JPS622159Y2 - - Google Patents
Info
- Publication number
- JPS622159Y2 JPS622159Y2 JP1982195721U JP19572182U JPS622159Y2 JP S622159 Y2 JPS622159 Y2 JP S622159Y2 JP 1982195721 U JP1982195721 U JP 1982195721U JP 19572182 U JP19572182 U JP 19572182U JP S622159 Y2 JPS622159 Y2 JP S622159Y2
- Authority
- JP
- Japan
- Prior art keywords
- oxide
- base
- alumina ceramic
- decorative structure
- flat
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 25
- 239000003086 colorant Substances 0.000 claims description 13
- 230000004907 flux Effects 0.000 claims description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical group O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 8
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 6
- 229910052751 metal Inorganic materials 0.000 claims description 5
- 239000002184 metal Substances 0.000 claims description 5
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 claims description 4
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 4
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Chemical compound [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 claims description 4
- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 claims description 4
- 239000000377 silicon dioxide Substances 0.000 claims description 4
- 229920003002 synthetic resin Polymers 0.000 claims description 4
- 239000000057 synthetic resin Substances 0.000 claims description 4
- 239000002023 wood Substances 0.000 claims description 4
- 239000005751 Copper oxide Substances 0.000 claims description 3
- 229910000431 copper oxide Inorganic materials 0.000 claims description 3
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 2
- 239000003245 coal Substances 0.000 claims description 2
- 229910000428 cobalt oxide Inorganic materials 0.000 claims description 2
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 claims description 2
- 239000010433 feldspar Substances 0.000 claims description 2
- 229910000480 nickel oxide Inorganic materials 0.000 claims description 2
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 claims description 2
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 claims description 2
- 229910001887 tin oxide Inorganic materials 0.000 claims description 2
- 239000011787 zinc oxide Substances 0.000 claims description 2
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 claims 1
- 229910000423 chromium oxide Inorganic materials 0.000 claims 1
- 239000000843 powder Substances 0.000 description 17
- 239000000919 ceramic Substances 0.000 description 11
- 238000010304 firing Methods 0.000 description 8
- 238000000034 method Methods 0.000 description 8
- 239000010437 gem Substances 0.000 description 6
- 229910001751 gemstone Inorganic materials 0.000 description 6
- 229910044991 metal oxide Inorganic materials 0.000 description 5
- 150000004706 metal oxides Chemical class 0.000 description 5
- 239000003973 paint Substances 0.000 description 5
- 239000002994 raw material Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 238000002844 melting Methods 0.000 description 3
- 230000008018 melting Effects 0.000 description 3
- 238000010422 painting Methods 0.000 description 3
- 239000002002 slurry Substances 0.000 description 3
- 239000000758 substrate Substances 0.000 description 3
- 239000000263 2,3-dihydroxypropyl (Z)-octadec-9-enoate Substances 0.000 description 2
- RZRNAYUHWVFMIP-GDCKJWNLSA-N 3-oleoyl-sn-glycerol Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@H](O)CO RZRNAYUHWVFMIP-GDCKJWNLSA-N 0.000 description 2
- 229910004298 SiO 2 Inorganic materials 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- RZRNAYUHWVFMIP-UHFFFAOYSA-N monoelaidin Natural products CCCCCCCCC=CCCCCCCCC(=O)OCC(O)CO RZRNAYUHWVFMIP-UHFFFAOYSA-N 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 235000017166 Bambusa arundinacea Nutrition 0.000 description 1
- 235000017491 Bambusa tulda Nutrition 0.000 description 1
- 241001330002 Bambuseae Species 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 235000015334 Phyllostachys viridis Nutrition 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 239000011425 bamboo Substances 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- GQVCNZBQZKXBMX-UHFFFAOYSA-N butan-2-one;toluene Chemical compound CCC(C)=O.CC1=CC=CC=C1 GQVCNZBQZKXBMX-UHFFFAOYSA-N 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- RCJVRSBWZCNNQT-UHFFFAOYSA-N dichloridooxygen Chemical compound ClOCl RCJVRSBWZCNNQT-UHFFFAOYSA-N 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 239000011120 plywood Substances 0.000 description 1
- 229920006267 polyester film Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
Landscapes
- Adornments (AREA)
Description
【考案の詳細な説明】
本考案は、カフス釦、ネクタイピン、ブロー
チ、ペンダント等の種々のアクセサリー等の用途
に基体と共に好適に使用できる装飾用構造体に関
し、更に詳しくは、例えば、金属、木材、合成樹
脂等の板状体等の基体上に、着色剤と融剤で絵付
して焼成した絵付層を有する、特定の厚さの平坦
なアルミナセラミツクス板を設けた装飾用構造体
に関するものである。[Detailed description of the invention] The present invention relates to a decorative structure that can be suitably used together with a base for various accessories such as cuff buttons, tie pins, brooches, and pendants. , relates to a decorative structure in which a flat alumina ceramic plate of a specific thickness is provided on a substrate such as a plate-shaped body made of synthetic resin, etc., and has a painted layer painted with a coloring agent and a flux and fired. be.
従来、例えば、カフス釦、ネクタイピン、ブロ
ーチ、ペンダント等のアクセサリーの装身具に、
天然の宝石や、人工のルビー、サフアイヤ等の模
造宝石等、或は陶磁器類などが多用されている。
これらの装身具中、例えば、天然宝石、模造宝石
等は種々の美しい立体観のある形状のものに、或
は平坦な板状等に加工研磨され、例えば、種々の
形状の金属体等の基体に、嵌着、締着、貼着、挾
着、挿着、添着、埋設、突設、敷設、吊設等さ
れ、装飾用構造体として用いられている。また、
比較的に安価な陶磁器類では、粘土を主とした組
成物を所望の形状に成形し、焼成した素地上に美
しい模様等の絵付を行い、天然宝石、模造宝石等
と同様にして金属体等の基体に該陶磁器類を設
け、種々の装飾構造体として用いられている。 Conventionally, for example, accessories such as cuff buttons, tie pins, brooches, pendants, etc.
Natural gemstones, imitation gemstones such as artificial rubies and saphires, and ceramics are often used.
Among these accessories, for example, natural gemstones, imitation gemstones, etc. are processed and polished into various beautiful three-dimensional shapes or into flat plate shapes, etc. It is used as a decorative structure by fitting, fastening, pasting, clamping, inserting, attaching, burying, protruding, laying, hanging, etc. Also,
Relatively inexpensive ceramics are made by molding a clay-based composition into a desired shape, painting beautiful patterns on the fired base, and creating metal objects in the same way as natural gemstones, imitation gemstones, etc. The ceramics are provided on a base and used as various decorative structures.
然し乍ら、陶磁器類では、美しい絵付を施した
肉薄でアクセサリーに適する平坦な陶磁器類を得
ることは極めて困難である。肉薄で平坦な素地に
美しい模様等の絵付を行い焼成する場合には、目
的とする模様が変化したり、また、素地に彎曲変
形等が生ずるので、例えば、平坦な金属体、木製
品等の基体と一体化させ、嵌着、貼着、挿着等を
行うには煩雑な細工等が免れなかつた。 However, when it comes to ceramics, it is extremely difficult to obtain thin, flat ceramics with beautiful paintings that are suitable for accessories. When painting a beautiful pattern on a thin, flat base and firing it, the intended pattern may change or the base may become curved or deformed. Complicated work was required to integrate, attach, attach, and insert the parts into one piece.
従来、陶磁器類では、基体とぴつたりしたもの
にするには、必然的に上記の理由で、肉厚のもの
か、或は、カマボコ状のもので、これを使用した
アクセサリーは極めて重量感があり体積が大き
く、装身具としての使用上の制限があつた。 Traditionally, in order to make ceramics that fit tightly to the base, for the reasons mentioned above, it was necessary to use thick or hollow-shaped pieces, and accessories using this were extremely heavy. Due to its large volume, there were restrictions on its use as an accessory.
本考案者らは、従来の比較的安価な陶磁器類で
達成されなかつた、所望の美しい模様付けがで
き、且つ、肉薄であり、基体に容易に嵌着、貼
着、挿着等を行い得る平坦性、軽量性をも有する
装身具を得るため種々工夫を重ねた結果、意外に
も機械的強度に優れた薄いアルミナセラミツクス
板を用いることで従来の陶磁器類で遭遇する諸問
題が一挙に解決し得ることを見出し、本考案を完
成するに至つたものである。 The inventors of the present invention have found that it is possible to create a desired beautiful pattern that could not be achieved with conventional relatively inexpensive ceramics, is thin, and can be easily fitted, pasted, inserted, etc. to a base. As a result of various efforts to obtain accessories that are both flat and lightweight, we were able to solve all the problems encountered with conventional ceramics at once by using thin alumina ceramic plates that have excellent mechanical strength. This led to the completion of the present invention.
本考案を図で具体的に示すと次の通りである。 The present invention is specifically illustrated in the following figure.
第１図は、厚さ0.2〜２mmの平坦なアルミナセ
ラミツクス板２に、着色剤と融剤で絵付して焼成
した絵付層１を有するものが、凹型の基体３に挿
着されているものであり、第２図は、厚さ0.2〜
２mmの平坦なアルミナセラミツクス板２に、着色
剤と融剤で絵付して焼成した絵付層１を有するも
のが、平坦な基体３に貼着されている装飾用構造
体である。 In Figure 1, a flat alumina ceramic plate 2 with a thickness of 0.2 to 2 mm has a painted layer 1 painted with a coloring agent and a flux and fired, which is inserted into a concave base 3. Yes, Figure 2 shows thickness 0.2~
A decorative structure is a 2 mm flat alumina ceramic plate 2 having a painted layer 1 painted with a coloring agent and a flux and fired, which is attached to a flat base 3.
本考案に用いる基体３としては、平坦なアルミ
ナセラミツクス板２を、固着、重着、嵌着、被
着、貼着、挾着、挿着、添着、周設、併設、埋
設、載設、並設、連設、突設、敷設、覆設等でき
るものであれば特に制限なく用いることができ、
例えば、該基体３の形状として、三角形、四辺
形、円、楕円、等目的に応じ種々のものを用いる
こともできる。該材質としても特に制限されるも
のではないが、強度、接着の容易性、軽量性の観
点等から、鉄、アルミ板銅板、錫、等の金属類；
木、ベニヤ板、合成木板、竹等の木質類；熱可塑
性、熱硬化性等の合成樹脂類が好適に用い得る。 As the substrate 3 used in the present invention, a flat alumina ceramic plate 2 can be fixed, overlapped, fitted, adhered, adhered, clamped, inserted, attached, peripherally mounted, attached, buried, placed, or parallel. As long as it can be installed, connected, protruded, laid, covered, etc., it can be used without any particular restrictions.
For example, the shape of the base 3 may be a triangle, a quadrilateral, a circle, an ellipse, etc. depending on the purpose. The material is not particularly limited, but from the viewpoint of strength, ease of adhesion, lightweight, etc., metals such as iron, aluminum plate, copper plate, tin, etc.;
Wood materials such as wood, plywood, synthetic wood boards, and bamboo; synthetic resins such as thermoplastic and thermosetting resins can be suitably used.
本考案で使用する厚さ0.2〜２mmの平坦なアル
ミナセラミツクス板２は、例えば、先づ、アルミ
ナ粉末に各種の金属酸化物粉末を添加して原料粉
末とし、この粉末に、例えば、ポリビニルアルコ
ール、ブチラール樹脂等のバインダー、ジブチル
フタレート等の可塑剤、グリセリールモノオレエ
ート等の分散剤、及びメチルエチルケトン、トル
エン等の溶剤等を加え、ボールミル等で混練し、
粉末含有量の多い泥漿を作り、これを平滑な、例
えば、ポリエステルフイルム等の支持体上に、所
謂、ドクターブレートを用いて平坦なシートに成
形するスリツプキヤスト法、あるいはアルミナ粉
末と金属酸化物の原料粉末を焼成過程で分解揮発
するバインダー等を添加しておいて、冷間プレス
によつて平坦なシートに成形するプレス法等の公
知の手段によつて成形したのち、乾燥し可撓性の
ある生シートとする。 The flat alumina ceramic plate 2 with a thickness of 0.2 to 2 mm used in the present invention is made by first adding various metal oxide powders to alumina powder to obtain a raw material powder, and then adding, for example, polyvinyl alcohol, Add a binder such as butyral resin, a plasticizer such as dibutyl phthalate, a dispersant such as glyceryl monooleate, and a solvent such as methyl ethyl ketone or toluene, and knead with a ball mill etc.
The slip cast method involves making a slurry with a high powder content and forming it into a flat sheet on a smooth support such as a polyester film using a so-called doctor blade, or the slip cast method in which a slurry with a high powder content is formed into a flat sheet using a so-called doctor blade, or a slurry made of alumina powder and metal oxide is used. A binder that decomposes and volatilizes during the firing process is added to the raw material powder, and after being formed by a known method such as a press method in which it is formed into a flat sheet by cold pressing, it is dried and made into a flexible sheet. Let's take a certain raw sheet.
次いで、例えば、該生シート中の有機成分を予
備焼成で除いたのち、空気または水素気流中で温
度1400〜1800℃で本焼成することによつて得たも
のを、所望の任意の大きさ、形状に切断、穿穴、
分割等の加工をすることによつて得ることができ
る。 Next, for example, after removing the organic components in the raw sheet by pre-firing, the raw sheet is subjected to main firing at a temperature of 1,400 to 1,800°C in an air or hydrogen stream, and the resulting sheet is shaped into any desired size. Cut to shape, drill holes,
It can be obtained by processing such as division.
しかし、該アルミナセラミツクス板２の大きさ
としては、カフス釦、ネクタイピン等への適用の
観点から、最大の径または辺の長さが15mm以下〜
３mm以上のものがよい。 However, from the viewpoint of application to cuff buttons, tie pins, etc., the size of the alumina ceramic plate 2 is such that the maximum diameter or side length is 15 mm or less.
3mm or more is better.
勿論、生シートから本考案に係る装飾用構造体
に適するように、所望の任意の形状に加工したも
のを、予備焼成、本焼成等の工程を経てアルミナ
セラミツクス板２とすることもできる。 Of course, the raw sheet can be processed into any desired shape suitable for the decorative structure according to the present invention, and the alumina ceramic board 2 can also be made through processes such as preliminary firing and main firing.
而して、アルミナセラミツク板２の機械的強度
等の点から、前記のアルミナ粉末を含む原料粉末
は、１μ以下の微粉末であり、且つ、該アルミナ
粉末に添加する金属酸化物粉末の量は20重量％以
下のものが好ましく、特に６〜２重量％の量がよ
い。このような金属酸化物粉末としては、例え
ば、SiO2，MgO，CaO，Ca2O3，MnO，Fe2O3，
NiO，CuO，TiO2等を挙げることができ、これ
らの１種または２種以上を用いることができる。 Therefore, from the viewpoint of the mechanical strength of the alumina ceramic plate 2, the raw material powder containing the alumina powder is a fine powder of 1μ or less, and the amount of metal oxide powder added to the alumina powder is An amount of 20% by weight or less is preferred, particularly an amount of 6 to 2% by weight. Examples of such metal oxide powder include SiO 2 , MgO, CaO, Ca 2 O 3 , MnO, Fe 2 O 3 ,
Examples include NiO, CuO, TiO2, etc., and one or more of these can be used.
尚、該板２のアクセサリー等としての機械的強
度および軽量性から厚さが0.2〜２mmで平坦であ
る必要がある。 Note that the plate 2 needs to have a thickness of 0.2 to 2 mm and be flat from the viewpoint of mechanical strength and lightness as an accessory.
かくして得られたアルミナセラミツクス板２
に、次いで着色剤と融剤で絵付を行い焼成し絵付
層１を設けるが、絵付層１はアルミナセラミツク
ス板２の片面に設けるのがよい。 Alumina ceramic plate 2 thus obtained
Next, the plate is decorated with a coloring agent and a flux and fired to form a decorated layer 1. It is preferable that the painted layer 1 is provided on one side of the alumina ceramic plate 2.
また、前記基体３にアルミナセラミツクス板２
を１個設けてもよいし、２個以上の複数個設けて
もよい。 Further, an alumina ceramic plate 2 is attached to the base 3.
One may be provided, or two or more may be provided.
更に、第１図に示す如く基体３が金属類であれ
ば、該基体３にアルミナセラミツクス板２を挿着
したのち、該アルミナセラミツクス板２に着色剤
と融剤で絵付を行い焼成し絵付層１を設けてもよ
い。 Furthermore, if the base 3 is metal as shown in FIG. 1, the alumina ceramic plate 2 is inserted into the base 3, and then the alumina ceramic plate 2 is painted with a coloring agent and a flux, and fired to form a painted layer. 1 may be provided.
本考案でいう「焼成」とは、所謂、ユウ焼、本
焼、上絵焼の１種以上を含む加熱融着操作をい
い、「絵付」とは、所謂、不絵付、（色ユウ、結晶
ユウ、キレツユウ等の）ユウガケ、上絵付の操作
をいい、「着色剤」とは、不絵付、ユウガケ、上
絵付に用いる顔料をいい、「融剤」とは、下絵
付、ユウガケ、上絵付の顔料等の組成物の融点よ
り低い温度で融解を促進する作用のあるものをい
う。 In the present invention, "firing" refers to a heating and fusing operation that includes one or more of so-called Yu-yaki, Hon-yaki, and Over-e-yaki. ``Coloring agent'' refers to the pigment used for underpainting, overpainting, overpainting, and ``fluxing agent'' refers to the operation of underpainting, overpainting, and overpainting. A substance that has the effect of promoting melting of a composition such as a pigment at a temperature lower than its melting point.
絵付層１の一成分である着色剤としては、特に
制限なく本考案に係る装飾用構造体の使用目的に
応じ、公知の着色剤の１種または２種以上を適宜
使用することができるが、アルミナセラミツク板
２との親和性等から、酸化銅、酸化鉄、酸化マン
ガン、酸化コバルト、酸化クロール、酸化ニツケ
ルの金属酸化物の微粉末が好適である。また、他
の一成分である融剤も、着色剤と同様に、特に制
限なく使用することができるが、硅石、長石、石
炭、炭酸ソーダ、酸化亜鉛、酸化錫、酸化バリユ
ーム、が好適である。 As the coloring agent which is a component of the painted layer 1, one or more known coloring agents can be used as appropriate depending on the purpose of use of the decorative structure according to the present invention without particular limitation. In view of their affinity with the alumina ceramic plate 2, fine powders of metal oxides such as copper oxide, iron oxide, manganese oxide, cobalt oxide, chloro oxide, and nickel oxide are suitable. Further, the fluxing agent, which is another component, can be used without any particular restrictions in the same way as the coloring agent, but silica, feldspar, coal, soda carbonate, zinc oxide, tin oxide, and barium oxide are preferred. .
アルミナセラミツクス板２に絵付層１を設ける
方法を例示すると次の通りである。 An example of a method for providing the painted layer 1 on the alumina ceramic board 2 is as follows.
所望する色彩を得る着色剤と融剤を擂かい機な
どに入れ、水を入れ、充分に磨潰し、乾燥して絵
具を作る。次いで、該絵具をガラス板上にとり、
過した「ふのり」と少量の水で充分すり合わせ
た後、セラミツクス板２に施し、該絵具を乾燥さ
せ、続いて電気窯などで700〜800℃で焼成し、絵
付層１を設ける。 To obtain the desired color, put the coloring agent and flux into a grinder, add water, grind thoroughly, and dry to make paint. Next, take the paint on a glass plate,
After sufficiently rubbing the "Funori" with a small amount of water, it is applied to a ceramic board 2, the paint is dried, and then fired at 700 to 800°C in an electric kiln to form a painted layer 1.
或は、繊細な模様や線で彩飾するには、セラミ
ツクス板２上に、予め「にかわ」、「ゼラチン」な
どを塗布し、この上にマンガン、コバルト、紅柄
などを水ですり合わせた液を使用して線描きし、
絵模様を描き、前記絵具を使用して彩色し、焼成
し、彩飾した絵付層１を設けることもできる。 Alternatively, to decorate with delicate patterns and lines, apply glue, gelatin, etc. on the ceramic board 2 in advance, and then rub a liquid of manganese, cobalt, red pattern, etc. with water on top of this. Draw a line using
It is also possible to provide a painted layer 1 in which a pattern is drawn, colored using the paint, fired, and decorated.
更には、金や銀の彩飾を施すこともできる。ま
た、所望するならば、絵付層２に、例えば透明な
合成樹脂等の被覆層等を設けることもできる。 Furthermore, it can also be decorated with gold or silver. Furthermore, if desired, the painted layer 2 can be provided with a covering layer of, for example, a transparent synthetic resin.
以下、実施例で本考案を更に詳細に説明する
が、本考案はこれに限定されるものではない。 Hereinafter, the present invention will be explained in more detail with reference to Examples, but the present invention is not limited thereto.
実施例 １
微粉末の、アルミナ96.5重量％、SiO21.5重量
％、MgO1.0重量％、CaO1.0重量％、を混合し原
料粉末とした。この原料粉末100重量部に対し、
ジブチルフタレート４重量部、グリセリールモノ
オレート0.6重量部、ポリビニルブチラール７重
量部、メチルエチルケトン−トルエン溶剤34重量
部、を配合しボールミルで混練し、スリツプキヤ
スト法で厚さ1.0mmの平坦な生シートを得た。こ
れを乾燥したのち、直径10mmφの円形の金型で打
抜いて得た形状のものを、予備焼成し、1600℃で
本焼成して、厚さ約1.0mm、直径約１cmφの平坦
なアルミナセラミツクス板２を得た。Example 1 Fine powders of 96.5% by weight of alumina, 1.5% by weight of SiO 2 , 1.0% by weight of MgO, and 1.0% by weight of CaO were mixed to prepare a raw material powder. For 100 parts by weight of this raw material powder,
4 parts by weight of dibutyl phthalate, 0.6 parts by weight of glyceryl monooleate, 7 parts by weight of polyvinyl butyral, and 34 parts by weight of methyl ethyl ketone-toluene solvent were mixed and kneaded in a ball mill, and a flat green sheet with a thickness of 1.0 mm was formed using the slip cast method. Obtained. After drying this, the obtained shape was punched out using a circular mold with a diameter of 10 mmφ, which was pre-fired and then main fired at 1600℃ to form a flat alumina ceramic with a thickness of about 1.0 mm and a diameter of about 1 cmφ. Board 2 was obtained.
この板２の両面上に、先づ、「にわか」1grと水
200c.c.を沸騰させ溶かした「にわか液」を塗り、
乾燥して「にわか」の薄い膜を設け、この上に酸
化銅と硅石及び酸化鉄と硅石から調合した絵具を
用い、夫々を「ふのり」と水で溶かし、筆で絵模
様を描き、乾燥したのち、電気窯で約800℃、５
時間焼成して青色、赤色の彩飾をした絵付層１を
設け、これを、直径2.5cmφ、厚さ２mmの凹部を
有する金属板の基体３に嵌込み、美術的で且つ軽
量性をも有する本考案の装飾用構造体を得た。 First, on both sides of this board 2, add 1g of "Niwaka" and water.
Apply "niwaka liquid" made by boiling and melting 200 c.c.
After drying, a thin film of ``Niwaka'' was formed, and on top of this, paints made from copper oxide and silica, and iron oxide and silica were dissolved in ``Funori'' and water, and patterns were drawn with a brush and dried. Later, in an electric kiln at about 800℃, 5
A painted layer 1 decorated with blue and red colors by time firing is provided, and this is fitted into a metal plate base 3 having a recess with a diameter of 2.5 cmφ and a thickness of 2 mm to create an artistic and lightweight book. A decorative structure of the invention was obtained.
以上のように、本考案の装飾用構造体は、着色
剤と融剤で絵付して焼成した絵付層１を有する、
厚さ0.2〜２mmの平坦なアルミナセラミツクス板
２を、基体３に設けたもので、従来の陶磁器類の
装身具では見られないユニークなもので、肉薄
で、且つ、平坦性、軽量性を有し、更に美術的彩
飾が容易である装飾用構造体で、カフス釦、ネク
タイピン、ブローチ、ペンダント等の装身具、お
よびその他の装飾用途に広く利用できる美術的価
値を有するものである。 As described above, the decorative structure of the present invention has a painted layer 1 painted with a coloring agent and a flux and fired.
A flat alumina ceramic plate 2 with a thickness of 0.2 to 2 mm is provided on the base 3. It is unique and not seen in conventional ceramic accessories, and is thin, flat, and lightweight. Furthermore, it is a decorative structure that can be easily decorated artistically, and has artistic value that can be widely used as accessories such as cuff buttons, tie clips, brooches, pendants, and other decorative uses.
第１図および第２図は本考案の装飾用構造体の
一実施態様の断面図を示すものである。
１……絵付層、２……アルミナセラミツクス
板、３……基体。
1 and 2 are cross-sectional views of one embodiment of the decorative structure of the present invention. 1...Painted layer, 2...Alumina ceramic board, 3...Substrate.
Claims (1)
有する、厚さ0.2〜２mmの平坦なアルミナセラ
ミツクス板２を、基体３に設けてなることを特
徴とする装飾用構造体。 (2) 該基体３が、金属類、木質類、合成樹脂類で
ある実用新案登録請求の範囲第１項記載の装飾
用構造体。 (3) 該着色剤が、酸化銅、酸化鉄、酸化マンガ
ン、酸化コバルト、酸化クローム、酸化ニツケ
ル、からなる群から選ばれた１種または２種以
上のものである実用新案登録請求の範囲第１項
記載の装飾用構造体。 (4) 該融剤が、硅石、長石、石炭、炭酸ソーダ、
酸化亜鉛、酸化錫、酸化バリユーム、からなる
群から選ばれた１種または２種以上のものであ
る実用新案登録請求の範囲第１項記載の装飾用
構造体。[Claims for Utility Model Registration] (1) A flat alumina ceramic plate 2 with a thickness of 0.2 to 2 mm is provided on a base 3, and has a painted layer 1 coated with a coloring agent and a flux and fired. Features decorative structures. (2) The decorative structure according to claim 1, wherein the base 3 is made of metal, wood, or synthetic resin. (3) Utility model registration claim No. 1 in which the coloring agent is one or more selected from the group consisting of copper oxide, iron oxide, manganese oxide, cobalt oxide, chromium oxide, and nickel oxide. The decorative structure according to item 1. (4) The flux is silica, feldspar, coal, soda carbonate,
The decorative structure according to claim 1, which is one or more selected from the group consisting of zinc oxide, tin oxide, and barium oxide.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP19572182U JPS59102397U (en) | 1982-12-27 | 1982-12-27 | decorative structures |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP19572182U JPS59102397U (en) | 1982-12-27 | 1982-12-27 | decorative structures |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS59102397U JPS59102397U (en) | 1984-07-10 |
| JPS622159Y2 true JPS622159Y2 (en) | 1987-01-19 |
Family
ID=30420223
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP19572182U Granted JPS59102397U (en) | 1982-12-27 | 1982-12-27 | decorative structures |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS59102397U (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4884671A (en) * | 1972-02-09 | 1973-11-10 | ||
| JPS5085479A (en) * | 1973-11-30 | 1975-07-10 | ||
| JPS5139253A (en) * | 1974-09-26 | 1976-04-01 | Hajime Tojo | |
| JPS53137216A (en) * | 1977-05-06 | 1978-11-30 | Ngk Spark Plug Co | Colored ceramics |
-
1982
- 1982-12-27 JP JP19572182U patent/JPS59102397U/en active Granted
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4884671A (en) * | 1972-02-09 | 1973-11-10 | ||
| JPS5085479A (en) * | 1973-11-30 | 1975-07-10 | ||
| JPS5139253A (en) * | 1974-09-26 | 1976-04-01 | Hajime Tojo | |
| JPS53137216A (en) * | 1977-05-06 | 1978-11-30 | Ngk Spark Plug Co | Colored ceramics |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS59102397U (en) | 1984-07-10 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN110627510A (en) | Ceramic tile with adjustable stereoscopic pattern and preparation method thereof | |
| JPS622159Y2 (en) | ||
| CN108189575A (en) | A kind of ceramic marble paper printing technology | |
| JPS622157Y2 (en) | ||
| JP2903547B2 (en) | Transfer sheet for ceramic painting | |
| JPS5820407A (en) | Manufacture of pottery | |
| KR20160054233A (en) | Manufacturing method for dotaechilgi with inlay | |
| JP3022452B2 (en) | Manufacturing method of ceramics | |
| CN213228163U (en) | Negative oxygen ion sandstone picture | |
| JPH01176530A (en) | Preparation of in-mold decorative molding | |
| KR910003179B1 (en) | Process for the preparation of mountings for pictures | |
| JP4297591B2 (en) | Method for decorating sintered body and sintered body | |
| CN1065625A (en) | Adhesive marquetry technique for ceramic | |
| JPS56135091A (en) | Heating transcribing paper | |
| JPS62182176A (en) | Manufacture of ceramic product with steric pattern | |
| JPH0473200A (en) | Structure having decorative ceramic and manufacture thereof | |
| CN100418794C (en) | Stamp-inlaid ceramic tray, box, or plate and its making method | |
| JPH0523597Y2 (en) | ||
| JPS5919054B2 (en) | Decoration method using glaze | |
| CN111907249A (en) | Negative oxygen ion sandstone picture and manufacturing method thereof | |
| KR100905751B1 (en) | Transfer paper, manufacturing method of transfer paper and coloring pattern formation method using transfer paper | |
| KR950013718B1 (en) | Objects of glass craft work | |
| CN2140843Y (en) | Ceramic pieces picture | |
| CN1070371A (en) | The preparation method of porcelain board shell carving picture | |
| JPH01192778A (en) | Engraving-resistant color for ceramics and method for forming ceramics using said color |