JPS62224354A - Solid aromatic agent - Google Patents
Solid aromatic agentInfo
- Publication number
- JPS62224354A JPS62224354A JP61066987A JP6698786A JPS62224354A JP S62224354 A JPS62224354 A JP S62224354A JP 61066987 A JP61066987 A JP 61066987A JP 6698786 A JP6698786 A JP 6698786A JP S62224354 A JPS62224354 A JP S62224354A
- Authority
- JP
- Japan
- Prior art keywords
- fragrance
- present
- polynorbornene
- product
- fragrances
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000007787 solid Substances 0.000 title claims description 12
- 125000003118 aryl group Chemical group 0.000 title description 14
- 239000003205 fragrance Substances 0.000 claims description 63
- 229920000636 poly(norbornene) polymer Polymers 0.000 claims description 19
- -1 Yellow No. 4 Chemical compound 0.000 description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 15
- 239000000203 mixture Substances 0.000 description 11
- 239000012459 cleaning agent Substances 0.000 description 10
- 238000004140 cleaning Methods 0.000 description 8
- 235000005979 Citrus limon Nutrition 0.000 description 7
- 244000131522 Citrus pyriformis Species 0.000 description 7
- 239000004094 surface-active agent Substances 0.000 description 6
- 238000002156 mixing Methods 0.000 description 5
- ULQISTXYYBZJSJ-UHFFFAOYSA-N 12-hydroxyoctadecanoic acid Chemical class CCCCCCC(O)CCCCCCCCCCC(O)=O ULQISTXYYBZJSJ-UHFFFAOYSA-N 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 239000003599 detergent Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000000796 flavoring agent Substances 0.000 description 4
- 235000019634 flavors Nutrition 0.000 description 4
- 239000003349 gelling agent Substances 0.000 description 4
- 238000003860 storage Methods 0.000 description 4
- HZVFRKSYUGFFEJ-YVECIDJPSA-N (2r,3r,4s,5r)-7-phenylhept-6-ene-1,2,3,4,5,6-hexol Chemical class OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=CC1=CC=CC=C1 HZVFRKSYUGFFEJ-YVECIDJPSA-N 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 239000002386 air freshener Substances 0.000 description 3
- 230000006866 deterioration Effects 0.000 description 3
- 230000014759 maintenance of location Effects 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 235000019198 oils Nutrition 0.000 description 3
- 229920000259 polyoxyethylene lauryl ether Polymers 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- FMZUHGYZWYNSOA-VVBFYGJXSA-N (1r)-1-[(4r,4ar,8as)-2,6-diphenyl-4,4a,8,8a-tetrahydro-[1,3]dioxino[5,4-d][1,3]dioxin-4-yl]ethane-1,2-diol Chemical class C([C@@H]1OC(O[C@@H]([C@@H]1O1)[C@H](O)CO)C=2C=CC=CC=2)OC1C1=CC=CC=C1 FMZUHGYZWYNSOA-VVBFYGJXSA-N 0.000 description 2
- 229940114072 12-hydroxystearic acid Drugs 0.000 description 2
- RNMDNPCBIKJCQP-UHFFFAOYSA-N 5-nonyl-7-oxabicyclo[4.1.0]hepta-1,3,5-trien-2-ol Chemical compound C(CCCCCCCC)C1=C2C(=C(C=C1)O)O2 RNMDNPCBIKJCQP-UHFFFAOYSA-N 0.000 description 2
- SGHZXLIDFTYFHQ-UHFFFAOYSA-L Brilliant Blue Chemical compound [Na+].[Na+].C=1C=C(C(=C2C=CC(C=C2)=[N+](CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C=2C(=CC=CC=2)S([O-])(=O)=O)C=CC=1N(CC)CC1=CC=CC(S([O-])(=O)=O)=C1 SGHZXLIDFTYFHQ-UHFFFAOYSA-L 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- 229920000161 Locust bean gum Polymers 0.000 description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 2
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- 241000288706 Sorex Species 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 150000001408 amides Chemical class 0.000 description 2
- 239000000679 carrageenan Substances 0.000 description 2
- 235000010418 carrageenan Nutrition 0.000 description 2
- 229920001525 carrageenan Polymers 0.000 description 2
- 229940113118 carrageenan Drugs 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- ZSWFCLXCOIISFI-UHFFFAOYSA-N cyclopentadiene Chemical compound C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 description 2
- 229940087101 dibenzylidene sorbitol Drugs 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 238000011010 flushing procedure Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical compound Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 239000000711 locust bean gum Substances 0.000 description 2
- 235000010420 locust bean gum Nutrition 0.000 description 2
- 239000002304 perfume Substances 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 239000000344 soap Substances 0.000 description 2
- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 description 2
- KRTGXMRAJNNWOH-DPDRHGIRSA-N (2s)-2-(dodecanoylamino)-n,n'-dioctadecylpentanediamide Chemical compound CCCCCCCCCCCCCCCCCCNC(=O)CC[C@H](NC(=O)CCCCCCCCCCC)C(=O)NCCCCCCCCCCCCCCCCCC KRTGXMRAJNNWOH-DPDRHGIRSA-N 0.000 description 1
- QIVRABJQTNPYAI-QFIPXVFZSA-N (2s)-n,n'-dibutyl-2-(dodecanoylamino)pentanediamide Chemical compound CCCCCCCCCCCC(=O)N[C@H](C(=O)NCCCC)CCC(=O)NCCCC QIVRABJQTNPYAI-QFIPXVFZSA-N 0.000 description 1
- QGKMIGUHVLGJBR-UHFFFAOYSA-M (4z)-1-(3-methylbutyl)-4-[[1-(3-methylbutyl)quinolin-1-ium-4-yl]methylidene]quinoline;iodide Chemical compound [I-].C12=CC=CC=C2N(CCC(C)C)C=CC1=CC1=CC=[N+](CCC(C)C)C2=CC=CC=C12 QGKMIGUHVLGJBR-UHFFFAOYSA-M 0.000 description 1
- FFJCNSLCJOQHKM-CLFAGFIQSA-N (z)-1-[(z)-octadec-9-enoxy]octadec-9-ene Chemical compound CCCCCCCC\C=C/CCCCCCCCOCCCCCCCC\C=C/CCCCCCCC FFJCNSLCJOQHKM-CLFAGFIQSA-N 0.000 description 1
- CJYDNDLQIIGSTH-UHFFFAOYSA-N 1-(3,5,7-trinitro-1,3,5,7-tetrazocan-1-yl)ethanone Chemical compound CC(=O)N1CN([N+]([O-])=O)CN([N+]([O-])=O)CN([N+]([O-])=O)C1 CJYDNDLQIIGSTH-UHFFFAOYSA-N 0.000 description 1
- RFVNOJDQRGSOEL-UHFFFAOYSA-N 2-hydroxyethyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCO RFVNOJDQRGSOEL-UHFFFAOYSA-N 0.000 description 1
- GWGVQDWXRVUTSW-UQKRIMTDSA-N CCCCCCCCCCCC[NH3+].CCCCCCCCCCCC(=O)N[C@@H](CCC(O)=O)C([O-])=O Chemical compound CCCCCCCCCCCC[NH3+].CCCCCCCCCCCC(=O)N[C@@H](CCC(O)=O)C([O-])=O GWGVQDWXRVUTSW-UQKRIMTDSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- ZKQDCIXGCQPQNV-UHFFFAOYSA-N Calcium hypochlorite Chemical compound [Ca+2].Cl[O-].Cl[O-] ZKQDCIXGCQPQNV-UHFFFAOYSA-N 0.000 description 1
- 238000005698 Diels-Alder reaction Methods 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 241000402754 Erythranthe moschata Species 0.000 description 1
- FPVVYTCTZKCSOJ-UHFFFAOYSA-N Ethylene glycol distearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCOC(=O)CCCCCCCCCCCCCCCCC FPVVYTCTZKCSOJ-UHFFFAOYSA-N 0.000 description 1
- KZSNJWFQEVHDMF-BYPYZUCNSA-N L-valine Chemical compound CC(C)[C@H](N)C(O)=O KZSNJWFQEVHDMF-BYPYZUCNSA-N 0.000 description 1
- 244000178870 Lavandula angustifolia Species 0.000 description 1
- 235000010663 Lavandula angustifolia Nutrition 0.000 description 1
- 235000019501 Lemon oil Nutrition 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 235000019082 Osmanthus Nutrition 0.000 description 1
- 241000333181 Osmanthus Species 0.000 description 1
- 235000021314 Palmitic acid Nutrition 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- KZSNJWFQEVHDMF-UHFFFAOYSA-N Valine Natural products CC(C)C(N)C(O)=O KZSNJWFQEVHDMF-UHFFFAOYSA-N 0.000 description 1
- IJCWFDPJFXGQBN-RYNSOKOISA-N [(2R)-2-[(2R,3R,4S)-4-hydroxy-3-octadecanoyloxyoxolan-2-yl]-2-octadecanoyloxyethyl] octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@@H](OC(=O)CCCCCCCCCCCCCCCCC)[C@H]1OC[C@H](O)[C@H]1OC(=O)CCCCCCCCCCCCCCCCC IJCWFDPJFXGQBN-RYNSOKOISA-N 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 125000004442 acylamino group Chemical group 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 235000001014 amino acid Nutrition 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- 239000000872 buffer Substances 0.000 description 1
- DNSISZSEWVHGLH-UHFFFAOYSA-N butanamide Chemical compound CCCC(N)=O DNSISZSEWVHGLH-UHFFFAOYSA-N 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 239000004203 carnauba wax Substances 0.000 description 1
- 235000013869 carnauba wax Nutrition 0.000 description 1
- 239000000645 desinfectant Substances 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- OKUKGXPRGMWAFM-LHEWISCISA-N didodecyl (2s)-2-(dodecanoylamino)pentanedioate Chemical compound CCCCCCCCCCCCOC(=O)CC[C@H](NC(=O)CCCCCCCCCCC)C(=O)OCCCCCCCCCCCC OKUKGXPRGMWAFM-LHEWISCISA-N 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- ILRSCQWREDREME-UHFFFAOYSA-N dodecanamide Chemical compound CCCCCCCCCCCC(N)=O ILRSCQWREDREME-UHFFFAOYSA-N 0.000 description 1
- JRBPAEWTRLWTQC-UHFFFAOYSA-N dodecylamine Chemical class CCCCCCCCCCCCN JRBPAEWTRLWTQC-UHFFFAOYSA-N 0.000 description 1
- 239000002552 dosage form Substances 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 229940100608 glycol distearate Drugs 0.000 description 1
- 239000000017 hydrogel Substances 0.000 description 1
- WPFVBOQKRVRMJB-UHFFFAOYSA-N hydroxycitronellal Chemical compound O=CCC(C)CCCC(C)(C)O WPFVBOQKRVRMJB-UHFFFAOYSA-N 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 125000000400 lauroyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000001102 lavandula vera Substances 0.000 description 1
- 235000018219 lavender Nutrition 0.000 description 1
- 239000010501 lemon oil Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 239000001683 mentha spicata herb oil Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- CXKWCBBOMKCUKX-UHFFFAOYSA-M methylene blue Chemical compound [Cl-].C1=CC(N(C)C)=CC2=[S+]C3=CC(N(C)C)=CC=C3N=C21 CXKWCBBOMKCUKX-UHFFFAOYSA-M 0.000 description 1
- 229960000907 methylthioninium chloride Drugs 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- RQTRYXKWNDRECO-HKBQPEDESA-N n-[(2s)-1-(dodecylamino)-1-oxo-3-phenylpropan-2-yl]dodecanamide Chemical compound CCCCCCCCCCCCNC(=O)[C@@H](NC(=O)CCCCCCCCCCC)CC1=CC=CC=C1 RQTRYXKWNDRECO-HKBQPEDESA-N 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- JFNLZVQOOSMTJK-KNVOCYPGSA-N norbornene Chemical compound C1[C@@H]2CC[C@H]1C=C2 JFNLZVQOOSMTJK-KNVOCYPGSA-N 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 125000006353 oxyethylene group Chemical group 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 239000001818 polyoxyethylene sorbitan monostearate Substances 0.000 description 1
- 235000010989 polyoxyethylene sorbitan monostearate Nutrition 0.000 description 1
- 230000002250 progressing effect Effects 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 238000007151 ring opening polymerisation reaction Methods 0.000 description 1
- 239000010666 rose oil Substances 0.000 description 1
- 235000019719 rose oil Nutrition 0.000 description 1
- 239000001589 sorbitan tristearate Substances 0.000 description 1
- 235000011078 sorbitan tristearate Nutrition 0.000 description 1
- 229960004129 sorbitan tristearate Drugs 0.000 description 1
- 235000019721 spearmint oil Nutrition 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- UJMBCXLDXJUMFB-UHFFFAOYSA-K trisodium;5-oxo-1-(4-sulfonatophenyl)-4-[(4-sulfonatophenyl)diazenyl]-4h-pyrazole-3-carboxylate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)C1=NN(C=2C=CC(=CC=2)S([O-])(=O)=O)C(=O)C1N=NC1=CC=C(S([O-])(=O)=O)C=C1 UJMBCXLDXJUMFB-UHFFFAOYSA-K 0.000 description 1
- 239000004474 valine Substances 0.000 description 1
- 239000000341 volatile oil Substances 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
Landscapes
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
Abstract
(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.
Description
【発明の詳細な説明】
産業上の利用分野
本発明は固形芳香剤、詳しくはポリノルボルネンを含有
する固形芳香剤に関する。DETAILED DESCRIPTION OF THE INVENTION Field of the Invention The present invention relates to solid fragrances, particularly solid fragrances containing polynorbornene.
従 来 の 技 術
従来より、苗内その他の限定空間内を斌香するための固
形芳香剤は種々研究開発されているが、いずれも、芳香
性、保形性、製造作業性、安定性等の面で尚改善される
余地があった。Conventional technology A variety of solid fragrances have been researched and developed to infuse the inside of seedlings and other confined spaces, but all of them have problems such as aroma, shape retention, manufacturing workability, stability, etc. There was still room for improvement in this respect.
また近年、生活水準の向上に伴い、貯水式水洗トイレも
普及し、該トイレ用芳香剤やインタンク式トイレ洗浄剤
の研究開発もまた種々行なわれており、特に上記芳香剤
とインタンク式トイレ洗浄剤との両者を兼備えた商品の
開発も進められている。然るに上記芳香剤とは本来空気
との接触によ゛り空間斌香をなし得るものであり、一方
法浄剤は水との接触により水中に溶解され、便器その他
の洗浄効果を奏するものであり、両者は、本質的にその
使用形態及び機能を異にし、之等に応じて夫々別個にv
A製され、単に之等を組み合せた所で両機能即ち徐々に
溶解して所望の洗浄効果を奏する機能及び空気中に揮散
して芳香性雰囲気とする機能を、同時に且つ充分に発揮
させることは困難である。In addition, in recent years, as living standards have improved, water storage type flush toilets have become popular, and various research and development efforts have been conducted on air fresheners for these toilets and in-tank toilet cleaners. The development of products that combine both cleaning and detergent properties is also progressing. However, the above-mentioned air fresheners are essentially those that can scent a space when they come into contact with the air, whereas the method cleaners are those that dissolve in water when they come into contact with water and have the effect of cleaning toilet bowls and other areas. , both have essentially different usage forms and functions, and can be used separately depending on the
It is possible to simultaneously and fully exert both functions, namely, the function of gradually dissolving to produce the desired cleaning effect and the function of volatilizing into the air to create an aromatic atmosphere, simply by combining these functions. Have difficulty.
発明が解決しようとする問題点
本発明の目的は、従来の芳香剤を改良し、また芳香剤と
洗浄剤との両機能を具備する新しい芳香剤乃至芳香洗浄
剤を提供することにある。Problems to be Solved by the Invention An object of the present invention is to improve conventional fragrances and to provide a new fragrance or fragrance cleaning agent that functions as both a fragrance and a cleaning agent.
問題点を解決するための手段
本発明によれば、ポリノルボルネンを含有することを特
徴とする固形芳香剤が提供される。Means for Solving the Problems According to the present invention, a solid fragrance characterized by containing polynorbornene is provided.
本発明者らは、鋭意研究を重ねた結果、上記ポリノルボ
ルネンが、常温下で多量の香料成分を吸油固化する能力
を有し、この吸油能は水の存在下でも低下せず、また上
記固化物は熱に対して安定で約70℃前後でも形がくず
れないという事実を見出し、この知見に基づいて本発明
を完成するに至った。As a result of extensive research, the present inventors have discovered that the above-mentioned polynorbornene has the ability to absorb and solidify a large amount of fragrance ingredients at room temperature, and that this oil-absorbing ability does not decrease even in the presence of water. They discovered that objects are stable against heat and do not lose their shape even at temperatures around 70°C, and based on this knowledge they have completed the present invention.
従って、本発明の芳香剤は、上記ポリノルボルネンの使
用に基づいて、香料成分を多量に配合することができ、
しかも製品形態に試形する際等に加熱や加温を必要とば
ず、その製造作業が容易、簡便であると共に、これに伴
われる香料成分の変質もなく、非常に優れた芳香性を有
する。また上記ポリノルボルネンは、水の存在下でも吸
油能の低下がなく、選択的に香料を吸油固化できるので
、本発明芳香剤は、これをとドロゲルタイプとすること
もでき、本発明によれば高濃度で香料を含有する上記ヒ
ドロゲルタイプの芳香剤も提供される。Therefore, the fragrance of the present invention can contain a large amount of fragrance ingredients based on the use of the above-mentioned polynorbornene,
Furthermore, there is no need for heating or warming when testing into a product form, making the manufacturing process easy and simple, and there is no accompanying deterioration of fragrance components, resulting in extremely excellent aromatic properties. . In addition, the above-mentioned polynorbornene does not reduce its oil-absorbing ability even in the presence of water and can selectively absorb and solidify fragrances, so the fragrance of the present invention can also be made into a drogel type. Also provided are hydrogel-type fragrances as described above containing perfume in concentrations.
更に本発明の芳香剤は上記ポリノルボルネンの使用に基
づいて熱に対して安定であり、約70 ’C前後でも形
崩れがないという優れた保形性を有する。Further, the fragrance of the present invention is stable against heat due to the use of the above polynorbornene, and has excellent shape retention that does not lose its shape even at around 70'C.
また上記各種の利点に基づいて、本発明芳香剤は、これ
に更に界面活性剤や次亜塩素酸塩等の塩素系の洗浄剤等
を配合すれば、上記利点を保持した芳香洗浄剤として利
用できる。即ち、該芳香洗浄剤は、これを例えば貯水タ
ンクの手洗部等に設置すれば、フラッシングによる水洗
時、水中に洗浄剤成分が溶出して洗浄効果が奏されると
共に、上記フラッシング時以外は、製品自体は水と接触
せず空気中に露出され、これにより空間賦香の目的を効
果的に達成できる。しかも実に驚くべきことに繰返しフ
ラッシングによっても製品自体の崩壊流出がなく、香料
の揮発性も阻害されず、これが製品の香料含有率の高さ
と相俟って、芳香剤として充分な芳香を持続発揮できる
。殊に本発明芳香剤は高香料含有率でも安定で、空間賦
香をより効果的に行ない得るものである。Furthermore, based on the various advantages mentioned above, the aromatic agent of the present invention can be used as an aromatic cleaning agent that maintains the above advantages by adding surfactants, chlorine-based cleaning agents such as hypochlorite, etc. can. That is, if the aromatic cleaning agent is installed, for example, in the hand washing section of a water storage tank, the cleaning agent components will be eluted into the water during flushing, and the cleaning effect will be achieved. The product itself does not come into contact with water and is exposed to air, which can effectively achieve the purpose of spatial perfuming. What is really surprising is that even after repeated flushing, the product itself does not disintegrate and flow out, and the volatility of the fragrance is not inhibited.This, combined with the product's high fragrance content, allows it to maintain a sufficient fragrance as an air freshener. can. In particular, the fragrance of the present invention is stable even at a high fragrance content and can more effectively perfume a space.
本発明芳香剤は、ポリノルボルネンを含有することを必
須とする。該ポリノルボルネンは、エチレンとシクロペ
ンタジェンとのディールス・アルダ−反応により得られ
るノルボルネンを開環重合して得られ、二重結合と五員
環とが交互に結合した構造を有するポリマーであり、そ
の代表例としテハ、フランスCdFケーミ(Cd F
Chime)社の開発した「ノーソレツクス(nor
sorex ) J及び[フイクソール(fixol
) J (日本ゼオン社)を例示できる。該ポリノル
ボルネンは、得られる芳香剤製品中に通常約1〜30重
量%、好ましくは約3〜20重量%配合されるのがよく
、この配合により、本発明所期の優れた効果を奏する。The fragrance of the present invention essentially contains polynorbornene. The polynorbornene is a polymer obtained by ring-opening polymerization of norbornene obtained by a Diels-Alder reaction between ethylene and cyclopentadiene, and has a structure in which double bonds and five-membered rings are alternately bonded, Typical examples are Teha, France CdF Cemi (CdF
"Nor Solex" developed by Chime
sorex) J and [fixol
) J (Nippon Zeon Co., Ltd.) is an example. The polynorbornene is usually blended in an amount of about 1 to 30% by weight, preferably about 3 to 20% by weight, in the resulting fragrance product, and this blend provides the excellent effects desired by the present invention.
本発明芳香剤において香料成分としては、従来より芳香
剤として使用されている各種のものを1種単独で又は2
種以上調合して用いることができる。その具体例として
は例えば天然植物精油であるラベンダー、レモン油、ロ
ーズ油、スペアミント油、グリーン油等、動物性香料で
あるムスク、シペット等、合成香料であるアルデヒド類
、ケトン類、エステル類、之等の混合物等を例示できる
。As the fragrance component in the fragrance of the present invention, various types conventionally used as fragrances may be used singly or in combination.
It is possible to mix and use more than one species. Specific examples include natural plant essential oils such as lavender, lemon oil, rose oil, spearmint oil, and green oil; animal fragrances such as musk and cipette; and synthetic fragrances such as aldehydes, ketones, and esters. Examples include mixtures of the like.
上記香料の本発明芳香剤中への配合旦は、香料の種類や
香りの強度、得られる芳香剤の大きさ等に応じて若干異
なるが、例えば全量15(lの芳香剤の場合、通常該芳
香剤中に約5〜95i1jit%の範囲で含有される囲
とするのが好ましい。The amount of incorporation of the above fragrance into the fragrance of the present invention varies slightly depending on the type of fragrance, the strength of the fragrance, the size of the fragrance obtained, etc., but for example, in the case of a total amount of 15 (l) of fragrance, it is usually Preferably, it is contained in the fragrance in a range of about 5-95%.
本発明芳香剤は、上記ポリノルボルネンと香料とのみか
らなっていてもよいが、通常この種芳香剤に配合される
ことの知られている各種の添加剤、例えば芳香剤の有効
性の目安とする色素や上記ポリノルボルネン以外のゲル
化剤(同化剤)等を配合することができる。上記色素と
しては、水溶性の染料例えばメチレンブルー、シアニン
ブルー、青色1号、黄色4号、黄色5号、緑色3号、青
色202号、青色203号等を例示できる。その配合徂
は、用いる色素の種類(色調、濃度)に応じて適宜決定
でき、通常のこの種芳香剤におけるそれらと同様でよく
、一般には製品中に約10〜30重量%含まれるmとす
るのが適当である。また上記ゲル化剤としては、通常の
油ゲル化剤、例えばゴム等の高分子物質、カルナバワッ
クス、パラフィンろう等の親油性の樹脂、ワックス等、
蛋白質誘導体、ステアリン酸、パルミチン酸等の脂肪酸
のカルシウム、リチウム等の金属石鹸、12−ヒドロキ
システアリン酸、ジベンジリデンソルビトール、N−ア
シルアミノ酸のアミド、エステル、アミン塩等のアミノ
酸系油ゲル化剤等を例示できる。之等のうちでは、ベン
ジリデンソルビトール類(モノベンジリデンソルビトー
ル、ジベンジリデンソルビトール、トリベンジリデンソ
ルビトール及び之等の混合物)、12−とドロキシステ
アリン酸、及びラウロイルグルタミン酸ジブチルアミド
、ラウロイルグルタミン酸ジステアリルアミド、ラウロ
イルグルタミン酸ラウリルアミン塩、ラウロイルグルタ
ミン酸ジラウリルエステル、シカブリロイルリジンラウ
リルアミド、シカブリロイルリジンラウリルアミン塩、
シカブリロイルリジンラウリルエステル、ラウロイルバ
リンブチルアミド、ラウロイルフェニルアラニンラウリ
ルアミン塩、ラウロイルフェニルアラニンラウリルアミ
ド等のアシルアミノ酸誘導体が好ましい。上記12−ヒ
ドロキシステアリン酸は、製品中に約0.1〜8重口%
、ベンジリデンソルビトール類は、約0.1〜5重口%
、アシルアミン誘導体は、約0.1〜10重量%配合さ
れるのが望ましい。The fragrance of the present invention may consist only of the above-mentioned polynorbornene and fragrance, but various additives known to be usually added to this type of fragrance, such as a measure of the effectiveness of the fragrance, may be used. A gelling agent (assimilating agent) other than the above-mentioned polynorbornene and the like can be blended. Examples of the dye include water-soluble dyes such as methylene blue, cyanine blue, Blue No. 1, Yellow No. 4, Yellow No. 5, Green No. 3, Blue No. 202, and Blue No. 203. The blending range can be determined as appropriate depending on the type of pigment used (color tone, concentration), and may be the same as that in ordinary fragrances of this type, and is generally about 10 to 30% by weight of m contained in the product. is appropriate. The gelling agent may include ordinary oil gelling agents, such as polymeric substances such as rubber, lipophilic resins such as carnauba wax and paraffin wax, and wax.
Protein derivatives, metal soaps such as calcium and lithium fatty acids such as stearic acid and palmitic acid, amino acid oil gelling agents such as amide, ester, and amine salts of 12-hydroxystearic acid, dibenzylidene sorbitol, and N-acylamino acids, etc. can be exemplified. Among these, benzylidenesorbitols (monobenzylidenesorbitol, dibenzylidenesorbitol, tribenzylidenesorbitol and mixtures thereof), 12- and droxystearic acid, and lauroylglutamic acid dibutylamide, lauroylglutamic acid distearylamide, lauroylglutamic acid laurylamine salt, lauroylglutamic acid dilauryl ester, cicabriloyllisine laurylamide, cicabriloyllisine laurylamine salt,
Preferred are acyl amino acid derivatives such as cicabriloyl lisine lauryl ester, lauroyl valine butyramide, lauroyl phenylalanine lauryl amine salt, and lauroyl phenylalanine lauryl amide. The above 12-hydroxystearic acid is approximately 0.1 to 8% by weight in the product.
, benzylidene sorbitol, approximately 0.1 to 5% by weight
The acylamine derivative is preferably blended in an amount of about 0.1 to 10% by weight.
また、本発明芳香剤には、更に界面活性剤、石鹸、塩素
系洗浄剤等を配合して洗浄作用を兼備えさせることもで
きる。上記界面活性剤としては、広く公知の各種のもの
を使用でき、その代表例としては、例えばポリオキシエ
チレンラウリルエーテル、ポリオキシエチレンセチルエ
ーテル、ポリオキシエチレンオレイルエーテル、ポリオ
キシエチレンノニルフェノールエーテル、ポリオキシエ
チレンソルビタントリステアレート、ポリオキシエチレ
ンソルビタンモノステアレート、ポリエチレングリコー
ルモノステアレート、ポリエチレングリコールジステア
レート、ポリオキシエチレンジステアレート、オキシエ
チレンオキシブロビレンブロツクボリマー等を例示でき
る。之等は一種単独で又は二種以上混合して使用できる
。之等のうちでは特にポリオキシエチレンジステアレー
ト、ポリオキシエチレンノニルフェノールエーテル、ポ
リオキシエチレンラウリルエーテル等が好ましい。上記
界面活性剤は、製品中に約5〜70fffffi%の範
囲で配合することができる。また洗浄剤(漂白剤)とし
ては、例えば次亜塩素酸カルシウム、塩素化イソレアヌ
ル酸等を例示できる。2等界面活性剤、洗浄剤等の配合
により所望の芳香洗浄剤製品を得ることができる。Further, the fragrance of the present invention may be further blended with surfactants, soaps, chlorine-based detergents, etc. to have a cleaning action. As the above-mentioned surfactant, various widely known surfactants can be used, and typical examples include polyoxyethylene lauryl ether, polyoxyethylene cetyl ether, polyoxyethylene oleyl ether, polyoxyethylene nonylphenol ether, and polyoxyethylene lauryl ether, polyoxyethylene cetyl ether, polyoxyethylene Examples include ethylene sorbitan tristearate, polyoxyethylene sorbitan monostearate, polyethylene glycol monostearate, polyethylene glycol distearate, polyoxyethylene distearate, and oxyethylene oxybrobylene block polymer. These can be used singly or in a mixture of two or more. Among these, polyoxyethylene distearate, polyoxyethylene nonylphenol ether, polyoxyethylene lauryl ether, etc. are particularly preferred. The above-mentioned surfactant can be blended into the product in an amount of about 5 to 70fffffi%. Examples of the cleaning agent (bleaching agent) include calcium hypochlorite and chlorinated isoleanuric acid. By blending secondary surfactants, detergents, etc., desired aromatic detergent products can be obtained.
上記芳香洗浄剤には、更に必要に応じて、公知のpH調
節剤、緩衝剤、消毒剤、殺菌剤、脱塩素剤、漂白剤、フ
ロー防止剤等の添加剤を加えることもできる。The aromatic cleaning agent may further contain known additives such as pH regulators, buffers, disinfectants, sterilizers, dechlorinators, bleaches, anti-flow agents, and the like, if necessary.
本発明芳香剤は、単にポリノルボルネン、香料及び必要
に応じて各種の添加剤を常温で混合したのち、適宜の製
品形態にとするための型に入れて該型内で固化させるこ
とにより調製することができる。また洗浄剤を兼備えた
本発明の芳香剤、即ち芳香洗浄剤も各成分を混合後、混
合物を任意の形状の型に注入し冷却固化させることによ
り調製され、かくして固型の貯水式水洗トイレ用固形芳
香洗浄剤製品とされる。上記混合に当っては、各成分の
混合状態をより均一にするため若干の加温を行なうこと
もできる。また上記芳香洗浄剤製品の剤型は、その使用
形態に応じて適当に決定され、通常適当な大きさの容器
例えば皿状容器に収容した塊状固体形態とされ、他にペ
レット状、棒状、錠剤状等であってもよい。該製品は、
例えば適当な通水孔及び排水孔を有する装置に収容され
、貯水タンクの手洗部に設置して、実用できる。また該
製品は例えば不織布等の通水通気性シート等で包装して
上記手洗部等に設置されてもよい。上記芳香洗浄剤製品
の大きさも任意であり、その表面積(水との接触面積)
、使用期間等に応じて適当に決定され、通常製品159
で約1ケ月の使用が可能である。The fragrance of the present invention is prepared by simply mixing polynorbornene, fragrance, and various additives as necessary at room temperature, and then placing the mixture in a mold to form an appropriate product and solidifying the mixture in the mold. be able to. In addition, the aromatic agent of the present invention that also serves as a cleaning agent, that is, the aromatic cleaning agent, is prepared by mixing each component, pouring the mixture into a mold of any shape, cooling and solidifying it, and thus forming a solid water storage type flush toilet. It is considered to be a solid aromatic cleaning product. During the above-mentioned mixing, slight heating may be performed in order to make the mixed state of each component more uniform. The dosage form of the above-mentioned aromatic cleaning product is appropriately determined depending on its usage form, and is usually in the form of a solid block placed in an appropriate size container, such as a dish-shaped container, and may also be in the form of pellets, rods, or tablets. It may also be in the form of The product is
For example, it can be put into practical use by being housed in a device having suitable water holes and drainage holes and installed in a hand washing section of a water storage tank. Further, the product may be packaged with a water permeable breathable sheet such as a non-woven fabric and placed in the hand washing area or the like. The size of the above-mentioned aromatic cleaning products is also arbitrary, and its surface area (contact area with water)
, determined appropriately according to the period of use, etc., and the standard product 159
It can be used for about 1 month.
実 施 例
以下実施例を挙げ、本発明を更に詳細に説明する。尚、
各側においてポリノルボルネンとしては、フランスCd
Fケーミ社製「ノーソレツクス」(日本ゼオン社販売
)を、レモン香料としては、高砂香料社1urpH26
61Jを用いた。EXAMPLES The present invention will be explained in more detail with reference to Examples below. still,
As polynorbornene on each side, French Cd
F-Kemi's "No Sorex" (sold by Nippon Zeon) was used, and the lemon flavor was Takasago Fragrance Co., Ltd. 1urpH26.
61J was used.
実施例1
下記第1表に記載の配合割合でポリノルボルネン及びレ
モン香料(全ffi15g)を混合し、上面直径55n
+m、底面直径50mm、高さ13mmの皿型容器に分
注し、固化させて本発明の固形芳香剤を得た。Example 1 Polynorbornene and lemon flavor (total ffi 15g) were mixed in the proportions listed in Table 1 below, and the top surface diameter was 55n.
+m, a bottom diameter of 50 mm, and a height of 13 mm, and solidified to obtain a solid fragrance of the present invention.
第 1 表
芳香剤No、 ポリノルボルネン レモン香料本発明
1a 5重量部 95重良品本発明1b
10 〃 90 I/本発明IC20//
80 II本発明1d 30 〃 70
〃本発明1e 40 II 60
u本発明1f 50 〃 50 !!得られた
各芳香剤(本発明18〜1「)は、いずれも、優れた芳
香性、保形性及び安定性を有していた。特に2等各製品
を70℃下に2時間放置しても何ら製品形態の崩壊(型
崩れ)は認められなかった。Table 1 Fragrance No. Polynorbornene Lemon fragrance Invention 1a 5 parts by weight 95 weight Good product Invention 1b
10 〃 90 I/Invention IC20//
80 II Invention 1d 30 〃 70
〃Invention 1e 40 II 60
uThis invention 1f 50 〃 50! ! Each of the obtained fragrances (Inventions 18 to 1'') had excellent fragrance, shape retention, and stability.In particular, each of the second class products was left at 70°C for 2 hours. However, no collapse of the product form (loss of shape) was observed.
実施例2
実施例1においてレモン香料に代えて、キンモクセイ香
料(高砂香料社製rpH4171J)の各々同量を用い
て、同様にして本発明固形芳香剤N o、2 a〜2「
を得た。Example 2 In the same manner as in Example 1, the same amounts of osmanthus fragrance (rpH4171J, manufactured by Takasago Fragrance Co., Ltd.) were used in place of the lemon fragrance, and the solid fragrances No. 2 a to 2 of the present invention were prepared in the same manner.
I got it.
得られた各芳香剤は、いずれも実施例1で得られたそれ
らと同様の特性を有していた。Each of the obtained fragrances had properties similar to those obtained in Example 1.
実施例3
下記第2表に記載の配合割合でポリノルボルネン、レモ
ン香料、パラオキシエチレンジステアレート及び色素(
青色1号)を全量が15oとなるように混合し、上面直
径55mm、底面直径5Qmm。Example 3 Polynorbornene, lemon flavor, paraoxyethylene distearate, and pigment (
Blue No. 1) was mixed so that the total amount was 15o, and the top diameter was 55mm and the bottom diameter was 5Qmm.
高さ13mmの皿型容器に分注し、固化させて本発明の
固形芳香剤を得た。The mixture was dispensed into a dish-shaped container with a height of 13 mm and solidified to obtain a solid fragrance of the present invention.
得られた芳香剤は、芳香性に優れ、しかも常温で液体の
香料を多量に配合させた場合にも、この香料の高含有率
化に拘わらず、高温での安定性に優れており、香料の変
質等の認められないものであった。The obtained fragrance has excellent aromatic properties, and even when a large amount of liquid fragrance at room temperature is blended, it has excellent stability at high temperatures despite the high content of this fragrance. No deterioration in quality was observed.
第 2 表
実施例4
ポリノルボルネン 8市川部カラギーナン
2重量部ローカストビーンガム
2重量部レモン香料 80重缶
部KC(20,5ffiffi部
水 115.
5mm部合 計 2
00重は部上記成分組成となるように、まずカラギーナ
ン、ローカストビーンガム及び水を混合して加熱(75
℃)し、この混合物にレモン香料を添加、撹拌後、ポリ
ノルボルネン及びKCQを順次添加し、冷却固化させて
、本発明芳香剤を得た。Table 2 Example 4 Polynorbornene 8 Ichikawabe Carrageenan 2 parts by weight Locust bean gum
2 parts by weight Lemon fragrance 80 parts KC (20.5 parts water 115.
5mm section total 2
First, carrageenan, locust bean gum, and water were mixed and heated (75% by weight) so that the composition was as described above.
C), lemon flavor was added to this mixture, and after stirring, polynorbornene and KCQ were sequentially added and solidified by cooling to obtain a fragrance of the present invention.
かくして得られた本発明芳香剤(ヒドロゲルタイプ)は
、香料を多!1t(40重量%)に含有させることがで
き、この香料の高含有率化で高温で非常に安定で香料の
変質等は見られず、しかも組成物は適度の粘性を有し、
その製造作業性が良好なものであった。The fragrance of the present invention thus obtained (hydrogel type) contains a large amount of fragrance! 1 t (40% by weight), and with this high fragrance content, it is very stable at high temperatures and no deterioration of the fragrance is observed, and the composition has an appropriate viscosity.
The manufacturing workability was good.
(以 上) ゛・1.−ノ(that's all) ゛・1. -ノ
Claims (1)
形芳香剤。(1) A solid fragrance characterized by containing polynorbornene.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP61066987A JPS62224354A (en) | 1986-03-25 | 1986-03-25 | Solid aromatic agent |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP61066987A JPS62224354A (en) | 1986-03-25 | 1986-03-25 | Solid aromatic agent |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS62224354A true JPS62224354A (en) | 1987-10-02 |
JPH0580232B2 JPH0580232B2 (en) | 1993-11-08 |
Family
ID=13331875
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP61066987A Granted JPS62224354A (en) | 1986-03-25 | 1986-03-25 | Solid aromatic agent |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS62224354A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2014525818A (en) * | 2011-08-31 | 2014-10-02 | フイルメニツヒ ソシエテ アノニム | Carrageenan gel air freshener |
-
1986
- 1986-03-25 JP JP61066987A patent/JPS62224354A/en active Granted
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2014525818A (en) * | 2011-08-31 | 2014-10-02 | フイルメニツヒ ソシエテ アノニム | Carrageenan gel air freshener |
Also Published As
Publication number | Publication date |
---|---|
JPH0580232B2 (en) | 1993-11-08 |
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