JPS622868B2 - - Google Patents
Info
- Publication number
- JPS622868B2 JPS622868B2 JP5103183A JP5103183A JPS622868B2 JP S622868 B2 JPS622868 B2 JP S622868B2 JP 5103183 A JP5103183 A JP 5103183A JP 5103183 A JP5103183 A JP 5103183A JP S622868 B2 JPS622868 B2 JP S622868B2
- Authority
- JP
- Japan
- Prior art keywords
- water
- pattern
- based paint
- uki
- ink
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003973 paint Substances 0.000 claims description 49
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 35
- 239000000463 material Substances 0.000 claims description 23
- 239000004744 fabric Substances 0.000 claims description 16
- 238000007639 printing Methods 0.000 claims description 9
- 238000004040 coloring Methods 0.000 claims description 6
- 238000013461 design Methods 0.000 claims description 6
- 229920002678 cellulose Polymers 0.000 claims description 5
- 239000001913 cellulose Substances 0.000 claims description 5
- 239000000835 fiber Substances 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims description 4
- 229920002994 synthetic fiber Polymers 0.000 claims description 4
- 239000012209 synthetic fiber Substances 0.000 claims description 4
- 239000000378 calcium silicate Substances 0.000 claims description 3
- 229910052918 calcium silicate Inorganic materials 0.000 claims description 3
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 claims description 3
- 239000000758 substrate Substances 0.000 claims description 2
- 239000000976 ink Substances 0.000 description 20
- 238000000034 method Methods 0.000 description 11
- 239000000203 mixture Substances 0.000 description 9
- 229920003002 synthetic resin Polymers 0.000 description 7
- 239000000057 synthetic resin Substances 0.000 description 7
- 239000000853 adhesive Substances 0.000 description 6
- 230000001070 adhesive effect Effects 0.000 description 6
- 238000005034 decoration Methods 0.000 description 6
- 239000000839 emulsion Substances 0.000 description 6
- 238000009833 condensation Methods 0.000 description 5
- 239000000982 direct dye Substances 0.000 description 5
- 239000000975 dye Substances 0.000 description 5
- 238000009472 formulation Methods 0.000 description 5
- 230000002265 prevention Effects 0.000 description 5
- 229920003169 water-soluble polymer Polymers 0.000 description 5
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 229920002472 Starch Polymers 0.000 description 3
- 239000011230 binding agent Substances 0.000 description 3
- 239000005018 casein Substances 0.000 description 3
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 3
- 235000021240 caseins Nutrition 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 230000005494 condensation Effects 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- 238000010422 painting Methods 0.000 description 3
- -1 polyethylene Polymers 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- 239000008107 starch Substances 0.000 description 3
- 235000019698 starch Nutrition 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 239000002612 dispersion medium Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000003292 glue Substances 0.000 description 2
- 238000007646 gravure printing Methods 0.000 description 2
- 229920000609 methyl cellulose Polymers 0.000 description 2
- 239000001923 methylcellulose Substances 0.000 description 2
- 235000010981 methylcellulose Nutrition 0.000 description 2
- 239000004570 mortar (masonry) Substances 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 229920002223 polystyrene Polymers 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 238000012546 transfer Methods 0.000 description 2
- JHPBZFOKBAGZBL-UHFFFAOYSA-N (3-hydroxy-2,2,4-trimethylpentyl) 2-methylprop-2-enoate Chemical compound CC(C)C(O)C(C)(C)COC(=O)C(C)=C JHPBZFOKBAGZBL-UHFFFAOYSA-N 0.000 description 1
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 1
- FHVDTGUDJYJELY-UHFFFAOYSA-N 6-{[2-carboxy-4,5-dihydroxy-6-(phosphanyloxy)oxan-3-yl]oxy}-4,5-dihydroxy-3-phosphanyloxane-2-carboxylic acid Chemical compound O1C(C(O)=O)C(P)C(O)C(O)C1OC1C(C(O)=O)OC(OP)C(O)C1O FHVDTGUDJYJELY-UHFFFAOYSA-N 0.000 description 1
- 244000215068 Acacia senegal Species 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 229920001353 Dextrin Polymers 0.000 description 1
- 239000004375 Dextrin Substances 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000001856 Ethyl cellulose Substances 0.000 description 1
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 239000004606 Fillers/Extenders Substances 0.000 description 1
- 229920002907 Guar gum Polymers 0.000 description 1
- 229920000084 Gum arabic Polymers 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- 229920001479 Hydroxyethyl methyl cellulose Polymers 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- SJEYSFABYSGQBG-UHFFFAOYSA-M Patent blue Chemical compound [Na+].C1=CC(N(CC)CC)=CC=C1C(C=1C(=CC(=CC=1)S([O-])(=O)=O)S([O-])(=O)=O)=C1C=CC(=[N+](CC)CC)C=C1 SJEYSFABYSGQBG-UHFFFAOYSA-M 0.000 description 1
- 244000046052 Phaseolus vulgaris Species 0.000 description 1
- 235000010627 Phaseolus vulgaris Nutrition 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- 229920002978 Vinylon Polymers 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- 239000000205 acacia gum Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000980 acid dye Substances 0.000 description 1
- 125000005396 acrylic acid ester group Chemical group 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 229940072056 alginate Drugs 0.000 description 1
- 235000010443 alginic acid Nutrition 0.000 description 1
- 229920000615 alginic acid Polymers 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 239000003125 aqueous solvent Substances 0.000 description 1
- 239000000981 basic dye Substances 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 235000010418 carrageenan Nutrition 0.000 description 1
- 239000000679 carrageenan Substances 0.000 description 1
- 229920001525 carrageenan Polymers 0.000 description 1
- 229940113118 carrageenan Drugs 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 239000008119 colloidal silica Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 235000019425 dextrin Nutrition 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 235000019325 ethyl cellulose Nutrition 0.000 description 1
- 229920001249 ethyl cellulose Polymers 0.000 description 1
- 238000007667 floating Methods 0.000 description 1
- 239000000665 guar gum Substances 0.000 description 1
- 235000010417 guar gum Nutrition 0.000 description 1
- 229960002154 guar gum Drugs 0.000 description 1
- 229920000591 gum Polymers 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 229920000592 inorganic polymer Polymers 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 238000009940 knitting Methods 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 239000013521 mastic Substances 0.000 description 1
- 239000000983 mordant dye Substances 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 238000007645 offset printing Methods 0.000 description 1
- 229920000620 organic polymer Polymers 0.000 description 1
- 229920001277 pectin Polymers 0.000 description 1
- 239000001814 pectin Substances 0.000 description 1
- 235000010987 pectin Nutrition 0.000 description 1
- 239000011120 plywood Substances 0.000 description 1
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 239000002964 rayon Substances 0.000 description 1
- 239000000985 reactive dye Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 238000007650 screen-printing Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000000988 sulfur dye Substances 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- OLSOUGWNONTDCK-UHFFFAOYSA-J tetrasodium 5-amino-3-[[4-[4-[(8-amino-1-hydroxy-3,6-disulfonatonaphthalen-2-yl)diazenyl]-3-methoxyphenyl]-2-methoxyphenyl]diazenyl]-4-hydroxynaphthalene-2,7-disulfonate Chemical compound [Na+].[Na+].[Na+].[Na+].C1=C(S([O-])(=O)=O)C=C2C=C(S([O-])(=O)=O)C(N=NC3=CC=C(C=C3OC)C=3C=C(C(=CC=3)N=NC=3C(=CC4=CC(=CC(N)=C4C=3O)S([O-])(=O)=O)S([O-])(=O)=O)OC)=C(O)C2=C1N OLSOUGWNONTDCK-UHFFFAOYSA-J 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
- 239000000984 vat dye Substances 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 238000004078 waterproofing Methods 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 description 1
Landscapes
- Application Of Or Painting With Fluid Materials (AREA)
- Laminated Bodies (AREA)
Description
【発明の詳細な説明】
本発明は、構築物の天井、壁、床など、及び家
具、調度品などの装飾に於いて、深みを有する様
に意匠模様が表面に浮き出す画期的な意匠の浮絵
模様版を製造する方法に関するものである。DETAILED DESCRIPTION OF THE INVENTION The present invention provides an innovative design in which a deep design pattern stands out on the surface in the decoration of ceilings, walls, floors, etc. of buildings, furniture, furnishings, etc. The present invention relates to a method of manufacturing an uki-e pattern plate.
従来より天井、壁、床等、及び家具、調度品等
の構築物の装飾の一つとして、表面に各種塗料を
塗装する方法がとられていた。塗料を塗装するこ
とにより被装飾面の防錆、防水、結露防止、ヒビ
割れ防止、防カビといつた機能上の効果を提供す
ることはできるが装飾性に於いては、単に色彩や
艶や、塗装面形状を変化させ得る程度の画一的な
ものにとどまらざるを得なかつた。 BACKGROUND ART Conventionally, as a decoration of structures such as ceilings, walls, floors, etc., and furniture and furnishings, a method has been used to apply various paints to the surfaces. By applying paint, it is possible to provide functional effects such as rust prevention, waterproofing, dew condensation prevention, crack prevention, and mold prevention to the decorated surface, but in terms of decoration, it is not just about color, gloss, etc. However, it had no choice but to remain uniform to the extent that the shape of the painted surface could be changed.
本発明は、この点に観み、特殊インキで模様を
施した印刷物と水系塗料との組合せで単色の塗料
層に下地の印刷模様を滲出させることにより従来
の印刷技術をもつてしても表現でき得ない深みの
ある独特な風合の模様を発現する方法を提供する
ものである。 In view of this point, the present invention combines a printed matter with a pattern made with special ink and a water-based paint to exude the underlying printed pattern into a monochromatic paint layer, which can be expressed even with conventional printing technology. This provides a method for creating patterns with depth and unique texture that cannot be achieved.
すなわち本発明は、塗料のもつ機能性を具備さ
せつつ、印刷による豊富な模様、柄を乾燥塗膜中
に転移せしめることにより装飾性に富んだ多種多
様な模様、柄を発現せしめるものであり、しかも
発現する模様、柄も壁装材の表面模様を構成する
インキが塗膜中に溶出、転移する際の時間的な要
因や、塗料の粘度的要因の作用等により微妙に変
化するため画一的にはならず、従来の印刷技術を
もつてしても得難い模様、柄、風合を得ることが
できるものである。 In other words, the present invention enables a wide variety of highly decorative patterns and patterns to be expressed by transferring the rich patterns and patterns by printing into a dry coating film while providing the functionality of a paint. Moreover, the patterns and patterns that appear are not uniform because they vary slightly due to factors such as the time factor when the ink that makes up the surface pattern of the wall covering material dissolves and transfers into the paint film, and the action of the viscosity factor of the paint. It is possible to obtain patterns, patterns, and textures that are difficult to obtain using conventional printing techniques.
本発明の目的は、構築物の天井、壁、床等、及
び家具、調度品等の装飾に於いて、従来にない模
様柄、風合を現出しつつ、被装飾部材の保護機能
をも同時に満足せしめる画期的な技術手段を提供
することである。 The purpose of the present invention is to create unprecedented patterns and textures in the decoration of ceilings, walls, floors, etc. of structures, furniture, furnishings, etc., while simultaneously satisfying the protection function of the decorated members. The goal is to provide innovative technological means to encourage people to do more.
この目的は、水溶性ビヒクル中に、主要な着色
材料として染料を含有したインキを使用して、セ
ルローズ紙、合成紙、天然繊維布、合成繊維布等
の可撓性、折り曲げ性のある基材に、意匠性を有
する模様、柄を印刷し、天井、壁、床等及び家
具、調度品等の構築物もしくは、ケイ酸カルシウ
ム板、フレキシブル板等の躯体板に貼着した後、
その印刷表面に、不透明な水系塗料を塗着し、該
水系塗料中に前記模様、柄を、表面まで溶出転移
めしせることによつて達成される。 The purpose is to use inks containing dyes as the primary coloring material in a water-soluble vehicle to print on flexible, bendable substrates such as cellulose paper, synthetic paper, natural fiber cloth, synthetic fiber cloth, etc. After printing a design pattern or design on the material and pasting it on the ceiling, wall, floor, etc., or structures such as furniture and furnishings, or building blocks such as calcium silicate boards and flexible boards,
This is achieved by applying an opaque water-based paint to the printing surface and eluating and transferring the pattern or pattern into the water-based paint to the surface.
以下に本発明の構成を詳細に説明する。 The configuration of the present invention will be explained in detail below.
本発明に於いて使用する可撓性、折り曲げ性の
ある基材として、まずセルローズ紙とは、和紙、
洋紙いずれでもよく、又合成樹脂等により耐水加
工された種類のものでも一向に差し仕えない。又
合成紙とは、ポリスチレン、ポリエチレン、ポリ
プロピレン、ポリ塩化ビニール等を素材として、
それに紙状の性質を与える加工をしたものであ
り、後述するインキで印刷可能なものであればい
ずれも使用することができる。又天然繊維布とし
ては、木綿布、麻布、絹布等が挙げられる。又合
成繊維布としては、レーヨン布、アクリル布、ポ
リエステル布、ナイロン布、ビニロン布、あるい
は上記した天然繊維または合成繊維の素材の２種
類以上を組み合わせた混紡布等が挙げられる。又
その他に上記した編織によらないで加工された不
織布も本発明に於ける装飾布の基材として使用で
きる。 First, cellulose paper is used as a flexible and bendable base material to be used in the present invention.
Any type of Western paper may be used, and even one that has been treated to be water-resistant with synthetic resin or the like will not pose a problem. Synthetic paper is made from polystyrene, polyethylene, polypropylene, polyvinyl chloride, etc.
It is processed to give it paper-like properties, and any material that can be printed with the ink described below can be used. Examples of the natural fiber cloth include cotton cloth, linen cloth, and silk cloth. Examples of the synthetic fiber cloth include rayon cloth, acrylic cloth, polyester cloth, nylon cloth, vinylon cloth, and a blended cloth in which two or more of the above-mentioned natural fibers or synthetic fiber materials are combined. In addition, nonwoven fabrics processed without the above-mentioned knitting or weaving process can also be used as the base material of the decorative fabric in the present invention.
本発明に於ける水溶性ビヒクルとは、水溶性ポ
リマーもしくは、合成樹脂エマルジヨンであつ
て、水溶媒中で安定に溶解もしくは分散する有機
高分子体をいう。水溶性ポリマーとしては、カゼ
イン澱粉、デキストリン、メチルセルロース、エ
チルセルロース、カルボキシルメチルセルロー
ス、ヒドロキシエチルメチルセルロース、アラビ
アゴム、グアーガム、カラギーナン、ザンサンガ
ム、ロールカストビーンガム、ペクチン、アルギ
ン酸塩、ポリビニール、膠等が挙げられる。又合
成樹脂エマルジヨンとしては、アクリル酸エステ
ル、メタアクリル酸エステル、酢酸ビニール、塩
化ビニリデン、エチレン、酢酸ビニール共重合
体、酢酸ビニール・バーサチツク酸共重合体等が
単独もしくは２種類以上の共重合体、ないしはブ
レンド物として挙げられる。又上記した水溶性ポ
リマーとの併用も差し仕えない。 The water-soluble vehicle in the present invention refers to an organic polymer that is a water-soluble polymer or a synthetic resin emulsion that is stably dissolved or dispersed in an aqueous solvent. Examples of water-soluble polymers include casein starch, dextrin, methylcellulose, ethylcellulose, carboxymethylcellulose, hydroxyethylmethylcellulose, gum arabic, guar gum, carrageenan, xanthan gum, roll cast bean gum, pectin, alginate, polyvinyl, glue, and the like. As the synthetic resin emulsion, acrylic ester, methacrylic ester, vinyl acetate, vinylidene chloride, ethylene, vinyl acetate copolymer, vinyl acetate/versatlic acid copolymer, etc. alone or a copolymer of two or more types, or as a blend. In addition, it is not a problem to use it in combination with the above-mentioned water-soluble polymers.
本発明で用いられる染料とは、直接染料、反応
染料、建染染料、媒染染料、硫化染料、酸性染料
等があげられる。 Dyes used in the present invention include direct dyes, reactive dyes, vat dyes, mordant dyes, sulfur dyes, acid dyes, and the like.
本発明に於ける不透明な水系塗料とは、水を基
本的に溶媒又は分散媒としたすべての塗料を意味
するもので、塗膜形成主要素として、水溶性ポリ
マーあるいは合成樹脂エマルジヨン、又はコロイ
ダルシリカのごとき無機質高分子を用い、必要に
応じて炭酸カルシカム、クレー、タルク、硅石粉
等の体質顔料メチルセルロース、ポリアクリル酸
ソーダ等の増粘剤、消泡剤、防腐剤、界面活性
剤、着色顔料等を添加混合せしめたものである。
該水系塗料は、一般的にフラツト塗料、スチツプ
ル塗料、吹付塗料、マスチツク塗料、弾性塗料、
艶有り塗料、コンクリート塗料、結露防止塗料等
であり、機能面作業面、形状付与面等の観点より
種々に呼称されるものである。 In the present invention, opaque water-based paints refer to all paints that basically use water as a solvent or dispersion medium, and include water-soluble polymers, synthetic resin emulsions, or colloidal silica as the main component for forming the paint film. Using inorganic polymers such as, if necessary, extender pigments such as calcium carbonate, clay, talc, silica powder, methylcellulose, thickeners such as sodium polyacrylate, antifoaming agents, preservatives, surfactants, and coloring pigments. etc. are added and mixed.
The water-based paints generally include flat paints, stipple paints, spray paints, mastic paints, elastic paints,
These are glossy paints, concrete paints, anti-condensation paints, etc., and are variously called from the viewpoint of functional surfaces, work surfaces, shape-imparting surfaces, etc.
本発明を構成する技術手段を、上記した素材中
一つの例を使用して以下に詳細に説明する。 The technical means constituting the present invention will be explained in detail below using one example of the above-mentioned materials.
まず第１に上記セルローズ紙等に、染料を含有
するインキを用いて任意の模様、柄を印刷する。
もし該インキ以外のインキを用いた場合には後述
する水系塗料を塗装した際に、該インキが不透明
な水系塗料中に滲出することなく隠蔽されてしま
い浮絵模様が形成できなくなる。本発明のごとく
水系塗料中に、印刷されたインキが表面まで滲出
するためには、水系塗料中の溶媒水もしくは分散
媒水に、印刷されたインキのバインダーが溶解、
もしくはバインダーと染料とが結合力の低下を起
すことが必要である点と、バインダーに包含され
た着色材料が水系塗料中に拡散溶出する必要があ
る。 First, an arbitrary pattern or design is printed on the cellulose paper or the like using ink containing a dye.
If an ink other than the above-mentioned ink is used, when the water-based paint described later is applied, the ink will not bleed into the opaque water-based paint and will be hidden, making it impossible to form an uki-e pattern. In order for the printed ink to ooze out to the surface of the water-based paint as in the present invention, the binder of the printed ink must be dissolved in the solvent water or dispersion medium water in the water-based paint.
Alternatively, it is necessary to reduce the bonding strength between the binder and the dye, and the coloring material contained in the binder must be diffused and eluted into the water-based paint.
本発明者等は、この点を鋭意研究した結果、イ
ンキ中の水溶性ビヒクルと染料の組合せを見い出
したのである。又本発明に於いて、該インキをセ
ルローズ紙等の基材に印刷する方法としては、従
来からの各種印刷機（オフセツト印刷機、グラビ
ア印刷機、スクリーン印刷機等）を使用して容易
に行うことができる。又該基材に印刷する前に、
基材の裏面に再湿粘着加工あるいは粘着加工を施
しておいても一向に差し仕えないことは言うまで
もない。 As a result of intensive research into this point, the present inventors discovered a combination of a water-soluble vehicle and a dye in the ink. In addition, in the present invention, the ink can be easily printed on a base material such as cellulose paper using various conventional printing machines (offset printing machine, gravure printing machine, screen printing machine, etc.). be able to. Also, before printing on the base material,
It goes without saying that applying rewetting adhesive processing or adhesive processing to the back side of the base material will not cause any problem.
次に、上記した方法で作成した装飾材を構築物
の天井、壁、床など、及び家具、調度品等に接着
剤（例えば、澱粉糊、合成樹脂エマルジヨン、水
溶性ポリマー、合成樹脂ワニス等）を使用して貼
着するか又は、あらかじめケイ酸カルシウム板、
フレキシブル板、樹脂板、鉄板、合板、セメント
板、シージング板等の躯体板に同様な方法で貼着
する。ただし躯体板に貼着した場合には、該躯体
板を構築物の壁、天井等に施工することによつ
て、該装飾材面を露出させることになる。上記の
方法によつて、構築物に直接又は間接的に該装飾
材を施工した後に、前記水系塗料を塗装する。こ
の塗装方法としては、従来からの塗装技術を用い
ればよく例えば、スプレー、ローラー、ハケ等を
使用して行うことができる。しかしながら塗装す
るに際して、水系塗料の粘度を水で希釈する等し
て50000センチポイズ（ブルツクフイールド型回
転粘度計で12RPM値）以下に調整してから後に
行なわなければならない。50000センチポイズ以
上では、装飾材中の着色材料が滲出しないために
浮絵模様が形成されない。又塗装する水系塗料の
塗装時点での厚みが５ｍ／ｍ以上になると装飾材
中の着色材料が滲出しても、水系塗料の表面層近
くまで達成せずに結果として、浮絵模様が形成さ
れない。 Next, the decorative material created by the above method is applied to the ceiling, walls, floor, etc. of the structure, as well as furniture, furniture, etc. with an adhesive (e.g., starch paste, synthetic resin emulsion, water-soluble polymer, synthetic resin varnish, etc.). Paste using or pre-calcium silicate plate,
It is attached in the same way to frame boards such as flexible boards, resin boards, iron boards, plywood, cement boards, sheathing boards, etc. However, if it is attached to a building frame board, the decorative material surface will be exposed by attaching the building board to the wall, ceiling, etc. of the structure. After applying the decorative material directly or indirectly to the structure by the method described above, the water-based paint is applied. For this coating method, any conventional coating technique may be used, and for example, spraying, rollers, brushes, etc. may be used. However, before painting, the viscosity of the water-based paint must be adjusted to less than 50,000 centipoise (12 RPM value using a Bruckfield rotational viscometer) by diluting it with water, etc. At 50,000 centipoise or higher, the coloring material in the decorative material does not bleed out, so no ukie pattern is formed. Furthermore, if the thickness of the water-based paint at the time of application is 5 m/m or more, even if the coloring material in the decorative material oozes out, it will not reach near the surface layer of the water-based paint, and as a result, no floating pattern will be formed.
以上のような方法で装飾材面の水系塗料を塗装
すると、該水系塗料が乾燥硬化進行中に、装飾材
が有する模様、柄が微妙に変化し転移することに
より、従来にない独特な風合を現出せしめる。又
多種多様な模様等を表現しつつ、水系塗料のもつ
機能性を構築物に付与できることも本発明の大き
な特徴の一つである。 When a water-based paint is applied to the surface of a decorative material using the method described above, the patterns and patterns of the decorative material change and transfer slightly while the water-based paint dries and hardens, creating a unique texture that has never existed before. make it appear. Another major feature of the present invention is that it can express a wide variety of patterns while imparting the functionality of water-based paints to structures.
本発明の浮絵模様版製造方法に於いては、構築
物の天井、壁、床等の装飾に於いて、従来にない
独特な風合を提供するばかりか、構築物を構成す
る各部材に要求され得る性能も、従来からの水系
塗料を相互に選択することにより達せられる特徴
を有するものである。 In the method of manufacturing a Uki-e pattern plate of the present invention, it not only provides a unique texture that has not been seen before in the decoration of the ceiling, walls, floor, etc. of a structure, but also provides a unique texture that is required for each member constituting the structure. Performance also has characteristics that can be achieved by mutually selecting conventional water-based paints.
以下に実施例を詳述する。なお実施例中、部と
あるのは、水べて重量部を表わす。 Examples will be described in detail below. In the examples, parts refer to parts by weight.
実施例 １
赤インキの配合
水 25
イソプロピルアルコール 35
エチルセロソルブ 15
ナトリウムカゼイン ５
ヒドロキシエチルセルローズ 10
直接染料（アイゼンフアーストレツドFA） 10
黄色インキの配合
赤色インキと同配合とし、直接染料としてア
イゼンペーパーイエロー2GH
青色インキの配合
赤色インキと同配合とし、直接染料としてア
イゼンダイレクトスカイブルー5B
上記した配合のインキ３色を使用して、グラビ
ア印刷機にて、花柄模様をポリスチレン合成紙に
印刷し浮絵模様版を作成した。該浮絵模様版を６
畳の応接間に、酢酸エマルジヨン系の接着剤を用
いて、貼着した。その後24時間経過し接着剤が乾
燥したのを確認してから、水系塗料（商品名：ケ
ツロナイン：菊水化学工業社製結露防止塗料）を
スプレーガンを用いて、厚さ１ｍ／ｍに塗装し
た。なおこの水系塗料の塗装した際の粘度は、
2000センチポイズであつた。乾燥後、浮絵模様版
に印刷されていた花柄模様が水系塗料中に、微妙
に歪曲しぼけた浮絵模様として転移したことが確
認できた。又該水系塗料は、結露を防止する機能
を有していたが、塗装後一冬期間観察した結果完
全に結露を防止できたことも確認した。Example 1 Red ink formulation Water 25 Isopropyl alcohol 35 Ethyl cellosolve 15 Sodium casein 5 Hydroxyethyl cellulose 10 Direct dye (Eisenfarstred FA) 10 Yellow ink formulation The same formulation as the red ink, with Eisen Paper Yellow 2GH as the direct dye. Blue ink composition Same composition as red ink, Eisen Direct Sky Blue 5B as direct dye.Using the three colors of ink with the above composition, a floral pattern was printed on polystyrene synthetic paper using a gravure printing machine. It was created. The Uki-e pattern version is 6
It was attached to the tatami living room using acetic acid emulsion adhesive. After 24 hours had passed and it was confirmed that the adhesive had dried, a water-based paint (trade name: Ketsuronine: anti-condensation paint manufactured by Kikusui Chemical Co., Ltd.) was applied to a thickness of 1 m/m using a spray gun. The viscosity of this water-based paint when applied is
It was 2000 centipoise. After drying, it was confirmed that the floral pattern printed on the uki-e pattern plate was transferred to the water-based paint as a slightly distorted and blurred uki-e pattern. Furthermore, although the water-based paint had a function of preventing dew condensation, it was confirmed through observation for one winter after painting that it was able to completely prevent dew condensation.
実施例 ２
実施例１に於けるインキ配合中ナトリウムカゼ
インをアクリル酸エステル合成樹脂エマルジヨン
に置き替え、実施例１と同様な方法で実施した
が、全く同様な結果を得ることが確認できた。Example 2 The same method as in Example 1 was conducted except that the sodium casein in the ink formulation in Example 1 was replaced with an acrylic acid ester synthetic resin emulsion, and it was confirmed that exactly the same results were obtained.
実施例 ３
実施例１に於けるインキ配合中、直接染料を塩
基性染料に置き換え、実施例１と同様な方法で実
施したが、全く同様な結果を得た。Example 3 The same method as in Example 1 was carried out except that the direct dye was replaced with a basic dye during the ink formulation in Example 1, and exactly the same results were obtained.
実施例 ４
実施例１と同様な方法で浮絵模様版を作成し、
該浮絵模様版をモルタル下地の廊下廻りに、澱粉
糊を用いて貼着した。その後24時間経過し、接着
剤が乾燥したのを確認してから、水系塗料（商品
名：ソフトワン：菊化学工業社製ヒビ割防止塗
料）をスプレーガンを用いて、厚さ0.5ｍ／ｍに
塗装した。なお水系塗料を塗装した際の粘度は、
1500センチポイズであつた。乾燥後、該浮絵模様
版に印刷された花柄模様が、水系塗料中に転移
し、従来からの印刷技術では得がたい独特な風合
の浮絵模様として転移したことが確認できた。又
該水系塗料は、ゴム弾性を有し下地に亀裂が生じ
ても塗膜が伸長することにより亀裂を隠蔽する機
能を有するものであるが、塗装後半年経過しても
なおかつ塗装表面に亀裂は全く見られなかつた。
念のため該装飾処理面を剥離したところ、モルタ
ル下地には、かなり亀裂が生じていた。このこと
から該水系塗料の機能が作用していることが確認
された。Example 4 A Uki-e pattern plate was created in the same manner as in Example 1,
The Uki-e pattern plate was attached to the mortar base around the corridor using starch glue. After 24 hours have passed, and after confirming that the adhesive has dried, use a spray gun to apply water-based paint (product name: Soft One: crack prevention paint manufactured by Kiku Kagaku Kogyo Co., Ltd.) to a thickness of 0.5 m/m. Painted on. The viscosity when applying water-based paint is
It was 1500 centipoise. After drying, it was confirmed that the floral pattern printed on the uki-e pattern plate was transferred into the water-based paint, and was transferred as an uki-e pattern with a unique texture that is difficult to obtain using conventional printing techniques. Furthermore, the water-based paint has rubber elasticity and has the ability to cover up cracks by elongating the paint film even if cracks occur in the base; however, even after 6 months of painting, there are still no cracks on the painted surface. I couldn't see it at all.
When I peeled off the decoratively treated surface just to be sure, I found that there were considerable cracks in the mortar base. From this, it was confirmed that the function of the water-based paint was working.
以上述べたとおり本発明の浮絵模様版製造方法
によればの塗料のもつ機能上の特性を有効に発揮
すると共に、従来にない独特な風合をもつ装飾性
に富んだ新規な浮絵模様版を提供することができ
るものであり、構築物の装飾にとつて新しい可能
性を生み出したと言つても過言ではない。 As described above, the method for producing an ukie pattern plate of the present invention not only effectively exhibits the functional characteristics of the paint, but also produces a novel ukie pattern plate rich in decorativeness with a unique texture that has not been seen before. It is no exaggeration to say that it has created new possibilities for the decoration of buildings.
Claims (1)
染料を含有したインキを使用して、セルローズ
紙、合成紙、天然繊維布、合成繊維布等の可撓
性、折り曲げ性のある基材に、意匠性を有する模
様、柄を印刷し、天井、壁、床等及び家具、調度
品等の構築物もしくは、ケイ酸カルシウム板、フ
レキシブル板等の躯体板に貼着した後、その印刷
表面に、不透明な水系塗料を塗着し、該水系塗料
中に前記模様、柄を、表面まで溶出転移せしめて
浮絵模様を形成することを特徴とする浮絵模様版
の製造方法。1. Using an ink containing a dye as the main coloring material in a water-soluble vehicle, designs can be applied to flexible and bendable substrates such as cellulose paper, synthetic paper, natural fiber cloth, and synthetic fiber cloth. After printing a unique pattern or pattern and pasting it on a structure such as a ceiling, wall, floor, etc. or furniture or furnishings, or a building block such as a calcium silicate board or a flexible board, an opaque material is applied to the printed surface. 1. A method for producing an uki-e pattern plate, which comprises applying a water-based paint and transferring the pattern into the water-based paint to the surface to form an uki-e pattern.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP5103183A JPS59177173A (en) | 1983-03-25 | 1983-03-25 | Manufacture of relief patterned plate |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP5103183A JPS59177173A (en) | 1983-03-25 | 1983-03-25 | Manufacture of relief patterned plate |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS59177173A JPS59177173A (en) | 1984-10-06 |
| JPS622868B2 true JPS622868B2 (en) | 1987-01-22 |
Family
ID=12875437
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP5103183A Granted JPS59177173A (en) | 1983-03-25 | 1983-03-25 | Manufacture of relief patterned plate |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS59177173A (en) |
-
1983
- 1983-03-25 JP JP5103183A patent/JPS59177173A/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS59177173A (en) | 1984-10-06 |
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