JPS6143389B2 - - Google Patents
Info
- Publication number
- JPS6143389B2 JPS6143389B2 JP53042720A JP4272078A JPS6143389B2 JP S6143389 B2 JPS6143389 B2 JP S6143389B2 JP 53042720 A JP53042720 A JP 53042720A JP 4272078 A JP4272078 A JP 4272078A JP S6143389 B2 JPS6143389 B2 JP S6143389B2
- Authority
- JP
- Japan
- Prior art keywords
- fluidized bed
- dye
- particles
- dye solution
- sprayed onto
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000002245 particle Substances 0.000 claims description 10
- 238000000034 method Methods 0.000 claims description 8
- 238000004519 manufacturing process Methods 0.000 claims description 4
- 239000007787 solid Substances 0.000 claims description 4
- 238000005299 abrasion Methods 0.000 claims description 3
- 239000004067 bulking agent Substances 0.000 claims description 3
- 239000004606 Fillers/Extenders Substances 0.000 claims 1
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims 1
- 235000002639 sodium chloride Nutrition 0.000 claims 1
- 239000011780 sodium chloride Substances 0.000 claims 1
- 239000000975 dye Substances 0.000 description 20
- 239000000243 solution Substances 0.000 description 9
- 239000000843 powder Substances 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- 239000000654 additive Substances 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000011282 treatment Methods 0.000 description 2
- BTEYIHUKHHAVAN-KDKWOIFOSA-N (4r,4as,7ar,12bs)-4a-hydroxy-9-methoxy-3-methyl-2,4,5,6,7a,13-hexahydro-1h-4,12-methanobenzofuro[3,2-e]isoquinoline-7-one;terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1.O=C([C@@H]1O2)CC[C@@]3(O)[C@H]4CC5=CC=C(OC)C2=C5[C@@]13CCN4C.O=C([C@@H]1O2)CC[C@@]3(O)[C@H]4CC5=CC=C(OC)C2=C5[C@@]13CCN4C BTEYIHUKHHAVAN-KDKWOIFOSA-N 0.000 description 1
- 241000384110 Tylos Species 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 238000004094 preconcentration Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000000985 reactive dye Substances 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0071—Process features in the making of dyestuff preparations; Dehydrating agents; Dispersing agents; Dustfree compositions
- C09B67/0092—Dyes in solid form
- C09B67/0095—Process features in the making of granulates
Description
本発明は非飛散性耐摩耗性で水溶性の染料粒子
を製造する方法に関する。
水溶性染料、特に反応性染料を、その濃縮溶液
から噴霧室中において製造することは公知であ
る。この場合に生ずる染料粉末は非常に細かく且
つそれ故に嵩密度が相応して低くそして著しく飛
散し易い。細かい粒子は、高い溶解速度およびそ
れによつて可能とされる作業速度が得られるので
望ましいが、作業者への苦痛や害並びに製造室内
のおよび生成物の汚染を避ける為に、飛散しない
かまたは飛散し難い染料および染料調整物が要求
されている。
染料粉末中に飛散防止剤、例えば油またはその
他の色々な添加物等またはそれらの組合せ物を混
入する追加的飛散防止処理を行うことは公知であ
る。飛散防止剤の混入によるかかる追加的飛散防
止処理は、一方においては非常に費用が掛り、他
方においてはいかなる物質を飛散防止剤として用
いるかによつて、染料使用上にわずらわしい新た
な問題を生ぜしめ得る。また、この方法では、低
い嵩密度の問題は考慮されていない。
それ故に本発明の課題は、非飛散性耐摩耗性の
染料粒子を製造する方法を開発することにある。
この課題は、湿気を吸収し得るガス流によつて
生ずる染料粒子の流動床中に染料水溶液を噴霧す
ることによつて解決される。
染料溶液は上から、下からおよび／または側方
から流動床に噴霧することができる。この溶液は
増量剤（Stellmite）を含有していてもよい。染
料水溶液なる用語は、０％から飽和状態までの固
形分を溶解した水溶液を意味する。固形分は染
料、増量剤、添加剤（例えば界面活性剤、結合剤
等）及びこれらの組成物である。増量剤としては
殊に食塩が好ましい。染料粒子を分級しそして過
小粒子並びに粉砕された過大粒子を流動床に戻す
ことができる。
更に蒸気を流動床に噴霧し得る。必要ないとは
いえ、溶剤に例えばマヌテツクス（商標；
Manutex）またはチローゼ（商標；Tylos）の如
き結合剤を加えてもよい。染料溶液あるいは調整
した染料溶液を適当な装置中で予備的濃縮に付す
る時に、これら溶液の流動床における滞留時間お
よびこれと関連してあり得る温度負荷を、エネル
ギーを節約しつつ減少させることができる。ノズ
ルの配置―上から、下からおよび／または側方か
ら噴霧できる配置―は顆粒化工程には本質的な影
響がない。流動床上に上から噴霧し得る配置が最
も有利である。
本方法は不連続的にもあるいは連続的にも実施
できる。連続的に実施する場合には、染料粉末ま
たは顆粒または顆粒と粉末との混合物の生成物供
給流を染料溶液の円錐形噴霧によつて案内するの
が有利である。団塊（アグロメレート）は例えば
回転バルブのような適当な装置により公知の方法
で解消される。排出空気によつて連れ出される染
料塵は自己精製乾燥フイルターによつて捕らえら
れそして直接または供給手段を通して流動床に戻
される。
本発明を以下の実施例（表）によつて更に詳細
に説明する。実験装置を例示的に図に示す。
流動床装置は流動室のためのハウジング１で構
成されている。この流動床装置は配量供給手段５
の他に少なくとも１つの噴霧ノズル２を有してい
る。熱い流動用空気はガス導入口４から多孔板６
を通して供給されそして湿気を含んで７の所から
流動床装置を出る。目的生成物用の排出用接続管
８は多孔板６のすぐ上えで流動室に向かつて開放
されている。この接続管８は回転バルブ３を備え
ている。
The present invention relates to a method for producing non-scattering, abrasion-resistant, water-soluble dye particles. It is known to produce water-soluble dyes, especially reactive dyes, from their concentrated solutions in a spray chamber. The dye powders produced in this case are very fine and therefore have a correspondingly low bulk density and are highly susceptible to scattering. Fine particles are desirable because of the high dissolution rates and thereby the work speeds they enable, but they are non-splattered or shattered to avoid pain and harm to workers and contamination of the manufacturing room and product. There is a need for dyes and dye preparations that are difficult to dye. It is known to provide additional anti-scattering treatment by incorporating anti-scattering agents such as oils or various other additives or combinations thereof into the dye powder. Such additional anti-scattering treatments by incorporating anti-scattering agents are on the one hand very expensive and on the other hand create troublesome new problems in the use of dyes, depending on what substances are used as anti-scattering agents. obtain. Also, this method does not take into account the problem of low bulk density. It is therefore an object of the present invention to develop a method for producing non-scattering, abrasion-resistant dye particles. This problem is solved by spraying an aqueous dye solution into a fluidized bed of dye particles created by a gas stream capable of absorbing moisture. The dye solution can be sprayed into the fluidized bed from above, from below and/or from the side. This solution may contain a bulking agent (Stellmite). The term aqueous dye solution refers to an aqueous solution containing dissolved solids from 0% to saturation. Solids include dyes, fillers, additives (eg surfactants, binders, etc.) and compositions thereof. Salt is particularly preferred as a bulking agent. The dye particles can be classified and the undersized particles as well as the crushed oversized particles can be returned to the fluidized bed. Additionally, steam may be sprayed into the fluidized bed. Although not necessary, solvents such as Manutex (trademark)
Binders such as Manutex or Tylos may also be added. When dye solutions or prepared dye solutions are subjected to preconcentration in suitable equipment, the residence time of these solutions in the fluidized bed and the possible temperature loads associated therewith can be reduced while saving energy. can. The arrangement of the nozzle - which allows spraying from above, from below and/or from the side - has no essential influence on the granulation process. Arrangements that allow spraying from above onto a fluidized bed are most advantageous. The method can be carried out discontinuously or continuously. If carried out continuously, it is advantageous to guide the product feed stream of dye powder or granules or a mixture of granules and powder by a conical spray of dye solution. Agglomerates are broken up in a known manner by means of suitable devices, such as rotary valves. The dye dust entrained by the exhaust air is captured by a self-refining drying filter and returned to the fluidized bed either directly or through feed means. The invention will be explained in more detail by the following examples (tables). The experimental setup is exemplarily shown in the figure. The fluidized bed apparatus consists of a housing 1 for a fluidizing chamber. This fluidized bed apparatus has a metering supply means 5
In addition, it has at least one spray nozzle 2. Hot flowing air is passed from the gas inlet 4 to the perforated plate 6.
and exits the fluidized bed apparatus at 7 containing moisture. A discharge connection 8 for the desired product opens directly above the perforated plate 6 into the flow chamber. This connecting pipe 8 is equipped with a rotary valve 3.
【表】【table】
図面は、本発明を実施する為の実験的装置の一
例を示したものであり、図中の記号はそれぞれ以
下の通りである。
１……ハウジング、２……ノズル、３……回転
バルブ、４……ガス導入口、５……配量供給手
段、６……多孔板、７……ガス排出口、８……排
出用接続管。
The drawing shows an example of an experimental apparatus for carrying out the present invention, and the symbols in the drawing are as follows. DESCRIPTION OF SYMBOLS 1... Housing, 2... Nozzle, 3... Rotary valve, 4... Gas inlet, 5... Metering supply means, 6... Perforated plate, 7... Gas outlet, 8... Discharge connection tube.
Claims (1)
粒子の流動床中に染料水溶液を噴霧することを特
徴とする、非飛散性、耐摩耗性で水溶性の染料粒
子の製造方法。 ２ 染料溶液を上から流動床に噴霧する特許請求
の範囲第１項記載の方法。 ３ 増量剤を含有した染料溶液を流動床上に噴霧
する特許請求の範囲第１項記載の方法。 ４ ０％から飽和状態までの固形分含有量を有し
且つ増量剤として食塩を含有する染料溶液を流動
床上に噴霧する特許請求の範囲第１項記載の方
法。 ５ 第二循環系において固体粒子を分級しそして
粉砕された過大粒子および／または過小粒子を流
動床に戻す特許請求の範囲第１項記載の方法。Claims: 1. A process for producing non-scattering, abrasion-resistant, water-soluble dye particles, characterized in that an aqueous dye solution is sprayed into a fluidized bed of dye particles created by a gas stream capable of absorbing moisture. Production method. 2. The method according to claim 1, in which the dye solution is sprayed onto the fluidized bed from above. 3. The method according to claim 1, wherein the dye solution containing an extender is sprayed onto a fluidized bed. 2. A process as claimed in claim 1, in which a dye solution having a solids content of 40% to saturation and containing common salt as a bulking agent is sprayed onto the fluidized bed. 5. Process according to claim 1, in which the solid particles are classified in the second circulation system and the crushed oversized and/or undersized particles are returned to the fluidized bed.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE792909157A DE2909157C2 (en) | 1978-03-10 | 1979-03-08 | ROTATIONAL COMPRESSORS |
| US06/247,953 US4345886A (en) | 1978-03-10 | 1981-03-26 | Rotary compressor with vanes in the housing and suction through the rotor |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19772716478 DE2716478A1 (en) | 1977-04-14 | 1977-04-14 | PROCESS FOR THE PRODUCTION OF ABRASION-RESISTANT, NON-DUSTING, WATER-SOLUBLE COLORANT PARTICLES |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS53128634A JPS53128634A (en) | 1978-11-09 |
| JPS6143389B2 true JPS6143389B2 (en) | 1986-09-27 |
Family
ID=6006263
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP4272078A Granted JPS53128634A (en) | 1977-04-14 | 1978-04-13 | Method of making dustless* abrasionnresistant and waterrsoluble dye particulate |
Country Status (9)
| Country | Link |
|---|---|
| JP (1) | JPS53128634A (en) |
| AR (1) | AR219741A1 (en) |
| BR (1) | BR7802311A (en) |
| CH (1) | CH633031A5 (en) |
| DE (1) | DE2716478A1 (en) |
| FR (1) | FR2387270A1 (en) |
| GB (1) | GB1567734A (en) |
| IN (1) | IN148409B (en) |
| IT (1) | IT1095579B (en) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CH635862A5 (en) * | 1977-10-15 | 1983-04-29 | Ciba Geigy Ag | Process for granulation of pigments. |
| EP0024655A3 (en) * | 1979-08-22 | 1981-03-25 | Ciba-Geigy Ag | Granules of metal complex dyestuffs and process for their preparation |
| EP0024654A1 (en) * | 1979-08-22 | 1981-03-11 | Ciba-Geigy Ag | Granules of fibre-reactive dyestuffs and process for their preparation |
| FR2468633A1 (en) * | 1979-09-21 | 1981-05-08 | Ugine Kuhlmann | Non-dusty azo metal complex dye granules prepn. - by pulverising aq. dye paste above or inside fluidised bed |
| US4560747A (en) * | 1979-10-30 | 1985-12-24 | Ciba Geigy Corporation | Process for producing granulates of water-soluble dyes by fluidized bed granulation |
| IT1212796B (en) * | 1983-12-12 | 1989-11-30 | Ates Componenti Elettron | DIGITAL PHASE SYNCHRONIZER FOR ISOFREQUENTIAL SIGNALS, ESPECIALLY FOR SIGNAL DEMODULATOR. |
| CH658667A5 (en) * | 1984-05-04 | 1986-11-28 | Ciba Geigy Ag | METHOD FOR PRODUCING DYE GRANULES. |
| DE3635313A1 (en) * | 1986-10-17 | 1988-04-28 | Bayer Ag | METHOD FOR PRODUCING GRANULES |
| JP3092152B2 (en) * | 1990-08-28 | 2000-09-25 | 住友化学工業株式会社 | Granular reactive dye composition and method for dyeing or printing cellulosic fiber material using the same |
| US5143671A (en) * | 1990-10-31 | 1992-09-01 | Eastman Kodak Company | Fluidized bed process for treating pigments |
| EP1002022B2 (en) | 1997-07-21 | 2005-05-04 | Clariant Finance (BVI) Limited | Granular compacts, their production and use |
| JP4724617B2 (en) * | 2006-07-25 | 2011-07-13 | 本田技研工業株式会社 | Parking brake device |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4884117A (en) * | 1972-01-26 | 1973-11-08 |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1254730A (en) * | 1969-02-13 | 1971-11-24 | Vyzk Ustav Organ Syntez | A process for isolating reactive dyestuffs, or reactive optical brightening agents. |
-
1977
- 1977-04-14 DE DE19772716478 patent/DE2716478A1/en active Granted
-
1978
- 1978-04-07 IN IN381/CAL/78A patent/IN148409B/en unknown
- 1978-04-11 CH CH388278A patent/CH633031A5/en not_active IP Right Cessation
- 1978-04-12 IT IT22245/78A patent/IT1095579B/en active
- 1978-04-13 JP JP4272078A patent/JPS53128634A/en active Granted
- 1978-04-13 AR AR271768A patent/AR219741A1/en active
- 1978-04-13 BR BR7802311A patent/BR7802311A/en unknown
- 1978-04-14 FR FR7811032A patent/FR2387270A1/en active Granted
- 1978-04-14 GB GB14797/78A patent/GB1567734A/en not_active Expired
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4884117A (en) * | 1972-01-26 | 1973-11-08 |
Also Published As
| Publication number | Publication date |
|---|---|
| DE2716478C2 (en) | 1987-01-08 |
| AR219741A1 (en) | 1980-09-15 |
| DE2716478A1 (en) | 1978-10-26 |
| CH633031A5 (en) | 1982-11-15 |
| FR2387270B1 (en) | 1985-03-01 |
| JPS53128634A (en) | 1978-11-09 |
| IT7822245A0 (en) | 1978-04-12 |
| GB1567734A (en) | 1980-05-21 |
| IT1095579B (en) | 1985-08-10 |
| BR7802311A (en) | 1978-11-28 |
| IN148409B (en) | 1981-02-14 |
| FR2387270A1 (en) | 1978-11-10 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JPS6143389B2 (en) | ||
| EP0961646B1 (en) | Spray drying method and apparatus and cleaning method for such an apparatus | |
| GB1350098A (en) | Spray drying | |
| RU2102100C1 (en) | Method for production of free-flowing powder including coated particles on spray driers or spray coolers | |
| EP0612557B1 (en) | Method and device for uniformly distributing a small amount of liquid on bulk goods | |
| BR0317595A (en) | Method and apparatus for producing particles, method for producing a mixture of dry powder and pharmaceutical composition. | |
| JP2005513151A5 (en) | ||
| DE1442866C3 (en) | Process for replacing an organic liquid mixed with polypropylene with water | |
| US4871398A (en) | Method for pregelatinized, spray-dried starch agglomerates | |
| GB1142046A (en) | Method of and apparatus for pelletizing powders | |
| CN100368282C (en) | Sodium percarbonate dry method granulation processes and apparatus thereof | |
| US3401216A (en) | Methods for preparing pharmaceutical compositions | |
| DE2941637A1 (en) | Biomass and albumin suspensions drying - by hot air in shaped fluidised bed dryer producing granules for fodder etc. | |
| CN1986425A (en) | Preparing process of spherical ammonium metatungstate particle | |
| GB1270020A (en) | Improvements in or relating to spray drying devices and methods for the operation of such devices | |
| JP3934179B2 (en) | Method and granulated product for granulating powder made of substance ingested into animal body | |
| KR20080043280A (en) | A spray dry system utilizing a vacuum chamber | |
| GB1238737A (en) | ||
| MY136440A (en) | Process for the preparation of urea granules | |
| JPH01236932A (en) | Spray granulator | |
| DE1468226A1 (en) | Process and device for the production of cellulose derivatives | |
| US2502778A (en) | Apparatus for homogeneously combining finely divided substances | |
| DE2346770C2 (en) | Device for agglomerating powder particles | |
| JPS61257229A (en) | Granulating method for liquid material | |
| JPS57171956A (en) | Concentration of aqueous solution of urea |