JPS62149612A - Cold wave first solution combined with yeast separation solution from saccharide fermentation mixture - Google Patents

Abstract

PURPOSE:A cold wave first solution that is prepared by adding a yeast-separated solution from a saccharide fermentation mixture to a usual cold wave first solution mainly containing ammonium thioglycolate and an alkali, thus removing the unpleasant odor characteristic in permanent wave setting. CONSTITUTION:Yeasts are removed from saccharide fermentation mixture and the resultant solution is added to a usual cold wave setting first solution mainly containing ammonium thioglycolate and an alkali in an amount of over 0.5%, preferably 1% to give the objective cold wave first solution which can remove irritating and unpleasant odor of mercaptans, when permanent waves are set. Moreover, the use of yeast-separated solution can reduce the amount enough to completely remove the bad smell in comparison with the fermentation solution according to a known method and can greatly reduce the ammonia odor, as well, while good waves are set on hair without damaging the hair.

Description

【発明の詳細な説明】 「産業上の利用分野」 本発明はパーマ施術中および後に特有の不快臭のしない
コールドウェーブ第１剤に関する。DETAILED DESCRIPTION OF THE INVENTION "Field of Industrial Application" The present invention relates to a cold wave first agent that does not have a characteristic unpleasant odor during and after a perm treatment.

「従来の技術」 従来のコールドウェーブ第１剤としては、チオグリコー
ル酸アンモニウムおよびアルカリ剤が使用されており、
当該剤に毛髪のケラチン物質誘導体を配合した方法等も
知られている。"Prior art" Ammonium thioglycolate and an alkaline agent are used as the first cold wave agent in the past.
A method in which a hair keratin substance derivative is blended with the agent is also known.

しかしながら、上記方法ではある程度毛髪の損傷は防止
出来るが、毛髪蛋白ケラチンをチオグリコール酸で還元
することにより発生するメルカプト臭は除去出来なかっ
た。又この特異的な不快臭を除き毛髪の損傷を防止する
目的で、システィンパーマも行われているが、ウェーブ
形成力が弱く難点があった。However, although the above method can prevent hair damage to some extent, it cannot remove the mercapto odor generated by reducing the hair protein keratin with thioglycolic acid. Cystine perms have also been performed in order to remove this unique unpleasant odor and prevent hair damage, but they have a drawback in that they have weak wave-forming ability.

「発明が解決しようとする問題点」 本発明はパーマ施術中および後に特有の不快臭のしない
新規なコールドウェーブ第１剤を提供することを技術的
課題とする。"Problems to be Solved by the Invention" The technical problem of the present invention is to provide a novel cold wave first agent that does not have a characteristic unpleasant odor during and after a perm treatment.

「問題点を解決するための手段」 本発明者等は従来のコールドウェーブ第１荊に中性にし
たＦ’ｌｌ酵液を添加すればパーマ処理中および後に特
有の不快臭のしないコールドウェーブ第１剤が得られる
ことを見出した。（特願昭６０−２０９５５０号） 上記糖醗酵液は以下に記載した方法により得られた。"Means for Solving the Problems" The present inventors have proposed that by adding neutralized F'll fermentation liquid to the conventional cold wave first stage, a cold wave stage that does not have the peculiar unpleasant odor during and after the perm process can be achieved. It was found that one drug could be obtained. (Japanese Patent Application No. 60-209550) The above sugar fermentation liquid was obtained by the method described below.

即ち、水に約１０％のＷ類を加え、撹拌溶Ｍ、後１００
°Ｃにて殺菌し、冷後３０〜４０°Ｃにて１〜２％のサ
ツカロミセス属酵母を加え、１０分間攪拌分散し、醗酵
を行い、適時分離生成した炭酸ガスを撹拌により除去し
、約５０〜６０時間で醗酵を終了する。醗酵温度は３７
℃が最適である。醗酵終了後、濾過により酵母を分離し
、７０°Ｃ以上に加温し、蛋白変性後、ｔｉ醗酵液を得
た。That is, add about 10% W to water, stir the solution M, and then add 100%
Sterilize at °C, cool and then add 1-2% Satucharomyces yeast at 30-40 °C, stir and disperse for 10 minutes, ferment, separate and remove the generated carbon dioxide gas by stirring, and remove the produced carbon dioxide gas by stirring. Fermentation is completed in 50 to 60 hours. Fermentation temperature is 37
°C is optimal. After the fermentation was completed, yeast was separated by filtration, heated to 70°C or higher, and after protein denaturation, a ti fermentation liquid was obtained.

上記１１！醗酵液の恒数は比重０．９９７．屈折率１　
、３３０９、酸価２．８、ｐＨ２，５〜２．８、ガスク
ロマド分析によりアルコール生成量は３．８〜４．１％
であり、還元糖の有無はフェーリング試薬陰性で、アミ
ノ酸生成はニンヒドリン反応において赤紫色を呈し確認
できた。この糖醗酵液は水酸化ナトリウム又は他のアル
カリ剤で中和して中性にして使用する。Above 11! The constant of the fermentation liquid is the specific gravity of 0.997. refractive index 1
, 3309, acid value 2.8, pH 2.5-2.8, alcohol production amount 3.8-4.1% by gas chromad analysis.
The presence or absence of reducing sugars was confirmed by Fehling's reagent negative test, and the production of amino acids was confirmed by the appearance of a reddish-purple color in the ninhydrin reaction. This sugar fermentation liquid is neutralized with sodium hydroxide or other alkaline agent to make it neutral before use.

サツカロミセス属酵母としてはサツカロミセスセレビシ
ェ（Ｓａｃｃｈａｒｏｍｙｃｅｓ　ｃｅｒｅｖｉｓｉａ
ｅ）、サッカロミセスカールスベルゲンシス（Ｓ、ｃａ
ｒｌｓｂ−ｅｒｇｅｎｓ　ｉｓ）　、サツ力ロミセスセ
レビシエヴアルエリブソイダス（Ｓ、ｃｅｒｅｖｉｓｉ
ａｅ　ｖａｒ　ｅｌｌｉｐｓｏｉ−ｄｅｕｓ）等があげ
られ、特にサツカロミセスセレビシェが有効である。The yeast of the genus Saccharomyces is Saccharomyces cerevisiae.
e), Saccharomyces carlsbergensis (S, ca
rlsb-ergens is), S. cerevisi
ae var ellipsoi-deus), and Saccharomyces cerevisiae is particularly effective.

糖としては上記サツカロミセス属酵母で醗酵しうる単糖
類および三糖類があげられるが、特にぶどう糖および蔗
糖が好適である。Examples of sugars include monosaccharides and trisaccharides that can be fermented with the yeast of the genus Saccharomyces, and glucose and sucrose are particularly preferred.

コールドウェーブ第１剤中のＩＪｉ　ＩＩ酵液液量２０
％以上が好適である。IJi II fermentation liquid amount in cold wave 1st agent 20
% or more is suitable.

〔参考例〕[Reference example]

・強アンモニア水（２８％）　　　１．３（〃）・エデ
ト酸ナトリウム　　　　０．１（〃）・中性Ｉ！ｉ醗酵
液　　　　　　３０．０　（〃）・精製水　　　　　　
　　　５５．６（〃）上記組成のコールドウェーブ第１
剤で、毛髪を室温にて１５分間処理後、第２剤（臭素酸
ナトリウム６．５％）にて室温で１５分間処理した後、
水洗した。処理中および処理後においてメルカプト臭は
全くなく、アンモニア臭についても、従来のものに比較
して大幅に減少した。毛髪の損傷はなく、良好なカール
が出来た。・Strong ammonia water (28%) 1.3 (〃) ・Sodium edetate 0.1 (〃) ・Neutral I! i Fermentation liquid 30.0 (〃)・Purified water
55.6 (〃) Cold wave 1 with the above composition
After treating the hair with the agent for 15 minutes at room temperature, and then treating the hair with the second agent (6.5% sodium bromate) at room temperature for 15 minutes,
Washed with water. There was no mercapto odor during or after the treatment, and the ammonia odor was significantly reduced compared to conventional products. There was no damage to the hair, and good curls were created.

本発明者らはこの糖醗酵液について研究を続行し、酵母
培養後、酵母を分離した後のＩＩ！醗酵液である酵母分
離液を用いれば、前記のＩ！醗酵液よりもはるかに少な
い使用量即ち０．５％以上、好適には１％の添加で十分
その不快臭を除去できることを知見し、本発明を完成す
るに至ったものである。The present inventors continued research on this sugar fermentation solution, and after culturing yeast and separating yeast, II! If you use the yeast separation liquid, which is a fermentation liquid, the above-mentioned I! It was discovered that the unpleasant odor can be sufficiently removed by adding a much smaller amount than that of fermentation liquid, that is, 0.5% or more, preferably 1%, and this led to the completion of the present invention.

この酵母分離液は例えば特公昭５２−５０２６７号明細
書に記載された方法により得られる。This yeast separation liquid can be obtained, for example, by the method described in Japanese Patent Publication No. 52-50267.

即ち、製糖工程で得られる糖水を糖質源とし、コーン・
ステイープ・リカー（Ｃ，Ｓ、　Ｌ）　又は／及び廃糖
蜜を糖水に対し１０〜１００重量％添加してなる培地を
用いて、パン酵母を培養した後、酵母を分離し、本発明
の酵母分離液を得た。In other words, sugar water obtained in the sugar manufacturing process is used as a carbohydrate source, and corn
After culturing baker's yeast using a medium prepared by adding 10 to 100% by weight of staple liquor (C, S, L) or/and blackstrap molasses to sugar water, the yeast is separated, and the yeast isolation of the present invention is performed. I got the liquid.

当該酵母分離液の恒数は比重１．０２６．屈折率１．３
４３５．酸価３．９．　　ｐ　Ｈ５，５＋砒素１　ｐｐ
ｍ以下、および重金属１０．０　ｐｐｍ以下であった。The constant of the yeast separation liquid is a specific gravity of 1.026. Refractive index 1.3
435. Acid value 3.9. pH 5,5 + Arsenic 1 pp
m or less, and heavy metals were less than 10.0 ppm.

上記方法において糖水とは甘蔗、テンサイ等から蔗糖を
精製するに当たり、活性炭処理工程を経て無着色の蔗糖
溶液としたものであって蔗糖を結晶化する前の溶液であ
る。In the above method, the sugar water is a uncolored sucrose solution obtained through an activated carbon treatment step when sucrose is purified from cane, sugar beet, etc., and is a solution before sucrose is crystallized.

これは通常約７０％の蔗糖及び少量の還元糖及び灰分を
含んでおり、これを酵母の培養に適当な糖濃度となるよ
う希釈して用いれば良い。This usually contains about 70% sucrose and small amounts of reducing sugar and ash, and may be diluted to a sugar concentration suitable for yeast culture.

Ｃ，Ｓ、Ｌはとうもろこしを亜硫酸溶液に浸漬した時の
浸出液であり、微生物の生長促進物質を含んでおり、微
量栄養素源として微生物の培養にしばしば用いられてい
る。C, S, and L are the leachate obtained when corn is soaked in a sulfite solution, which contains substances that promote the growth of microorganisms, and is often used as a source of micronutrients in the cultivation of microorganisms.

又、廃糖蜜は甘蔗、テンサイ等より蔗糖を精製した残り
で糖分を多く含むために、微生物培養の糖源として広く
用いられているが、この物質は同時に糖水の如く精製さ
れた糖源にはあまり存在しない成長促進物質を多量に含
んでいることでも知られている。In addition, blackstrap molasses is the residue obtained by refining sucrose from cane, sugar beet, etc., and contains a large amount of sugar, so it is widely used as a sugar source for microbial culture. It is also known to contain large amounts of growth-promoting substances that are not commonly found.

コールドウェーブ第１剤中の酵母分離液量は０．５％以
上であれば良く、１％が最適である。The amount of yeast separation liquid in the first cold wave agent may be 0.5% or more, and 1% is optimal.

「実施例」 以下、実施例をあげて本発明を説明する。"Example" The present invention will be explained below with reference to Examples.

〔実施例〕〔Example〕

・チオグリコール酸 アンモニウム（５０％）　　　　１３．０（重量％）・
強アンモニア水（２８％）　　　１．５（〃）・エデト
酸ナトリウム　　　　０．１（〃）・酵母分離液　　　
　　　　　１．０（〃）・精製水　　　　　　　　　８
４．４　（〃）上記組成のコールドウェーブ第１剤で毛
髪を室温にて１５分間処理後、第２剤（臭素酸ナトリウ
ム６．５％）にて室温で１５分間処理した後、水洗した
。・Ammonium thioglycolate (50%) 13.0 (wt%)・
Strong ammonia water (28%) 1.5 (〃)・Sodium edetate 0.1 (〃)・Yeast separation liquid
1.0 (〃)・Purified water 8
4.4 (〃) Hair was treated for 15 minutes at room temperature with the first agent of cold wave having the above composition, then treated with the second agent (sodium bromate 6.5%) for 15 minutes at room temperature, and then washed with water.

処理中および処理後メルカプト臭は全くなく、アンモニ
ア臭も従来のものに比較して大幅に減少した。毛髪の損
傷もなく、しっかりウェーブもついた。There was no mercapto odor during or after the treatment, and the ammonia odor was significantly reduced compared to conventional products. There was no damage to the hair and the waves were well formed.

〔比較例〕[Comparative example]

・チオグリコール酸 アンモニウム（５０％）　　　　１３．０（重量％）・
強アンモニア水（２８％”）　　　１．３（〃）・エデ
ト酸ナトリウム　　　　０．１（〃）・精製水　　　　
　　　　　８５．６　（〃）上記組成のコールドウェー
ブ第１剤で毛髪を室温にて１５分間処理後、第２剤（臭
素酸ナトリウム６．５％）にて室温で１５分間処理後、
水洗した。毛髪が水ぬれの状態ではもちろんのこと、乾
燥後もメルカプト臭およびアンモニア臭が強かった。・Ammonium thioglycolate (50%) 13.0 (wt%)・
Strong ammonia water (28%) 1.3 (〃)・Sodium edetate 0.1 (〃)・Purified water
85.6 (〃) After treating the hair with the first cold wave agent of the above composition for 15 minutes at room temperature, and after treating the hair with the second agent (6.5% sodium bromate) at room temperature for 15 minutes,
Washed with water. The mercapto odor and ammonia odor were strong not only when the hair was wet, but also after drying.

「発明の効果」 少量の酵母分離液を添加した本発明のコールドウェーブ
第１剤を使用することにより、パーマ施術中および後の
強烈なメルカプト臭を完全に除去出来、又アンモニア臭
も大幅に減少出来、毛髪に損傷を与えることなく良好な
ウェーブをつけることが出来た。"Effects of the invention" By using the cold wave first agent of the present invention, which contains a small amount of yeast isolate, it is possible to completely eliminate the strong mercapto odor during and after the perm treatment, and the ammonia odor is also significantly reduced. I was able to create good waves without damaging my hair.

これは当分野待望の画期的な効果である。This is a long-awaited breakthrough effect in this field.

Claims (1)

【特許請求の範囲】[Claims] チオグリコール酸アンモニウム及びアルカリを主成分と
するコールドウェーブ第１剤に糖醗酵液である酵母分離
液を添加したことを特徴とするコールドウェーブ第１剤
。A cold wave first agent, which is characterized in that a yeast separation liquid, which is a sugar fermentation liquid, is added to a cold wave first agent whose main components are ammonium thioglycolate and an alkali.