JPS61258100A - Polyester blended paper - Google Patents

Polyester blended paper

Info

Publication number
JPS61258100A
JPS61258100A JP60098104A JP9810485A JPS61258100A JP S61258100 A JPS61258100 A JP S61258100A JP 60098104 A JP60098104 A JP 60098104A JP 9810485 A JP9810485 A JP 9810485A JP S61258100 A JPS61258100 A JP S61258100A
Authority
JP
Japan
Prior art keywords
polyester
paper
fibers
wood pulp
short fibers
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP60098104A
Other languages
Japanese (ja)
Inventor
邦夫 西村
董 平川
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Teijin Ltd
Original Assignee
Teijin Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Teijin Ltd filed Critical Teijin Ltd
Priority to JP60098104A priority Critical patent/JPS61258100A/en
Publication of JPS61258100A publication Critical patent/JPS61258100A/en
Pending legal-status Critical Current

Links

Abstract

(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。
(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.

Description

【発明の詳細な説明】 〈産業上の利用分野〉 本発明はポリエステル短繊維を主体とする短繊維群及び
木材パルプを湿式抄紙して成る極めて柔軟でかつ高い引
裂強力を有する不織布に関する。本発明により得られた
ポリエステル混抄紙は優れたドレープ性と引張強力、更
に高い引裂強力を有しているため例えば、ディスポーザ
ノル衣料1紙おむつ、生理用ナプキ/の表面材、ディス
ポーザブル手術衣。
DETAILED DESCRIPTION OF THE INVENTION <Industrial Application Field> The present invention relates to a nonwoven fabric which is extremely flexible and has high tear strength and is made by wet papermaking of short fibers mainly consisting of short polyester fibers and wood pulp. The polyester blend paper obtained according to the present invention has excellent drapeability, tensile strength, and high tear strength, so it can be used, for example, as disposable diapers, surface materials for sanitary napkins, and disposable surgical gowns.

覆布1手術室内着衣、シーツ、テーブルクaス、カーテ
ン、芯地9合成皮革の基布などに利用できる。
Covering fabric 1 Can be used for operating room clothing, sheets, tablecloths, curtains, interlining 9 synthetic leather base fabric, etc.

〈従来技術〉 ポリエステル短繊維、木材バとプおよび樹脂りり成るポ
リエステル混抄紙は従来より知られている。
<Prior Art> Polyester blend paper consisting of short polyester fibers, wood pulp and resin resin has been known for some time.

またこのような混抄紙にエノボス加工やクレープ処理あ
るいはシワ加工などt−施すことに工っていくらか組織
を柔軟化させ、引裂強力ヲ高めることも知られ”(イル
It is also known that by subjecting such mixed paper to t-processing such as enovos processing, crepe processing, or wrinkle processing, the structure can be softened to some extent and its tear strength can be increased.

しかしこの工うな混抄紙はポリエステル繊維自身の有す
る剛性あるいは木材パルプ、樹脂による集合体組織への
充填率の増大に起因する剛性のために風合が極めて硬く
なりペーパーライタとなる。また実用的に見て引裂強力
が低い。柔軟で引裂強力の高い不織布を得るために構成
繊維を細デニール化する方法もありこの場合はある程度
柔かい風合に近づくが引裂強度が低下する。一般にポリ
エステル繊維を高伸度化すると柔軟化が期待できるLう
に予想されるが未延伸状態に近いポリエステル繊維では
高伸度であるにも拘らず、不織布としたときは極めて硬
い風合になるので、やはり実用的でない。これらの欠点
はいわばポリエステル繊維の本質によるところが大きく
極めて柔軟でかつ良好なドレープ性を有し引裂強力の大
きい混抄紙を作ることは困難である。
However, due to the rigidity of the polyester fibers themselves or the rigidity caused by the increased filling rate of the aggregate structure with wood pulp and resin, this unprocessed mixed paper has an extremely hard feel and becomes paper lighter. In addition, from a practical standpoint, tear strength is low. In order to obtain a nonwoven fabric that is flexible and has high tear strength, there is a method of making the constituent fibers finer in denier, but in this case, the texture is close to being soft to some extent, but the tear strength is reduced. In general, it is expected that increasing the elongation of polyester fibers will make them more flexible, but even though unstretched polyester fibers have a high elongation, when made into non-woven fabrics, they have an extremely hard texture. , it's still not practical. These drawbacks largely depend on the nature of the polyester fibers, and it is difficult to produce a blended paper that is extremely flexible, has good drape properties, and has high tear strength.

〈発明の目的〉 本発明の目的はこのような欠点を改良することにある。<Purpose of the invention> The object of the present invention is to improve these drawbacks.

すなわち優れた柔軟性、ドレープ性および引裂強力に優
れ、かつ触感の良好なポリエステル混抄紙を得ることに
ある。
That is, the object is to obtain a polyester-mixed paper that has excellent flexibility, drapability, and tear strength, and has a good feel.

〈発明の構成〉 すなわち、本発明は「ポリニス短繊維、木材パルプおよ
び樹脂エリなる混抄紙において90℃以上で繊維軸方向
の収縮率が負となるポリエステル短繊維(A)がポリエ
ステル短繊維群の少なくとも60重量%を占めることt
−特徴とするポリエステル混抄紙」である。ポリエステ
ルとは例えばインフタル酸、テレフタル酸、ジフェニル
ジカルボン酸、ナフタリンジカルボン酸などの芳香族ジ
カルボン酸、アジピン酸、セバシン酸、デカンジカルボ
ン酸などの脂肪族ジカルボン酸、またはへキサヒドロテ
レフタル酸の如き脂肪族ジカルボン酸を二塩基酸成分と
しエチレングリフール、プロパンジオ−ル、トリメチレ
ングリコール、テトラメチレングリコール、デカメチレ
ンクリコール、ジエチレングリコール、2,2−ジメチ
ルプロパンジオール、ヘキサヒトクキシリレングリフー
ル、キシリレングリフ、イルなどの脂肪族、脂環族また
は芳香族グリコール或いはポリエチレングリフールの如
きポリオキシアルキレングリコールをグリコール成分と
するポリエステルなどである。これら二塩基酸成分また
はグリコール成分をそれぞれ1種或いは2種以上組合せ
た共重合ポリエステルであってもよい。特に好ましい例
としてはポリエチレンテレフタレート、ポリテトラメチ
レンテレフタレート、ポリトリメチレンテレフタレート
あるいは米国特許第 3.763.109号会報、同3,023,192号公
報。
<Structure of the Invention> In other words, the present invention provides that "polyester short fibers (A) having a negative contraction rate in the fiber axis direction at 90° C. or higher in a mixed paper consisting of polyvarnish short fibers, wood pulp, and resinous fibers are a group of polyester short fibers. account for at least 60% by weight
-Featured polyester blend paper. Polyesters include aromatic dicarboxylic acids such as inphthalic acid, terephthalic acid, diphenyl dicarboxylic acid, and naphthalene dicarboxylic acid; aliphatic dicarboxylic acids such as adipic acid, sebacic acid, and decane dicarboxylic acid; and aliphatic dicarboxylic acids such as hexahydroterephthalic acid. Ethylene glycol, propane diol, trimethylene glycol, tetramethylene glycol, decamethylene glycol, diethylene glycol, 2,2-dimethylpropanediol, hexahoxylylene glycol, xylylene glycol, with dicarboxylic acid as the dibasic acid component. , polyesters containing aliphatic, alicyclic or aromatic glycols such as , yl, or polyoxyalkylene glycols such as polyethylene glycol as a glycol component. A copolymerized polyester containing one type or a combination of two or more of these dibasic acid components or glycol components may also be used. Particularly preferred examples include polyethylene terephthalate, polytetramethylene terephthalate, polytrimethylene terephthalate, and US Pat. Nos. 3,763,109 and 3,023,192.

同3.6 s x、014号公報あるL/1 ハ(fJ
 3,766,146号公報等に記載されているポリエ
ステルエラストマー等を用いてもよい。さらに可塑性や
溶融粘度を増大させるために重合体に可塑剤。
3.6 s x, L/1 Ha (fJ
Polyester elastomers such as those described in Japanese Patent No. 3,766,146 may also be used. Plasticizers in polymers to further increase plasticity and melt viscosity.

増粘剤などを添加し【もよい。また通常、繊維の添加剤
として使用される光安定剤、顔料。
You may also add a thickener etc. Also commonly used as fiber additives are light stabilizers and pigments.

熱安定剤、−燃剤、滑剤、艶消剤等が添加されていても
よい◎ ポリエステル短繊維を構成する各々の繊維の形状は繊維
長3〜20mm、繊度0.5〜3デニールの範囲のもの
が好ましい。繊維長が3闘未満であると得られるポリエ
ステル混抄紙の引裂強力及び引張強力は極めて低くなる
・繊維長が20關を越えると得られるポリエステル混抄
紙の地合が不良となり好ましくない。
A heat stabilizer, a flame agent, a lubricant, a matting agent, etc. may be added.◎ The shape of each fiber constituting the polyester short fibers is within the range of fiber length 3 to 20 mm and fineness 0.5 to 3 denier. is preferred. If the fiber length is less than 3 mm, the tear strength and tensile strength of the resulting polyester-mixed paper will be extremely low.If the fiber length exceeds 20 mm, the resulting polyester-mixed paper will have poor formation, which is not preferred.

更に繊度が0.5デニ一ル未満では得られるポリエステ
ル混抄紙の引裂強力が低下する。また3デニールを越え
ると引張強力が低下する・を生せしめることなく少なく
とも繊維軸方向に20%の収縮を許容する条件下で一定
時間加熱収縮せしめることによって得られるポリエステ
ルフィラメントをカットすることに工り得ることができ
る。該短繊維囚は90℃以上の温度で繊維軸方向の収縮
率が負となる繊維、即ち不可逆的自発伸長を発現すると
いう特徴を有するも01ある・      7.・短繊
維(4)の繊維形状も繊維長3〜20mm。
Furthermore, if the fineness is less than 0.5 denier, the tear strength of the resulting polyester-mixed paper decreases. In addition, we have developed techniques for cutting polyester filaments obtained by heating and shrinking them for a certain period of time under conditions that allow at least 20% shrinkage in the fiber axis direction without causing a decrease in tensile strength if the denier exceeds 3. Obtainable. 7. The short fibers are characterized by having a negative contraction rate in the fiber axis direction at a temperature of 90° C. or higher, that is, exhibiting irreversible spontaneous elongation. - The fiber shape of the short fibers (4) also has a fiber length of 3 to 20 mm.

繊度0.5〜3デニールの範囲のものが好ましくポリエ
ステル繊維中における短繊維囚の混合比率はポリエステ
ル短繊維の少なくとも60重量%以上である。混合比率
が60重量%未満であれば、不織布の柔軟性と引裂強力
を改良せしめるだけの能力はなく、木材パルプや樹脂の
物性による影響が大きい。
The fineness of the polyester fibers is preferably in the range of 0.5 to 3 deniers, and the mixing ratio of short fibers in the polyester fibers is at least 60% by weight of the polyester short fibers. If the mixing ratio is less than 60% by weight, there is no ability to improve the flexibility and tear strength of the nonwoven fabric, and the physical properties of the wood pulp and resin will have a large effect.

抄紙用分散液はポリエステル短繊維、木材パルプを水中
に分散して得る。この場合、木材パルプは短繊維と混抄
しても良く又、秒置せをしてもよい。更に、木材パルプ
のみ抄いたものと混抄したものを秒置せたり、ポリエス
テル短繊維のみ抄いたものと混抄したものを秒置せした
りすることができる。一般に抄ル 合せる場合は混抄紙の表層と裏層で異なる性能が要求さ
れる場合が多い。例えば木材パルプの多い層は、ポリエ
ステル短繊維が多い層に比べて触感がなめらかであり、
しつとりした風合となる。一方短繊維の多い層では木材
パルプの多い膚に比べて硬い風合となるが木材パルプだ
けでは得られない引張強力や引裂強力を得ることができ
る。したがって皮*)6手な風合と実用強度を兼備せし
めるために秒置せたりあるいは同一層に付与する場合は
郷抄したりする。ポリエステル繊維に対する木材パルプ
の混抄率は単層、複層などの混抄紙構造に依存するがほ
ぼ25〜400重景%が好ましい。400重量%t−越
えると引裂強力が低下する。251f%未満になると木
材パルプの有するなめらか々手触りが損われる。
A papermaking dispersion is obtained by dispersing polyester staple fibers and wood pulp in water. In this case, the wood pulp may be mixed with short fibers or left for a few seconds. Furthermore, it is possible to leave for a second a mixture of wood pulp and a mixture thereof, or a mixture of a mixture of polyester staple fibers and a mixture of wood pulp for a second. Generally, when paper is combined, different performance is often required for the front and back layers of the mixed paper. For example, a layer containing a lot of wood pulp feels smoother than a layer containing a lot of short polyester fibers.
It has a moist texture. On the other hand, a layer with a lot of short fibers has a harder texture than a skin with a lot of wood pulp, but it can provide tensile strength and tear strength that cannot be obtained with wood pulp alone. Therefore, in order to achieve both a soft texture and practical strength, it is left to stand for a few seconds, or when applied to the same layer, it is applied to the skin. The mixing ratio of wood pulp to polyester fibers depends on the mixed paper structure, such as single layer or multilayer, but is preferably about 25 to 400%. If it exceeds 400% by weight, the tear strength decreases. If it is less than 251f%, the smooth feel of wood pulp will be impaired.

更に本発明にいう樹脂とは、抄紙用分散液へ内添あるい
はドライヤー前でスプレーする外添あるいは乾燥後、=
−ティノブや含浸あるいはスプレーによる後処理方式な
どにより混抄紙に付与することができる。一般にポリエ
ステル短繊維及び木材パルプより成る繊維集合体を硬く
拘束するような樹脂は好ましくない。具体的にはアクリ
ル酸2エチルヘキシルエステル、アクリル酸ブチルエス
テル、アクリル酸メチルエステル、アクリル酸メチルエ
ステル、更には各種アクリル酸エステルとスチレンモノ
マーとの共重合体、ポリエステル樹脂、ポリウレタン樹
脂、スチレン/ブタジェン・ゴム(SBR) 、アクリ
ロニトリル/フタジエン・ゴム(NBR) 、エチレン
/ビニルアセテート・ゴム(EVA) 、ポリブタジェ
ンなどが良好である。又付着量は用途に依存するが抄紙
後の坪量に対し20〜60重量%程度が望ましい。更に
用途に応じ該樹脂中KM料。
Furthermore, the resin referred to in the present invention means that it can be added internally to a papermaking dispersion, added externally by spraying it in front of a dryer, or added after drying.
- It can be applied to mixed paper by post-treatment methods such as tinobing, impregnation, or spraying. In general, resins that rigidly constrain the fiber aggregate made of short polyester fibers and wood pulp are not preferred. Specifically, acrylic acid 2-ethylhexyl ester, acrylic acid butyl ester, acrylic acid methyl ester, acrylic acid methyl ester, copolymers of various acrylic esters and styrene monomers, polyester resins, polyurethane resins, styrene/butadiene, etc. Good examples include rubber (SBR), acrylonitrile/phtadiene rubber (NBR), ethylene/vinyl acetate rubber (EVA), and polybutadiene. The amount of adhesion depends on the application, but it is preferably about 20 to 60% by weight based on the basis weight after paper making. Additionally, KM additives may be added to the resin depending on the application.

添料、帯電防止剤、増粘剤、撥水剤、防炎剤。Additives, antistatic agents, thickeners, water repellents, flame retardants.

難燃剤などを添加しても工い。It is also possible to add flame retardants, etc.

更に本発明におけるポリエステル混抄紙は一層の柔軟性
を与えるためのシワ加工やエンボス加工などによりその
表面に微細な凹凸を有することが好ましい。この凹凸は
極めて嵩°高でかつ重厚で品位ある風合を与えるととも
に柔軟な風合を与える。
Further, it is preferable that the polyester blend paper in the present invention has fine irregularities on its surface by wrinkle processing, embossing, etc., in order to provide further flexibility. These irregularities are extremely bulky and provide a solid, dignified texture, as well as a flexible texture.

〈発明の効果〉 本発明のポリエステル混抄紙は従来の木材パルプ及びポ
リエステル短繊維からなる混抄紙に比べ高度の柔軟性と
高い引裂強力を有している。かかる特性を生かして例え
ばディスポーザブル衣料1紙おむつや生理用ナプキンの
表面材、デイスポーサブル手術衣、覆布。
<Effects of the Invention> The polyester blended paper of the present invention has a higher degree of flexibility and higher tear strength than conventional blended paper made of wood pulp and polyester short fibers. Taking advantage of these characteristics, for example, disposable clothing 1. Surface materials for disposable diapers and sanitary napkins, disposable surgical gowns, and coverings.

手術室内着衣、シーツ、テーブルクロス、カーテン、芯
地1合成皮革の基布などの用途に最適である。
It is ideal for applications such as operating room clothing, sheets, tablecloths, curtains, and base cloth for interlining synthetic leather.

〈実施例〉 以下、実施例にエリ本発明を具体的に説明する。実施例
におゆる各測定値は以下の方法により測定した。
<Examples> Hereinafter, the present invention will be specifically explained in Examples. Each measurement value in the examples was measured by the following method.

(1)強力、伸度:定速伸長屋引張試験機を用いJIS
 P−8113の方法に従って 測定した。
(1) Strength and elongation: JIS using a constant speed elongator tensile tester
It was measured according to the method of P-8113.

(2)引裂強カニ定速伸長型引張試験機を用いJIS 
L−1096の方法に従いシングルタンク法により測定
した。
(2) Using JIS tear strength crab constant speed extension type tensile tester
It was measured by the single tank method according to the method of L-1096.

(3)剛軟度:カンチレバー法(JIS L−1096
)に従って測定した。
(3) Bending resistance: Cantilever method (JIS L-1096
).

第1表、第2表における上記(1)〜(3)の各値はた
て、工こ方向値の平均値である。
Each of the values (1) to (3) above in Tables 1 and 2 is the average value of the vertical and vertical direction values.

実施例1〜3.比較例1〜2 繊度1.5デニール、S維長10mm、強度3.3g/
d、伸度129%、180℃で20分間熱処理したとき
の乾熱収縮率が−5,0%の自己伸長ポリエチレンテレ
フタレート短繊維(A)全繊度1.5デニール、線維長
10mm、強度5.0g/d。
Examples 1-3. Comparative Examples 1-2 Fineness 1.5 denier, S fiber length 10 mm, strength 3.3 g/
d. Self-extending polyethylene terephthalate short fiber (A) with an elongation of 129% and a dry heat shrinkage rate of -5.0% when heat treated at 180°C for 20 minutes (A) total fineness of 1.5 denier, fiber length of 10 mm, strength of 5. 0g/d.

伸度48%、180℃で20分間熱処理したときの乾熱
収縮率が+5.5%のポリエチレンテレツクレート短繊
維の)K第1表に示した割合で混綿し、更に木材パルプ
を添加し、スラリーを作成した。
Polyethylene telexcrate short fibers with an elongation of 48% and a dry heat shrinkage rate of +5.5% when heat treated at 180°C for 20 minutes were mixed in the proportions shown in Table 1, and wood pulp was further added, Created slurry.

次に角型抄紙機を用いて該スラリーを抄紙後ドラム型ロ
ータリードライヤーで120℃で1分間乾燥し47g/
rrfのポリエステル混抄紙を得た。更にアクリル酸エ
ステル樹脂(K−3:日本アクリル■jilりを主剤と
する下肥の樹脂液中に紋理抄紙を浸漬後、二・ンプσ−
ラにより余分の液を除去し140℃で2分間乾燥させた
Next, the slurry was made into paper using a square paper machine, and then dried for 1 minute at 120°C with a drum rotary dryer to produce 47g/
An rrf polyester mixed paper was obtained. Furthermore, after immersing the Monri paper in a resin liquid of acrylic acid ester resin (K-3: Nippon Acrylic), the main ingredient is 2.
Excess liquid was removed using a vacuum cleaner, and the mixture was dried at 140°C for 2 minutes.

樹脂液(重量部) Ryudye−W Turq 、Blue FBL (
lit料)     1.32部Ryudy@−wGr
een FBT cone (顔料)    0.33
部(いずれも大日本インク化学■製) K−3(日本アクリル■製’)           
 50.00部子ルギン涜ナトリウム(2%水浴液) 
     12.35 m水            
        36.00部計  100.00部 得られた混抄紙は68g/in”の坪量で樹脂付着量は
抄上紙の重量に対し45重量%であった。更に柔軟性を
向上させるために150℃の金属a−ル上で予熱処理後
、一対のプレート間に#混抄紙を押込み挿入しながら微
細シワ加工を施し混抄紙の表面に微細な凹凸を形成せし
めた。
Resin liquid (parts by weight) Ryudye-W Turq, Blue FBL (
lit fee) 1.32 parts Ryudy@-wGr
een FBT cone (pigment) 0.33
(all made by Dainippon Ink Chemical) K-3 (made by Nippon Acrylic)
50.00 parts sodium lugin (2% water bath solution)
12.35 m water
36.00 copies total 100.00 copies The obtained mixed paper had a basis weight of 68 g/in'' and a resin adhesion amount of 45% by weight based on the weight of the paper. After preheating on a metal aru at a temperature of .degree. C., the # mixed paper was inserted between a pair of plates and subjected to fine wrinkle processing to form fine irregularities on the surface of the mixed paper.

得られた混抄紙の諸物性を第1表に示す。この結果、短
繊維(4)がポリエステル短繊維の少なくとも60重量
%を占めている場合は特に高い引裂強度と低い剛軟度値
を示した(実施例1〜3)。一方、60重量%未満の場
合は、高強度は得られたが引裂強力が低下しかつ柔軟性
も低下した(比較例1〜2)。
Table 1 shows the physical properties of the obtained mixed paper. As a result, when the short fibers (4) accounted for at least 60% by weight of the polyester short fibers, especially high tear strength and low stiffness values were exhibited (Examples 1 to 3). On the other hand, when the content was less than 60% by weight, high strength was obtained, but the tear strength and flexibility decreased (Comparative Examples 1 and 2).

実施例4〜7.比較例3〜6 繊度0.5〜3デニール、繊維長3〜20mm。Examples 4-7. Comparative examples 3 to 6 Fineness 0.5-3 denier, fiber length 3-20mm.

強度3.3 g/d 、伸度129%、180℃で20
分間熱処還したときの乾熱収縮率が−5,0%の自己伸
長ポリエチレンテレフタレート短繊維(4)を繊度0.
5〜3デニール、*維長3〜20mm1強度5.0g/
d 、伸度48%、180℃で20分間熱処理したとき
の乾熱収縮率が+5.5%のポリエチレンテレフタレー
ト短繊維@ K 142 表K 示した割合で混綿し、
更に木材パルプを添加しスラリーを作成した。
Strength 3.3 g/d, elongation 129%, 20 at 180°C
Self-extending polyethylene terephthalate staple fibers (4) with a dry heat shrinkage rate of -5.0% when heat treated for minutes are 0.
5-3 denier, *Fiber length 3-20mm 1 strength 5.0g/
d, polyethylene terephthalate short fibers with an elongation of 48% and a dry heat shrinkage rate of +5.5% when heat treated at 180°C for 20 minutes @ K 142 Table K Blend in the proportions shown,
Furthermore, wood pulp was added to create a slurry.

次に実施例1〜3.比較例1〜2と同様の方法で抄紙、
樹脂加工、柔軟化処理を施した。得られた混抄紙の諸物
性を第2表に示す。この結果、繊度が0.5デニ一ル未
満や3.0デニールを越えると引裂強力が低下した9強
度が低下することがわかる(比較例3及び4)。一方、
繊維長が3 am未満のときは、強度引裂強力とも低下
しく比較例5)、繊維長が2011Ilt−越えるとき
は、引裂強力が低下することがわかる(比較例6)。
Next, Examples 1 to 3. Paper making in the same manner as Comparative Examples 1 and 2,
Treated with resin processing and softening treatment. Table 2 shows the physical properties of the obtained mixed paper. The results show that when the fineness is less than 0.5 denier or more than 3.0 denier, the tear strength decreases (Comparative Examples 3 and 4). on the other hand,
It can be seen that when the fiber length is less than 3 am, the strength and tear strength decrease (Comparative Example 5), and when the fiber length exceeds 2011 Ilt-, the tear strength decreases (Comparative Example 6).

Claims (3)

【特許請求の範囲】[Claims] (1)ポリエステル短繊維、木材パルプおよび樹脂から
なる混抄紙において、90℃以上で繊維軸方向の収縮率
が負となるポリエステル短繊維(A)がポリエステル短
繊維の少なくとも60重量%を占めることを特徴とする
ポリエステル混抄紙
(1) In a mixed paper made of polyester staple fibers, wood pulp, and resin, polyester staple fibers (A) whose shrinkage rate in the fiber axis direction is negative at 90°C or higher account for at least 60% by weight of the polyester staple fibers. Features of polyester blend paper
(2)ポリエステル短繊維が繊維長3〜20mm、繊度
0.5〜3デニールの短繊維であることを特徴とする特
許請求の範囲第(1)項に記載のポリエステル混抄紙
(2) The polyester blend paper according to claim (1), wherein the polyester short fibers are short fibers with a fiber length of 3 to 20 mm and a fineness of 0.5 to 3 denier.
(3)ポリエステル短繊維が微細な凹凸をその表面に有
することを特徴とする特許請求の範囲第(1)項に記載
のポリエステル混抄紙
(3) The polyester blend paper according to claim (1), wherein the polyester short fibers have fine irregularities on the surface thereof.
JP60098104A 1985-05-10 1985-05-10 Polyester blended paper Pending JPS61258100A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP60098104A JPS61258100A (en) 1985-05-10 1985-05-10 Polyester blended paper

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP60098104A JPS61258100A (en) 1985-05-10 1985-05-10 Polyester blended paper

Publications (1)

Publication Number Publication Date
JPS61258100A true JPS61258100A (en) 1986-11-15

Family

ID=14211018

Family Applications (1)

Application Number Title Priority Date Filing Date
JP60098104A Pending JPS61258100A (en) 1985-05-10 1985-05-10 Polyester blended paper

Country Status (1)

Country Link
JP (1) JPS61258100A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6426799A (en) * 1987-07-22 1989-01-30 Hattori Seishi Kk Kitchen paper
JPH0598594A (en) * 1991-10-11 1993-04-20 Oji Paper Co Ltd Base paper for wet towel
JP2001288661A (en) * 2000-04-03 2001-10-19 Teijin Ltd Nonwoven fabric for artificial leather
JP2010203006A (en) * 2009-03-04 2010-09-16 Kohjin Co Ltd Impregnation-coating type japanese paper tape substrate
JP2019063541A (en) * 2015-05-12 2019-04-25 山田 菊夫 Disposable article

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5729700A (en) * 1980-07-29 1982-02-17 Teijin Ltd Synthetic paper
JPS5876597A (en) * 1981-10-26 1983-05-09 帝人株式会社 Production of polyester paper with excellent heat resistance

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5729700A (en) * 1980-07-29 1982-02-17 Teijin Ltd Synthetic paper
JPS5876597A (en) * 1981-10-26 1983-05-09 帝人株式会社 Production of polyester paper with excellent heat resistance

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6426799A (en) * 1987-07-22 1989-01-30 Hattori Seishi Kk Kitchen paper
JPH0598594A (en) * 1991-10-11 1993-04-20 Oji Paper Co Ltd Base paper for wet towel
JP2001288661A (en) * 2000-04-03 2001-10-19 Teijin Ltd Nonwoven fabric for artificial leather
JP2010203006A (en) * 2009-03-04 2010-09-16 Kohjin Co Ltd Impregnation-coating type japanese paper tape substrate
JP2019063541A (en) * 2015-05-12 2019-04-25 山田 菊夫 Disposable article

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