JPS63112797A - Papermaking size composition - Google Patents
Papermaking size compositionInfo
- Publication number
- JPS63112797A JPS63112797A JP25696786A JP25696786A JPS63112797A JP S63112797 A JPS63112797 A JP S63112797A JP 25696786 A JP25696786 A JP 25696786A JP 25696786 A JP25696786 A JP 25696786A JP S63112797 A JPS63112797 A JP S63112797A
- Authority
- JP
- Japan
- Prior art keywords
- carbon atoms
- acid
- emulsifier
- composition
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims description 26
- 239000003995 emulsifying agent Substances 0.000 claims description 25
- -1 fatty acid ester Chemical class 0.000 claims description 19
- 125000004432 carbon atom Chemical group C* 0.000 claims description 18
- 150000008064 anhydrides Chemical class 0.000 claims description 16
- 238000004513 sizing Methods 0.000 claims description 14
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 12
- 239000000194 fatty acid Substances 0.000 claims description 12
- 229930195729 fatty acid Natural products 0.000 claims description 12
- 239000003795 chemical substances by application Substances 0.000 claims description 10
- 229920001515 polyalkylene glycol Polymers 0.000 claims description 9
- 125000000217 alkyl group Chemical group 0.000 claims description 8
- 125000003342 alkenyl group Chemical group 0.000 claims description 5
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 claims description 5
- 239000000126 substance Substances 0.000 claims description 4
- 150000001733 carboxylic acid esters Chemical class 0.000 claims 1
- 239000000839 emulsion Substances 0.000 description 15
- 239000002253 acid Substances 0.000 description 9
- 230000001804 emulsifying effect Effects 0.000 description 9
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 8
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 6
- 150000004665 fatty acids Chemical class 0.000 description 6
- 239000002245 particle Substances 0.000 description 6
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 4
- 150000001336 alkenes Chemical class 0.000 description 4
- 229910000019 calcium carbonate Inorganic materials 0.000 description 4
- 150000001735 carboxylic acids Chemical class 0.000 description 4
- 238000004945 emulsification Methods 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- 239000005639 Lauric acid Substances 0.000 description 3
- 150000007513 acids Chemical class 0.000 description 3
- 229920006319 cationized starch Polymers 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
- 230000007935 neutral effect Effects 0.000 description 3
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 3
- 125000006353 oxyethylene group Chemical group 0.000 description 3
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 2
- GQEZCXVZFLOKMC-UHFFFAOYSA-N 1-hexadecene Chemical compound CCCCCCCCCCCCCCC=C GQEZCXVZFLOKMC-UHFFFAOYSA-N 0.000 description 2
- HFDVRLIODXPAHB-UHFFFAOYSA-N 1-tetradecene Chemical compound CCCCCCCCCCCCC=C HFDVRLIODXPAHB-UHFFFAOYSA-N 0.000 description 2
- ULQISTXYYBZJSJ-UHFFFAOYSA-N 12-hydroxyoctadecanoic acid Chemical compound CCCCCCC(O)CCCCCCCCCCC(O)=O ULQISTXYYBZJSJ-UHFFFAOYSA-N 0.000 description 2
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 2
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 2
- YAXXOCZAXKLLCV-UHFFFAOYSA-N 3-dodecyloxolane-2,5-dione Chemical class CCCCCCCCCCCCC1CC(=O)OC1=O YAXXOCZAXKLLCV-UHFFFAOYSA-N 0.000 description 2
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 2
- 241000251468 Actinopterygii Species 0.000 description 2
- 229920003043 Cellulose fiber Polymers 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- 239000005642 Oleic acid Substances 0.000 description 2
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical group CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical compound CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 2
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 2
- 238000005886 esterification reaction Methods 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
- VAMFXQBUQXONLZ-UHFFFAOYSA-N icos-1-ene Chemical compound CCCCCCCCCCCCCCCCCCC=C VAMFXQBUQXONLZ-UHFFFAOYSA-N 0.000 description 2
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- FBUKVWPVBMHYJY-UHFFFAOYSA-N nonanoic acid Chemical compound CCCCCCCCC(O)=O FBUKVWPVBMHYJY-UHFFFAOYSA-N 0.000 description 2
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 235000011118 potassium hydroxide Nutrition 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229950004959 sorbitan oleate Drugs 0.000 description 2
- GGQQNYXPYWCUHG-RMTFUQJTSA-N (3e,6e)-deca-3,6-diene Chemical compound CCC\C=C\C\C=C\CC GGQQNYXPYWCUHG-RMTFUQJTSA-N 0.000 description 1
- OYHQOLUKZRVURQ-NTGFUMLPSA-N (9Z,12Z)-9,10,12,13-tetratritiooctadeca-9,12-dienoic acid Chemical compound C(CCCCCCC\C(=C(/C\C(=C(/CCCCC)\[3H])\[3H])\[3H])\[3H])(=O)O OYHQOLUKZRVURQ-NTGFUMLPSA-N 0.000 description 1
- CRSBERNSMYQZNG-UHFFFAOYSA-N 1 -dodecene Natural products CCCCCCCCCCC=C CRSBERNSMYQZNG-UHFFFAOYSA-N 0.000 description 1
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 1
- 229940114072 12-hydroxystearic acid Drugs 0.000 description 1
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- 235000021357 Behenic acid Nutrition 0.000 description 1
- 239000005632 Capric acid (CAS 334-48-5) Substances 0.000 description 1
- 239000005635 Caprylic acid (CAS 124-07-2) Substances 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 239000005643 Pelargonic acid Substances 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 229920001214 Polysorbate 60 Polymers 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 1
- NWGKJDSIEKMTRX-AAZCQSIUSA-N Sorbitan monooleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O NWGKJDSIEKMTRX-AAZCQSIUSA-N 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 150000008065 acid anhydrides Chemical class 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 229940037003 alum Drugs 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 1
- ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 description 1
- 239000010425 asbestos Substances 0.000 description 1
- 229940116226 behenic acid Drugs 0.000 description 1
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 229920006317 cationic polymer Polymers 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 229940069096 dodecene Drugs 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- QIZDLUWRENVVJW-UHFFFAOYSA-N hexadec-3-ene Chemical compound CCCCCCCCCCCCC=CCC QIZDLUWRENVVJW-UHFFFAOYSA-N 0.000 description 1
- SIHWESHIQGPCBP-UHFFFAOYSA-N hexadec-4-ene Chemical compound CCCCCCCCCCCC=CCCC SIHWESHIQGPCBP-UHFFFAOYSA-N 0.000 description 1
- IIYJCOKOQWJTHO-UHFFFAOYSA-N hexadec-5-ene Chemical compound CCCCCCCCCCC=CCCCC IIYJCOKOQWJTHO-UHFFFAOYSA-N 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 150000002484 inorganic compounds Chemical class 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- 125000001972 isopentyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- YIYQJOMDMPTKEL-UHFFFAOYSA-N octadec-5-ene Chemical compound CCCCCCCCCCCCC=CCCCC YIYQJOMDMPTKEL-UHFFFAOYSA-N 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- CCCMONHAUSKTEQ-UHFFFAOYSA-N octadecene Natural products CCCCCCCCCCCCCCCCC=C CCCMONHAUSKTEQ-UHFFFAOYSA-N 0.000 description 1
- 229960002446 octanoic acid Drugs 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 239000001254 oxidized starch Substances 0.000 description 1
- 235000013808 oxidized starch Nutrition 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000011505 plaster Substances 0.000 description 1
- ONJQDTZCDSESIW-UHFFFAOYSA-N polidocanol Chemical compound CCCCCCCCCCCCOCCOCCOCCOCCOCCOCCOCCOCCOCCO ONJQDTZCDSESIW-UHFFFAOYSA-N 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 229920001083 polybutene Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 1
- 229920002717 polyvinylpyridine Polymers 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229910052895 riebeckite Inorganic materials 0.000 description 1
- 230000005476 size effect Effects 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 229910001388 sodium aluminate Inorganic materials 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- 229940095068 tetradecene Drugs 0.000 description 1
- 235000010215 titanium dioxide Nutrition 0.000 description 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 238000011179 visual inspection Methods 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Landscapes
- Polyethers (AREA)
- Paper (AREA)
Abstract
(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。(57) [Abstract] This bulletin contains application data before electronic filing, so abstract data is not recorded.
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明の組成物は、アルケニルコハク酸無水物とその乳
化剤としてのアルコキシ化ポリアルキレングリコールの
ＩＩＲ肪酸エステルからなり中性ないしは弱アルカリ性
の抄造条件で使用される製紙用サイズ剤組成物に関する
。Detailed Description of the Invention [Industrial Field of Application] The composition of the present invention is composed of an alkenylsuccinic anhydride and an IIR fatty acid ester of an alkoxylated polyalkylene glycol as an emulsifier, and is a neutral or weakly alkaline paper-forming material. The present invention relates to a papermaking sizing agent composition used under certain conditions.
更に詳しくは、アルケニルコハク酸無水物と乳化剤を長
期間共存させても経時によって変化せず、使用の際には
、優れた乳化物を生成しこれを紙料に添加することによ
り、紙のサイジング処理を良好に行うことができる製紙
用中性サイズ剤組成物に関するものである。More specifically, even when alkenylsuccinic anhydride and an emulsifier coexist for a long period of time, they do not change over time, and when used, an excellent emulsion is generated and added to the paper stock, which can be used to improve paper sizing. The present invention relates to a neutral sizing agent composition for paper manufacturing that can be processed well.
中性抄紙法で添料として炭酸カルシウムを使用する場合
の内添サイズ剤として、セルロース繊維のヒドロキシル
基と共有結合するアルケニルコハク酸無水物は、通常水
性エマルジョンの形で紙料に添加される。水性エマルジ
ョン化を行う場合、乳化剤として、水溶性ポリマー（カ
チオン化澱粉、酸化澱粉、カルボキシメチルセルロース
、ポリビニールアルコールなど）界面活性剤〔ポリオキ
シエチレン（以下ＰＯＥと書く）アルキルエーテル、Ｐ
ＯＥアルキルアリルエーテル、ＰＯＥソルビタンオレエ
ート〕などの乳化剤を使用し、高速ミキサー、高圧ホモ
ジナイザーなどの乳化装置を用い水中で強制的に乳化す
ることによって行われている。As an internal sizing agent when calcium carbonate is used as an additive in neutral papermaking processes, alkenylsuccinic anhydride, which covalently bonds to the hydroxyl groups of cellulose fibers, is usually added to the paper stock in the form of an aqueous emulsion. When making an aqueous emulsion, water-soluble polymers (cationized starch, oxidized starch, carboxymethyl cellulose, polyvinyl alcohol, etc.), surfactants [polyoxyethylene (hereinafter referred to as POE), alkyl ethers, P
Emulsifiers such as OE alkyl allyl ether and POE sorbitan oleate are used, and emulsification is forcibly carried out in water using an emulsifying device such as a high-speed mixer or a high-pressure homogenizer.
しかしながら、これらの乳化剤とアルケニルコハク酸無
水物とを混和したままでは、数時間でサイズが低下して
しまい、混和後は速やかに使用しなければならない欠点
を有する。However, if these emulsifiers and alkenylsuccinic anhydride are mixed together, the size decreases in a few hours, and the problem is that the emulsifier must be used immediately after mixing.
本発明者等は上記欠点の改良されたサイズ剤を得るべく
鋭意検討の結果、本発明に到達したものである。The present inventors have arrived at the present invention as a result of intensive studies to obtain a sizing agent that has improved the above-mentioned drawbacks.
即ち１本発明は、アルケニルコハク酸無水物と乳化剤を
混合したサイズ剤組成物を、長時間、例えば−年間の長
期にわたり保存しても密閉された状態であれば、乳化機
能を維持し、使用時均−且つ装定な良好なエマルジョン
を生成し、紙料に添加することにより、良好なサイズが
得られる組成物で、アルケニルコハク酸無水物に乳化剤
として下記一般式に示すアルコキシ化ポリアルキレング
リコールの脂肪酸エステル
ＣＨ。That is, 1. The present invention provides that even if a sizing composition containing an alkenylsuccinic anhydride and an emulsifier is stored for a long period of time, for example, for a year, if it is kept in an airtight state, the emulsifying function is maintained and the composition can be used easily. It is a composition that produces a good emulsion in a timely and consistent manner, and when added to paper stock, a good size can be obtained.The alkoxylated polyalkylene glycol represented by the following general formula is used as an emulsifier in alkenylsuccinic anhydride. Fatty acid ester CH.
■
ＲＯ（ＣＨ，ＣＨ，○）Ｑ（ＣＨ，−ＣＨｏ）ｒｎＯｃ
Ｒ。■ RO(CH,CH,○)Q(CH,-CHO)rnOc
R.
（但し、Ｒは炭素数１〜６のアルキル基、シクロヘキシ
ル基、Ｒ１は炭素数８以上のアルキル基。(However, R is an alkyl group having 1 to 6 carbon atoms or a cyclohexyl group, and R1 is an alkyl group having 8 or more carbon atoms.
Ｑは４〜６ｏの整数１ｍは○、もしくは１〜１゜の整数
で、１２十ｍが５〜７０の整数）を含有させることによ
り得られる。Q is an integer of 4 to 6o, 1m is a circle, or an integer of 1 to 1°, and 120m is an integer of 5 to 70).
本発明におけるアルケニルコハク酸無水物は、二重結合
を末端ないしは内部に有する直鎖状または分岐状オレフ
ィンと、無水マレイン酸との反応により容易に得られる
。これらのオレフィンとしては、α−オレフィン、異性
化した内部オレフィン例えば、ドデセン、テトラデセン
、ヘキサデセン、オクタデセン、エイコセン等の直鎖オ
レフィン、１−メチル−２ペンタデセン、１−エチル−
２−テトラデセン、１−プロピル−２−トリデセン、ｌ
−プロピル−２−ペンタデセン等の分岐オレフィン、プ
ロピレン、ブチレン、イソブチン、ブテンなどの単量体
から得られるポリプロピレン、ポリブテン、ポリイソブ
チン、などのオリゴマーがある。The alkenylsuccinic anhydride in the present invention can be easily obtained by reacting a linear or branched olefin having a terminal or internal double bond with maleic anhydride. These olefins include α-olefins, isomerized internal olefins such as linear olefins such as dodecene, tetradecene, hexadecene, octadecene, and eicosene, 1-methyl-2pentadecene, 1-ethyl-
2-tetradecene, 1-propyl-2-tridecene, l
- Branched olefins such as propyl-2-pentadecene, and oligomers such as polypropylene, polybutene, and polyisobutyne obtained from monomers such as propylene, butylene, isobutyne, and butene.
これらのうち炭素数１２以上、特に炭素数１５以上のア
ルケニル基を有するアルケニルコハク酸無水物が好まし
い、アルケニル基の炭素数が２４を越えると、高粘度に
よる流動性の低下などのハンドリングの面の不便が生ず
る。乳化剤として一般式に示すアルコキシ化ポリアルキ
レングリコールの脂肪酸エステルは、アルコキシ化ポリ
アルキレングリコールと脂肪酸との通常のエステル化反
応を行うことにより容易に得られる。Among these, alkenyl succinic anhydrides having an alkenyl group having 12 or more carbon atoms, particularly 15 or more carbon atoms, are preferred.If the alkenyl group has more than 24 carbon atoms, handling problems such as decreased fluidity due to high viscosity are preferred. This causes inconvenience. A fatty acid ester of an alkoxylated polyalkylene glycol represented by the general formula as an emulsifier can be easily obtained by carrying out a conventional esterification reaction between an alkoxylated polyalkylene glycol and a fatty acid.
一般式におけるＲは炭素数１〜６のアルキル基、シクロ
ヘキシル基であるが、これらのアルキル基を有するアル
コールとしては、メチル、エチル、プロピル、イソプロ
ピル、ブチル、イソブチル、ターシャリ−ブチル、アミ
ル、イソアミル、ヘキシル、シクロヘキシル、などの各
アルコールがある。R in the general formula is an alkyl group having 1 to 6 carbon atoms or a cyclohexyl group, and alcohols having these alkyl groups include methyl, ethyl, propyl, isopropyl, butyl, isobutyl, tert-butyl, amyl, isoamyl, There are various alcohols such as hexyl and cyclohexyl.
良好な乳化性能を得るためには、Ｒ１とのバランスが重
要であるが、炭素数６以下がＩＩＴましく。In order to obtain good emulsifying performance, the balance with R1 is important, and IIT is preferably 6 or less carbon atoms.
そのうちでも、１〜３が最も好ましい。Among them, 1 to 3 are most preferred.
ＣＨ。CH.
（ＣＨ，ＣＨＯ）は、オキシプロピレン基を示し、乳化
剤の低温での流動性及び、乳化性の面で（ＣＨ，ＣＨ，
Ｏ）単独の場合よりも好ましい場合がある。（ＣＨ，Ｃ
Ｈ，Ｏ）はオキシエチレン基を示す、Ｑは４〜６０の整
数であるが、乳化性からは、８〜３０、悲及びｍはΩ＝
０、もしくは、Ｑ十ｍ＝１０〜３０、この場合、Ｑ／ｍ
＝９／１〜８／２の範囲が好ましい。オ印ジプロピレン
、オキシエチレン基はブロック及びランダム、いづれで
もよい。(CH, CHO) represents an oxypropylene group, and (CH, CH,
O) It may be more preferable than the case alone. (CH,C
H, O) represents an oxyethylene group, Q is an integer from 4 to 60, but in terms of emulsifying properties, 8 to 30, and m and Ω =
0, or Q0m=10~30, in this case, Q/m
The range of =9/1 to 8/2 is preferable. The dipropylene and oxyethylene groups may be either block or random.
Ｒ１は炭素数８以上の脂肪酸残基（カルボン酸の示性式
より一〇〇ＯＨを除いた部分）でこれに相当するカルボ
ン酸としては、オクチル酸、ソニック酸、ペラルゴン酸
、カプリル酸、カプリン酸。R1 is a fatty acid residue having 8 or more carbon atoms (the part obtained by removing 100OH from the carboxylic acid formula), and the corresponding carboxylic acids include octylic acid, sonic acid, pelargonic acid, caprylic acid, and capric acid. acid.
ラウリン酸、ミリスチン酸、バルミチル酸、ステアリン
酸、イソステアリン酸、１２−ヒドロキシステアリン酸
、オレイン酸、リノール酸、リルン酸、ワシルイン酸、
ベヘニン酸及び炭素数８以上の合成カルボン酸等がある
。良好な乳化性を得るためには、炭素数１２現上のカル
ボン酸が好ましく、液状のオレイン酸が取り扱いやすく
、また良好である。Lauric acid, myristic acid, balmicylic acid, stearic acid, isostearic acid, 12-hydroxystearic acid, oleic acid, linoleic acid, linuric acid, wasillic acid,
Examples include behenic acid and synthetic carboxylic acids having 8 or more carbon atoms. In order to obtain good emulsifying properties, carboxylic acids with 12 carbon atoms are preferred, and liquid oleic acid is easy to handle and is also good.
本発明では、アルケニルコハク酸無水物の安定で良好な
乳化剤としてアルコキシ化ポリアルキレングリコールの
脂肪酸エステルを挙でいるが、中性抄紙法で提示されて
いる脂肪酸無水物、例えば無水ステアリン酸、無水パル
ミチン酸等の脂肪酸無水物に対しても、同様の添加量、
同様の処方で優れた乳化性能を示す、また、本発明で用
いる脂肪酸の替りに、他のカルボン酸、例えば、アルキ
ルベンゼンカルボン酸、アルキルナフタレンカルボン酸
、などを用いても、良好な乳化剤が得られるが、脂肪酸
を用いることに比較して経済的に不利である。In the present invention, fatty acid esters of alkoxylated polyalkylene glycols are mentioned as stable and good emulsifiers for alkenylsuccinic anhydrides. For fatty acid anhydrides such as acids, the same amount of addition,
A similar formulation shows excellent emulsifying performance, and good emulsifiers can also be obtained by using other carboxylic acids, such as alkylbenzenecarboxylic acids and alkylnaphthalenecarboxylic acids, in place of the fatty acids used in the present invention. However, it is economically disadvantageous compared to using fatty acids.
一般式の乳化剤は、少量の未反応物を除き、○Ｈ基を分
子内に持たないため、酸無水物とこれらの乳化剤の混合
物を長時間放置しても、反応せず、安定で、したがって
、いつでも簡単な攪拌操作で良好安定なエマルジョンを
作る二とができる。Emulsifiers of the general formula do not have ○H groups in their molecules, except for a small amount of unreacted substances, so even if a mixture of acid anhydride and these emulsifiers is left for a long time, it does not react and is stable. It is possible to make a good and stable emulsion at any time with a simple stirring operation.
アルケニルコハク酸無水物に対する乳化剤の添加量は通
常アルケニルコハク酸無水物と乳化剤のトータルの１〜
２０重量％好ましくは、２〜１０重量％である。添加量
が２重量％以下の場合は、良好な乳化物をえがたい。ま
た２０重量％をこえると乳化は極めて良好であるがサイ
ズ性能が大巾に低下する。The amount of emulsifier added to the alkenylsuccinic anhydride is usually 1 to 1 to the total of the alkenylsuccinic anhydride and the emulsifier.
20% by weight, preferably 2-10% by weight. If the amount added is less than 2% by weight, it is difficult to obtain a good emulsion. Moreover, if it exceeds 20% by weight, emulsification is extremely good, but the size performance is greatly reduced.
アルケニルコハク酸無水物を乳化剤で、乳化する場合は
両者を均一に混合し、混合物を水中に分散させる方法、
乳化剤を水に分散させ、それにアルケニルコハク酸無水
物を加え乳化させる方法があるが、前者の方法が、最も
簡単で、しかも最も少い乳化剤量で、粒子径の小さな乳
化物が得られ、サイズ効果も高い、乳化は通常の攪拌操
作で可能である。When emulsifying alkenylsuccinic anhydride with an emulsifier, a method of uniformly mixing the two and dispersing the mixture in water;
There is a method of dispersing an emulsifier in water and adding alkenylsuccinic anhydride to it to emulsify it, but the former method is the simplest, uses the least amount of emulsifier, and produces an emulsion with a small particle size. It is highly effective, and emulsification can be achieved by ordinary stirring operations.
本発明の組成物に他の内添サイズ剤、たとえばロジン、
石油樹脂、アルキルケテンニ量体、パラフィンワックス
、脂肪酸無水物などを併用してもよい。本発明の組成物
を使用して、製紙を行うに際しサイズ剤をパルプに定着
させるために、下記の如き種々のカチオン性物質が用い
られる。ミョウバン、塩化アルミニウム、アルミン酸ナ
トリウム。Other internal sizing agents may be added to the composition of the present invention, such as rosin,
Petroleum resins, alkyl ketene dimers, paraffin wax, fatty acid anhydrides, and the like may be used in combination. When the composition of the present invention is used to make paper, various cationic substances as described below are used to fix the sizing agent to the pulp. Alum, aluminum chloride, sodium aluminate.
硫酸アルミニウムなどの多価金属型の無機化合物。Inorganic compounds of the polyvalent metal type, such as aluminum sulfate.
種々のカチオン化澱粉、ポリアミンポリアミド−エピク
ロルヒドリン樹脂、ジアリルハロゲン化物の環化重合体
、ポリビニールピリジン、種々のカチオン化ポリアクリ
ルアミドなどのカチオン性ポリマー等である。These include cationic polymers such as various cationized starches, polyamine polyamide-epichlorohydrin resins, cyclized polymers of diallyl halides, polyvinyl pyridine, and various cationized polyacrylamides.
本組成物は製紙用に用いられるが、セルロース繊維のヒ
ドロキシル基と共有結合をすることにより。The composition is used for papermaking by covalently bonding with the hydroxyl groups of cellulose fibers.
サイズ効果を発揮することから、セルロース物質を１０
％以上含有する材質に対し有効である。Due to its size effect, cellulose material is
It is effective for materials containing more than %.
材質上、セルロースとの組合せはアスベスト、ガラス、
合成樹脂（ポリエステル、ポリアミド、ポリアクリロニ
トリル、ポリスチレン、ポリエチレン、ポリプロピレン
）など多岐にわたる種々のケースがある。Due to the material, combinations with cellulose include asbestos, glass,
There are a wide variety of cases including synthetic resins (polyester, polyamide, polyacrylonitrile, polystyrene, polyethylene, polypropylene).
本組成物のパルプに対する使用量は得ようとする最終紙
製品によって左右されるが、通常パルプの乾燥重量に対
し０．０５〜５％の範囲で用いることができる。The amount of the composition to be used in the pulp depends on the final paper product to be obtained, but it can generally be used in the range of 0.05 to 5% based on the dry weight of the pulp.
本組成物は、パルプが、ヘッドボックス、ビータ−、ハ
イドロパルパーまたはストックチェスト中にある間にパ
ルプに加えることができる。The composition can be added to the pulp while it is in the headbox, beater, hydropulper or stock chest.
本組成物でサイズされる紙には種々の顔料及び充填剤を
含有させることが出来る。たとえば、炭酸カルシウム、
タルク、チタン白、白土、石膏などが挙られる。Paper sized with the present compositions can contain various pigments and fillers. For example, calcium carbonate,
Examples include talc, titanium white, white clay, and plaster.
以下実施例により、本発明を更に詳しく説明するが、本
発明はこれらの実施例に限定されるものではない。The present invention will be explained in more detail with reference to Examples below, but the present invention is not limited to these Examples.
実施例１
ブタノールにエチレンオキサイドを２０モル、プロピレ
ンオキサイドを２モルランダムに付加したブトキシポリ
アルキレングリコール５９０ｆｉｆｉ部工業用ラウリン
酸１００重量部、フレーク苛性カリ２重量部を温度計、
コンデンサー、窒素導入管、攪拌機をセットした四ツロ
フラスコに仕込み、窒素を導入しながら２３０℃で８時
間、脱水エステル化反応を行い、酸価２のブトキシポリ
アルキレングリコールのラウリン酸エステルを得た。工
業用リン酸で、苛性カリ触媒を中和、濾過して乳化剤を
得た（これを乳化剤 胤ｌとする）、この乳化剤を炭素
数１５〜２０の直鎖内部オレフィンから得られたアルケ
ニルコハク酸無水物中に５重量％配合しこれを水に加え
実験用スターラーで攪拌希釈し、重量％のエマルジョン
を得た。目視で良好なエマルジョンが得られた６コール
ターカウンターで粒子径を測定マたところ粒子径は１〜
２μであった。またこのエマルジョンを室温で１２＃間
放置し安定性を観察したが均一安定であった。Example 1 590 fifi parts of butoxypolyalkylene glycol prepared by randomly adding 20 moles of ethylene oxide and 2 moles of propylene oxide to butanol, 100 parts by weight of industrial lauric acid, and 2 parts by weight of flaked caustic potash were mixed with a thermometer,
The mixture was placed in a four-way flask equipped with a condenser, a nitrogen inlet tube, and a stirrer, and a dehydration esterification reaction was carried out at 230° C. for 8 hours while introducing nitrogen to obtain a lauric acid ester of butoxypolyalkylene glycol with an acid value of 2. An emulsifier was obtained by neutralizing the caustic potash catalyst with industrial phosphoric acid and filtering it (this is referred to as the emulsifier). A 5% by weight emulsion was added to water and stirred and diluted using a laboratory stirrer to obtain a 5% by weight emulsion. A good emulsion was obtained by visual inspection.The particle size was measured using a Coulter counter.The particle size was 1~
It was 2μ. Further, this emulsion was left at room temperature for 12 days and its stability was observed, and it was found to be uniform and stable.
また、炭素数１５〜２ｏのアルケニルコハク酸無水物に
乳化剤ｆｆ１ｌを５重量％配分した組成物を５０℃の恒
温槽で１週間熱処理し処理前後の乳化性をテストしたが
良好で変化がなかった。更に炭素数Ｃｉ ａ〜Ｃ８，の
アルケニルコハク酸無水物に乳化剤患ｌを５重量％配合
した組成物の、５０℃。In addition, a composition in which 5% by weight of emulsifier ff1 was distributed to alkenylsuccinic anhydride having 15 to 2 carbon atoms was heat-treated in a constant temperature bath at 50°C for one week, and the emulsifying properties before and after the treatment were tested, and the result was good with no change. . Further, a composition containing an alkenylsuccinic anhydride having a carbon number of Cia to C8 and an emulsifier (5% by weight) was heated at 50°C.
１週間経時後のサンプルを用い炭酸カルシウムを添料と
する紙の内添サイズ剤として対乾燥バルブ当り、０．２
％の添加量で抄紙、サイズ性能をステキヒトサイズ度［
ＪＩＳ Ｐ−８１２２（’５４）コで比佼した。その
結果を表２に示す。Using a sample after one week aging, 0.2 per dry bulb was added as an internal sizing agent for paper containing calcium carbonate as an additive.
Paper making and size performance can be improved by adding % to Steckigt size degree [
It was compared with JIS P-8122 ('54). The results are shown in Table 2.
実施例、２〜７と比較例１〜４
実施例１と同様の方法で合成した乳化剤Ｎ１１Ｌ２〜隘
７（表１）を炭素数１５〜２０のアルケニルコハク酸無
水物に５重量％配合し、５０℃、１週間の経時テストを
行った。これを水に加え実験用スターラーで攪拌し１重
量％のエマルジョンを作成した。Examples, 2 to 7 and Comparative Examples 1 to 4 5% by weight of emulsifiers N11L2 to 7 (Table 1) synthesized in the same manner as in Example 1 were blended with alkenylsuccinic anhydride having 15 to 20 carbon atoms, A time-lapse test was conducted at 50°C for one week. This was added to water and stirred with a laboratory stirrer to prepare a 1% by weight emulsion.
このエマルジョンの目視での乳化性、コールタ−カウン
ターでの粒径の測定、室温での乳化安定性（１０時間）
、対バルブ０．２％濃度でのサイズ性能（ステキヒトサ
イズ度１秒）を測定した。同時に比較品についても行っ
た（比較例１〜４）結果を表２に示す。Visual emulsifying property of this emulsion, measurement of particle size with Coulter counter, emulsion stability at room temperature (10 hours)
The size performance (Steckicht size degree 1 second) was measured at a concentration of 0.2% relative to the valve. At the same time, comparative products were also tested (Comparative Examples 1 to 4), and the results are shown in Table 2.
表１．供試乳化Ｍ（患２〜魚７）
表１中のＲ１Ω、 ｍ、 Ｒ，は下記一般式中のＲｌＱ
、ｍ、Ｒ，に相当する。Table 1. Test emulsion M (affected fish 2 to fish 7) R1Ω, m, R, in Table 1 are RlQ in the general formula below.
,m,R,.
ＣＨ。CH.
Ｒ○（ＣＨ，ＣＨ，○）Ｑ（ＣＨ，−ＣＨＯ）ｍＯｃＲ
。R○(CH,CH,○)Q(CH,-CHO)mOcR
.
表２．乳化（安定）性及びサイズ度
比較例の乳化剤
１、ＰＯＥＮＰ＋ ポリ（１０）オキシエチレンノニ
ルフェニールエーテル
２、ＰＯＥＳＯ： ポリ（１４）オキシエチレンソル
ビタンオレエート
３、ＰＯＥＬＥ： ポリ（１０）オキシエチレンラウ
ルエーテル
４、ＰＯＥＬＡ： ポリ（８）オキシエチレンラウリ
ルアマイド
抄紙条件
バルブ： ＬＢＫＰ １００％
ＣＦＳ＝４００
坪 量 ： ７０ｇ／ｒｒｒ、 灰分２
０％填 料 ： 軽質炭酸カルシウム
サイズ剤 ＝ ０．２％対バルブ［サイズ剤ｌカチオン
化澱粉（Ｃａｔｏ １５）＝１７２コパルプー濃度 ：
１％スラリー
硫酸バンド ： ０．５％対バルブ
抄紙温度 ＝ ２０〜２５℃
抄 紙 機 ： タツビ式スタンダードシートマシーン
乾 燥 ： １１０℃×２分以上の実施例か
ら、本発明のサイズ剤組成物が安定で、良好なサイズ性
能を発揮することがわかる。Table 2. Emulsifier 1 of emulsification (stability) and size comparison example, POENP+ poly(10) oxyethylene nonyl phenyl ether 2, POESO: poly(14) oxyethylene sorbitan oleate 3, POELE: poly(10) oxyethylene laur ether 4 , POELA: Poly(8) oxyethylene laurylamide Paper making conditions Valve: LBKP 100% CFS=400 tsubo Weight: 70g/rrr, Ash content 2
0% filler: light calcium carbonate sizing agent = 0.2% to valve [sizing agent l cationized starch (Cato 15) = 172 Coparpoum concentration:
1% slurry sulfuric acid band: 0.5% vs. valve paper making temperature = 20-25°C Paper machine: Tatsubi type standard sheet machine Drying: 110°C x 2 minutes or more From the examples, it was found that the sizing composition of the present invention It can be seen that it is stable and exhibits good size performance.
出願人 東邦化学工業株式会社
特許庁長官 黒 １）明 雄 殿
１、事件の表示
昭和６１年特許願第 ２５６９６７号
２、発明の名称
３、補正をする者
事件との関係 特許出願人
４、補正の対象
明細書の「特許請求の範囲」の欄及び「発明の詳細な説
明」の欄 。Applicant Toho Chemical Industry Co., Ltd. Commissioner of the Patent Office Kuro 1) Yu Akira 1, Indication of the case Patent Application No. 256967 of 1988 2, Title of the invention 3, Person making the amendment Relationship with the case Patent applicant 4, Amendment ``Claims'' column and ``Detailed Description of the Invention'' column of the subject specification.
６、補正の内容 （１）特許請求の範囲 別紙のとうり （２）発明の詳細な説明の欄 ｉ）明細書第８ページ５行目の 「１〜２０重量％好ましくは」を 「１〜２０重量％、好ましくは」 と訂正する。6. Contents of amendment (1) Scope of claims Attachment details (2) Column for detailed description of the invention i) Line 5 of page 8 of the specification "1 to 20% by weight preferably" "1 to 20% by weight, preferably" I am corrected.
ｉｔ ）同第１０ページ２行目の
「乾燥重量に対し０．０５〜５％の」を［乾燥重量に対
し０．０１〜５％の」
と訂正する。it) Correct "0.05 to 5% of the dry weight" in the second line of page 10 to "0.01 to 5% of the dry weight."
市）同第１１ページ９〜１０行目の ｆ攪拌希釈し、 重量％の」を 「攪拌希釈し、１重量％の」 と訂正する。City) page 11, lines 9-10 f Stir to dilute and add % by weight. "Stir and dilute to 1% by weight." I am corrected.
ｉｖ）同第１１ページ１２行目の 「粒子径を測定マたところ」を 「粒子径を測定したところ」 と訂正する。iv) Page 11, line 12 ``Where the particle size was measured'' "Measurement of particle size" I am corrected.
別紙
特許請求の範囲
（１）アルケニルコハク酸無水物と乳化剤としてアルコ
キシ化ポリアルキレングリコールの脂肪酸エステルを含
有してなる製紙用サイズ剤組成物（２）アルケニル基の
炭素数が１２以上である特許請求の範囲第１項記載の組
成物。Attached Claims (1) A paper sizing composition comprising an alkenylsuccinic anhydride and a fatty acid ester of alkoxylated polyalkylene glycol as an emulsifier (2) A patent claim in which the alkenyl group has 12 or more carbon atoms The composition according to item 1.
（３）アルコキシ化ポリアルキレングリコールの脂肪酸
エステルが一般式
％式％
［但し、Ｒは炭素数１〜６のアルキル基、シクロヘキシ
ル基、Ｒ３は炭素数８臭上のアルキル基、アルケニル基
、Ｑは４〜６０の整数、ｍはＯもしくは１〜１０の整数
でｆｌ＋ｍが５〜７０の整数］で示される特許請求の範
囲第１項記載の組成物。(3) Fatty acid ester of alkoxylated polyalkylene glycol has the general formula % [However, R is an alkyl group having 1 to 6 carbon atoms or a cyclohexyl group, R3 is an alkyl group having 8 carbon atoms or an alkenyl group, and Q is The composition according to claim 1, wherein m is O or an integer of 1 to 10, and fl+m is an integer of 5 to 70.
Claims (3)
キシ化ポリアルキレングリコールの脂肪酸エステルを含
有してなる製紙用サイズ剤組成物。(1) A paper sizing agent composition comprising alkenylsuccinic anhydride and a fatty acid ester of alkoxylated polyalkylene glycol as an emulsifier.
範囲第一項記載の組成物。(2) The composition according to claim 1, wherein the alkenyl group has 12 or more carbon atoms.
ン酸エステルが一般式 ▲数式、化学式、表等があります▼ 〔但し、Ｒは炭素数１〜６のアルキル基：シクロヘキシ
ル基、Ｒ＿１は炭素数８以下のアルキル基、アルケニル
基、ｌは４〜６０の整数、ｍは０もしくは１〜１０の整
数でｌ＋ｍが５〜７０の整数〕で示される特許請求の範
囲第一項記載の組成物。(3) Carboxylic acid ester of alkoxylated polyalkylene glycol has the general formula ▲ Numerical formula, chemical formula, table, etc. ▼ [However, R is an alkyl group with 1 to 6 carbon atoms: cyclohexyl group, R_1 is an alkyl group with 8 or less carbon atoms The composition according to claim 1, wherein l is an integer of 4 to 60, m is 0 or an integer of 1 to 10, and l+m is an integer of 5 to 70.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP25696786A JPS63112797A (en) | 1986-10-30 | 1986-10-30 | Papermaking size composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP25696786A JPS63112797A (en) | 1986-10-30 | 1986-10-30 | Papermaking size composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS63112797A true JPS63112797A (en) | 1988-05-17 |
Family
ID=17299858
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP25696786A Pending JPS63112797A (en) | 1986-10-30 | 1986-10-30 | Papermaking size composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS63112797A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005187415A (en) * | 2003-12-26 | 2005-07-14 | Lion Corp | Fatty acid polyoxyalkylenealkyl ether and method for producing the same |
| WO2012144233A1 (en) * | 2011-04-21 | 2012-10-26 | 星光Pmc株式会社 | Sizing agent composition, paper making process, and process for producing paperboard |
| KR20160019501A (en) * | 2013-06-13 | 2016-02-19 | 에코랍 유에스에이 인코퍼레이티드 | Water-free surface sizing composition and method for treating a paper substrate with same |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS58220897A (en) * | 1982-06-11 | 1983-12-22 | 三洋化成工業株式会社 | Papermaking size agent |
| JPS6034697A (en) * | 1983-08-04 | 1985-02-22 | 荒川化学工業株式会社 | Self-emulsifiable size composition |
| JPS6128098A (en) * | 1984-07-13 | 1986-02-07 | 出光石油化学株式会社 | Size composition |
-
1986
- 1986-10-30 JP JP25696786A patent/JPS63112797A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS58220897A (en) * | 1982-06-11 | 1983-12-22 | 三洋化成工業株式会社 | Papermaking size agent |
| JPS6034697A (en) * | 1983-08-04 | 1985-02-22 | 荒川化学工業株式会社 | Self-emulsifiable size composition |
| JPS6128098A (en) * | 1984-07-13 | 1986-02-07 | 出光石油化学株式会社 | Size composition |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005187415A (en) * | 2003-12-26 | 2005-07-14 | Lion Corp | Fatty acid polyoxyalkylenealkyl ether and method for producing the same |
| WO2012144233A1 (en) * | 2011-04-21 | 2012-10-26 | 星光Pmc株式会社 | Sizing agent composition, paper making process, and process for producing paperboard |
| JP5408560B2 (en) * | 2011-04-21 | 2014-02-05 | 星光Ｐｍｃ株式会社 | Sizing composition, papermaking method, and board manufacturing method |
| KR20160019501A (en) * | 2013-06-13 | 2016-02-19 | 에코랍 유에스에이 인코퍼레이티드 | Water-free surface sizing composition and method for treating a paper substrate with same |
| EP3008241A4 (en) * | 2013-06-13 | 2017-01-11 | Ecolab USA Inc. | Water-free surface sizing composition and method for treating a paper substrate with same |
| US10745862B2 (en) | 2013-06-13 | 2020-08-18 | Ecolab Usa Inc. | Water-free surface sizing composition and method for treating a paper substrate with same |
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