JPS6261119B2 - - Google Patents
Info
- Publication number
- JPS6261119B2 JPS6261119B2 JP60136492A JP13649285A JPS6261119B2 JP S6261119 B2 JPS6261119 B2 JP S6261119B2 JP 60136492 A JP60136492 A JP 60136492A JP 13649285 A JP13649285 A JP 13649285A JP S6261119 B2 JPS6261119 B2 JP S6261119B2
- Authority
- JP
- Japan
- Prior art keywords
- exchange resin
- ion exchange
- solution
- metal
- mixed
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003456 ion exchange resin Substances 0.000 claims description 37
- 229920003303 ion-exchange polymer Polymers 0.000 claims description 37
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 claims description 34
- 229910052751 metal Inorganic materials 0.000 claims description 20
- 239000002184 metal Substances 0.000 claims description 20
- 239000000243 solution Substances 0.000 claims description 18
- 150000001875 compounds Chemical class 0.000 claims description 7
- 239000000725 suspension Substances 0.000 claims description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 5
- 239000007864 aqueous solution Substances 0.000 claims description 5
- 229910052731 fluorine Inorganic materials 0.000 claims description 5
- 239000011737 fluorine Substances 0.000 claims description 5
- 239000003960 organic solvent Substances 0.000 claims description 5
- 229920000642 polymer Polymers 0.000 claims description 5
- 239000003638 chemical reducing agent Substances 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims description 4
- 239000012046 mixed solvent Substances 0.000 claims description 3
- 239000011248 coating agent Substances 0.000 claims description 2
- 238000000576 coating method Methods 0.000 claims description 2
- 239000011259 mixed solution Substances 0.000 claims description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical group [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 24
- 239000012528 membrane Substances 0.000 description 14
- -1 aliphatic alcohols Chemical class 0.000 description 12
- 230000003197 catalytic effect Effects 0.000 description 12
- 238000000034 method Methods 0.000 description 11
- 229910052697 platinum Inorganic materials 0.000 description 11
- 239000000203 mixture Substances 0.000 description 7
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 6
- 239000003054 catalyst Substances 0.000 description 6
- 239000011347 resin Substances 0.000 description 6
- 229920005989 resin Polymers 0.000 description 6
- TXEYQDLBPFQVAA-UHFFFAOYSA-N tetrafluoromethane Chemical compound FC(F)(F)F TXEYQDLBPFQVAA-UHFFFAOYSA-N 0.000 description 6
- 238000007772 electroless plating Methods 0.000 description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 4
- 239000004810 polytetrafluoroethylene Substances 0.000 description 4
- 229920000557 Nafion® Polymers 0.000 description 3
- 238000007731 hot pressing Methods 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 229910021645 metal ion Inorganic materials 0.000 description 3
- 239000007784 solid electrolyte Substances 0.000 description 3
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 2
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 239000012279 sodium borohydride Substances 0.000 description 2
- 229910000033 sodium borohydride Inorganic materials 0.000 description 2
- 125000000542 sulfonic acid group Chemical group 0.000 description 2
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000007900 aqueous suspension Substances 0.000 description 1
- 230000000712 assembly Effects 0.000 description 1
- 238000000429 assembly Methods 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000003411 electrode reaction Methods 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- CLSUSRZJUQMOHH-UHFFFAOYSA-L platinum dichloride Chemical compound Cl[Pt]Cl CLSUSRZJUQMOHH-UHFFFAOYSA-L 0.000 description 1
- 230000010287 polarization Effects 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1004—Fuel cells with solid electrolytes characterised by membrane-electrode assemblies [MEA]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Sustainable Development (AREA)
- Sustainable Energy (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
- Inert Electrodes (AREA)
- Electrodes For Compound Or Non-Metal Manufacture (AREA)
Description
【発明の詳細な説明】
産業上の利用分野
本発明はイオン交換樹脂膜―電極接合体の製造
法に関するものである。さらに詳しくは、本発明
はイオン交換樹脂膜を固体電解質とする各種電気
化学装置に用いられるイオン交換樹脂膜―電極接
合体の製造法に関するものである。DETAILED DESCRIPTION OF THE INVENTION Field of Industrial Application The present invention relates to a method for producing an ion exchange resin membrane-electrode assembly. More specifically, the present invention relates to a method for manufacturing an ion exchange resin membrane-electrode assembly used in various electrochemical devices using an ion exchange resin membrane as a solid electrolyte.
従来の技術
イオン交換樹脂膜を固体電解質とする電気化学
装置には、燃料電池、水電解槽、食塩電解槽、酸
素分離装置、塩酸電解槽あるいは水電解式湿度セ
ンサなどがある。これらの電気化学装置において
は、一般にイオン交換樹脂膜に電極が一体に接合
されたものが用いられる。イオン交換樹脂膜に電
極を接合する方法としては、電極触媒粉末とフツ
素樹脂結着剤との混合物をホツトプレスする方法
（例えば特公昭58−15544号）と、無電解メツキ法
（例えば特開昭55−38934号）とが提案されてい
る。BACKGROUND ART Electrochemical devices using an ion exchange resin membrane as a solid electrolyte include fuel cells, water electrolyzers, salt electrolyzers, oxygen separators, hydrochloric acid electrolyzers, and water electrolysis type humidity sensors. These electrochemical devices generally use an ion exchange resin membrane with an electrode integrally bonded thereto. Methods for bonding electrodes to ion-exchange resin membranes include hot-pressing a mixture of electrode catalyst powder and fluororesin binder (e.g., Japanese Patent Publication No. 15544/1983), and electroless plating method (e.g., Japanese Patent Publication No. 15544/1983). 55-38934) has been proposed.
発明が解決しようとする問題点
従来のイオン交換樹脂膜―電極接合体において
は、ホツトプレス法にしろ無電解メツキ法にし
ろ、電極反応サイトが電解質であるイオン交換樹
脂膜と電極との接合部である二次元的な界面に局
限されていたため、実質的な作用面積が小さかつ
た。Problems to be Solved by the Invention In conventional ion exchange resin membrane-electrode assemblies, whether using the hot pressing method or the electroless plating method, the electrode reaction site is the electrolyte at the junction between the ion exchange resin membrane and the electrode. Since it was localized to a certain two-dimensional interface, the effective area of action was small.
問題点を解決するための手段
本発明は、含フツ素高分子を骨格とするイオン
交換樹脂の有機溶媒溶液もしくは有機溶媒と水と
の混合溶媒溶液に触媒金属を含む化合物を直接溶
解せしめるか又は触媒金属を含む化合物の水溶液
を混合せしめたものに還元剤を作用せしめること
により、金属を析出せしめて得られる金属が分散
懸濁せるイオン交換樹脂の溶液もしくは該溶液と
フツ素樹脂懸濁液との混合懸濁液をイオン交換樹
脂膜に塗着せしめることによつて、上述の如き問
題点を解決せんとするものである。Means for Solving the Problems The present invention involves directly dissolving a compound containing a catalytic metal in an organic solvent solution or a mixed solvent solution of an organic solvent and water of an ion exchange resin having a fluorine-containing polymer as a backbone; A solution of an ion exchange resin in which the metal is dispersed and suspended by precipitating the metal by acting on a reducing agent on a mixture of an aqueous solution of a compound containing a catalytic metal, or a solution of the ion exchange resin and a fluororesin suspension. The above-mentioned problems are attempted to be solved by applying a mixed suspension of the above to an ion exchange resin membrane.
作 用
含フツ素高分子を骨格とするイオン交換樹脂に
は、例えばパーフルオロカーボンスルフオン酸樹
脂がある。パーフルオロカーボンスルフオン酸樹
脂は、高温高圧下では低級脂肪族アルコールある
いはジメチルスルフオキシドなどの有機溶媒に溶
解することが知られている。このようなパーフル
オロカーボンスルフオン酸樹脂の溶液は例えばア
メリカのアルドリツチケミカル社からナフイオン
溶液（低級脂肪族アルコールと水との混合溶媒溶
液）という商標で発売されている。Function Examples of ion exchange resins having a fluorine-containing polymer as a backbone include perfluorocarbon sulfonic acid resins. It is known that perfluorocarbon sulfonic acid resins dissolve in lower aliphatic alcohols or organic solvents such as dimethyl sulfoxide under high temperature and high pressure. Such solutions of perfluorocarbon sulfonic acid resins are sold, for example, by Aldrich Chemical Company of the United States under the trade name Nafion Solution (mixed solvent solution of lower aliphatic alcohol and water).
上記パーフルオロカーボンスルフオン酸樹脂の
溶液に触媒金属を含む化合物を直接溶解させるか
又は触媒金属を含む化合物の水溶液を混合する
と、スルフオン酸基の水素イオンと触媒金属イオ
ンあるいは触媒金属を含むカチオンとの置換が起
こり、パーフルオロカーボンスルフオン酸樹脂に
触媒金属が捕捉されたような形になる。このよう
な混合溶液を還元剤で処理すると触媒金属が析出
し、イオン交換樹脂溶液の中で、微細に分散懸濁
する。このようなイオン交換樹脂の溶液もしくは
該溶液とフツ素樹脂懸濁液との混合懸濁液を含フ
ツ素高分子を骨格とするイオン交換樹脂膜に塗着
し、溶媒を揮散せしめると、イオン交換膜と触媒
金属―イオン交換樹脂混合体との接合体が形成さ
れる。なお、塗着したのち、常温でプレスするか
加熱してプレスすると接合強度が大きくなる。か
くして、イオン交換樹脂膜と触媒金属―イオン交
換樹脂混合体との接合体が完成する。触媒金属―
イオン交換樹脂混合体は電極として作用する。 When a compound containing a catalytic metal is directly dissolved in a solution of the above perfluorocarbon sulfonic acid resin or an aqueous solution of a compound containing a catalytic metal is mixed, hydrogen ions of the sulfonic acid group and catalytic metal ions or cations containing the catalytic metal are combined. Substitution occurs and the catalytic metal becomes trapped in the perfluorocarbon sulfonic acid resin. When such a mixed solution is treated with a reducing agent, the catalyst metal is precipitated and finely dispersed and suspended in the ion exchange resin solution. When a solution of such an ion exchange resin or a mixed suspension of the solution and a fluororesin suspension is applied to an ion exchange resin membrane having a fluorine-containing polymer skeleton and the solvent is evaporated, ions are released. A bond between the exchange membrane and the catalytic metal-ion exchange resin mixture is formed. Note that after application, the bonding strength will be increased if the adhesive is pressed at room temperature or heated. In this way, a bonded body of the ion exchange resin membrane and the catalytic metal-ion exchange resin mixture is completed. Catalytic metal
The ion exchange resin mixture acts as an electrode.
このようなイオン交換樹脂膜―電極接合体にお
いては、電極の中のイオン交換樹脂も固体電解質
として機能するので、反応サイトは従来のように
イオン交換樹脂膜と電極との二次元的な界面だけ
でなくて、電極の中の触媒金属とイオン交換樹脂
との接点をも含めた三次元的な拡がりをもつこと
になり、実質的な電極作用面積が増大し、このよ
うな接合体を電気化学装置に適用したとき、分極
特性が向上する。 In such an ion exchange resin membrane-electrode assembly, the ion exchange resin in the electrode also functions as a solid electrolyte, so the reaction sites are limited to the two-dimensional interface between the ion exchange resin membrane and the electrode, as in the past. Rather, it has a three-dimensional extension that includes the contact point between the catalyst metal and ion exchange resin in the electrode, increasing the effective electrode area, and making such a bonded body electrochemical. When applied to a device, polarization properties are improved.
触媒金属としては、白金族金属を用いるのが適
当である。また触媒金属を含む化合物としては、
触媒金属の塩もしくはアンミン錯体が適当であ
る。さらに還元剤としては、ヒドラジン、水素化
ホウ素ナトリウムあるいは水素等が適用可能であ
る。 As the catalyst metal, it is appropriate to use a platinum group metal. In addition, compounds containing catalytic metals include:
Catalytic metal salts or ammine complexes are suitable. Further, as the reducing agent, hydrazine, sodium borohydride, hydrogen, etc. can be used.
なお、塗着の際、カーボン粉末を混合懸濁液の
中に添加すると、触媒金属の使用量を減量するこ
とができるという意味で効果的なことがある。 Note that adding carbon powder to the mixed suspension during coating may be effective in the sense that the amount of catalyst metal used can be reduced.
実施例
次に本発明によるイオン交換樹脂膜―電極接合
体の製造法の一実施例を説明する。EXAMPLE Next, an example of the method for producing an ion exchange resin membrane-electrode assembly according to the present invention will be described.
直径が120mmのパーフルオロカーボンスルフオ
ン酸樹脂膜であるデユポン社（アメリカ）製のナ
フイオン117膜の片面の中心部の直径80mmの部分
に、無電解メツキ法により白金を接合せしめた。
次にナフイオン117の５％有機溶媒―水混合溶液
（アルドリツチケミカル社（アメリカ）製、有機
溶媒は低級脂肪族アルコール）10ccの中に、クロ
ロペンタアンモニウム白金クロライド（〔Pt
（NH3）5Cl〕Cl2）の水溶液（白金として２mg/cc
を含む）を10cc加え、しばらく放置することによ
り、ナフイオン117溶液中のスルフオン酸基の水
素イオンとクロロペンタアンモニウム白金イオン
（〔Pt（NH3）5Cl〕2+）とを置換した。次に５％の水
素化ホウ素ナトリウムの水溶液を加え、クロロペ
ンタアンモニウム白金イオンを還元して白金を析
出させた。このとき、微細な白金の粒子が溶液の
中に分散懸濁される。次にこの分散懸濁液に、ポ
リ４フツ化エチレンの60％水懸濁液を3cc添加し
たものを、上述の白金を接合したナフイオン117
膜の白金が接合されていない面に吹き付け、100
℃の温度、100Kg/cm2の圧力でプレスした。そして
最後に上述のナフイオン膜―電極接合体を湯洗
し、乾燥して、白金とナフイオン117とポリ４フ
ツ化エチレン以外のすべての成分を除去した。か
くして、イオン交換樹脂膜―電極接合体を完成し
た。 Platinum was bonded to the central 80 mm diameter portion of one side of the Nafion 117 membrane, which is a perfluorocarbon sulfonic acid resin membrane with a diameter of 120 mm and manufactured by DuPont (USA), by an electroless plating method.
Next, chloropentaammonium platinum chloride ([Pt
(NH 3 ) 5 Cl〕Cl 2 ) aqueous solution (2 mg/cc as platinum)
By adding 10 cc of chloropentaammonium platinum ion ([Pt(NH 3 ) 5 Cl] 2+ ) to the solution and allowing it to stand for a while, the hydrogen ions of the sulfonic acid groups in the Nafion 117 solution were replaced with chloropentaammonium platinum ions ([Pt(NH 3 ) 5 Cl] 2+ ). Next, a 5% aqueous solution of sodium borohydride was added to reduce the chloropentaammonium platinum ions and precipitate platinum. At this time, fine platinum particles are dispersed and suspended in the solution. Next, 3 cc of a 60% aqueous suspension of polytetrafluoroethylene was added to this dispersion, and the platinum-bonded naphion 117
Spray the platinum on the non-bonded side of the membrane,
Pressed at a temperature of 100Kg/ cm2 . Finally, the above napfion membrane-electrode assembly was washed with hot water and dried to remove all components other than platinum, naphion 117, and polytetrafluoroethylene. In this way, an ion exchange resin membrane-electrode assembly was completed.
上記のようにして得られたイオン交換樹脂膜―
電極接合体は、無電解メツキ法により接合された
白金電極を陽極とし、白金とナフイオン117とポ
リ４フツ化エチレンとの混合物層からなる電極を
陰極とし、この陰極に空気を供給し、陽極に水を
供給すると、空気から酸素を電気化学的に分離す
る装置となる。 Ion exchange resin membrane obtained as above -
The electrode assembly uses a platinum electrode bonded by an electroless plating method as an anode, an electrode made of a mixture layer of platinum, naphion 117, and polytetrafluoroethylene as a cathode, and air is supplied to this cathode to form an anode. The supply of water results in a device that electrochemically separates oxygen from air.
発明の効果
上述の実施例で得られたイオン交換樹脂膜―電
極接合体をＡとし、陽極を上述の実施例と同様に
して形成し、陰極をホツトプレス法の白金ブラツ
クとポリ４フツ化エチレンとの混合物により形成
した従来方法によるイオン交換樹脂膜―電極接合
体をＢとし、それぞれを用いて電気化学的酸素分
離装置を構成し、電流―電圧特性を求めたとこ
ろ、図に示すような結果が得られた。この図から
明らかなように、本発明によつて得られたイオン
交換樹脂膜―電極接合体の方がよりすぐれた特性
を示すことが瞭然としている。。これは電極層を
電極触媒とイオン交換樹脂との混合層から形成す
ることによつて、実質的な作用面積が増大したか
らに他ならない。Effects of the Invention The ion exchange resin membrane-electrode assembly obtained in the above example was designated as A, the anode was formed in the same manner as in the above example, and the cathode was formed using hot pressed platinum black and polytetrafluoroethylene. An ion-exchange resin membrane-electrode assembly formed by a conventional method using a mixture of B was used to construct an electrochemical oxygen separation device, and the current-voltage characteristics were determined, and the results shown in the figure were obtained. Obtained. As is clear from this figure, it is clear that the ion exchange resin membrane-electrode assembly obtained according to the present invention exhibits better characteristics. . This is due to the substantial effect area being increased by forming the electrode layer from a mixed layer of an electrode catalyst and an ion exchange resin.
以上のように本発明方法によれば、従来の無電
解メツキ法、ホツトプレス法に比べて、実質的な
作用面積の多いイオン交換樹脂膜―電極接合体を
得ることができる。 As described above, according to the method of the present invention, it is possible to obtain an ion exchange resin membrane-electrode assembly having a substantially larger working area than the conventional electroless plating method or hot pressing method.
図は本発明方法および従来の方法によつて得ら
れたイオン交換樹脂膜―電極接合体を電気化学的
酸素分離装置に用いた場合の電流―電圧特性を示
す図である。
The figure shows the current-voltage characteristics when the ion exchange resin membrane-electrode assembly obtained by the method of the present invention and the conventional method is used in an electrochemical oxygen separation device.
Claims (1)
の有機溶媒溶液もしくは有機溶媒と水との混合溶
媒溶液に金属を含む化合物を溶解せしめるか又は
金属を含む化合物の水溶液を混合せしめた混合液
に還元剤を作用せしめることにより、金属を析出
せしめて得られる金属が分散懸濁せるイオン交換
樹脂の溶液もしくは該溶液とフツ素樹脂懸濁液と
の混合懸濁液を含フツ素高分子を骨格とするイオ
ン交換樹脂の片面もしくは両面に塗着せしめるこ
とを特徴とするイオン交換樹脂膜―電極接合体の
製造法。1. A compound containing a metal is dissolved in an organic solvent solution of an ion exchange resin having a fluorine-containing polymer as a skeleton or a mixed solvent solution of an organic solvent and water, or a mixed solution containing an aqueous solution of a compound containing a metal is mixed. A solution of an ion exchange resin in which the metal is dispersed and suspended by the action of a reducing agent to precipitate the metal, or a mixed suspension of the solution and a fluororesin suspension, is used as a backbone of a fluorine-containing polymer. 1. A method for producing an ion exchange resin membrane-electrode assembly, which comprises coating one or both sides of an ion exchange resin.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP60136492A JPS61295388A (en) | 1985-06-21 | 1985-06-21 | Production of ion exchange resin membrane-electrode joined body |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP60136492A JPS61295388A (en) | 1985-06-21 | 1985-06-21 | Production of ion exchange resin membrane-electrode joined body |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS61295388A JPS61295388A (en) | 1986-12-26 |
| JPS6261119B2 true JPS6261119B2 (en) | 1987-12-19 |
Family
ID=15176419
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP60136492A Granted JPS61295388A (en) | 1985-06-21 | 1985-06-21 | Production of ion exchange resin membrane-electrode joined body |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS61295388A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5723173A (en) * | 1995-01-26 | 1998-03-03 | Matsushita Electric Industrial Co., Ltd. | Method for manufacturing solid polymer electrolyte fuel cell |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5272017A (en) * | 1992-04-03 | 1993-12-21 | General Motors Corporation | Membrane-electrode assemblies for electrochemical cells |
| DE19745904A1 (en) * | 1997-10-17 | 1999-04-22 | Hoechst Ag | Water-soluble metal colloid solution, used as catalyst for fuel cells and electrolysis cells |
| CN1516311A (en) | 1998-06-16 | 2004-07-28 | ���µ�����ҵ��ʽ���� | High-molecular electrolyte fuel battery |
| WO2002003489A1 (en) | 2000-07-03 | 2002-01-10 | Matsushita Electric Industrial Co., Ltd. | Polyelectrolyte fuel cell |
| KR100441800B1 (en) | 2000-08-04 | 2004-07-27 | 마쯔시다덴기산교 가부시키가이샤 | Polyelectrolyte fuel cell and production method therefor |
| US6916575B2 (en) | 2001-03-08 | 2005-07-12 | Matsushita Electric Industrial Co., Ltd. | Polymer electrolyte type fuel cell |
| EP1298751A3 (en) | 2001-09-27 | 2006-04-26 | Matsushita Electric Industrial Co., Ltd. | Polymer electrolyte fuel cell and production method thereof |
| US7569302B2 (en) | 2002-11-05 | 2009-08-04 | Panasonic Corporation | Fuel cell for generating electric power |
| JP2006252910A (en) * | 2005-03-10 | 2006-09-21 | Konica Minolta Holdings Inc | Fuel cell |
| EP2704239A1 (en) | 2012-08-29 | 2014-03-05 | SolviCore GmbH & Co KG | Colloidal dispersions comprising precious metal particles and acidic ionomer components and methods of their manufacture and use |
-
1985
- 1985-06-21 JP JP60136492A patent/JPS61295388A/en active Granted
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5723173A (en) * | 1995-01-26 | 1998-03-03 | Matsushita Electric Industrial Co., Ltd. | Method for manufacturing solid polymer electrolyte fuel cell |
| DE19602629C2 (en) * | 1995-01-26 | 2000-09-28 | Matsushita Electric Ind Co Ltd | Method for producing a fuel cell with a polymer solid electrolyte |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS61295388A (en) | 1986-12-26 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| LAPS | Cancellation because of no payment of annual fees |