JPS6286096A - Lubricant for plastic working - Google Patents
Lubricant for plastic workingInfo
- Publication number
- JPS6286096A JPS6286096A JP22693785A JP22693785A JPS6286096A JP S6286096 A JPS6286096 A JP S6286096A JP 22693785 A JP22693785 A JP 22693785A JP 22693785 A JP22693785 A JP 22693785A JP S6286096 A JPS6286096 A JP S6286096A
- Authority
- JP
- Japan
- Prior art keywords
- oil
- lubricant
- lubricating
- component
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000314 lubricant Substances 0.000 title claims abstract description 23
- 239000004033 plastic Substances 0.000 title claims description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims abstract description 22
- 239000000126 substance Substances 0.000 claims abstract description 11
- 230000001050 lubricating effect Effects 0.000 claims abstract description 10
- 239000003921 oil Substances 0.000 claims abstract description 10
- 239000002480 mineral oil Substances 0.000 claims abstract description 6
- 150000001412 amines Chemical class 0.000 claims abstract description 5
- 239000010689 synthetic lubricating oil Substances 0.000 claims abstract description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 5
- 150000008044 alkali metal hydroxides Chemical class 0.000 claims abstract description 3
- 235000011007 phosphoric acid Nutrition 0.000 claims abstract 3
- 235000010446 mineral oil Nutrition 0.000 claims description 5
- 239000003513 alkali Substances 0.000 claims description 2
- 150000004649 carbonic acid derivatives Chemical class 0.000 claims 1
- 229910052751 metal Inorganic materials 0.000 claims 1
- 239000002184 metal Substances 0.000 claims 1
- 229910019142 PO4 Inorganic materials 0.000 abstract description 8
- 239000010452 phosphate Substances 0.000 abstract description 8
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 abstract description 8
- 239000003925 fat Substances 0.000 abstract description 5
- -1 KOH) Chemical class 0.000 abstract description 4
- 238000002156 mixing Methods 0.000 abstract description 3
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 abstract description 2
- 229910000288 alkali metal carbonate Inorganic materials 0.000 abstract description 2
- 150000008041 alkali metal carbonates Chemical class 0.000 abstract description 2
- 239000003093 cationic surfactant Substances 0.000 abstract description 2
- 239000010779 crude oil Substances 0.000 abstract description 2
- 239000002736 nonionic surfactant Substances 0.000 abstract description 2
- 239000003208 petroleum Substances 0.000 abstract description 2
- 238000007670 refining Methods 0.000 abstract description 2
- WBHHMMIMDMUBKC-XLNAKTSKSA-N ricinelaidic acid Chemical compound CCCCCC[C@@H](O)C\C=C\CCCCCCCC(O)=O WBHHMMIMDMUBKC-XLNAKTSKSA-N 0.000 abstract description 2
- 229960003656 ricinoleic acid Drugs 0.000 abstract description 2
- FEUQNCSVHBHROZ-UHFFFAOYSA-N ricinoleic acid Natural products CCCCCCC(O[Si](C)(C)C)CC=CCCCCCCCC(=O)OC FEUQNCSVHBHROZ-UHFFFAOYSA-N 0.000 abstract description 2
- XLYOFNOQVPJJNP-DYCDLGHISA-N deuterium hydrogen oxide Chemical compound [2H]O XLYOFNOQVPJJNP-DYCDLGHISA-N 0.000 abstract 1
- 230000003472 neutralizing effect Effects 0.000 abstract 1
- 239000000463 material Substances 0.000 description 11
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 8
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- 235000019198 oils Nutrition 0.000 description 6
- 235000014113 dietary fatty acids Nutrition 0.000 description 5
- 239000000194 fatty acid Substances 0.000 description 5
- 229930195729 fatty acid Natural products 0.000 description 5
- 150000004665 fatty acids Chemical class 0.000 description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 150000002148 esters Chemical class 0.000 description 4
- 235000019197 fats Nutrition 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- BLFRQYKZFKYQLO-UHFFFAOYSA-N 4-aminobutan-1-ol Chemical group NCCCCO BLFRQYKZFKYQLO-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 229910000831 Steel Inorganic materials 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- GSGDTSDELPUTKU-UHFFFAOYSA-N nonoxybenzene Chemical compound CCCCCCCCCOC1=CC=CC=C1 GSGDTSDELPUTKU-UHFFFAOYSA-N 0.000 description 3
- 239000010959 steel Substances 0.000 description 3
- QUSNBJAOOMFDIB-UHFFFAOYSA-N Ethylamine Chemical compound CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- 235000019484 Rapeseed oil Nutrition 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 238000010306 acid treatment Methods 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 150000001340 alkali metals Chemical class 0.000 description 2
- 150000003973 alkyl amines Chemical class 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 235000015278 beef Nutrition 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 2
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000010721 machine oil Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 2
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 2
- 150000003014 phosphoric acid esters Chemical class 0.000 description 2
- 229920001515 polyalkylene glycol Polymers 0.000 description 2
- 229920000098 polyolefin Polymers 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- RYYKJJJTJZKILX-UHFFFAOYSA-M sodium octadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC([O-])=O RYYKJJJTJZKILX-UHFFFAOYSA-M 0.000 description 2
- 150000005846 sugar alcohols Polymers 0.000 description 2
- 239000003760 tallow Substances 0.000 description 2
- OYHQOLUKZRVURQ-NTGFUMLPSA-N (9Z,12Z)-9,10,12,13-tetratritiooctadeca-9,12-dienoic acid Chemical compound C(CCCCCCC\C(=C(/C\C(=C(/CCCCC)\[3H])\[3H])\[3H])\[3H])(=O)O OYHQOLUKZRVURQ-NTGFUMLPSA-N 0.000 description 1
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- HXKKHQJGJAFBHI-UHFFFAOYSA-N 1-aminopropan-2-ol Chemical compound CC(O)CN HXKKHQJGJAFBHI-UHFFFAOYSA-N 0.000 description 1
- BTGGRPUPMPLZNT-PGEUSFDPSA-N 2,2-bis[[(z)-octadec-9-enoyl]oxymethyl]butyl (z)-octadec-9-enoate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC(CC)(COC(=O)CCCCCCC\C=C/CCCCCCCC)COC(=O)CCCCCCC\C=C/CCCCCCCC BTGGRPUPMPLZNT-PGEUSFDPSA-N 0.000 description 1
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- 235000021357 Behenic acid Nutrition 0.000 description 1
- 244000060011 Cocos nucifera Species 0.000 description 1
- 235000013162 Cocos nucifera Nutrition 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 239000005639 Lauric acid Substances 0.000 description 1
- 229910001209 Low-carbon steel Inorganic materials 0.000 description 1
- 244000062730 Melissa officinalis Species 0.000 description 1
- 235000010654 Melissa officinalis Nutrition 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 235000021314 Palmitic acid Nutrition 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical group CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- SLINHMUFWFWBMU-UHFFFAOYSA-N Triisopropanolamine Chemical compound CC(O)CN(CC(C)O)CC(C)O SLINHMUFWFWBMU-UHFFFAOYSA-N 0.000 description 1
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 125000002877 alkyl aryl group Chemical group 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 229940116226 behenic acid Drugs 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 description 1
- LVTYICIALWPMFW-UHFFFAOYSA-N diisopropanolamine Chemical compound CC(O)CNCC(C)O LVTYICIALWPMFW-UHFFFAOYSA-N 0.000 description 1
- 229940043276 diisopropanolamine Drugs 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 238000005242 forging Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- VKOBVWXKNCXXDE-UHFFFAOYSA-N icosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCC(O)=O VKOBVWXKNCXXDE-UHFFFAOYSA-N 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 239000000865 liniment Substances 0.000 description 1
- 239000010687 lubricating oil Substances 0.000 description 1
- 238000005461 lubrication Methods 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 235000014593 oils and fats Nutrition 0.000 description 1
- 235000021313 oleic acid Nutrition 0.000 description 1
- 125000006353 oxyethylene group Chemical group 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 229920001083 polybutene Polymers 0.000 description 1
- 235000015277 pork Nutrition 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 238000007586 pull-out test Methods 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 230000001568 sexual effect Effects 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 230000003746 surface roughness Effects 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Landscapes
- Lubricants (AREA)
- Forging (AREA)
- Metal Extraction Processes (AREA)
Abstract
Description
【発明の詳細な説明】
産業上の利用分野
本発明は、鋼材の・■性膜［Ｊｌ ＩＩ？ｌ滑剤に関す
る。[Detailed Description of the Invention] Industrial Field of Application The present invention is directed to a steel film [Jl II? l Regarding lubricants.
したがって本発明は、１？１滑剤を製造する産業および
鋼材を加重する産業において利用されるものである。Therefore, the present invention finds use in the 1:1 lubricant manufacturing industry and the steel weighting industry.
従来の技７１ドｉ
鋼の塑性膜１１、たとえば鍛造、引抜、ヘングー加下等
を行うときは、被膜ｌ二材料をリン酸塩処理したのちに
、脂肪酸や鉱油、油脂笠の１ｌｊＪ ？ｆ′Ｉ剤を適用
して加重する方法が多用されている。Conventional Techniques 71 When forming a plastic film 11 on steel, such as forging, drawing, bending, etc., the material is treated with phosphate, and then treated with fatty acids, mineral oil, oil or fat. A method of weighting by applying an f'I agent is often used.
リン酸塩処理は、リン酸■１Ｆ鉛やリン酸マンカンの水
溶液に被膜重材料を浸漬して、被膜Ｅ材料表面にリン酸
１１！の被膜を形成するものであるが、これを天施する
には、被膜「材ネ１を浸漬するための処理槽を必要とす
るので、多大の設備費を黄する。そのし、処ＦＩＩ液は
ｃＩｔ性が強いので使用に際しての安全の問題や、廃液
処理に際しての公害の問題があり、めんどうな措１セ１
や配處が必要である。Phosphate treatment is performed by immersing the coated heavy material in an aqueous solution of phosphoric acid 1F lead or mankan phosphate, and applying phosphoric acid 11! to the surface of the coated E material. However, in order to apply this coating, a treatment tank is required to immerse the coating material, which incurs a large amount of equipment cost. Because it has a strong cIt property, there are safety issues when using it and pollution issues when treating waste liquid, and it requires troublesome measures.
It is necessary to provide additional facilities and facilities.
したがって、リン酸用処理を施さなくても、これを施し
たのと回等の効果が得られるようなＩｌ！１′ｌ１１７
剤が望まれているが、現在までこの要求を満たすような
１テト滑剤は知られていない。Therefore, even if phosphoric acid treatment is not performed, the same effect as that obtained with phosphoric acid treatment can be obtained. 1'l117
However, to date, no lubricant has been known that satisfies this requirement.
発明が解決しようとする問題点
り記の現状であるから、リン酸塩処理を行わなくても、
これを１Ｙったのと量子のｌｌＩ？ｌｊ効果が得られる
ような１１￥１滑剤を提供することが本発明の目的であ
る。Given the current state of the problems that the invention seeks to solve, even without phosphate treatment,
Is this 1Y and quantum llI? It is an object of the present invention to provide a lubricant with lj effect.
問題点を解決するためのＬ段
本発明は、
（イ）ｌ［リン酸、
（ロ）鉱物油、油脂または合成潤滑油から選ばれた１種
または２挿具１−のｎ！１滑性成分、（ハ）アルカリ金
Ｊ４の水酸化物、アルカリ金属のｉμ酸塩またはアミン
類から選ばれた１種または２挿具にの１１！基性物箕お
よび
（ニ）水
を必須成分とすることを特徴とする塑性加工用潤滑剤で
ある。The L-stage present invention for solving the problems consists of: (a) l[phosphoric acid; (b) one or two types of inserts selected from mineral oil, oil or synthetic lubricating oil; n! 1 lubricating component, (c) one or two selected from alkali gold J4 hydroxide, alkali metal i-acid or amines; 11! A lubricant for plastic working characterized by containing a basic substance and (d) water as essential components.
本発明の構成について以Ｆに詳説する。The configuration of the present invention will be explained in detail below.
（潤滑性成分）
本発明で使用される潤滑性成分としては、鉱物油、油脂
および合成潤滑油から成る群から選択された１種または
２挿具ｌ二のものがある。(Lubricating component) The lubricating component used in the present invention includes one or two lubricating components selected from the group consisting of mineral oil, fat and oil, and synthetic lubricating oil.
鉱物油としては任５αのものが使用されるが１通常は石
油原油を蒸留して得られる潤滑油留分を精製処理して得
られるものであって、キャノンフェンスケ粘度計を用い
て測定された動粘度が４０°Ｃでｌ 、Ｏ−１、ＯＯＯ
ｍｒｎ’／ｓのものが好ましい。The mineral oil used is 5α, but it is usually obtained by refining a lubricating oil fraction obtained by distilling petroleum crude oil, and it is measured using a Cannon Fenske viscometer. The kinematic viscosity at 40°C is l, O-1, OOO
mrn'/s is preferred.
油脂としては、牛脂、豚脂、ナタネ油、ヤシＶ＋ｂ、バ
ーム油、ヌカ油およびこれらの水素添加物を用いること
ができる。As the oil and fat, beef tallow, pork fat, rapeseed oil, coconut V+b, balm oil, bran oil, and hydrogenated products thereof can be used.
合成潤滑油としては、
（１）リシノール酸縮合物、
（２）前記の油脂から得られる脂肪酸の混合物、（３）
前記の脂肪酸混合物を構成する個々の脂肪酸と、１価ま
たは多価のアルコール類とのエステル、
（４）ポリオレフィン。Synthetic lubricating oils include (1) ricinoleic acid condensates, (2) mixtures of fatty acids obtained from the above oils and fats, (3)
an ester of each fatty acid constituting the fatty acid mixture and a monohydric or polyhydric alcohol; (4) a polyolefin;
（５）アルキレングリコールおよびポリアルキレングリ
コールおよび、
（６）リン酸エステル
を例示することができる。(5) alkylene glycols and polyalkylene glycols; and (6) phosphoric acid esters.
群（３）のエステルを構成する脂肪酸としては、ラウリ
ン酸、ミリスチン酸、パルミチン酸、ステアリン酸 ア
ラキン酸、ベヘニン酸、オレイン酸 リノール酸、リル
ン酸などを例示することができる。Examples of fatty acids constituting the esters of group (3) include lauric acid, myristic acid, palmitic acid, stearic acid, arachic acid, behenic acid, oleic acid, linoleic acid, and lylunic acid.
詳（３）のエステルを構成する１価のアルコールは、炭
、に原子数が１〜２２個のものであって、その例はメタ
ノール、エタノール、ブタノール、オクタ／−ル、ドデ
カノール、ヘキサデカノール、オクタデカノールなどで
ある。The monohydric alcohol constituting the ester in detail (3) has 1 to 22 carbon atoms, and examples thereof include methanol, ethanol, butanol, octyl, dodecanol, and hexadecanol. , octadecanol, etc.
群（３）のエステルを構成する多価アルコールの例は、
エチレングリコール、プロピレングリコール、ネオペン
チルグリコール、トリメチロールプロパン、ペンタエリ
トリントなと゛である。Examples of polyhydric alcohols constituting the esters of group (3) are:
These include ethylene glycol, propylene glycol, neopentyl glycol, trimethylolpropane, and pentaerythrin.
Ｒ￥（４）のポリオレフィンの例としては、ポリブテン
および）父素原ｒ・数が５〜ｌＯのα−オレフィンオリ
ゴマーを示すことができる。Examples of the polyolefin of R¥(4) include polybutene and α-olefin oligomers having a parent atom r number of 5 to 10.
群（５）のアルキレングリコールとしては１エチレ／グ
１ノコールおよびプロピレングリコールを例示すること
ができ、ポリアルキレングリコールとしては、ジエチレ
ングリコール、ジプロピレングリコールおよびトリエチ
レングリコールを例示することができる。Examples of the alkylene glycol of group (5) include 1 ethylene/g 1 nocol and propylene glycol, and examples of the polyalkylene glycol include diethylene glycol, dipropylene glycol, and triethylene glycol.
群（６）のリン酸エステルとしては、ド記のものを使用
することができる。As the phosphoric acid ester of group (6), those listed below can be used.
（ＲＯ） ３ ＰＯｌ （ＲＯ）２ Ｆ （０）ＯＨ１
ＲＯ−ＰＯ（ＯＨ） ２、
ＲＯ（Ｃ２Ｈ４０） ｎ ＰＯ（ＯＨ） ２（ただし上
式の中のＲは炭素原子数が７〜１８個のアルキル基また
はアルキルアリール基を意味する。）
（ｉｔｉ基性物性物
質発明においてリン酸を中和するために使用される塩基
性物質としては、アルカリ金属の水酸化物、アルカリ金
属の炭酸塩またはアミン類から選ばれた１種または２挿
具ｊ−の物質を使用することができる。(RO) 3 POl (RO)2 F (0)OH1
RO-PO(OH) 2, RO(C2H40) n PO(OH) 2 (However, R in the above formula means an alkyl group or alkylaryl group having 7 to 18 carbon atoms.) (iti group The basic substance used to neutralize phosphoric acid in the invention of a physical property substance is one or two selected from alkali metal hydroxides, alkali metal carbonates, and amines. Substances can be used.
アルカリ金属としてはカリウムおよびナトリウム等を用
いることがでる。Potassium, sodium, etc. can be used as the alkali metal.
アミン類としてはアルキルアミン ノールアミンを用いることができる。Alkylamines as amines Nolamine can be used.
アルキルアミンの例としては、モノエチルアミンおよび
ジエチルアミンを示すことができる。As examples of alkylamines, monoethylamine and diethylamine may be mentioned.
アルカノールアミンの例を示せば、モノエタノールアミ
ン、ジェタノールアミン、トリエタノールアミン、モノ
イソプロパツールアミン、ジイソプロパツールアミン、
トリイソプロパツールアミン、モノセカンタリーブタノ
ールアミン、ジセカンタリーブタノールアミンおよびト
リセカンダリ−ブタノールアミンがある。Examples of alkanolamines include monoethanolamine, jetanolamine, triethanolamine, monoisopropanolamine, diisopropanolamine,
These include triisopropanolamine, monosecondary butanolamine, disecondary butanolamine, and trisecondary butanolamine.
Ｉｉ！基性物性物質ｆｉ １．にはリン酸を中和するの
に必要な；Ｉ（の１０〜９０改量％の範囲であることが
望ましい、塩）、（性物質のＷｊｒ ：Ｍがｈ記の呈よ
り少ないと、ｆｉｌｌ滑剤による被加工材料や機械の腐
食が起こり１ 」、記の吊を越えると潤滑効果がネト分
となる。Ii! Basic physical substance fi 1. is necessary to neutralize phosphoric acid; I (preferably in the range of 10 to 90%, salt), (Wjr of the sexual substance: If M is less than the expression in h, fill The lubricant causes corrosion of the workpiece material and the machine, and when the above limit is exceeded, the lubricating effect becomes negligible.
（任意成分）
所望によっては１本発明の潤滑剤に非イオン界面活性剤
またはカチオン界面活性剤を乳化剤として添加すること
ができる。(Optional Components) If desired, a nonionic surfactant or a cationic surfactant may be added to the lubricant of the present invention as an emulsifier.
（製造方法と使用方法）
本発明の、′ｒ？ｊ性加Ｉ性膜潤滑用は、必イ（成分を
混合し、すへての成分を均一に溶解または分散させるこ
とによって容易に製造することができる。また、任、−
１成分をも使用するときは、必須成分と任意成分とを混
合し１すへての成分を均・に溶解または分散させること
によって容易に製造することができる。(Manufacturing method and usage method) The 'r? Additive film lubricants can be easily manufactured by mixing the components and uniformly dissolving or dispersing all the components.
When one component is used, it can be easily manufactured by mixing the essential component and the optional component and uniformly dissolving or dispersing the entire component.
本発明の・ｑＪ性性膜川用滑剤を使用するときは、被加
工材料を潤滑剤に浸漬するか、被加工材料に本発明のＩ
’ｌｌ滑剤をへヶ塗り、スプレー塗り等の方法によって
塗Ｊする。When using the lubricant for lubricant with qJ properties of the present invention, the workpiece material is immersed in the lubricant, or the workpiece material is coated with the lubricant of the present invention.
'll Apply lubricant to the surface by coating, spraying, etc.
実 施 例
つぎに実施例および比較例によって本発明を置体的に説
１］する。ただし本発明はこれらの実施例および比較例
によってなんら制限されるものではない。EXAMPLES Next, the present invention will be explained in detail with reference to Examples and Comparative Examples. However, the present invention is not limited in any way by these Examples and Comparative Examples.
以ドの記述において％は改１□；−％を、部は毛；ａ一
部を表わすものである。In the following description, % means 1□;-%, and part means a part.
まず、第１表に本発明の塑性却下用１１７１滑剤の配合
例を示す。First, Table 1 shows formulation examples of the 1171 lubricant for plasticity rejection of the present invention.
第１表
注Ｉ ＪＩＳ Ｋ２２３８に規定されているＩＳＯ
ＶＧ４６
２ 加熱脱水縮合物（＋−均均分分子縮合３ ’ Ｃ，
、、）Ｉ、、５０（Ｃ，、Ｈ４０）４ＰＯ（０）１）２
４ トリメチロールプロパントリオレエート５ ポリ（
オキシエチレンｅオキシプロピレン）グリコール・モノ
エーテル（ｆｉ １’均分１’：＋：カｌ ５ 、 Ｏ
ＯＯノモ（７））６ ノニルフェニルエーテルのエチレ
ンオキシト（２モル）付加物
７ ノニルフェニルエーテルのエチレンオキノド（６モ
ル）付加物
８ ノニルフェニルエーテルのエチレンオキシド（１４
モル）付加物
９ ｉ１Ｅリン酸を完全に中和するのに心安な塩基性
物質のＦ４に対する実際に用いられた塩基性物質の４Ｘ
の比率
比較例としてｆ記の潤滑剤を用いた。Table 1 Note I ISO specified in JIS K2238
VG46 2 Heated dehydrated condensate (+- homogeneous fractional molecular condensation 3'C,
,,)I,,50(C,,H40)4PO(0)1)2
4 Trimethylolpropane trioleate 5 Poly(
oxyethylene e oxypropylene) glycol monoether (fi 1' equal fraction 1': +: Cal 5, O
OO Nomo (7)) 6 Ethylene oxide (2 mol) adduct of nonylphenyl ether 7 Ethylene oxide (6 mol) adduct of nonylphenyl ether 8 Ethylene oxide (14) of nonylphenyl ether
Mol) Adduct 9 i1E 4X of the basic substance actually used for F4, which is a basic substance that is safe to completely neutralize phosphoric acid.
As a ratio comparison example, the lubricant listed in f was used.
比較例１
ステアリン酸ナトリウム １５部
水 ８５
部比較例２
マシン油（注１） ２５部牛脂
５部
ステアリン酸ナトリウム ６部
界面活性剤−２（注１０） １．．５部水
８５ 部比較例
３
ナタネ油 ３０部
Ｉｔ！ 、）、化パラフィン（汀１１）２０部マシン油
（注１） ４０部
オレイン酎 １０部（注１ ）
ＪＡＳ Ｋ２２３８１ＳＯＶＧ４８（注１０） 第１
表に記載のもの
（注目）Ｉｉ！素分５０重；、；、％のもの１−記の実
施例および比較例の潤滑剤を用い、ｆ記の条件で引抜試
験を行ない、引抜力の測定をした。また引抜いたあとの
材料の表面状態をｒＪ視観察するとともに、表面粗さを
測定した。Comparative Example 1 Sodium stearate 15 parts Water 85
Part Comparative Example 2 Machine oil (Note 1) 25 parts Beef tallow
5 parts Sodium stearate 6 parts Surfactant-2 (Note 10) 1. ．． 5 parts water
85 parts Comparative Example 3 Rapeseed oil 30 parts It! , ), Paraffinated paraffin (Tane 11) 20 parts Machine oil (Note 1) 40 parts Oleic spirit 10 parts (Note 1)
JAS K22381SOVG48 (Note 10) 1st
Items listed in the table (notice) Ii! A pullout test was conducted using the lubricants of Examples and Comparative Examples 1-1 and 50% by weight under the conditions described in f, and the pulling force was measured. In addition, the surface condition of the material after being pulled out was observed with rJ vision, and the surface roughness was measured.
試験条件
試験装置 ■島ＩＰ製作所製 オートグラフ引抜速度
３００ｍｍ／ｍｉｎ。Test conditions Test device ■ Manufactured by Shima IP Seisakusho Autograph drawing speed 300 mm/min.
グイス 超硬 半角＝７度、孔径：４ｍｍ材料
軟鋼線 （ＳＷＲＭ−８）線径：５ｍｍ
断面減少率 ３６％
潤滑処理方法 温度５０℃の潤滑剤に材料を１０分間浸
漬した。Guis Carbide Half angle = 7 degrees, hole diameter: 4mm Material
Mild steel wire (SWRM-8) Wire diameter: 5 mm Section reduction rate: 36% Lubrication treatment method The material was immersed in a lubricant at a temperature of 50° C. for 10 minutes.
試験結果を第２表に示す。The test results are shown in Table 2.
第２表の表面状態の列において、記号Ｏは焼付きなし、
Ｘは焼付きありを意味する。In the surface condition column of Table 2, symbol O indicates no seizure;
X means burn-in.
また、第２表中の参考例はＦ記の方法でリン酸塩処理し
、４テ１滑剤を塗７１】シて試験に供したものである。Further, the reference examples in Table 2 were treated with phosphate according to the method described in F, coated with a 4/1 lubricant, and then subjected to the test.
処理液：１１本パー力ライジング株製のボンデライト１
８１の９屯：、１１％水溶液に同社製の促進剤５００ｐ
ｐｍを添加したも
の。Treatment liquid: 11 bottles Bonderite 1 manufactured by Parriki Rising Co., Ltd.
9 tons of 81: 500p of the company's accelerator in 11% aqueous solution
Added pm.
浸漬温度と時間ニア５°Ｃ〜８０℃で５分。Soaking temperature and time: 5 minutes at 5°C to 80°C.
潤・滑剤の塗ＩＨｊ ニステアリン酸ナトリウムを８０
″Ｃに加熱溶融し、材料を
１０分間浸漬した。Lubricant coating IHj Sodium nistearate 80
"C" was heated and melted, and the material was immersed for 10 minutes.
発明の効果
本発明の塑性前玉用潤滑剤を用いることにより、リン酸
塩処理を施した場合と同等のＩ’ｌτ４滑効果を得るこ
とができる。したがって未発ｉ１によれば、リン酸塩処
理に伴う安゛令の問題や公害の問題が解消され、処理槽
の設備費や管理費が節減できる。Effects of the Invention By using the lubricant for plastic front lenses of the present invention, it is possible to obtain an I'lτ4 lubricating effect equivalent to that obtained when phosphate treatment is applied. Therefore, according to the unreleased i1, the safety and pollution problems associated with phosphate treatment can be solved, and the equipment costs and management costs for treatment tanks can be reduced.
Claims (1)
または２種以上の潤滑性成分、 （ハ）アルカリ金属の水酸化物、アルカリ金属の炭酸塩
またはアミン類から選ばれた１種 または２種以上の塩基性物質および （ニ）水 を必須成分とすることを特徴とする塑性加工用潤滑剤。[Scope of Claims] (a) Orthophosphoric acid; (b) one or more lubricating components selected from mineral oil, oil or synthetic lubricating oil; (c) alkali metal hydroxide, alkali A lubricant for plastic working, characterized in that the essential components are one or more basic substances selected from metal carbonates or amines, and (d) water.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP22693785A JPS6286096A (en) | 1985-10-14 | 1985-10-14 | Lubricant for plastic working |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP22693785A JPS6286096A (en) | 1985-10-14 | 1985-10-14 | Lubricant for plastic working |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS6286096A true JPS6286096A (en) | 1987-04-20 |
Family
ID=16852942
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP22693785A Pending JPS6286096A (en) | 1985-10-14 | 1985-10-14 | Lubricant for plastic working |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6286096A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62149795A (en) * | 1985-12-25 | 1987-07-03 | Yushiro Chem Ind Co Ltd | Lubricating agent for plastic working |
| WO2004069968A1 (en) * | 2003-02-03 | 2004-08-19 | Honda Motor Co., Ltd. | Water-soluble metal working lubricant |
| WO2013073617A1 (en) * | 2011-11-17 | 2013-05-23 | 出光興産株式会社 | Water-soluble metalworking oil agent, metalworking fluid, and metalworking method |
| JP2014080623A (en) * | 2014-01-14 | 2014-05-08 | Idemitsu Kosan Co Ltd | Metal processing oil agent |
| CN105567392A (en) * | 2015-12-23 | 2016-05-11 | 南京科润工业介质股份有限公司 | Drawing lubricant oil |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4986229A (en) * | 1972-08-24 | 1974-08-19 | ||
| JPS59193995A (en) * | 1983-04-20 | 1984-11-02 | Nippon Steel Corp | Lubrication for cold rolling |
-
1985
- 1985-10-14 JP JP22693785A patent/JPS6286096A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4986229A (en) * | 1972-08-24 | 1974-08-19 | ||
| JPS59193995A (en) * | 1983-04-20 | 1984-11-02 | Nippon Steel Corp | Lubrication for cold rolling |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62149795A (en) * | 1985-12-25 | 1987-07-03 | Yushiro Chem Ind Co Ltd | Lubricating agent for plastic working |
| WO2004069968A1 (en) * | 2003-02-03 | 2004-08-19 | Honda Motor Co., Ltd. | Water-soluble metal working lubricant |
| US7833951B2 (en) | 2003-02-03 | 2010-11-16 | Honda Motor Co., Ltd. | Water-soluble metal working lubricant |
| WO2013073617A1 (en) * | 2011-11-17 | 2013-05-23 | 出光興産株式会社 | Water-soluble metalworking oil agent, metalworking fluid, and metalworking method |
| JP2013107938A (en) * | 2011-11-17 | 2013-06-06 | Idemitsu Kosan Co Ltd | Water-soluble metalworking oil, metalworking fluid, and metalworking method |
| US9683189B2 (en) | 2011-11-17 | 2017-06-20 | Idemitsu Kosan Co., Ltd. | Water-soluble metalworking oil agent, metalworking fluid, and metalworking method |
| JP2014080623A (en) * | 2014-01-14 | 2014-05-08 | Idemitsu Kosan Co Ltd | Metal processing oil agent |
| CN105567392A (en) * | 2015-12-23 | 2016-05-11 | 南京科润工业介质股份有限公司 | Drawing lubricant oil |
| CN105567392B (en) * | 2015-12-23 | 2018-03-02 | 南京科润新材料技术有限公司 | A kind of drawing lubrication oil |
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