JPS62255413A - Heating type hair-deforming agent - Google Patents
Heating type hair-deforming agentInfo
- Publication number
- JPS62255413A JPS62255413A JP9919486A JP9919486A JPS62255413A JP S62255413 A JPS62255413 A JP S62255413A JP 9919486 A JP9919486 A JP 9919486A JP 9919486 A JP9919486 A JP 9919486A JP S62255413 A JPS62255413 A JP S62255413A
- Authority
- JP
- Japan
- Prior art keywords
- hair
- agent
- acid
- heating
- sodium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000010438 heat treatment Methods 0.000 title abstract description 20
- 125000003545 alkoxy group Chemical group 0.000 claims abstract description 4
- 125000002947 alkylene group Chemical group 0.000 claims abstract 2
- 239000000126 substance Substances 0.000 claims description 5
- 125000004432 carbon atom Chemical group C* 0.000 claims description 4
- 210000004209 hair Anatomy 0.000 abstract description 41
- 239000003795 chemical substances by application Substances 0.000 abstract description 27
- 150000003839 salts Chemical class 0.000 abstract description 10
- 150000001875 compounds Chemical class 0.000 abstract description 8
- 108090000765 processed proteins & peptides Proteins 0.000 abstract description 8
- 150000003961 organosilicon compounds Chemical group 0.000 abstract description 6
- 229920000642 polymer Polymers 0.000 abstract description 6
- 230000003700 hair damage Effects 0.000 abstract description 5
- 229910052751 metal Inorganic materials 0.000 abstract description 5
- 239000002184 metal Substances 0.000 abstract description 5
- 125000002091 cationic group Chemical group 0.000 abstract description 4
- 230000000694 effects Effects 0.000 abstract description 4
- 239000007853 buffer solution Substances 0.000 abstract description 3
- 239000002904 solvent Substances 0.000 abstract description 2
- 125000003396 thiol group Chemical group [H]S* 0.000 abstract description 2
- 230000002265 prevention Effects 0.000 abstract 1
- -1 Next Substances 0.000 description 16
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Inorganic materials [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 16
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 13
- 238000000034 method Methods 0.000 description 11
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 10
- 239000000178 monomer Substances 0.000 description 10
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 9
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 8
- 239000002253 acid Substances 0.000 description 8
- 150000003863 ammonium salts Chemical class 0.000 description 8
- 239000000243 solution Substances 0.000 description 8
- 230000002378 acidificating effect Effects 0.000 description 7
- 229920002554 vinyl polymer Polymers 0.000 description 7
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 6
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 5
- KDXKERNSBIXSRK-UHFFFAOYSA-N Lysine Natural products NCCCCC(N)C(O)=O KDXKERNSBIXSRK-UHFFFAOYSA-N 0.000 description 5
- 239000004472 Lysine Substances 0.000 description 5
- 229910021529 ammonia Inorganic materials 0.000 description 5
- 239000003205 fragrance Substances 0.000 description 5
- 102000004196 processed proteins & peptides Human genes 0.000 description 5
- 239000007870 radical polymerization initiator Substances 0.000 description 5
- 239000004475 Arginine Substances 0.000 description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 4
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 4
- 235000001014 amino acid Nutrition 0.000 description 4
- 229940024606 amino acid Drugs 0.000 description 4
- 150000001413 amino acids Chemical class 0.000 description 4
- 235000019270 ammonium chloride Nutrition 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 4
- ODKSFYDXXFIFQN-UHFFFAOYSA-N arginine Natural products OC(=O)C(N)CCCNC(N)=N ODKSFYDXXFIFQN-UHFFFAOYSA-N 0.000 description 4
- 238000011156 evaluation Methods 0.000 description 4
- NOESYZHRGYRDHS-UHFFFAOYSA-N insulin Chemical compound N1C(=O)C(NC(=O)C(CCC(N)=O)NC(=O)C(CCC(O)=O)NC(=O)C(C(C)C)NC(=O)C(NC(=O)CN)C(C)CC)CSSCC(C(NC(CO)C(=O)NC(CC(C)C)C(=O)NC(CC=2C=CC(O)=CC=2)C(=O)NC(CCC(N)=O)C(=O)NC(CC(C)C)C(=O)NC(CCC(O)=O)C(=O)NC(CC(N)=O)C(=O)NC(CC=2C=CC(O)=CC=2)C(=O)NC(CSSCC(NC(=O)C(C(C)C)NC(=O)C(CC(C)C)NC(=O)C(CC=2C=CC(O)=CC=2)NC(=O)C(CC(C)C)NC(=O)C(C)NC(=O)C(CCC(O)=O)NC(=O)C(C(C)C)NC(=O)C(CC(C)C)NC(=O)C(CC=2NC=NC=2)NC(=O)C(CO)NC(=O)CNC2=O)C(=O)NCC(=O)NC(CCC(O)=O)C(=O)NC(CCCNC(N)=N)C(=O)NCC(=O)NC(CC=3C=CC=CC=3)C(=O)NC(CC=3C=CC=CC=3)C(=O)NC(CC=3C=CC(O)=CC=3)C(=O)NC(C(C)O)C(=O)N3C(CCC3)C(=O)NC(CCCCN)C(=O)NC(C)C(O)=O)C(=O)NC(CC(N)=O)C(O)=O)=O)NC(=O)C(C(C)CC)NC(=O)C(CO)NC(=O)C(C(C)O)NC(=O)C1CSSCC2NC(=O)C(CC(C)C)NC(=O)C(NC(=O)C(CCC(N)=O)NC(=O)C(CC(N)=O)NC(=O)C(NC(=O)C(N)CC=1C=CC=CC=1)C(C)C)CC1=CN=CN1 NOESYZHRGYRDHS-UHFFFAOYSA-N 0.000 description 4
- 238000005342 ion exchange Methods 0.000 description 4
- 235000011121 sodium hydroxide Nutrition 0.000 description 4
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 description 3
- 102000011782 Keratins Human genes 0.000 description 3
- 108010076876 Keratins Proteins 0.000 description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 3
- VBIIFPGSPJYLRR-UHFFFAOYSA-M Stearyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)C VBIIFPGSPJYLRR-UHFFFAOYSA-M 0.000 description 3
- 150000007513 acids Chemical class 0.000 description 3
- 239000001099 ammonium carbonate Substances 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 229910021538 borax Inorganic materials 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- UQGFMSUEHSUPRD-UHFFFAOYSA-N disodium;3,7-dioxido-2,4,6,8,9-pentaoxa-1,3,5,7-tetraborabicyclo[3.3.1]nonane Chemical compound [Na+].[Na+].O1B([O-])OB2OB([O-])OB1O2 UQGFMSUEHSUPRD-UHFFFAOYSA-N 0.000 description 3
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 3
- 239000010931 gold Substances 0.000 description 3
- 229910052737 gold Inorganic materials 0.000 description 3
- 230000014759 maintenance of location Effects 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 229910000402 monopotassium phosphate Inorganic materials 0.000 description 3
- 235000019796 monopotassium phosphate Nutrition 0.000 description 3
- 229910000403 monosodium phosphate Inorganic materials 0.000 description 3
- 235000019799 monosodium phosphate Nutrition 0.000 description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 239000011591 potassium Substances 0.000 description 3
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 3
- AJPJDKMHJJGVTQ-UHFFFAOYSA-M sodium dihydrogen phosphate Chemical compound [Na+].OP(O)([O-])=O AJPJDKMHJJGVTQ-UHFFFAOYSA-M 0.000 description 3
- 239000004328 sodium tetraborate Substances 0.000 description 3
- 235000010339 sodium tetraborate Nutrition 0.000 description 3
- 230000009466 transformation Effects 0.000 description 3
- HPYNZHMRTTWQTB-UHFFFAOYSA-N 2,3-dimethylpyridine Chemical compound CC1=CC=CN=C1C HPYNZHMRTTWQTB-UHFFFAOYSA-N 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- 229910000013 Ammonium bicarbonate Inorganic materials 0.000 description 2
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- 102000004877 Insulin Human genes 0.000 description 2
- 108090001061 Insulin Proteins 0.000 description 2
- ODKSFYDXXFIFQN-BYPYZUCNSA-P L-argininium(2+) Chemical compound NC(=[NH2+])NCCC[C@H]([NH3+])C(O)=O ODKSFYDXXFIFQN-BYPYZUCNSA-P 0.000 description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 2
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 108010073771 Soybean Proteins Proteins 0.000 description 2
- 235000012538 ammonium bicarbonate Nutrition 0.000 description 2
- 235000011114 ammonium hydroxide Nutrition 0.000 description 2
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 2
- 150000001450 anions Chemical class 0.000 description 2
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 2
- 239000004327 boric acid Substances 0.000 description 2
- 239000000872 buffer Substances 0.000 description 2
- 239000006172 buffering agent Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000003638 chemical reducing agent Substances 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 description 2
- YMAWOPBAYDPSLA-UHFFFAOYSA-N glycylglycine Chemical compound [NH3+]CC(=O)NCC([O-])=O YMAWOPBAYDPSLA-UHFFFAOYSA-N 0.000 description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 229940125396 insulin Drugs 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 239000007800 oxidant agent Substances 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 150000004965 peroxy acids Chemical class 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 235000018102 proteins Nutrition 0.000 description 2
- 108090000623 proteins and genes Proteins 0.000 description 2
- 102000004169 proteins and genes Human genes 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 235000017557 sodium bicarbonate Nutrition 0.000 description 2
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 description 2
- 235000019710 soybean protein Nutrition 0.000 description 2
- CWERGRDVMFNCDR-UHFFFAOYSA-N thioglycolic acid Chemical compound OC(=O)CS CWERGRDVMFNCDR-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 1
- LCPVQAHEFVXVKT-UHFFFAOYSA-N 2-(2,4-difluorophenoxy)pyridin-3-amine Chemical compound NC1=CC=CN=C1OC1=CC=C(F)C=C1F LCPVQAHEFVXVKT-UHFFFAOYSA-N 0.000 description 1
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
- SJIXRGNQPBQWMK-UHFFFAOYSA-N 2-(diethylamino)ethyl 2-methylprop-2-enoate Chemical compound CCN(CC)CCOC(=O)C(C)=C SJIXRGNQPBQWMK-UHFFFAOYSA-N 0.000 description 1
- QHVBLSNVXDSMEB-UHFFFAOYSA-N 2-(diethylamino)ethyl prop-2-enoate Chemical compound CCN(CC)CCOC(=O)C=C QHVBLSNVXDSMEB-UHFFFAOYSA-N 0.000 description 1
- JKNCOURZONDCGV-UHFFFAOYSA-N 2-(dimethylamino)ethyl 2-methylprop-2-enoate Chemical compound CN(C)CCOC(=O)C(C)=C JKNCOURZONDCGV-UHFFFAOYSA-N 0.000 description 1
- DPBJAVGHACCNRL-UHFFFAOYSA-N 2-(dimethylamino)ethyl prop-2-enoate Chemical compound CN(C)CCOC(=O)C=C DPBJAVGHACCNRL-UHFFFAOYSA-N 0.000 description 1
- 229920000536 2-Acrylamido-2-methylpropane sulfonic acid Polymers 0.000 description 1
- XHZPRMZZQOIPDS-UHFFFAOYSA-N 2-Methyl-2-[(1-oxo-2-propenyl)amino]-1-propanesulfonic acid Chemical compound OS(=O)(=O)CC(C)(C)NC(=O)C=C XHZPRMZZQOIPDS-UHFFFAOYSA-N 0.000 description 1
- XUDBVJCTLZTSDC-UHFFFAOYSA-N 2-ethenylbenzoic acid Chemical compound OC(=O)C1=CC=CC=C1C=C XUDBVJCTLZTSDC-UHFFFAOYSA-N 0.000 description 1
- KGIGUEBEKRSTEW-UHFFFAOYSA-N 2-vinylpyridine Chemical compound C=CC1=CC=CC=N1 KGIGUEBEKRSTEW-UHFFFAOYSA-N 0.000 description 1
- KFDVPJUYSDEJTH-UHFFFAOYSA-N 4-ethenylpyridine Chemical compound C=CC1=CC=NC=C1 KFDVPJUYSDEJTH-UHFFFAOYSA-N 0.000 description 1
- CUZYEVGHBNUHCA-UHFFFAOYSA-N 5-methyl-4-oxohex-5-ene-1-sulfonic acid Chemical compound CC(=C)C(=O)CCCS(O)(=O)=O CUZYEVGHBNUHCA-UHFFFAOYSA-N 0.000 description 1
- DCXYFEDJOCDNAF-UHFFFAOYSA-N Asparagine Natural products OC(=O)C(N)CC(N)=O DCXYFEDJOCDNAF-UHFFFAOYSA-N 0.000 description 1
- 239000004342 Benzoyl peroxide Substances 0.000 description 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical class OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- WHUUTDBJXJRKMK-UHFFFAOYSA-N Glutamic acid Natural products OC(=O)C(N)CCC(O)=O WHUUTDBJXJRKMK-UHFFFAOYSA-N 0.000 description 1
- 108010053070 Glutathione Disulfide Proteins 0.000 description 1
- 239000004471 Glycine Substances 0.000 description 1
- 108010008488 Glycylglycine Proteins 0.000 description 1
- XUJNEKJLAYXESH-REOHCLBHSA-N L-Cysteine Chemical compound SC[C@H](N)C(O)=O XUJNEKJLAYXESH-REOHCLBHSA-N 0.000 description 1
- DCXYFEDJOCDNAF-REOHCLBHSA-N L-asparagine Chemical compound OC(=O)[C@@H](N)CC(N)=O DCXYFEDJOCDNAF-REOHCLBHSA-N 0.000 description 1
- WHUUTDBJXJRKMK-VKHMYHEASA-N L-glutamic acid Chemical compound OC(=O)[C@@H](N)CCC(O)=O WHUUTDBJXJRKMK-VKHMYHEASA-N 0.000 description 1
- KDXKERNSBIXSRK-YFKPBYRVSA-N L-lysine Chemical compound NCCCC[C@H](N)C(O)=O KDXKERNSBIXSRK-YFKPBYRVSA-N 0.000 description 1
- 235000019687 Lamb Nutrition 0.000 description 1
- FFDGPVCHZBVARC-UHFFFAOYSA-N N,N-dimethylglycine Chemical compound CN(C)CC(O)=O FFDGPVCHZBVARC-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical group OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 1
- 108010039918 Polylysine Proteins 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 1
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
- 241000750631 Takifugu chinensis Species 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 150000001242 acetic acid derivatives Chemical class 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- CEGOLXSVJUTHNZ-UHFFFAOYSA-K aluminium tristearate Chemical compound [Al+3].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CEGOLXSVJUTHNZ-UHFFFAOYSA-K 0.000 description 1
- 229940063655 aluminum stearate Drugs 0.000 description 1
- 235000012501 ammonium carbonate Nutrition 0.000 description 1
- 229910001870 ammonium persulfate Inorganic materials 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- HOPRXXXSABQWAV-UHFFFAOYSA-N anhydrous collidine Natural products CC1=CC=NC(C)=C1C HOPRXXXSABQWAV-UHFFFAOYSA-N 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 235000009582 asparagine Nutrition 0.000 description 1
- 229960001230 asparagine Drugs 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 235000019400 benzoyl peroxide Nutrition 0.000 description 1
- 230000000975 bioactive effect Effects 0.000 description 1
- 235000008429 bread Nutrition 0.000 description 1
- SXDBWCPKPHAZSM-UHFFFAOYSA-M bromate Chemical class [O-]Br(=O)=O SXDBWCPKPHAZSM-UHFFFAOYSA-M 0.000 description 1
- 238000012662 bulk polymerization Methods 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 239000005018 casein Substances 0.000 description 1
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 1
- 235000021240 caseins Nutrition 0.000 description 1
- 150000001768 cations Chemical group 0.000 description 1
- WOWHHFRSBJGXCM-UHFFFAOYSA-M cetyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+](C)(C)C WOWHHFRSBJGXCM-UHFFFAOYSA-M 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- UTBIMNXEDGNJFE-UHFFFAOYSA-N collidine Natural products CC1=CC=C(C)C(C)=N1 UTBIMNXEDGNJFE-UHFFFAOYSA-N 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 235000018417 cysteine Nutrition 0.000 description 1
- XUJNEKJLAYXESH-UHFFFAOYSA-N cysteine Natural products SCC(N)C(O)=O XUJNEKJLAYXESH-UHFFFAOYSA-N 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- OGGXGZAMXPVRFZ-UHFFFAOYSA-N dimethylarsinic acid Chemical compound C[As](C)(O)=O OGGXGZAMXPVRFZ-UHFFFAOYSA-N 0.000 description 1
- 108700003601 dimethylglycine Proteins 0.000 description 1
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N dimethylmethane Natural products CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 1
- 150000002009 diols Chemical class 0.000 description 1
- 229910000396 dipotassium phosphate Inorganic materials 0.000 description 1
- 235000019797 dipotassium phosphate Nutrition 0.000 description 1
- KCIDZIIHRGYJAE-YGFYJFDDSA-L dipotassium;[(2r,3r,4s,5r,6r)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl] phosphate Chemical compound [K+].[K+].OC[C@H]1O[C@H](OP([O-])([O-])=O)[C@H](O)[C@@H](O)[C@H]1O KCIDZIIHRGYJAE-YGFYJFDDSA-L 0.000 description 1
- 229910000397 disodium phosphate Inorganic materials 0.000 description 1
- 235000019800 disodium phosphate Nutrition 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 210000003746 feather Anatomy 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 235000013922 glutamic acid Nutrition 0.000 description 1
- 239000004220 glutamic acid Substances 0.000 description 1
- YPZRWBKMTBYPTK-BJDJZHNGSA-N glutathione disulfide Chemical compound OC(=O)[C@@H](N)CCC(=O)N[C@H](C(=O)NCC(O)=O)CSSC[C@@H](C(=O)NCC(O)=O)NC(=O)CC[C@H](N)C(O)=O YPZRWBKMTBYPTK-BJDJZHNGSA-N 0.000 description 1
- 229940043257 glycylglycine Drugs 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 210000000003 hoof Anatomy 0.000 description 1
- 229940088597 hormone Drugs 0.000 description 1
- 239000005556 hormone Substances 0.000 description 1
- 210000003284 horn Anatomy 0.000 description 1
- 150000004678 hydrides Chemical class 0.000 description 1
- 235000011167 hydrochloric acid Nutrition 0.000 description 1
- 150000003840 hydrochlorides Chemical class 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 210000003127 knee Anatomy 0.000 description 1
- 150000002596 lactones Chemical class 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 239000002075 main ingredient Substances 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 239000001630 malic acid Substances 0.000 description 1
- 235000011090 malic acid Nutrition 0.000 description 1
- 125000005527 methyl sulfate group Chemical group 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- WGESLFUSXZBFQF-UHFFFAOYSA-N n-methyl-n-prop-2-enylprop-2-en-1-amine Chemical compound C=CCN(C)CC=C WGESLFUSXZBFQF-UHFFFAOYSA-N 0.000 description 1
- ITAJKWQQNHHGFJ-UHFFFAOYSA-N n-methylmethanamine;2-methyl-n-propylprop-2-enamide Chemical compound CNC.CCCNC(=O)C(C)=C ITAJKWQQNHHGFJ-UHFFFAOYSA-N 0.000 description 1
- UFQOAIGWDYZJJO-UHFFFAOYSA-N n-methylmethanamine;n-propylprop-2-enamide Chemical compound CNC.CCCNC(=O)C=C UFQOAIGWDYZJJO-UHFFFAOYSA-N 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- YPZRWBKMTBYPTK-UHFFFAOYSA-N oxidized gamma-L-glutamyl-L-cysteinylglycine Natural products OC(=O)C(N)CCC(=O)NC(C(=O)NCC(O)=O)CSSCC(C(=O)NCC(O)=O)NC(=O)CCC(N)C(O)=O YPZRWBKMTBYPTK-UHFFFAOYSA-N 0.000 description 1
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 1
- 229920000656 polylysine Polymers 0.000 description 1
- 229920000259 polyoxyethylene lauryl ether Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 1
- 159000000001 potassium salts Chemical class 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000012673 precipitation polymerization Methods 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 239000003531 protein hydrolysate Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000001632 sodium acetate Substances 0.000 description 1
- 235000017281 sodium acetate Nutrition 0.000 description 1
- XUXNAKZDHHEHPC-UHFFFAOYSA-M sodium bromate Chemical compound [Na+].[O-]Br(=O)=O XUXNAKZDHHEHPC-UHFFFAOYSA-M 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 1
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Substances [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- SPDUKHLMYVCLOA-UHFFFAOYSA-M sodium;ethaneperoxoate Chemical compound [Na+].CC(=O)O[O-] SPDUKHLMYVCLOA-UHFFFAOYSA-M 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 239000003206 sterilizing agent Substances 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical class [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 1
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 238000010557 suspension polymerization reaction Methods 0.000 description 1
- GFYHSKONPJXCDE-UHFFFAOYSA-N sym-collidine Natural products CC1=CN=C(C)C(C)=C1 GFYHSKONPJXCDE-UHFFFAOYSA-N 0.000 description 1
- 150000003892 tartrate salts Chemical class 0.000 description 1
- 150000003512 tertiary amines Chemical group 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 1
- 230000001131 transforming effect Effects 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Landscapes
- Cosmetics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野１
本発明は加温式毛髪変形用処理剤、更に詳細には、少な
くとも１個のメルカプト基金有する有機ケイ素化合物全
主要成分とする、加温することにより毛髪に半永久的な
変形上流すことができる加温式毛髪変形用処理剤に関す
る。DETAILED DESCRIPTION OF THE INVENTION [Industrial Field of Application 1] The present invention relates to a heating-type treatment agent for hair transformation, more specifically, a heating-type treatment agent for hair transformation, more specifically, a treatment agent for heating hair, which comprises as a main component an organosilicon compound having at least one mercapto group. The present invention relates to a heating type hair deforming treatment agent which can impart semi-permanent deformation to hair.
毛髪に所望のウェーブを与える方法は、初期には高、Ｈ
のアルカリ剤水溶液を用いて加熱する、所謂毛髪と呼ば
れ友毛髪の変形方法であった。近年最も一般的に行なわ
れる方法としては、まずチオグリコール酸、システィ／
、亜硫酸塩等の還元剤を主成分とするパーマネ／トウエ
ーブｉｔ剤全用いて毛髪中のＳ−８結合を還元開鎖し、
次いで臭素酸塩、過ホウ酸塩、過酸化水素水等の酸化剤
？主成分とするパーマネントウェーブ第２剤を用いて酸
化閉鎖する所謂コールドバーマネ／ト法で６る０
しかし、これらの方法によると、高ｐＨのアルカリ剤水
溶液及び高温による加熱、ろるいｖ′ｉ還元、酸化とい
う悪条件に曝されるため、毛髪の強匣の低下、触感の劣
化が起きるという欠点がめった。The way to give your hair the desired wave is to use high, H
It was a method of transforming so-called hair, which involves heating using an aqueous solution of an alkaline agent. The most common method used in recent years is to use thioglycolic acid, cysteine,
, Reductively open the S-8 bonds in the hair using all permanent/tweave it agents whose main ingredients are reducing agents such as sulfites,
Next, oxidizing agents such as bromates, perborates, and hydrogen peroxide? However, according to these methods, high pH alkaline aqueous solutions, heating at high temperatures, and sluggish v'i Because it is exposed to adverse conditions such as reduction and oxidation, it often suffers from a decrease in the strength of the hair and a deterioration of the texture.
本発明者は毛髪を変形する方法、特に従来のバ−マネン
トウエーブによって得られるウェーブと同様半永久的に
毛髪を変形することができ、しかも毛髪に拶傷を与える
ような高、ｆ（のアルカリ剤水溶液あるいは酸化剤を使
用しない方法について鋭意研究を行った結果、従来、笥
うでは還元力が低く、コールドパーマネントウェーブ剤
の還元剤成分として使用できないとされていた従述の一
般弐山又は（［１で表わされる有機ケイ素化合物を毛髪
に施用した後、加温すれば毛髪全半永久的に変形できる
ことを見出し、本発明を完成した。The present inventor has developed a method for deforming hair, in particular a method that can semi-permanently deform hair similar to the waves obtained by conventional permanent wave, and that has a high alkali content of f(f) that can damage the hair. As a result of intensive research on methods that do not use an aqueous agent solution or an oxidizing agent, we found that the general Nisan or ( [We have completed the present invention by discovering that the entire hair can be semi-permanently deformed by applying the organosilicon compound represented by 1 to the hair and then heating it.
すなわち、本発明は、次の一般式（１１又は（ＩＩ）、
Ｒ７
Ｒ，−８ｉ −Ｒ，−ＳＲ（１）
（式中、Ｒ，、Ｒ，及びＲ３は炭素数１〜３のアルコキ
シ基、Ｒ，、Ｒ，及び烏は炭素数１〜３のアルキレフ基
を示す）
を含有することを特徴とする加温式毛髪変形用処理剤を
提供するものである。That is, the present invention provides the following general formula (11 or (II),
R7 R, -8i -R, -SR (1) (In the formula, R,, R, and R3 are alkoxy groups having 1 to 3 carbon atoms; R, , R, and Karasu are alkyref groups having 1 to 3 carbon atoms. The present invention provides a heating type hair deforming treatment agent characterized by containing the following:
本発明の（Ｉ）又は（ＩＩ）式で表わされる有機ケイ素
化合物はすでに公知の化合物であり、常法によって製造
される。The organosilicon compound represented by formula (I) or (II) of the present invention is a known compound and can be produced by a conventional method.
本発明の加温式毛髪変形用処理剤は、有機ケイ素化合物
ｔｏ、ｏｔ〜５．０重量％（以下、単にチで示す）、好
ましくはＯ１１〜０．５チになる：うに溶剤に溶屏し、
緩衝液で、Ｈ８−１０，５に調整することにより製せら
れる。The heating type hair deforming treatment agent of the present invention contains an organosilicon compound to, ot to 5.0% by weight (hereinafter simply referred to as ``chi''), preferably O11 to 0.5% by weight. death,
It is produced by adjusting H8-10.5 with a buffer solution.
緩衝剤としては、例えばクエン酸／リン酸水素ニナトリ
ウム、塩酸／パルビタールナトリウム／酢酸ナトリウム
、塩酸又はマレイン酸／トリスヒドロキシアミンメタン
、リン酸二水素カリウム又はナトリウム／リン酸水素二
カリウム又はナトリウム、塩酸又はリン酸二水素カリウ
ム又はナトリウム／四ホウ酸ナトリウム、リン酸二水素
カリウム又はナトリウム／水酸化ナトリウム又はカリウ
ム、塩酸／コリジン、ホウ酸／炭酸ナトリウム又は四ホ
ウ酸ナトリウム、塩酸／アミノメチルプロパ／ジオール
、グリシ／／水酸化ナトリウム又はカリウム、ホウ酸／
水酸化ナトウウム、塩酸／ジメチルグリシンナトリウム
、炭酸水素ナトリウム／炭酸ナトリウム、四ホウ酸ナト
リウム／水酸化ナトリウム、炭酸水素ナトリウム／水酸
化ナトリウム又は水溶性アンモニウム塩／ア／モニアの
組み合わせがめげられる。このうち、毛髪、皮膚等にア
ルカリ剤が残留しにくく、毛髪損傷、あるいは皮膚刺激
の少ないものとして、水溶性アンモニウム塩／ア／モニ
アの組み合わせ、水溶性アンモニウム塩／アルギニン、
リジン等の塩基性アミノ酸の組合わせが好ましく、水溶
性アンモニウム塩とじては塩酸塩、炭酸塩、重炭酸塩が
好ましい。Examples of buffering agents include citric acid/disodium hydrogen phosphate, hydrochloric acid/sodium parbital/sodium acetate, hydrochloric acid or maleic acid/trishydroxyaminemethane, potassium or sodium dihydrogen phosphate/dipotassium or sodium hydrogen phosphate, Hydrochloric acid or potassium or sodium dihydrogen phosphate/sodium tetraborate, potassium or sodium dihydrogen phosphate/sodium or potassium hydroxide, hydrochloric acid/collidine, boric acid/sodium carbonate or sodium tetraborate, hydrochloric acid/aminomethyl propane/ Diol, glycine//sodium or potassium hydroxide, boric acid/
Combinations of sodium hydroxide, hydrochloric acid/sodium dimethylglycine, sodium bicarbonate/sodium carbonate, sodium tetraborate/sodium hydroxide, sodium bicarbonate/sodium hydroxide or water-soluble ammonium salts/ammonia are mentioned. Among these, the combination of water-soluble ammonium salt/ammonium salt, water-soluble ammonium salt/arginine,
Combinations of basic amino acids such as lysine are preferred, and water-soluble ammonium salts are preferably hydrochlorides, carbonates, and bicarbonates.
これらの緩衝剤は１例えば水溶性アンモニウム塩／アン
モニアの組み合せで使用する場合１．水溶性アンモニウ
ム塩、例えば重炭酸アンモニウム。These buffers may be used in combinations such as 1. eg water-soluble ammonium salt/ammonia; Water-soluble ammonium salts, such as ammonium bicarbonate.
炭酸アンモニウム又は塩化アンモニウムを本発明処理剤
中に０．０５〜１０チ、好ましくは０．１〜５．０％配
合し、ｐＨｔアンモニア、アルギニ／、リジン等で８．
０〜ｔ Ｏ，Ｓに調整する等の方法で使用される。Ammonium carbonate or ammonium chloride is blended in the treatment agent of the present invention in an amount of 0.05 to 10%, preferably 0.1 to 5.0%, and pHt ammonia, arginine/lysine, etc. is added to 8.0%.
It is used in a method such as adjusting to 0 to t O,S.
更Ｋ、これらの緩衝剤は一種又は二種以上を組み合せて
使用することができる。Furthermore, these buffering agents can be used alone or in combination of two or more.
本発明の加温式毛髪変形用処理剤には、ウェーブ形成効
果の向上、毛髪損傷防止等の目的で、次の（：）ペプチ
ド又はその誘導体、ＩＩ） ２価金属塩、噛）カチオニ
ツク又は両性ポリマー等の１種又は２種以上を併用する
のが好ましい。The heating type hair deforming treatment agent of the present invention contains the following (:) peptides or derivatives thereof, II) divalent metal salts, cationic or amphoteric salts, for the purpose of improving the wave forming effect and preventing hair damage. It is preferable to use one kind or two or more kinds of polymers and the like in combination.
（１） ペプチド又はその誘導体
■塩基性アミノ酸（例えばリジン、アル４二ン〕の１種
又は２種から合成され７ｈ ２３体以上のペプチド、又
は酸性アミノ酸（例えばグルタミン酸、アスパラギ／酸
）の１種又は２種から合成された２ｉｋ体以上のペプチ
ド；■羊毛、羽毛、ひづめ、角などのケラチン蛋白質、
アルフミン、クロッＩＪ ｙ 、コングリシニン、カゼ
インの蛋白質あるいは大豆蛋白質等の分解誘導体として
特開昭５７−８５３０８号等に記載てれている方法によ
り製造された加水分解物：■天然に存在するホルモン、
又は生理活性ペプチド、列えはインスリ／、酸化型グル
タチオ７等が挙げられる。これらのうち、分子量ｔｏ、
ｏｏｏ以下、好ましぐはｓ、 ｏ ｏ ｏ以下のポリリ
ジン；ケラチン蛋白質、大豆蛋白質等の加水分解物；イ
ンスリンが特に好ましい。(1) Peptides or derivatives thereof - A 7h23 or more peptide synthesized from one or two basic amino acids (e.g. lysine, al-42), or one type of acidic amino acid (e.g. glutamic acid, asparagine/acid) or 2ik or more peptides synthesized from two species; ■ Keratin proteins of wool, feathers, hooves, horns, etc.;
Hydrolysates produced by the method described in JP-A-57-85308 etc. as decomposed derivatives of proteins such as alfumin, clot IJ y, conglycinin, casein or soybean protein: ■ Naturally occurring hormones;
Alternatively, bioactive peptides such as insulin/, oxidized glutathione 7, etc. may be mentioned. Among these, molecular weight to,
Polylysine of ooo or less, preferably s, o o o or less; hydrolyzate of keratin protein, soybean protein, etc.; insulin is particularly preferred.
これらのペプチド又はその誘導体は、単独又は２種以上
組合せて、毛髪変形用処理剤に０．ＯＬ〜５０重量％（
以下、単にチで示す）、好ましぐは０．１〜１０％配合
される。These peptides or derivatives thereof may be used alone or in combination of two or more to be added to the hair modification treatment agent. OL ~ 50% by weight (
(hereinafter simply referred to as H), preferably 0.1 to 10%.
（ｉｌ） ２価金属塩
次の一般式
％式％
（式中、ＡはＢ ａ”、Ｃａ２＋、ｚｎ”、 Ｎｉ”＋
及びＭｇ”よりなる群から選ばれる陽イオンを、ＢはＦ
−１Ｃ６−１Ｂｒ−、ニー、５ＯＳ−１ｐｏ；−１ＯＨ
−及び００％−ニジなる群から選ばれる陰イオン金示し
、ｍばＢの原子価を示す）
で表わされる水浴性無機化合物、るるいは上記２価金属
囚の酢酸塩、クエン酸塩、乳酸塩、コ・・り酸塩、酒石
酸塩等の有機酸塩が挙げられ、就中、カルシウム、亜鉛
、ニンケル、マグネ／ラム、バリウムの酢酸塩、あるい
は塩化物が特に好ましい。(il) Divalent metal salt The following general formula % formula % (wherein A is Ba", Ca2+, zn", Ni"+
B is a cation selected from the group consisting of
-1C6-1Br-, knee, 5OS-1po;-1OH
- and 00% - anion selected from the group consisting of 2, 2, 3, 3, 3, 3, 3, 3, 3, 3, 3, 3, 3, 4, 5, 10, 10, 10, 10, 10, 00%, 100%, 00%, 00%, of the anion selected from the group consisting of 2, 3, 3, 3, 3, 3, 3, 3, 3, 3, 3, 3, 3, 4, 5, 1, 1, 2, 1, 1, 1, 1, and 10 of Examples include organic acid salts such as salts, co-phosphates, and tartrates. Among them, acetates or chlorides of calcium, zinc, nickel, magne/lamb, and barium are particularly preferred.
この２価金属塩は、単独又は２種以上組合せて、最終便
用形態において、金属イオノと１〜で１０〜５０００
ｐｐｍ、好ましくは１００〜Ｌ Ｏ００ｐｐｍになるよ
うに配合される。These divalent metal salts may be used singly or in combination of two or more, and in the form for final use, 1 to 5000% of the metal iono is used.
ppm, preferably 100 to 000 ppm.
Ｏｉｉ！ カチオニツク又は両性ポリマー特開昭５６
−９２８１２号に記載の水浴性あるいは無機塩又は有機
塩の存在において水に可尋な次のものが挙げられる。Oiii! Cationic or amphoteric polymer JP-A-56
-92812, which are compatible with water in terms of water bathability or the presence of inorganic salts or organic salts.
■ 酸性ビニル単量体と塩基性ビニル争量体との共重合
物
典型的なものとしては、酸性ビニル単量体又はその塩４
５〜５５モルチ、塩基性ビニル単量体又はその塩４５〜
５５モルチからなる単量体混合換金、公知のラジカル重
合開始剤の存在下で、マ友公知の促進剤の存在下あるい
は不在１１５０℃で共重合すること（ζ：り得られる両
性共重合体金弟げることができる６、。■ Copolymers of acidic vinyl monomers and basic vinyl monomers Typical copolymers include acidic vinyl monomers or their salts4.
5 to 55 molti, basic vinyl monomer or its salt 45 to
Copolymerization at 1150°C in the presence of a known radical polymerization initiator and in the presence or absence of a known Mayu promoter (ζ: the resultant amphoteric copolymer gold) 6. You can have a younger brother.
ここにいうモル比はそれぞれのビニル単量体が１分子中
に１つの酸性基または塩基性基金有する場合金いい、１
分子中に複数個の酸性基ま之は塩基性基金有する単量体
の場合は、正味の電荷がほぼＯとなるよう適宜モル比を
調整する。The molar ratio referred to here is gold when each vinyl monomer has one acidic group or basic group in one molecule;
In the case of a monomer having a plurality of acidic groups and a basic group in its molecule, the molar ratio is appropriately adjusted so that the net charge is approximately O.
酸性ビニル単量体とは、１分子中にカルボキシル基、ス
ルホノ酸基、リン酸基などの酸性基と、重合可能なビニ
ル基？有する化合物でろって、例えば、アクリル竣、メ
タクリル酸、クロトン酸、ビニル安息香酸、２−アクリ
ルアミド−２−メチルプロパンスルホン酸、ステン／ス
ルホ／酸、ビニルスルホ／酸、アリルスルホ７ｔＪｌ、
メタリルスルホンＮ、３−メタクリルプロパンスル
ホン酸、等の不飽和−ｉ基酸及びイタコン酸、マレイ／
酸、フマール酸の如き不飽和二塩基酸、及びこれらのモ
ノエステル等を挙げることが出来る。また、それらの塩
としては、ナトリウム塩、カリウム塩、ア／モニウム塩
等が挙げられる。Acidic vinyl monomers have acidic groups such as carboxyl groups, sulfonate groups, and phosphoric acid groups in one molecule, and polymerizable vinyl groups? For example, acrylic acid, methacrylic acid, crotonic acid, vinylbenzoic acid, 2-acrylamido-2-methylpropanesulfonic acid, sten/sulfo/acid, vinyl sulfo/acid, allylsulfo 7tJl,
unsaturated -i-based acids such as methallylsulfone N, 3-methacrylpropanesulfonic acid, and itaconic acid, malei/
Examples thereof include acids, unsaturated dibasic acids such as fumaric acid, and monoesters thereof. In addition, examples of the salts include sodium salts, potassium salts, ammonium salts, and the like.
塩基性ビニル単量体とは、１分子中に１級アミ７基、２
級アミノ基、３級アミン基等の塩基性基と、重合可能な
ビニル基と金有する化合物でろって、例えば、ジメチル
アミノエチルメタクリレート、ジエチルアミノエチルメ
タクリレート、ジメチルアミノエチルアクリレート、ジ
エチルアミノエチルアクリレート、ジメチルアミノプロ
ピルアクリレート、ジメチルアミンプロピルメタクリル
アミド、ジメチルアミンプロピルアクリルアミド、２−
ビニルビリジ／％ ４−ビニルピリジン、ジメチル了り
ルアミン、ジアリルメチルアミ／等およびその４級化物
を挙げることが出来る。A basic vinyl monomer has 7 primary amino groups and 2 primary amino groups in one molecule.
Compounds containing a basic group such as a primary amino group or a tertiary amine group and a polymerizable vinyl group, such as dimethylaminoethyl methacrylate, diethylaminoethyl methacrylate, dimethylaminoethyl acrylate, diethylaminoethyl acrylate, dimethylamino Propyl acrylate, dimethylamine propyl methacrylamide, dimethylamine propyl acrylamide, 2-
Vinyl pyridine/% 4-vinyl pyridine, dimethyl pyridine, diallyl methyl amine/etc. and quaternized products thereof can be mentioned.
４級化物とは、水素化物、メチル化物、エチル化物等で
あって、対アニオンが塩素イオン。Quaternary compounds include hydrides, methylated compounds, ethylated compounds, etc., and the counter anion is a chlorine ion.
臭素イオン等のハロゲンイオン、水酸基イオン、メチル
硫酸基等でるる化合物が挙げられる。Examples include compounds containing halogen ions such as bromide ions, hydroxyl ions, methyl sulfate groups, and the like.
■ 両性単量体の重合物
典型的なものとして一般式（１ｉ＋で表わされる両性ｉ
Ｌｇ体金、ラジカル重合開始剤の存在下で２０〜１２０
℃の温度範囲で重合して得らルる両性重合体が挙げら几
る。■ Polymers of amphoteric monomers Typical examples include amphoteric i expressed by the general formula (1i+)
Lg body gold, 20-120 in the presence of a radical polymerization initiator
Examples include amphoteric polymers obtained by polymerization in the temperature range of °C.
（式Ｉｌｌ中、Ｒ，、Ｒ，、Ｒ，は水素原子又はメチル
基、Ｒ，、Ｒ，はメチル基又はエチル基でおり、八は一
〇−又は−ＮＨ−１Ｘは−ＣＯｔ 、 −５Ｏ３又は−
ＰＩ（Ｏ，でろり、ｍ、ｎは１〜３の整数である。）
一般式（Ｉｌｌで表わされる両性単量体は、適当なアク
リル酸もしくはメタクリル酸のアミノアルキルエステル
あるいはアミノアルキルアミドとラクトン、サルトノま
之は環状ホスファイトとの反応によって合成することが
できる。(In formula Ill, R,, R,, R, are hydrogen atoms or methyl groups, R,, R, are methyl groups or ethyl groups, 8 is 10-, or -NH-1X is -COt, -5O3 Or-
PI (O, strength, m, n are integers of 1 to 3) The amphoteric monomer represented by the general formula (Ill) is a suitable aminoalkyl ester or aminoalkyl amide of acrylic acid or methacrylic acid and a lactone. , can be synthesized by reaction with a cyclic phosphite.
これらの化合物としでは、渕えば３−ジメチル（メタク
リル酸そジエチル）アンモニウム・プロパ／スルホネー
ト、３−ジメチル（メタクロイルアミドプロピル）アン
モニウム・プロパノスルホネートなどｋｇげることがで
きる。Examples of these compounds include 3-dimethyl (diethyl methacrylate) ammonium propa/sulfonate and 3-dimethyl (methacrylamidopropyl) ammonium propanosulfonate.
重合反応は従来公知の方法、例えば、塊状重合、水溶液
重合、逆相懸濁重合、沈澱重合などの方法により遂行す
ることができ、反応温度２０〜１５０℃でラジカル重合
開始剤の存在下において円滑に行なわれる。The polymerization reaction can be carried out by conventionally known methods such as bulk polymerization, aqueous solution polymerization, reverse phase suspension polymerization, and precipitation polymerization, and can be carried out smoothly at a reaction temperature of 20 to 150°C in the presence of a radical polymerization initiator. It will be held in
ラジカル重合開始剤としては、過硫酸ナトリウム、過硫
酸カリウム、過硫酸アンモニウム ２ 、 ＋）／−ア
ゾビス（２−アミジノプロパン）二塩酸塩、過酸化ベン
ゾイル、過酸（ｔ’水素、過酢酸ナトリウム、ヒドロ過
酸クメノ。Examples of radical polymerization initiators include sodium persulfate, potassium persulfate, ammonium persulfate (2,+)/-azobis(2-amidinopropane) dihydrochloride, benzoyl peroxide, peracid (t' hydrogen, sodium peracetate, hydrochloride), Peracid Kumeno.
アゾビスインブチルニトリルなどが使用てれる。ラジカ
ル重合開始剤の使用量はその種類に工り差はあるが、一
般に全単貸体に対し０．０１〜５重量％程度が好適であ
る。Azobisinbutylnitrile etc. are used. Although the amount of the radical polymerization initiator to be used varies depending on its type, it is generally preferable to use about 0.01 to 5% by weight based on the entire single polymer body.
更に不発明の加温式毛髪変形処理剤には、本発明の効果
を妨げない範囲において、従来公知の他の成分を添加配
合することができる。他の成分としては、例えば、高級
アルコール、カチオン性。Furthermore, other conventionally known ingredients may be added to the heating type hair deforming treatment agent of the present invention within a range that does not impede the effects of the present invention. Other ingredients include, for example, higher alcohols and cationic substances.
アニオン性１両性の界面活性剤、尿累、シリコーン、ス
テアリン酸アルミニウム、明パン等のアルミニウム化合
物、クエ／酸、リンゴ酸等の有機酸、塩酸等の無機酸、
エチレンジアミン、モノ−、ジーもしくはトリーエタノ
ールアミン、モルホリン。Anionic and amphoteric surfactants, silicone, aluminum compounds such as aluminum stearate and light bread, organic acids such as querque acid and malic acid, inorganic acids such as hydrochloric acid,
Ethylenediamine, mono-, di- or triethanolamine, morpholine.
アルギニン、リジン等の塩基性アミノ酸、アンモニア、
苛性ソーダ等のアルカリ剤、養毛料、殺菌料、着色料、
香料等が挙げられる。Basic amino acids such as arginine and lysine, ammonia,
Alkaline agents such as caustic soda, hair nourishing agents, sterilizing agents, coloring agents,
Examples include fragrances and the like.
本発明の加温毛髪変形用処理剤は、まず毛髪に処理剤全
施用する。毛髪は、処理剤の施用に先立ち、ロッド、カ
ーラー、可熱可能なハンディ−タイプのセント器具等に
巻きつけ、所望のウェーブを形成しておくことが望まし
いが、ゆるやかなウェーブ？望む場合は、ドライで−、
ブラシを用いて１通常のブロー仕上げ方法によるくせづ
けが行なえる。施用量は、加温温度等の条件によっても
異なるが通常１回当り１０−１５０Ｍとするのが好まし
い。次いで、毛髪を４０〜１６０℃に加温する。加温温
度及び時間は、毛髪の損傷の程度、使用するペプチドの
種類、緩衝剤の種類、ＤＨ１処理剤の剤型によって変化
し、パーマやヘヤダイ、ブリーチなどをしていない健常
毛髪に対しては、高温での処理が有利であるが、加熱に
よる毛髪の損傷を考慮すると４０〜１６０℃、特に４０
〜８０℃の間が好ましい。又、加温時に、毛髪から水分
が蒸散しないように、キャンプで覆い、更に加湿を行な
うと効果的である。加熱時間は、低温程、長時間を要す
るが、同様の理由から３０分以下、３分〜ｌＯ分の間が
好ましい。一方パーマ、ヘアダイ、ブリーチなどをし念
化学処理毛では、エフ緩和な処理条件を選択することが
望ましＡｏ〔発明の効果〕
本発明の加温式毛髪変形用処理剤全使用←すれば簡単な
操作にエリ比較的低温短時間で毛髪に強固なウェーブ全
形成することができる。また高濃度のアルカリ剤るるい
は遣元性物質及び酸化性物質を使用しないので毛受蛋白
質の浴出が原因となる毛髪の損傷を軽減することができ
るなど従来のバーマネ／トウエーブ剤の有する取扱い上
の諸問題とも屏決できるという利点がある。The heating treatment agent for hair transformation of the present invention is first applied entirely to the hair. Before applying the treatment agent, it is preferable to wrap the hair around a rod, curler, heatable hand-held centrifuge, etc. to form the desired waves.However, gentle waves? Dry, if desired.
Using a brush, you can apply the usual blow finishing method. The amount of application varies depending on conditions such as heating temperature, but it is usually preferably 10-150M per application. The hair is then heated to 40-160°C. The heating temperature and time will vary depending on the degree of hair damage, the type of peptide used, the type of buffer, and the formulation of the DH1 treatment agent. , treatment at high temperature is advantageous, but considering the damage to hair caused by heating, treatment at 40 to 160 °C, especially at 40 °C
Preferably, the temperature is between 80°C and 80°C. Furthermore, it is effective to cover the hair with a camp cover and further humidify it to prevent moisture from evaporating from the hair during heating. The lower the temperature, the longer the heating time is required, but for the same reason, the heating time is preferably 30 minutes or less, and preferably between 3 minutes and 10 minutes. On the other hand, for chemically treated hair that has been permed, dyed, bleached, etc., it is desirable to select treatment conditions that are gentle on the effect. It is possible to form strong waves on the hair in a short time at a relatively low temperature. In addition, since it does not use high-concentration alkaline agents, oxidizing substances, or oxidizing substances, it can reduce hair damage caused by leaching out of hair-receptive proteins. It has the advantage of being able to decide both of the above issues at once.
（以下余白）
〔実施例〕
次に実施例を挙げて本発明を説明するが、本発明はこれ
らの実施例に制約されるものではない。(Margins below) [Examples] Next, the present invention will be explained with reference to Examples, but the present invention is not limited to these Examples.
実施例１
表１に示す組成の加温式毛髪変形用処理剤を調製し、溶
液の安定性、パーマのかか夛、感触及び臭いくついて評
価した。結果を表２に示す。Example 1 A heating type hair modification treatment agent having the composition shown in Table 1 was prepared and evaluated for solution stability, perm shape, texture, and odor. The results are shown in Table 2.
〈評価方法〉
（１）安定性
詞！１１！後、密栓をした状態で室温下に一週間放置し
、製造直後との液の性状の変化ｔ−視察した。<Evaluation method> (1) Stability words! 11! Thereafter, the solution was left sealed at room temperature for one week, and the changes in the properties of the solution compared to those immediately after production were observed.
評価基準二 〇 透明
× 沈殿物生成
（２） パーマのかかり
製造直後のサンプル及び、−週間放置したサンプルを用
い、ロッド上に巻かれた日本人健常毛髪ドレスに塗布し
、１０分間８０℃で加温した後、水ですすぎ、ロッドか
ら毛髪をはずし、ウェーブのでき方を評価した。Evaluation Criteria 2: Transparent x Precipitate Formation (2) Using a sample immediately after perming and a sample that had been left for - weeks, it was applied to a dress of healthy Japanese hair wrapped around a rod, and heated at 80°C for 10 minutes. After warming, the rod was rinsed with water, the hair was removed from the rod, and the formation of waves was evaluated.
評価基準： ◎ やや強い Ｏ普通 △ やや弱い × 弱い （３） パーマ処理による感触 （２）のバー１処理後要の感触、艶の評価を行なった。Evaluation criteria: ◎ Slightly strong O normal △ Slightly weak × Weak (3) Feeling after perm treatment After the bar 1 treatment in (2), the feel and gloss were evaluated.
評価基準
（１）滑らかさ
○：やや良い ◎：良い
△：普通
×：悪い
（２）艶
○：やや良い ◎：良い
△：普通
×：悪い
表 ２
実施例２
表３に示す加温−温式パーマネントウエーブ剤を調製し
、ウェーブ形成及びウェーブ保持性を試験した。その結
果を表３に示す。Evaluation criteria (1) Smoothness ○: Fairly good ◎: Good △: Normal Formula permanent wave agents were prepared and tested for wave formation and wave retention. The results are shown in Table 3.
ウェーブ度及びウェーブ保持力創建試験（１）１５ｃ＋
ａの日本人の健常毛髪１０本を一束とレガラス管（直径
１０ｆｉ）に巻き、これを各処理剤中に３０℃、５０℃
、８０℃で各々２０分間浸漬した。水で充分すすいだ後
、毛束をガラス管よシはすすと、毛髪はコイル状になる
。このときの毛髪のコイルの長さを測定した。Wave degree and wave holding power creation test (1) 15c+
A bundle of 10 healthy Japanese hairs (a) was wrapped around a reglas tube (diameter 10fi) and placed in each treatment agent at 30°C and 50°C.
, and immersed at 80° C. for 20 minutes each. After rinsing thoroughly with water, the hair strands are rinsed through a glass tube, and the hair becomes coiled. The length of the hair coil at this time was measured.
ウェーブ度は次式よシ求めた。The wave degree was calculated using the following formula.
■
Ｘ：毛髪の全長（１５ＣＩｆｔ）
Ｙ二毛髪コイルの長さくａＩＬ）
（ａｒ）（１）で使用した毛髪をつり下げたまま１日風
乾した後４０℃のラウリル硫酸ナトリウムの０．５チ水
溶液に１分間浸漬したままで軽く動かし洗浄した。次い
で、これを充分すすぎ、再び毛髪コイルの長さを測定し
た。ウェーブ保持力は、次式により求めたウェーブ保持
率で評価した。■ X: Total length of hair (15 CIft) Y: Length of two hair coils (aIL) (ar) The hair used in (1) was air-dried for one day, then treated with a 0.5% aqueous solution of sodium lauryl sulfate at 40°C. The product was soaked in water for 1 minute and then gently moved for cleaning. This was then thoroughly rinsed and the length of the hair coil was measured again. The wave retention force was evaluated by the wave retention rate determined by the following formula.
以下余白
＋：ＳＨ基濃度が各還元剤で同一になるように設定
蒼Ｊｋ：第１液（７チチオグリコール酸、声９．０）に
１０分浸漬、第２液（４％臭素酸ナトリウム）に１０分
浸漬
聞調整：０．２Ｍ塩化アンモニウム／アンモニア緩衝液
系
溶媒： ８１（ＯＣＨｓ）ｓＣ）Ｉ４＆（％ＳＨｎ−
グロ／’？ノール ２４チ〔部Ｃ迅Ｃ迅Ｃ烏８１（Ｃル
）、〕ρ 〃４５慢（Ｃ（ＣＨｓ）ｓｏ）ｓｓｉｃ迅ｃ
＆ｃＨｔｓＨ’ ５６ ％実施例３
次の組成からなる加温−温式パーマネントウエーブ剤を
調製した。Below margin +: SH group concentration is set to be the same for each reducing agent Blue Jk: Immersed in the first solution (7 thiothioglycolic acid, voice 9.0) for 10 minutes, second solution (4% sodium bromate) ) for 10 minutes Adjustment: 0.2M ammonium chloride/ammonia buffer system Solvent: 81(OCHs)sC)I4&(%SHn-
Glo/'? Nor 24 Chi [part C quick C quick C crow 81 (C le),] ρ 〃45 arrogant (C(CHs) so) ssic quick c
&cHtsH' 56% Example 3 A heating-heating permanent waving agent having the following composition was prepared.
処方Ｉ
Ａ、５ｉ（ＯＣＨｓ）ｓｃ馬ｃＨ４Ｈ＊ｓＨ２，０（％
）Ｂ、ｎ−グロパノール ２４．ＯＣ２ケ
ラチン蛋白質加水分解物（Ｍ、Ｗ６３０ ）
１．０Ｄ、 塩化ステアリルトリメチルアンモ
ニウムクロライド １．ＯＥ、 ポリオキシエチレン
ラウリルエーテル（Ｅ、０２３モル） １．０２６重
炭酸アンモニウム ３．０Ｇ、アルギニン
ｐＨ８，５に調整■１．香料
０．２
丁、イオン交換水 バランス窒素置換し
たイオン交換水にＣ，Ｆを溶解させ、ＢにＡ、Ｄ、Ｅ、
Ｈを溶解させた液を加え最後にＧで声を調整し製造する
。Prescription I A, 5i (OCHs) sc Horse scH4H*sH2,0 (%
) B, n-gropanol 24. OC2 keratin protein hydrolyzate (M, W630)
1.0D, stearyltrimethylammonium chloride 1. OE, polyoxyethylene lauryl ether (E, 023 mol) 1.026 ammonium bicarbonate 3.0G, arginine Adjust to pH 8.5■1. fragrance
0.2 tons, ion exchange water Dissolve C and F in ion exchange water that has been replaced with balance nitrogen, and add A, D, E,
Add a solution containing H and finally adjust the voice with G to manufacture.
処方２
Ａ、 ＣＨ８ＣＨｔＣＨ２ＣＨ，５ｉ（ＣＨｓ）ｚＥ
ｚｏ １．５ （％）Ｂ、ｎ−プロパツール
３０．ＯＣ６塩化カルシカルシウム
１．ＯＤ、 塩化セチルトリメチルアンモニウムク
ロライド ２．０Ｅ、塩化アンモニウム
２．５Ｆ、 アンモニア水（２８％）
聞９．ＯＧ、香料 ０．Ｉ
Ｈ，イオン交換水 バランス窒素置換
したイオン交換水にＣ，Ｅを溶解させ、ＢにＡ、Ｄ、Ｇ
を溶解させ之１ｙ、全加え、最後にＦでメ（調整を行な
い製造する。Prescription 2 A, CH8CHtCH2CH, 5i(CHs)zE
zo 1.5 (%) B, n-proper tool 30. OC6 Calcium Chloride
1. OD, Cetyltrimethylammonium chloride 2.0E, Ammonium chloride
2.5F, ammonia water (28%)
9. OG, fragrance 0. I H, ion-exchanged water Balance Dissolve C and E in ion-exchanged water substituted with nitrogen, and add A, D, and G to B.
Dissolve 1y, add everything, and finally adjust with F to produce.
処方３
Ａ、 ５ｉ（ＯＣＨａ）ｓｃＨ２ｃＨｔｃＨｔｓＨ２
，０（％）Ｃ，ｎ−プロパツール ２０．
ＯＤ、 塩化ステアリルトリメチルアンモニウムクロラ
イド ２．ＯＥ、グリシルグリシン ３．
５Ｆ、 リジン ｐｊ（
９，ＯＫ調整Ｇ、香料 ０．２
Ｈ，イオン交換水 バランス１００
．０
窒素置換し次イオン交換水にＢ、Ｅを溶解させ、ＣＫＡ
、Ｄ、Ｇ全溶解したａｔ−加え、最後にＦでｐＨｔ−調
整し、製造する。Prescription 3 A, 5i(OCHa)scH2cHtcHtsH2
,0(%)C,n-Proper Tool 20.
OD, stearyltrimethylammonium chloride 2. OE, glycylglycine 3.
5F, Lysine pj (
9, OK adjustment G, fragrance 0.2 H, ion exchange water balance 100
．． 0 Dissolve B and E in ion-exchanged water after replacing with nitrogen, and add CKA.
, D, G completely dissolved at-added, and finally pHt-adjusted with F to produce.
処方４
Ａ−０（ＳＣ＆Ｃ＆ＣＨｚＳｌ（ＣＨａ）ＪｔＯ２，０
（％）Ｂ、 ｎ−プロパツール ２５．Ｏ
Ｄ、塩化ナトリウム ３．ＯＥ、 塩化
ステアリルトリメチルアンモニウムクロライド２．０Ｆ
、塩化アンモニウム １．０Ｇ、アンモニ
ア水 ｐＨ９，０に博Ｈ１香料
０．２
工、イオン交換水 バランス１００．
００
窒素置換したイオン交換水ＫＡ、Ｃ，Ｄ、Ｆを溶解させ
、ＢＫＥ 、Ｈを溶解させた液を加え、最後にＧで…を
調整し、製造する。Prescription 4 A-0 (SC&C&CHzSl(CHa)JtO2,0
(%)B, n-proper tool 25. O
D. Sodium chloride 3. OE, stearyltrimethylammonium chloride 2.0F
, ammonium chloride 1.0G, ammonia water pH 9.0, Hiroshi H1 fragrance
0.2 engineering, ion exchange water balance 100.
00 Dissolve nitrogen-substituted ion-exchanged water KA, C, D, and F, add a solution in which BKE and H are dissolved, and finally adjust with G to produce.
以上that's all
Claims (1)
ルコキシ基、Ｒ＿４、Ｒ＿５及びＲ＿６は炭素数１〜３
のアルキレン基を示す） を含有することを特徴とする加温式毛髪変形用処理剤。[Claims] 1. The following general formula (I) or (II) ▲There are mathematical formulas, chemical formulas, tables, etc.▼(I) ▲There are mathematical formulas, chemical formulas, tables, etc.▼(II) (In the formula, R_1 , R_2 and R_3 are alkoxy groups having 1 to 3 carbon atoms, and R_4, R_5 and R_6 are alkoxy groups having 1 to 3 carbon atoms.
(representing an alkylene group).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP9919486A JPS62255413A (en) | 1986-04-28 | 1986-04-28 | Heating type hair-deforming agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP9919486A JPS62255413A (en) | 1986-04-28 | 1986-04-28 | Heating type hair-deforming agent |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS62255413A true JPS62255413A (en) | 1987-11-07 |
Family
ID=14240837
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP9919486A Pending JPS62255413A (en) | 1986-04-28 | 1986-04-28 | Heating type hair-deforming agent |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS62255413A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5609861A (en) * | 1994-12-02 | 1997-03-11 | L'oreal | Composition and process using silicone thiols for the protection of the color of dyed keratinous fibres |
| US5609856A (en) * | 1991-04-19 | 1997-03-11 | L'oreal | Composition and process using silicone thiols for the color of dyed keratinous fibres |
| FR2928087A1 (en) * | 2008-02-29 | 2009-09-04 | Oreal | COMPOSITION FOR COLORING KERATIN FIBERS COMPRISING AT LEAST ONE DIRECT DYE WITH PROTECTED DISULFIDE / THIOL FUNCTION AND AT LEAST ONE THIOL FUNCTIONAL SILICY COMPOUND AND PROCESS USING THE COMPOSITION. |
| WO2013092779A2 (en) | 2011-12-20 | 2013-06-27 | L'oreal | Cosmetic composition comprising at least one silicone functionalized with one or more mercapto groups and at least one hygroscopic salt |
| JP2013538842A (en) * | 2010-10-01 | 2013-10-17 | ロレアル | Process for treating keratin fibers using at least one sulfur-containing reducing agent, at least one cationic polymer and at least one mercaptosiloxane |
-
1986
- 1986-04-28 JP JP9919486A patent/JPS62255413A/en active Pending
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5609856A (en) * | 1991-04-19 | 1997-03-11 | L'oreal | Composition and process using silicone thiols for the color of dyed keratinous fibres |
| US5609861A (en) * | 1994-12-02 | 1997-03-11 | L'oreal | Composition and process using silicone thiols for the protection of the color of dyed keratinous fibres |
| FR2928087A1 (en) * | 2008-02-29 | 2009-09-04 | Oreal | COMPOSITION FOR COLORING KERATIN FIBERS COMPRISING AT LEAST ONE DIRECT DYE WITH PROTECTED DISULFIDE / THIOL FUNCTION AND AT LEAST ONE THIOL FUNCTIONAL SILICY COMPOUND AND PROCESS USING THE COMPOSITION. |
| WO2009109457A3 (en) * | 2008-02-29 | 2009-11-05 | L'oreal | Composition for dyeing keratin fibres comprising at least one direct dye comprising a disulphide/protected-thiol function and at least one siliceous compound comprising a thiol function and method using the composition |
| JP2013538842A (en) * | 2010-10-01 | 2013-10-17 | ロレアル | Process for treating keratin fibers using at least one sulfur-containing reducing agent, at least one cationic polymer and at least one mercaptosiloxane |
| WO2013092779A2 (en) | 2011-12-20 | 2013-06-27 | L'oreal | Cosmetic composition comprising at least one silicone functionalized with one or more mercapto groups and at least one hygroscopic salt |
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