JPS61284210A - Curtain for controlling insect - Google Patents
Curtain for controlling insectInfo
- Publication number
- JPS61284210A JPS61284210A JP12496885A JP12496885A JPS61284210A JP S61284210 A JPS61284210 A JP S61284210A JP 12496885 A JP12496885 A JP 12496885A JP 12496885 A JP12496885 A JP 12496885A JP S61284210 A JPS61284210 A JP S61284210A
- Authority
- JP
- Japan
- Prior art keywords
- curtain
- chlorinated polyethylene
- repellent
- repellents
- curtains
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 241000238631 Hexapoda Species 0.000 title description 3
- 239000004709 Chlorinated polyethylene Substances 0.000 claims description 19
- 241000607479 Yersinia pestis Species 0.000 claims description 19
- 229920001971 elastomer Polymers 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 7
- 239000000806 elastomer Substances 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 229920006352 transparent thermoplastic Polymers 0.000 claims description 2
- 239000005871 repellent Substances 0.000 description 27
- 230000002940 repellent Effects 0.000 description 27
- 239000003814 drug Substances 0.000 description 10
- 229940079593 drug Drugs 0.000 description 10
- 230000000694 effects Effects 0.000 description 10
- -1 polyethylene Polymers 0.000 description 9
- 150000001408 amides Chemical class 0.000 description 8
- 239000000126 substance Substances 0.000 description 8
- 241000255925 Diptera Species 0.000 description 7
- 239000000077 insect repellent Substances 0.000 description 6
- XLOPRKKSAJMMEW-SFYZADRCSA-M (R,R)-chrysanthemate Chemical compound CC(C)=C[C@@H]1[C@@H](C([O-])=O)C1(C)C XLOPRKKSAJMMEW-SFYZADRCSA-M 0.000 description 5
- 238000002844 melting Methods 0.000 description 5
- 230000008018 melting Effects 0.000 description 5
- 229920002725 thermoplastic elastomer Polymers 0.000 description 5
- 239000004698 Polyethylene Substances 0.000 description 4
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 4
- 239000008187 granular material Substances 0.000 description 4
- 239000002917 insecticide Substances 0.000 description 4
- 229920000573 polyethylene Polymers 0.000 description 4
- 239000005060 rubber Substances 0.000 description 4
- 239000005062 Polybutadiene Substances 0.000 description 3
- 239000000417 fungicide Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 238000005192 partition Methods 0.000 description 3
- 229920002857 polybutadiene Polymers 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 229920002959 polymer blend Polymers 0.000 description 3
- 229920001155 polypropylene Polymers 0.000 description 3
- 229920000915 polyvinyl chloride Polymers 0.000 description 3
- 239000004800 polyvinyl chloride Substances 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 229920003048 styrene butadiene rubber Polymers 0.000 description 3
- 229920003002 synthetic resin Polymers 0.000 description 3
- 239000000057 synthetic resin Substances 0.000 description 3
- 229920001169 thermoplastic Polymers 0.000 description 3
- 239000004416 thermosoftening plastic Substances 0.000 description 3
- ZBVDYZBXFDCDDF-UHFFFAOYSA-N 2,3,6-trimethylbenzamide Chemical compound CC1=CC=C(C)C(C(N)=O)=C1C ZBVDYZBXFDCDDF-UHFFFAOYSA-N 0.000 description 2
- 241001674044 Blattodea Species 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- 239000002174 Styrene-butadiene Substances 0.000 description 2
- 238000013459 approach Methods 0.000 description 2
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- YPHMISFOHDHNIV-FSZOTQKASA-N cycloheximide Chemical compound C1[C@@H](C)C[C@H](C)C(=O)[C@@H]1[C@H](O)CC1CC(=O)NC(=O)C1 YPHMISFOHDHNIV-FSZOTQKASA-N 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 230000000749 insecticidal effect Effects 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 230000005923 long-lasting effect Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- GTCAXTIRRLKXRU-UHFFFAOYSA-N methyl carbamate Chemical compound COC(N)=O GTCAXTIRRLKXRU-UHFFFAOYSA-N 0.000 description 2
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 2
- 229920000098 polyolefin Polymers 0.000 description 2
- 229920002635 polyurethane Polymers 0.000 description 2
- 239000004814 polyurethane Substances 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000011115 styrene butadiene Substances 0.000 description 2
- 238000013268 sustained release Methods 0.000 description 2
- 239000012730 sustained-release form Substances 0.000 description 2
- 230000005068 transpiration Effects 0.000 description 2
- ZMKHZNCBQCXECQ-UHFFFAOYSA-N (2,4-dimethyl-4h-1,3-dioxin-6-yl) acetate Chemical compound CC1OC(C)C=C(OC(C)=O)O1 ZMKHZNCBQCXECQ-UHFFFAOYSA-N 0.000 description 1
- VEMKTZHHVJILDY-PMACEKPBSA-N (5-benzylfuran-3-yl)methyl (1r,3s)-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropane-1-carboxylate Chemical compound CC1(C)[C@@H](C=C(C)C)[C@H]1C(=O)OCC1=COC(CC=2C=CC=CC=2)=C1 VEMKTZHHVJILDY-PMACEKPBSA-N 0.000 description 1
- UKDOTCFNLHHKOF-FGRDZWBJSA-N (z)-1-chloroprop-1-ene;(z)-1,2-dichloroethene Chemical group C\C=C/Cl.Cl\C=C/Cl UKDOTCFNLHHKOF-FGRDZWBJSA-N 0.000 description 1
- ZWBANJRSWNLUEP-UHFFFAOYSA-N 2,2,2-trichloro-1,1-bis(2-chlorophenyl)ethanol Chemical compound C=1C=CC=C(Cl)C=1C(C(Cl)(Cl)Cl)(O)C1=CC=CC=C1Cl ZWBANJRSWNLUEP-UHFFFAOYSA-N 0.000 description 1
- VTJMSIIXXKNIDJ-UHFFFAOYSA-N 2-(4-chlorophenyl)-3-methylbutyric acid Chemical compound CC(C)C(C(O)=O)C1=CC=C(Cl)C=C1 VTJMSIIXXKNIDJ-UHFFFAOYSA-N 0.000 description 1
- QVTWQIWXCYMFQI-CZDSEFAFSA-N 2-[(1r,2r,3s,4r,5r,6s)-3-(diaminomethylideneamino)-4-[(2r,3r,4r,5s)-3-[(2s,3s,4s,5r,6s)-4,5-dihydroxy-6-(hydroxymethyl)-3-(methylamino)oxan-2-yl]oxy-4-formyl-4-hydroxy-5-methyloxolan-2-yl]oxy-2,5,6-trihydroxycyclohexyl]guanidine;trihydrochloride Chemical compound Cl.Cl.Cl.CN[C@H]1[C@H](O)[C@@H](O)[C@H](CO)O[C@H]1O[C@@H]1[C@](C=O)(O)[C@H](C)O[C@H]1O[C@@H]1[C@@H](N=C(N)N)[C@H](O)[C@@H](N=C(N)N)[C@H](O)[C@H]1O QVTWQIWXCYMFQI-CZDSEFAFSA-N 0.000 description 1
- NCDBYAPSWOPDRN-UHFFFAOYSA-N 2-[dichloro(fluoro)methyl]sulfanylisoindole-1,3-dione Chemical compound C1=CC=C2C(=O)N(SC(Cl)(Cl)F)C(=O)C2=C1 NCDBYAPSWOPDRN-UHFFFAOYSA-N 0.000 description 1
- ZDRBJJNXJOSCLR-YZKQBBCCSA-N 2-amino-2-[(2r,3s,5s,6r)-5-amino-2-methyl-6-[(2r,3s,5s,6s)-2,3,4,5,6-pentahydroxycyclohexyl]oxyoxan-3-yl]iminoacetic acid;hydron;chloride Chemical compound Cl.N[C@H]1C[C@H](N=C(N)C(O)=O)[C@@H](C)O[C@@H]1OC1[C@H](O)[C@@H](O)C(O)[C@H](O)[C@@H]1O ZDRBJJNXJOSCLR-YZKQBBCCSA-N 0.000 description 1
- PCLKVJBRTCQNDU-UHFFFAOYSA-N 2-methylsulfonylpyridine Chemical compound CS(=O)(=O)C1=CC=CC=N1 PCLKVJBRTCQNDU-UHFFFAOYSA-N 0.000 description 1
- 241000238876 Acari Species 0.000 description 1
- 241001465677 Ancylostomatoidea Species 0.000 description 1
- NLICKERYPVEIHB-UHFFFAOYSA-N CC1CC(=O)N(C(=O)C1(C)Cl)C2=CC(=CC(=C2)Cl)Cl Chemical compound CC1CC(=O)N(C(=O)C1(C)Cl)C2=CC(=CC(=C2)Cl)Cl NLICKERYPVEIHB-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 229920000181 Ethylene propylene rubber Polymers 0.000 description 1
- 241001466042 Fulgoromorpha Species 0.000 description 1
- 241000287828 Gallus gallus Species 0.000 description 1
- 241000257303 Hymenoptera Species 0.000 description 1
- 241000002163 Mesapamea fractilinea Species 0.000 description 1
- MMOXZBCLCQITDF-UHFFFAOYSA-N N,N-diethyl-m-toluamide Chemical compound CCN(CC)C(=O)C1=CC=CC(C)=C1 MMOXZBCLCQITDF-UHFFFAOYSA-N 0.000 description 1
- 229920000459 Nitrile rubber Polymers 0.000 description 1
- 241000283984 Rodentia Species 0.000 description 1
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical compound ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- PXGQYAOENQJPTC-UHFFFAOYSA-N [Zn].C(N)(S)=S.C(N)(S)=S.C=C Chemical compound [Zn].C(N)(S)=S.C(N)(S)=S.C=C PXGQYAOENQJPTC-UHFFFAOYSA-N 0.000 description 1
- 238000004378 air conditioning Methods 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 230000006399 behavior Effects 0.000 description 1
- RIOXQFHNBCKOKP-UHFFFAOYSA-N benomyl Chemical compound C1=CC=C2N(C(=O)NCCCC)C(NC(=O)OC)=NC2=C1 RIOXQFHNBCKOKP-UHFFFAOYSA-N 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- VFSBFZATUKZTDU-UHFFFAOYSA-N carbamodithioic acid ethene manganese Chemical compound [Mn].C=C.NC(S)=S.NC(S)=S VFSBFZATUKZTDU-UHFFFAOYSA-N 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- CRQQGFGUEAVUIL-UHFFFAOYSA-N chlorothalonil Chemical compound ClC1=C(Cl)C(C#N)=C(Cl)C(C#N)=C1Cl CRQQGFGUEAVUIL-UHFFFAOYSA-N 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical class C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- RHQJCKLIFXAQOG-UHFFFAOYSA-N dimethylcarbamodithioic acid;2-(dithiocarboxyamino)ethylcarbamodithioic acid;zinc Chemical compound [Zn].[Zn].CN(C)C(S)=S.CN(C)C(S)=S.SC(=S)NCCNC(S)=S RHQJCKLIFXAQOG-UHFFFAOYSA-N 0.000 description 1
- XWBDWHCCBGMXKG-UHFFFAOYSA-N ethanamine;hydron;chloride Chemical compound Cl.CCN XWBDWHCCBGMXKG-UHFFFAOYSA-N 0.000 description 1
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 1
- USPVNSDVCUTNJN-UHFFFAOYSA-N ethenyl cyclopropanecarboxylate Chemical compound C=COC(=O)C1CC1 USPVNSDVCUTNJN-UHFFFAOYSA-N 0.000 description 1
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 1
- 239000005038 ethylene vinyl acetate Substances 0.000 description 1
- 229920006244 ethylene-ethyl acrylate Polymers 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 229920000578 graft copolymer Polymers 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 208000015181 infectious disease Diseases 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 230000009545 invasion Effects 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- YKSNLCVSTHTHJA-UHFFFAOYSA-L maneb Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S YKSNLCVSTHTHJA-UHFFFAOYSA-L 0.000 description 1
- 229920000940 maneb Polymers 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- ZWDZJRRQSXLOQR-UHFFFAOYSA-N n-butyl-n-phenylacetamide Chemical compound CCCCN(C(C)=O)C1=CC=CC=C1 ZWDZJRRQSXLOQR-UHFFFAOYSA-N 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920002589 poly(vinylethylene) polymer Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229920005604 random copolymer Polymers 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000003128 rodenticide Substances 0.000 description 1
- 230000000391 smoking effect Effects 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000000638 solvent extraction Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 229940124530 sulfonamide Drugs 0.000 description 1
- 150000003456 sulfonamides Chemical class 0.000 description 1
- 238000013269 sustained drug release Methods 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000003856 thermoforming Methods 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- WJCNZQLZVWNLKY-UHFFFAOYSA-N thiabendazole Chemical compound S1C=NC(C=2NC3=CC=CC=C3N=2)=C1 WJCNZQLZVWNLKY-UHFFFAOYSA-N 0.000 description 1
- KUAZQDVKQLNFPE-UHFFFAOYSA-N thiram Chemical compound CN(C)C(=S)SSC(=S)N(C)C KUAZQDVKQLNFPE-UHFFFAOYSA-N 0.000 description 1
- 238000002834 transmittance Methods 0.000 description 1
- 229960002415 trichloroethylene Drugs 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Landscapes
- Building Environments (AREA)
- Curtains And Furnishings For Windows Or Doors (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明は害虫防除用カーテンに関するもので、蝿、蚤、
ダニ、ゴキブリ、蚊、蟻、昆虫等の害虫が近寄り易い場
所、例えば食品店舗、食品保管倉庫、食品工場、病院、
牛舎、豚舎、鶏舎、大小屋等、或いは上記害虫の侵入を
極度に嫌う場所、例えば薬品、化学成品工場、精密品製
造工場等に好適に使用され、通常のカーテンのように吊
り下げることによって、上記害虫の侵入を防止できる害
虫防除用カーテンに関するものである。DETAILED DESCRIPTION OF THE INVENTION (Field of Industrial Application) The present invention relates to a curtain for controlling pests, including flies, fleas,
Places where pests such as ticks, cockroaches, mosquitoes, ants, and insects can easily approach, such as food stores, food storage warehouses, food factories, hospitals,
Suitable for use in cow sheds, pig pens, chicken houses, large sheds, etc., or places where the invasion of the above pests is extremely discouraged, such as pharmaceutical, chemical product factories, precision product manufacturing factories, etc. By hanging it like a regular curtain, The present invention relates to a pest control curtain that can prevent the above pests from entering.
（従来の技術）
従来、樹脂フィルム等のカーテンは簡易的な間仕切り用
として設置が簡単であることから各所で重用されていた
。かかるカーテンを取付ける目的は冷暖房等による寒気
、暖気の放流防止のため、或いは防虫、防塵等のためで
あったが、このようなカーテンが取付けられている場所
は、人の出入りがあったり、又外から内部が見えるよう
な所に使用されることが多く、そのためカーテンで仕切
った内部に害虫が簡単に侵入できるものであった。又、
害虫が侵入した場合は殺虫剤を噴霧、燻煙、蒸散、散布
等により使用することが多く、そのことによってカーテ
ンで仕切りした内部の空気を悪くする等の問題もあった
。(Prior Art) Conventionally, curtains made of resin films and the like have been widely used as simple room partitions because they are easy to install. The purpose of installing such curtains was to prevent the release of cold and warm air from air conditioning and heating, or to prevent insects and dust, but the place where such curtains are installed is not suitable for areas where people come and go, or where people come and go. They were often used in places where the inside could be seen from the outside, making it easy for pests to get into the curtained interior. or,
When pests invade, insecticides are often used by spraying, smoking, evaporating, dispersing, etc., which poses problems such as worsening the air inside the curtained interior.
また、従来、カーテンとしてポリエチレン、ポリプロピ
レン、ポリ塩化ビニル等の熱可塑性合成樹脂シートやフ
ィルムが使用されており、これらに防虫効果を付与する
方法として比較鉤虫が嫌うオレンジ色に着色したシート
やフィルムがあるが、これらは初期効果が幾分あるもの
の効果の持続性がなく、効果もそれほど顕著でない。In addition, sheets and films of thermoplastic synthetic resins such as polyethylene, polypropylene, and polyvinyl chloride have traditionally been used as curtains, and as a method of imparting an insect repellent effect to these sheets and films, sheets and films colored orange, which hookworms hate, are used. However, although these have some initial effects, the effects are not long-lasting and the effects are not very pronounced.
（発明が解決しようとする問題点）
従来、間仕切りや隔離用として用いられているカーテン
は、その仕切られた内部に例えば食品や明り等があると
、害虫がカーテンの外に群がり、食品の取り出し時や人
の出入りの際、害虫が簡頓に侵入できるものであった。(Problem to be Solved by the Invention) Curtains conventionally used for partitioning or isolating rooms, for example, if there is food or light inside the partition, pests will swarm outside the curtain, making it difficult to take out the food. Pests could easily enter the building at any time or when people came and went.
ところでポリエチレン、ポリプロピレン、ポリ塩化ビニ
ル等の熱可塑性樹脂に忌避剤等の薬剤を混ぜることを試
みても、これらの樹脂は一般に融点が１００″Ｃ以上で
比較的高く、熱可塑性を利用して樹脂の熔融状態で薬剤
を練り込む場合は薬剤の分解あるいは蒸散が激しく、た
とえ少量の分解、蒸散であっても長時間の連続運転では
それが多量に蓄積されるので、製造工程上の安全性や効
率を考慮すれば実用的でない。By the way, even if attempts are made to mix chemicals such as repellents with thermoplastic resins such as polyethylene, polypropylene, and polyvinyl chloride, these resins generally have a relatively high melting point of 100"C or higher, and the melting point of these resins is generally higher than 100"C. When kneading drugs in a molten state, the drug decomposes or evaporates rapidly, and even if there is only a small amount of decomposition or transpiration, a large amount of it will accumulate over long periods of continuous operation, which may affect the safety of the manufacturing process. This is not practical if efficiency is considered.
さらに、薬剤をカーテンの基材表面から蒸散させるため
には、薬剤自体が比較的蒸気圧の低い室温で液体や固体
の物質でなければならず、特に効力の高いものは室温で
蒸散性が高く、これらの薬剤を融点の高い熱可塑性合成
樹脂に混練すれば薬剤の分解や基材表面へのブリードが
起こるという問題があった。Furthermore, in order for the drug to evaporate from the surface of the curtain's base material, the drug itself must be a liquid or solid substance at room temperature with a relatively low vapor pressure, and particularly effective drugs have high transpiration properties at room temperature. However, when these chemicals are kneaded into a thermoplastic synthetic resin having a high melting point, there is a problem in that the chemicals decompose or bleed onto the surface of the base material.
また、間仕切り等の用途として使用される合成樹脂製の
カーテンは、カーテンの向う側がうつすらと見える程度
以上の光透過性が必要であるという条件があった。その
ため、光透過性があり、しかも害虫が近寄らないような
防虫効果があり、さらにその効果は長期に持続性があり
、適度に薬剤の徐放性がコントロールされたカーテンの
開発が切望されていた。Furthermore, synthetic resin curtains used as partitions and the like are required to have a light transmittance that allows the other side of the curtain to be clearly seen. Therefore, there was a strong need for the development of a curtain that is transparent to light, has an insect repellent effect that prevents pests from approaching, has a long-lasting effect, and has appropriately controlled sustained drug release. .
（問題点を解決するための手段）
上記問題点を解決するため、鋭意研究を行った結果、害
虫防除剤を含む透明性のある塩素化ポリエチレン単独、
又は該塩素化ポリエチレンと該塩素化ポリエチレンの屈
折率と略近似の屈折率を有する透明性のある他の熱可塑
性エラストマーとをブレンドしたものを、シート状又は
フィルム状に成形することによって、目的の防虫用カー
テンの発明を完成するに至った。(Means for solving the problem) In order to solve the above problem, as a result of intensive research, we found that transparent chlorinated polyethylene containing pest control agent alone,
Or, by forming a blend of the chlorinated polyethylene and another transparent thermoplastic elastomer having a refractive index approximately similar to that of the chlorinated polyethylene into a sheet or film, the desired object can be obtained. He completed the invention of insect-proof curtains.
害虫防除剤としては種々の薬剤が挙げられるが、本発明
に特に有効に用いられるものはアミド系忌避剤である。Although there are various types of insect repellents, amide repellents are particularly effective in the present invention.
アミド系忌避剤としては、Ｎ、 Ｎ−ジエチル−ｍ−ト
ルアミド、Ｎ−ブチルアセトアニリドやプロピルＮ、Ｎ
−ジエチルサクシナメート等を挙げることができ、これ
らの忌避剤の一種又は二種以上が用いられる。Amide repellents include N,N-diethyl-m-toluamide, N-butylacetanilide and propyl N,N.
-diethyl succinamate, etc., and one or more of these repellents can be used.
そして殺虫、防虫殺菌用としての効果を発揮させるため
には上記のアミド系忌避剤に下記の殺虫剤や防虫剤、殺
菌剤等を適量混入して使用される。殺虫剤としては３−
アリル−２−メチルシクロジンター２−エン−４−オン
−１−イル ｄＡ−シス／トランスークリサンテマート
、３−アリル−２−メチルシクロペンタ−２−エン−４
−オン−１−イル ｄ−シス／トランスークリサンテマ
ート、ｄ−３−アリル−２−メチルシクロペンタ−２−
エン−４−オン−１−イル−ｄ−）ランスークリサンテ
マート、３−アリル−２−メチルシクロペンタ−２−エ
ン−４−オン−１−イルｄ−トランスークリサンテマー
ト、５−ベンジル−３−フリルメチル ｄ−シス／トラ
ンスークリサンテマート、５−（２−プロパギル）−３
−フリルメチルクリサンテマート、３−フェノキシベン
ジル ２，２−ジメチル−３−（２’、２’−ジクロロ
）ビニルシクロプロパンカルボキシレート、３−フェノ
キシベンジル ｄ−シス／トランス−クリサンナマー）
、Ｏ，Ｏ−イソブロボキシフヱニルメチルカーバメート
、０，０−ジメチル０−（３−メチル−４−ニトロフェ
ニル）チオノフォスフェート、０，０−ジエチル ０−
２−イソプロピル−４−メチル−ピリミジル−６−チオ
フォスフェート、Ｎ−（３，４，５，６−チトラヒドロ
フタリミド）−メチル ｄＡ’−シス／トランスークリ
サンテマート、ｏ、ｏ−′ジメチル ５−（１，２−ジ
カルボエトキシエチル）−ジメチオフォスフェート、α
−イソプロピル−４−クロロフェニルアセテート、Ｏ−
（４−ブロモ−２゜５−ジクロロフェニル）０，０−ジ
メチルホスホロチオエートなどが挙げられる。In order to exhibit its insecticidal and insecticidal effects, the above-mentioned amide repellent is mixed with appropriate amounts of the following insecticides, repellents, fungicides, etc. 3- as an insecticide
Allyl-2-methylcyclodinter-2-en-4-one-1-yl dA-cis/trans-chrysanthemate, 3-allyl-2-methylcyclopent-2-ene-4
-on-1-yl d-cis/trans-chrysanthemate, d-3-allyl-2-methylcyclopenta-2-
en-4-one-1-yl-d-)trans-chrysanthemate, 3-allyl-2-methylcyclopent-2-en-4-one-1-yl d-trans-chrysanthemate, 5- Benzyl-3-furylmethyl d-cis/trans-chrysanthemate, 5-(2-propargyl)-3
-Furylmethyl chrysanthemate, 3-phenoxybenzyl 2,2-dimethyl-3-(2',2'-dichloro)vinylcyclopropanecarboxylate, 3-phenoxybenzyl d-cis/trans-chrysannamer)
, O,O-isobroboxyphenyl methyl carbamate, 0,0-dimethyl 0-(3-methyl-4-nitrophenyl)thionophosphate, 0,0-diethyl 0-
2-isopropyl-4-methyl-pyrimidyl-6-thiophosphate, N-(3,4,5,6-titrahydrophthalimido)-methyl dA'-cis/trans-chrysanthemate, o, o-'dimethyl 5-(1,2-dicarboethoxyethyl)-dimethiophosphate, α
-isopropyl-4-chlorophenylacetate, O-
(4-bromo-2°5-dichlorophenyl)0,0-dimethylphosphorothioate and the like.
また、殺菌剤としては、２，４．４’−）ジクロロ−２
′−ハイドロキシジフエニルエーテル、２．３，５．６
−チトラクロロー４ （メチルスルフォニル）ピリジン
、アルキルヘンシルジメチルアンモニウムクロライド、
ヘンシルメチル ２−（２−（ｐ−１，１，３，３−テ
トラメチルブチルフェノキシ）エトキシ〕エチル アン
モニウムクロライド、４−イソプロピルトロボロン Ｎ
。In addition, as a bactericidal agent, 2,4.4'-)dichloro-2
'-Hydroxydiphenyl ether, 2.3, 5.6
-Titrachloro4 (methylsulfonyl)pyridine, alkylhensyldimethylammonium chloride,
Hensylmethyl 2-(2-(p-1,1,3,3-tetramethylbutylphenoxy)ethoxy]ethyl ammonium chloride, 4-isopropyltroborone N
.
Ｎ−ジメチル−Ｎ−フェニル−Ｎ−（フルオロジクロロ
メチルチオ）スルフォンアミド、２− （４′チアゾリ
ル）ベンズイミダゾール、Ｎ−（フルオロジクロロメチ
ルチオ）−フタールイミド、６−アセトキシ−２，４−
ジメチル−ｍ−ジオキシン、エチレンビス（ジチオカル
バミド酸）亜鉛、エチレンビス（ジチオカルバミド酸）
マンガン、亜鉛マンネブ錯化合物、ビス（ジメチルジチ
オカルバミド酸）エチレンビス（ジチオカルバミド酸）
二亜鉛、ビス（ジメチルチオカルバモイル）ジスルフィ
ド、クロトン酸２，６−シニトロー４−オクチルフェニ
ル反応異性体混合物、Ｎ−）ジクロロメチルチオテトラ
ヒドロフタルイミド、２゜３−ジシアノ−１，４−ジチ
アアントラキノン、２．４−ジクロロ−６−（ｐ−クロ
ロアニリン）−３−トリアジン、５−ｎ−ブチル５ｌ−
ｐ−ターシャリ−ブチルベンジルＮ−３−ピリジルジチ
オカルボンイミデート、Ｎ−（３’、５’−ジクロロフ
ェニル）−１，２−ジメチルクロロプロパンジカルボキ
シイミド、ビス（クロロフェニル）トリクロロエタノー
ル、６−メチルキノキサリン−２，３−ジチオカーボネ
ート、テトラクロロイソフタロニトリル、メチル−１−
（ブチルカルバモイル）−２−ベンゾイミダゾールカー
バメート、プラストサイジンＳ−ペンジルアミノベンゼ
ンスルホ糸−１・、ストレプトマイシン塩酸塩、カスガ
マイシン塩酸塩、シクロへキシミド等が挙げられる。N-dimethyl-N-phenyl-N-(fluorodichloromethylthio)sulfonamide, 2-(4'thiazolyl)benzimidazole, N-(fluorodichloromethylthio)-phthalimide, 6-acetoxy-2,4-
Dimethyl-m-dioxin, ethylene bis(dithiocarbamic acid) zinc, ethylene bis(dithiocarbamic acid)
Manganese, zinc maneb complex compound, bis(dimethyldithiocarbamic acid) ethylene bis(dithiocarbamic acid)
Dizinc, bis(dimethylthiocarbamoyl) disulfide, 2,6-cynitro-4-octylphenyl crotonic acid isomer mixture, N-)dichloromethylthiotetrahydrophthalimide, 2゜3-dicyano-1,4-dithianthraquinone, 2 .4-dichloro-6-(p-chloroaniline)-3-triazine, 5-n-butyl 5l-
p-Tertiary-butylbenzyl N-3-pyridyldithiocarbonimidate, N-(3',5'-dichlorophenyl)-1,2-dimethylchloropropane dicarboximide, bis(chlorophenyl)trichloroethanol, 6-methylquinoxaline- 2,3-dithiocarbonate, tetrachloroisophthalonitrile, methyl-1-
(Butylcarbamoyl)-2-benzimidazole carbamate, plasticidin S-pendylaminobenzene sulfonite-1, streptomycin hydrochloride, kasugamycin hydrochloride, cycloheximide, and the like.
上記のような忌避剤や殺菌剤等よりなる害虫防除剤は、
塩素化ポリエチレンと混合して顆粒状となし、この混合
物を熱可塑性プラスチックと混線して熱成形するのであ
る。また、用途に応じて上記の薬剤の他に殺鼠剤、譬歯
類動物用忌避剤、鳥類用忌避剤、香料、共力剤、帯電防
止剤、除塵剤ん等も併用できることは勿論である。Pest control agents such as repellents and fungicides as mentioned above are
It is mixed with chlorinated polyethylene to form granules, and this mixture is mixed with thermoplastic and thermoformed. It goes without saying that in addition to the above-mentioned drugs, rodenticides, rodent repellents, bird repellents, perfumes, synergists, antistatic agents, dust removers, etc. can also be used depending on the purpose.
また上記化の熱可塑性。エラストマーとしてはポリオレ
フィン系（エチレン−プロピレンポリマー）、スチレン
ブタジェン系（スチレン−ブタジェン共重合体）、塩ビ
系（軟質塩ビ、塩ビニトリルラバーブレンド体、塩ビウ
レタン共重合体）。Also the above mentioned thermoplasticity. Elastomers include polyolefin (ethylene-propylene polymer), styrene-butadiene (styrene-butadiene copolymer), and vinyl chloride (soft vinyl chloride, vinyl chloride nitrile rubber blend, and vinyl urethane copolymer).
ポリウレタン系、ポリエステル系、エチレン−プロピレ
ンラバー、エチレン−エチルアクリレート共重合体、エ
チレン酢酸ビニル共重合体、及びシンジオタクチック１
．２−ポリブタジェンなど融点の低いものが挙げられ、
好ましくは融点１００°Ｃ以下のものが用いられる。こ
れらはブレンドした時、相分離を起こして透明性を失わ
ない程度の量比でブレンドしなければならない。Polyurethane-based, polyester-based, ethylene-propylene rubber, ethylene-ethyl acrylate copolymer, ethylene-vinyl acetate copolymer, and syndiotactic 1
．． Examples include those with low melting points such as 2-polybutadiene,
Preferably, those having a melting point of 100°C or less are used. These must be blended in such a proportion that phase separation will not occur and transparency will not be lost when blended.
（作用）
塩素化ポリエチレンは常温で液状のアミド系忌避剤に対
して極めて親和性に富み、その含有率を高くでき、しか
も塩素化ポリエチレンはパウダー状であり、アミド系忌
避剤を均一に含浸させることができ、これを顆粒状とし
て熱成形できるものである。一方、前記熱可塑性エラス
トマーは、その分子構造（特にポリマーの側鎖や共重合
成分）に起因する化学的性質により忌避剤との親和性の
程度が左右される。(Function) Chlorinated polyethylene has an extremely high affinity for amide repellents, which are liquid at room temperature, and its content can be increased, and since chlorinated polyethylene is in powder form, it can be uniformly impregnated with amide repellents. This can be thermoformed into granules. On the other hand, the degree of affinity of the thermoplastic elastomer with the repellent is determined by the chemical properties resulting from its molecular structure (particularly the side chains of the polymer and copolymer components).
またエラストマーの種類（ブロック共重合体。Also types of elastomers (block copolymers.
グラフト共重合体、ランダム共重合体、単独重合体、ブ
レンド体、化学修飾体など）によっては非拘束成分のゴ
ム相に対して種々の拘束部分（凍結相、水素結合、結晶
相イオン架橋等）が存在し、この物理的構造が薬剤の保
持と放出を多様にコントロールすると考えられる。一般
にゴム相は分子がランダムの状態であるために薬剤の保
持成分となり、拘束部分は分子が緻密にそろった集合体
を形成しているので、薬剤の放出をコントロールする成
分として作用すると考えられる。またポリマーブレンド
により生ずるポリマー間の界面は薬剤が成形体の内部か
ら表面へ移行する微細な通路を形成すると考えられる。Depending on the type of polymer (graft copolymer, random copolymer, homopolymer, blend, chemically modified product, etc.), various restraints (frozen phase, hydrogen bonding, crystalline phase ionic crosslinking, etc.) may be present in the rubber phase of the unrestricted component. exists, and this physical structure is thought to control drug retention and release in various ways. In general, the rubber phase is a drug-retaining component because the molecules are in a random state, and the constrained part forms a densely arranged aggregate of molecules, so it is thought to act as a component that controls the release of the drug. It is also believed that the interface between the polymers created by the polymer blend forms fine passages through which the drug migrates from the interior of the molded article to the surface.
以上の如き要因が絡まって薬剤の徐放性がうまくコント
ロールされると考えられる。ところで塩素化ポリエチレ
ンは、塩素含有率３０〜４５ｗｔ％で構造的にはエチレ
ン３塩化ビニル、１，２−ジクロルエチレンの三元共重
合体と見られており、原料のポリエチレンの結晶化度に
相応して結晶相とゴム相から形成されている。結晶相で
ある拘束部分は擬似ラメラの硬質相である。また化学的
にはポリエチレンとポリ塩化ビニルの中間的性質を示す
以下の構造を有している。It is thought that the factors mentioned above work together to effectively control the sustained release of the drug. By the way, chlorinated polyethylene has a chlorine content of 30 to 45 wt% and is structurally considered to be a terpolymer of ethylene trichloride and 1,2-dichloroethylene, and the crystallinity of the raw material polyethylene Correspondingly, it is formed from a crystalline phase and a rubbery phase. The constrained portion, which is a crystalline phase, is a pseudo-lamellar hard phase. Chemically, it has the following structure showing intermediate properties between polyethylene and polyvinyl chloride.
このパウダー状の塩素化ポリエチレンと前述した忌避剤
を混合すると、後者は前者に非常に良く吸収される。両
者を混合した場合、塩素化ポリエチレンの結晶化度が１
０〜２５％と比較的高い場合は、混合初期において前記
忌避剤は塩素化ポリエチレンに吸収されにくいが、時間
を経ると忌避剤は徐々に吸収されてカステラ状に膨潤し
てくる。When this powdered chlorinated polyethylene is mixed with the repellent described above, the latter is very well absorbed by the former. When both are mixed, the crystallinity of chlorinated polyethylene is 1.
If the repellent is relatively high, such as 0 to 25%, the repellent is not easily absorbed by the chlorinated polyethylene in the early stage of mixing, but as time passes, the repellent is gradually absorbed and swells into a castella shape.
一方、結晶化度が約５％までの比較的低い場合は忌避剤
の吸収が速く吸収した粉体が塊状となる。On the other hand, when the degree of crystallinity is relatively low, up to about 5%, the repellent is absorbed quickly and the absorbed powder becomes lumpy.
従って、本発明に適する塩素化ポリエチレンは拘束部分
である結晶相の少ない換言すればゴム相の多いものが好
ましい。Therefore, it is preferable that the chlorinated polyethylene suitable for the present invention has less crystal phase, which is a constrained part, or in other words, more rubber phase.
また、分子量の高いもの、例えば１０〜２０万程度のも
のは、忌避剤を徐々に吸収し、全体がブロック塊となる
。このものを使用すると透明性はあまり良くない。分子
量の低いもの、例えば５万以下のものは忌避剤を吸収し
ても粉体状であり、透明性も極めて良好である。Moreover, those with a high molecular weight, for example, those with a molecular weight of about 100,000 to 200,000, absorb the repellent gradually, and the whole becomes a block mass. Transparency is not very good when using this product. Those with a low molecular weight, for example, those with a molecular weight of 50,000 or less, remain powder-like even after absorbing the repellent, and have extremely good transparency.
一方、前記可塑性エラストマー成分のうち比較的極性の
少ないポリオレフィン系、スチレン−ブタジェン系、■
、２−ポリブタジェン等はアミド系忌避剤との親和性が
殆どな（、ゴム相あるいはポリマーブレンドの界面は物
理的に若干忌避剤を保持するが、結晶相の多少により本
質的に忌避剤の放出に作用する。On the other hand, among the plastic elastomer components, polyolefin type, styrene-butadiene type, which has relatively low polarity,
, 2-polybutadiene, etc. have little affinity with amide-based repellents (the interface of the rubber phase or polymer blend physically retains the repellent to some extent, but the amount of crystalline phase essentially prevents the release of the repellent). It acts on
幾分極性基を含むエチレン−酢ビ共重合体、塩ビ系ポリ
ウレタン系などは中間的な作用を有する。ごのためエラ
ストマーのブレンド成分は忌避剤の放出の度合を考慮し
て自由に選択できる。一般にアミド系の忌避剤はＩＭ量
％以上で効果が顕著であり、実用的には効果の持続性と
コストを考慮して５〜２０％程度が好ましいが用途によ
っては４０〜５０％を含有する場合もある。塩素化ポリ
エチレンは透明性の良好な結晶化度が５〜２５％のもの
を使用するとよい。Ethylene-vinyl acetate copolymers, vinyl chloride polyurethane systems, etc. containing somewhat polar groups have intermediate effects. The blend components of the elastomer can be freely selected with consideration to the degree of repellent release. Generally, amide repellents are most effective when the amount of IM is % or more, and in practical terms, it is preferably about 5 to 20% in consideration of the sustainability of the effect and cost, but depending on the use, the content is 40 to 50%. In some cases. It is preferable to use chlorinated polyethylene having good transparency and crystallinity of 5 to 25%.
そして、塩素化ポリエチレンの屈折率に近い熱可塑性エ
ラストマーとして１．２−ポリブタジェンが挙げられる
が、その他の熱可塑性エラストマーであっても、カーテ
ンとしてカーテンの向う側にうつすらと物が見える程度
の光透過度を有するものであれば本発明の熱可塑性エラ
ストマーとしては使用可能である。また殺虫剤や殺菌剤
はそれ自身単独で混入する場合もあるが徐放的効果を発
揮させるためには、アミド系忌避剤と併用させることに
より有効にその効果を出させることができる。1,2-polybutadiene is an example of a thermoplastic elastomer with a refractive index close to that of chlorinated polyethylene, but even other thermoplastic elastomers can be used as a curtain to transmit light to the extent that objects can be seen on the other side of the curtain. The thermoplastic elastomer of the present invention can be used as long as the thermoplastic elastomer has a certain temperature. Insecticides and fungicides may be mixed alone, but in order to exert a sustained release effect, they can be effectively used in combination with an amide repellent.
又、シート状、フィルム状に熱成形するための手段は従
来公知の押出成形やプレス成形等によって成形加工すれ
ばよい。又、用途によっては、シート状の内部にガラス
繊維やその他の繊維や糸状部をラミネート等によって入
れることも可能である。その他、本発明によるシート状
あるいはフィルム状物を短冊状或いは帯状、紐状に切っ
てそのままカーテンと同様に使用する場合や、それを他
の物に貼ってカーテンと同じように使用する場合も本発
明の概念を逸脱するものではない。In addition, the means for thermoforming into a sheet or film may be formed by conventionally known extrusion molding, press molding, or the like. Further, depending on the use, it is also possible to insert glass fibers, other fibers, or thread-like parts into the sheet-like interior by laminating or the like. In addition, this invention also applies when cutting the sheet-like or film-like material according to the present invention into strips, strips, or strings and using it as it is in the same way as a curtain, or when pasting it on another object and using it in the same way as a curtain. This does not deviate from the concept of the invention.
（効果）
本発明による害虫防除用カーテンは長期にわたって持続
的に適度の薬剤を放出するので、害虫は該カーテンに近
寄らず、本発明品を間仕切り等に使用した場合、人の出
入りによって害虫が侵入することを防ぐことができ、し
かもカーテン自身が薬剤によって汚れたすせず、さらに
光透過性であるので従来のカーテンと同様の使用が可能
であるという利点がある。特に、食品工場や病院等に使
用した場合、ゴキブリに対して顕著な効果があり、又犬
小屋等に使用すれば蚊の防除ができフィラリアにかかる
ことを防止できる。(Effect) The pest control curtain according to the present invention continuously releases an appropriate amount of chemicals over a long period of time, so pests do not come close to the curtain. Moreover, the curtains themselves are free from stains caused by chemicals, and since they are transparent, they can be used in the same way as conventional curtains. In particular, when used in food factories, hospitals, etc., it has a remarkable effect on cockroaches, and when used in dog kennels, etc., it can control mosquitoes and prevent heartworm infections.
次に本発−明の具体的実施例を示す。Next, specific examples of the present invention will be shown.
（実施例）
１）塩素化ポリエチレン〔商品８二ダインラックＧ
−２３５，大阪曹達（株））３００部に忌避剤としてジ
メチルトルアミドを塩素化ポリエチレンに５ｆｆｉｆｆ
ｉ％をバーチカルグラニユレータ−を用いて混合して程
良い顆粒状とした。これを押出機を用いて１００℃〜１
１０℃にて押出し、２ｍｍの軟質シート状の防虫用カー
テンを作成した。(Example) 1) Chlorinated polyethylene [Product 8 Two Dyne Rack G
-235, Osaka Soda Co., Ltd. 300 parts dimethyltoluamide as a repellent to chlorinated polyethylene 5ffiff
i% was mixed using a vertical granulator to form moderate granules. This is heated to 100℃ using an extruder.
It was extruded at 10° C. to produce a 2 mm soft sheet-like insect repellent curtain.
２）塩素化ポリエチレン〔商品８二ダインラックＧ
−２３５，大阪曹達（株））３００部と１゜２−ポリブ
タジェン〔商品名：ＪＳＲＲＢ−８１０、日本合成ゴム
（株）〕 １０部を混ぜ、このポリマーブレンド物に忌
避剤としてジメチルトルアミド１０ｍｆｆ１％をバーチ
カルグラニユレータ−を用いて混合して顆粒状とした。2) Chlorinated polyethylene [Product 8 Two Dyne Rack G
-235, Osaka Soda Co., Ltd.) and 10 parts of 1゜2-polybutadiene [trade name: JSRRB-810, Japan Synthetic Rubber Co., Ltd.] were mixed, and this polymer blend was mixed with 10mff1% of dimethyltoluamide as a repellent. were mixed into granules using a vertical granulator.
これを押出機を用いてｉｏｏ℃〜１１０°Ｃにて押出し
、２ｍｍの軟質シート状の防虫用カーテンを作成した。This was extruded using an extruder at 100°C to 110°C to produce a 2 mm soft sheet-like insect repellent curtain.
これらのシートは、いずれも光を透過し、カーテンを通
して向うが充分見える程度の透明性を有しているもので
ある。これを食品包装等に使用されているアルミホイル
製造工場で使用テストを行った。従来使用されているカ
ーテンと上記実施例１）及び実施例２）のカーテンをそ
れぞれ高ざ３ｍ、中５ｍの大きさで並用して吊り下げ、
害虫の集まり数を調べた。その結果、実施例１）及び実
施例２）のカーテンの外側には害虫がほとんど見当たら
ず、従来のカーテンの外側にはウンカ等の害虫が１０日
間で２３７匹確認された。その後継続してテストを行っ
たが、３ケ月経ても本実絶品の効果に変化は見られなか
った。All of these sheets transmit light and have sufficient transparency to allow light to be seen through the curtain. This product was tested at a factory that manufactures aluminum foil, which is used for food packaging, etc. The conventionally used curtains and the curtains of Example 1) and Example 2) were hung side by side with a height of 3 m and a medium size of 5 m, respectively.
The number of pests gathered was investigated. As a result, almost no pests were found on the outside of the curtains of Example 1) and Example 2), and 237 pests such as planthoppers were found on the outside of the conventional curtain over 10 days. After that, tests were continued, but no change was observed in the effectiveness of Honjitsuzeppin even after three months.
また、室内に大小屋を設けてその中に犬を鎖で繋ぎ、こ
の大小屋の入り口に実施例１）のカーテンを吊りさげて
から、室内に蚊を１００匹放ち、その挙動を観察した。In addition, a large shed was set up indoors, a dog was chained inside, the curtain of Example 1) was hung at the entrance of the large shed, and 100 mosquitoes were released into the room and their behavior was observed.
蚊は入り口付近に近づこうとはせず、１０時間の観察の
間、−匹の蚊も大小屋内に進入しなかった。同様の実験
を３ケ月後に再度行ったが、カーテンの防虫効果は低下
しておらず、最初の観察のときと同じく一匹の蚊も大小
屋内に進入しなかった。Mosquitoes did not try to approach the entrance area, and during the 10 hours of observation, not a single mosquito entered the large hut. A similar experiment was conducted again three months later, but the insect repellent effect of the curtains did not decrease, and as with the first observation, not a single mosquito entered the large hut.
Claims (1)
レン単独、又は該塩素化ポリエチレンと該塩素化ポリエ
チレンの屈折率と略近似の屈折率を有する透明性のある
他の熱可塑性エラストマーとをブレンドしたものを、シ
ート状又はフィルム状に成形したことを特徴とする害虫
防除用カーテン。(1) Transparent chlorinated polyethylene alone containing a pest control agent, or the chlorinated polyethylene and another transparent thermoplastic elastomer having a refractive index approximately similar to that of the chlorinated polyethylene. A pest control curtain characterized by forming a blend into a sheet or film.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP12496885A JPS61284210A (en) | 1985-06-07 | 1985-06-07 | Curtain for controlling insect |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP12496885A JPS61284210A (en) | 1985-06-07 | 1985-06-07 | Curtain for controlling insect |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS61284210A true JPS61284210A (en) | 1986-12-15 |
| JPH0533042B2 JPH0533042B2 (en) | 1993-05-18 |
Family
ID=14898673
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP12496885A Granted JPS61284210A (en) | 1985-06-07 | 1985-06-07 | Curtain for controlling insect |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS61284210A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002114606A (en) * | 2000-10-04 | 2002-04-16 | Okamoto Ind Inc | Mothproof sheet |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4934461A (en) * | 1972-08-02 | 1974-03-29 |
-
1985
- 1985-06-07 JP JP12496885A patent/JPS61284210A/en active Granted
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4934461A (en) * | 1972-08-02 | 1974-03-29 |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002114606A (en) * | 2000-10-04 | 2002-04-16 | Okamoto Ind Inc | Mothproof sheet |
| JP4651174B2 (en) * | 2000-10-04 | 2011-03-16 | オカモト株式会社 | Insect-proof partition sheet |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0533042B2 (en) | 1993-05-18 |
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