JPS6144996B2 - - Google Patents
Info
- Publication number
- JPS6144996B2 JPS6144996B2 JP55047065A JP4706580A JPS6144996B2 JP S6144996 B2 JPS6144996 B2 JP S6144996B2 JP 55047065 A JP55047065 A JP 55047065A JP 4706580 A JP4706580 A JP 4706580A JP S6144996 B2 JPS6144996 B2 JP S6144996B2
- Authority
- JP
- Japan
- Prior art keywords
- pattern
- sol
- base sheet
- flooring material
- resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000011347 resin Substances 0.000 claims description 41
- 229920005989 resin Polymers 0.000 claims description 41
- 238000009408 flooring Methods 0.000 claims description 29
- 239000000463 material Substances 0.000 claims description 28
- 238000004519 manufacturing process Methods 0.000 claims description 15
- 239000011120 plywood Substances 0.000 claims description 14
- 238000007639 printing Methods 0.000 claims description 14
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 13
- 239000004800 polyvinyl chloride Substances 0.000 claims description 13
- 239000000853 adhesive Substances 0.000 claims description 8
- 230000001070 adhesive effect Effects 0.000 claims description 8
- 239000006260 foam Substances 0.000 claims description 6
- 239000010425 asbestos Substances 0.000 claims description 2
- 239000003365 glass fiber Substances 0.000 claims description 2
- 229910052895 riebeckite Inorganic materials 0.000 claims description 2
- 239000001038 titanium pigment Substances 0.000 claims description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 2
- 229920002554 vinyl polymer Polymers 0.000 claims description 2
- 238000000034 method Methods 0.000 description 36
- 238000005187 foaming Methods 0.000 description 17
- 239000010410 layer Substances 0.000 description 16
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 8
- 238000000576 coating method Methods 0.000 description 6
- 238000010438 heat treatment Methods 0.000 description 6
- 239000003981 vehicle Substances 0.000 description 5
- 239000011248 coating agent Substances 0.000 description 4
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 239000004604 Blowing Agent Substances 0.000 description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 3
- 239000004745 nonwoven fabric Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 235000010215 titanium dioxide Nutrition 0.000 description 3
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 239000008096 xylene Substances 0.000 description 2
- 239000004156 Azodicarbonamide Substances 0.000 description 1
- 239000004606 Fillers/Extenders Substances 0.000 description 1
- XOZUGNYVDXMRKW-AATRIKPKSA-N azodicarbonamide Chemical compound NC(=O)\N=N\C(N)=O XOZUGNYVDXMRKW-AATRIKPKSA-N 0.000 description 1
- 235000019399 azodicarbonamide Nutrition 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- VJRITMATACIYAF-UHFFFAOYSA-N benzenesulfonohydrazide Chemical compound NNS(=O)(=O)C1=CC=CC=C1 VJRITMATACIYAF-UHFFFAOYSA-N 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000008602 contraction Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000007766 curtain coating Methods 0.000 description 1
- 230000032798 delamination Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000004049 embossing Methods 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000004088 foaming agent Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000007646 gravure printing Methods 0.000 description 1
- 229940042795 hydrazides for tuberculosis treatment Drugs 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 239000004005 microsphere Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 125000000018 nitroso group Chemical group N(=O)* 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229940088417 precipitated calcium carbonate Drugs 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000007650 screen-printing Methods 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 230000001360 synchronised effect Effects 0.000 description 1
- 238000010345 tape casting Methods 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 239000000052 vinegar Substances 0.000 description 1
- 235000021419 vinegar Nutrition 0.000 description 1
Landscapes
- Laminated Bodies (AREA)
- Floor Finish (AREA)
- Thermal Transfer Or Thermal Recording In General (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
Description
【発明の詳細な説明】
本発明は、床材の製造法に係わり、さらに詳し
くは耐熱性を有する含浸性のある基体シートは少
なくとも一部分が発泡インキよりなる絵柄を設け
た後、透明塩ビゾルを塗布ししかる後加熱して発
泡インキを発泡させると共に透明塩ビゾルをゲル
化させる工程よりなる床材の製造法およびこれに
より得られた床材を実（さね）加工した合板に貼
着する合板貼りの床材の製造法に関し、その目的
とするところは従来の方法に比べ著しく簡易に安
価な同調凹凸床材を供給する事にある。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a method for manufacturing flooring materials, and more specifically, the present invention relates to a method for manufacturing flooring materials, and more specifically, a heat-resistant and impregnable base sheet is coated with transparent vinyl chloride sol after a pattern is formed, at least a portion of which is made of foamed ink. A method for manufacturing a flooring material comprising a step of applying and then heating to foam the foaming ink and gelatinize the transparent PVC sol, and a plywood in which the flooring material obtained by this method is attached to a rabbeted plywood. The purpose of the method for manufacturing laminate flooring is to provide a symmetrical uneven flooring that is significantly simpler and cheaper than conventional methods.
従来、同調凹凸床材の製造法としては大別して
次のような方法がある。 Conventionally, there are the following methods for manufacturing synchronous uneven flooring materials.
(1) 基体シートに発泡性樹脂層を設け、該表面に
発泡性樹脂の発泡を促進およびあるいは抑制さ
せるインキにて印刷した後発泡する方法、
(2) 基体シートに発泡性樹脂および硬化性樹脂か
らなる樹脂層を設け、該表面に硬化性樹脂の硬
化を促進およびあるいは抑制するインキにて印
刷した後発泡する方法、
(3) 基体シートに発泡性樹脂層を設け、該表面に
侵透性のある硬化性樹脂インキにて印刷した後
浸透硬化させしかる後発泡する方法、
(4) 基体シートに発泡性樹脂層を設け、該表面に
熱吸収インキ、比熱の大きいインキにて印刷し
た後、場合によつては熱線を照射しながら発泡
する方法、
(5) 基体シートに発泡性樹脂層を設け、力学的ひ
ずみ与えながら発泡する方法、
(6) 基体シートに樹脂層を設け、発泡インキにて
シルクスクリーン印刷し、さらにその上に透明
樹脂層を設け、しかる後発泡する方法、及び
(7) 基体シートに樹脂層を設け、盛上げインキに
て印刷しさらにその上に透明樹脂層を設ける方
法である。(1) A method in which a foamable resin layer is provided on a base sheet, and the surface is printed with an ink that promotes and/or suppresses foaming of the foamable resin, and then foamed; (2) A method in which a foamable resin and a curable resin are provided on the base sheet. (3) A method in which a foamable resin layer is provided on a base sheet, and the surface is printed with an ink that promotes and/or suppresses the curing of the curable resin, and then foamed. (4) A method in which a foamable resin layer is provided on the base sheet, and the surface is printed with a heat-absorbing ink, an ink with a large specific heat, (5) A method in which a foamable resin layer is provided on a base sheet and foaming is performed while applying mechanical strain; (6) A method in which a resin layer is provided on a base sheet and foamed ink is (7) A method of providing a resin layer on a base sheet, printing with a raised ink, and further providing a transparent resin layer on top of it. It is.
これらの方法は、それぞれ別工程として透明樹
脂層を表面保護層として設ける工程を後工程ある
いは中間工程として有している。 These methods each have a step of providing a transparent resin layer as a surface protective layer as a separate step or as an intermediate step.
しかし、これらの方法では以下のような欠点が
ある。 However, these methods have the following drawbacks.
すなわち(1)の方法では促進抑制インキのライフ
が短かく生産安定性に欠け、(2)の方法では未硬化
樹脂のべとつきや有毒性が問題となり、(3)の方法
では硬化性樹脂インキの乾燥性が欠如し生産スピ
ードを著しく阻害する。また(4)の方法では多大な
熱量を必要とし、(5)の方法ではシヤープなエンボ
スが不可能である。６，７の方法では前記方法に
比べ簡易であり安価な床材を供給することが可能
であるが、後工程で設けられる透明樹脂層が(7)の
方法では盛り上げインキの凹凸効果を減少させる
し、いずれにしても基体シート上に予め樹脂層を
設ける工程を必要とする。本発明者は(6)の方法の
利点に注目し、含浸性のある基体シートを用い、
最上層に透明樹脂層を設ける工程によつて最初の
樹脂層を設ける工程を省略する方法を開発したも
のである。 In other words, in method (1), the life of the promotion-inhibiting ink is short and production stability is lacking, in method (2), there are problems with stickiness and toxicity of uncured resin, and in method (3), the life of the curable resin ink is poor. The lack of drying properties significantly impedes production speed. Furthermore, method (4) requires a large amount of heat, and method (5) makes it impossible to achieve sharp embossing. Methods 6 and 7 can provide flooring materials that are simpler and cheaper than the above methods, but in method (7), the transparent resin layer provided in the subsequent process reduces the unevenness effect of the raised ink. However, in any case, a step of previously providing a resin layer on the base sheet is required. The present inventor focused on the advantage of method (6), and used an impregnable base sheet,
A method has been developed in which the step of providing the first resin layer is omitted by providing the transparent resin layer as the top layer.
すなわち、本発明は耐熱性を有する含浸性のあ
る基体シートに絵柄を設けるに際し、該絵柄の全
部あるいは一部を発泡性樹脂をベヒクルとする印
刷インキ（以後、発泡インキという）によつて設
けた後、透明ポリ塩化ビニル樹脂からゾル（以
後、塩ビゾルという）を上記絵柄を含む全面に塗
布し、該ゾルを上記絵柄を通して基体シートに含
浸させ、しかる後加熱し、上記発泡インキを発泡
させると同時に前記塩ビゾルをゲル化させる工程
よりなる床材の製造法および該床材を実加工を施
した合板とチタン顔料を含む隠蔽性のある接着剤
を介して貼り合わせる工程よりなる合板貼りの床
材の製造法を要旨とするものである。 That is, in the present invention, when a pattern is provided on a heat-resistant and impregnable base sheet, the pattern is formed entirely or partially using a printing ink using a foamable resin as a vehicle (hereinafter referred to as foamed ink). After that, a sol (hereinafter referred to as vinyl chloride sol) made of transparent polyvinyl chloride resin is applied to the entire surface including the above-mentioned pattern, the sol is impregnated into the base sheet through the above-mentioned pattern, and then heated to foam the above-mentioned foamed ink. At the same time, a method for manufacturing a flooring material comprising a step of gelling the PVC sol, and a plywood flooring step comprising a step of bonding the flooring material to a processed plywood via a concealing adhesive containing titanium pigment. The gist is the manufacturing method of the material.
以下、図面を参照しながら本発明を詳細に説明
する。第１図示の如くまず第１に耐熱性を有する
含浸性のある基体シート１に発泡性樹脂をベヒク
ルとする発泡インキによる絵柄部分２ａと非発泡
性樹脂層をベヒクルとする印刷インキによる絵柄
部分２ｂを設ける。耐熱性を有する含浸性のある
基体シート１とは後から塗布される透明塩ビゾル
３を含浸し、しかも印刷インキの転移性を考慮し
適度な透気度と平滑性を有する基体シートを選択
する。 Hereinafter, the present invention will be explained in detail with reference to the drawings. As shown in the first diagram, first, a pattern part 2a is formed by foaming ink using a foamable resin as a vehicle on a heat-resistant and impregnable base sheet 1, and a pattern part 2b is formed by printing ink using a non-foaming resin layer as a vehicle. will be established. The heat-resistant and impregnated base sheet 1 is a base sheet that is impregnated with the transparent vinyl chloride sol 3 that will be applied later, and that has appropriate air permeability and smoothness in consideration of the transferability of printing ink. .
基体シートとしては紙、ガラス不織布、ポリエ
ステル不織布、などが使用できるが、印刷適性お
よび加工時の寸法安定性を考えるとアスベストあ
るいはガラス繊維を５〜50％含有した30〜100
ｇ／m2の混抄紙が好適である。また、ポリエステ
ル不織布は寸法安定性に欠けるが、多少の伸縮が
あつても問題のない柄を使用すれば40〜100ｇ／
m2のものが好適である。尚、これらの含浸性のあ
る基体シートを使用した場合、含浸性のない基体
シートを使用する場合に比べ、発泡インキ中の溶
剤の拡散があるため少量の乾燥により印刷済基体
シートを巻取れる利点もある。 Paper, glass nonwoven fabric, polyester nonwoven fabric, etc. can be used as the base sheet, but considering printability and dimensional stability during processing, 30 to 100 sheets containing asbestos or glass fiber at 5 to 50% can be used.
g/m 2 mixed paper is preferred. Also, polyester nonwoven fabric lacks dimensional stability, but if you use a pattern that does not cause problems even if it has some expansion and contraction, it will weigh 40 to 100 g/
m2 is preferred. Furthermore, when using these impregnating base sheets, compared to using non-impregnating base sheets, there is an advantage that the printed base sheet can be rolled up with a small amount of drying due to the diffusion of the solvent in the foamed ink. There is also.
絵柄２ａを構成する発泡インキは、マイクロス
フエアを使用した低温発泡型インキあるいは樹脂
ゾル中に発泡剤を混入した高温発泡型インキが使
用できるが、用途、および加工法を考えると後者
が望ましい。発泡インキを構成する樹脂として
は、後から塗布される塩ビゾルとの密着性を考
え、ポリ塩化ビニル樹脂およびその誘導体あるい
は他の樹脂との混合物あるいは共重合体が望まし
い。また発泡剤としてはベンゼンスルフオニルヒ
ドラジドなどのヒドラジド系；アゾジカルボンア
ミドなどのアゾ系；ジニトロソペンタテトラミン
などのニトロソ系；あるいは炭酸水素ナトリウム
などの無機発泡剤などが用いられ、該発泡剤を樹
脂100部（重量基準、以下同じ）に対して３〜10
部加え、更に必要に応じてジオクチルフタレート
（DOP）、ジブチルフタレート（DBP）などの可
塑剤０〜50部、その他に発泡助剤、チタン白など
の着色剤、安定剤、充填剤などを加えてなる発泡
性樹脂にキシレン、ターベンなどの遅乾溶剤など
を加えて印刷に適した粘度とする。印刷に適した
粘度は2000〜3000cpsであるが、キシレンを加え
てなる発泡インキはインキ中の樹脂ゾルの経時的
増粘を引き起こしターベンを加えてなる発泡イン
キは乾燥性に欠けるため適宜分量を調節する。発
泡インキを設ける印刷手法としては、その塗布量
を考えシルクスクリーン印刷が最も望ましいが、
版深80〜150μ程度からなるグラビア方式によつ
ても可能である。また、場合によつてはフレキソ
方式、凸版方式、オフセツト方式なども使用でき
る。 As the foamed ink constituting the pattern 2a, a low-temperature foaming ink using microspheres or a high-temperature foaming ink containing a foaming agent in a resin sol can be used, but the latter is preferable considering the application and processing method. The resin constituting the foamed ink is preferably a polyvinyl chloride resin, its derivatives, or a mixture or copolymer with other resins, in view of its adhesion to the vinyl chloride sol applied later. As blowing agents, hydrazides such as benzenesulfonyl hydrazide; azos such as azodicarbonamide; nitrosos such as dinitrosopentatetramine; or inorganic blowing agents such as sodium bicarbonate are used. 3 to 10 parts per 100 parts of resin (based on weight, same below)
If necessary, add 0 to 50 parts of a plasticizer such as dioctyl phthalate (DOP) or dibutyl phthalate (DBP), a foaming aid, a coloring agent such as titanium white, a stabilizer, a filler, etc. A slow-drying solvent such as xylene or turbene is added to the foamable resin to create a viscosity suitable for printing. The suitable viscosity for printing is 2,000 to 3,000 cps, but foamed ink made by adding xylene causes the resin sol in the ink to thicken over time, and foamed ink made by adding turbene lacks drying properties, so adjust the amount accordingly. do. Silk screen printing is the most desirable printing method for applying foam ink, considering the amount of ink to be applied.
It is also possible to use a gravure method with a plate depth of about 80 to 150 μm. In some cases, a flexographic method, a letterpress method, an offset method, etc. can also be used.
非発泡性の絵柄２ｂを構成するインキは発泡イ
ンキと同様に透明塩ビゾルとの密着性を考えポリ
塩化ビニル樹脂系が望ましいが含浸性を考慮し造
膜性の少ない樹脂にすることが肝要である。造膜
性を減少させるにはベヒクル樹脂の重合度を低下
させたり、炭酸カルシウム、沈降性バリウム、ク
レイなどの体質顔料を加えることも可能である。
このような印刷済み基体シートの表面に透明塩ビ
ゾル３を50〜500ｇ／m2塗布するが、耐摩耗性、
作業性を考慮すると100〜200ｇ／m2が最も望まし
い。塗布方法としてはナイフコーテイング、フロ
ーコーテイング、カーテンコーテイング、バーコ
ーテイングなどの公知のコーテイング方式の他に
シルクスクリーンベタ版による印刷コーテイング
も可能である。 The ink constituting the non-foaming pattern 2b is preferably a polyvinyl chloride resin based in consideration of its adhesion to the transparent vinyl chloride sol, similar to the foaming ink, but it is important to consider impregnability and use a resin with low film-forming properties. be. To reduce film-forming properties, it is also possible to lower the degree of polymerization of the vehicle resin or to add extender pigments such as calcium carbonate, precipitated barium, and clay.
50 to 500 g/m 2 of transparent PVC sol 3 is applied to the surface of such a printed base sheet, but the wear resistance and
Considering workability, 100 to 200 g/m 2 is most desirable. As a coating method, in addition to known coating methods such as knife coating, flow coating, curtain coating, and bar coating, printing coating using a silk screen solid plate is also possible.
透明塩ビゾルをコーテイングした基体シート
は、そのまま巻取らず加熱炉中で透明塩ビゾルを
半ゲル化して巻取り、別に発泡工程を設けても良
いが工程の簡略さを考慮すると、加熱炉中で発泡
インキの発泡と同時に透明塩ビゾルのゲル化を行
なうのが良い。これらの条件は発泡剤と樹脂の性
質にもよるが、150℃〜250℃で１分〜３分が好ま
しい。ここで加熱のタイミングとしては、製品化
した場合の基体シートの層間剥離を防止するた
め、透明塩ビゾルが流動性を保ち含浸性のある基
体シートの裏面に到達したと同時にゲル化させる
のが好ましい。この流動性を得るため透明塩ビゾ
ル中の可塑性、溶剤などの量を調整する。このよ
うな加熱発泡と同時に上記ゾルをゲル化すること
により発泡インキ２ａが発泡した２a′となつた第
２図示の如き床材が得られる。このような床材の
製造法は印刷工程と塗布加熱工程の２工程により
なる簡易な製造法である。 The base sheet coated with transparent PVC sol may not be rolled up as it is, but the transparent PVC sol may be turned into a semi-gel in a heating furnace and rolled up, and a separate foaming process may be performed, but considering the simplicity of the process, it is recommended to It is preferable to gel the transparent vinyl chloride sol at the same time as foaming the foaming ink. These conditions depend on the properties of the blowing agent and resin, but are preferably 150°C to 250°C and 1 minute to 3 minutes. Regarding the timing of heating, in order to prevent delamination of the base sheet when it is commercialized, it is preferable to gel the transparent PVC sol at the same time as it reaches the back side of the base sheet, which maintains fluidity and is impregnable. . In order to obtain this fluidity, the plasticity and the amount of solvent in the transparent PVC sol are adjusted. By gelling the sol at the same time as heating and foaming, a floor material as shown in the second figure in which the foamed ink 2a becomes foamed 2a' can be obtained. The manufacturing method of such flooring material is a simple manufacturing method consisting of two steps: a printing step and a coating and heating step.
含浸性のある基体シートに透明塩ビゾルを含浸
すると基体シートは透明化し、絵柄のない部分は
隠蔽性に欠けるため、図示しないが隠蔽性のある
ベタ層を設けておく事も可能である。 When an impregnable base sheet is impregnated with a transparent PVC sol, the base sheet becomes transparent, and since areas without a pattern lack hiding properties, it is also possible to provide a solid layer with hiding properties, although not shown.
このようにして製造された床材はそのまま建築
物基材に貼合わせてあるいは置いて使用すること
も可能であるが、第３図示の如く実加工Ａ、Ｂを
施こした合板５に接着剤４を介して貼合わせ、合
板貼り床材としても使用できる。本発明の床材は
コスト、仕様等から特に合板貼り床材としての用
途に向いている。合板貼り床材として使用すれ
ば、前述した隠蔽性のあるベタ層を設けなくとも
チタン白などのチタン顔料のような隠蔽性のある
顔料を含有する接着剤４によつて合板に貼合わせ
ることにより上記ベタ印刷工程を省略することが
できる。 The flooring material manufactured in this way can be used as is by being attached to or placed on a building base material, but as shown in the third figure, adhesive is applied to the plywood 5 which has been subjected to actual processing A and B. It can also be used as a plywood flooring material by laminating it through 4. The flooring material of the present invention is particularly suitable for use as a plywood flooring material due to cost, specifications, etc. If used as a plywood flooring material, it can be bonded to plywood using an adhesive 4 containing a concealing pigment such as titanium white, without providing the solid layer with concealing properties as described above. The solid printing step described above can be omitted.
以下、実施例を示して本発明を具体的に説明す
る。 Hereinafter, the present invention will be specifically explained with reference to Examples.
＜実施例 １＞
ガラス混抄紙（阿波製紙社製TA−60）にポリ
塩化ビニル樹脂をベヒクルとするインキ（諸星イ
ンキ社製VTP）を用いてグラビア印刷により非
発泡絵柄部分を設け、発泡インキ（大日精化社製
LVS−９）によつて発泡絵柄部分を設け120℃で
30秒乾燥した。しかる後、透明塩ビゾル（日本ビ
オン社製ゼオン121）を100ｇ／m2塗布し、ゾルが
ガラス混抄紙の裏面に達した時に加熱炉で200℃
において１分40秒加熱したところ、絵柄と同調し
た発泡凹凸床材を得た。<Example 1> A non-foamed pattern was provided on a glass-mixed paper (TA-60 manufactured by Awa Paper Co., Ltd.) by gravure printing using an ink using polyvinyl chloride resin as a vehicle (VTP manufactured by Moroboshi Ink Co., Ltd.), Manufactured by Dainichiseika Co., Ltd.
A foam pattern was created using LVS-9) at 120℃.
Dry for 30 seconds. After that, 100g/ m2 of transparent vinyl chloride sol (Zeon 121 manufactured by Nippon Bion Co., Ltd.) was applied, and when the sol reached the back side of the glass-mixed paper, it was heated to 200℃ in a heating furnace.
When heated for 1 minute and 40 seconds, a foamed uneven flooring material that matched the pattern was obtained.
＜実施例 ２＞
塩酢ビエマルジヨン接着剤（中央理化社製BA
−620）にチタン白を10％加えてなる接着剤を用
いて実施例１に得られた床材を、実加工した合板
（20m／ｍ厚）と貼合わせて、合板貼り床材を得
た。<Example 2> Salt and vinegar vinyl emulsion adhesive (BA manufactured by Chuo Rika Co., Ltd.)
The flooring material obtained in Example 1 was laminated with actual processed plywood (20m/m thick) using an adhesive made by adding 10% titanium white to (620) to obtain a plywood-bonded flooring material. .
第１図は本発明の方法における発泡前の床材中
間製品を模式的に示す断面図、第２図及び第３図
は本発明の方法により得られる床材を模式的に示
す断面図である。
１……含浸性のある基体シート、２ａ……発泡
インキ、２ｂ……非発泡インキ、３……透明塩ビ
ゾル、４……接着剤、５……合板。
FIG. 1 is a cross-sectional view schematically showing an intermediate flooring product before foaming in the method of the present invention, and FIGS. 2 and 3 are cross-sectional views schematically showing the flooring material obtained by the method of the present invention. . DESCRIPTION OF SYMBOLS 1... Impregnating base sheet, 2a... Foaming ink, 2b... Non-foaming ink, 3... Transparent vinyl chloride sol, 4... Adhesive, 5... Plywood.
Claims (1)
柄を設けるに際し、該絵柄の全部あるいは一部を
発泡性樹脂をベヒクルとする印刷インキによつて
設けた後、透明ポリ塩化ビニル樹脂からなるゾル
を上記絵柄を含む全面に塗布し、該ゾルを上記絵
柄を通して基体シートに含浸させ、しかる後加熱
し上記発泡性樹脂をベヒクルとする印刷インキを
発泡させると同時に上記ゾルをゲル化させること
を特徴とする床材の製造法。 ２ 前記耐熱性を有する含浸性のある基体シート
がアスベストあるいはガラス繊維の混抄紙である
特許請求の範囲第１項記載の床材の製造法。 ３ 耐熱性を有する含浸性のある基体シートに絵
柄を設けるに際し、該絵柄の全部あるいは一部を
発泡性樹脂をベヒクルとする印刷インキによつて
設けた後、透明ポリ塩化ビニル樹脂からなるゾル
を上記絵柄を含む全面に塗布し、該ゾルを上記絵
柄を通して基体シートに含浸させ、しかる後加熱
し上記発泡性樹脂をベヒクルとする印刷インキを
発泡させると同時に上記ゾルをゲル化させて床材
を作成し、しかる後該床材の非絵柄面を接着剤を
介して、実加工を施した合板に貼り合わせること
を特徴とする合板貼りの床材の製造法。 ４ 前記接着剤が、チタン顔料を含み隠蔽性を有
するものである特許請求の範囲第３項記載の床材
の製造法。[Scope of Claims] 1. When a pattern is provided on a heat-resistant, impregnable base sheet, the pattern is provided in whole or in part with a printing ink using a foamable resin as a vehicle, and then a transparent polychloride resin is applied. A sol made of vinyl resin is applied to the entire surface including the above-mentioned pattern, the sol is impregnated into the base sheet through the above-mentioned pattern, and then heated to foam the printing ink using the above-mentioned foamable resin as a vehicle, while at the same time turning the sol into a gel. A manufacturing method for flooring materials characterized by the following: 2. The method for producing a flooring material according to claim 1, wherein the heat-resistant and impregnable base sheet is a paper mixed with asbestos or glass fiber. 3. When forming a pattern on a heat-resistant, impregnable base sheet, after all or part of the pattern is formed using printing ink using a foamable resin as a vehicle, a sol made of transparent polyvinyl chloride resin is applied. The sol is applied to the entire surface including the pattern, impregnated into the base sheet through the pattern, and then heated to foam the printing ink using the foamable resin as a vehicle and at the same time gel the sol to form the flooring material. A method for producing a plywood flooring material, which comprises creating a plywood flooring material, and then bonding the non-patterned surface of the flooring material to processed plywood via an adhesive. 4. The method for producing a flooring material according to claim 3, wherein the adhesive contains a titanium pigment and has concealing properties.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4706580A JPS56144773A (en) | 1980-04-10 | 1980-04-10 | Production of floor material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4706580A JPS56144773A (en) | 1980-04-10 | 1980-04-10 | Production of floor material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS56144773A JPS56144773A (en) | 1981-11-11 |
| JPS6144996B2 true JPS6144996B2 (en) | 1986-10-06 |
Family
ID=12764750
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP4706580A Granted JPS56144773A (en) | 1980-04-10 | 1980-04-10 | Production of floor material |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS56144773A (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS58163240U (en) * | 1982-04-23 | 1983-10-31 | 凸版印刷株式会社 | laminate flooring |
| JPS5948935U (en) * | 1982-09-22 | 1984-03-31 | ロンシール工業株式会社 | decorative flooring |
| JPH01299676A (en) * | 1988-05-27 | 1989-12-04 | Dainippon Printing Co Ltd | Production of decorative sheet |
| JPH05229299A (en) * | 1991-05-13 | 1993-09-07 | Dainippon Printing Co Ltd | Transfer paper forming relief pattern |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5815300B2 (en) * | 1975-01-30 | 1983-03-24 | 富双合成 （株） | Manufacturing method for flooring materials, etc. |
| JPS5645966Y2 (en) * | 1976-06-03 | 1981-10-27 |
-
1980
- 1980-04-10 JP JP4706580A patent/JPS56144773A/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS56144773A (en) | 1981-11-11 |
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