JPS61254221A - Apparatus for removing co2 - Google Patents
Apparatus for removing co2Info
- Publication number
- JPS61254221A JPS61254221A JP60093599A JP9359985A JPS61254221A JP S61254221 A JPS61254221 A JP S61254221A JP 60093599 A JP60093599 A JP 60093599A JP 9359985 A JP9359985 A JP 9359985A JP S61254221 A JPS61254221 A JP S61254221A
- Authority
- JP
- Japan
- Prior art keywords
- gas
- adsorption tank
- adsorbent
- tank
- steam
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/20—Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
- Y02C20/00—Capture or disposal of greenhouse gases
- Y02C20/40—Capture or disposal of greenhouse gases of CO2
Landscapes
- Respiratory Apparatuses And Protective Means (AREA)
- Treating Waste Gases (AREA)
- Separation Of Gases By Adsorption (AREA)
Abstract
Description
【発明の詳細な説明】 （産業上の利用分野） 本発明は密閉空間２例えば宇宙ステーション。[Detailed description of the invention] (Industrial application field) The present invention is applicable to a closed space 2 such as a space station.
潜水艦、ライフサイエンス実験室等で使用するＣＯ２除
去装置に関するものである。This relates to CO2 removal equipment used in submarines, life science laboratories, etc.
（従来の技術）
従来のＣｏｔ（二酸化炭素）除去装置は２アミン系イオ
ン交換樹脂や活性炭等の吸着剤を使用して、気体中から
ＣＯ２を脱着した後、吸着剤に水蒸気を流し、同吸着剤
からＣＯ２を分離して２回収するようにしている。(Prior art) Conventional Cot (carbon dioxide) removal equipment uses an adsorbent such as a diamine ion exchange resin or activated carbon to desorb CO2 from the gas, and then flows water vapor through the adsorbent to absorb the same. CO2 is separated from the agent and recovered twice.
（発明が解決しようとする問題点）
その場合、ＣＯ□を含有する空気が吸着槽に入り、ＣＯ
，が同吸着槽内に充填された吸着剤に吸着される一方、
Ｃｏｇを分離した空気が同吸着槽から排出され２次いで
同吸着槽に置換ガスの水蒸気が供給される。このとき、
水蒸気の凝縮が起こり、吸着剤が加熱され、吸着剤に吸
着されていたＣＯ２が吸着剤から脱着されて、吸着剤が
再生されると同時に脱着されたＣＯ□が回収される。こ
の再生された吸着剤は、凝縮水等の水分をもっているが
、脱着完了後の吸着剤は高温であり、ＣＯ２を含有する
空気が再び流れ始めると、同空気が加熱されると同時に
水分が蒸発して、吸着剤の乾燥と冷却とが行われ、同時
にＣＯ２の吸着が再開される。上記吸着槽から排出され
るＣＯ□を分離した空気が持っている熱エネルギーは、
水蒸気発生に要するエネルギーに略等しく、この熱を回
収して、省エネルギーを図る必要がある。(Problem to be solved by the invention) In that case, air containing CO□ enters the adsorption tank and CO
, is adsorbed by the adsorbent filled in the adsorption tank, while
The air from which the Cog has been separated is discharged from the adsorption tank, and then water vapor as a replacement gas is supplied to the adsorption tank. At this time,
Condensation of water vapor occurs, the adsorbent is heated, the CO2 adsorbed on the adsorbent is desorbed from the adsorbent, and the adsorbent is regenerated and at the same time the desorbed CO□ is recovered. This regenerated adsorbent contains moisture such as condensed water, but the adsorbent is at a high temperature after completion of desorption, and when the air containing CO2 starts flowing again, the air is heated and the moisture evaporates. Then, the adsorbent is dried and cooled, and at the same time, CO2 adsorption is restarted. The thermal energy possessed by the air from which the CO□ discharged from the adsorption tank is separated is
This heat is approximately equal to the energy required to generate water vapor, and it is necessary to recover this heat to save energy.
（問題点を解決するための手段）
本発明は前記の問題点に対処するもので、ＣＯ２を含有
する気体を導くガス導入管と、同ガス導入管により供給
された気体中からＣＯｚを捕獲する吸着剤を内部に充填
した吸着槽と、ＣＯｔから分離した気体を同吸着槽内か
ら導出するガス導出管と、気体から分離したＣＯｔを同
吸着槽内から導出するＣＣｈ導出管と、水蒸気を同吸着
槽内へ供給する水蒸気発生器と、上記各導出管と上記水
蒸気発生器から上記吸着槽への水蒸気流通経路とに設け
た開閉弁と、前記水蒸気発生器へ供給される給水を前記
ガス導出管からの気体により予熱する熱交換器とを具え
ていることを特徴としたＣＯ２除去装置に係わり、その
目的とする処は、熱回収効率を向上できる。またガス導
出管に設ける排出気体冷却用ターラの容量を小さくでき
る改良されたＣｏ２除去装置を供する点にある。(Means for Solving the Problems) The present invention addresses the above-mentioned problems, and includes a gas introduction pipe for introducing a gas containing CO2, and a system for capturing COz from the gas supplied by the gas introduction pipe. An adsorption tank filled with adsorbent, a gas outlet pipe that leads out the gas separated from COt from inside the adsorption tank, a CCh lead-out pipe that leads out the COt separated from the gas from inside the adsorption tank, and a water vapor A steam generator for supplying into the adsorption tank, an on-off valve provided in each of the lead-out pipes and a steam flow path from the steam generator to the adsorption tank, and a gas derivation system for supplying water to be supplied to the steam generator. The present invention relates to a CO2 removal device characterized by comprising a heat exchanger that is preheated by gas from a tube, and its purpose is to improve heat recovery efficiency. Another object of the present invention is to provide an improved Co2 removal device that can reduce the capacity of the exhaust gas cooling colander provided in the gas outlet pipe.
本発明は前記のようにＣＯ２を含有する気体を導くガス
導入管と、同ガス導入管により供給された気体中からＣ
Ｏ□を捕獲する吸着剤を内部に充填した吸着槽と、ＣＯ
ｚから分離した気体を同吸着槽内から導出するガス導出
管と、気体から分離したＣ Ｏｚを同吸着槽内から導出
するＣ Ｏを導出管と、水蒸気を同吸着槽内へ供給する
水蒸気発生器と、上記各導出管と上記水蒸気発生器から
上記吸着槽への水蒸気流通経路とに設けた開閉弁と。As described above, the present invention provides a gas introduction pipe for introducing a gas containing CO2, and a CO2-containing gas from the gas supplied by the gas introduction pipe.
An adsorption tank filled with adsorbent to capture O□ and CO
A gas derivation pipe for deriving the gas separated from Z from the adsorption tank, a CO derivation pipe for deriving the COz separated from the gas from the adsorption tank, and a steam generator for supplying water vapor into the adsorption tank. an on-off valve provided in each of the outlet pipes and a steam flow path from the steam generator to the adsorption tank.
前記水蒸気発生器へ供給される給水を前記ガス導出管か
らの気体により予熱する熱交換器とを具えており、開閉
弁を切り換えて、ＣＯｔを含有する空気からＣＯ２を除
去するとき、即ち、Ｃ０２を含有する空気が吸着槽に入
り、ＣＯ□が同吸着槽内に充填された吸着剤に吸着され
る一方、ＣＯ。It is equipped with a heat exchanger that preheats the feed water supplied to the steam generator with the gas from the gas outlet pipe, and when removing CO2 from air containing COt by switching the on-off valve, that is, CO2 Air containing CO enters the adsorption tank, and CO□ is adsorbed by the adsorbent filled in the adsorption tank, while CO.
を分離した空気が同吸着槽からガス導出管を経て排出さ
れ２次いで吸着槽に水蒸気が供給されて。The separated air is discharged from the adsorption tank through a gas outlet pipe, and then water vapor is supplied to the adsorption tank.
吸着剤が加熱され、吸着剤に吸着されていたＣＯ２が吸
着剤から脱着されて、吸着剤が再生されると同時に脱着
されたＣ ＯｚがＣＯｔ導出管を経て回収され２次いで
ＣＯ□の脱着を完了した直後の高温吸着剤にＣＯｚを含
有する空気が再び供給されて、同空気が加熱されると同
時に水分が蒸発して、吸着剤の乾燥と冷却とが行われ、
同時にＣＯ２の吸着が再開されて、加熱された空気がガ
ス導出管を経て排出されるときに、給水管内を流れて。The adsorbent is heated, the CO2 adsorbed on the adsorbent is desorbed from the adsorbent, and at the same time the adsorbent is regenerated, the desorbed COz is recovered via the COt outlet pipe, and then CO□ is desorbed. Air containing COz is again supplied to the high-temperature adsorbent immediately after completion, and the air is heated and moisture evaporates at the same time, drying and cooling the adsorbent.
At the same time, CO2 adsorption is resumed and the heated air flows through the water supply pipe as it is discharged through the gas outlet pipe.
水蒸気発生器に向かう給水が熱交換器で上記ガス導出管
を経て排出される高温の空気により予熱されるので、熱
回収効率が向上される。またガス導出管には、排出され
る気体の温度を低下させるために、排出気体冷却用クー
ラを設けるが、上記のように給水に熱を与えて温度の低
下した気体が同排出気体冷却用ターラに入るので、排出
気体冷却用ターラの容量が小さくてよいようになる。Since the feed water headed for the steam generator is preheated in the heat exchanger by the high temperature air discharged through the gas outlet pipe, heat recovery efficiency is improved. In addition, a cooler for cooling the discharged gas is installed in the gas outlet pipe in order to lower the temperature of the discharged gas, but as mentioned above, the gas whose temperature has been lowered by applying heat to the water supply is transferred to the cooler for cooling the discharged gas. , the capacity of the exhaust gas cooling roller can be small.
（実施例）
次に本発明のＣＯ，除去装置を第１図に示す一実施例に
より説明すると、 （１）（２）が空気中からＣＯ２を
捕獲する吸着剤（アミン系イオン交換樹脂或いは活性炭
等） （ｌａ） （２ａ）を内部に充填した吸着槽、
（１９）がＣｏｔを含有する空気を上記吸着槽（１）
（２）の入口側に導くガス導入管、（４）が同ガス導入
管（１９）に設けた空気ファン、 （１１） （１３）
が同ガス導入管（１９）に設けた自動切換弁、 （２３
）が水供給源から供給された給水を加熱して水蒸気にす
る水蒸気発生器、 （２１）が同水蒸気発生器（２３）
で発生した水蒸気（置換ガス）を上記吸着槽（１） （
２）の入口側に導く水蒸気導入管、 （１６）（１Ｂ）
が同水蒸気導入管（２１）に設けた自動切換弁、 （２
０）がＣＯｚから分離した空気を上記吸着槽（１） （
２）の出口側から導出するガス導出管、 （１２） （
１４）が同ガス導出管（２０）に設けた自動切換弁、
（２２）が吸着剤（ｌａ） （２ａ）から脱着 。(Example) Next, the CO removal device of the present invention will be explained using an example shown in FIG. etc.) (la) An adsorption tank filled with (2a) inside,
(19) transfers the air containing Cot to the above adsorption tank (1).
(2) A gas introduction pipe leading to the inlet side, (4) an air fan installed on the same gas introduction pipe (19), (11) (13)
is an automatic switching valve installed in the same gas introduction pipe (19), (23
) is a steam generator that heats water supplied from a water supply source to turn it into steam, and (21) is the steam generator (23).
The water vapor (replacement gas) generated in the above adsorption tank (1) (
2) Steam introduction pipe leading to the inlet side, (16) (1B)
is an automatic switching valve installed in the steam introduction pipe (21), (2
0) separates the air from COz into the adsorption tank (1) (
2) Gas outlet pipe leading out from the outlet side of (12) (
14) is an automatic switching valve installed in the gas outlet pipe (20),
(22) is desorbed from adsorbent (la) (2a).
したＣＯ□を上記吸着槽（１） （２）の出口側から取
り出すＣＯｚ導出管、（１５） （１７）が同ガス導出
管（２２）に設けた自動切換弁、（６）が同ガス導出管
（２２）ニ設けたＣＯｔ圧縮機、（６°）が同ガス導出
管（２２）に設けたＣＯ２タンク、（２１”）が水供給
源から上記水蒸気発生器（２３）へ延びた給水管、 （
２８）が同給水管（２１′）中を流れる給水を上記ガス
導出管（２０）からの空気により予熱する熱交換器、（
２８”）が同ガス導出管（２０）の下流側に設けた排出
空気冷却用ターラである。なお上記吸着槽（１） （２
）の出口側には、Ｃｏｔの脱着状態を検出するＣＯ□検
出センサがあり、同各ＣＯｔ検出センサからの検出信号
に基づいて上記各自動切換弁（１１）〜（１８）を制御
する制御器があるが、同各ＣＯ□検出センサ及び同制御
器は１図示を省略している。The COz outlet pipe takes out the CO□ from the outlet side of the adsorption tanks (1) and (2), (15) and (17) are automatic switching valves installed on the gas outlet pipe (22), and (6) is the gas outlet pipe. The COt compressor is installed in the pipe (22), the CO2 tank (6°) is installed in the same gas outlet pipe (22), and the water supply pipe (21'') extends from the water supply source to the steam generator (23). , (
28) is a heat exchanger for preheating the water supply flowing through the water supply pipe (21') with the air from the gas outlet pipe (20);
28'') is a exhaust air cooling colander installed on the downstream side of the gas outlet pipe (20).
) is equipped with a CO□ detection sensor that detects the state of attachment and detachment of Cot, and a controller that controls each of the automatic switching valves (11) to (18) based on the detection signal from each COt detection sensor. However, illustration of each CO□ detection sensor and the same controller is omitted.
（作用）
次に前記第１図に示したＣ Ｏを除去装置の作用を説明
する。いま吸着槽（１）の吸着剤（１ａ）が空気からＣ
Ｏ□を吸着中であり、吸着槽（２）の吸着剤（２ａ）が
ＣＯｚを脱着中であるとすると、自動切換弁（１１）
（１２） （１７） （１８）は開状態、自動切換弁（
１３） （１４） （１５） （１６）は閉状態、空気
ファン（４）及びＣＯＺ圧縮機（５）は作動中、吸着槽
（２）出口側のＣＯ！濃度検出センサはＣＯｚ濃度を検
出中である。この状態で引き続き吸着槽（２）でＣＯｔ
の脱着を続けると、水蒸気の流入による温度上昇により
、ＣＯ□温度検出センサが作動し、そのとき得られるＣ
Ｏｚ温度検出信号が同ＣＯ２濃度検出センサから制御
器へ送られ、同制御器から自動切換弁（１１）（１７）
（１Ｂ）へ閉の制御信号が送られ、同制御器から自動
切換弁（１３） （１４） （１５）へ開の制御信号が
送られて、同自動切換弁（１１） （１７） （１８）
が閉じ、同自動切換弁（１３） （１４） （１５）が
開いて、吸着槽（１）が脱着状態に入り、吸着槽（２）
が吸着状態に入る。またこの状態になって、吸着槽（１
）出口側のＣＯを濃度検出センサがＣＯ□を検出すると
、そのとき得られるＣＯ□濃度検出信号が同ＣＯＺ濃度
検出センサから制御器へ送られ、同制御器から自動切換
弁（１６）へ開の制御信号が送られ、同制御器から自動
切換弁（１２）へ閉の制御信号が送られて、同自動切換
弁（１６）が開き、同自動切換弁（１２）が閉じて、Ｃ
ＯｔがＣＯｔタンク（６゛）に回収される。またその後
に吸着槽（１）出口側のＣＯｚ温度検出センサが水蒸気
によるＣｏｔの温度上昇を検出すると、そのとき得られ
るＣＯ□温度検出信号が同ＣＯｚ温度検出センサから制
御器゛へ送られ、同制御器から自動切換弁（１１） （
１２） （１７）へ開の制御信号が送られ。(Function) Next, the function of the C 2 O removal device shown in FIG. 1 will be explained. Now, the adsorbent (1a) in the adsorption tank (1) is absorbing C from the air.
Assuming that O□ is being adsorbed and the adsorbent (2a) in the adsorption tank (2) is desorbing COz, the automatic switching valve (11)
(12) (17) (18) are open, automatic switching valve (
13) (14) (15) (16) are closed, air fan (4) and COZ compressor (5) are operating, CO! The concentration detection sensor is currently detecting the COz concentration. In this state, COt is continued in the adsorption tank (2).
As the desorption of CO continues, the temperature rises due to the inflow of water vapor, which activates the CO□ temperature detection sensor, and the resulting C
Oz temperature detection signal is sent from the CO2 concentration detection sensor to the controller, and the automatic switching valve (11) (17) is sent from the controller.
A close control signal is sent to (1B), and an open control signal is sent from the controller to automatic switching valves (13), (14), and (15), which in turn send an open control signal to automatic switching valves (11), (17, and 18). )
closes, the automatic switching valves (13), (14), and (15) open, the adsorption tank (1) enters the desorption state, and the adsorption tank (2)
enters the adsorption state. In this state again, the adsorption tank (1
) When the concentration detection sensor detects CO□ in the CO on the outlet side, the CO□ concentration detection signal obtained at that time is sent from the COZ concentration detection sensor to the controller, and from the controller the automatic switching valve (16) is opened. A control signal is sent from the controller, a close control signal is sent to the automatic switching valve (12), the automatic switching valve (16) opens, the automatic switching valve (12) closes, and the automatic switching valve (12) closes.
Ot is collected in a COt tank (6゛). Furthermore, when the COz temperature detection sensor on the outlet side of the adsorption tank (1) detects a temperature rise in Cot due to water vapor, the COz temperature detection signal obtained at that time is sent from the COz temperature detection sensor to the controller. Automatic switching valve (11) from the controller (
12) An open control signal is sent to (17).
同制御器から自動切換弁（１３） （１５） （１６）
へ閉の制御信号が送られて、同自動切換弁（１１） （
１２） （１７）が開き、同自動切換弁（１３） （１
５） （１６）が閉じて、吸着槽（２）が脱着状態に入
る。また吸着槽（２）側のＣＯ２濃度検出センサがＣＯ
ｚを検出すると、そのとき得られるＣＯ□濃度検出信号
が同ＣＯ２濃度検出センサから制御器へ送られ、同制御
器から自動切換弁（１８）へ開の制御信号が送られ、同
制御器から自動切換弁（１４）へ閉の制御信号が送られ
て、同自動切換弁（１８）が開き、同自動切換弁（１４
）が閉じて、ＣＯ，がＣＯｚタンク（６゛）に回収され
る。それからも上記の作用が繰り返し行われて、Ｃｏｇ
が連続的に回収される。以上の説明から明らかなように
本実施例では、空気中のＣＯｚを吸着槽（１） （２）
内に充填した吸着剤（ｌａ） （２ａ）に吸着し、また
同吸着剤（ｌａ） （２ａ）に吸着したＣＯ，を水蒸気
により脱着すると戎に、吸着槽（１） （２）の出口側
に設けたＣ Ｏｚ濃度検出センサからの検出信号を脱着
開始信号とし、ＣＯ□温度検出センサからの検出信号を
脱着終了信号としている。また吸着槽の数は、処理量、
処理効率、運転時間等により決定されるが、空気を連続
的に処理する場合には、最低２槽が必要で、切り換え例
を第２図に示した。同２図では、平行線のない部分が吸
着状態を、水平の平行線部が空気追い出し状態を、斜め
の平行線部がＣＯを回収状態を、それぞれ示している。Automatic switching valve (13) (15) (16) from the same controller
A close control signal is sent to the automatic switching valve (11) (
12) (17) opens, and the same automatic switching valve (13) (1
5) (16) is closed and the adsorption tank (2) enters the desorption state. In addition, the CO2 concentration detection sensor on the adsorption tank (2) side
When z is detected, the CO□ concentration detection signal obtained at that time is sent from the CO2 concentration detection sensor to the controller, and the controller sends an open control signal to the automatic switching valve (18). A close control signal is sent to the automatic switching valve (14), the automatic switching valve (18) opens, and the automatic switching valve (14) opens.
) is closed and CO, is recovered in the COz tank (6°). After that, the above action is repeated, and Cog
are collected continuously. As is clear from the above explanation, in this example, COz in the air is absorbed into adsorption tanks (1) (2).
When CO adsorbed on the adsorbent (la) (2a) filled in the adsorbent (la) (2a) and desorbed by the same adsorbent (la) (2a) is desorbed by water vapor, the outlet side of the adsorption tank (1) (2) The detection signal from the COz concentration detection sensor provided at is used as the desorption start signal, and the detection signal from the CO□ temperature detection sensor is used as the desorption end signal. In addition, the number of adsorption tanks depends on the processing amount,
Although it is determined by treatment efficiency, operating time, etc., if air is to be treated continuously, at least two tanks are required, and an example of switching is shown in Fig. 2. In FIG. 2, the portions without parallel lines indicate the adsorption state, the horizontal parallel lines indicate the air expulsion state, and the diagonal parallel lines indicate the CO recovery state.
吸着槽（１）または（２）が脱着工程から吸着工程に切
り換えられた吸着初期には、吸着槽内の吸着剤は。At the initial stage of adsorption when the adsorption tank (1) or (2) is switched from the desorption process to the adsorption process, the adsorbent in the adsorption tank is
水蒸気により高温になっており、吸着剤に残留する高温
凝縮水が処理空気に同伴して蒸発し、吸着剤は乾燥、冷
却されるが、処理空気は高温の水分飽和に近い状態で排
出される。この熱エネルギーは、熱交換器（２８）で給
水管（２１’）内を流れる給水に与えられて、同給水が
予熱される。このときの状態を示したのが第４図で、高
温の水分飽和に近い状態で排出された処理空気が熱交換
器（２８）の伝熱管（２８ａ）内を流れて、給水管（２
１°）内を流れる給水が加熱される。蒸気発生器（２３
）で必要とする熱エネルギーは、水蒸気導入管（２１）
に設けた温度調節器（３０）または圧力調節器（３１）
からの検出信号に基づいて蒸気発生器（２３）のヒータ
（加熱装置）の出力を制御するが、このとき、上記のよ
うに給水が予熱されており、その分だけヒータの出力が
少なくなる（第３図参照）。なおヒータの出力は。The temperature is high due to water vapor, and the high-temperature condensed water remaining in the adsorbent evaporates along with the treated air, drying and cooling the adsorbent, but the treated air is discharged at a high temperature close to moisture saturation. . This thermal energy is given to the feed water flowing in the water supply pipe (21') by the heat exchanger (28) to preheat the feed water. The state at this time is shown in Fig. 4, where the treated air discharged at a high temperature and near moisture saturation flows through the heat exchanger tube (28a) of the heat exchanger (28), and the water supply pipe (2
1°) is heated. Steam generator (23
) The heat energy required by the steam introduction pipe (21)
Temperature regulator (30) or pressure regulator (31) installed in
The output of the heater (heating device) of the steam generator (23) is controlled based on the detection signal from the steam generator (23). (See Figure 3). Furthermore, the output of the heater is as follows.
熱交換器（２８）の大きさにもよるが、１０％程度節減
可能である。またガス導出管（２０）の下流側に設けた
排出空気冷却用ターラ（２８’）は、上記のように処理
空気が熱交換器（２８）で冷却され為ことにより、その
容量が１／２程度に小さくなる。Although it depends on the size of the heat exchanger (28), it is possible to save about 10%. In addition, the capacity of the discharge air cooling colander (28') provided downstream of the gas outlet pipe (20) is reduced to 1/2 because the treated air is cooled by the heat exchanger (28) as described above. becomes smaller to a certain degree.
（発明の効果）
本発明は前記のようにＣＯＺを含有する気体を導くガス
導入管と、同ガス導入管により供給された気体中からＣ
Ｏ□を捕獲する吸着剤を内部に充填した吸着槽と、ＣＯ
，から分離した気体を同吸着槽内から導出するガス導出
管と、気体から分離したＣｏｔを同吸着槽内から導出す
るＣＯ□導出管と、水蒸気を同吸着槽内へ供給する水蒸
気発生器と、上記各導出管と上記水蒸気発生器から上記
吸着槽への水蒸気流通経路とに設けた開閉弁と。(Effects of the Invention) As described above, the present invention provides a gas introduction pipe for introducing a gas containing COZ, and a COZ-containing gas introduction pipe for introducing COZ from the gas supplied by the gas introduction pipe.
An adsorption tank filled with adsorbent to capture O□ and CO
, a gas derivation pipe for deriving the gas separated from the gas from the adsorption tank, a CO□ derivation pipe for deriving the Cot separated from the gas from the adsorption tank, and a steam generator for supplying water vapor into the adsorption tank. , an on-off valve provided in each of the outlet pipes and a steam flow path from the steam generator to the adsorption tank.
前記水蒸気発生器へ供給される給水を前記ガス導出管か
らの気体により予熱する熱交換器とを具えており、開閉
弁を切り換えて、Ｃｏｇを含有する空気からＣＣｈを除
去するとき、即ち、ＣＯｚを含有する空気が吸着槽に入
り、ＣＯｚが同吸着槽内に充填された吸着剤に吸着され
る一方、ＣＯ□を分離した空気が同吸着槽からガス導出
管を経て排出され１次いで吸着槽に水蒸気が供給されて
。and a heat exchanger that preheats the feed water supplied to the steam generator with the gas from the gas outlet pipe, and when removing CCh from the air containing Cog by switching the on-off valve, that is, COz The air containing CO enters the adsorption tank, and COz is adsorbed by the adsorbent filled in the adsorption tank, while the air from which CO□ has been separated is discharged from the adsorption tank through a gas outlet pipe and then sent to the adsorption tank. water vapor is supplied to.
吸着剤が加熱され、吸着剤に吸着されていたＣ０２が吸
着剤から脱着されて、吸着剤が再生されると同時に脱着
されたＣＯ，がＣＯ，導出管を経て回収され１次いでＣ
Ｏｚの脱着を完了した直後の高温吸着剤にＣｏｔを含有
する空気が再び供給されて、同空気が加熱されると同時
に水分が蒸発して、吸着剤の乾燥と冷却とが行われ、同
時に００２の吸着が再開されて、加熱された空気がガス
導出管を経て排出されるときに、給水管内を流れて。The adsorbent is heated, and the CO2 adsorbed on the adsorbent is desorbed from the adsorbent, and the adsorbent is regenerated. At the same time, the desorbed CO is recovered through the outlet pipe, and the CO2 is then recovered as CO.
Immediately after completing desorption of Oz, air containing Cot is supplied again to the high-temperature adsorbent, and the air is heated and at the same time moisture evaporates, drying and cooling the adsorbent, and at the same time adsorption is resumed and the heated air flows through the water supply pipe when it is discharged through the gas outlet pipe.
水蒸気発生器に向かう給水が熱交換器で上記ガス導出管
を経て排出される高温の空気により予熱されるので、熱
回収効率を向上できる。またガス導出管には、排出され
る気体の温度を低下させるために、排出気体冷却用ター
ラを設けるが、上記のように給水に熱を与えて温度の低
下した気体が同排出気体冷却用ターラに入るので、排出
気体冷却用クーラの容量を小さくできる効果がある。Since the water supplied to the steam generator is preheated in the heat exchanger by the high temperature air discharged through the gas outlet pipe, heat recovery efficiency can be improved. In addition, the gas outlet pipe is equipped with an exhaust gas cooling tara in order to lower the temperature of the exhausted gas, but as mentioned above, the gas whose temperature has been lowered by applying heat to the water supply is passed through the exhaust gas cooling tartar. This has the effect of reducing the capacity of the exhaust gas cooling cooler.
以上本発明を実施例により説明したが２本発明はこのよ
うな実施例だけに限定されるものでなく。Although the present invention has been described above with reference to Examples, the present invention is not limited to these Examples.
本発明の精神を逸脱しない範囲内で種々の設計の改変を
施し得るものである。例えば温度調節装置は、気体の入
口温度を調節できるものであれば。Various design changes may be made without departing from the spirit of the invention. For example, the temperature control device can adjust the inlet temperature of the gas.
いかなるものでもよい。また水蒸気は、製造容易だし、
環境汚染がなくて、置換ガスとして有利である。また置
換ガス導入管、ガス導出管、ＣＯ□導出管は、吸着槽に
直接設ける必要はなく、 ＣＯ２導出管をガス導出管
から分岐して設けるなどしてもよい。またＣ０２回収タ
ンクをＣＯ□導出管に設ければ、ＣＯ２導出管がＣＯ□
回収装置になる。またＣＯ□回収タンクを設けずにＣｏ
２を系外へ直接放出してもよい。It can be anything. Also, water vapor is easy to produce,
It does not cause environmental pollution and is advantageous as a replacement gas. Further, the replacement gas inlet pipe, the gas outlet pipe, and the CO□ outlet pipe do not need to be provided directly in the adsorption tank, and the CO2 outlet pipe may be provided as a branch from the gas outlet pipe. Also, if a CO2 recovery tank is installed in the CO□ outlet pipe, the CO2 outlet pipe will become CO□
It becomes a collection device. Also, CO□ can be collected without installing a recovery tank.
2 may be directly released to the outside of the system.
第１図は本発明に係わるＣＯ，除去装置の一実施例を示
す系統図、第２図はその作用説明図、第３図は吸着後の
脱着開始時からの処理空気の排出温度を示す説明図、第
４図は熱交換器の作用説明図である。
（１）（２） −−・吸着槽、（ｌａ）（ｌｂ） −
−−吸着剤。
（１１）〜（１８）・・・開閉弁、 （１９） ・・
・ガス導入管、 （２０）・・・ガス導出管、 （２２
）・・・ＣＯ，導出管、 （２３） ・・・水蒸気発
生器、 （２８）・・・熱交換器。
復代理人弁理士岡本重文外２名
第３図
路
％４図Fig. 1 is a system diagram showing an embodiment of the CO removal device according to the present invention, Fig. 2 is an explanatory diagram of its operation, and Fig. 3 is an explanation showing the exhaust temperature of treated air from the start of desorption after adsorption. FIG. 4 is an explanatory diagram of the operation of the heat exchanger. (1) (2) --- Adsorption tank, (la) (lb) -
--Adsorbent. (11) to (18)...on/off valve, (19)...
・Gas inlet pipe, (20)...Gas outlet pipe, (22
)...CO, outlet pipe, (23)...steam generator, (28)...heat exchanger. Sub-Agent Patent Attorney Shigemon Okamoto (2 persons) Figure 3 % 4 Figure
Claims (1)
入管により供給された気体中からＣＯ＿２を捕獲する吸
着剤を内部に充填した吸着槽と、ＣＯ＿２から分離した
気体を同吸着槽内から導出するガス導出管と、気体から
分離したＣＯ＿２を同吸着槽内から導出するＣＯ＿２導
出管と、水蒸気を同吸着槽内へ供給する水蒸気発生器と
、上記各導出管と上記水蒸気発生器から上記吸着槽への
水蒸気流通経路とに設けた開閉弁と、前記水蒸気発生器
へ供給される給水を前記ガス導出管からの気体により予
熱する熱交換器とを具えていることを特徴としたＣＯ＿
２除去装置。A gas introduction pipe that introduces gas containing CO_2, an adsorption tank filled with an adsorbent that captures CO_2 from the gas supplied by the gas introduction pipe, and a gas separated from CO_2 that is led out from within the adsorption tank. a CO_2 outlet pipe that leads out CO_2 separated from the gas from the adsorption tank; a steam generator that supplies water vapor into the adsorption tank; CO_, characterized by comprising an on-off valve provided in a steam flow path to the tank, and a heat exchanger that preheats the water supplied to the steam generator with gas from the gas outlet pipe.
2 removal device.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP60093599A JPS61254221A (en) | 1985-05-02 | 1985-05-02 | Apparatus for removing co2 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP60093599A JPS61254221A (en) | 1985-05-02 | 1985-05-02 | Apparatus for removing co2 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS61254221A true JPS61254221A (en) | 1986-11-12 |
| JPH0568290B2 JPH0568290B2 (en) | 1993-09-28 |
Family
ID=14086779
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP60093599A Granted JPS61254221A (en) | 1985-05-02 | 1985-05-02 | Apparatus for removing co2 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS61254221A (en) |
Cited By (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6359339A (en) * | 1986-08-29 | 1988-03-15 | Sumitomo Heavy Ind Ltd | Heat recovery method in carbon dioxide removing apparatus |
| JPS6369527A (en) * | 1986-09-10 | 1988-03-29 | Sumitomo Heavy Ind Ltd | Waste heat recovering method in carbon dioxide removing method by ion exchange resin |
| JPH04108568U (en) * | 1991-02-25 | 1992-09-18 | サンデン株式会社 | oxygen enrichment device |
| JP2009502483A (en) * | 2005-07-28 | 2009-01-29 | グローバル リサーチ テクノロジーズ，エルエルシー | Carbon dioxide removal from the air |
| JP2010069398A (en) * | 2008-09-17 | 2010-04-02 | Ngk Insulators Ltd | Co2 separating/recovering method |
| WO2012164856A1 (en) * | 2011-05-31 | 2012-12-06 | 川崎重工業株式会社 | Co2 recovery method and apparatus |
| JP2014504695A (en) * | 2011-01-20 | 2014-02-24 | サウジ アラビアン オイル カンパニー | In-vehicle recovery and storage of CO2 derived from automobile exhaust gas |
| JP2014509360A (en) * | 2011-01-20 | 2014-04-17 | サウジ アラビアン オイル カンパニー | Reversible solid adsorption method and system using waste heat for in-vehicle capture and storage of CO2 |
| US8999279B2 (en) | 2008-06-04 | 2015-04-07 | Carbon Sink, Inc. | Laminar flow air collector with solid sorbent materials for capturing ambient CO2 |
| JP2015515925A (en) * | 2012-05-04 | 2015-06-04 | ピーター・アイゼンベルガー | System and method for capturing and sequestering carbon dioxide |
| US9205372B2 (en) | 2006-03-08 | 2015-12-08 | Carbon Sink, Inc. | Air collector with functionalized ion exchange membrane for capturing ambient CO2 |
| US9266051B2 (en) | 2005-07-28 | 2016-02-23 | Carbon Sink, Inc. | Removal of carbon dioxide from air |
| US9266052B2 (en) | 2006-10-02 | 2016-02-23 | Carbon Sink, Inc. | Method and apparatus for extracting carbon dioxide from air |
| US9527747B2 (en) | 2008-02-19 | 2016-12-27 | Carbon Sink, Inc. | Extraction and sequestration of carbon dioxide |
| US9616375B2 (en) | 2007-04-17 | 2017-04-11 | Carbon Sink, Inc. | Capture of carbon dioxide (CO2) from air |
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-
1985
- 1985-05-02 JP JP60093599A patent/JPS61254221A/en active Granted
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6359339A (en) * | 1986-08-29 | 1988-03-15 | Sumitomo Heavy Ind Ltd | Heat recovery method in carbon dioxide removing apparatus |
| JPS6369527A (en) * | 1986-09-10 | 1988-03-29 | Sumitomo Heavy Ind Ltd | Waste heat recovering method in carbon dioxide removing method by ion exchange resin |
| JPH04108568U (en) * | 1991-02-25 | 1992-09-18 | サンデン株式会社 | oxygen enrichment device |
| JP2009502483A (en) * | 2005-07-28 | 2009-01-29 | グローバル リサーチ テクノロジーズ，エルエルシー | Carbon dioxide removal from the air |
| US10010829B2 (en) | 2005-07-28 | 2018-07-03 | Carbon Sink, Inc. | Removal of carbon dioxide from air |
| US9266051B2 (en) | 2005-07-28 | 2016-02-23 | Carbon Sink, Inc. | Removal of carbon dioxide from air |
| US9205372B2 (en) | 2006-03-08 | 2015-12-08 | Carbon Sink, Inc. | Air collector with functionalized ion exchange membrane for capturing ambient CO2 |
| US10150112B2 (en) | 2006-03-08 | 2018-12-11 | Carbon Sink, Inc. | Air collector with functionalized ion exchange membrane for capturing ambient CO2 |
| US9266052B2 (en) | 2006-10-02 | 2016-02-23 | Carbon Sink, Inc. | Method and apparatus for extracting carbon dioxide from air |
| US9861933B2 (en) | 2006-10-02 | 2018-01-09 | Carbon Sink, Inc. | Method and apparatus for extracting carbon dioxide from air |
| US9616375B2 (en) | 2007-04-17 | 2017-04-11 | Carbon Sink, Inc. | Capture of carbon dioxide (CO2) from air |
| US9527747B2 (en) | 2008-02-19 | 2016-12-27 | Carbon Sink, Inc. | Extraction and sequestration of carbon dioxide |
| US8999279B2 (en) | 2008-06-04 | 2015-04-07 | Carbon Sink, Inc. | Laminar flow air collector with solid sorbent materials for capturing ambient CO2 |
| JP2010069398A (en) * | 2008-09-17 | 2010-04-02 | Ngk Insulators Ltd | Co2 separating/recovering method |
| JP2014509360A (en) * | 2011-01-20 | 2014-04-17 | サウジ アラビアン オイル カンパニー | Reversible solid adsorption method and system using waste heat for in-vehicle capture and storage of CO2 |
| JP2014504695A (en) * | 2011-01-20 | 2014-02-24 | サウジ アラビアン オイル カンパニー | In-vehicle recovery and storage of CO2 derived from automobile exhaust gas |
| JP2012250142A (en) * | 2011-05-31 | 2012-12-20 | Kawasaki Heavy Ind Ltd | Co2 recovery method and apparatus |
| AU2012264072C9 (en) * | 2011-05-31 | 2015-11-12 | Kawasaki Jukogyo Kabushiki Kaisha | CO2 recovery method and apparatus |
| AU2012264072C1 (en) * | 2011-05-31 | 2015-08-27 | Kawasaki Jukogyo Kabushiki Kaisha | CO2 recovery method and apparatus |
| AU2012264072B2 (en) * | 2011-05-31 | 2015-05-07 | Kawasaki Jukogyo Kabushiki Kaisha | CO2 recovery method and apparatus |
| US8951490B2 (en) | 2011-05-31 | 2015-02-10 | Kawaski Jukogyo Kabushiki Kaisha | CO2 recovery method and apparatus |
| CN103501876A (en) * | 2011-05-31 | 2014-01-08 | 川崎重工业株式会社 | CO2 recovery method and apparatus |
| WO2012164856A1 (en) * | 2011-05-31 | 2012-12-06 | 川崎重工業株式会社 | Co2 recovery method and apparatus |
| JP2015515925A (en) * | 2012-05-04 | 2015-06-04 | ピーター・アイゼンベルガー | System and method for capturing and sequestering carbon dioxide |
| US11737398B2 (en) | 2018-02-16 | 2023-08-29 | Carbon Sink, Inc. | Fluidized bed extractors for capture of CO2 from ambient air |
| CN113075949A (en) * | 2021-03-24 | 2021-07-06 | 西北大学 | Fruit vegetables storeroom CO2Automatic concentration regulating and controlling device and working method thereof |
| CN113075949B (en) * | 2021-03-24 | 2022-03-25 | 西北大学 | Fruit vegetables storeroom CO2Automatic concentration regulating and controlling device and working method thereof |
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|---|---|
| JPH0568290B2 (en) | 1993-09-28 |
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