JPS6126785A - Manufacture of heat exchanger member - Google Patents
Manufacture of heat exchanger memberInfo
- Publication number
- JPS6126785A JPS6126785A JP14792884A JP14792884A JPS6126785A JP S6126785 A JPS6126785 A JP S6126785A JP 14792884 A JP14792884 A JP 14792884A JP 14792884 A JP14792884 A JP 14792884A JP S6126785 A JPS6126785 A JP S6126785A
- Authority
- JP
- Japan
- Prior art keywords
- tube
- heat exchanger
- heat transfer
- powder
- porous layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C26/00—Coating not provided for in groups C23C2/00 - C23C24/00
- C23C26/02—Coating not provided for in groups C23C2/00 - C23C24/00 applying molten material to the substrate
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Other Surface Treatments For Metallic Materials (AREA)
Abstract
Description
【発明の詳細な説明】
産業上の利用分野
本発明は熱移動により流体を加熱又は冷却する熱交換器
用部材の製造方法に関するものである。DETAILED DESCRIPTION OF THE INVENTION Field of the Invention The present invention relates to a method of manufacturing a member for a heat exchanger that heats or cools a fluid by heat transfer.
従来例の構成とその問題点
従来熱交換器部材としては熱交換部分の接触面積を可及
的に大きくするように伝熱表面の工夫をされてきた。し
かし近年その効率をさらに改善するものとして多孔質の
金属層を設けたものが提案されているが、これは沸騰伝
熱の促進を利用する蒸発器用管部材として特に有効なこ
とが実証されている。従来、金属物体上に多孔質層を形
成する方法として、金属粉末を焼結あるいは特殊なろう
材を用いて接着する方法がある。これらの方法はいずれ
も高温で長時間処理する共通の欠点を有している。又、
一般に空調用に用いられる熱交換器はアルミニウムフィ
ンと銅円管で構成されておシ、特にその効果が期待され
る銅円管内に金属粉末を焼結する等の方法はAlの融点
以上になること及び円管内に均一に長距離にわたって多
孔質層を形成することが不可能なことからして極めて困
難で実用化に至らなかった。Conventional Structures and Problems Conventional heat exchanger members have been designed with heat transfer surfaces to maximize the contact area of heat exchange parts. However, in recent years, a porous metal layer has been proposed to further improve its efficiency, and this has been proven to be particularly effective as a tube member for evaporators that utilizes the promotion of boiling heat transfer. . Conventionally, as a method for forming a porous layer on a metal object, there is a method of sintering metal powder or bonding it using a special brazing material. All of these methods have the common drawback of high temperature and long processing times. or,
Generally, heat exchangers used for air conditioning are composed of aluminum fins and copper circular tubes, and methods such as sintering metal powder inside copper circular tubes, which are expected to be particularly effective, have a temperature higher than the melting point of Al. In addition, it is extremely difficult to form a porous layer uniformly over a long distance within a circular pipe, and it has not been put to practical use.
発明の目的
そこで本発明は、Alに影響を与えない温度以下で熱処
理ができ、長管路においても多孔質の層を形成すること
が可能な且つ産業上容易な多孔質層を形成する方法を提
供するものである。Purpose of the Invention Therefore, the present invention provides a method for forming a porous layer that can be heat-treated at a temperature below that does not affect Al, that can form a porous layer even in a long pipe, and that is industrially easy. This is what we provide.
発明の構成 すなわち、本発明はハンダ中に亜鉛粉末を混入。Composition of the invention That is, the present invention mixes zinc powder into solder.
溶融しながら、蒸発管内伝熱表面にコーティングしてや
り、冷却した後酸にてZnのみをエツチングし、多孔質
層を形成するようにしたものである。While melting, the heat transfer surface inside the evaporation tube is coated, and after cooling, only the Zn is etched with acid to form a porous layer.
実施例の説明 以下本発明の一実施例を添付図面に従って説明する。Description of examples An embodiment of the present invention will be described below with reference to the accompanying drawings.
第1図の冷凍空調用熱交換器において、フィン1はAl
より成り、管2はCuより成り、機械的にCu管を拡管
することにより組み立てられた構造をしている。フィン
1側には被冷却用空気3が流れ、管2内にはフロン系冷
媒4が流れ、蒸発器の場合、沸騰−強制対流伝熱状態に
なっている。In the heat exchanger for refrigeration and air conditioning shown in Fig. 1, the fins 1 are made of Al
The tube 2 is made of Cu and has a structure assembled by mechanically expanding the Cu tube. Air to be cooled 3 flows on the fin 1 side, and a fluorocarbon-based refrigerant 4 flows in the tube 2, and in the case of an evaporator, a boiling-forced convection heat transfer state is established.
この場合、管2の内壁面に5oμ〜200μ程の空孔を
もつ多孔質を形成すれば、管内側の沸騰−強制対流熱伝
達率を3〜10倍向上する極めて高い効果が得られるこ
とが実証されている。In this case, if a porous material with pores of about 5 to 200 microns is formed on the inner wall surface of the tube 2, an extremely high effect of improving the boiling-forced convection heat transfer coefficient inside the tube by 3 to 10 times can be obtained. Proven.
この管2内にPb −Sn用ハンダフラックスを流入し
、管2内に7ラツクスをコーティングする。Pb--Sn solder flux is introduced into the tube 2 to coat the inside of the tube 2 with 7 lux.
次に熱交換器を3oo℃程度の炉温を持つチャンバーに
入れ、熱交換器フィン1側をこの炉温空気にて冷却しな
がら、一方でZn粉末を混入したPb−8n系ハンダを
350℃程度で溶融しなから管2内に流入させる。溶融
ハンダを流入させると、管2の内壁表面では流入ノ・ン
ダの一部が凝固し、管2の内壁表面にハンダ層ができる
。その後、酸系エツチング剤を管内に満たし、化学反応
により本実施例において、Pb−8n系がZnとの相溶
性がよく、300C〜400℃で溶融する。凝固時にお
いて適度の粒径にてZn成分が凝集するので酸系エツチ
ングによシ1μ〜50μの空孔を持つ多孔質層が形成さ
れ、これによって極めて高い沸騰熱伝達効果が得られた
。Next, the heat exchanger was placed in a chamber with a furnace temperature of about 300°C, and while the heat exchanger fin 1 side was cooled by the furnace-temperature air, the Pb-8n solder mixed with Zn powder was heated to 350°C. After melting at a certain level, it flows into the tube 2. When the molten solder flows in, a portion of the inflow solder solidifies on the inner wall surface of the tube 2, and a solder layer is formed on the inner wall surface of the tube 2. Thereafter, the tube is filled with an acid-based etching agent, and a chemical reaction occurs. In this example, Pb-8n has good compatibility with Zn and melts at 300C to 400C. During solidification, the Zn component agglomerated to a suitable particle size, so that a porous layer with pores of 1 to 50 microns was formed by acid etching, resulting in an extremely high boiling heat transfer effect.
発明の効果
以上の説明からも明らかなように、本発明はノ・ンダに
て多孔質層を形成するものであるから、管材料として銅
以外の鉄、アルミ等のものまで巾広く適用でき、複雑な
形状をもつ内管のものまで多孔質を形成することが可能
となり、沸騰伝熱を促進して、熱交換器の効率向上を果
たせる。Effects of the Invention As is clear from the above explanation, since the present invention forms a porous layer in a solid state, it can be widely applied to pipe materials other than copper, such as iron and aluminum. It is now possible to make even inner tubes with complex shapes porous, promoting boiling heat transfer and improving the efficiency of the heat exchanger.
第1図は本発明の一実施例によシ製造された熱交換器の
斜視図、第2図は第1図の…−■′線による断面図、第
3図は第2図のト」′線による拡大断面図である。
2・・・・・・管(熱交換器伝熱表面)、6・・・・・
・多孔質層。
代理人の氏名 弁理士 中 尾 敏 男 ほか1名第2
図FIG. 1 is a perspective view of a heat exchanger manufactured according to an embodiment of the present invention, FIG. 2 is a sectional view taken along the line . FIG. 2...Tube (heat exchanger heat transfer surface), 6...
・Porous layer. Name of agent: Patent attorney Toshio Nakao and 1 other person 2nd
figure
Claims (1)
ィングした後、酸にて上記亜鉛粉末のみを溶かし、伝熱
表面に多孔質層を形成することを特徴とする熱交換器部
材の製造方法。Manufacture of a heat exchanger member characterized by coating the heat transfer surface of the heat exchanger with solder mixed with zinc powder, and then melting only the zinc powder with acid to form a porous layer on the heat transfer surface. Method.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP14792884A JPS6126785A (en) | 1984-07-17 | 1984-07-17 | Manufacture of heat exchanger member |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP14792884A JPS6126785A (en) | 1984-07-17 | 1984-07-17 | Manufacture of heat exchanger member |
Publications (1)
Publication Number | Publication Date |
---|---|
JPS6126785A true JPS6126785A (en) | 1986-02-06 |
Family
ID=15441244
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP14792884A Pending JPS6126785A (en) | 1984-07-17 | 1984-07-17 | Manufacture of heat exchanger member |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS6126785A (en) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH01159504A (en) * | 1987-05-25 | 1989-06-22 | Hisaka Works Ltd | Evaporator with preheater |
KR100717952B1 (en) | 2005-12-16 | 2007-05-11 | 김경일 | Heat exchanger pipe and manufacturing method thereof |
US8123109B2 (en) * | 2003-05-30 | 2012-02-28 | Uop Llc | Method for making brazed heat exchanger and apparatus |
CN103727833A (en) * | 2013-09-11 | 2014-04-16 | 太仓派欧技术咨询服务有限公司 | Ceramic-based composite material heat exchange tube |
CN103727825A (en) * | 2013-09-11 | 2014-04-16 | 太仓派欧技术咨询服务有限公司 | Refractory metal heat-exchange tube |
-
1984
- 1984-07-17 JP JP14792884A patent/JPS6126785A/en active Pending
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH01159504A (en) * | 1987-05-25 | 1989-06-22 | Hisaka Works Ltd | Evaporator with preheater |
US8123109B2 (en) * | 2003-05-30 | 2012-02-28 | Uop Llc | Method for making brazed heat exchanger and apparatus |
KR100717952B1 (en) | 2005-12-16 | 2007-05-11 | 김경일 | Heat exchanger pipe and manufacturing method thereof |
CN103727833A (en) * | 2013-09-11 | 2014-04-16 | 太仓派欧技术咨询服务有限公司 | Ceramic-based composite material heat exchange tube |
CN103727825A (en) * | 2013-09-11 | 2014-04-16 | 太仓派欧技术咨询服务有限公司 | Refractory metal heat-exchange tube |
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