JPS62196134A - Composite material - Google Patents
Composite materialInfo
- Publication number
- JPS62196134A JPS62196134A JP3801486A JP3801486A JPS62196134A JP S62196134 A JPS62196134 A JP S62196134A JP 3801486 A JP3801486 A JP 3801486A JP 3801486 A JP3801486 A JP 3801486A JP S62196134 A JPS62196134 A JP S62196134A
- Authority
- JP
- Japan
- Prior art keywords
- fibers
- fiber
- composite material
- present
- synthetic resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000002131 composite material Substances 0.000 title claims description 25
- 239000000835 fiber Substances 0.000 claims description 62
- 229920003002 synthetic resin Polymers 0.000 claims description 14
- 239000000057 synthetic resin Substances 0.000 claims description 14
- 229920002994 synthetic fiber Polymers 0.000 claims description 2
- 239000012209 synthetic fiber Substances 0.000 claims description 2
- 230000000694 effects Effects 0.000 description 4
- -1 polyethylene Polymers 0.000 description 4
- 239000003365 glass fiber Substances 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 229920000049 Carbon (fiber) Polymers 0.000 description 2
- 239000004641 Diallyl-phthalate Substances 0.000 description 2
- 239000004952 Polyamide Substances 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 description 2
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 description 2
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 2
- 229920006231 aramid fiber Polymers 0.000 description 2
- 238000005452 bending Methods 0.000 description 2
- QUDWYFHPNIMBFC-UHFFFAOYSA-N bis(prop-2-enyl) benzene-1,2-dicarboxylate Chemical compound C=CCOC(=O)C1=CC=CC=C1C(=O)OCC=C QUDWYFHPNIMBFC-UHFFFAOYSA-N 0.000 description 2
- 239000004917 carbon fiber Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 230000000877 morphologic effect Effects 0.000 description 2
- 229920002647 polyamide Polymers 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 1
- 101100137177 Drosophila melanogaster polyph gene Proteins 0.000 description 1
- 229920002430 Fibre-reinforced plastic Polymers 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- 239000002033 PVDF binder Substances 0.000 description 1
- 239000004696 Poly ether ether ketone Substances 0.000 description 1
- 239000004962 Polyamide-imide Substances 0.000 description 1
- 239000004695 Polyether sulfone Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004642 Polyimide Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- 229920001807 Urea-formaldehyde Polymers 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 239000004760 aramid Substances 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 239000011151 fibre-reinforced plastic Substances 0.000 description 1
- 238000009730 filament winding Methods 0.000 description 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 229920002312 polyamide-imide Polymers 0.000 description 1
- 229920001707 polybutylene terephthalate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920006393 polyether sulfone Polymers 0.000 description 1
- 229920002530 polyetherether ketone Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- LLZRNZOLAXHGLL-UHFFFAOYSA-J titanic acid Chemical compound O[Ti](O)(O)O LLZRNZOLAXHGLL-UHFFFAOYSA-J 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 229920006305 unsaturated polyester Polymers 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
Landscapes
- Laminated Bodies (AREA)
Abstract
(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は合成樹脂と繊維とを主体とする複合材料ｔこ関
するものである。DETAILED DESCRIPTION OF THE INVENTION [Field of Industrial Application] The present invention relates to a composite material mainly composed of synthetic resin and fiber.
従来からガラス繊維、炭素繊維等の繊維と不飽和ボリエ
ヌテル、ヌチロール、ジアリルフタレート等の合成樹脂
原料とを混合し、該合成樹脂原料を硬化せしめた複合材
料、即ち繊維強化プラスチック（ＦＴＬＰ、ＦＲＴＰ）
あるいは繊維強化ゴム（ＦＲ几）が提供されている。Conventionally, composite materials such as fiber-reinforced plastics (FTLP, FRTP) are produced by mixing fibers such as glass fibers and carbon fibers with synthetic resin raw materials such as unsaturated Borienether, Nutylol, and diallyl phthalate, and curing the synthetic resin raw materials.
Alternatively, fiber reinforced rubber (FR) is provided.
該複合材料において繊維は、直線形状２編織布形状、フ
ィラメントワインディング法によるヘリカル形状、また
は渦巻状マ、）の形態で用いられており、該繊維はその
強度によって合成樹脂を強化している。In this composite material, the fibers are used in the form of a linear two-knit woven fabric, a helical shape by a filament winding method, or a spiral shape, and the fibers reinforce the synthetic resin with their strength.
しかしながら一般に高剛性・高強度繊維は伸び率が低い
ため、従来の複合材料は引張りに対する靭性および＃撃
強度が充分でないと言う欠点を有するものである。これ
は、繊維を直線形状で用いた場合、繊維自体の伸び率に
よって複合材料の伸びが規定され、また繊維を璃織布形
状、ヘリカル形状または渦巻状形態で用いた場合でも、
異なる方向に配列した隣接繊維によって該繊維の伸びが
抑制されるためである。However, since high-rigidity/high-strength fibers generally have a low elongation rate, conventional composite materials have the drawback of insufficient tensile toughness and impact strength. This means that when fibers are used in a straight shape, the elongation of the composite material is determined by the elongation rate of the fibers themselves, and even when fibers are used in a woven, helical, or spiral shape,
This is because the elongation of the fibers is suppressed by adjacent fibers arranged in different directions.
本発明は上記従来の問題点を解決する手段として、合成
樹脂内の繊維を波形状とし、かつ各繊維の波形状の波長
の方向を整合せしめるものである。The present invention solves the above-mentioned conventional problems by making the fibers in the synthetic resin wavy and matching the wavelength directions of the wavy shapes of each fiber.
本発明を以下に詳細に説明すれば、本発明に用いられる
合成樹脂原料としては従来の繊維複合材料に通常用いら
れている不飽和ポリエステル、スチロール、ジアリルフ
タレート、フェノ−／’ｍｌ 脂。The present invention will be described in detail below. The synthetic resin raw materials used in the present invention include unsaturated polyester, styrene, diallyl phthalate, and phenol resin, which are commonly used in conventional fiber composite materials.
エポキシ樹脂等の他メラミン樹脂、尿素樹脂、ウレタン
樹脂、ポリイミド等の熱軟化性合成樹脂やポリ塩化ビニ
ル、ポリエチレン、ポリプロピレン。In addition to epoxy resins, heat-softening synthetic resins such as melamine resins, urea resins, urethane resins, and polyimides, as well as polyvinyl chloride, polyethylene, and polypropylene.
ポリ弗化エチレン、ポリ弗化ビニリデン、ポリアミド、
ポリカーボネート、ポリブチレンテレフタレート、ポリ
フ、ニセンサルファイド、ポリエーテルスルホン、ポリ
エーテルエーテルケトン、ポリアミドイミド等の熱可塑
性合成樹脂全般を対象とするものである。Polyfluoroethylene, polyvinylidene fluoride, polyamide,
It targets thermoplastic synthetic resins in general, such as polycarbonate, polybutylene terephthalate, polyph, Nicene sulfide, polyether sulfone, polyether ether ketone, and polyamideimide.
上記例示は本発明を限定するものではない。The above examples are not intended to limit the invention.
本発明に用いられる繊維としては従来の繊維複合材料に
通常用いられる繊維を対象とし、これを例示すればガラ
ス繊維、炭素繊維、ポロン繊維。The fibers used in the present invention include fibers commonly used in conventional fiber composite materials, such as glass fibers, carbon fibers, and poron fibers.
アルミナ繊維、チタン酸、カリウム繊維、ンリカ繊維、
タングステン繊維、ステンレス繊維、セラミック繊維、
金属繊維、アラミド繊維、ポリアミド繊維、ポリエステ
ル繊維、木綿等の無機金属あるいは有機質繊維である。Alumina fiber, titanic acid, potassium fiber, linica fiber,
tungsten fiber, stainless steel fiber, ceramic fiber,
These are inorganic metal or organic fibers such as metal fibers, aramid fibers, polyamide fibers, polyester fibers, and cotton.
上記例示は本発明を限定するものではない。The above examples are not intended to limit the invention.
本発明においては上記合成樹脂内において上記繊維は波
形状をなしかつ各繊維について該波形状の波長の方向が
整合せしめられる。即ち第１図に示すように各繊維（１
）は合成樹脂相（２）内において同一形状、即ち同一の
波長と波高を有するサインカーブを画き、かつ各繊維（
１）のサインカーブ間の位相差は０である。In the present invention, the fibers in the synthetic resin have a wave shape, and the wavelength directions of the wave shapes are matched for each fiber. That is, as shown in Figure 1, each fiber (1
) has the same shape in the synthetic resin phase (2), that is, a sine curve with the same wavelength and wave height, and each fiber (
The phase difference between the sine curves in 1) is 0.
第３図では各１＆維は合成樹脂内において同一形状を有
するサインカーブを画き、かつ各繊維のサインカーブ間
の位相差はランダムである。さらに第１図、第３図は本
発明を限定するものではなく本発明の複合材料では各繊
維の波長と波高および各繊維間の位相差は任意であり、
波長、波高９位相差の異った繊維の組合せた複合材料も
本発明に含まれる。又、本発明においては波形状連続繊
維の波長の方向が整合していれば波形状連続繊維の波高
方向が異っていても同様の作用効果が得られる。In FIG. 3, each fiber draws a sine curve having the same shape in the synthetic resin, and the phase difference between the sine curves of each fiber is random. Furthermore, FIGS. 1 and 3 do not limit the present invention, and in the composite material of the present invention, the wavelength and wave height of each fiber and the phase difference between each fiber are arbitrary.
The present invention also includes a composite material in which fibers having different wavelengths, wave heights, and phase differences are combined. Further, in the present invention, as long as the wavelength directions of the wavy continuous fibers are matched, the same effect can be obtained even if the wave height directions of the wavy continuous fibers are different.
本発明に言う繊維（１）とは単繊維は勿論のこと該単繊
維を数本から数百本懲り合せたストランド、更に該スト
ランドを数本〜数十本集束したロービング等を包含する
ものである。The fiber (1) referred to in the present invention includes not only single fibers but also strands made of several to several hundred such single fibers, and rovings made of several to several tens of such strands. be.
本発明の複合材料を繊維の波形の波長の方向（第１図工
方向）に沿った方向において引張ると合成樹脂相自体は
伸び変形を生ずるか繊維は波形が伸び形態的に変形する
だけで繊維自体の変形は極めて少ない。繊維の波形が直
線に近づくに従って繊維自体の伸びと応力が著しく増大
する。When the composite material of the present invention is pulled in the direction along the wavelength direction of the waveform of the fibers (first drawing direction), either the synthetic resin phase itself elongates and deforms, or the fibers only undergo morphological deformation due to the elongation of the waveform. deformation is extremely small. As the waveform of the fiber approaches a straight line, the elongation and stress of the fiber itself increase significantly.
したがって本発明においては繊維の波形が伸びる分だけ
従来の繊維複合材料に比して伸び方向の靭性が向上し衝
撃強度も大巾に向上する。Therefore, in the present invention, the toughness in the elongation direction is improved and the impact strength is also greatly improved compared to conventional fiber composite materials by the extent that the waveform of the fibers is elongated.
実施例１
第２図はアクリロニトリル・ブタジェン命スチレン樹脂
−ガラス繊維複合体の応力−歪曲線である。図中ａ／λ
のλは波長、ａは振幅を示す。即ちａ／λが大穴いこと
は繊維の屈曲度が大きいことを示すものである。図中実
線は第１図に示すように波形繊維（１）の位相を同じに
した場合（同位相モデ／ｌ／）で、破線は第３図に示す
ように位相をランダムにずらせた場合（ランダム位相モ
デ）ｖ）である。同位相モデルはランダム位相モデルよ
りも初期の剛性は低いが高い伸び率を示し、いずれも従
来の直線形状の繊維を用いた場合、即ち第２図でａ／λ
＝Ｏの場合よりもはるかに高い伸び率を示す。繊維の屈
曲度ａ／λが大きくなると複合体の縦弾性係数は低下す
るが伸びは向上する。ａ／λ＝０．１の場合において本
発明の複合材料はグラフの傾斜が漸増する。これは繊維
が形態的に次第に伸びて縦弾性係数が増大１７ていくこ
とを示すものである。また第２図で、応力−歪曲線の下
側面積（図中の斜線部分）は靭性を測る尺度となるもの
であるが、同位相モデルはａ／λ＝Ｏの場合よりもはる
かに高い靭性を示すことが明らかである。Example 1 FIG. 2 is a stress-strain curve of an acrylonitrile-butadiene styrene resin-glass fiber composite. a/λ in the figure
λ is the wavelength, and a is the amplitude. That is, the fact that a/λ is large indicates that the degree of bending of the fiber is large. The solid line in the figure shows the case when the phase of the wave-shaped fiber (1) is the same as shown in Fig. 1 (same phase model /l/), and the broken line shows the case when the phase is randomly shifted as shown in Fig. 3 ( random phase model) v). The same-phase model has a lower initial stiffness than the random-phase model, but shows a higher elongation rate.
It exhibits a much higher elongation rate than the case of =O. As the bending degree a/λ of the fiber increases, the longitudinal elastic modulus of the composite decreases, but the elongation increases. In the case of a/λ=0.1, the slope of the graph of the composite material of the present invention gradually increases. This indicates that the fibers gradually elongate in shape and the longitudinal elastic modulus increases17. In addition, in Figure 2, the area under the stress-strain curve (the shaded area in the figure) is a measure of toughness, and the in-phase model shows much higher toughness than the case where a/λ=O. It is clear that
実施例２
第４図はアクリロニトリル・ブタジェン・スチレン樹脂
−アラミド繊維複合体の応力−歪曲線である。図中実線
は第１図の同位相モデル、破線は第３図のランダム位相
モデルを示す。図において、実施例１の場合と同様にａ
／λ〉０の本発明の複合材料はａ／λ＝００複合材料に
比して高い伸び率と靭性を示す。またａ／λ＝０．１の
グラフにおける傾斜の漸増は実施例１と同様に繊維が形
態的に次第に伸びて行くことを示している。ランダム位
相モデｐでは、位相の異なる隣接繊維によって繊維波形
の形態的伸びが抑制されるため、縦弾性係数は高いが伸
び率が小さい。Example 2 FIG. 4 is a stress-strain curve of an acrylonitrile-butadiene-styrene resin-aramid fiber composite. In the figure, solid lines indicate the same phase model in FIG. 1, and broken lines indicate the random phase model in FIG. 3. In the figure, as in Example 1, a
The composite material of the present invention with /λ>0 exhibits higher elongation and toughness than the composite material with a/λ=0. Further, the gradual increase in the slope in the graph of a/λ=0.1 indicates that the fibers gradually elongate in shape, as in Example 1. In the random phase model p, the morphological elongation of the fiber waveform is suppressed by adjacent fibers with different phases, so the longitudinal elastic modulus is high but the elongation rate is small.
以上の実施例は波形状繊維の波形の波長と波高がほぼ同
じで、波形状繊維の位相差をＯにした場合と位相をラン
ダムにずらせた場合の例であるが、波形状繊維の波長と
波高を適宜選択することをこより、複合材料の伸び率は
調節可能であり、使用目的により、波長、波高は適宜選
択可能である。The above examples are examples in which the wavelength and wave height of the waveform of the waveform fiber are almost the same, and the phase difference of the waveform fiber is O, and the phase is randomly shifted. By appropriately selecting the wave height, the elongation rate of the composite material can be adjusted, and the wavelength and wave height can be appropriately selected depending on the purpose of use.
又、単一の平面内においては波長と波高がほぼ同じ波形
状繊維を用いた複合材料を積層した積層複合材料も本願
発明と同様効果を得ることができ。Further, a laminated composite material in which composite materials using wave-shaped fibers having substantially the same wavelength and wave height in a single plane are laminated can also obtain the same effect as the present invention.
さらに波長と波高の異なる数種の複合材料を組せて積層
することにより積層複合材料の伸び率を調節することも
可能である。Furthermore, it is also possible to adjust the elongation rate of the laminated composite material by combining and laminating several types of composite materials having different wavelengths and wave heights.
さらに波形状連続繊維の波長の方向が整合していれば繊
維の波高の方向が異っていても本願発明と同様の効果を
得ることができる。又、波形状繊維を同一平面内に配列
することにより、複合材料の厚さを小さくすることが可
能になる。Furthermore, as long as the wavelength directions of the wave-shaped continuous fibers are matched, the same effect as the present invention can be obtained even if the wave height directions of the fibers are different. Also, by arranging the corrugated fibers in the same plane, it is possible to reduce the thickness of the composite material.
第１図は同位相モデル、第２図は実施例１の応力−歪曲
線、第３図はランダム位相モデルの内部構造の模式図、
第４図は実施例２の応力−歪曲線である。Figure 1 is the same phase model, Figure 2 is the stress-strain curve of Example 1, Figure 3 is a schematic diagram of the internal structure of the random phase model,
FIG. 4 is a stress-strain curve of Example 2.
Claims (1)
維は合成樹脂内において波形状をなし、各繊維の波形状
の波長の方向を整合せしめたことを特徴とする複合材料A composite material mainly consisting of a synthetic resin and fibers, wherein the fibers have a wave shape within the synthetic resin, and the directions of the wavelengths of the wave shapes of each fiber are matched.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3801486A JPS62196134A (en) | 1986-02-21 | 1986-02-21 | Composite material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3801486A JPS62196134A (en) | 1986-02-21 | 1986-02-21 | Composite material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS62196134A true JPS62196134A (en) | 1987-08-29 |
Family
ID=12513718
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP3801486A Pending JPS62196134A (en) | 1986-02-21 | 1986-02-21 | Composite material |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS62196134A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10227464B2 (en) | 2014-03-20 | 2019-03-12 | Teijin Limited | Fiber-reinforced plastic shaped product |
-
1986
- 1986-02-21 JP JP3801486A patent/JPS62196134A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10227464B2 (en) | 2014-03-20 | 2019-03-12 | Teijin Limited | Fiber-reinforced plastic shaped product |
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