JPS61225779A - Liquid fuel cell - Google Patents

Liquid fuel cell

Info

Publication number
JPS61225779A
JPS61225779A JP60066304A JP6630485A JPS61225779A JP S61225779 A JPS61225779 A JP S61225779A JP 60066304 A JP60066304 A JP 60066304A JP 6630485 A JP6630485 A JP 6630485A JP S61225779 A JPS61225779 A JP S61225779A
Authority
JP
Japan
Prior art keywords
separator
electrode
electrodes
electrolyte
fuel cell
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP60066304A
Other languages
Japanese (ja)
Inventor
Toshiaki Konuki
利明 小貫
Yoichi Nomura
洋一 野村
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Resonac Corp
Original Assignee
Shin Kobe Electric Machinery Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shin Kobe Electric Machinery Co Ltd filed Critical Shin Kobe Electric Machinery Co Ltd
Priority to JP60066304A priority Critical patent/JPS61225779A/en
Publication of JPS61225779A publication Critical patent/JPS61225779A/en
Pending legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/02Details
    • H01M8/0271Sealing or supporting means around electrodes, matrices or membranes
    • H01M8/0273Sealing or supporting means around electrodes, matrices or membranes with sealing or supporting means in the form of a frame
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/24Grouping of fuel cells, e.g. stacking of fuel cells
    • H01M8/2455Grouping of fuel cells, e.g. stacking of fuel cells with liquid, solid or electrolyte-charged reactants
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Fuel Cell (AREA)

Abstract

PURPOSE:To prevent electrolyte leakage by using expansion material in a connecting part of a cell frame and a separator, and separately pressing an electrode surface and separator surface. CONSTITUTION:A flange 10 having expansion and contracting property is formed in a separator 1, and the separator 1 and a cell frame 2' are connected by the flange 10. Liquid sealing of a cell main body is performed in such a way that a gasket 3 is arranged between electrodes 4, 5, and the sealing surface is fastened with a compression plate 7, bolt 8, and nut 9 to make the gasket 3 and cell frames 2, 2' to adhere closely. An electrode compression plate 11 is arranged inside the compression plate 7, and pressed to simultaneously compress the separator 1 and electrodes 4, 5 with the flange 10. Thereby, adhesion of the electrodes 4, 5 with electrolyte 6 is increased and electrolyte leakage can be prevented.

Description

【発明の詳細な説明】 産業上の利用分野 本発明は、液体を燃料とするヒドラジン−空気燃料電池
、メタノール−空気燃料電池等に関するものである。特
に電極面とシール面の加圧の均一化に関するものである
DETAILED DESCRIPTION OF THE INVENTION Field of the Invention The present invention relates to hydrazine-air fuel cells, methanol-air fuel cells, etc. that use liquid as fuel. In particular, it relates to equalizing the pressure applied to the electrode surface and the seal surface.

従来の技術 従来、この種の燃料電池は、安定した電池性能を得るた
めに電極と電解質を密着させなければならない。また、
電池内の液シールをする鬼めのガスケットを加圧する必
要がある。これら2種の面を、電池本体の両端にボルト
穴をあけた加圧板を配置し、これら加圧板と電池本体を
ボルト、ナツトにより締め付けることにより同時に加圧
していた。
BACKGROUND OF THE INVENTION Conventionally, this type of fuel cell requires close contact between electrodes and electrolyte in order to obtain stable cell performance. Also,
It is necessary to pressurize the gasket that seals the liquid inside the battery. These two types of surfaces were simultaneously pressurized by placing pressure plates with bolt holes at both ends of the battery body and tightening these pressure plates and the battery body with bolts and nuts.

発明が解決しようとする問題点 上記従来の燃料電池を第3図に示す。加圧板7、ボルト
8とナツト9にて電池本体を締め付は加圧する。液シー
ルは、ガスケット3をセパレータ1、電池枠2で加圧密
着させて行なっている。また、電極4.5と電解質6の
密着は、セパレータlにて電極4.5を加圧することに
より密着させている。このようにζ電極面とシール面を
同時に加圧しており、従来、この両面の加圧を最適な状
態にするため、電池本体の締め付は後の寸法を限定し、
その時の電極面およびシール面に加わる圧力をあらかじ
め測定しておき、それに合せて締め付は加圧を行なって
いた。この方法で設計値よりも厚くなった電極を使用し
、電極と電解質の密着を最適状態になるよう加圧すると
、シール面の加圧が不足し液漏れが生じる。この状態で
シール面の加圧を最適にすると、電極が破損するという
問題があった。
Problems to be Solved by the Invention The conventional fuel cell described above is shown in FIG. The battery body is tightened and pressurized using the pressure plate 7, bolts 8, and nuts 9. Liquid sealing is performed by pressing the gasket 3 into close contact with the separator 1 and the battery frame 2. Moreover, the electrode 4.5 and the electrolyte 6 are brought into close contact by pressurizing the electrode 4.5 with the separator 1. In this way, the ζ electrode surface and the sealing surface are pressurized at the same time, and conventionally, in order to optimize the pressurization on both sides, the tightening of the battery body was limited to the later dimensions.
The pressure applied to the electrode surface and sealing surface at that time was measured in advance, and the pressure was applied accordingly. If this method uses an electrode that is thicker than the designed value and pressurizes the electrode and electrolyte to achieve optimal adhesion, the sealing surface will not be pressurized enough, causing liquid leakage. If the pressure on the sealing surface was optimized in this state, there was a problem that the electrode would be damaged.

また、設計値よりも薄い電極を使用し、電極と電解質の
密着を最適状態にすると、シール面の加圧が過剰になり
、ガスケットに皺が生じ液漏れが起る。逆にシール面の
加圧を最適にすると電極と電解質の密着性が低下し、安
定した電池性能が得られないという問題が生じる。同様
に他の電池部品の厚さが変化しても上述のような問題が
生じる。電極面とシール面を同時に最適な状態になるよ
う加圧するには、電池部品の厚さ方向の寸法精度を1/
20■以内にしなければならないという欠点があった。
Furthermore, if an electrode is used that is thinner than the designed value and the adhesion between the electrode and the electrolyte is optimized, the pressure on the sealing surface will be excessive, causing wrinkles in the gasket and causing liquid leakage. On the other hand, if the pressure applied to the sealing surface is optimized, the adhesion between the electrode and the electrolyte decreases, causing the problem that stable battery performance cannot be obtained. Similarly, the above-mentioned problems occur when the thicknesses of other battery components change. In order to pressurize the electrode surface and the seal surface simultaneously to the optimum state, the dimensional accuracy in the thickness direction of the battery components should be reduced by 1/2.
There was a drawback that it had to be within 20 ■.

本発明は上記欠点を解決することを目的とするものであ
る。
The present invention aims to solve the above-mentioned drawbacks.

問題点を解決するための手段 上記の目的を達成するため2こ、セパレータノ外寸法を
電極のそれと同程度にし、この外周に伸縮性のあるゴム
、合成樹脂等の鍔を設け、セパレータと電池枠をこの鍔
によって連結するようにしたものである。
Means for Solving the Problems In order to achieve the above objectives, the outer dimensions of the separator are made to be the same as those of the electrodes, and a collar made of elastic rubber, synthetic resin, etc. is provided around the outer periphery of the separator, and the separator and battery are The frames are connected by this tsuba.

作用 これにより、シール面の加圧と電極面の加圧を別個に行
なうことができる。
Effect: This makes it possible to pressurize the sealing surface and the electrode surface separately.

実施例 本発明の一実施例を第1図、第2図により説明する。Example An embodiment of the present invention will be described with reference to FIGS. 1 and 2.

セパレータ1に伸縮性のある鍔10を設け、この鍔10
にてセパレータlと電池枠2′を連結する。
A stretchable collar 10 is provided on the separator 1, and this collar 10
At this point, the separator l and the battery frame 2' are connected.

間に配置し、このシール面を加圧板7、ボルト8、ナツ
ト9により締め付は加圧し、ガスケット3と電池枠2.
2′を密着させて行なう。
The gasket 3 and the battery frame 2 are placed between the gasket 3 and the battery frame 2.
2' in close contact.

加圧板7にネジ穴を設け、このネジ穴に六角ポル)12
を取り付け、加圧板7の内側に電極加圧板11を配置し
、六角ポル)12を時計回りに回転させる事により電極
加圧板11を加圧し、伸縮性のある鍔LOにて電池枠2
′と連結された加圧方向において自由度のあるセパレー
タLと、その内側に位置する電極4.5も同時に加圧す
ることにより、この電極4.5と電解質6の密着性を良
好にする。
A screw hole is provided in the pressure plate 7, and a hexagonal hole is inserted into this screw hole.
, place the electrode pressure plate 11 inside the pressure plate 7, pressurize the electrode pressure plate 11 by rotating the hexagonal pole 12 clockwise, and attach the battery frame 2 with the elastic collar LO.
By simultaneously pressurizing the separator L, which has a degree of freedom in the pressurizing direction and is connected to the separator L, and the electrode 4.5 located inside the separator L, the adhesion between the electrode 4.5 and the electrolyte 6 is improved.

また、液シールにガスケット3を使用せず、電池枠2及
び2′を熱溶着あるいは超音波溶着等の溶着法にて密着
させて液シールする方法でも加圧方向に自由度のあるセ
パレータLにて、電極4.5と電解質6の密着を良好に
することができる。
Alternatively, the separator L can be used with flexibility in the pressure direction even if the gasket 3 is not used for liquid sealing, and the battery frames 2 and 2' are closely attached using a welding method such as heat welding or ultrasonic welding. Therefore, the adhesion between the electrode 4.5 and the electrolyte 6 can be improved.

発明の効果 上述のように、本発明によりシール面の加圧と電極面の
加圧を別個に行なうことができるため、それぞれの加圧
面が最適に加圧され、液漏れがなくなり安定した電池性
能を得ることができ、さらに、シール面を溶着しても電
極面の加圧が可能になる。また、電池部品の寸法精度を
L / 2 w程度にまで粗くすることができるため、
極めて工業的価値大なるものである。
Effects of the Invention As mentioned above, according to the present invention, it is possible to pressurize the sealing surface and the electrode surface separately, so each pressurizing surface is optimally pressurized, eliminating leakage and achieving stable battery performance. Furthermore, even if the sealing surface is welded, the electrode surface can be pressurized. In addition, the dimensional accuracy of battery parts can be made as rough as L/2W.
It has extremely great industrial value.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は本発明の一実施例を示す要部断面図、第2図は
第1図におけるセパレータの断面図、第3図は従来の燃
料電池を示す要部断面図である。
FIG. 1 is a sectional view of a main part showing an embodiment of the present invention, FIG. 2 is a sectional view of a separator in FIG. 1, and FIG. 3 is a sectional view of a main part of a conventional fuel cell.

Claims (1)

【特許請求の範囲】[Claims] 相対向する陰極および陽極、陰極と陽極の間に電解質、
それぞれの陰極と陽極の外側にセパレータ、これらを囲
むように電池枠を配置した液体燃料電池において、電池
枠とセパレータとの連結部分に伸縮性材料を用いること
により、電極面とシール面の加圧を別個に行なうことを
特徴とする液体燃料電池。
A cathode and an anode facing each other, an electrolyte between the cathode and the anode,
In a liquid fuel cell in which a separator is placed on the outside of each cathode and anode, and a battery frame is placed to surround them, pressure can be applied between the electrode surface and the sealing surface by using a stretchable material at the connection between the battery frame and the separator. A liquid fuel cell characterized by separately carrying out the following.
JP60066304A 1985-03-29 1985-03-29 Liquid fuel cell Pending JPS61225779A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP60066304A JPS61225779A (en) 1985-03-29 1985-03-29 Liquid fuel cell

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP60066304A JPS61225779A (en) 1985-03-29 1985-03-29 Liquid fuel cell

Publications (1)

Publication Number Publication Date
JPS61225779A true JPS61225779A (en) 1986-10-07

Family

ID=13311933

Family Applications (1)

Application Number Title Priority Date Filing Date
JP60066304A Pending JPS61225779A (en) 1985-03-29 1985-03-29 Liquid fuel cell

Country Status (1)

Country Link
JP (1) JPS61225779A (en)

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0620609A1 (en) * 1993-03-26 1994-10-19 Daimler-Benz Aktiengesellschaft Electrochemical multicell-battery
EP1094536A1 (en) * 1999-10-22 2001-04-25 General Motors Corporation Fuel cell stack compression method and apparatus
US6663995B2 (en) 2002-04-30 2003-12-16 General Motors Corporation End plates for a fuel cell stack structure
US6936362B2 (en) 2003-04-14 2005-08-30 General Motors Corporation Variable pressure drop stack
US7087333B2 (en) 2003-02-26 2006-08-08 General Motors Corporation Hydrogen recirculation without a pump
US7169491B2 (en) 2003-02-26 2007-01-30 General Motors Corporation Flexible system for hydrogen recirculation
US7344797B2 (en) 2002-04-30 2008-03-18 General Motors Corporation Compact fuel cell stack structure
US7396601B2 (en) 2003-04-14 2008-07-08 General Motors Corporation Flow control for multiple stacks
US7704626B2 (en) 2004-07-29 2010-04-27 Gm Global Technology Operations, Inc. Isolated and insulated stack end unit inlet/outlet manifold headers

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0620609A1 (en) * 1993-03-26 1994-10-19 Daimler-Benz Aktiengesellschaft Electrochemical multicell-battery
EP1094536A1 (en) * 1999-10-22 2001-04-25 General Motors Corporation Fuel cell stack compression method and apparatus
US6428921B1 (en) 1999-10-22 2002-08-06 General Motors Corporation Fuel cell stack compression method and apparatus
US6663995B2 (en) 2002-04-30 2003-12-16 General Motors Corporation End plates for a fuel cell stack structure
US7344797B2 (en) 2002-04-30 2008-03-18 General Motors Corporation Compact fuel cell stack structure
US7087333B2 (en) 2003-02-26 2006-08-08 General Motors Corporation Hydrogen recirculation without a pump
US7169491B2 (en) 2003-02-26 2007-01-30 General Motors Corporation Flexible system for hydrogen recirculation
US6936362B2 (en) 2003-04-14 2005-08-30 General Motors Corporation Variable pressure drop stack
US7396601B2 (en) 2003-04-14 2008-07-08 General Motors Corporation Flow control for multiple stacks
US7749634B2 (en) 2003-04-14 2010-07-06 Gm Global Technology Operations, Inc. Flow control for multiple stacks
US7704626B2 (en) 2004-07-29 2010-04-27 Gm Global Technology Operations, Inc. Isolated and insulated stack end unit inlet/outlet manifold headers

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