JPS6147796A - Production of emulsifying nucleus for emulsion fuel of water-in-oil type - Google Patents
Production of emulsifying nucleus for emulsion fuel of water-in-oil typeInfo
- Publication number
- JPS6147796A JPS6147796A JP59169959A JP16995984A JPS6147796A JP S6147796 A JPS6147796 A JP S6147796A JP 59169959 A JP59169959 A JP 59169959A JP 16995984 A JP16995984 A JP 16995984A JP S6147796 A JPS6147796 A JP S6147796A
- Authority
- JP
- Japan
- Prior art keywords
- water
- emulsion
- emulsifying
- fuel oil
- nucleus
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/32—Liquid carbonaceous fuels consisting of coal-oil suspensions or aqueous emulsions or oil emulsions
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Liquid Carbonaceous Fuels (AREA)
- Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
- Colloid Chemistry (AREA)
Abstract
Description
【発明の詳細な説明】
本発明は石油燃料（ＩＩ重質油び重質油）と水との極め
て安定した乳化状態の長期間（２ケ年以上）油と水が再
分離しない油中水滴Ｉｔ （Ｗｌｏ） １１エマルジ四
ン燃料を作る丸めの乳化核の製造方法に関するものであ
る。DETAILED DESCRIPTION OF THE INVENTION The present invention provides water droplets in oil in which petroleum fuel (II heavy oil and heavy oil) and water remain in an extremely stable emulsified state for a long period of time (2 years or more) without re-separation of oil and water. It (Wlo) 11 relates to a method for producing rounded emulsion nuclei for producing emulsion fuel.
また本発明は石油燃料（軽質油及び重質油共）の燃焼時
に発生する大量の有毒ガスやばいじんの発生を大幅に減
少させて公害を防止すると共に完全燃焼による燃焼効率
の改善で省エネルギー効果を社かることを目的とするも
のである。In addition, the present invention significantly reduces the generation of large amounts of toxic gas and dust generated when petroleum fuels (both light oil and heavy oil) are burned, thereby preventing pollution, and improving combustion efficiency through complete combustion, resulting in energy saving effects. The purpose is to help the company.
従来のエマルジ璽ン燃料は、乳化剤としてモノエタノー
ルアミン、トリエタノールアミン、オレイン酸、脂肪族
スルホン酸塩、アルコニル脂肪駿エステル等その他の薬
剤が使用されているが、これらの薬剤は高価な九め製造
コストが高く、またこれらの薬剤を添加混合して製造し
たエマルジ璽ン燃料は乳化状態が不安定で成虫後短時間
に油と水が再分離をおこすため乳化装置を燃焼機器に付
設して乳化と同時に燃焼を行なわねばならず、燃料自体
としての貯鼠管理は不可能であり、乳化装置についての
燃焼技術や高価な乳化装置等一般中小企業の消費者には
経済的なメリットが少いものが多い。Conventional emulsion fuels use other chemicals such as monoethanolamine, triethanolamine, oleic acid, aliphatic sulfonates, and alconyl fatty acid esters as emulsifiers, but these chemicals are expensive and expensive. The production cost is high, and the emulsion fuel produced by adding and mixing these chemicals has an unstable emulsification state, and the oil and water will re-separate within a short time after the insects become adults, so an emulsifier is attached to the combustion equipment. Combustion must be carried out at the same time as emulsification, and storage management as a fuel itself is impossible, and the combustion technology for emulsifiers and expensive emulsifiers have little economic benefit for consumers in small and medium-sized enterprises. There are many things.
本発明は上記のような欠点を抜本的に解決し、均一分散
の安定した乳化状態により長期間（２ケ年以上）油と水
が再分離しないので純石油燃料と同様に貯蔵管理が出来
、油タンクに入れたままで在来の燃焼機器で使用するた
め高価な乳化装置や・特別な燃焼技術を必要としない。The present invention fundamentally solves the above-mentioned drawbacks, and because oil and water do not separate again for a long period of time (more than 2 years) due to the stable emulsified state of uniform dispersion, it can be stored and managed in the same way as pure petroleum fuel. Because it can be used with conventional combustion equipment while still in the oil tank, there is no need for expensive emulsification equipment or special combustion technology.
即ち、本発明の乳化核を作るのに
（１）Ａ重油・・・・・・・・・・・・ ５０ｄ以上１
０〇−（２）Ｂ重油・・・・・・・・・・・・１００ｄ
以上２０〇−（３）Ｃ重油・・・・・・・・・・・・３
０〇−以上４５０ｍ（４）メタノール・・・・・・１０
０−以上１５〇−（５）デキストリン・・・・・２００
ｆ以上３００ｔ（６）水・・・・・・・・・・・・・・
・・・・・・・全容量が１０００ｍになるまでの残量上
記の各成分のうち、先Ｋ ％ （１） ＃ （２）、
（３）、 （４）、の成分を一攪拌混合した全容量に、
（５）と（６）の成分を混合溶解させた溶液を加え、高
速攪拌機（毎回３０００回転以上）で１０分間攪拌混合
して本発明の乳化核を製造する。That is, to make the emulsion core of the present invention, (1) A heavy oil... 50d or more 1
0〇-(2) B heavy oil・・・・・・・・・100d
Above 20〇-(3) C heavy oil・・・・・・・・・・・・3
0〇- or more 450m (4) Methanol・・・10
0- or more 150-(5) Dextrin...200
f or more 300t (6) Water・・・・・・・・・・・・・・・
・・・・・・Remaining capacity until the total capacity reaches 1000 m Among the above components, the first K % (1) # (2),
To the total volume of the ingredients (3) and (4) mixed together,
A solution obtained by mixing and dissolving the components (5) and (6) is added, and the mixture is stirred and mixed for 10 minutes using a high-speed stirrer (3000 revolutions or more each time) to produce the emulsion core of the present invention.
このようにして製造した乳化核は超微粒化（０，５ミク
ロン〜１ミクロン）し均一分散した乳化状態にあり、こ
の乳化核を石油燃料と水に添加して攪拌混合すると乳化
核は四散し二次微粒化現象をおこし極微粒子の均一分散
の安定したエマルジョン燃料が得られる。The emulsion nuclei produced in this way are ultra-fine (0.5 to 1 micron) and are in a uniformly dispersed emulsified state. When these emulsion nuclei are added to petroleum fuel and water and mixed with stirring, the emulsion nuclei are dispersed. By causing the secondary atomization phenomenon, a stable emulsion fuel with uniformly dispersed ultrafine particles can be obtained.
本発明を詳しく述べると、軽質石油燃料（軽油、灯油、
Ａ重油）と水の容量比を油９０％〜６５チ、水１０チ〜
３５チの比率からなる合計量に本発明の乳化核を１００
０分の１０以上１０００分の３０を添加混合して均一分
散の安定した乳化状態の軽質石油エマルジョン燃料を製
造し、また重質石油燃料（Ｂ重油、Ｃ重油）と水の容量
比を９０９６〜６０チ、熱水（７０℃以上９０℃）１０
チ〜４０チの比率からなる合計量に本発明の乳化核を１
０００分の２以上１０００分の１０を添加混合して長期
間再分離しない均一分散の乳化状態の安定した重質石油
エマルジョン燃料を製造する。To describe the present invention in detail, light petroleum fuels (diesel oil, kerosene,
A heavy oil) and water volume ratio: 90% oil ~ 65 cm, water 10 cm ~
The emulsifying core of the present invention is added to a total amount of 100% of the total amount consisting of a ratio of 35%
A light petroleum emulsion fuel in a uniformly dispersed and stable emulsified state is produced by adding and mixing 10/10 to 30/1000, and the volume ratio of heavy petroleum fuel (B heavy oil, C heavy oil) to water is 9096 to 9096. 60 degrees, hot water (70 degrees Celsius or more 90 degrees Celsius) 10
1 emulsifying nucleus of the present invention is added to the total amount consisting of a ratio of 1 to 40
By adding and mixing 2/1,000 to 10,000, a heavy petroleum emulsion fuel with a uniformly dispersed emulsified state that does not separate again for a long period of time and is stable is produced.
本発明の乳化核を使用して製造した石油燃料（軽質油及
び重質油共）エマルジョン燃料は油中に極微粒子の水が
均一に分散し安定した乳化状態であるため燃焼安定性が
良く完全燃焼するので未燃焼分の燃焼や排気ガスのスス
の消失等燃焼効率の改善向上による省エネルギーがはか
れるばかりでなく窒素酸化物やばいじん等有毒排気物の
発生を大幅に減少させ公害肪止の効果が大きい。The petroleum fuel (both light oil and heavy oil) produced using the emulsifying core of the present invention has extremely fine water particles dispersed uniformly in the oil and is in a stable emulsified state, resulting in good combustion stability and complete combustion. Because it burns, it not only saves energy by improving combustion efficiency by burning unburned parts and eliminating soot from exhaust gas, but also significantly reduces the generation of toxic exhaust such as nitrogen oxides and soot, and has the effect of reducing pollution. big.
また従来の乳化剤にくらべて著しく安価であることも経
済的に大きなメリットである。 −最後に本発明の
乳化核により製造し＆Ａ重重油エマルジノン燃料Ｂ重油
エマルジョン燃料及びＣ重油エマルジョン燃料の燃焼実
験を実施した新水のような結果を得た。Furthermore, it is a great economic advantage that it is significantly cheaper than conventional emulsifiers. -Finally, a combustion experiment was conducted on &A heavy oil emulsion fuel, B heavy oil emulsion fuel, and C heavy oil emulsion fuel produced using the emulsifying core of the present invention, and similar results were obtained.
以 下 余 白
表２ 燃料消費量及び乳化剤単価の比較差に＠線状態上
記の表１は本発明の乳化核を使用したＡ重油、Ｂ重油、
Ｃ重油の各エマルジョン燃料の燃焼時における窒素酸化
物及びばいじんの発生量を市販の他のエマルジョン燃料
と比較したもので窒素酸化物はＡ重声エマルジ、ン燃料
が６０’ｊ％Ｂ重油エマルジ冒ン燃料が４４チ、Ｃ重油
エマルジ、ン燃料がｓｓ％発生量が少く、またばいじん
発生量はＡ重油エマルジ、ン燃料が５２チ、Ｂ重油エマ
ルジ、ン燃料が９３チ、０重油エマルジョン燃料が７２
％発生量カ少く市販の他のエマルジョン燃料と比較して
本発明の乳化核によるエマルジョン燃料の公害貼止の効
果が如何に大きいかが確認され良。Table 2 shows the comparative differences in fuel consumption and emulsifier unit price.
The amount of nitrogen oxides and soot generated during combustion of each C heavy oil emulsion fuel is compared with other emulsion fuels on the market. The amount of soot and dust generated is 44 inches for A heavy oil emulsion, 93 inches for B heavy oil emulsion, and 93 inches for 0 heavy oil emulsion fuel. 72
It can be confirmed how much more effective the emulsion fuel is in terms of preventing pollution due to the emulsion nuclei of the present invention compared to other commercially available emulsion fuels which have a smaller amount of generation.
（註）分析方法
（１）窒素酸化物濃度は ＪＩＳＫＯ１０４（２）ばい
じん濃度は ＪＩ８Ｚ８８６８上記の表２は、３重油
エマルジョン燃料、Ｃ重油エマルジ、ン燃料共風呂屋の
温水ボイラーで１週間連続して燃焼し実測した結果であ
り省エネルギー効果が大きい。(Note) Analysis method (1) Nitrogen oxide concentration is JISKO104 (2) Soot and dust concentration is JI8Z8868 The above Table 2 shows the results for one week in a row using triple fuel oil emulsion fuel, C heavy oil emulsion fuel, and a hot water boiler at a public bath house. This is the result of actual measurements during combustion, and the energy saving effect is significant.
従来からエマルジョン燃料によって各種の効果（省エネ
ルギー排ガス清浄化など）があると１われているがトラ
ブルなく最大の効果を発揮するには優れた安定のエマル
ジョン燃料をつくることである。本発明の乳化核を使用
することにより極微粒化した均一分散の安定した乳化状
態の各油種別エマルジョン燃料が得られ、従来のエマル
ジョン燃料で社不可能でありた長期間の貯薦が出来るよ
うになり、そのため−焼機器に付設して使用する乳化装
置も必要がなく純石油燃料同様に在来の燃焼機器で使用
することが出来るようになった。ま。It has been said that emulsion fuel has various effects (such as energy saving and purification of exhaust gas), but in order to achieve the maximum effect without trouble, it is necessary to create an emulsion fuel that is excellent and stable. By using the emulsifying core of the present invention, it is possible to obtain emulsion fuel for each oil type in a stable emulsified state with ultra-fine particles and uniform dispersion, making it possible to store it for a long period of time, which was not possible with conventional emulsion fuels. Therefore, there is no need for an emulsifying device attached to combustion equipment, and it can now be used in conventional combustion equipment in the same way as pure petroleum fuel. Ma.
たエマルジョン燃料の本来の目的である省エネル頓−効
果と公害防止の効果においても本発明の乳托核を使用す
る２とＫより十分に満すことが出来特許出顯人 羅
鍾 ９即The original purpose of the emulsion fuel, energy saving effect and pollution prevention effect, can be more fully met than in 2 and K using the milk spores of the present invention, and the patent has been issued.
Zhong 9 immediately
Claims (1)
核の製造方法 乳化核１０００ｍｌを作るのに （１）Ａ重油・・・・・・・・・・・・５０ｍｌ以上１
００ｍｌ（２）Ｂ重油・・・・・・・・・・・・１００
ｍｌ以上２００ｍｌ（３）Ｃ重油・・・・・・・・・・
・・３００ｍｌ以上４５０ｍｌ（４）メタノール・・・
・・・１００ｍｌ以上１５０ｍｌ（５）デキストリン・
・・・・・２００ｇ以上３００ｇ（６）水・・・・・・
・・・・・・・・・・・・全容量が１０００ｍｌになる
までの残量[Claims] Method for producing emulsion cores for water-in-oil emulsion fuel consisting of the following components To make 1000ml of emulsion cores: (1) Heavy oil A...50ml or more1
00ml (2) B heavy oil・・・・・・・・・100
ml or more 200ml (3) C heavy oil...
...300ml or more 450ml (4) Methanol...
...100ml or more 150ml (5) Dextrin・
...200g or more 300g (6) Water...
・・・・・・・・・Remaining amount until the total capacity reaches 1000ml
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP59169959A JPS6147796A (en) | 1984-08-16 | 1984-08-16 | Production of emulsifying nucleus for emulsion fuel of water-in-oil type |
| KR1019840007621A KR860001870A (en) | 1984-08-16 | 1984-12-03 | Process for preparing emulsified nuclei for water-in-oil (W / O / type) emulsion zone fuels |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP59169959A JPS6147796A (en) | 1984-08-16 | 1984-08-16 | Production of emulsifying nucleus for emulsion fuel of water-in-oil type |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6147796A true JPS6147796A (en) | 1986-03-08 |
| JPH0471118B2 JPH0471118B2 (en) | 1992-11-12 |
Family
ID=15896003
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP59169959A Granted JPS6147796A (en) | 1984-08-16 | 1984-08-16 | Production of emulsifying nucleus for emulsion fuel of water-in-oil type |
Country Status (2)
| Country | Link |
|---|---|
| JP (1) | JPS6147796A (en) |
| KR (1) | KR860001870A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6330593A (en) * | 1986-07-24 | 1988-02-09 | Kotobuki Senpaku Shoji:Kk | Method of reforming fuel oil |
| WO2010086908A1 (en) * | 2009-01-30 | 2010-08-05 | Inazawa Susumu | Emulsifier for water-in-oil emulsion fuel |
| WO2011089698A1 (en) * | 2010-01-21 | 2011-07-28 | ナノマイザー株式会社 | Emulsified fuel and method for producing the same |
| WO2017006920A1 (en) * | 2015-07-08 | 2017-01-12 | 株式会社シクロケム | Liquid fuel and method for producing same |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS555800A (en) * | 1978-06-29 | 1980-01-16 | Catalyse Soc Prod Francais | New catalyst for improving change into contact hydrogen and for forming aromatic hydrocarbon and its use |
| JPS5839878A (en) * | 1981-08-31 | 1983-03-08 | Aisin Warner Ltd | Oil pressure regulating device in stepless automatic speed change gear for car |
-
1984
- 1984-08-16 JP JP59169959A patent/JPS6147796A/en active Granted
- 1984-12-03 KR KR1019840007621A patent/KR860001870A/en not_active Application Discontinuation
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS555800A (en) * | 1978-06-29 | 1980-01-16 | Catalyse Soc Prod Francais | New catalyst for improving change into contact hydrogen and for forming aromatic hydrocarbon and its use |
| JPS5839878A (en) * | 1981-08-31 | 1983-03-08 | Aisin Warner Ltd | Oil pressure regulating device in stepless automatic speed change gear for car |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6330593A (en) * | 1986-07-24 | 1988-02-09 | Kotobuki Senpaku Shoji:Kk | Method of reforming fuel oil |
| WO2010086908A1 (en) * | 2009-01-30 | 2010-08-05 | Inazawa Susumu | Emulsifier for water-in-oil emulsion fuel |
| US8882860B2 (en) | 2009-01-30 | 2014-11-11 | Susumu Inazawa | Emulsifier for water-in-oil emulsion fuel |
| WO2011089698A1 (en) * | 2010-01-21 | 2011-07-28 | ナノマイザー株式会社 | Emulsified fuel and method for producing the same |
| WO2017006920A1 (en) * | 2015-07-08 | 2017-01-12 | 株式会社シクロケム | Liquid fuel and method for producing same |
Also Published As
| Publication number | Publication date |
|---|---|
| KR860001870A (en) | 1986-03-24 |
| JPH0471118B2 (en) | 1992-11-12 |
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