JPS62267109A - Molding tool - Google Patents
Molding toolInfo
- Publication number
- JPS62267109A JPS62267109A JP11088486A JP11088486A JPS62267109A JP S62267109 A JPS62267109 A JP S62267109A JP 11088486 A JP11088486 A JP 11088486A JP 11088486 A JP11088486 A JP 11088486A JP S62267109 A JPS62267109 A JP S62267109A
- Authority
- JP
- Japan
- Prior art keywords
- alumina cement
- cement
- water
- powder
- binder
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000465 moulding Methods 0.000 title claims description 14
- 239000004568 cement Substances 0.000 claims abstract description 29
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000000843 powder Substances 0.000 claims abstract description 16
- 239000000203 mixture Substances 0.000 claims abstract description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000003638 chemical reducing agent Substances 0.000 claims description 5
- 239000003607 modifier Substances 0.000 claims description 4
- 238000000034 method Methods 0.000 abstract description 11
- 239000011230 binding agent Substances 0.000 abstract description 7
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 abstract description 4
- 238000005452 bending Methods 0.000 abstract description 3
- 239000004640 Melamine resin Substances 0.000 abstract description 2
- 229920000877 Melamine resin Polymers 0.000 abstract description 2
- XFWJKVMFIVXPKK-UHFFFAOYSA-N calcium;oxido(oxo)alumane Chemical compound [Ca+2].[O-][Al]=O.[O-][Al]=O XFWJKVMFIVXPKK-UHFFFAOYSA-N 0.000 abstract description 2
- 238000006243 chemical reaction Methods 0.000 abstract description 2
- 150000007522 mineralic acids Chemical class 0.000 abstract description 2
- PSZYNBSKGUBXEH-UHFFFAOYSA-N naphthalene-1-sulfonic acid Chemical compound C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-N 0.000 abstract description 2
- 239000002245 particle Substances 0.000 abstract description 2
- 239000012024 dehydrating agents Substances 0.000 abstract 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 abstract 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 abstract 1
- 229910052783 alkali metal Inorganic materials 0.000 abstract 1
- 150000001340 alkali metals Chemical class 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 230000001629 suppression Effects 0.000 abstract 1
- 239000000835 fiber Substances 0.000 description 10
- 239000000463 material Substances 0.000 description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 8
- 238000001723 curing Methods 0.000 description 8
- -1 Fi sulfuric acid Chemical class 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 5
- 229910052751 metal Inorganic materials 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- 229910000831 Steel Inorganic materials 0.000 description 4
- 238000002474 experimental method Methods 0.000 description 4
- 238000009472 formulation Methods 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 239000010959 steel Substances 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 238000010276 construction Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000002347 injection Methods 0.000 description 3
- 239000007924 injection Substances 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- 229910001018 Cast iron Inorganic materials 0.000 description 2
- 229910000616 Ferromanganese Inorganic materials 0.000 description 2
- 229910000519 Ferrosilicon Inorganic materials 0.000 description 2
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
- 239000003677 Sheet moulding compound Substances 0.000 description 2
- 238000005266 casting Methods 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- 238000005520 cutting process Methods 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 238000006703 hydration reaction Methods 0.000 description 2
- DALUDRGQOYMVLD-UHFFFAOYSA-N iron manganese Chemical compound [Mn].[Fe] DALUDRGQOYMVLD-UHFFFAOYSA-N 0.000 description 2
- 238000004898 kneading Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000012071 phase Substances 0.000 description 2
- 239000012779 reinforcing material Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000004575 stone Substances 0.000 description 2
- 239000010409 thin film Substances 0.000 description 2
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- 229910052580 B4C Inorganic materials 0.000 description 1
- 229910052582 BN Inorganic materials 0.000 description 1
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 description 1
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- 241000218691 Cupressaceae Species 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 229910052581 Si3N4 Inorganic materials 0.000 description 1
- 229920002978 Vinylon Polymers 0.000 description 1
- 229910052936 alkali metal sulfate Inorganic materials 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910052849 andalusite Inorganic materials 0.000 description 1
- 239000010425 asbestos Substances 0.000 description 1
- 229910000963 austenitic stainless steel Inorganic materials 0.000 description 1
- 229910001570 bauxite Inorganic materials 0.000 description 1
- 229910052614 beryl Inorganic materials 0.000 description 1
- 238000000071 blow moulding Methods 0.000 description 1
- INAHAJYZKVIDIZ-UHFFFAOYSA-N boron carbide Chemical compound B12B3B4C32B41 INAHAJYZKVIDIZ-UHFFFAOYSA-N 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 239000000378 calcium silicate Substances 0.000 description 1
- 229910052918 calcium silicate Inorganic materials 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical class OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000000748 compression moulding Methods 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229910052593 corundum Inorganic materials 0.000 description 1
- 239000010431 corundum Substances 0.000 description 1
- 238000004512 die casting Methods 0.000 description 1
- 229910001651 emery Inorganic materials 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 238000009313 farming Methods 0.000 description 1
- 239000010881 fly ash Substances 0.000 description 1
- RRDQTXGFURAKDI-UHFFFAOYSA-N formaldehyde;naphthalene-2-sulfonic acid Chemical compound O=C.C1=CC=CC2=CC(S(=O)(=O)O)=CC=C21 RRDQTXGFURAKDI-UHFFFAOYSA-N 0.000 description 1
- 239000005350 fused silica glass Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010438 granite Substances 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
- 239000011396 hydraulic cement Substances 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- SZVJSHCCFOBDDC-UHFFFAOYSA-N iron(II,III) oxide Inorganic materials O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 1
- 239000010977 jade Substances 0.000 description 1
- 229910052865 lawsonite Inorganic materials 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000002557 mineral fiber Substances 0.000 description 1
- 239000006082 mold release agent Substances 0.000 description 1
- 150000004767 nitrides Chemical class 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000011028 pyrite Substances 0.000 description 1
- NIFIFKQPDTWWGU-UHFFFAOYSA-N pyrite Chemical compound [Fe+2].[S-][S-] NIFIFKQPDTWWGU-UHFFFAOYSA-N 0.000 description 1
- 229910052683 pyrite Inorganic materials 0.000 description 1
- 229910052895 riebeckite Inorganic materials 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- 229910052596 spinel Inorganic materials 0.000 description 1
- 239000011029 spinel Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000003460 sulfonic acids Chemical class 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 229910052613 tourmaline Inorganic materials 0.000 description 1
- 239000011032 tourmaline Substances 0.000 description 1
- 229940070527 tourmaline Drugs 0.000 description 1
- 238000001721 transfer moulding Methods 0.000 description 1
- UONOETXJSWQNOL-UHFFFAOYSA-N tungsten carbide Chemical compound [W+]#[C-] UONOETXJSWQNOL-UHFFFAOYSA-N 0.000 description 1
- 229910052845 zircon Inorganic materials 0.000 description 1
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C33/00—Moulds or cores; Details thereof or accessories therefor
- B29C33/38—Moulds or cores; Details thereof or accessories therefor characterised by the material or the manufacturing process
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は、各楕材料の成形の際に有用な成形型、特に高
強度セメント製の成形型に関する。DETAILED DESCRIPTION OF THE INVENTION [Industrial Field of Application] The present invention relates to a mold useful in molding various elliptical materials, particularly a mold made of high-strength cement.
従来、金属材料をプレス成形するための成形型、及び引
用成形、リアクション イン モールド（Ｒｅｒｃｔｉ
ｏｎ ｉｎ Ｍｏ１ｄ、以下１．ＲＩＭと略記すル）、
シート モールディング コンパウンド（５ｈｅｅｔ
Ｍｏｌｄｉｎｇ Ｃｏｍｐｏｕｎｄ、以下、ＳＭＣと略
記する）などの樹脂相の成形型として、一般に低融点合
金、鋳鉄及び鋼等の金網製のものが使用されている。し
かしながら、これら成形型の表作ｔよ、その工程が複雑
であり、製作日数が長いことから、金属に代りうるもの
で、かつ製作方法が簡便で経済的な材料による成形型の
開発が要望されている。Conventionally, molds for press molding metal materials, quotation molding, and reaction-in-mold (reaction-in-mold)
on in Mold, hereinafter 1. (abbreviated as RIM),
Sheet molding compound (5heet)
As molding molds for resin phase such as Molding Compound (hereinafter abbreviated as SMC), molds made of wire mesh made of low melting point alloys, cast iron, steel, etc. are generally used. However, since the manufacturing process of these molds is complicated and the production time is long, there is a demand for the development of molds made of materials that can replace metal, are simple to manufacture, and are economical. ing.
一方、土木、建築の分野で使用されているセメントコン
クリートは常温成形が可能であり、成形方法等が非常に
簡便な材料であるため成形型に利用することが可能であ
る。On the other hand, cement concrete, which is used in the fields of civil engineering and architecture, can be molded at room temperature and is a material that can be molded very easily, so it can be used in molds.
〔発明が解決【２ようとする問題点〕
しかしながら、それらは曲は強度あるいは硬度が低いた
め、樹脂成形型においては細い凸部等が破損すること、
プレス成形型においては、Ｒ部の摩耗が多い等の問題点
があり、よシ耐入力に優れた成形型の開発が要望されて
いる。[Problem to be solved by the invention [2]] However, since the bends have low strength or hardness, thin convex parts etc. in the resin mold may break.
Press molds have problems such as excessive wear on the R portion, and there is a demand for the development of molds with excellent resistance to force.
本発明の目的は、セメント製の成形型であるが、高強度
、特に高曲は強度及び高い硬度を持つ成形型を提供する
ことにある。An object of the present invention is to provide a mold made of cement that has high strength, particularly high bending strength and high hardness.
本発明を概説すれば、本発明は篩強度七メント製成形型
に関する発明でおって、アルミナセメント、超微粉、高
性能減水剤、硬化調整剤及び水を主成分とする組成物全
成形硬化してなることを特徴とする。To summarize the present invention, the present invention relates to a mold made of 7-mention sieve strength, and the present invention relates to a mold made of 7-mention sieve strength, in which a composition whose main components are alumina cement, ultrafine powder, a high-performance water reducing agent, a hardening modifier, and water is completely molded and hardened. It is characterized by being
以下、本発明について具体的に脱明する。The present invention will be explained in detail below.
本発明で使用されるアルミナセメントとはＣａＯをＣｓ
Ａｌ５Ｏｓ Ｖ Ａとすると、ＣＡ、ＣＡ、、ＣＩ
ｍＡ７ 等と示されるカルシウムアルミネートのうち少
なくとも１槓を主成分とする水硬化セメントである。組
成鉱物中の微を成分としてわずかの８１０．、Ｆθｓｏ
ｓ 、 Ｔｉ□、 等の成分を含んだものであっても
良く、水和活性のないＡｔ、Ｏｎや８１０雪などの無機
材料′ｔ−含んだものでも良い。これらの市販品として
Ｆｉ「デンカアルミナセメント１号」、「デンカアルミ
ナセメント２号」、「デンカハイアルミナセメント」〔
いずれも電気化学工業（株）製、商品名〕、「アサノア
ルミナセメント」〔日本セメント（株）製、商品名〕、
「アサヒホンジュ」〔旭硝子（株）裂、商品名〕などが
挙けられる。The alumina cement used in the present invention is CaO and Cs.
If Al5Os V A, then CA, CA, , CI
It is a hydraulic cement whose main component is at least one type of calcium aluminate, such as mA7. Composition Only 810. ,Fθso
It may contain components such as S, Ti□, etc., or it may contain inorganic materials such as At, On, and 810 snow which have no hydration activity. These commercially available products include Fi “Denka Alumina Cement No. 1,” “Denka Alumina Cement No. 2,” and “Denka High Alumina Cement.”
Both are manufactured by Denki Kagaku Kogyo Co., Ltd. (trade name), "Asano Alumina Cement" (manufactured by Nippon Cement Co., Ltd., trade name),
Examples include ``Asahi Honju'' (product name, manufactured by Asahi Glass Co., Ltd.).
本発明における超微粉とに、アルミナセメントの平均粒
径よすも、少なくとも１オーダー、好ましくＦｉ２オー
ダー小さな平均粒径を有するものであり、１μｍ以下、
好ましくはｎ、５μｍ以下のものである。具体的にはフ
ェロシリコンや金属シリコンなどの製造時に副生ずるシ
リカダスト、あるいは高炉スラグ、フライアッシュ、ア
ルミナセメント、アルミナ及びシリカなどを粉砕・分級
したものや、気相法や液相沈殿法などにより生成した無
機質の超微粉などである。The ultrafine powder used in the present invention includes alumina cement having an average particle diameter of at least 1 order of magnitude, preferably Fi2 order of magnitude, 1 μm or less,
Preferably n is 5 μm or less. Specifically, silica dust, which is a by-product during the production of ferrosilicon and metal silicon, or crushed and classified blast furnace slag, fly ash, alumina cement, alumina and silica, etc., or by gas phase method or liquid phase precipitation method, etc. The resulting inorganic ultrafine powder.
超微粉の使用量は、アルミナセメントに対【７５〜５０
重普チ程度であり、５重量％未満では、混練物の流動性
がダイラタンテイツクになり、まｆｃ５０ｍｔ％を越え
ると流動性を得ることが難しく、いずれの場合も練ｐ混
ぜが難しく、流し込み成形可能な混線物を得ることが難
しくなるＯ
本発明における高性能減水剤の例としては、ナフタレン
スルホン酸又はそれらの塩のホルマリン縮合物又はその
＠導体やメラミン樹脂スルホン酸又はその塩などが挙け
られ、その添加量はアルミナセメントと超微粉の合計（
以下、結合材という）に対し１〜５東ｉｔチ程度であり
、好ましくは１．５〜３重量−である。１重量−未満で
は流動性を得ることが難Ｌ＜、５重＊ｑｂを越えると、
水和反応の遅抵が著しくなる。The amount of ultrafine powder used is [75 to 50] compared to alumina cement.
If it is less than 5% by weight, the fluidity of the kneaded product becomes dilatant, and if it exceeds 50mt%, it is difficult to obtain fluidity, and in either case, it is difficult to mix and pour. Examples of the high performance water reducing agent in the present invention include formalin condensates of naphthalene sulfonic acid or salts thereof or conductors thereof, and melamine resin sulfonic acids or salts thereof. The amount added is the sum of alumina cement and ultrafine powder (
The amount is about 1 to 5 parts by weight, preferably 1.5 to 3 parts by weight (hereinafter referred to as a binder). If it is less than 1 weight, it is difficult to obtain fluidity; if it exceeds 5 weights * qb,
The hydration reaction becomes extremely slow.
また、硬化調整剤は、高性能減水剤によシ得られた流動
性を保持するために必要なものである。硬化調整剤の例
としてＦｉ硫酸などの無機酸、アルカリ金属の硫酸塩、
炭酸塩、炭酸水素塩、クエン酸などの有機酸及びリン酸
エステルなどが挙けられる。その使用１ｌｔＦｉ、結合
材に対し３重量％以下が好適である０
本発明においては、エリ少量の水を用いることが転化の
抑制及び高強度の肉から好ましく、結合材に対し３０重
ｆｔ部以下が好ましく、２５ｘｉｉ部以下がより好まし
い。Further, the hardening modifier is necessary to maintain the fluidity obtained by the high performance water reducing agent. Examples of hardening modifiers include inorganic acids such as Fi sulfuric acid, alkali metal sulfates,
Examples include carbonates, hydrogen carbonates, organic acids such as citric acid, and phosphoric esters. Its use is preferably 1ltFi, 3% by weight or less based on the binder. In the present invention, it is preferable to use a small amount of water to suppress conversion and provide high strength, and it is less than 30% by weight based on the binder. is preferable, and 25xii parts or less is more preferable.
東に、通常は骨材を併用する場合が大半である。骨材は
一般に土木建築分野でコンクリートを調合する際に使用
されているものが良いが、より硬５＆なもの、具体的に
は、モース硬度６以上、好ましくは７以上、又にヌープ
圧子硬度７００略／−以上、好ましくは８００ゆ／謹２
以上のいずれかの基準で選定されたものを用いると、強
度を著しく向上させることができるので好適である。こ
の基準を満足するものを例示すれば、けい石、エメリー
、黄鉄鉱、磁鉄鉱、黄玉、ローソン石、コランダム、ツ
ェナサイト、スピネル、緑柱石、全縁石、電気石、花こ
う岩、紅柱石、十字石、ジルコン、焼成ボーキサイト、
重焼ばん土けつ岩、炭化はう素、炭化タングステン、フ
ェロシリコンナイトライド、窒化けい素、溶融シリカ、
電融マグネシア、炭化けい素、立方晶窒化はう素などが
挙けられる。また機械加工可能な鉄粉、ステンレス粉及
びフェロマンガン粉などの金属等も有用である。％に曲
は強度の向上という点からは鉄粉やオーステナイト系ス
テンレス粉及びフェロマンガン粉が好筐しい。この理由
は定かではないが、それ自身の強度が高いことと、セメ
ントマトリックスへの付層性が優れているためと推犀さ
れる。To the east, aggregate is usually used in most cases. Aggregates that are generally used when mixing concrete in the civil engineering and construction field are good, but those with a harder hardness of 5 or higher, specifically, those with a Mohs hardness of 6 or higher, preferably 7 or higher, or a Knoop indenter hardness of 700. About /- or more, preferably 800 yu/min 2
It is preferable to use a material selected based on any of the above criteria because the strength can be significantly improved. Examples of materials that meet this criteria include silica, emery, pyrite, magnetite, yellow jade, lawsonite, corundum, zenasite, spinel, beryl, full curb stone, tourmaline, granite, andalusite, and cross stone. , zircon, calcined bauxite,
Heavy burnt silica, boron carbide, tungsten carbide, ferrosilicon nitride, silicon nitride, fused silica,
Examples include electrofused magnesia, silicon carbide, and cubic boron nitride. Also useful are metals that can be machined, such as iron powder, stainless steel powder, and ferromanganese powder. In terms of improving strength, iron powder, austenitic stainless steel powder, and ferromanganese powder are preferable. The reason for this is not certain, but it is assumed that it has high strength itself and excellent adhesion to the cement matrix.
骨材の使用量は、通常、結合材に対して、５Ｘｔｓ量以
内で選択使用される。但し、プレパックドやポストパッ
クド工法などの特殊な成形方法の場合にはこの限りでな
い。The amount of aggregate used is usually selected within 5Xts relative to the binder. However, this does not apply to special molding methods such as pre-packed and post-packed construction methods.
以上の配合材料の他に、各檜繊維や網の併用も可能であ
る。繊維の例としては、びびり切削法などにより製造さ
れる鋳鉄繊維、スチール繊維及びステンレス繊維などの
金属繊維、及び、石綿やアルミナ繊維などの各種天然又
は合成鉱物繊維、炭素繊維、ガラス繊維、更に、ポリプ
ロピレン、ビニロン、アクリロニトリル及びセルロース
などの天然又は合成のＭ機繊維等が挙ケラレる。また、
補強材として従来より用いられている鋼棒やＦＲＰロッ
ドなどを用いることも可能であり、特に大型のものには
これら補強材が必要不可欠なものである。なお繊維に関
しては、流動性ｔ′損なわないという点からは、５ｗ程
度の長さの金ｌＩ４短繊維や、更にそれよりも短いウィ
スカーなどが好ましい。In addition to the above compounded materials, it is also possible to use cypress fibers and nets in combination. Examples of fibers include metal fibers such as cast iron fibers, steel fibers, and stainless steel fibers produced by chatter cutting methods, various natural or synthetic mineral fibers such as asbestos and alumina fibers, carbon fibers, glass fibers, and Natural or synthetic fibers such as polypropylene, vinylon, acrylonitrile, and cellulose are listed. Also,
It is also possible to use conventionally used steel rods, FRP rods, etc. as reinforcing materials, and these reinforcing materials are indispensable, especially for large ones. Regarding the fibers, from the viewpoint of not impairing the fluidity t', it is preferable to use short gold lI4 fibers having a length of about 5W or whiskers even shorter than that.
材料の混練方法は、特に限定されるものではないが、充
分に混練することが好ましい。本発明においては、混線
時や混練後に真空脱泡処理を行うことが、曲は強度を向
上させる面から好ましいことである。それらの操作を行
うための具体的装置の例としては、真空鋳込装置〔高木
田
製作所（株）製〕、真空オムニミキサ〔千代技研Δ
工業（株）製〕及び真空混合機〔（株）三英製作所製〕
などが挙けられる。また、その他の方法として薄膜を形
成して脱泡する方法などがある。The method of kneading the materials is not particularly limited, but it is preferable to thoroughly knead them. In the present invention, it is preferable to perform a vacuum defoaming treatment at the time of mixing or after kneading, from the viewpoint of improving the strength of the curve. Examples of specific equipment for performing these operations include a vacuum casting machine [manufactured by Takakida Seisakusho Co., Ltd.], a vacuum omnimixer [manufactured by Chiyo Giken Delta Industries Co., Ltd.], and a vacuum mixer [manufactured by San Co., Ltd.]. Made in England]
Examples include. Other methods include forming a thin film to defoam.
特に薄膜を形成して脱泡する方法は、脱泡速度が早く効
果が著しい。脱泡条件は、５０〜７０１ｇ程度の真空度
とするのが、水分の蒸発等を考慮した場合適当である。In particular, the method of defoaming by forming a thin film has a fast defoaming speed and is highly effective. A suitable defoaming condition is a degree of vacuum of about 50 to 701 g, taking into consideration the evaporation of water.
また、脱泡時間は特に限定されるものではないが、通常
５〜３０分程度が好ましい。更にまた、成形時に真空脱
泡処理と振動を組合せることも、非常に有効であるＯ
養生は各棟の養生方法が可能であり、常ｉ養生、常圧蒸
気養生、高温高圧養生及び誦温養生のいずれの方法も採
用することができ、必要ならば、これらの組合せを行っ
て高強度セメント硬化体を得ることもできる。なお、最
も＾い曲は強度の値を示すのは５０℃程度で養生する場
合である。Further, the defoaming time is not particularly limited, but is usually preferably about 5 to 30 minutes. Furthermore, it is also very effective to combine vacuum defoaming treatment and vibration during molding.Curing can be done using different curing methods, such as normal curing, normal pressure steam curing, high temperature and high pressure curing, and temperature curing. Any of the curing methods can be employed, and if necessary, a combination of these methods can be used to obtain a high-strength hardened cement body. Note that the strongest song shows the strength value when it is cured at about 50°C.
成形型の製作方法に＃′ｉ特に制限はない。通常、元型
に離型剤を塗布した後、流し込むことで容易に農作する
ことができる。#'i There are no particular restrictions on the method of manufacturing the mold. Normally, farming can be easily done by applying a mold release agent to the master mold and then pouring it into the mold.
本発明の成形型は、通常のセメントコンクリートである
カルシウムシリケート系化合物を含む組成物を用いた成
形型に比較して、曲は強度、硬度共に優れたものである
。また、早期に強度を発現するので、工期が非常に短縮
される。本発明の成形型は、５０℃、５＃ｆ間程度でａ
ＯＯ捜ｆ／−以上の圧縮強度を示す。The mold of the present invention has superior curve strength and hardness compared to a mold using a composition containing a calcium silicate compound, which is ordinary cement concrete. In addition, since strength is developed early, the construction period is greatly shortened. The mold of the present invention has a
It shows a compressive strength of OO f/- or more.
本発明の成形型は、技量、曲は型、絞り型及び圧縮型等
の金輌プレス型、圧縮成形用、移送成形用、射出成形用
、吹込成形用、真を成形用、ＲＩＭ用、尚温ＲＩＭ用及
び８ＭＣ’川等のプラスチック型、ダイカスト型、誠業
型、ゴム型、ガラス型及び鋳造用型等に応用できる。The molding mold of the present invention can be applied to metal press molds such as curved molds, drawing molds and compression molds, compression molding, transfer molding, injection molding, blow molding, core molding, RIM, etc. It can be applied to plastic molds such as warm RIM and 8MC' rivers, die casting molds, Kogyo molds, rubber molds, glass molds, casting molds, etc.
以下、本発明全実施例により更に具体的に睨明するが、
本発明はこれに限定されない。Hereinafter, the present invention will be explained in more detail with reference to all the embodiments,
The present invention is not limited to this.
実施例１
下記表−１に示す配合のＨＩ強度セメント組成物を用い
て成形型を製作した。まず、５０ｔオムニミキサ〔千代
田技研工業（株）製〕にて、１０分間練り混ぜ、振動を
与えながら真空説泡全し、２Ｘ２Ｘ８ｍの供試体を作製
した。Example 1 A mold was manufactured using a HI strength cement composition having the composition shown in Table 1 below. First, the mixture was mixed for 10 minutes using a 50 ton omnimixer (manufactured by Chiyoda Giken Kogyo Co., Ltd.), and vacuum bubbles were removed while applying vibration to prepare a 2 x 2 x 8 m specimen.
ポリエチレンで封かんし、５０℃で７日間養生を行った
ものについて圧縮及び曲は強度、値開を測足した。その
結果も表−１に示す。After sealing with polyethylene and curing at 50°C for 7 days, the compression and bending strength and value difference were measured. The results are also shown in Table-1.
（使用材料）
白色セメント：秩父セメントＣ株）Ｍ
アルミナセメント＝［デンカハイアルミナセメント］〔
電気化学工業（株）
製〕
超微粉ニジリカヒユーム〔日本重化学工業■製〕
高性能減水剤：β−ナフタレンスルホン酸塩ホルムアル
デヒド縮合物系
〔商品名［セルフ０−１１０
ＰＪｗＪ−工業製薬（株）委〕
骨 材：還元鉄粉［メタレットＪ（Ｌｌ ５閣下（日本
磁力選（株）製）
短繊維： ８Ｕ８４３０ 、φ５０μｍ×長さ２．５■
びびり切削法による〔東京製
鋼（株）製〕
硬化調整剤： Ｎａ１８０４ （試薬）同様の方法によ
り、プレス成形型の絞９ｍ及び射出成形型を製作した。(Materials used) White cement: Chichibu Cement C Co., Ltd.) M Alumina cement = [Denka High Alumina Cement] [
Manufactured by Denki Kagaku Kogyo Co., Ltd.] Ultra-fine powder Nijirika Huyum [manufactured by Japan Heavy Chemical Industries, Ltd.] High-performance water reducing agent: β-naphthalene sulfonate formaldehyde condensate system [Product name [Self 0-110 PJwJ-Kyogyo Seiyaku Co., Ltd.] Aggregate material: Reduced iron powder [Metallet J (Ll 5 Excellent (manufactured by Nihon Magnetic Sen Co., Ltd.) Short fiber: 8U8430, φ50μm x length 2.5■
By chatter cutting method [manufactured by Tokyo Steel Corporation] Hardening regulator: Na1804 (reagent) A press mold with a diameter of 9 m and an injection mold were manufactured in the same manner.
プレス成形型全使用してオイルタンクのプレス試験を実
施したところ、実験番号１及び２の配合を用いた比較例
においては’、２００枚目程度からコーナーのＲ部の摩
耗が観察されたが、実験番号３の配合を用いた本発明の
実施例においては観察されなかった。When we conducted a press test on an oil tank using all the press molds, in the comparative examples using the formulations of experiment numbers 1 and 2, wear at the corner R was observed from about the 200th sheet; This was not observed in the example of the present invention using the experiment number 3 formulation.
筐た、射出成形型を使用してチェンジレバーを射出成形
したが、ＡＢ８樹脂の成形時、実験番号１及び２の配合
を用いた比較例の場合には凸部が破損した。しかし、実
験番号Ｓの配合を用いた本発明の実施例においては、成
形を満足に行うことができた。A change lever was injection molded using an injection mold, but when AB8 resin was molded, the convex part was damaged in the comparative example using the formulations of Experiment Nos. 1 and 2. However, in the example of the present invention using the formulation of Experiment No. S, molding could be performed satisfactorily.
〔発明の効果〕
以上、詳細に説明したように、本発明の成形型は、成形
方法が簡便で、工期が短く製作でき、強度性状及び硬度
等が優れているので、この型を用いる成形も従来のよう
なトラブルな〈実施することができるという顕著な効果
を奏するものである。[Effects of the Invention] As explained in detail above, the mold of the present invention has a simple molding method, can be manufactured in a short period of time, and has excellent strength properties, hardness, etc., and therefore molding using this mold is also possible. It has the remarkable effect of being able to be implemented without the troubles of conventional methods.
Claims (1)
整剤及び水を主成分とする組成物を成形硬化してなるこ
とを特徴とする高強度セメント製成形型。1. A high-strength cement mold characterized by being formed by molding and hardening a composition whose main components are alumina cement, ultrafine powder, a high-performance water reducing agent, a hardening modifier, and water.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP11088486A JPS62267109A (en) | 1986-05-16 | 1986-05-16 | Molding tool |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP11088486A JPS62267109A (en) | 1986-05-16 | 1986-05-16 | Molding tool |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS62267109A true JPS62267109A (en) | 1987-11-19 |
| JPH0570563B2 JPH0570563B2 (en) | 1993-10-05 |
Family
ID=14547133
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP11088486A Granted JPS62267109A (en) | 1986-05-16 | 1986-05-16 | Molding tool |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS62267109A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2009019203A1 (en) * | 2007-08-09 | 2009-02-12 | MAX BÖGL Fertigteilwerke GmbH & Co. KG | Casting mold and method for producing a casting mold |
-
1986
- 1986-05-16 JP JP11088486A patent/JPS62267109A/en active Granted
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2009019203A1 (en) * | 2007-08-09 | 2009-02-12 | MAX BÖGL Fertigteilwerke GmbH & Co. KG | Casting mold and method for producing a casting mold |
| EP2025488A1 (en) * | 2007-08-09 | 2009-02-18 | Max Bögl Fertigteilwerke GmbH & Co. KG | Mould and method for manufacturing a mould |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0570563B2 (en) | 1993-10-05 |
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|---|---|---|---|
| LAPS | Cancellation because of no payment of annual fees |