JPS6135155B2 - - Google Patents
Info
- Publication number
- JPS6135155B2 JPS6135155B2 JP5770581A JP5770581A JPS6135155B2 JP S6135155 B2 JPS6135155 B2 JP S6135155B2 JP 5770581 A JP5770581 A JP 5770581A JP 5770581 A JP5770581 A JP 5770581A JP S6135155 B2 JPS6135155 B2 JP S6135155B2
- Authority
- JP
- Japan
- Prior art keywords
- layer
- ceramic
- transfer
- glaze
- thermoplastic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000012546 transfer Methods 0.000 claims description 40
- 239000000919 ceramic Substances 0.000 claims description 37
- 238000000034 method Methods 0.000 claims description 30
- 238000010422 painting Methods 0.000 claims description 19
- 239000000463 material Substances 0.000 claims description 17
- 239000003795 chemical substances by application Substances 0.000 claims description 16
- 229920001169 thermoplastic Polymers 0.000 claims description 13
- 239000012815 thermoplastic material Substances 0.000 claims description 13
- 239000004416 thermosoftening plastic Substances 0.000 claims description 13
- 238000010304 firing Methods 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 8
- 239000010410 layer Substances 0.000 description 40
- 239000001993 wax Substances 0.000 description 8
- 239000000839 emulsion Substances 0.000 description 7
- 238000013461 design Methods 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 5
- 239000013032 Hydrocarbon resin Substances 0.000 description 4
- 229920001577 copolymer Polymers 0.000 description 4
- 229920006270 hydrocarbon resin Polymers 0.000 description 4
- 239000000123 paper Substances 0.000 description 4
- 229920005989 resin Polymers 0.000 description 4
- 239000011347 resin Substances 0.000 description 4
- 229920001038 ethylene copolymer Polymers 0.000 description 3
- 239000012188 paraffin wax Substances 0.000 description 3
- -1 polyethylene terephthalate Polymers 0.000 description 3
- 238000007639 printing Methods 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 239000005995 Aluminium silicate Substances 0.000 description 2
- 235000019738 Limestone Nutrition 0.000 description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- 235000012211 aluminium silicate Nutrition 0.000 description 2
- 235000013871 bee wax Nutrition 0.000 description 2
- 239000012166 beeswax Substances 0.000 description 2
- 238000007646 gravure printing Methods 0.000 description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 2
- 239000006028 limestone Substances 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 235000019198 oils Nutrition 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- 238000007650 screen-printing Methods 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- WCOXQTXVACYMLM-UHFFFAOYSA-N 2,3-bis(12-hydroxyoctadecanoyloxy)propyl 12-hydroxyoctadecanoate Chemical compound CCCCCCC(O)CCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCC(O)CCCCCC)COC(=O)CCCCCCCCCCC(O)CCCCCC WCOXQTXVACYMLM-UHFFFAOYSA-N 0.000 description 1
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- 229920002907 Guar gum Polymers 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 229920000459 Nitrile rubber Polymers 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 239000002174 Styrene-butadiene Substances 0.000 description 1
- 229920000180 alkyd Polymers 0.000 description 1
- 239000010775 animal oil Substances 0.000 description 1
- 239000012164 animal wax Substances 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- DQXBYHZEEUGOBF-UHFFFAOYSA-N but-3-enoic acid;ethene Chemical compound C=C.OC(=O)CC=C DQXBYHZEEUGOBF-UHFFFAOYSA-N 0.000 description 1
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 239000000679 carrageenan Substances 0.000 description 1
- 235000010418 carrageenan Nutrition 0.000 description 1
- 229920001525 carrageenan Polymers 0.000 description 1
- 229940113118 carrageenan Drugs 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 239000005038 ethylene vinyl acetate Substances 0.000 description 1
- 239000010433 feldspar Substances 0.000 description 1
- 239000010408 film Substances 0.000 description 1
- 239000000665 guar gum Substances 0.000 description 1
- 235000010417 guar gum Nutrition 0.000 description 1
- 229960002154 guar gum Drugs 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- 239000011229 interlayer Substances 0.000 description 1
- 239000002655 kraft paper Substances 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 238000007645 offset printing Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000007591 painting process Methods 0.000 description 1
- 239000012165 plant wax Substances 0.000 description 1
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229920002379 silicone rubber Polymers 0.000 description 1
- 239000004945 silicone rubber Substances 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 229910052572 stoneware Inorganic materials 0.000 description 1
- 239000011115 styrene butadiene Substances 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 description 1
- 229910052845 zircon Inorganic materials 0.000 description 1
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Decoration By Transfer Pictures (AREA)
Description
【発明の詳細な説明】
本発明は陶磁器の絵付方法に関するものであ
り、その目的は美麗な多色図柄を簡単に絵付で
き、しかも低エネルギーコストで実施できる陶磁
器絵付方法を提供することにある。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a method for painting ceramics, and its purpose is to provide a method for painting ceramics that can easily paint beautiful multicolored designs and can be carried out at low energy costs.
従来より陶磁器に絵付する方法としては次の３
通りの方法があつた。即ち素焼陶磁器面に釉薬
を塗布し、約1000℃〜1300℃で焼成後絵付を施
し、その後約800℃〜1200℃で焼成する所謂上絵
付方法、素焼陶磁器面に絵付を施し、約500℃
〜700℃で焼成の後その上に釉薬を塗布し、約
1000℃〜1300℃で焼成する所謂下絵付方法、素
焼陶磁器面に釉薬と樹脂の混合物を塗布し、その
上に絵付した後約1000℃〜1300℃で焼成する所謂
生釉上絵付方法等である。これらの方法のうち
，の方法は焼成工程が２度あるためエネルギ
ーコストの高いものであつた。又、においては
スクリーン印刷等の直接絵付法は印刷時に生釉面
が傷つき易く、精密な多色刷が困難なため特に繊
細な意匠の図柄に対して不適当なものであつた。
従つて従来はスライド転写材を用いたスライド転
写方法が適用されていた。これは転写材を水に膨
潤させて図柄層をスライドせしめ手貼り等の手段
により器物表面に貼着する方法であるが、多くは
手作業に依るため手間のかかるものである上、上
記の方法においては器物表面が水分を吸収し易
い状態であるからそのままでは転写できず、転写
前に釉薬上に十分な量の樹脂層を設ける必要があ
り、工程の複雑なものであつた。 Traditionally, there are three methods for painting ceramics:
There was a standard method. In other words, the so-called overglaze method involves applying a glaze to the unglazed ceramic surface, firing it at approximately 1000°C to 1300°C, and then firing it at approximately 800°C to 1200°C.
After firing at ~700℃, glaze is applied on top of it, and approximately
The so-called underpainting method involves firing at 1000°C to 1300°C, and the so-called raw glaze overpainting method involves applying a mixture of glaze and resin to the unglazed ceramic surface, painting on top of it, and then firing it at approximately 1000°C to 1300°C. . Among these methods, method (1) requires high energy costs because it requires two firing steps. In addition, direct painting methods such as screen printing were unsuitable for particularly delicate designs because the raw glaze surface was easily damaged during printing and precise multicolor printing was difficult.
Therefore, conventionally, a slide transfer method using a slide transfer material has been applied. This is a method in which the transfer material is swollen in water, the pattern layer is slid, and it is attached to the surface of the utensil by means such as hand-applying.However, it is a time-consuming process as it is mostly manual work, and the method described above is difficult. Since the surface of the glaze easily absorbs moisture, it cannot be directly transferred, and it is necessary to provide a sufficient amount of resin layer on the glaze before transfer, making the process complicated.
本発明は以上のような従来法の欠点に鑑み、上
記の方法においてスライド転写ではない所謂乾
式転写方法を適用すれば低エネルギーコストで且
つ繊細美麗な絵付を施し得るとの知見に基づい
て、種々研究考案した結果本発明を完成するに至
つたものである。即ち本発明は基体シート上に、
常温では粘着性を有することなく、加熱により粘
着性を帯び、一定時間その粘着性を持続するよう
な熱可塑性物質層を形成し、その上に陶磁器絵付
用インキよりなる図柄層を形成した転写材を該熱
可塑性物質層が粘着性を帯びる温度に加熱し、転
写用パツドを該転写材の図柄層とを圧接せしめる
ことにより図柄層及び熱可塑物質層を転写用パツ
ド表面に転移せしめ、しかる後釉薬及び固化剤が
塗布された素焼陶磁器面と転写用パツド表面とを
圧接せしめ、該素焼陶磁器面に図柄層及び熱可塑
性物質層を転移せしめ、その後焼成することを特
徴とする陶磁器絵付方法である。 In view of the drawbacks of the conventional methods as described above, the present invention is based on the knowledge that if a so-called dry transfer method, rather than slide transfer, is applied to the above method, it is possible to apply delicate and beautiful paintings at low energy costs. As a result of research and ideas, the present invention was completed. That is, the present invention provides, on a base sheet,
A transfer material that has a thermoplastic material layer that does not have tackiness at room temperature but becomes tacky when heated and maintains that tackiness for a certain period of time, and a pattern layer made of ceramic painting ink formed on top of this layer. is heated to a temperature at which the thermoplastic layer becomes sticky, and the transfer pad is brought into pressure contact with the pattern layer of the transfer material, thereby transferring the pattern layer and the thermoplastic layer to the surface of the transfer pad, and then A method for painting ceramics, which is characterized in that the surface of the unglazed ceramic coated with a glaze and a solidifying agent is brought into pressure contact with the surface of a transfer pad, the pattern layer and the thermoplastic layer are transferred to the surface of the unglazed ceramic, and then fired. .
以下本発明にかかる陶磁器絵付方法について更
に詳しく説明する。 The ceramic painting method according to the present invention will be explained in more detail below.
本発明において使用する転写材は基体シート
１、熱可塑性物質層２及び図柄層３から構成され
る（第１図参照）。 The transfer material used in the present invention is composed of a base sheet 1, a thermoplastic layer 2 and a pattern layer 3 (see FIG. 1).
基体シート１は通常の転写材に供されるもので
よく、上質紙、コート紙、クラフト紙等の紙類或
いはポリエチレンテレフタレート等のフイルム類
を用いる。 The base sheet 1 may be one that is used as a normal transfer material, and may be paper such as high-quality paper, coated paper, or kraft paper, or film such as polyethylene terephthalate.
熱可塑性物質層２は常温では粘着性を有するこ
となく、加熱により粘着性を帯び、一定時間その
粘着性を持続するものである。このような性質の
熱可塑性物質層２は合成合金ワツクス、酸化変成
ワツクス、パラフイン系ワツクス、動植物ろう、
ミネラル油、動植物油、熱可塑性炭化水素樹脂、
エチレン共重合物等の主にろう状の混合物により
形成されるか、或いは熱可塑性ラテツクス類、ス
チレンブタジエンラテツクス、ニトリルブタジエ
ンゴムラテツクス、アルキツドエマルジヨン、ア
クリルエステル共重合体エマルジヨン、エチレン
酢酸ビニル共重合エマルジヨン、アクリルエマル
ジヨン、塩化ビニル共重合エマルジヨン、その他
の熱可塑性樹脂の共重合エマルジヨン、炭化水素
樹脂及びロジンエマルジヨン等を単独で又は混合
して用いて形成される。又、該熱可塑性物質層２
は前記したような物質を通常の方法で基体シート
１上に塗布することにより形成されるが、前記の
物質群から適宜選択して、複数の層よりなる構成
にしてもよい。この場合、軟化点、融点が各層で
異なるように設けると、後述する転写時の熱可塑
性物質層２の剥離、粘着工程が比較的スムースに
行なわれる。尚、後述する焼成工程にて熱分解す
るようなものが好ましい。 The thermoplastic layer 2 does not have tackiness at room temperature, but becomes tacky when heated and maintains its tackiness for a certain period of time. The thermoplastic material layer 2 having such properties may be made of synthetic alloy wax, oxidized modified wax, paraffin wax, animal or plant wax,
Mineral oil, animal and vegetable oil, thermoplastic hydrocarbon resin,
It is mainly formed from waxy mixtures such as ethylene copolymers, or thermoplastic latexes, styrene-butadiene latexes, nitrile-butadiene rubber latexes, alkyd emulsions, acrylic ester copolymer emulsions, ethylene vinyl acetate. It is formed using a copolymer emulsion, an acrylic emulsion, a vinyl chloride copolymer emulsion, a copolymer emulsion of other thermoplastic resins, a hydrocarbon resin, a rosin emulsion, etc. alone or in combination. Moreover, the thermoplastic material layer 2
is formed by applying the above-mentioned substances onto the base sheet 1 in a conventional manner, but the structure may be made up of a plurality of layers by appropriately selecting from the above-mentioned substance group. In this case, if each layer is provided with a different softening point and melting point, the peeling and adhesion process of the thermoplastic layer 2 during transfer, which will be described later, can be performed relatively smoothly. Note that it is preferable to use a material that can be thermally decomposed in the firing step described later.
図柄層は通常の陶磁器絵付用インキよりなるも
ので、オフセツト印刷、スクリーン印刷、グラビ
ア印刷又はそれらの組合せの印刷手段によつて形
成される。 The pattern layer is made of ordinary ceramic painting ink and is formed by printing means such as offset printing, screen printing, gravure printing, or a combination thereof.
次に本発明における絵付工程について説明す
る。 Next, the painting process in the present invention will be explained.
まず前記の転写材を加熱する。加熱は前記熱可
塑性物質層２が粘着性を帯びる温度で行う。前記
のような物質を用いた場合は80℃〜200℃の温度
範囲で加熱手段は特定されないが、加熱板６を用
いると次の転写用パツド４を用いて圧接する工程
に即座に移ることができるので好ましい（第２図
参照）。 First, the transfer material described above is heated. Heating is carried out at a temperature at which the thermoplastic layer 2 becomes sticky. When the above-mentioned material is used, the heating means is not specified within the temperature range of 80°C to 200°C, but if the heating plate 6 is used, it is possible to immediately move on to the next step of pressure contact using the transfer pad 4. This is preferable because it can be done (see Figure 2).
転写材を加熱した後、転写用パツド４と前記転
写材の図柄層３とを圧接せしめる。この圧接によ
り図柄層の全部及び熱可塑性物質層２のほとんど
が転写用パツド４表面に転移する（第３図参
照）。 After heating the transfer material, the transfer pad 4 and the pattern layer 3 of the transfer material are brought into pressure contact. By this pressure contact, all of the pattern layer and most of the thermoplastic material layer 2 are transferred to the surface of the transfer pad 4 (see FIG. 3).
しかる後該転写用パツド４と素焼陶磁器５面と
を圧接せしめる。この素焼陶磁器５面には釉薬及
び固化剤７が予め塗布されている。釉薬は通常陶
磁器に用いるものを使用し、固化剤は例えばでん
ぷん系、セルローズ系、アクリル系、ビニール系
樹脂等或いはこれらとポリオキシエチレンオキサ
イド、カラギーナン、グアーガム等との混合物等
を使用する。釉薬及び固化剤７の塗布は、予め両
者を混合したものを塗布してもよく、又まず釉薬
を塗布しその上に固化剤を塗布してもよい。 Thereafter, the transfer pad 4 and the 5 surfaces of the unglazed ceramics are brought into pressure contact. A glaze and a solidifying agent 7 are applied in advance to the 5 sides of this unglazed ceramic. The glaze used is normally used for ceramics, and the solidifying agent is, for example, starch, cellulose, acrylic, vinyl resin, or a mixture of these with polyoxyethylene oxide, carrageenan, guar gum, etc. The glaze and the solidifying agent 7 may be applied by mixing the two in advance, or by first applying the glaze and then applying the solidifying agent thereon.
前記転写用パツド４と素焼陶磁器５面との圧接
によつて素焼陶磁器５面、詳しくは釉薬及び固化
剤７が塗布された素焼陶磁器５面上に図柄層３及
び熱可塑性物質層２が転移する（第４図参照）。 By pressure contact between the transfer pad 4 and the 5 surface of the unglazed ceramic, the pattern layer 3 and the thermoplastic material layer 2 are transferred onto the 5 surface of the unglazed ceramic, specifically, onto the 5 surface of the unglazed ceramic coated with the glaze and solidifying agent 7. (See Figure 4).
その後焼成する。焼成は約1000℃〜1300℃で行
うのが好ましい。この焼成よつて図柄は釉薬と一
体となつて焼結され良好な絵付が施される（第５
図参照）。 Then it is fired. Preferably, calcination is carried out at about 1000°C to 1300°C. As a result of this firing, the design is sintered together with the glaze, resulting in a good decoration (No. 5
(see figure).
本発明は以上のような陶磁器の絵付方法である
から、低いエネルギーコストで美麗な多色図柄を
簡単に絵付できるものである。即ち焼成工程が一
度でよく、且つ素焼陶磁器面に塗布する釉薬及び
固化剤は従来のスライド転写におけるよう転写前
に樹脂層を設ける必要がない。又、釉薬の層間強
度のみを考慮して釉薬を選定できるからスライド
転写に比べて少量の固化剤でよい。従つて産業上
の利用価値の高い陶磁器絵付方法である。 Since the present invention is a method of painting ceramics as described above, it is possible to easily paint beautiful multicolored designs at low energy costs. That is, the firing process only needs to be carried out once, and the glaze and solidifying agent applied to the unglazed ceramic surface do not need to be coated with a resin layer before transfer, unlike in conventional slide transfer. Furthermore, since the glaze can be selected by considering only the interlayer strength of the glaze, a smaller amount of solidifying agent is required than in slide transfer. Therefore, it is a ceramic painting method with high industrial value.
以下本発明の実施例を説明する。 Examples of the present invention will be described below.
＜実施例 １＞
128ｇ／m2のコート紙を基体シートとし下記の
成分の混合物を用いて熱可塑性物質層第１、第２
を順次積層した上に無機顔料を主成分とした陶磁
器絵付用インキを用いてグラビア印刷にて図柄層
を形成して転写材を得た。<Example 1> Using 128 g/m 2 coated paper as a base sheet, the first and second thermoplastic layers were prepared using a mixture of the following components.
A transfer material was obtained by sequentially laminating the above and forming a pattern layer by gravure printing using a ceramic painting ink containing an inorganic pigment as a main component.
熱可塑性物質層第１
炭化水素樹脂 38部
合成合金ヘキストろうCaW−20
（ヘキスト社製） ８部
酸化変成ヘキストろうKPE
（ヘキスト社製） 12部
酸化変成ヘキストろうＲ−21
（ヘキスト社製） ４部
エチレン共重合ろう ８部
みつろう ４部
パラフインろう 16部
ホワイトオイル 10部
熱可塑性物質層第２
炭化水素樹脂 16部
酸化変成ろうKPE
（ヘキスト社製） 16部
エチレン共重合ろう 12部
カスターワツクス ８部
みつろう ８部
パラフインろう 24部
ホワイトオイル 16部
この転写材を予熱板上で約130℃に加熱し、同
時にシリコンゴム製の転写用パツドの該図柄層に
圧接せしめ該転写用パツド表面に図柄層及び熱可
塑性物質層を転移せしめた。しかる後、下記組成
の釉薬に固化剤を約10％混合したものを表面に塗
布した素焼陶磁器面に前記転写用パツドと圧接せ
しめ、図柄層及び熱可塑性物質層を転移せしめ
た。その後1350℃で焼成を施した結果、美麗で堅
固な図柄が絵付された陶磁器を得た。 Thermoplastic layer 1 Hydrocarbon resin 38 parts Synthetic alloy Hoechst wax CaW-20 (manufactured by Hoechst) 8 parts Oxidized modified Hoechst wax KPE (manufactured by Hoechst) 12 parts Oxidized modified Hoechst wax R-21 (manufactured by Hoechst) 4 Parts Ethylene copolymer wax 8 parts Beeswax 4 parts Paraffin wax 16 parts White oil 10 parts Thermoplastic material layer 2 Hydrocarbon resin 16 parts Oxidation modified wax KPE (manufactured by Hoechst) 16 parts Ethylene copolymer wax 12 parts Castor wax 8 Part: Beeswax 8 parts Paraffin wax 24 parts White oil 16 parts This transfer material is heated to about 130℃ on a preheating plate, and at the same time it is pressed against the pattern layer of a transfer pad made of silicone rubber, and the pattern layer is applied to the surface of the transfer pad. and transferred the thermoplastic layer. Thereafter, the transfer pad was brought into pressure contact with the unglazed ceramic surface coated with a glaze having the composition shown below mixed with about 10% of a solidifying agent, thereby transferring the pattern layer and the thermoplastic material layer. The ceramics were then fired at 1,350°C, resulting in ceramics with beautiful and solid patterns painted on them.
釉 薬
長 石 42.10％
石灰石 17.64％
カオリン 13.06％
石 英 27.20％
固化剤
ヒドロキシエチルセルロース 8.00％
ポリオキシエチレンオキサイド 1.20％
水 90.80％
＜実施例 ２＞
＜実施例１＞と同様の転写材、転写方法を用い
て素焼陶磁器面に図柄層及び熱可塑性物質層を転
写した。素焼陶磁器面には予め下記組成の釉薬が
塗布された上に下記組成の固化剤が塗布され、乾
燥されたものを用いた。その後1200℃で焼成を施
した結果美麗で堅固な絵付されたストーンウエア
を得た。 Glaze Stone 42.10% Limestone 17.64% Kaolin 13.06% Quartz 27.20% Solidifying agent Hydroxyethyl cellulose 8.00% Polyoxyethylene oxide 1.20% Water 90.80% <Example 2> The same transfer material and transfer method as <Example 1> were used. The pattern layer and the thermoplastic material layer were transferred onto the unglazed ceramic surface using the following method. The unglazed ceramic surface was previously coated with a glaze having the composition shown below, and then a solidifying agent having the composition shown below was applied and dried. Afterwards, it was fired at 1200℃, resulting in beautiful and solid painted stoneware.
釉 薬 釜戸長石 45％ 石灰石 10％ 珪 石 16％ 朝鮮カオリン ７％ 灰酸バリウム ９％ 珪酸ジルコン 10％ 弁 柄 ３％ 固化剤 プライマールAC−33 （日本アクリル社製） 15％ 水 85％ glaze Kamado feldspar 45% Limestone 10% Silica stone 16% Korean kaolin 7% Barium ash 9% Zircon silicate 10% Bento 3% solidifying agent Primal AC-33 (Manufactured by Nippon Acrylic Co., Ltd.) 15% water 85%
第１図は本発明にかかる陶磁器絵付方法におい
て使用する転写材の部分拡大断面図を、第２図、
第３図、第４図及び第５図は本発明にかかる絵付
方法の各工程の拡大断面図をそれぞれ示す。
図中、１……基体シート、２……熱可塑性物質
層、３……図柄層、４……転写用パツド、５……
素焼陶磁器、６……加熱板、７……釉薬及び固化
剤。
FIG. 1 is a partially enlarged sectional view of the transfer material used in the ceramic painting method according to the present invention, and FIG.
FIG. 3, FIG. 4, and FIG. 5 each show an enlarged sectional view of each step of the painting method according to the present invention. In the figure, 1... Base sheet, 2... Thermoplastic material layer, 3... Design layer, 4... Transfer pad, 5...
Unglazed ceramics, 6... heating plate, 7... glaze and solidifying agent.
Claims (1)
となく、加熱により粘着性を帯び、一定時間その
粘着性を持続するような熱可塑性物質層を形成
し、その上に陶磁器絵付用インキよりなる図柄層
を形成した転写材を該熱可塑性物質層が粘着性を
帯びる温度に加熱し、転写用パツドと該転写材の
図柄層とを圧接せしめることにより図柄層及び熱
可塑性物質層を転写用パツド表面に転移せしめ、
しかる後釉薬及び固化剤が塗布された素焼陶磁器
面と転写用パツド表面とを圧接せしめ、該素焼陶
磁器面に図柄層及び熱可塑性物質層を転移せし
め、その後焼成することを特徴とする陶磁器絵付
方法。 ２ 熱可塑性物質層が焼成によつて熱分解するも
のであることを特徴とする特許請求の範囲第１項
記載の陶磁器絵付方法。 ３ 素焼陶磁器面が、釉薬と固化剤の混合物が塗
布されたものであることを特徴とする特許請求の
範囲第１項記載の陶磁器絵付方法。 ４ 素焼陶磁器面が、まず釉薬が塗布されその上
に固化剤が塗布されたものであることを特徴とす
る特許請求の範囲第１項記載の陶磁器絵付方法。[Claims] 1. A thermoplastic material layer is formed on a base sheet, which does not have tackiness at room temperature but becomes tacky when heated and maintains that tackiness for a certain period of time, and a ceramic layer is formed on the base sheet. The transfer material on which the pattern layer made of decorative ink has been formed is heated to a temperature at which the thermoplastic layer becomes sticky, and the transfer pad and the pattern layer of the transfer material are brought into pressure contact, thereby removing the pattern layer and the thermoplastic material. Transfer the layer to the surface of the transfer pad,
A ceramic painting method characterized in that the unglazed ceramic surface coated with a glaze and a solidifying agent is then brought into pressure contact with the transfer pad surface, a pattern layer and a thermoplastic material layer are transferred to the unglazed ceramic surface, and then fired. . 2. The ceramic painting method according to claim 1, wherein the thermoplastic material layer is thermally decomposed by firing. 3. The ceramic painting method according to claim 1, wherein the surface of the unglazed ceramic is coated with a mixture of a glaze and a solidifying agent. 4. The ceramic painting method according to claim 1, wherein the surface of the unglazed ceramic is first coated with a glaze and then coated with a solidifying agent.
Priority Applications (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP5770581A JPS57175784A (en) | 1981-04-16 | 1981-04-16 | Ceramic painting method |
| US06/325,054 US4597815A (en) | 1980-11-29 | 1981-11-25 | Transfer printing |
| EP85113888A EP0185895A3 (en) | 1980-11-29 | 1981-11-26 | Apparatus for coloring an article by transfer printing |
| DE8181109938T DE3176204D1 (en) | 1980-11-29 | 1981-11-26 | Transfer material |
| EP19810109938 EP0055395B1 (en) | 1980-11-29 | 1981-11-26 | Transfer material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP5770581A JPS57175784A (en) | 1981-04-16 | 1981-04-16 | Ceramic painting method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS57175784A JPS57175784A (en) | 1982-10-28 |
| JPS6135155B2 true JPS6135155B2 (en) | 1986-08-11 |
Family
ID=13063349
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP5770581A Granted JPS57175784A (en) | 1980-11-29 | 1981-04-16 | Ceramic painting method |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS57175784A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6317052U (en) * | 1986-07-15 | 1988-02-04 |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2593754B2 (en) * | 1991-08-05 | 1997-03-26 | 名古屋パルプ株式会社 | Painting transfer paper |
-
1981
- 1981-04-16 JP JP5770581A patent/JPS57175784A/en active Granted
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6317052U (en) * | 1986-07-15 | 1988-02-04 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS57175784A (en) | 1982-10-28 |
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