JPS62212302A - Resin molded article for repelling insect pest, having durability - Google Patents
Resin molded article for repelling insect pest, having durabilityInfo
- Publication number
- JPS62212302A JPS62212302A JP5489986A JP5489986A JPS62212302A JP S62212302 A JPS62212302 A JP S62212302A JP 5489986 A JP5489986 A JP 5489986A JP 5489986 A JP5489986 A JP 5489986A JP S62212302 A JPS62212302 A JP S62212302A
- Authority
- JP
- Japan
- Prior art keywords
- insecticide
- repellent
- molded article
- chlorine
- containing polymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 241000607479 Yersinia pestis Species 0.000 title claims abstract description 17
- 239000011347 resin Substances 0.000 title claims abstract description 17
- 229920005989 resin Polymers 0.000 title claims abstract description 17
- 241000238631 Hexapoda Species 0.000 title abstract description 6
- 230000001846 repelling effect Effects 0.000 title abstract 2
- 239000005871 repellent Substances 0.000 claims abstract description 44
- 230000002940 repellent Effects 0.000 claims abstract description 44
- 239000002917 insecticide Substances 0.000 claims abstract description 32
- 229920000642 polymer Polymers 0.000 claims abstract description 20
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims abstract description 19
- 239000000460 chlorine Substances 0.000 claims abstract description 19
- 229910052801 chlorine Inorganic materials 0.000 claims abstract description 19
- 239000011574 phosphorus Substances 0.000 claims abstract description 11
- 229910052698 phosphorus Inorganic materials 0.000 claims abstract description 11
- 239000000203 mixture Substances 0.000 claims abstract description 10
- 239000002728 pyrethroid Substances 0.000 claims abstract description 5
- 150000005690 diesters Chemical class 0.000 claims abstract description 3
- 238000013508 migration Methods 0.000 claims description 19
- 230000005012 migration Effects 0.000 claims description 19
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical group [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 10
- 150000002148 esters Chemical class 0.000 claims description 10
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 4
- 229920001296 polysiloxane Polymers 0.000 claims description 4
- 239000004593 Epoxy Substances 0.000 claims description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 3
- 150000001733 carboxylic acid esters Chemical class 0.000 claims description 3
- -1 polyvinyl chloride Chemical class 0.000 abstract description 10
- 150000002430 hydrocarbons Chemical group 0.000 abstract description 7
- 239000000463 material Substances 0.000 abstract description 6
- 241001674044 Blattodea Species 0.000 abstract description 4
- 125000002091 cationic group Chemical group 0.000 abstract description 4
- 150000001875 compounds Chemical class 0.000 abstract description 4
- 239000004215 Carbon black (E152) Substances 0.000 abstract description 2
- 239000002253 acid Substances 0.000 abstract description 2
- 229930195733 hydrocarbon Natural products 0.000 abstract description 2
- 229920000915 polyvinyl chloride Polymers 0.000 abstract description 2
- 239000004800 polyvinyl chloride Substances 0.000 abstract description 2
- 230000003405 preventing effect Effects 0.000 abstract 2
- 238000009435 building construction Methods 0.000 abstract 1
- 230000000694 effects Effects 0.000 description 14
- 239000000077 insect repellent Substances 0.000 description 12
- 239000003795 chemical substances by application Substances 0.000 description 7
- 238000000465 moulding Methods 0.000 description 7
- 125000004432 carbon atom Chemical group C* 0.000 description 6
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 5
- 235000014113 dietary fatty acids Nutrition 0.000 description 5
- KUMNEOGIHFCNQW-UHFFFAOYSA-N diphenyl phosphite Chemical compound C=1C=CC=CC=1OP([O-])OC1=CC=CC=C1 KUMNEOGIHFCNQW-UHFFFAOYSA-N 0.000 description 5
- 239000000194 fatty acid Substances 0.000 description 5
- 229930195729 fatty acid Natural products 0.000 description 5
- 239000012760 heat stabilizer Substances 0.000 description 5
- 229910019142 PO4 Inorganic materials 0.000 description 4
- YREQHYQNNWYQCJ-UHFFFAOYSA-N etofenprox Chemical compound C1=CC(OCC)=CC=C1C(C)(C)COCC1=CC=CC(OC=2C=CC=CC=2)=C1 YREQHYQNNWYQCJ-UHFFFAOYSA-N 0.000 description 4
- DNIAPMSPPWPWGF-UHFFFAOYSA-N monopropylene glycol Natural products CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 4
- 235000021317 phosphate Nutrition 0.000 description 4
- 238000006116 polymerization reaction Methods 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- 241001465754 Metazoa Species 0.000 description 3
- 238000013329 compounding Methods 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 3
- 239000010452 phosphate Substances 0.000 description 3
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- TXBCBTDQIULDIA-UHFFFAOYSA-N 2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)CO TXBCBTDQIULDIA-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 240000004460 Tanacetum coccineum Species 0.000 description 2
- ROVGZAWFACYCSP-MQBLHHJJSA-N [2-methyl-4-oxo-3-[(2z)-penta-2,4-dienyl]cyclopent-2-en-1-yl] (1r,3r)-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropane-1-carboxylate Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OC1C(C)=C(C\C=C/C=C)C(=O)C1 ROVGZAWFACYCSP-MQBLHHJJSA-N 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
- 239000004205 dimethyl polysiloxane Substances 0.000 description 2
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 2
- ASMQGLCHMVWBQR-UHFFFAOYSA-M diphenyl phosphate Chemical compound C=1C=CC=CC=1OP(=O)([O-])OC1=CC=CC=C1 ASMQGLCHMVWBQR-UHFFFAOYSA-M 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 230000000749 insecticidal effect Effects 0.000 description 2
- 238000004898 kneading Methods 0.000 description 2
- HQKMJHAJHXVSDF-UHFFFAOYSA-L magnesium stearate Chemical compound [Mg+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O HQKMJHAJHXVSDF-UHFFFAOYSA-L 0.000 description 2
- 238000005192 partition Methods 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 2
- HYJYGLGUBUDSLJ-UHFFFAOYSA-N pyrethrin Natural products CCC(=O)OC1CC(=C)C2CC3OC3(C)C2C2OC(=O)C(=C)C12 HYJYGLGUBUDSLJ-UHFFFAOYSA-N 0.000 description 2
- 229940015367 pyrethrum Drugs 0.000 description 2
- 239000003549 soybean oil Substances 0.000 description 2
- 235000012424 soybean oil Nutrition 0.000 description 2
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- HVLLSGMXQDNUAL-UHFFFAOYSA-N triphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)OC1=CC=CC=C1 HVLLSGMXQDNUAL-UHFFFAOYSA-N 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- PZGVVCOOWYSSGB-KWZUVTIDSA-L (z)-but-2-enedioate;dioctyltin(2+) Chemical compound [O-]C(=O)\C=C/C([O-])=O.CCCCCCCC[Sn+2]CCCCCCCC PZGVVCOOWYSSGB-KWZUVTIDSA-L 0.000 description 1
- QMMJWQMCMRUYTG-UHFFFAOYSA-N 1,2,4,5-tetrachloro-3-(trifluoromethyl)benzene Chemical compound FC(F)(F)C1=C(Cl)C(Cl)=CC(Cl)=C1Cl QMMJWQMCMRUYTG-UHFFFAOYSA-N 0.000 description 1
- 239000005711 Benzoic acid Substances 0.000 description 1
- LCFVJGUPQDGYKZ-UHFFFAOYSA-N Bisphenol A diglycidyl ether Chemical compound C=1C=C(OCC2OC2)C=CC=1C(C)(C)C(C=C1)=CC=C1OCC1CO1 LCFVJGUPQDGYKZ-UHFFFAOYSA-N 0.000 description 1
- 241000238660 Blattidae Species 0.000 description 1
- SUNPWPSLRLHVJP-UHFFFAOYSA-L C(C)(C)OP(=O)([O-])[O-].[Ca+2] Chemical compound C(C)(C)OP(=O)([O-])[O-].[Ca+2] SUNPWPSLRLHVJP-UHFFFAOYSA-L 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 239000004801 Chlorinated PVC Substances 0.000 description 1
- 239000004709 Chlorinated polyethylene Substances 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- FBPFZTCFMRRESA-KVTDHHQDSA-N D-Mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KVTDHHQDSA-N 0.000 description 1
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 1
- WHUUTDBJXJRKMK-UHFFFAOYSA-N Glutamic acid Natural products OC(=O)C(N)CCC(O)=O WHUUTDBJXJRKMK-UHFFFAOYSA-N 0.000 description 1
- WHUUTDBJXJRKMK-VKHMYHEASA-N L-glutamic acid Chemical compound OC(=O)[C@@H](N)CCC(O)=O WHUUTDBJXJRKMK-VKHMYHEASA-N 0.000 description 1
- 239000005639 Lauric acid Substances 0.000 description 1
- 229930195725 Mannitol Natural products 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 229920001214 Polysorbate 60 Polymers 0.000 description 1
- VQXSOUPNOZTNAI-UHFFFAOYSA-N Pyrethrin I Natural products CC(=CC1CC1C(=O)OC2CC(=O)C(=C2C)CC=C/C=C)C VQXSOUPNOZTNAI-UHFFFAOYSA-N 0.000 description 1
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- 229920002433 Vinyl chloride-vinyl acetate copolymer Polymers 0.000 description 1
- TVXBFESIOXBWNM-UHFFFAOYSA-N Xylitol Natural products OCCC(O)C(O)C(O)CCO TVXBFESIOXBWNM-UHFFFAOYSA-N 0.000 description 1
- VXSIXFKKSNGRRO-MXOVTSAMSA-N [(1s)-2-methyl-4-oxo-3-[(2z)-penta-2,4-dienyl]cyclopent-2-en-1-yl] (1r,3r)-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropane-1-carboxylate;[(1s)-2-methyl-4-oxo-3-[(2z)-penta-2,4-dienyl]cyclopent-2-en-1-yl] (1r,3r)-3-[(e)-3-methoxy-2-methyl-3-oxoprop-1-enyl Chemical class CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)O[C@@H]1C(C)=C(C\C=C/C=C)C(=O)C1.CC1(C)[C@H](/C=C(\C)C(=O)OC)[C@H]1C(=O)O[C@@H]1C(C)=C(C\C=C/C=C)C(=O)C1 VXSIXFKKSNGRRO-MXOVTSAMSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 229920006243 acrylic copolymer Polymers 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- WNLRTRBMVRJNCN-UHFFFAOYSA-L adipate(2-) Chemical compound [O-]C(=O)CCCCC([O-])=O WNLRTRBMVRJNCN-UHFFFAOYSA-L 0.000 description 1
- 125000002877 alkyl aryl group Chemical group 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 125000004103 aminoalkyl group Chemical group 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 125000003710 aryl alkyl group Chemical group 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 235000010233 benzoic acid Nutrition 0.000 description 1
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 1
- ZFMQKOWCDKKBIF-UHFFFAOYSA-N bis(3,5-difluorophenyl)phosphane Chemical compound FC1=CC(F)=CC(PC=2C=C(F)C=C(F)C=2)=C1 ZFMQKOWCDKKBIF-UHFFFAOYSA-N 0.000 description 1
- QNRMTGGDHLBXQZ-UHFFFAOYSA-N buta-1,2-diene Chemical compound CC=C=C QNRMTGGDHLBXQZ-UHFFFAOYSA-N 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 1
- 235000013539 calcium stearate Nutrition 0.000 description 1
- 239000008116 calcium stearate Substances 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 229920000457 chlorinated polyvinyl chloride Polymers 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 231100000517 death Toxicity 0.000 description 1
- 230000034994 death Effects 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- HTDKEJXHILZNPP-UHFFFAOYSA-N dioctyl hydrogen phosphate Chemical compound CCCCCCCCOP(O)(=O)OCCCCCCCC HTDKEJXHILZNPP-UHFFFAOYSA-N 0.000 description 1
- HGQSXVKHVMGQRG-UHFFFAOYSA-N dioctyltin Chemical compound CCCCCCCC[Sn]CCCCCCCC HGQSXVKHVMGQRG-UHFFFAOYSA-N 0.000 description 1
- OGVJEUDMQQIAPV-UHFFFAOYSA-N diphenyl tridecyl phosphite Chemical compound C=1C=CC=CC=1OP(OCCCCCCCCCCCCC)OC1=CC=CC=C1 OGVJEUDMQQIAPV-UHFFFAOYSA-N 0.000 description 1
- POULHZVOKOAJMA-UHFFFAOYSA-M dodecanoate Chemical compound CCCCCCCCCCCC([O-])=O POULHZVOKOAJMA-UHFFFAOYSA-M 0.000 description 1
- 230000001999 effect on insects Effects 0.000 description 1
- 230000000856 effect on pests Effects 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000004220 glutamic acid Substances 0.000 description 1
- 235000013922 glutamic acid Nutrition 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 230000009545 invasion Effects 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- QPPQHRDVPBTVEV-UHFFFAOYSA-N isopropyl dihydrogen phosphate Chemical compound CC(C)OP(O)(O)=O QPPQHRDVPBTVEV-UHFFFAOYSA-N 0.000 description 1
- 229940070765 laurate Drugs 0.000 description 1
- 231100000225 lethality Toxicity 0.000 description 1
- 239000000944 linseed oil Substances 0.000 description 1
- 235000021388 linseed oil Nutrition 0.000 description 1
- 230000005923 long-lasting effect Effects 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- 235000019359 magnesium stearate Nutrition 0.000 description 1
- 239000000594 mannitol Substances 0.000 description 1
- 235000010355 mannitol Nutrition 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- HEBKCHPVOIAQTA-UHFFFAOYSA-N meso ribitol Natural products OCC(O)C(O)C(O)CO HEBKCHPVOIAQTA-UHFFFAOYSA-N 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000004200 microcrystalline wax Substances 0.000 description 1
- 235000019808 microcrystalline wax Nutrition 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 125000005375 organosiloxane group Chemical group 0.000 description 1
- 210000001672 ovary Anatomy 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- MFPCPCHVMQLDJN-UHFFFAOYSA-N phenyl ditridecyl phosphite Chemical compound CCCCCCCCCCCCCOP(OCCCCCCCCCCCCC)OC1=CC=CC=C1 MFPCPCHVMQLDJN-UHFFFAOYSA-N 0.000 description 1
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 1
- 235000011007 phosphoric acid Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920000233 poly(alkylene oxides) Polymers 0.000 description 1
- 229920001084 poly(chloroprene) Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 150000007519 polyprotic acids Polymers 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 235000019260 propionic acid Nutrition 0.000 description 1
- VJFUPGQZSXIULQ-XIGJTORUSA-N pyrethrin II Chemical compound CC1(C)[C@H](/C=C(\C)C(=O)OC)[C@H]1C(=O)O[C@@H]1C(C)=C(C\C=C/C=C)C(=O)C1 VJFUPGQZSXIULQ-XIGJTORUSA-N 0.000 description 1
- 229940070846 pyrethrins Drugs 0.000 description 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
- 150000004671 saturated fatty acids Chemical class 0.000 description 1
- 235000003441 saturated fatty acids Nutrition 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical group [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 235000010356 sorbitol Nutrition 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 239000001384 succinic acid Substances 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 description 1
- MGMXGCZJYUCMGY-UHFFFAOYSA-N tris(4-nonylphenyl) phosphite Chemical compound C1=CC(CCCCCCCCC)=CC=C1OP(OC=1C=CC(CCCCCCCCC)=CC=1)OC1=CC=C(CCCCCCCCC)C=C1 MGMXGCZJYUCMGY-UHFFFAOYSA-N 0.000 description 1
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 239000000811 xylitol Substances 0.000 description 1
- HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 description 1
- 235000010447 xylitol Nutrition 0.000 description 1
- 229960002675 xylitol Drugs 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Description
【発明の詳細な説明】 （産業上の利用分野） 本発明は持続性に優れた害虫忌避樹脂成形体に関する。[Detailed description of the invention] (Industrial application field) TECHNICAL FIELD The present invention relates to a pest repellent resin molded article with excellent durability.
ぐ従来の技術）
従来、生活空間に害虫が侵入するのを防止するため、各
種防虫剤や害虫忌避剤が広く使用されている。このよう
な用途の一つに、樹脂中に防虫剤や忌避剤を混入し、シ
ート等に成形したものが知られており（特開昭６０−１
４６８０５号公報）。Conventional technology) Conventionally, various insect repellents and pest repellents have been widely used to prevent pests from entering living spaces. One of the known uses is to mix insect repellent or repellent into a resin and mold it into a sheet, etc. (Japanese Patent Laid-Open No. 60-1
46805).
この害虫忌避剤では混入された忌避剤が樹脂成形体表面
に移行することにより、害虫忌避効果が得られるもので
ある。In this pest repellent, the mixed repellent migrates to the surface of the resin molding, thereby obtaining the pest repellent effect.
（発明が解決しようとする問題点）
しかしながら、樹脂中に殺虫剤や４日避剤を配合し、成
形したシー１．Ｆの成形体においては、害虫に対する防
虫性能や忌避性能が未だ不満足であることがわかった。(Problems to be Solved by the Invention) However, the molded sheet 1. It was found that the molded product F was still unsatisfactory in its insect repellent and repellent performance against pests.
その理由は、一つには用いる薬品の耐熱性があり、樹脂
の溶融成形条件下で分解、揮散等が生じ易いこと、及び
二つには薬品の耐熱性をクリアーできたとしても、成形
体表面への薬効成分の移行が未だ不」−分であり、上の
な効力と持続性とが得られないことが考えられる。One of the reasons for this is that the chemicals used have heat resistance, which tends to cause decomposition and volatilization under the resin melt molding conditions, and second, even if the heat resistance of the chemicals can be met, the molded product It is thought that the transfer of the medicinal ingredients to the surface is still insufficient, and the higher efficacy and durability cannot be obtained.
従って本発明は害虫に対する防虫乃至忌避効果と該効果
の持続性とに優れた害虫忌避樹脂成形体を提供すること
を課題とする。Therefore, an object of the present invention is to provide an insect repellent resin molded article that has an excellent insect repellent or repellent effect on insect pests and the sustainability of the effect.
（問顯点を解決するための手段）
本発明においては、塩素含有重合体、害虫に対する殺虫
剤乃至忌避剤及びリンのオキシ酸エステルで代表される
移行促進剤を含有する組成物から成形体を製造すること
により、害虫に対する防虫乃至忌避効果とその効果の持
続性とが得られる。(Means for solving the problem) In the present invention, a molded article is produced from a composition containing a chlorine-containing polymer, an insecticide or repellent for pests, and a migration accelerator represented by a phosphorus oxyacid ester. By manufacturing it, an insect repellent or repellent effect against pests and a sustainability of the effect can be obtained.
（作 用）
本発明は、塩素含有重合体と移行促進剤との組合せが、
塩素含有重合体に配合された殺虫剤乃至忌避剤の成形品
表面への移行（ブリードアウト）を徐々にしかしながら
確実にしかも長期にわたって行ない、その結果として防
虫乃至忌避効果が確実に且つ長期にわたって奏されると
いう知見に基づくものである。(Function) The present invention provides that the combination of a chlorine-containing polymer and a migration accelerator
The insecticide or repellent blended into the chlorine-containing polymer gradually but reliably transfers (bleeds out) to the surface of the molded product over a long period of time, and as a result, the insect repellent or repellent effect is reliably and over a long period of time. This is based on the knowledge that
一般に移行（＋ｗｉｇｒａｔｉｏｎ）とは、ゴムや可塑
化プラスチックに配合された配合剤が、配合物内で高濃
度の側から低濃度の方（表面）へ移動する現象として知
られており、この移行現象の生成する程度はプラスチッ
クと配合剤との相溶性等の性質にも関連している０本発
明の塩素含有重合体において、安定した害虫に対する防
虫乃至忌避効果が生ずるのは、塩素含有重合体中に配合
された殺虫剤乃至忌避剤が成形体表面に有効に移行する
ことによるものであるが、これは移行促進剤が自ら殺虫
剤乃至忌避剤を伴なって表面に移行するか及び／又は移
行促進剤が殺虫剤乃至忌避剤の塩素含有重合体への相溶
の程度を減じる作用を行い、その結果として殺虫剤乃至
忌避剤の移行を促進するためと思われる。何れにせよ、
本発明では、害虫に対する殺虫剤乃至忌避剤の配合量に
比して著しく少ない移行促進剤の配合で、未配合のもの
に比して確実な防虫乃至忌避効果とこの効果の長期持続
性とが得られることは真に意外の知見であった。また、
本発明において、移行促進剤を配合したものでは、成形
直後からの初期防虫乃至忌避効果に優れていることは、
北記移行促進剤が、殺虫剤乃至忌避剤をも混練成形時に
加わる熱に対して安定化する作用を行っているものとも
推察される。Migration is generally known as a phenomenon in which compounding agents blended into rubber or plasticized plastic move from the higher concentration side to the lower concentration side (surface) within the compound. The extent to which this is formed is also related to properties such as the compatibility between the plastic and the compounding agent.In the chlorine-containing polymer of the present invention, stable insect repellent or repellent effects against pests occur because of the presence of the chlorine-containing polymer in the chlorine-containing polymer. This is due to the fact that the insecticide or repellent blended into the molded product effectively migrates to the surface of the molded product. This seems to be because the accelerator acts to reduce the degree of compatibility of the insecticide or repellent with the chlorine-containing polymer, and as a result promotes the migration of the insecticide or repellent. In any case,
In the present invention, the migration accelerator is blended in a significantly smaller amount than the amount of insecticide or repellent against pests, and the insect repellent or repellent effect is more reliable and the effect lasts longer than when it is not blended. What we obtained was truly surprising knowledge. Also,
In the present invention, the product containing the migration accelerator has an excellent initial insect repellent or repellent effect immediately after molding.
It is also inferred that the migration accelerator described above has the effect of stabilizing the insecticide or repellent against the heat applied during kneading and molding.
（発明の作用効果）
本発明によれば、塩素含有重合体に害虫に対する殺虫剤
乃至忌避剤とリンのオキシ酸エステル系移行促進剤とを
配合するという簡便な手段で、成形体表面に優れた防虫
乃至忌避効果と長期にわたる効果の持続性とを付芋する
ことができ、例えば台所用家具、建築用構造材、壁材或
いは窓枠部材、電子機奏用容器或いはド敷等として、ゴ
キブリその他の害虫の侵入を防止する用途に有効に利用
される。(Operations and Effects of the Invention) According to the present invention, by a simple means of blending a chlorine-containing polymer with an insecticide or repellent for harmful insects and a phosphorus oxyacid ester transfer accelerator, the surface of the molded product can be improved. It can be used as an insect repellent or repellent effect and has a long-term sustainability, for example, it can be used as kitchen furniture, architectural structural materials, wall materials or window frame members, electronic instrument containers or mats, etc. to prevent cockroaches and other insects. It is effectively used to prevent the invasion of pests.
（発明の実施態様の説明）
本発明において、移行促進剤としてはリンのオキシ酸エ
ステル系、シリコーン系、カルボン酸系、アルコール系
、カルボン酸エステル系、エポキシ系等の各種のものが
使用されるがこの内設も代表的なリンのオキシ酸エステ
ル系移行促進剤としてはホスファイト（亜リン酸エステ
ル）系又はホスフェート（リン酸エステル）系のものを
挙げることができる。ホスファイト系移行促進剤として
は、下記式
式中、Ｒは水素原子、カチオン性基、又は炭素数２０以
下の１価炭化水素１例えばアルキル基、アリール基、ア
ラールキル基又はアルカリール基であり、Ｒ１は炭素数
２０以下の１価炭化水素基である、
又は下記式
式中、Ｒ１及びＲ２はＬ述した意味を有し、Ｒ３は２価
炭化水素基である。(Description of Embodiments of the Invention) In the present invention, various types of migration accelerators are used, such as phosphorus oxyacid esters, silicone-based, carboxylic acid-based, alcohol-based, carboxylic ester-based, and epoxy-based ones. However, typical phosphorus oxyacid ester transfer accelerators include those based on phosphites or phosphates. As a phosphite-based migration promoter, in the following formula, R is a hydrogen atom, a cationic group, or a monovalent hydrocarbon having 20 or less carbon atoms, such as an alkyl group, an aryl group, an aralkyl group, or an alkaryl group, R1 is a monovalent hydrocarbon group having 20 or less carbon atoms, or in the following formula, R1 and R2 have the meanings described above, and R3 is a divalent hydrocarbon group.
で表わされる化合物；例えばトリフェニルホスファイト
、トリクレジルホスファイト、ジフェニルトリデシルホ
スファイト、フェニルジトリデシルホスファイト、トリ
ノニルフェニルホスファイト、ジフェニルホスファイト
、２．２−ビス（４−ジオクトキシホスフイノキシーフ
エニル）プロパン等を挙げることができる。また、ホス
フェート系移行促進剤としては下記式
式中、Ｒは水素原子、カチオン性基又は炭素数２０以下
の１価炭化水素基であり。Compounds represented by; for example, triphenyl phosphite, tricresyl phosphite, diphenyl tridecyl phosphite, phenyl ditridecyl phosphite, trinonylphenyl phosphite, diphenyl phosphite, 2,2-bis(4-dioctoxy) Examples include phosphinoxyphenyl)propane. Further, as a phosphate transfer promoter, in the following formula, R is a hydrogen atom, a cationic group, or a monovalent hydrocarbon group having 20 or less carbon atoms.
Ｒ１は炭素数２０以下の１価炭化水素基である、
で表わされるエステル類１例えばトリフェニルホスフェ
ート、トリクレジルホスフェート、ジフェニルホスフェ
ート、ジオクチルホスフェート、モノイソプロピルホス
フェート、モノイソプロピルホスフェートカルシウム等
を挙げることができる。R1 is a monovalent hydrocarbon group having 20 or less carbon atoms. Esters 1 represented by the following include, for example, triphenyl phosphate, tricresyl phosphate, diphenyl phosphate, dioctyl phosphate, monoisopropyl phosphate, calcium monoisopropyl phosphate, etc. can.
これらの内では、リンのオキシ酸のモノ又はジエステル
類、例えばジフェニルホスファイト、ジフェニルホスフ
ェート、モノインプロピルホスフェート、七ツインプロ
ピルホスフェートカルシウム等が本発明の目的に特に好
ましい。Among these, mono- or diesters of phosphorus oxyacids, such as diphenyl phosphite, diphenyl phosphate, mono-inpropyl phosphate, calcium heptad-twinpropyl phosphate, etc., are particularly preferred for the purposes of the present invention.
シリコーン系移行促進剤としては、オルガノシロキサン
類１例えばジメチルポリシロキサン、メチルフェニルポ
リシロキサン、メチル／＼イドロジエンポリシロキサン
、ジメチルポリシロ午サンーポリアルキレンオキシド共
重合体；或いはアルキルトリアルコキシシラン、アミノ
アルキルトリアルコキシシラン、ヒドロキシアルキルト
リアルコキシシラン、エポキシアルキルトリアルコキシ
シラン、これらのホモ或いはコ番オリゴマー等を挙げる
ことができる。Examples of the silicone migration accelerator include organosiloxanes such as dimethylpolysiloxane, methylphenylpolysiloxane, methyl/hydrodiene polysiloxane, dimethylpolysiloxane-polyalkylene oxide copolymer; or alkyltrialkoxysilane, aminoalkyl Examples include trialkoxysilane, hydroxyalkyltrialkoxysilane, epoxyalkyltrialkoxysilane, and homo or co-oligomers thereof.
カルボン酸系移行促進剤としては、炭素数２０以下の飽
和脂肪酸、不飽和脂肪酸或いは芳香族カルボン酸を挙げ
ることができ、これらは−塩基性の酸でも多塩基性の酸
でもよく１例として酢酸、プロピオン酸、ラウリン酸、
グルタミン酸、コＩ＼り酸、安息香酸、酒石酸等を挙げ
ることができアルコール系移行促進剤としては、炭素数
２０以下のアルコール類、特にポリオール類１例えばペ
ンタエリスリトール、マンニトール、キシリトール、ソ
ルビトール、グリセリン、ポリエチレングリコール、ジ
グリシジル、ジペンタエリスリトール等を挙げることが
できる。Examples of the carboxylic acid transfer accelerator include saturated fatty acids, unsaturated fatty acids, and aromatic carboxylic acids having 20 or less carbon atoms, and these may be basic acids or polybasic acids, such as acetic acid. , propionic acid, lauric acid,
Mention may be made of glutamic acid, phosphoric acid, benzoic acid, tartaric acid, etc. Alcohol transfer promoters include alcohols having 20 or less carbon atoms, particularly polyols 1 such as pentaerythritol, mannitol, xylitol, sorbitol, glycerin, Examples include polyethylene glycol, diglycidyl, dipentaerythritol, and the like.
カルボン酸エステル系移行促進剤としては、前述したカ
ルボン酸とアルコール類とのエステル類、例えばグリセ
リン脂肪酸エステル、プロピレングリコール脂肪酸エス
テル、ポリオキシエチレンソルビタン脂肪酸エステル、
ブチルステアレート等を挙げることができる。Examples of the carboxylic acid ester transfer accelerator include the aforementioned esters of carboxylic acid and alcohols, such as glycerin fatty acid ester, propylene glycol fatty acid ester, polyoxyethylene sorbitan fatty acid ester,
Butyl stearate and the like can be mentioned.
また、エポキシ系移行促進剤としては、エポキシ化大豆
油、エポキシ化アマニ油、エポキシ化ポリ−１，２−ブ
タジェン、ビスフェノールＡジグリシジルエーテル等を
挙げることができる。Examples of the epoxy migration accelerator include epoxidized soybean oil, epoxidized linseed oil, epoxidized poly-1,2-butadiene, and bisphenol A diglycidyl ether.
これらの移行促進剤は単独でも２挿具りの組合せでも勿
論使用することができる。Of course, these migration accelerators can be used alone or in combination.
殺虫剤乃至忌避剤としては、ゴキブリ等の害虫に対して
殺虫効果及び／又は忌避効果を有し、従来この種の用途
に使用されている殺虫剤乃至忌避剤を全て使用すること
ができる。好適な殺虫剤乃至忌避剤の例は、これに限定
されるものではないが、ピレスロイド系殺虫剤やピレト
リン系殺虫剤である。ピレトリン類は除虫菊花の子房に
含まれる殺虫成分であり、一方ピレスａイド系殺虫剤は
除虫菊成分をもとに合成された殺虫剤であり、これらは
人間や動物に対する毒性が極めて少なく。As the insecticide or repellent, any insecticide or repellent that has an insecticidal effect and/or a repellent effect on pests such as cockroaches and has been conventionally used for this type of application can be used. Examples of suitable insecticides or repellents include, but are not limited to, pyrethroid insecticides and pyrethrin insecticides. Pyrethrins are insecticidal components contained in the ovary of pyrethrum flowers, while pyreth-Aide insecticides are insecticides synthesized based on pyrethrum components, and these have extremely low toxicity to humans and animals.
皮膚への刺激も少なく、しかも効果に優れているという
特徴を有している。ピレスロイド系殺虫剤としては、エ
トフエンブロックス（化学名＝２−（４−エトキシフェ
ニル）−２−メチルプロピル３−フェノキシベンジルエ
ーテル−三井束Ｌ 化学■製）を好適に用いることがで
きる。It has the characteristics of being less irritating to the skin and being highly effective. As the pyrethroid insecticide, ethofenbrox (chemical name: 2-(4-ethoxyphenyl)-2-methylpropyl 3-phenoxybenzyl ether, manufactured by Mitsui Tsuka L Kagaku ■) can be suitably used.
塩素含有重合体としては、ポリ塩化ビニル、塩化ビニル
−酢酸ビニル共重合体、塩化ビニル−アクリル共重合体
、１１Ｘ化ビニル−ブタジェン共重合体、或いはこれら
のポリマーブレンドのような塩化ビニル樹脂；塩化ビニ
リレン樹脂：後塩素化ポリエチレン；塩素化ポリプロピ
レン；塩素化ポリ塩化ビニル；ポリクロロプレン或いは
これらの２種以上のブレンドを挙げることができる０本
発明はこれらの内でも、塩化ビニル樹脂、特に軟質塩化
ビニル樹脂に適用したときに著効が得られる。Examples of chlorine-containing polymers include vinyl chloride resins such as polyvinyl chloride, vinyl chloride-vinyl acetate copolymers, vinyl chloride-acrylic copolymers, 11X vinyl-butadiene copolymers, or blends of these polymers; Vinylylene resin: post-chlorinated polyethylene; chlorinated polypropylene; chlorinated polyvinyl chloride; polychloroprene or a blend of two or more of these; It is highly effective when applied to resins.
勿論、本発明に用いる塩素含有重合体には、それ自体公
知の配合剤を公知の処方に従って配合することができる
。このような配合剤の適当な例は、フタル酸ジオクチル
、アジピン酸ジオクチル、セパチン酸ジオクチル、ポリ
プロピレングリコールアジペート等の可塑剤；ステアリ
ン酸カルシウム、ステアリン酸マグネシウム、ステアリ
ン酸亜鉛、ジオクチル錫マレニートポリマー、ジオクチ
ル錫ラウレート等の熱安定剤；高級脂肪酸アマイド、ポ
リエチレンワックス、マイクロクリスタリンワックス等
の滑剤；炭酸カルシウム、水酸化アルミニウム、水酸化
マグネシウム、焼成りレイ等の充填剤−二酸化チタン、
カーボンブラック、ベンガラ、オーカー等の顔料；アニ
オン系。Of course, the chlorine-containing polymer used in the present invention can be blended with known compounding agents according to known formulations. Suitable examples of such additives include plasticizers such as dioctyl phthalate, dioctyl adipate, dioctyl sepatate, polypropylene glycol adipate; calcium stearate, magnesium stearate, zinc stearate, dioctyltin maleinate polymer, dioctyltin Heat stabilizers such as laurate; lubricants such as higher fatty acid amide, polyethylene wax, microcrystalline wax; fillers such as calcium carbonate, aluminum hydroxide, magnesium hydroxide, calcined lay - titanium dioxide,
Pigments such as carbon black, red iron, and ocher; anionic pigments.
カチオン系、ノニオン系或いは両性系の帯電防止剤等で
ある。These include cationic, nonionic, or amphoteric antistatic agents.
本発明において、塩素含有重合体を基帛にして、前記防
虫剤乃至忌避剤は０．０５乃至５重量％、特に０．５乃
至４型針％で用いるのが好ましく、一方リンのオキシ酸
エステル系移行促進剤は０．０５乃至３重量％、特に０
．１乃至１重量％の量で用いるのがよい。In the present invention, based on a chlorine-containing polymer, the insect repellent or repellent is preferably used in an amount of 0.05 to 5% by weight, particularly 0.5 to 4% by weight, while a phosphorus oxyacid ester The system transfer accelerator is 0.05 to 3% by weight, especially 0.
．． It is preferably used in an amount of 1 to 1% by weight.
塩素含有重合体への配合の順序には特に制限がなく、殺
虫剤乃至忌避剤とリンのオキシ酸エステル系移行促進剤
とを、他の配合成分と共に同時に配合してもよく、また
塩素含有重合体に他の配合成分を最後にブレンドし、最
後に殺虫剤乃至忌避剤とリンのオキシ酸エステル系移行
剤とを、この順序、逆の順序或いは同時にブレンドして
もよい。There is no particular restriction on the order in which they are added to the chlorine-containing polymer; the insecticide or repellent and the phosphorus oxyacid ester transfer accelerator may be added together with other ingredients, or the chlorine-containing polymer may be added to the chlorine-containing polymer at the same time. The other components may be blended together, and finally the insecticide or repellent and the phosphorus oxyacid ester transfer agent may be blended in this order, in the reverse order, or at the same time.
樹脂のブレンドは、所謂乾式ブレンドした後。The resin is blended after so-called dry blending.
成形機に供給することによって行ってもよいし。It may also be carried out by supplying it to a molding machine.
バンバリーミキサ−１−輌或いは二軸の押出機、ロール
等に供給して予め混練によるブレンドを行ってもよい、
樹脂の成形は、押出成形、カレンダーロールによるシー
ト成形、射出成形等により容易に行われ、シート、パネ
ル、ＰＬ枠、その他の構造材等が容易に得られる。Blending may be performed by kneading in advance by supplying the mixture to a Banbury mixer, a twin-screw extruder, rolls, etc.
Molding of the resin is easily performed by extrusion molding, sheet molding using calender rolls, injection molding, etc., and sheets, panels, PL frames, other structural materials, etc. can be easily obtained.
（実施例）
以下に示す実施例において効力の試験は次の通り行った
。(Example) In the examples shown below, efficacy tests were conducted as follows.
（１）強制接触試験方法
試験片（巾４０ｍｍＸ厚み１ ａｍ）を大きさ１００ｍ
５＋Ｘ１ｏｏａ■の台紙上に貼り合せ、チャバネゴキブ
リｌＯ頭（雄５匹、雌５匹）を入れた円筒状の容器（内
径８０諷腸×高さ１００鵬層）をかぶせ、ゴキブリを強
制的に試験片に接触せしめて、致死頭数を調べた。尚、
試験片は４０℃に放置し、６ケ月間致死頭数について調
べた。(1) Forced contact test method A test piece (width 40 mm x thickness 1 am) with a size of 100 m
The test piece was pasted onto a 5 + The number of fatalities was determined by contacting the animals. still,
The test piece was left at 40°C and the number of deaths was examined for 6 months.
（２）忌避試験方法
試験槽（縦１０１００Ｏｓ横１０００＋ｕ＋Ｘ高さ５０
０ ａｍ）の中央部に隔壁を設けて、Ａ室及びＢ室に二
分すると共に、該隔壁の中央部に巾１００１のＡ室及び
Ｂ室間の通路を設けた。一方の室Ａの丁端側部に巾４０
一層の試験片を貼り、Ａ室及びＢ室のほぼ中央にエサを
置くと共に、この中にワモンゴキブリｔｏＷ４を供試し
た。Ａ室の中にいるゴキブリの数を調べた。(2) Repellent test method Test tank (length 10100Os width 1000+u+X height 50
A partition wall was provided at the center of the room (0 am) to divide the room into chambers A and B, and a passage having a width of 1001 mm between the chambers A and B was provided at the center of the partition wall. A width of 40 mm is placed on the side of one of the chambers A.
A single layer of test pieces was pasted, food was placed approximately in the center of chambers A and B, and American cockroaches toW4 were placed therein. I checked the number of cockroaches in room A.
実施例 ｌ 下記処方の組成物を調製した。Example l A composition with the following formulation was prepared.
試料ｌ
塩化ビニル樹脂（重合度１３５０）１０００重量％ｇ／
Ｚｎ系熱安定剤 Ｂ ／／殺虫忌避剤
ＭＴＩ−５００・１ ３ ／／ジフェニルフォスファ
イト ° Ｑ、３ ｔｒ試′Ｊ４２
塩化ビニル樹脂（重合度１３５０）１００重量部Ｍｇ／
Ｚｎ系熱安定剤 １３ ／／殺虫忌
避剤 ＭＴＩ−５００３／１
試料３
塩化ビニル樹脂（重合度８２０）１００重量部熱安定剤
５ ／／殺虫忌避剤 ＭＴＩ
−５００３重量部
ジフェニルフォスファイト０．１ ／／試料４
塩化ビニル樹脂（重合度８２０）１００重量部熱安定剤
５ 〃殺虫忌避剤 ＭＴＩ−
５００３／／
殺虫忌避剤ＭＴＩ−５００は、２−（４−エトキシフェ
ニル）−２−メチルプロピル−３−フェノキシベンジル
エーテルで下記構造式
上記各試料を、試料ｌ及び２の場合は１５０℃、試料３
及び４の場合は１６０℃で押出成形し、巾４０ｍ腸、厚
み１厘膳のシートに成形した。Sample 1 Vinyl chloride resin (degree of polymerization 1350) 1000% by weight g/
Zn-based heat stabilizer B // Insecticide repellent MTI-500・1 3 // Diphenyl phosphite ° Q, 3 tr test 'J42 Vinyl chloride resin (degree of polymerization 1350) 100 parts by weight Mg/
Zn-based heat stabilizer 13 //Insecticide repellent MTI-5003/1 Sample 3 Vinyl chloride resin (degree of polymerization 820) 100 parts by weight Heat stabilizer 5 //Insecticide repellent MTI
-5003 parts by weight diphenyl phosphite 0.1 // Sample 4 Vinyl chloride resin (degree of polymerization 820) 100 parts by weight Heat stabilizer 5 Insecticide repellent MTI-
5003// Insecticide repellent MTI-500 is 2-(4-ethoxyphenyl)-2-methylpropyl-3-phenoxybenzyl ether with the following structural formula. 3
In the case of No. 4 and 4, extrusion molding was performed at 160° C. to form a sheet with a width of 40 m and a thickness of 1 liter.
この各シートを用いて前述した効力試験を行った。The efficacy test described above was conducted using each of these sheets.
強制接触試験の結果を下記表１に示す８表１の試験は４
０℃の温度下での促進試験により行われており、値は試
験開始２４時間後の致死頭数を示している。The results of the forced contact test are shown in Table 1 below.8 The test in Table 1 is 4.
This is an accelerated test conducted at a temperature of 0°C, and the values indicate the number of dead animals 24 hours after the start of the test.
表 １
上記第１表の結果は、フォスファイト系移行促進剤を併
用することにより、著しい致死性と効果の持続性とが得
られることがわかる。Table 1 The results shown in Table 1 above indicate that significant lethality and long-lasting effects can be obtained by using a phosphite-based migration promoter in combination.
次に忌避試験の結果をド記表２に示す。Next, the results of the repellent test are shown in Table 2.
表 ２
上記表２の結果は、殺虫忌避剤と共にボスファイト移行
剤を併用することにより、顕著な忌避効果が得られるこ
と及び移行剤の作用により試験片表面に薬剤が徐々にブ
リードし、！ｉ期にわたって安定した忌避効果が得られ
ることがわかる。Table 2 The results in Table 2 above show that by using a bosphite transfer agent together with an insecticide repellent, a remarkable repellent effect can be obtained, and that the agent gradually bleeds onto the surface of the test piece due to the action of the transfer agent. It can be seen that a stable repellent effect can be obtained over the i period.
実施例 ２
実施例１の試料１の処方において、ジフェニルフォスフ
ァイトの代りに下記の移行促進剤を用いる以外は実施例
１と同様にして成形シートを製造した。Example 2 A molded sheet was produced in the same manner as in Example 1 except that the following migration accelerator was used in place of diphenylphosphite in the formulation of Sample 1 of Example 1.
試料５ ジメチルポリシロキサン油
試料６ コハク酸
試料７ ジペンタエリスリトール
試料８ プロピレングリコール
脂肪酸エステル
試料９ エポキシ化大豆油
これらの各試料について１強制接触試験及び忌避試験を
行い、得られた結果を次に表３に示す。Sample 5 Dimethylpolysiloxane oil sample 6 Succinic acid sample 7 Dipentaerythritol sample 8 Propylene glycol fatty acid ester sample 9 Epoxidized soybean oil A forced contact test and a repellency test were conducted on each of these samples, and the results are shown below. Shown in 3.
Claims (5)
及び移行促進剤を含有する組成物から成ることを特徴と
する持続性を有する害虫忌避樹脂成形体。(1) A durable pest repellent resin molded article comprising a composition containing a chlorine-containing polymer, an insecticide or repellent for pests, and a migration accelerator.
乃至５重量％及び移行促進剤が０．０５乃至３重量％の
量で存在する特許請求の範囲第１項記載の成形体。(2) 0.05 insecticide or repellent per chlorine-containing polymer
Molded article according to claim 1, wherein the molded article is present in an amount of from 0.05 to 3% by weight and the migration promoter is present in an amount of from 0.05 to 3% by weight.
ーン系、カルボン酸系、アルコール系、カルボン酸エス
テル系或いはエポキシ系の移行促進剤である特許請求の
範囲第１項記載の成形体。(3) The molded article according to claim 1, wherein the migration promoter is a phosphorus oxyacid ester, silicone, carboxylic acid, alcohol, carboxylic ester, or epoxy migration promoter.
ルである特許請求の範囲第１項記載の成形体。(4) The molded article according to claim 1, wherein the migration accelerator is a mono- or diester of phosphorus oxyacid.
特許請求の範囲第１項記載の成形体。(5) The molded article according to claim 1, wherein the insecticide or repellent is a pyrethroid insecticide.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP5489986A JPS62212302A (en) | 1986-03-14 | 1986-03-14 | Resin molded article for repelling insect pest, having durability |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP5489986A JPS62212302A (en) | 1986-03-14 | 1986-03-14 | Resin molded article for repelling insect pest, having durability |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS62212302A true JPS62212302A (en) | 1987-09-18 |
| JPH0255402B2 JPH0255402B2 (en) | 1990-11-27 |
Family
ID=12983447
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP5489986A Granted JPS62212302A (en) | 1986-03-14 | 1986-03-14 | Resin molded article for repelling insect pest, having durability |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS62212302A (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4997650A (en) * | 1986-08-08 | 1991-03-05 | Mitsui Toatsu Chemicals, Inc. | Insecticidal resin coating film |
| WO1998053683A1 (en) * | 1997-05-27 | 1998-12-03 | Karl Engelhard Fabrik Pharm. Präparate Gmbh & Co. Kg | Insect repellent |
| JP2005139329A (en) * | 2003-11-07 | 2005-06-02 | Sumika Color Kk | Olefinic resin pellet in double layered structure for insect-proof resin composition |
| JP2006036759A (en) * | 2004-06-24 | 2006-02-09 | S T Chem Co Ltd | Insect repellent and insect-repelling device and method using the same |
| JP2010013761A (en) * | 2008-07-03 | 2010-01-21 | Sumitomo Chemical Co Ltd | Insecticidal filament |
| JP2011126826A (en) * | 2009-12-18 | 2011-06-30 | Sumitomo Chemical Co Ltd | Molded product made of polymer composition |
| JP2020109070A (en) * | 2018-12-28 | 2020-07-16 | 広島化成株式会社 | Partitioning sheet |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS58172302A (en) * | 1982-03-25 | 1983-10-11 | シエル・インタ−ナシヨネイル・リサ−チ・マ−チヤツピイ・ベ−・ウイ | Slow-release agricultural drug composition, manufacture and use |
-
1986
- 1986-03-14 JP JP5489986A patent/JPS62212302A/en active Granted
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS58172302A (en) * | 1982-03-25 | 1983-10-11 | シエル・インタ−ナシヨネイル・リサ−チ・マ−チヤツピイ・ベ−・ウイ | Slow-release agricultural drug composition, manufacture and use |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4997650A (en) * | 1986-08-08 | 1991-03-05 | Mitsui Toatsu Chemicals, Inc. | Insecticidal resin coating film |
| WO1998053683A1 (en) * | 1997-05-27 | 1998-12-03 | Karl Engelhard Fabrik Pharm. Präparate Gmbh & Co. Kg | Insect repellent |
| JP2005139329A (en) * | 2003-11-07 | 2005-06-02 | Sumika Color Kk | Olefinic resin pellet in double layered structure for insect-proof resin composition |
| JP4649104B2 (en) * | 2003-11-07 | 2011-03-09 | 住化カラー株式会社 | Two-layer olefin resin pellets for insect repellent resin composition |
| JP2006036759A (en) * | 2004-06-24 | 2006-02-09 | S T Chem Co Ltd | Insect repellent and insect-repelling device and method using the same |
| JP2010013761A (en) * | 2008-07-03 | 2010-01-21 | Sumitomo Chemical Co Ltd | Insecticidal filament |
| JP2011126826A (en) * | 2009-12-18 | 2011-06-30 | Sumitomo Chemical Co Ltd | Molded product made of polymer composition |
| JP2020109070A (en) * | 2018-12-28 | 2020-07-16 | 広島化成株式会社 | Partitioning sheet |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0255402B2 (en) | 1990-11-27 |
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