JPS61188992A - Glass fabrics for printed circuit board - Google Patents

Glass fabrics for printed circuit board

Info

Publication number
JPS61188992A
JPS61188992A JP60029038A JP2903885A JPS61188992A JP S61188992 A JPS61188992 A JP S61188992A JP 60029038 A JP60029038 A JP 60029038A JP 2903885 A JP2903885 A JP 2903885A JP S61188992 A JPS61188992 A JP S61188992A
Authority
JP
Japan
Prior art keywords
fabric
printed circuit
warp
agent
woven
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP60029038A
Other languages
Japanese (ja)
Other versions
JPH0571155B2 (en
Inventor
正治 矢野
高砂 和芳
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Arisawa Mfg Co Ltd
Original Assignee
Arisawa Mfg Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Arisawa Mfg Co Ltd filed Critical Arisawa Mfg Co Ltd
Priority to JP60029038A priority Critical patent/JPS61188992A/en
Publication of JPS61188992A publication Critical patent/JPS61188992A/en
Publication of JPH0571155B2 publication Critical patent/JPH0571155B2/ja
Granted legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K1/00Printed circuits
    • H05K1/02Details
    • H05K1/03Use of materials for the substrate
    • H05K1/0313Organic insulating material
    • H05K1/0353Organic insulating material consisting of two or more materials, e.g. two or more polymers, polymer + filler, + reinforcement
    • H05K1/0366Organic insulating material consisting of two or more materials, e.g. two or more polymers, polymer + filler, + reinforcement reinforced, e.g. by fibres, fabrics

Landscapes

  • Treatment Of Fiber Materials (AREA)
  • Woven Fabrics (AREA)

Abstract

(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。
(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.

Description

【発明の詳細な説明】 この発明は、ガラス織物の耳部なほつれ止めする際その
耳部が織物地よりも耳高にならないプリント基板用ガラ
ス織物に係るものである。
DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a glass fabric for printed circuit boards in which the edges of the glass fabric do not become higher than the fabric when the edges of the glass fabric are prevented from fraying.

本発明を添付図面を参照して詳述すると次の通りである
The present invention will be described in detail with reference to the accompanying drawings.

無杼織機(:よりプリント基板用ガラス織物を製織する
際プリント基板用織物の両側の耳部(1)の経糸(2]
を織地部経糸(3)よりも細い経糸を使用し、且つ織地
部(4)よりも経糸密度を高くして耳部(1)が織地部
(4)より薄いガラス織物(5)を製織し、この薄い耳
部(1]にほつれ防止剤(6)を耳部(1)が織地部(
4)と略同厚になるように塗布せしめる。
Shuttleless loom (: When weaving glass fabric for printed circuit boards, the warp threads (2) of the ears (1) on both sides of the fabric for printed circuit boards)
Weave a glass fabric (5) in which the selvage part (1) is thinner than the woven part (4) by using a warp thinner than the woven part warp (3) and having a higher warp density than the woven part (4). , apply an anti-fray agent (6) to this thin selvedge (1) so that the selvedge (1) is a woven fabric (
Apply it to approximately the same thickness as 4).

はつれ防止剤は、プリント基板用の樹脂含浸時に使用す
る溶剤に殆ど溶解しない、且つ含浸織物の乾燥温度にお
いて軟化しない接着剤を採用する。
As the anti-tangling agent, an adhesive is used that hardly dissolves in the solvent used when impregnating the resin for printed circuit boards and does not soften at the drying temperature of the impregnated fabric.

はつれ防止剤の塗布は、上記耳部の切断前でも切断後で
もよく、塗布方法は溶液型塗布またはホットメルト型塗
布等適宜都合の良い方法で行えば良い、(図中二点鎖線
が切断位置である。)はつれ防止剤の塗布量は、細糸を
使用した耳部にほつれ防止剤をほつれ防止効果が充分に
発揮できる量とし、且つほつれ防止剤を塗布した耳部の
厚さを織地部の厚さと実質的に同一厚さになるように樹
脂量を選択する。
The anti-tangling agent may be applied before or after cutting the above-mentioned ears, and may be applied by any convenient method such as solution-type coating or hot-melt coating. ) The amount of anti-fray agent to be applied is such that the amount of anti-fray agent applied to the selvedge using thin thread is enough to exert the fray-preventing effect, and the thickness of the selvage area to which the anti-fray agent is applied is The amount of resin is selected to have a thickness that is substantially the same as the thickness of the fabric.

少し位薄くなることは許容出来るが厚くしない。I can tolerate it being a little thinner, but I don't want it to be thicker.

従来、無杼織機:二より製織したプリント基板用ガラス
織物には、例えば特開昭52−34094号に記載され
ているように織物地部と同一構成である耳部にほつれ防
止剤を塗布し、乾燥後その耳部の外端を切除してロール
巻きする方法が開示されている。
Conventionally, shuttleless loom: Two-strand woven glass fabric for printed circuit boards has been coated with an anti-fray agent on the edges, which have the same structure as the woven fabric, as described in Japanese Patent Application Laid-Open No. 52-34094, for example. discloses a method of cutting off the outer end of the ear after drying and rolling it.

このような方法で製造した長尺のガラス織物をロール巻
きにすると耳部が織物地よりも肉厚の為捲回量が多くな
ればなる程耳高を生じる危険があり、耳部近くでのシワ
や織地部の緯糸の自白がりが発生し、品質の低下をもた
らす欠点があった。
When a long glass fabric manufactured by this method is rolled, the selvage is thicker than the fabric, so the more the winding amount is, the higher the selvage will be. There were drawbacks such as wrinkles and weft wefts in the woven fabric, which resulted in a decline in quality.

更に、はつれ防止剤の塗布量をロール巻き時の耳高が生
じない程度に減ずれば、はつれ防止効果が不充分となり
、織物のロール巻き時やその織物に樹脂な含浸、乾燥す
る時に切断端部の経糸はつれか発生し、ロールにからま
ったり、成るいはプリプレグ中ζ二混入したりする欠点
があった。
Furthermore, if the amount of anti-tangling agent applied is reduced to such an extent that no selvage occurs when the fabric is rolled, the anti-tangling effect will be insufficient, and the anti-tangling agent will be less effective when the fabric is rolled, impregnated with resin, and dried. The warp threads at the cut ends tend to become tangled, become tangled in the rolls, or get mixed into the prepreg.

また、この従来の方法で製造したガラス織物にほつれ防
止効果を充分に発揮できる量のほつれ防止剤を塗布する
と、プリプレグを所望の長さに切断し積み重ねた時に耳
高のためそれの中程が湾曲し、自動機械による搬送上の
トラブルを生じる欠点があった〇 (以下余白) −を 本発明は、このような欠点を解決したもので、耳部の経
糸は織物地の経糸よりも細く、且つ経糸密度を高くする
から耳部は必ず織物地よりも薄くなる。
Furthermore, if a sufficient amount of anti-fray agent is applied to the glass fabric manufactured by this conventional method to have a sufficient anti-fray effect, when the prepreg is cut to a desired length and stacked, the middle part of the prepreg will be cut due to the height of the edges. The present invention solves these drawbacks, and the warp of the selvedge is thinner than the warp of the woven fabric. In addition, since the warp density is increased, the selvage portion is always thinner than the woven fabric.

この薄くなった耳部にほつれ防止剤を塗布するから在来
のように耳部が織地部より肉厚になることが防止され、
所謂耳高による前記したような欠点が全て是正されるこ
とになり、ガラス織物をロール巻きする時、またガラス
織物を基材としてプリプレグな製造する時のいずれ(−
際しても、はつれ防止の効果を充分に発揮でき且つ耳高
による支障を発生させないプリント基板用ガラス織物と
なる。
By applying an anti-fray agent to this thinned selvage, the selvage is prevented from becoming thicker than the woven fabric, as is the case with conventional methods.
All of the above-mentioned drawbacks due to the so-called selvage height will be corrected, and it will be possible to correct both when winding glass fabric into rolls and when producing prepreg using glass fabric as a base material (-
At the same time, the glass fabric for printed circuit boards can sufficiently exhibit the effect of preventing fraying and does not cause problems due to the height of the edges.

その上細い経糸が密に並べられているところにほつれ防
止剤を塗布すれば太い経糸を並べている場合よりも接電
にあずかる表面積が大きくなるからそれだけ接着が良好
となり、少ない樹脂量でも確実にほつれ止め効果が得ら
れることになる。
Furthermore, if anti-fray is applied to areas where thin warp threads are closely arranged, the surface area available for electrical contact will be larger than when thick warp threads are arranged, resulting in better adhesion. This will provide a stopping effect.

この為はつれ止防止剤を塗布した部分を織地部と同厚に
することも容易となる。
For this reason, it is easy to make the part coated with the anti-tangling agent the same thickness as the woven fabric part.

このように織地部と耳部とが同一厚のガラス織物を使用
してプリント基板を製造すればプリント基板は必ず平ら
な基板にあるから銅箔を重ねた場合でもその銅箔にシワ
が生じて不良品になることなどもなくなる等プリント基
板用ガラス織物として秀れた実用性を発揮する。
If a printed circuit board is manufactured using a glass fabric with the same thickness for the fabric and edges, the printed circuit board will always be a flat board, so even if copper foil is layered, the copper foil will not wrinkle. It exhibits excellent practicality as a glass fabric for printed circuit boards, such as eliminating the possibility of defective products.

尚本発明のプリント基板用ガラス織物と、従来の製品と
の対比測定表を提示する。
A comparison measurement table between the glass fabric for printed circuit boards of the present invention and conventional products will be presented.

以下、実施例により本発明の具体化の諸態様を説明する
が、本発明はこれに限定されるものではない。
Hereinafter, various embodiments of the present invention will be explained with reference to Examples, but the present invention is not limited thereto.

実施例 プリント基板用ガラス織物を以下の方法で製織した。Example A glass fabric for printed circuit boards was woven by the following method.

ン(E・IEガラス、Cは長繊維、Gは7番手である)
を2172本、耳部用の経糸にECGI503Aのヤー
ンを16本使用してワーブ−ビームに巻き取った〇 このワープ−ビームを無杼織機(:仕掛け、緯糸HB 
CG 7r〆のヤーンを使用して製織した。
(E/IE glass, C is long fiber, G is 7th fiber)
2172 yarns and 16 ECGI503A yarns were used as the warp for the selvedges, and were wound around a warp beam. This warp beam was then wound on a shuttleless loom (: device, weft HB
It was woven using CG 7r yarn.

上記織物を350℃で100時間ヒートクリーニングし
た後、τ−グリシドオキシプロビルトリメトキシシラン
の011%水溶液で処理乾燥した。
The fabric was heat cleaned at 350° C. for 100 hours, then treated with a 0.11% aqueous solution of τ-glycidoxypropyltrimethoxysilane and dried.

次で、前記織物の耳部の経方向に帯状にテレフタル酸−
イソフタル酸−アジビン酸−1,4−ブタンジオールの
組成より成る共重合ポリエステル樹脂で軟化点180°
のほつれ防止剤を5舛塩化メデレン溶液で塗布乾燥した
Next, terephthalic acid is applied in a band shape in the warp direction of the selvage of the fabric.
A copolyester resin with a composition of isophthalic acid-adibic acid-1,4-butanediol with a softening point of 180°.
An anti-fray agent was applied with a solution of medelene chloride and dried.

はつれ防止剤の塗布幅は約6%、樹脂付着量は6%であ
)た。
The coating width of the anti-tangling agent was approximately 6%, and the amount of resin adhesion was 6%.

はつれ防止剤塗布帯の中央付近をスリッターでカットし
た。
A slitter was used to cut the area around the center of the strip coated with the anti-tangling agent.

はつれ防止効果を見るため、切断後の最端部の経糸の引
き剥がしをテストしたが目止め力が強く、その経糸は切
断した。
In order to see the effect of preventing fraying, we tested peeling off the warp at the end after cutting, but the sealing force was strong and that warp was cut.

上記のよう(:製造したほつれ防止剤を塗布したプリン
ト基板用ガラス織物の4,000”を紙管にショアー硬
度約80でロール巻キシタが、はつれ及び耳高、シワ、
自白カー0など)ま全く生じなかった。
As mentioned above (: 4,000" of manufactured glass fabric for printed circuit boards coated with an anti-fray agent is rolled into a paper tube with a Shore hardness of about 80.
Confession car 0, etc.) did not occur at all.

更に、上記織物にエポキシ樹脂を含浸・乾燥させて樹脂
金137%のプリプレグを作製した。
Furthermore, the fabric was impregnated with epoxy resin and dried to produce a prepreg containing 137% resin gold.

比較例 次::比較例として、経糸、緯糸とも(:E CG75
・兄のヤーンを使用して織地部と耳部の構成が同一であ
るガラス織物を無杼織機で製織した。
Comparative example: As a comparative example, both warp and weft (:E CG75
・Using my brother's yarn, I wove a glass fabric with the same fabric and selvedge configurations on a shuttleless loom.

この織物の耳部に実施例と同一の方法で各マつれ防止剤
を塗布しスリッターでカットした。
Each anti-tangling agent was applied to the edges of this fabric in the same manner as in the examples, and the fabric was cut with a slitter.

この織物及び実施例と同一方法で作製したプリプレグの
各々の厚さを測定した。
The thickness of each of this woven fabric and a prepreg produced by the same method as in the example was measured.

以上の実施例と比較例とを対比した測定表は次の通りで
ある。
A measurement table comparing the above examples and comparative examples is as follows.

測    定   表 尚はつれ防止剤の樹脂含量6%、エポキシ樹脂含量39
%である。
Measurement Table: Resin content of anti-tangling agent: 6%, epoxy resin content: 39
%.

【図面の簡単な説明】[Brief explanation of the drawing]

図面は本発明の一実施例を示すもので、第1因は半製品
一部の斜視図、′1PJ2図は耳部の拡大断面図、第3
図は製品一部の斜視図である。 (11・・耳部、(2)・・経糸、(3)・・織地部経
糸、(4)・・織地部、(5)・・ガラス織物、(6)
・・はつれ防止剤。 昭和60年2月16日 出願人  株式会社 有沢製作所 発明者  矢  野  正  治 ylA 、−ツ 7α席 ム17剣
The drawings show one embodiment of the present invention, the first factor is a perspective view of a part of the semi-finished product, the 1st page and 2nd figure are enlarged cross-sectional views of the ears, and the third factor is a perspective view of a part of the semi-finished product.
The figure is a perspective view of a part of the product. (11...Selvage, (2)...Warp, (3)...Weave part warp, (4)...Weave part, (5)...Glass fabric, (6)
...Anti-fade agent. February 16, 1985 Applicant: Arisawa Seisakusho Co., Ltd. Inventor: Masaharu Yano YILA, -tsu 7α Seat M17 Sword

Claims (1)

【特許請求の範囲】[Claims] 無杼織機によりプリント基板用ガラス織物を製織する際
プリント基板用織物の両側の耳部の経糸を織地部経糸よ
りも細い経糸を使用し、且つ織地部よりも経糸密度を高
くして耳部が織地部より薄いガラス織物を製織し、この
薄い耳部にほつれ防止剤を耳部が織地部と略同厚になる
ように塗布せしめたことを特徴とするプリント基板用ガ
ラス織物。
When weaving glass fabric for printed circuit boards using a shuttleless loom, we use thinner warp yarns for the selvedges on both sides of the woven fabric for printed circuit boards than for the woven fabric, and the warp density is higher than that for the woven fabric so that the selvedges are A glass fabric for a printed circuit board, characterized in that a glass fabric thinner than a woven fabric part is woven, and an anti-fray agent is applied to the thin edge part so that the edge part has approximately the same thickness as the woven fabric part.
JP60029038A 1985-02-16 1985-02-16 Glass fabrics for printed circuit board Granted JPS61188992A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP60029038A JPS61188992A (en) 1985-02-16 1985-02-16 Glass fabrics for printed circuit board

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP60029038A JPS61188992A (en) 1985-02-16 1985-02-16 Glass fabrics for printed circuit board

Publications (2)

Publication Number Publication Date
JPS61188992A true JPS61188992A (en) 1986-08-22
JPH0571155B2 JPH0571155B2 (en) 1993-10-06

Family

ID=12265229

Family Applications (1)

Application Number Title Priority Date Filing Date
JP60029038A Granted JPS61188992A (en) 1985-02-16 1985-02-16 Glass fabrics for printed circuit board

Country Status (1)

Country Link
JP (1) JPS61188992A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH05106137A (en) * 1991-10-18 1993-04-27 Nitto Boseki Co Ltd Tack-in-treated fiber woven fabric having low elongation

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS4930656A (en) * 1972-07-20 1974-03-19
JPS5234094A (en) * 1975-09-12 1977-03-15 Asahi Shiyueeberu Kk Prodvction of glass cloth tape

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS4930656A (en) * 1972-07-20 1974-03-19
JPS5234094A (en) * 1975-09-12 1977-03-15 Asahi Shiyueeberu Kk Prodvction of glass cloth tape

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH05106137A (en) * 1991-10-18 1993-04-27 Nitto Boseki Co Ltd Tack-in-treated fiber woven fabric having low elongation

Also Published As

Publication number Publication date
JPH0571155B2 (en) 1993-10-06

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