JPS62186987A - Method for removing impurity by ionization - Google Patents
Method for removing impurity by ionizationInfo
- Publication number
- JPS62186987A JPS62186987A JP2994186A JP2994186A JPS62186987A JP S62186987 A JPS62186987 A JP S62186987A JP 2994186 A JP2994186 A JP 2994186A JP 2994186 A JP2994186 A JP 2994186A JP S62186987 A JPS62186987 A JP S62186987A
- Authority
- JP
- Japan
- Prior art keywords
- water
- ionization
- magnetic
- magnetic field
- removal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000000034 method Methods 0.000 title claims description 12
- 239000012535 impurity Substances 0.000 title abstract description 7
- 229910001868 water Inorganic materials 0.000 claims abstract description 77
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 76
- 230000005291 magnetic effect Effects 0.000 claims abstract description 57
- 238000001223 reverse osmosis Methods 0.000 claims abstract description 7
- 238000005342 ion exchange Methods 0.000 claims abstract description 5
- 239000000696 magnetic material Substances 0.000 claims description 9
- 238000004519 manufacturing process Methods 0.000 claims description 2
- 238000011144 upstream manufacturing Methods 0.000 claims 1
- 239000000463 material Substances 0.000 abstract 1
- CZPRKINNVBONSF-UHFFFAOYSA-M zinc;dioxido(oxo)phosphanium Chemical compound [Zn+2].[O-][P+]([O-])=O CZPRKINNVBONSF-UHFFFAOYSA-M 0.000 abstract 1
- 230000000694 effects Effects 0.000 description 7
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 6
- 150000002500 ions Chemical class 0.000 description 6
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 4
- 238000010586 diagram Methods 0.000 description 4
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 3
- 230000009471 action Effects 0.000 description 3
- 229910001424 calcium ion Inorganic materials 0.000 description 3
- 229910002092 carbon dioxide Inorganic materials 0.000 description 3
- 239000001569 carbon dioxide Substances 0.000 description 3
- 239000012530 fluid Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 239000008399 tap water Substances 0.000 description 3
- 235000020679 tap water Nutrition 0.000 description 3
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 2
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 239000003792 electrolyte Substances 0.000 description 2
- 230000005672 electromagnetic field Effects 0.000 description 2
- 239000003456 ion exchange resin Substances 0.000 description 2
- 229920003303 ion-exchange polymer Polymers 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 229910021642 ultra pure water Inorganic materials 0.000 description 2
- 239000011882 ultra-fine particle Substances 0.000 description 2
- 239000012498 ultrapure water Substances 0.000 description 2
- 229910000859 α-Fe Inorganic materials 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000004809 Teflon Substances 0.000 description 1
- 229920006362 Teflon® Polymers 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 230000008094 contradictory effect Effects 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 230000005426 magnetic field effect Effects 0.000 description 1
- 230000005389 magnetism Effects 0.000 description 1
- 239000011859 microparticle Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 238000005192 partition Methods 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 229910052761 rare earth metal Inorganic materials 0.000 description 1
- 150000002910 rare earth metals Chemical class 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 230000009476 short term action Effects 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000005061 synthetic rubber Substances 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
Landscapes
- Separation Using Semi-Permeable Membranes (AREA)
- Treatment Of Water By Ion Exchange (AREA)
- Water Treatment By Electricity Or Magnetism (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は純水または超純水製造装置に用いるユニットに
係り、特に水中の不純な結晶物をイオン化して除去する
イオン化除去の方法に関する。DETAILED DESCRIPTION OF THE INVENTION [Field of Industrial Application] The present invention relates to a unit used in a pure water or ultrapure water production apparatus, and particularly to an ionization removal method for ionizing and removing impure crystals in water.
水中の不純物はイオンの形で存在する電解質と結晶で存
在する非電解質、そして微小分散性の固体粒子とガス泡
の三つに分類され、各種素性の超微細粒子の量は極めて
多い。Impurities in water are classified into three types: electrolytes that exist in the form of ions, non-electrolytes that exist in the form of crystals, and microdispersed solid particles and gas bubbles, and the amount of ultrafine particles of various elements is extremely large.
水の導電率はイオンの濃度と移動度に依存し、この導電
率を以て純水または超純水のバロメータとしている。イ
オン化する反応を促進するためには中性原子や分子が実
電荷を得ることからイオン化エネルギーが必要とされる
が、この必要なエネルギーとして磁気利用する開示があ
る。The electrical conductivity of water depends on the concentration and mobility of ions, and this electrical conductivity is used as a barometer for pure or ultrapure water. In order to promote the ionization reaction, ionization energy is required because neutral atoms and molecules acquire a real charge, and there is a disclosure of using magnetism as this necessary energy.
例えば、ベルギー特許第４６０５６０号には水あか防止
手段として磁気処理があって、水槽の管路に多用されて
いるし、水の磁気処理（日ソ通信社５９，１．２５発行
）の１１４〜１２５頁に詳説されている。For example, Belgian Patent No. 460,560 describes magnetic treatment as a water scale prevention means, which is often used in pipes of aquariums, and Magnetic Treatment of Water (published by Nippon-Soviet Press 59, 1.25), pp. 114-125. It is explained in detail on page.
また、更には本発明者の特願昭６０−１３７３４３には
イオン化エネルギーを水流に与えるために永久磁石また
は電磁石を用いて磁場を形成し１発生する磁力の方向に
対して直交または水平の方向に流水する構成を示した。Furthermore, in Japanese Patent Application No. 137343/1988, the inventor of the present invention describes the method of forming a magnetic field using permanent magnets or electromagnets in order to impart ionization energy to a water stream. A configuration with flowing water is shown.
水中に必然的に含有している炭酸カルシウム（ＣａＣＯ
３）と炭酸ガス（ＣＯ２）は、化学親和力によって結び
つけられている原子団の分子から構成されて結晶した形
体で粒子として存在する。Calcium carbonate (CaCO), which is naturally contained in water,
3) and carbon dioxide (CO2) exist as particles in a crystalline form composed of molecules of atomic groups bound together by chemical affinity.
このことから、次の化学式が成り立つ。From this, the following chemical formula holds true.
ＣａＣｏ３＋Ｈ２０＋Ｃ０２ｇＣａ”＋２ＨＣ：０３−
即ち、イオン化エネルギーを与えることによって、カル
シウムイオン（Ｃａ２＋）と炭酸イオン（２Ｈｃｏ３−
）にイオン化することが可能である。CaCo3+H20+C02gCa"+2HC:03-
That is, by applying ionization energy, calcium ions (Ca2+) and carbonate ions (2Hco3-
) can be ionized.
化学親和力・分子引力作用などに起因する分子間運動に
ついては、水の不純物の超微細粒子の量が極めて多いこ
とから解明に至ってないが、ソ連特許第２８８６８３号
には流体の処理効果を高める目的から通路の作用区間を
縦型永久磁石で作り、その各々が中心部に端の極と反対
符号の極から成る突起を持ち、一方圧いに向い合って配
置される突起の極が異なる符号を持つとしている。The intermolecular motion caused by chemical affinity, molecular attraction, etc. has not been elucidated due to the extremely large amount of ultrafine particles of impurities in water, but Soviet Patent No. 288683 states that it is intended to improve the treatment effect of fluids. The active section of the passage is made of vertical permanent magnets, each of which has a protrusion in its center with a pole of opposite sign to that of the end, while the poles of the protrusions disposed opposite to each other have a different sign. It is said that it will have it.
水の磁気処理として経験法則的に電磁場の作用機構は共
振型の現象と考えられ、磁界強さと周波数及びその周期
的関係において顕著に表われる。電磁場の短時間作用は
水の構造の事前破壊となり、磁場によってもたらされる
分子の歳差運動による有効衝突断面の増大はよりイオン
化への反応を促進する。As a rule of thumb for the magnetic treatment of water, the action mechanism of electromagnetic fields is considered to be a resonance type phenomenon, which is clearly manifested in the magnetic field strength, frequency, and their periodic relationship. The short-term action of the electromagnetic field results in a preliminary destruction of the water structure, and the increase in the effective collision cross section due to the precession of the molecules brought about by the magnetic field makes it more responsive to ionization.
水の不純物であるＣａＣ０，、ＣＯ２を水流によって有
効衝突断面を増加し、磁場によって分子との結合を弱め
、系の平衡を減じるには高勾配の磁場への侵入初時点、
磁極間隙内の流れ、磁界内の水の滞留時間、そしてミク
ロ粒子の表面付近での水の小規模乱流についてか必要で
ある。In order to increase the effective collision cross section of the water impurities CaC0, CO2 by the water flow, weaken the bond with molecules by the magnetic field, and reduce the equilibrium of the system, the first point of entry into the high gradient magnetic field,
We need information about the flow in the magnetic pole gap, the residence time of water in the magnetic field, and the small-scale turbulence of water near the surface of microparticles.
前記した従来技術においては次のような問題があった。 The prior art described above has the following problems.
即ち、異なる極の間隙に流水することによって水路の多
少の凸凹によって乱流となるものの有効衝突の回数、交
番磁場の形成において満足すべき構成ではなく、水路壁
面と磁場発生面とによる水抵抗によって一定のイオン化
エネルギーが与えられずに水の磁気処理としての効率が
低かったのである。そして、その結果として後流に設け
るイオン交換樹脂がアニオンブレークを生じ、イオン交
換樹脂の再生タイミングが一定しないという問題点があ
った。In other words, the number of effective collisions is not satisfactory for the formation of an alternating magnetic field, although turbulent flow occurs due to the unevenness of the channel due to water flowing into the gap between different poles, and due to the water resistance between the channel wall surface and the magnetic field generation surface. The efficiency of magnetic treatment of water was low because a certain amount of ionization energy was not provided. As a result, the ion exchange resin provided downstream suffers an anion break, resulting in the problem that the regeneration timing of the ion exchange resin is inconsistent.
本考案の目的は１通常の水中の不純物をイオン化して除
去し、純粋な水を得ることにある。The purpose of the present invention is to obtain pure water by ionizing and removing impurities in ordinary water.
本発明は磁場強度５０〜７５０ＫＡ／ｍの磁場を設けて
磁力作用の方向と直交するように水を供給して通水し、
磁場は交番磁場とすると共に通水はレイノルズ２，３０
０〜５，０００の乱流となるようにする。The present invention provides a magnetic field with a magnetic field strength of 50 to 750 KA/m and supplies water perpendicular to the direction of magnetic force action,
The magnetic field is an alternating magnetic field, and the water flow is Reynolds 2,30.
Aim for turbulence of 0 to 5,000.
磁場に影響される部位において急激な通水圧力変動を生
ゼしぬ、次段の磁場においても同様の作用をして繰返し
をし磁気エネルギーをイオン化エネルギーに効率よく充
当することにある。The purpose is to efficiently allocate magnetic energy to ionization energy by repeating the same action in the next stage of magnetic field without causing sudden water flow pressure fluctuations in areas affected by the magnetic field.
本発明のプロセスフローを第３図に示す。処理すべき原
水５０は清澄な水道水または高度処理水、地下水などを
用い、１０μｍ以下の孔径をもつフィルター５１で微粒
子を除去して処理水１とする。The process flow of the present invention is shown in FIG. The raw water 50 to be treated is clear tap water, highly treated water, underground water, etc., and treated water 1 is obtained by removing particulates with a filter 51 having a pore size of 10 μm or less.
処理水１は磁気処理ユニット５３で磁力によるイオン化
を促進されてカルシウムイオンと炭酸イオンになる。こ
のイオン化水２は逆浸透ユニット５４にて約９０％のイ
オン５６を除去し。The treated water 1 is ionized by magnetic force in the magnetic treatment unit 53 and becomes calcium ions and carbonate ions. About 90% of ions 56 are removed from this ionized water 2 in a reverse osmosis unit 54.
透過するイオン残存水５２をイオン交換ユニット５５へ
供給する。The permeated ion residual water 52 is supplied to an ion exchange unit 55.
このイオン交換ユニット５５はアニオン系とカチオン系
の樹脂を適宜な混合比を以て充填したものであって、こ
のユニットで残存イオン５７を置換除去して純水５８を
得る。This ion exchange unit 55 is filled with anionic and cationic resins at an appropriate mixing ratio, and this unit replaces and removes residual ions 57 to obtain pure water 58.
磁気処理ユニット５３でイオン化したイオンの多くを逆
浸透ユニット５４で一次除去し、更に二次除去をイオン
交換ユニット５５でするのである。Most of the ions ionized in the magnetic processing unit 53 are primarily removed in the reverse osmosis unit 54, and then secondary removal is performed in the ion exchange unit 55.
本発明の磁気処理ユニット５３はこのようなプロセスフ
ローを満足させるにあって、以下に第１図を以て詳説す
る。The magnetic processing unit 53 of the present invention satisfies such a process flow and will be explained in detail below with reference to FIG. 1.
一体のフレーム１１を磁性体でコ字状にしその溝内にＳ
極とＮ極が対面するように磁石８を設け、磁石８の対面
する間隙に筒状の非磁性体からなる水接面５を設ける。The integral frame 11 is made of magnetic material into a U-shape, and an S is inserted into the groove.
A magnet 8 is provided so that the pole and the north pole face each other, and a water contact surface 5 made of a cylindrical non-magnetic material is provided in the gap where the magnet 8 faces each other.
水接面５と連通ずるフランジ１５を以て入口ユニット１
８を構成する。同様にフレーム１ｏと磁石７と水接面を
以て中間ユニット１７とし、出口ユニット１６はフレー
ム９と磁石６と水接面３とフランジ１４で構成し、これ
らの入口、中間、出口ユニット１８．１１１６は非磁性
体からなる隔体１３．１２を介して水密に連結する。The inlet unit 1 has a flange 15 communicating with the water contact surface 5.
8. Similarly, the frame 1o, the magnet 7, and the water contact surface constitute an intermediate unit 17, and the outlet unit 16 is composed of the frame 9, the magnet 6, the water contact surface 3, and the flange 14, and these inlet, intermediate, and outlet units 18.1116 are They are watertightly connected via partitions 13 and 12 made of non-magnetic material.
第２図は第１図のＡ−Ａ断面を示し、入口ユニット１８
について述べる。FIG. 2 shows the AA cross section of FIG. 1, and shows the inlet unit 18.
Let's talk about.
磁石８ははゾ平板状とし片面にのみ突起１９を設けてＮ
極とし、対面する磁石２０はゾ同様構成とするがＳ極と
し、反極して磁石８と磁石２０の突起が近接するように
設ける。The magnet 8 is in the shape of a flat plate and has a protrusion 19 on only one side.
The magnets 20 that face each other have the same structure as in Z, but have S poles and are oppositely polarized so that the protrusions of the magnets 8 and 20 are close to each other.
水接面５は処理水１の水流による乱流が凹部においてレ
イノルズ数およそ２３００．突起部においてはおよそ５
０００となるようにし、磁石８と２０との突起で成す磁
場強度を３００〜７５０ＫＡ／ｍとし、他の部分では５
０〜１００ＫＡ／ｍとする。The water contact surface 5 has a Reynolds number of approximately 2300 in the concave portion where turbulent flow due to the water flow of the treated water 1 occurs. Approximately 5 at the protrusion
000, and the magnetic field strength formed by the protrusions of magnets 8 and 20 is set to 300 to 750 KA/m, and the other parts are set to 5
0 to 100 KA/m.
この水接面５について第４図を以て詳説する。This water contact surface 5 will be explained in detail with reference to FIG.
突起１９は永久磁石である複合マグネット。The protrusion 19 is a composite magnet that is a permanent magnet.
フェライトマグネット、希土類コバルト、鋳造マグネッ
トなどの永久磁石若しくは電磁石であって、処理水１と
接する近接点２１と流圧の変点２２．２５を以て水接面
５の全体を構成する。It is a permanent magnet or electromagnet such as a ferrite magnet, a rare earth cobalt magnet, or a cast magnet, and constitutes the entire water contact surface 5 with the proximal point 21 in contact with the treated water 1 and the fluid pressure transition points 22 and 25.
突起１９の表面２４には非磁性体である合成樹脂系また
はゴム系の離隔層２３を設けて処理水１へ磁石性分の溶
出を防止する。外表面に磁石性分の素材が露出しない内
装された複合マグネットが最適であって、プラスチック
マグネット、ゴムマグネットなどを用いるか、又は磁石
の表層にテフロン、セラミックなどの非磁性体をコーテ
ィングするようにしても良い。A separation layer 23 made of synthetic resin or rubber, which is a non-magnetic material, is provided on the surface 24 of the protrusion 19 to prevent magnetic components from leaching into the treated water 1. An internal composite magnet with no magnetic material exposed on the outer surface is optimal; use a plastic magnet, rubber magnet, etc., or coat the surface layer of the magnet with a non-magnetic material such as Teflon or ceramic. It's okay.
突起１９の断面外形は円弧または角形、台形とするがそ
の表面を粗面にするか又は断面の頂点を波形で凸凹する
段差にするとかすると更に乱流効果が大となる。流圧の
変点２２と２５は近接点２１に対して対称とは限らず、
処理水１の通過量と速度及び磁場強度から適宜に選択す
る。The cross-sectional outline of the protrusion 19 may be an arc, a square, or a trapezoid, but the turbulent flow effect will be further enhanced if the surface is roughened or the apex of the cross-section is formed into a corrugated step. The fluid pressure turning points 22 and 25 are not necessarily symmetrical with respect to the adjacent point 21,
An appropriate selection is made based on the amount and speed of the treated water 1 passing through and the magnetic field strength.
第２図に示したように水接面５を形成する離隔管２６を
独立して設け、別体の磁石８をフレーム１１との間に挿
入自在に設けると磁石８の磁場強度を変えるに好都合で
ある。この場合の接面２７．２８は密着して設は適宜に
固定する。As shown in FIG. 2, it is advantageous to provide an independent separation tube 26 that forms the water contact surface 5 and to provide a separate magnet 8 that can be freely inserted between the frame 11 and the magnetic field strength of the magnet 8. It is. In this case, the contact surfaces 27 and 28 are in close contact with each other and are appropriately fixed.
次に磁場を形成する近接点２１の配置について第１図を
参照し、第５図で例示説明する。Next, the arrangement of the proximity points 21 that form a magnetic field will be illustrated with reference to FIG. 1 and FIG. 5.
流心線Ｏ−０に対して、近接点２１を仮りにＮ□、Ｎ２
、Ｎ３点とし対応する位置にＳＬ、 Ｓ２゜８３点を設
け、その点を各々Ｓ極、Ｎ極とすればＳ□−Ｎ１磁場が
形成され、Ｓ２−Ｎ２、Ｓ、−Ｎ、と各々独立した磁場
が形成される。この時の磁力振幅の最大はＭであり、流
心線〇−〇を通過する処理水１は各点において相反する
逆方向の磁気作用を受ける。Ｎ□からＮ２までの距離。With respect to the center line O-0, let's assume that the nearby point 21 is N□, N2
, N3 point and SL, S2゜83 points are set at the corresponding positions, and if these points are set as S pole and N pole respectively, S□-N1 magnetic field is formed, and S2-N2, S, -N are each independent. A magnetic field is formed. The maximum amplitude of the magnetic force at this time is M, and the treated water 1 passing through the flow center line 〇-〇 is subjected to contradictory magnetic effects in opposite directions at each point. Distance from N□ to N2.
Ｎ２からＮ３までの距離は３０〜８０ｍｍの範囲に設け
、５０ｍをベストとする。The distance from N2 to N3 is set in the range of 30 to 80 mm, with 50 m being the best.
この距離は非磁性体である帰休１２，１３などで変える
と同時に隣接する異極との縁を切る。This distance is changed by using non-magnetic materials such as furrows 12, 13, etc., and at the same time, the edge of the adjacent different poles is cut off.
第１図と第２図に示した流心線は処理水１の入口から出
口まで一直線状に示しているが、第６図に示したように
０点を中心に０□〜０４のようにずらして流水すると乱
流効果と磁場効果がより促進されるので、ランダムに屈
折した流心線０−Ｏとすることもできる。この場合には
帰休１２，１３の部位で適宜に心をずらすのである。The flow center lines shown in Figures 1 and 2 are shown in a straight line from the inlet to the outlet of the treated water 1, but as shown in Figure 6, they are drawn from 0□ to 04 with the 0 point as the center. Since the turbulent flow effect and the magnetic field effect are further promoted when the water flows in a staggered manner, it is also possible to create a randomly bent flow center line 0-O. In this case, the mind should be shifted appropriately at the points 12 and 13.
実施事例を表−１に基づいて詳述する。 The implementation example will be explained in detail based on Table-1.
使用水としてＰＨ６，８，水温１９°Ｃの水道水を用い
て突起部で２ｍ／ｓの通水をした。Tap water with a pH of 6.8 and a water temperature of 19°C was used as the water used, and water was passed through the protrusion at a rate of 2 m/s.
磁石はフェライト磁石で半径５ｍの円弧状突起を設け、
突起は反極となるようにし、隣接する磁石とも反極とな
るようにし鋼板に固定した。The magnet is a ferrite magnet with an arcuate projection with a radius of 5m.
The protrusions were fixed to a steel plate so that they had opposite polarities, and the adjacent magnets also had opposite polarities.
突起の表面はＰＶＣ（塩化ビニール）で覆いをし、５０
ｍピッチで３個所数けた。The surface of the protrusion is covered with PVC (vinyl chloride) and
I counted three places with m pitch.
尚、水道水の無機性炭素濃度は２２■／Ｑであって、磁
場処理水は塩除去率９７％のスパイラル型の逆浸透ユニ
ットを通過させ、この通過水の無機性炭素濃度を表−１
に示す。The inorganic carbon concentration of tap water is 22■/Q, and the magnetically treated water is passed through a spiral type reverse osmosis unit with a salt removal rate of 97%, and the inorganic carbon concentration of this water is shown in Table 1.
Shown below.
事例１は無磁場を示し、逆浸透ユニットでの除去効果の
みを表わす。磁場での磁気処理をせずにダイレクトに逆
浸透ユニットに通水すると７９％の除去率となるが、事
例２に示すように１００ＫＡ／ｍ程度の磁気処理をする
と無機性炭素濃度が４．６から０．７に下がり６．６倍
もの効果がある。極めて顕著にその効果が表われる。Case 1 shows no magnetic field and represents only the removal effect in the reverse osmosis unit. If water is passed directly through the reverse osmosis unit without magnetic treatment in a magnetic field, the removal rate will be 79%, but as shown in case 2, if magnetic treatment is performed at about 100 KA/m, the inorganic carbon concentration will be 4.6%. This decreases from 0.7 to 0.7, which is 6.6 times more effective. The effect is extremely noticeable.
更に突起部における磁場強度をアップして事例３の３０
０ＫＡ／ｍにすると２，３倍の効果があるが、これ以上
の磁場強度では余り効果がない。Furthermore, the magnetic field strength at the protrusion was increased to 30 in Case 3.
A magnetic field strength of 0 KA/m is two to three times more effective, but a magnetic field strength higher than this is not very effective.
突起部のないストレートな流れで、単なる磁場をかける
特１［６Ｏ−１３７３４３（７）表−１と無機性炭素濃
度が０．７前後であって、事例２に相当する。このこと
から突起部を設けて乱流を促進し、３００〜５００ＫＡ
／ｍの磁場をかけると倍加する効果がある。It is a straight flow with no protrusions, and the inorganic carbon concentration is around 0.7, which corresponds to Case 2. For this reason, protrusions are provided to promote turbulence, and the 300-500KA
Applying a magnetic field of /m has a doubling effect.
表−１ 以下づTable-1 The following
第１図は本発明の磁気処理ユニットを示す断面図、第２
図は第１図のＡ−Ａ断面図、第３図は本発明のプロセス
フロー図、第４図は第１図の突起１９を示す詳細図、第
５図は第１図の磁場を形成する配置説明図、第６図は第
１図に示す処理水１とイオン化水２の流心を示す説明図
。
ｒ白
寿１ 図
第２月
第〕圀
発４凶FIG. 1 is a sectional view showing the magnetic processing unit of the present invention, and FIG.
The figure is a sectional view taken along the line A-A in FIG. 1, FIG. 3 is a process flow diagram of the present invention, FIG. 4 is a detailed view showing the protrusion 19 in FIG. 1, and FIG. 5 is a diagram showing the formation of the magnetic field in FIG. Layout explanatory diagram, FIG. 6 is an explanatory diagram showing flow centers of treated water 1 and ionized water 2 shown in FIG. 1. r Hakuju 1 Fig. 2nd month] Kokuhatsu 4
Claims (1)
浸透ユニット及びイオン交換ユニットを順に通過して純
水を製造する方法において、磁気処理ユニットの水接面
に磁石で磁場を形成する異極を設け、異極は対面して各
々が内方に突起し、水の通過断面が急変して更に乱流と
なるように通水することを特徴とするイオン化除去の方
法。 ２、磁場の強度は突起の近接部において３００〜７５０
ＫＡ／ｍとし、突起外の遠対面では５０〜１００ＫＡ／
ｍとすることを特徴とする特許請求の範囲第１項記載の
イオン化除去の方法。 ３、通水域の乱流がレイノルズ数２３００〜５０００と
なるように通水路及び磁場の突起を設け、その表面は非
磁性体を介して水接することを特徴とする特許請求の範
囲第１項記載のイオン化除去の方法。 ４、磁石は永久磁石若しくは電磁石とし、突起の断面外
形は内方に向けて円弧とすることを特徴とする特許請求
の範囲第１項記載のイオン化除去の方法。 ５、通水方向に対して直交するように突起する異極を設
け、隣接する極とも異極となるように交番磁場がかかる
複数段の突起を設けることを特徴とする特許請求の範囲
第１項記載のイオン化除去の方法。 ６、磁石は非磁性体を介して各々が独立し、常に異極が
対面するように交互に設け、隔たる突起の近接点の上下
流側を対称若しくは非対称とすることを特徴とする特許
請求の範囲第４項記載のイオン化除去の方法。[Claims] 1. In a method for producing pure water by passing pretreated water through a filter, a magnetic treatment unit, a reverse osmosis unit, and an ion exchange unit in order, a magnetic field is applied to the surface of the magnetic treatment unit in contact with water using a magnet. A method for removing ionization, characterized by providing different poles forming a , the different poles face each other, each protruding inwardly, and water is passed through so that the cross section of the water passing through it suddenly changes to create a more turbulent flow. 2. The strength of the magnetic field is 300-750 in the vicinity of the protrusion.
KA/m, and 50 to 100 KA/m on the far side outside the protrusion.
The method of ionization removal according to claim 1, characterized in that m is used for ionization removal. 3. The water passage and the magnetic field protrusion are provided so that the turbulent flow in the water flow has a Reynolds number of 2300 to 5000, and the surface thereof is in contact with water through a non-magnetic material, as described in claim 1. Method of ionization removal. 4. The ionization removal method according to claim 1, wherein the magnet is a permanent magnet or an electromagnet, and the cross-sectional shape of the protrusion is an inwardly arcuate shape. 5. Claim 1, characterized in that different poles protruding perpendicularly to the water flow direction are provided, and a plurality of protrusions to which an alternating magnetic field is applied are provided so that adjacent poles are also different poles. The method of ionization removal described in section. 6. A patent claim characterized in that the magnets are each independent through a non-magnetic material, and are arranged alternately so that different poles always face each other, and the upstream and downstream sides of the adjacent points of the separating protrusions are symmetrical or asymmetrical. The ionization removal method according to item 4.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2994186A JPS62186987A (en) | 1986-02-14 | 1986-02-14 | Method for removing impurity by ionization |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2994186A JPS62186987A (en) | 1986-02-14 | 1986-02-14 | Method for removing impurity by ionization |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS62186987A true JPS62186987A (en) | 1987-08-15 |
Family
ID=12290011
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2994186A Pending JPS62186987A (en) | 1986-02-14 | 1986-02-14 | Method for removing impurity by ionization |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS62186987A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6439899U (en) * | 1987-08-31 | 1989-03-09 | ||
| JPH0283096U (en) * | 1988-01-19 | 1990-06-27 | ||
| WO1998031637A1 (en) * | 1997-01-22 | 1998-07-23 | Seh America, Inc. | Production of ultrapure water by non-chemical treatment |
| WO2005077524A1 (en) * | 2004-02-12 | 2005-08-25 | Kihira, Katsutoshi | Magnetic treatment system |
| WO2023145669A1 (en) * | 2022-01-27 | 2023-08-03 | テンソー電磁技術工業株式会社 | Microbubbles amplifier |
-
1986
- 1986-02-14 JP JP2994186A patent/JPS62186987A/en active Pending
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6439899U (en) * | 1987-08-31 | 1989-03-09 | ||
| JPH0446880Y2 (en) * | 1987-08-31 | 1992-11-05 | ||
| JPH0283096U (en) * | 1988-01-19 | 1990-06-27 | ||
| WO1998031637A1 (en) * | 1997-01-22 | 1998-07-23 | Seh America, Inc. | Production of ultrapure water by non-chemical treatment |
| WO2005077524A1 (en) * | 2004-02-12 | 2005-08-25 | Kihira, Katsutoshi | Magnetic treatment system |
| WO2023145669A1 (en) * | 2022-01-27 | 2023-08-03 | テンソー電磁技術工業株式会社 | Microbubbles amplifier |
| JP2023109206A (en) * | 2022-01-27 | 2023-08-08 | テンソー電磁技術工業株式会社 | Microbubble amplifier |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US8168055B2 (en) | Arrangement of ion exchange material within an electrodeionization apparatus | |
| US4563286A (en) | System of ionized oxygen allotrope gas water purification and method and apparatus therefor | |
| TW200803967A (en) | Method and apparatus for shifting current distribution in electrodeionization systems | |
| HU225090B1 (en) | Treatment of water and apparatus for desalinating | |
| GB2307235A (en) | Water treatment method and water treatment facilities | |
| CN109534465B (en) | Parallel seawater desalination device based on ion concentration polarization effect | |
| JP2011502030A5 (en) | ||
| US20040007452A1 (en) | Water purification: ion separation | |
| US8197684B2 (en) | Desalination device using selective membranes and magnetic fields | |
| US20050126974A1 (en) | Water purifier having magnetic field generation | |
| JPS62186987A (en) | Method for removing impurity by ionization | |
| JP2001087768A (en) | Electric deionizing device | |
| JP3966421B2 (en) | Ultra-high magnetic field fluid treatment system | |
| RU66329U1 (en) | MAGNETIC LIQUID TREATMENT DEVICE IN A PIPELINE | |
| SU874090A1 (en) | Electrodialyzer | |
| AU2004303816B2 (en) | Fluid purifier having magnetic field generation | |
| JP2002186973A (en) | Continuous electro-deionization device | |
| JP4038279B2 (en) | Water treatment equipment using multipolar magnetic field | |
| US20170165630A1 (en) | Membrane Plasma Reactor | |
| JP2000263058A (en) | Electric desalting apparatus | |
| JP3128743U (en) | Fluid magnetic processing equipment | |
| RU20310U1 (en) | LIQUID TREATMENT DEVICE | |
| SU753468A1 (en) | Magnetic apparatus | |
| JPS621495A (en) | Apparatus for removing carbonic acid in water | |
| JPS6316091A (en) | Manufacturing facility for activated water |