脂と加硫剤、又はメラ
ミン樹脂のみを配合してなる組成物は、洗濯後の収縮率
及びカーリングが著しいのみならず、樹脂の剥離が認め
られて、カーペット裏打ち用組成物としての性能が劣る
。また、比較例２は、ラテックスにブロック化ポリイソ
シアネートのみを配合してなる組成物であって、収縮率
は幾分改善されているものの、特に、抜糸強度及び耐ブ
ロッキング性に劣り、同様に、カーペット裏打ち用組成
物としての性能が劣る。The results are shown in Table 1. First, as seen in Comparative Examples 1 and 3, compositions made by blending latex with melamine resin and a vulcanizing agent, or only melamine resin, not only show significant shrinkage and curling after washing, but also cause the resin to shrink. Peeling was observed and the performance as a carpet backing composition was poor. In addition, Comparative Example 2 is a composition formed by blending only blocked polyisocyanate with latex, and although the shrinkage rate is somewhat improved, it is particularly poor in suture removal strength and blocking resistance, and similarly, Poor performance as a carpet backing composition.
これに対して、実施例１〜３及び１７にみられるように
、ラテックスにブロック化ポリイソシアネートと共にメ
ラミン樹脂を配合してなる本発明の組成物によれば、収
縮率が顕著に改善されているのみならず、裏面状態もす
ぐれている。また、実施例７〜９にみられるように、ラ
テックスにブロック化ポリイソシアネートと共に加硫剤
を配合してなる本発明の組成物も、収縮率及び耐ブロッ
キング性が改善されており、更に、裏面状態もすくれて
いる。On the other hand, as seen in Examples 1 to 3 and 17, the shrinkage rate was significantly improved in the composition of the present invention, which is made by blending melamine resin with blocked polyisocyanate in latex. Not only that, but the back side is also in excellent condition. In addition, as seen in Examples 7 to 9, the composition of the present invention, which is formed by blending a vulcanizing agent with blocked polyisocyanate in latex, also has improved shrinkage rate and blocking resistance, and The condition is also poor.
特に、実施例４〜６．１０〜１６及び１８にみられるよ
うに、ラテックスにブロック化ポリイソシアネート、メ
ラミン樹脂及び加硫剤を配合してなる本発明の組成物に
よれば、収縮率が著しく小さいうえに、カーリング、裏
面状態及び抜糸強度等、耐洗）Ｕ性のすべての面におい
て総合的にすくれていることが明らかである。In particular, as seen in Examples 4 to 6, 10 to 16, and 18, the composition of the present invention in which blocked polyisocyanate, melamine resin, and vulcanizing agent are blended with latex has a remarkable shrinkage rate. In addition to being small, it is clear that it is comprehensively inferior in all aspects of curling, back surface condition, suture removal strength, and wash resistance.
特許出願人 武田薬品工業株式会社 同 ガンフ化成株式会社Patent applicant: Takeda Pharmaceutical Company Limited Ganf Kasei Co., Ltd.
Claims (3)
当りブロック化ポリイソシアネート０．５〜３０重量部
及びメラミン樹脂１〜１０重量部を含有することを特徴
とするカーペット裏打ち用組成物。(1) A carpet lining composition containing 0.5 to 30 parts by weight of a blocked polyisocyanate and 1 to 10 parts by weight of a melamine resin per 100 parts by weight of the solid content of the aqueous dispersion of a high molecular weight polymer. .
当りブロック化ポリイソシアネート０．５〜３０重量部
及び加硫剤０．５〜１０重量部を含有することを特徴と
するカーペット裏打ち用組成物。(2) A carpet backing characterized by containing 0.5 to 30 parts by weight of a blocked polyisocyanate and 0.5 to 10 parts by weight of a vulcanizing agent per 100 parts by weight of the solid content of the aqueous dispersion of a high molecular weight polymer. Composition for use.
当りブロック化ポリイソシアネート０．５〜３０重量部
、メラミン樹脂１〜１０重量部及び加硫剤０．５〜１０
重量部を含有することを特徴とするカーペット裏打ち用
組成物。(3) 0.5 to 30 parts by weight of blocked polyisocyanate, 1 to 10 parts by weight of melamine resin, and 0.5 to 10 parts by weight of vulcanizing agent per 100 parts by weight of solid content of the aqueous dispersion of high molecular weight polymer.
A carpet backing composition comprising parts by weight.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61-60256 | 1986-03-17 | ||
| JP6025686 | 1986-03-17 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6312767A true JPS6312767A (en) | 1988-01-20 |
| JPH0788623B2 JPH0788623B2 (en) | 1995-09-27 |
Family
ID=13136906
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP62056370A Expired - Fee Related JPH0788623B2 (en) | 1986-03-17 | 1987-03-11 | Dust control mat lining composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0788623B2 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| USD865514S1 (en) | 2015-11-17 | 2019-11-05 | Hunter Fan Company | Carton with color striping |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS52134660A (en) * | 1976-05-04 | 1977-11-11 | Dainippon Ink & Chem Inc | Latex-melamine resin compositions |
| JPS542499A (en) * | 1977-06-08 | 1979-01-10 | Kenji Nakamura | Treatment of toilet fibrous web |
| JPS599667A (en) * | 1982-07-09 | 1984-01-19 | Toray Ind Inc | Method for forming electrostatic latent image on electrophotographic receptor and on its photoreceptor |
-
1987
- 1987-03-11 JP JP62056370A patent/JPH0788623B2/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS52134660A (en) * | 1976-05-04 | 1977-11-11 | Dainippon Ink & Chem Inc | Latex-melamine resin compositions |
| JPS542499A (en) * | 1977-06-08 | 1979-01-10 | Kenji Nakamura | Treatment of toilet fibrous web |
| JPS599667A (en) * | 1982-07-09 | 1984-01-19 | Toray Ind Inc | Method for forming electrostatic latent image on electrophotographic receptor and on its photoreceptor |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| USD865514S1 (en) | 2015-11-17 | 2019-11-05 | Hunter Fan Company | Carton with color striping |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0788623B2 (en) | 1995-09-27 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| KR960003293B1 (en) | Compositions for carpet backings | |
| US7829637B2 (en) | Polymeric thickener for molding compounds | |
| JP2935188B2 (en) | Aqueous dispersion of urethane-acrylic polymer and method of using the same | |
| CN105121491A (en) | Water-borne polyamide-urea dispersions | |
| TWI740810B (en) | Waterborne polyamide, their chain extension with isocyanates to form cationic waterborne polyureas dispersions and process to make the same | |
| JPH06507437A (en) | One package polyurethane/thermoplastic plastisol composition | |
| CN1922231B (en) | Polyurethane dispersions and coatings made therefrom | |
| JPH06172478A (en) | Crosslinkable polyester / isocyanate composition suitable for manufacturing composite material | |
| US5025061A (en) | Aqueous dispersion coating material | |
| EP0361447B1 (en) | Process for producing a condensed resin dispersion | |
| DE1769089B2 (en) | Process for the production of, optionally microporous, shaped bodies | |
| CA2130921A1 (en) | Aqueous coating compositions | |
| CN1125840C (en) | Process for coating substrates having polar surfaces with polyurethane latexes | |
| JP2008522019A (en) | Stable thermosetting polyurethane dispersion | |
| JPS6312767A (en) | Carpet backing composition | |
| US3300431A (en) | Non-woven fabric and adhesive composition therefor | |
| KR101083817B1 (en) | Poly urethane emulsion hybrid with phase change material nanocapsules and preparing method of the same | |
| US5331051A (en) | Reaction injection molding polyurea resin composition | |
| JPS6312764A (en) | Carpet backing composition | |
| JPS6135212B2 (en) | ||
| JPH1171566A (en) | Adhesive composition, and production of board using the adhesive composition | |
| JPS59138211A (en) | Production of water-based polyurethane-acrylate resin | |
| JPS5912916A (en) | Preparation of polyol containing polymeric component | |
| JP2000044794A (en) | Polyurethane composition for coated substrate | |
| JPH093769A (en) | Treatment of aramid fiber |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| LAPS | Cancellation because of no payment of annual fees |