JPS61291700A - Foamable skin cleaning composition - Google Patents
Foamable skin cleaning compositionInfo
- Publication number
- JPS61291700A JPS61291700A JP60130866A JP13086685A JPS61291700A JP S61291700 A JPS61291700 A JP S61291700A JP 60130866 A JP60130866 A JP 60130866A JP 13086685 A JP13086685 A JP 13086685A JP S61291700 A JPS61291700 A JP S61291700A
- Authority
- JP
- Japan
- Prior art keywords
- salt
- skin cleansing
- acid
- foam
- cleansing composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Abstract
(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は、皮膚刺激が少なく、優れた泡の安定性を有し
、かつ使用感の良好な泡状皮膚洗浄剤組成物に関する。DETAILED DESCRIPTION OF THE INVENTION [Industrial Field of Application] The present invention relates to a foamy skin cleansing composition that causes little skin irritation, has excellent foam stability, and has a good feeling of use.
従来、皮膚洗浄剤として、石けんをペースとした固形又
はクリー人状のものが使用されているが、アルカリ性で
あるため皮膚刺激が強いという欠点がある。また最近、
ペースとして用いた界面活性剤の皮膚刺激性を改善する
ため、ポリオール類を多用したもの、皮膚刺激性を緩和
するため、中性〜弱酸性で有効なモノアルキルリン酸エ
ステル塩やＮ−アシルグルタミン酸のような界面活性剤
をペースとしたもの等の液状又はクリーム状の洗顔料が
市販されている。しかし、これら洗顔料は、いずれも皮
膚表面で摩擦することによシ泡立てて使用するものであ
るため、摩擦時の皮膚刺激を避けることは困難である。Conventionally, soap-based solid or soap-based detergents have been used as skin cleansers, but they have the disadvantage of being highly irritating to the skin because they are alkaline. Also recently,
In order to improve the skin irritation of the surfactant used as a paste, polyols are used extensively, and in order to alleviate the skin irritation, monoalkyl phosphate ester salts and N-acyl glutamic acid, which are effective in neutral to weak acidity, are used. Liquid or cream facial cleansers are commercially available, such as surfactant-based facial cleansers. However, since all of these facial cleansers are used by lathering them by rubbing them on the skin surface, it is difficult to avoid skin irritation during friction.
特に、にきびや皮膚炎のある肌に使用すると、使用時に
痛みすら伴なってしまう。In particular, when used on skin with acne or dermatitis, it may even cause pain during use.
一方、シューピングフオームのような泡状の皮膚洗浄剤
は、摩擦による泡立てが不要なため、摩擦による皮膚刺
激は避けられるが、この種の皮膚洗浄剤はひげを柔かく
するため石けんをペースとしたものであシ、それ自体皮
膚刺激性を有する。石けん以外の界面活性剤をペースと
した泡状洗浄剤は、泡の安定性が極めて悪く、心地良い
使用感が得られない。On the other hand, foam-like skin cleansers such as Shoeping Foam do not require lathering by friction, so skin irritation due to friction can be avoided. However, it is a skin irritant in itself. Foam cleaning agents based on surfactants other than soap have extremely poor foam stability and do not provide a comfortable feeling when used.
本発明は、皮膚刺激が少なく、優れた泡の安定性を有し
、かつ使用感の良好な泡状皮膚洗浄剤組成物を提供する
ことを目的とする。An object of the present invention is to provide a foamy skin cleansing composition that causes less skin irritation, has excellent foam stability, and is comfortable to use.
本発明は、皮、青刺激の非常に低いＮ−アシル酸性アミ
ノ酸またはその塩をペース界面活性剤として用い、この
物質の低い泡安定性をＮ−アシルペプチド塩および高級
脂肪酸を併用配合するととｋより改善した泡状皮膚洗浄
剤を提供するものである。The present invention uses an N-acyl acidic amino acid or its salt, which has very low skin irritation, as a pace surfactant, and combines the low foam stability of this substance with an N-acyl peptide salt and a higher fatty acid. The present invention provides an improved foam skin cleansing agent.
即ち、本発明の泡状皮膚洗浄剤組成物は、Ｎ−アシル酸
性アミノ酸塩、Ｎ−アシルペプチド９塩および高級脂肪
酸を含有することを特徴とする。That is, the foamy skin cleansing composition of the present invention is characterized by containing an N-acyl acidic amino acid salt, an N-acyl peptide 9 salt, and a higher fatty acid.
本発明の泡状皮膚洗浄剤組成物は、皮膚刺激が少なく、
優れた泡安定性を有し、使用感が良好であるなど、極め
て優れた効果を示す。The foamy skin cleansing composition of the present invention causes less skin irritation and
It has excellent foam stability and feels good when used, showing extremely excellent effects.
本発明の組成物の第１の必須成分であるＮ−アシル酸性
アミノ酸またはその塩として、下記一般式（１）で表わ
される化合物、そのＬ一体、Ｄ一体又は両者の混合物を
用いることができる。As the N-acyl acidic amino acid or its salt, which is the first essential component of the composition of the present invention, a compound represented by the following general formula (1), its L or D, or a mixture of both can be used.
（式中、Ｒは炭素数７〜２１のアルキル基又はアルケニ
ル基、ＭｌおよびＭ２は水素、アルカリ金属、又はアル
カノールアミン基、ｎハ１又は２である。）
一般式（１）の化合物の具体例として、Ｎ−ラウロイル
グルタミン酸、Ｎ−ミリストイルグルタミン酸、Ｎ−／
＃ルミトイルグルタミンＬ Ｎ−ｘテアロイルアスパ
ラギン酸、Ｎ−オレオイルグルタミン酸、Ｎ−ココイル
グルタミン酸、Ｎ−牛脂脂肪酸アシルグルタミン酸、又
はそれらのナトリウム塩、カリウム塩、モノエタノール
アンモニウム塩、ジェタノールアンモニウム塩、トリエ
タノールアンモニウム塩等がある。これら化合物の単独
又は２種以上を混合して用いてもよい。(In the formula, R is an alkyl group or alkenyl group having 7 to 21 carbon atoms, Ml and M2 are hydrogen, an alkali metal, or an alkanolamine group, and n is 1 or 2.) Specifications of the compound of general formula (1) Examples include N-lauroylglutamic acid, N-myristoylglutamic acid, N-/
#Lumitoylglutamine L N-x tearoyl aspartic acid, N-oleoylglutamic acid, N-cocoylglutamic acid, N-tallow fatty acid acylglutamic acid, or their sodium salt, potassium salt, monoethanolammonium salt, jetanolammonium salt, There are triethanolammonium salts, etc. These compounds may be used alone or in combination of two or more.
Ｎ−アシル酸性アミノ酸塩の配合量は、組成物全量に対
し好ましくは１〜２０重量％、更に好ましくは５〜１５
重量％である。The blending amount of the N-acyl acidic amino acid salt is preferably 1 to 20% by weight, more preferably 5 to 15% by weight based on the total amount of the composition.
Weight%.
本発明の組成物の第２の必須成分であるＮ−アシルペプ
チド塩として、下記一般式（２）に示す化合物がある。As the N-acyl peptide salt which is the second essential component of the composition of the present invention, there is a compound represented by the following general formula (2).
ＲＣＯ＋ＮＨＣＨＲ’ Ｃｏ ）ＯＭ ・・・
（２）（式中、、 ＲＣＯＵ炭素数８〜２２の飽和又は
不飽和脂肪酸残基、Ｒ′はアミノ酸中に見出される種々
の基、Ｍは水素、又はアルカリ金属、アルカノールアミ
ンから誘導されるカチオンを示す。）
一般式（２）Ｋ示すＮ−アシルペプチド塩は、天然に存
在する種々のタンノ９り質を、タンバク質分解酵素や塩
酸等の酸又は水酸化ナト１７ウム等のアルカリによ多部
分加水分解して得られる平均 □分子量３００〜
１０００、好ましくは３５０〜６００（Ｄ／リペグチド
（分子末端にはカチオン性基としての−Ｎ′Ｈ２基とア
ニオン性基としての−ＣＯＯＨ基を有する）の−ＮＨ２
基に１炭素数８〜２２の飽和又は不飽和脂肪酸あるいは
それらの酸クロライドを縮合（アシル化）シ、場合によ
ってはその一〇〇〇Ｈ基をアルカリ金属水酸化物又はア
ルカノールアミンによシ中和するととＫよシ得ることが
出来る。RCO+NHCHR'Co)OM...
(2) (wherein, RCOU is a saturated or unsaturated fatty acid residue having 8 to 22 carbon atoms, R' is various groups found in amino acids, M is hydrogen, or a cation derived from an alkali metal or alkanolamine) ) N-acyl peptide salts represented by the general formula (2)K are prepared by converting various naturally occurring tannins into protein-degrading enzymes, acids such as hydrochloric acid, or alkalis such as sodium hydroxide. Average molecular weight obtained by multipartial hydrolysis □Molecular weight 300~
-NH2 of 1000, preferably 350 to 600 (D/ripegutide (having -N'H2 group as a cationic group and -COOH group as an anionic group at the end of the molecule)
saturated or unsaturated fatty acids having 8 to 22 carbon atoms or their acid chlorides are condensed (acylated) to the group, and in some cases, the 1000H group is oxidized with an alkali metal hydroxide or an alkanolamine. If you add them together, you can get K.
Ｎ−アシル化４プチド塩のアシル基（脂肪酸残基）とし
ては、例えばヤシ油脂肪酸、ミリスチン酸、ステアリン
酸、オレイン酸、ウンデシレン酸およびイソステアリン
酸等の脂肪酸の残基が好ましい。As the acyl group (fatty acid residue) of the N-acylated tetrabutide salt, residues of fatty acids such as coconut oil fatty acid, myristic acid, stearic acid, oleic acid, undecylenic acid, and isostearic acid are preferred.
Ｎ−アシル−ｅｆチド塩の配合量は、組成物全量に対し
好ましくは０．１〜５重量％、更に好ましくは０．５〜
３重量％である。The amount of N-acyl-eftide salt to be blended is preferably 0.1 to 5% by weight, more preferably 0.5 to 5% by weight based on the total amount of the composition.
It is 3% by weight.
本発明の組成物の第３の必須成分では高級脂肪酸として
は、炭素数１２〜２２の飽和又は不飽和の直鎖又は分枝
鎖脂肪酸がある。具体的にはラウリン酸、ミリスチン酸
、ノぐルミチン酸、ステアリン酸、ベヘニン酸、オレイ
ン酸、インステアリン酸、ヤシ油脂肪酸、牛脂脂肪酸等
があシ、これらを単独で、又は２種以上混合して用いる
ことが出来る。In the third essential component of the composition of the present invention, higher fatty acids include saturated or unsaturated straight-chain or branched-chain fatty acids having 12 to 22 carbon atoms. Specifically, lauric acid, myristic acid, noglumitic acid, stearic acid, behenic acid, oleic acid, instearic acid, coconut oil fatty acid, beef tallow fatty acid, etc. are used alone or in combination of two or more. It can be used as
高級脂肪酸の配合量は、組成物全量に対し好ましくは０
．１〜１０重量％、更に好ましくは１〜５重量−である
。The amount of higher fatty acid blended is preferably 0 based on the total amount of the composition.
．． It is 1 to 10% by weight, more preferably 1 to 5% by weight.
本発明の泡状皮膚洗浄剤組成物は、上述した必須成分の
他に、本発明の効果をそこなわない範囲で、他のアニオ
ン界面活性剤、ノニオン界面活性剤、炭化水素、高級ア
ルコール、エステル油等の油分、香料、色素、プリオー
ル類、防腐剤、殺菌剤等の公知慣用成分を適宜含有し得
る。In addition to the above-mentioned essential ingredients, the foamy skin cleansing composition of the present invention may contain other anionic surfactants, nonionic surfactants, hydrocarbons, higher alcohols, esters, etc., to the extent that the effects of the present invention are not impaired. Known and commonly used ingredients such as oils, fragrances, pigments, preols, preservatives, and bactericidal agents may be contained as appropriate.
本発明の泡状皮膚洗浄剤組成物は、例えば、Ｎ−アシル
酸性アミノ酸またはその塩とＮ−アシル−ｅｆチド塩と
を水に加温溶解（６５〜７５℃）した後、溶融状態の高
級脂肪酸を攪拌しつつ添加し、乳化し、冷却することに
より原液を調製し、この原液を噴射剤（例えば液化石油
ガス）とともに密封容器に充填することによシ製造する
ことが出来る。The foamy skin cleansing composition of the present invention can be prepared, for example, by dissolving an N-acyl acidic amino acid or its salt and an N-acyl-eftide salt in water under heating (65 to 75°C), and then preparing a molten high-grade It can be produced by preparing a stock solution by adding fatty acids with stirring, emulsifying and cooling, and filling this stock solution together with a propellant (for example, liquefied petroleum gas) into a sealed container.
以下、本発明の実施例と比較例を示し、本発明の効果を
よシ具体的に説明する。なお、各成分の配合量は重量悌
である。EXAMPLES Hereinafter, the effects of the present invention will be explained in more detail by showing examples and comparative examples of the present invention. The amounts of each component are by weight.
各側の説明に先立って、各側で採用した試験法について
説明する。Before explaining each side, we will explain the test methods adopted by each side.
（１）泡の安定性
噴射剤とともに密封容器に充填された試料原液を広口の
円筒ガラス容器中に噴射して一定量の泡を採取し、容器
上部からの水分の蒸発を防いで静置する。噴射直後の泡
高と静置３０分後の泡高から泡高の変化率を求め、次の
基準で泡の安定性を評価した。(1) Stability of foam A sample stock solution filled in a sealed container with a propellant is injected into a wide-mouthed cylindrical glass container, a certain amount of foam is collected, and the container is allowed to stand still while preventing moisture from evaporating from the top of the container. . The rate of change in foam height was determined from the foam height immediately after injection and the foam height after 30 minutes of standing, and the stability of the foam was evaluated based on the following criteria.
Ａ：変化率１％未満 極めて安定な泡Ｂ： ’
１〜５チ 安定な泡
Ｃ： Ｉ ５〜１０チ やや不安定な泡Ｄ： ＃
１０’Ｊ以上 非常に不安定な泡なお、以上の評価
法による泡の安定性は、官能試験による泡の安定性評価
と明確な相関関係を示し、泡高の変化率が小さいほど官
能試験による泡の安定性が良いことが確認されている。A: Extremely stable foam with a change rate of less than 1% B: '
1~5ch Stable foam C: I 5~10ch Slightly unstable foam D: #
10'J or more Very unstable foam Note that the foam stability determined by the above evaluation method shows a clear correlation with the foam stability evaluation by the sensory test, and the smaller the rate of change in foam height, the higher the foam stability by the sensory test. It has been confirmed that the foam has good stability.
（２） 使房感
１８才から３０才の女性２０名を・母ネラーとして用い
、洗顔による・官能試験を行ない、次の基準で評価した
。(2) Embassy 20 women between the ages of 18 and 30 were used as mother nailers, and a sensory test was conducted by washing their faces, and evaluations were made based on the following criteria.
５：摩擦による刺激感はなく非常に良好４：摩擦による
刺激感はわずかにあるが、気にならず良好
３：どちらとも言え８−ない
２：摩擦による刺激感が気になシ、あｔシ良くない
１：摩擦による刺激感があシ、皮膚に疾患があるときは
使いたくない、
なお、２０名の・ｆネラーの評価点の平均値を各試料の
使用感とした。5: Very good, no irritation due to friction 4: There is a slight irritation due to friction, but not bothersome 3: Can't say either way 8- Not 2: I'm concerned about irritation due to friction. Not good 1: There is a feeling of irritation due to friction, and you do not want to use it if you have a skin disease.The average value of the evaluation scores of 20 people was used as the feeling of use for each sample.
一実施例１
第１表に示す配合組成のｓｋｉの泡状皮膚洗浄剤組成物
を調製し、それらの泡の安定性および。Example 1 Ski foam skin cleansing compositions having the formulation shown in Table 1 were prepared, and their foam stability and stability were evaluated.
使用感について評価した。その結果を同表に示す。The usability was evaluated. The results are shown in the same table.
第２表から明らかなように、本発明の３種の必須成分を
含有する組成物（実施例１）は、高い泡の安定性と刺激
感のない優れた使用感を示している。これに対し、本発
明の３種の必須成分の１種又は２１１しか含有しない組
成物（比較例１〜４）はいずれも泡の安定性は低く、使
用感も良くないことがわかる。As is clear from Table 2, the composition containing the three essential components of the present invention (Example 1) exhibits high foam stability and an excellent feeling of use without irritation. On the other hand, it can be seen that all of the compositions containing only one or 211 of the three essential components of the present invention (Comparative Examples 1 to 4) had low foam stability and poor usability.
実施例２，３
第２表に示す配合組成の６種の泡状皮膚洗浄剤組成物を
調製し、それらの泡の安定性訃よび使用感にりいて評価
した。その結果を同表に示す。なお、比較例５〜８では
Ｎ−アシル酸性ブミノ酸塩の代シに他の界面活性剤を用
いた。Examples 2 and 3 Six types of foam skin cleansing compositions having the formulations shown in Table 2 were prepared and evaluated based on the stability of the foam and the feeling of use. The results are shown in the same table. In addition, in Comparative Examples 5 to 8, other surfactants were used in place of the N-acyl acidic bumino acid salt.
第２表から明らかなように、本発明の３種の必須成分を
含有する組成物（実施例２，３）は・、池の安定性、使
用感ともに優れているが、Ｎ−アシル酸性アミノ酸塩の
代シに他の界面活性剤を配合した組成物（比較例５〜８
）は、泡の安定性が劣ることがわかる。As is clear from Table 2, the compositions containing the three essential components of the present invention (Examples 2 and 3) are excellent in both pond stability and usability, but N-acyl acidic amino acids Compositions containing salt and other surfactants (Comparative Examples 5 to 8)
), it can be seen that the foam stability is inferior.
実施例４，５
第３表に示す配合組成の５種の泡状皮膚洗浄剤組成物を
調製し、それらの泡の安定性および使用感について評価
した。その結果を同表に示す。なお、比較例９〜１１で
は高級脂肪酸の代シに他の油性成分を用いた。Examples 4 and 5 Five types of foam skin cleansing compositions having the formulations shown in Table 3 were prepared, and their foam stability and feeling of use were evaluated. The results are shown in the same table. In addition, in Comparative Examples 9 to 11, other oily components were used in place of higher fatty acids.
第３表から明らかなように、本発明の３種の必須成分を
含有する組成物（実施例４，５）は、泡の安定性および
使用感ともに優れているが、高級脂肪酸の代シに他の油
性成分を配合した組成物（比較例９〜１１）は、いずれ
も使用感が劣ることがわかる。As is clear from Table 3, the compositions containing the three essential components of the present invention (Examples 4 and 5) have excellent foam stability and feel when used, but are inferior to higher fatty acid substitutes. It can be seen that all of the compositions containing other oily components (Comparative Examples 9 to 11) have poor feel when used.
実施例６〜１１
第４表に示す配合組成の６種の泡状皮膚洗浄剤組成物を
調製し、それらの泡の安定性および使用感について評価
した。その結果を同表に示すＯ
第４表から明らかなように、各必須成分の配合量が所定
の範囲内にある場合に、特に高い泡の安定性および良好
な使用感が得られることがわかる。Examples 6 to 11 Six types of foam skin cleansing compositions having the formulations shown in Table 4 were prepared, and their foam stability and feeling of use were evaluated. The results are shown in the same table.O As is clear from Table 4, particularly high foam stability and good feeling of use can be obtained when the blending amounts of each essential ingredient are within the specified range. .
Claims (4)
ルペプチド塩および高級脂肪酸を含有することを特徴と
する泡状皮膚洗浄剤組成物。(1) A foamy skin cleansing composition characterized by containing an N-acyl acidic amino acid or its salt, an N-acyl peptide salt, and a higher fatty acid.
一般式で表わされる化合物の１種又は２種以上の混合物
であり、組成物全量に対し１〜２０重量％配合されてい
る特許請求の範囲第１項記載の泡状皮膚洗浄剤組成物。 ▲数式、化学式、表等があります▼ （式中、Ｒは炭素数７〜２１のアルキル基又はアルケニ
ル基、Ｍ＿１およびＭ＿２は水素、アルカリ金属、又は
アルカノールアミン基、ｎは１又は２である。）(2) The claim that the N-acyl acidic amino acid or its salt is one type or a mixture of two or more types of compounds represented by the following general formula, and is blended in an amount of 1 to 20% by weight based on the total amount of the composition. 2. Foamy skin cleansing composition according to item 1. ▲There are mathematical formulas, chemical formulas, tables, etc.▼ (In the formula, R is an alkyl group or alkenyl group having 7 to 21 carbon atoms, M_1 and M_2 are hydrogen, an alkali metal, or an alkanolamine group, and n is 1 or 2. )
〜１０００のポリペプチドと炭素数８〜２２の飽和又は
不飽和脂肪酸との縮合物、又はそのアルカリ金属塩又は
アルカノールアミン塩であり、組成物全量に対し０．１
〜５重量配合されている特許請求の範囲第１項記載の泡
状皮膚洗浄剤組成物。(3) The N-acyl peptide salt has an average molecular weight of 300
~1000 polypeptide and a saturated or unsaturated fatty acid having 8 to 22 carbon atoms, or an alkali metal salt or alkanolamine salt thereof, and 0.1% of the total amount of the composition.
5. The foamy skin cleansing composition according to claim 1, wherein the foamed skin cleansing composition is formulated in an amount of 5 to 5% by weight.
不飽和の直鎖又は分岐鎖脂肪酸の１種又は２種以上の混
合物であり、組成物全量に対し０．１〜１０重量％配合
されている特許請求の範囲第１項記載の泡状皮膚洗浄剤
組成物。(4) The higher fatty acid is one or a mixture of two or more saturated or unsaturated linear or branched fatty acids having 12 to 22 carbon atoms, and is contained in an amount of 0.1 to 10% by weight based on the total amount of the composition. A foamy skin cleansing composition according to claim 1.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP60130866A JPS61291700A (en) | 1985-06-18 | 1985-06-18 | Foamable skin cleaning composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP60130866A JPS61291700A (en) | 1985-06-18 | 1985-06-18 | Foamable skin cleaning composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS61291700A true JPS61291700A (en) | 1986-12-22 |
Family
ID=15044528
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP60130866A Pending JPS61291700A (en) | 1985-06-18 | 1985-06-18 | Foamable skin cleaning composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS61291700A (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4960541A (en) * | 1988-09-30 | 1990-10-02 | Mitsubishi Petrochemical Co., Ltd. | Aqueous liquid detergents containing an N-acyl-aspartate, amine oxide and alkyl ether sulfate |
| US5000877A (en) * | 1988-08-12 | 1991-03-19 | Mitsubishi Petrochemical Co., Ltd. | Aqueous liquid detergent containing an N-acylaspartate and a betaine or imidazoline surfactant |
| FR2762599A1 (en) * | 1997-04-28 | 1998-10-30 | Nippon Fine Chemical Co | ACYLATED PEPTIDES OR ONE OF THEIR SALTS AND COSMETIC COMPOSITION CONTAINING THEM |
| FR2787323A1 (en) * | 1998-12-22 | 2000-06-23 | Seppic Sa | USE OF N-ACYL COMPOUNDS OF AMINO ACIDS AS A TEXTURING AGENT |
| JP2006265338A (en) * | 2005-03-23 | 2006-10-05 | Cognis Japan Ltd | Detergent composition |
| JP2016183134A (en) * | 2015-03-26 | 2016-10-20 | 株式会社マンダム | Skin cleansing foam |
| JP2017095393A (en) * | 2015-11-24 | 2017-06-01 | 株式会社マンダム | Foamy skin cleanser |
-
1985
- 1985-06-18 JP JP60130866A patent/JPS61291700A/en active Pending
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5000877A (en) * | 1988-08-12 | 1991-03-19 | Mitsubishi Petrochemical Co., Ltd. | Aqueous liquid detergent containing an N-acylaspartate and a betaine or imidazoline surfactant |
| US4960541A (en) * | 1988-09-30 | 1990-10-02 | Mitsubishi Petrochemical Co., Ltd. | Aqueous liquid detergents containing an N-acyl-aspartate, amine oxide and alkyl ether sulfate |
| FR2762599A1 (en) * | 1997-04-28 | 1998-10-30 | Nippon Fine Chemical Co | ACYLATED PEPTIDES OR ONE OF THEIR SALTS AND COSMETIC COMPOSITION CONTAINING THEM |
| FR2787323A1 (en) * | 1998-12-22 | 2000-06-23 | Seppic Sa | USE OF N-ACYL COMPOUNDS OF AMINO ACIDS AS A TEXTURING AGENT |
| EP1013266A1 (en) * | 1998-12-22 | 2000-06-28 | Societe D'exploitation De Produits Pour Les Industries Chimiques-Seppic | Use of N-acyl aminoacids as texturing agents |
| US6274151B1 (en) | 1998-12-22 | 2001-08-14 | Societe D'exploitation De Produits Pour Les Industries Chimiques Seppic | Use of n-acylamino acid compounds as texturing agents |
| US6440435B1 (en) | 1998-12-22 | 2002-08-27 | Societe D'exploitation De Produits Pour Les Industries Chimiques Seppic | Use of N-acylamino acid compounds as texturing agents |
| JP2006265338A (en) * | 2005-03-23 | 2006-10-05 | Cognis Japan Ltd | Detergent composition |
| JP2016183134A (en) * | 2015-03-26 | 2016-10-20 | 株式会社マンダム | Skin cleansing foam |
| JP2017095393A (en) * | 2015-11-24 | 2017-06-01 | 株式会社マンダム | Foamy skin cleanser |
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