JPS62273297A - Detergent - Google Patents

Abstract

(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.

Description

【発明の詳細な説明】 ３、発明の詳細な説明 （産業上の利用分野） 本発明は、微粉末を混入した洗剤、特に白大理石の研磨
滓を混入した洗剤に関するものである。Detailed Description of the Invention 3. Detailed Description of the Invention (Field of Industrial Application) The present invention relates to a detergent mixed with fine powder, particularly a detergent mixed with white marble polishing slag.

〔発明の背景〕[Background of the invention]

従来、微粉末を混入した洗剤としては１例えば中性洗剤
に珪藻土、内窒、軽石、炭酸力ルシュウム等の混合粉末
を加えたクレンザ−が知られている。このクレンザ−は
２例えば食器、タイル、レンジフード等に付着した油分
を取るために多用されている。Conventionally, as detergents containing fine powders, for example, cleansers in which mixed powders of diatomaceous earth, inner nitrogen, pumice, lucium carbonate, etc. are added to a neutral detergent are known. This cleanser is often used to remove oil adhering to dishes, tiles, range hoods, etc., for example.

しかしながら、クレンザ−は珪藻土、自車。However, the cleanser is diatomaceous earth and my own car.

軽石、炭酸カルシュラム等の混合粉末が一般に研き粉と
しての機能を持たせるために多量添加されているため、
洗浄後に大量の水によって良く濯ぎ落とさないと粉末が
洗浄部分に残り、この残部を改めて洗浄する必要があっ
た。このためクレンザ−による洗浄には手間を要し、多
くの時間がかかった。A large amount of mixed powder such as pumice stone and calcilum carbonate is generally added to serve as a polishing powder.
If the powder is not rinsed thoroughly with a large amount of water after cleaning, the powder will remain on the cleaned area, and this residue will need to be cleaned again. Therefore, cleaning with a cleanser was troublesome and took a lot of time.

また、上記粉末はクレンザ−用としてその粒度を調整す
る必要があるが、その準備工程で微粉末にするためには
割高となるため、広い粒度分布の粒子を用いていた。従
って、洗浄時に食器等を傷つける虞れがあった。勿論１
粒度を細かくしたものも市販されているが、これはその
粒子を調えるために特別な処理を施す必要があったため
１食器洗い用のものに比して高価なものとなっていた。Further, the particle size of the above-mentioned powder needs to be adjusted for use in cleansers, but it is relatively expensive to make it into a fine powder in the preparation process, so particles with a wide particle size distribution have been used. Therefore, there is a risk of damaging tableware etc. during washing. Of course 1
Products with finer particles are also commercially available, but these require special treatment to control the particles, making them more expensive than products used for washing dishes.

〔発明の目的〕[Purpose of the invention]

本発明は上記従来の問題点を解決するためのもので、汚
れ落ちが良り、シかも濯ぎ残りがなく、安価にして洗浄
の対象物を選ばない洗剤を提供することを目的としてい
る。The present invention has been made to solve the above-mentioned conventional problems, and aims to provide a detergent that removes stains well, leaves no residue after rinsing, is inexpensive, and can be used on any object to be cleaned.

〔発明の構成〕[Structure of the invention]

上記目的を達成するため１本発明は界面活性剤２５〜５
０重量部と、白大理石の研磨滓７５〜５０重量部とから
成るものである。In order to achieve the above object, 1 the present invention uses surfactants 25 to 5
0 parts by weight and 75 to 50 parts by weight of white marble polishing slag.

ここに用いる界面活性剤は陰イオン界面活性剤、陽イオ
ン界面活性剤２両性界面活性剤、非イオン界面活性剤の
何れでも良い。The surfactant used here may be any of anionic surfactants, cationic surfactants, amphoteric surfactants, and nonionic surfactants.

また１本発明における白大理石の研磨滓は白大理石の砕
石を研磨して金魚・熱帯魚等の水槽や庭園等に敷く五色
砂利の白玉面を製造する過程で生じた一次滓を圧縮し、
脱水して得られたものである。In addition, the white marble polishing slag in the present invention is obtained by compressing the primary slag produced in the process of polishing crushed white marble to produce a white marble surface of five-colored gravel for use in aquariums for goldfish, tropical fish, etc., gardens, etc.
It is obtained by dehydration.

この白玉面の製造は第１図示のように白大理石の砕石を
研磨材と水と共に研磨機１に投入して研磨するため、そ
の過程で泥状の一次滓が極めて大量に排出される。この
−次滓は通常型枠に回収した後、圧縮機２により圧縮し
、脱水してブロック状にし、埋め立て地に運ばれて投棄
されるとともに、脱水により吐出した水は濾過器３によ
り濾過して前記研磨機１の研き用の水として再使用され
ている。To manufacture this white marble surface, as shown in the first figure, crushed white marble is put into a polishing machine 1 together with an abrasive material and water and polished, so a very large amount of mud-like primary slag is discharged during the process. This sludge is usually collected in a mold, compressed by a compressor 2, dehydrated and made into blocks, transported to a landfill and dumped, and the water discharged from the dehydration is filtered by a filter 3. The water is reused as polishing water for the polishing machine 1.

本発明にかかる洗剤は上記−次滓より得たブロック（脱
水後のブロック化しないものでもよい）を主原料とする
ものである。The detergent according to the present invention uses blocks obtained from the above-mentioned slag (which may not be formed into blocks after dehydration) as the main raw material.

前記ブロックを主原料として用いる場合は第２図示のよ
うに、これを適当なりラッシャー４により目安として０
．５〜２ｃｍ程度の大きさに砕き、その砕き片１０を界
面活性剤１１とともにミキサー５に投入して攪拌する。When using the block as the main raw material, as shown in the second figure, use the rasher 4 as a guide to reduce the block to 0.
．． It is crushed to a size of about 5 to 2 cm, and the crushed pieces 10 are put into a mixer 5 together with a surfactant 11 and stirred.

この場合。in this case.

通常の洗剤と同様に必要に応じて助剤１２を添加するこ
とは任意である。As with ordinary detergents, it is optional to add auxiliary agents 12 as necessary.

前記白玉面の製造過程で生じた白大理石の研磨滓はコー
ルタ−・カウンター法によれば９粒度分布が第１表に示
すように非常に細かい粒子から成っていることが確認で
きる。しかも、その分布は粒子数及び体積から明確なよ
うに細かい粒子が大半を占めているから、これを洗剤に
混合する微粉末として利用すれば被洗浄物に傷付ける虞
れはないことに着目して本発明を完成した。According to the Coulter Counter method, it can be confirmed that the white marble polishing slag produced in the manufacturing process of the white marble surface consists of extremely fine particles with a particle size distribution of 9 as shown in Table 1. Furthermore, as it is clear from the number and volume of the particles that they are distributed, the majority of them are fine particles, so if you use them as a fine powder to be mixed with detergent, there is no risk of damaging the items being cleaned. The invention has been completed.

第１表 また２本発明において、前述の如く、界面活性剤を２５
〜５０重量部、白大理石の研磨滓を７５〜５０重量部と
したのは界面活性剤が２５重量部未満では白大理石の研
磨滓が多くなり過ぎるため２両者の混合が十分に行なわ
れず、被洗浄物の洗浄後に白大理石の研磨滓が残るため
である。一方、界面活性剤が５０重量部を超えると、泡
切れや濯ぎ性が悪くなるし、界面活性剤によるベトつき
が生しる等の不具合が実験的に確認されたからである。Table 1 and 2 In the present invention, as mentioned above, 25% of the surfactant
~50 parts by weight, and 75 to 50 parts by weight of white marble polishing slag is because if the surfactant is less than 25 parts by weight, there will be too much white marble polishing slag, and the two will not be mixed sufficiently. This is because polishing slag of white marble remains after cleaning the object. On the other hand, if the surfactant exceeds 50 parts by weight, it has been experimentally confirmed that problems such as delathering, poor rinsing properties, and stickiness caused by the surfactant occur.

〔実施例〕〔Example〕

ＡＢＳと第１表に示す粒度分布を有する白大理石の研磨
滓を１次に示す第２表のように９種類のものを用意する
とともに、陶器製食器、ガラス鍋、流し台のステンレス
水槽、タイル等の通常品と、油を全面に付着したレンジ
フードの洗浄物とを用意し、それぞれについて洗浄力及
び濯ぎ性を検査した。Nine types of ABS and white marble polishing slag with the particle size distribution shown in Table 1 are prepared as shown in Table 2, as well as ceramic tableware, glass pots, stainless steel water tanks for sinks, tiles, etc. A regular product and a dishwashed range hood with oil all over its surface were prepared, and the detergency and rinsability of each was tested.

第２表 先ず、陶器製食器、ガラス鍋、流し台のステンレス水槽
、タイル等の通常品について考察すると１例■の場合に
は界面活性剤が少なすぎて研磨滓とよく混ざらなかった
ので、洗剤として使用しなかった１例■の場合には通常
品を洗浄する時に傷をつけることはなかったが、濯いで
も粉が残った。Table 2 First, when considering ordinary items such as ceramic tableware, glass pots, stainless steel water tanks for sinks, and tiles, in the case of example 1, there was too little surfactant and it did not mix well with the polishing slag, so it could be used as a detergent. In case (1), which was not used, there was no damage to the regular product when it was washed, but powder remained even after rinsing.

例■の場合には汚れ落ちが良く１通常品に傷をつけるこ
とがないし、濯いだときに粉が残らず、しかも例■に比
して濯ぎ易かった０例■〜例■の場合も前記例■とはソ
゛同様であった。In the case of Example ■, the stains were removed well; 1 did not damage the regular product, did not leave powder behind when rinsed, and was easier to rinse than in Example ■. The procedure was similar to that of Example ① above.

例■の場合には汚れ落ちが良く１通常品に傷付けること
がない点において３例■〜■と同様であったが、濯ぎの
点でやや劣るとともに、僅かに泡切れが悪かった８例■
の場合には例■に比して濯ぎが悪くなるとともに、泡切
れが悪かった６例■の場合には例■に比して更に濯ぎ性
が悪くなるとともに、洗浄後に手に少しベトつき怒が残
った。In case of Example ■, stain removal was good and 1. It was similar to Examples 3 to ■ in that it did not damage the regular product, but it was slightly inferior in terms of rinsing and it was slightly difficult to remove bubbles in Case 8
In case 6, the rinsing performance was worse than in Example ■, and in the case of Case 6, which had poor foam removal, the rinsing performance was even worse than in Example ■, and the hands were a little sticky and irritated after washing. remained.

以上の結果よりして例０〜例■の場合゛には被洗浄品に
傷をつけず、濯ぎが簡単になるということが判明した。From the above results, it was found that in Examples 0 to 2, the items to be cleaned were not damaged and could be easily rinsed.

また、油汚れの酷いレンジフードについて。Also, about the range hood that has a lot of oil stains.

例■〜■を考察したところ９例■及び■は殆ど使用でき
なった。After examining Examples ■ to ■, 9 cases ■ and ■ could hardly be used.

例０〜例■の場合にはそれぞれスポンジに含ませてレン
ジフードの油を拭き取ったところ。In the case of Examples 0 to 2, each oil was soaked in a sponge and wiped off from the range hood.

汚れは節単に取れた。The dirt was easily removed.

例０〜例■の場合には油を取ることはできたが９通常品
の場合と同様に濯ぎが悪く、洗浄後に手がベトつく等の
不具合があった。In the cases of Examples 0 to 2, the oil could be removed, but as in the case of the regular product 9, rinsing was difficult and there were problems such as hands becoming sticky after washing.

以上の結果から１例■〜■の場合には極度の油汚れであ
っても簡単に落ち２手にベトつきが残らないことが判明
した。From the above results, it was found that in cases 1 to 2, even extremely oily stains were easily removed and did not leave any sticky residue on the hands.

更に１例■〜■の場合には油汚れの手をこれらで洗うと
良く落ちて、濯ぎが簡単であり、ベトつき感が残らず、
サソバリとした洗浄感を得ることができた。Furthermore, in the case of cases ■~■, washing your oily hands with these removes them well, rinsing is easy, and there is no sticky feeling left behind.
I was able to get a refreshing cleansing feeling.

〔発明の効果〕〔Effect of the invention〕

以上説明したように本発明に係る洗剤は界面活性剤２５
〜５０重量部と、白大理石の研磨滓７５〜５０重量部と
を主剤としたことを特徴としているから、白大理石の研
磨滓が食器等に付着した油との剥離性が良く１食器等の
通常の被洗浄品は勿論のこと、油汚れのひどいレンジフ
ード等に対しても洗浄力が良好で洗浄時に傷をつけるこ
とがない。As explained above, the detergent according to the present invention has 25 surfactants.
-50 parts by weight and 75 to 50 parts by weight of white marble polishing slag as the main ingredients, so the white marble polishing slag has good peelability from oil adhering to tableware, etc. It has good cleaning power not only for ordinary items to be cleaned, but also for oil-stained range hoods, etc., and does not cause any damage when cleaning.

また、界面活性剤との馴染性がよいため、濯ぎが而単に
なり、微粉末が洗浄面は勿論、洗浄場所に残ることもな
い。In addition, since it has good compatibility with surfactants, rinsing is simple and no fine powder remains on the cleaning surface or in the cleaning area.

さらに１本発明は白大理石を研磨して玉石を製造する過
程で得られる廃棄物として捨てていた研磨滓の粒度が細
かいことに着目し、これを主原料として利用したもので
あるため、安価な洗剤を提供できるとともに、資源の再
利用の観点からも極めて有利である。Furthermore, the present invention focuses on the fine particle size of polishing slag, which was previously discarded as waste obtained in the process of polishing white marble to manufacture cobblestones, and uses this as the main raw material, making it inexpensive. In addition to being able to provide detergent, it is extremely advantageous from the viewpoint of resource reuse.

【図面の簡単な説明】[Brief explanation of the drawing]

第１図は白大理石の玉石を製造する過程を示すブロック
図、第２図は洗剤を製造する過程を示すブロック図であ
る。 １〇−砕き片（白大理石の研磨滓） １１−・界面活性剤 第１図 第２図FIG. 1 is a block diagram showing the process of manufacturing white marble boulders, and FIG. 2 is a block diagram showing the process of manufacturing detergent. 10- Crushed pieces (white marble polishing slag) 11- Surfactant Figure 1 Figure 2

Claims (2)

【特許請求の範囲】[Claims] （１）界面活性剤２５〜５０重量部と、白大理石の研磨
滓７５〜５０重量部とを主剤とすることを特徴とする洗
剤。(1) A detergent characterized by containing 25 to 50 parts by weight of a surfactant and 75 to 50 parts by weight of white marble polishing slag as main ingredients. （２）前記白大理石の研磨滓の粒度分布が、粒子数分布
として粒径４〜３２μ、体積分布として粒径４〜８０．
６μの範囲である特許請求の範囲第１項記載の洗剤。(2) The particle size distribution of the white marble polishing slag is 4 to 32 μm in particle number distribution and 4 to 80 μm in volume distribution.
The detergent according to claim 1, which has a particle diameter of 6μ.