JPS6078903A - Snake repellent composition and composition for repelling noxious life of tree - Google Patents

Snake repellent composition and composition for repelling noxious life of tree

Info

Publication number
JPS6078903A
JPS6078903A JP18723383A JP18723383A JPS6078903A JP S6078903 A JPS6078903 A JP S6078903A JP 18723383 A JP18723383 A JP 18723383A JP 18723383 A JP18723383 A JP 18723383A JP S6078903 A JPS6078903 A JP S6078903A
Authority
JP
Japan
Prior art keywords
acid
composition
chloro
base
snake
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP18723383A
Other languages
Japanese (ja)
Other versions
JPS624361B2 (en
Inventor
Tokuo Saito
斉藤 徳男
Saburo Tazawa
田澤 三郎
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SAITOU YAKU KAGAKU KENKYUSHO KK
Original Assignee
SAITOU YAKU KAGAKU KENKYUSHO KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SAITOU YAKU KAGAKU KENKYUSHO KK filed Critical SAITOU YAKU KAGAKU KENKYUSHO KK
Priority to JP18723383A priority Critical patent/JPS6078903A/en
Publication of JPS6078903A publication Critical patent/JPS6078903A/en
Publication of JPS624361B2 publication Critical patent/JPS624361B2/ja
Granted legal-status Critical Current

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Abstract

PURPOSE:To provide the titled composition containing a pyridazine derivative, an aryl-sulfonic acid and a coating base or an adhesive base as essential components, and capable of semi-permanently preventing the troubles caused by the snake ascending the pole attracted by the animal or bird dung attached to the electric wire or transformer, etc. CONSTITUTION:The objective composition is produced by compounding a pyridazine derivative, an arylsulfonic acid, and a coating base or an adhesive base, as essential components, and preferably containing an insecticidal component such as dimethyl phthalate. The pyridazine derivative is the one having particular ill odor or stimulative odor and forming an insoluble salt with the arylsulfonic acid, e.g. 3-chloro-6-phenylthiopyridazine, etc. of formula. The arylsulfonic acid is preferably dodecylbenzenesulfonic acid, etc., and the coating base is preferably a solution obtained by dissolving 40% 2-hydroxyethyl methacrylate resin in a mixture of xylene and butanol.

Description

【発明の詳細な説明】 酸、およびネオ1基剤tたQよ粘yfl性基剤・r必須
成分とする蛇忌避組成物ノタよびこれらの成分に加えて
フタール酸ジメチルエステルをも必須成分とJ−る樹木
有害生物忌避,i.l酸物に関する。
DETAILED DESCRIPTION OF THE INVENTION A snake repellent composition comprising an acid, a neo-1 base, a viscous base, and a viscous base, and in addition to these components, phthalic acid dimethyl ester is also an essential component. - tree pest repellent, i. Regarding l-acids.

電線、変圧器、クランプ力バー智(・こイ−t ;7i
 L y.= 、c′v獣類の糞や羽毛などに誘引され
て蛇がfjl住し,配電線の短絡事故を起こすことは一
般にOまそれほど知られていない。しかし、かかる蛇に
よる配電線事故は一般に予想されるよりも遥かに多発し
ており、その修理に要する費用は年間数1,01十〜数
−11,(一円に達している・) 蛇による配電線慣故を防止する/こめ、適当な蛇忌避剤
を電柱に(=J着せしめる方法が既に知られておf) 
( 4!J公昭55−19578号参照)、6る程度の
効果をあげている3.しかしながし、かかる既知の方法
は、蛇忌避剤を塗布した直後は有効であるが、時間の経
過と共に忌避剤の有効成分が流出したり揮散したシして
、比較的捲短時日にその効力を消失してしまう。本発明
者らは、かがる欠点のない、即ち永続性の蛇忌避剤を開
発すべく鋭意研究を重ねた結果、ある種のピリダジン誘
導体、アリー−スーホン酸、および塗料卆剤ま左は載着
性基剤゛を必須成分とする組成物を、半永久的芝蛇忌避
剤として使用し得る事実を見い出し本発明を完成した。
Wires, transformers, clamp force bars
Ly. It is generally not well known that snakes are attracted to the droppings and feathers of animals and can cause short circuits in power distribution lines. However, power distribution line accidents caused by snakes are far more frequent than generally expected, and the cost to repair them is between 1,010 to 11,000 yen per year. To prevent damage to power distribution lines, apply a suitable snake repellent to utility poles (=J method is already known)
(Refer to 4! J Publication No. 55-19578), 3. However, such known methods are effective immediately after applying the snake repellent, but over time, the active ingredients of the repellent leak out or volatilize, and the snake repellent loses its effectiveness in a relatively short period of time. Resulting in. As a result of extensive research to develop a permanent snake repellent without the disadvantage of scorching, the inventors have discovered that certain pyridazine derivatives, ary-sulfonic acids, and paint agents have been developed. The present invention was completed after discovering that a composition containing an adhesive base as an essential ingredient can be used as a semi-permanent lawn snake repellent.

 1 本発明で使用されるピリダジン誘導体は、峙異す悪臭お
よび/またけ刺激臭を有するものでろって、かつアリー
ルスルホン酸と不溶性の塩を桁成するものであればよい
。代表的なピリダジン誘:導体は、以下の式(1)で示
される3−クロロ−6−::フェニルチオピリダジンお
よび式(II)で示される3−クロロ−6−(ジメチル
−クロロ)フェノキシピリダジンである。
1. The pyridazine derivative used in the present invention may have a distinct malodor and/or an irritating odor, and may form a salt insoluble with the arylsulfonic acid. Representative pyridazine derivatives: 3-chloro-6-::phenylthiopyridazine represented by the following formula (1) and 3-chloro-6-(dimethyl-chloro)phenoxypyridazine represented by formula (II) It is.

本発明に係る組成物のもう1つの必須成分であるアリー
ルスルホン酸は、上記のピリダジン誘導体と反応して不
溶11の塩を形成するものであればいかなるものであっ
てもよいが、ドデシルベンゼンスルホニ/酸またはポリ
スチレンスルボン酸が好ましい3、 第3の必須成分である塗料基剤または活着Vト基剤は、
上藁2成分の反応生成物および後述の所望によシ添加さ
れるその他の成分を担持し、これらの成分を電柱または
樹木に直接まlζは間↑と的に塗布、接着せしめるに便
なる様に使用されるもので6J)、従って5あらゆる公
知の4享・1基剤および粘着性基剤が使用可能である。
The arylsulfonic acid, which is another essential component of the composition according to the present invention, may be any aryl sulfonic acid as long as it reacts with the above-mentioned pyridazine derivative to form an insoluble 11 salt. The paint base or adhesion base which is the third essential component is preferably 2/acid or polystyrene sulfonic acid.
It supports the reaction product of the two components of straw and other components added as desired as described later, and it is convenient to apply and adhere these components directly to utility poles or trees. 6J), therefore, all known 4K-1 bases and adhesive bases can be used.

特に好ましい塗料基剤は吸水性アクリル樹脂でアリ、例
えばダイヤナールL且の商品名で市販さJしているメタ
クリル酸2−ヒドロキシエチル樹脂を40qbの割合で
キシレンとブタノール(50:50)の混液に溶解した
ものが実用的価値が高い。特に好ましい粘−性基剤は松
脂、ゴマ油、ヒマシ油、牛脂、ボイ児油およヶice 
ET:あ、。 1 上記の3成分を混合すると、ピリダジン誘導体とアリー
ルスルホン酸が反応して塩を形成する。
A particularly preferred paint base is a water-absorbing acrylic resin, for example, a mixture of xylene and butanol (50:50) in a ratio of 40 qb of 2-hydroxyethyl methacrylate resin, commercially available under the trade name DIANAL L. The solution dissolved in is of high practical value. Particularly preferred viscous bases are pine resin, sesame oil, castor oil, beef tallow, boy's oil and ice cream.
ET: Oh. 1 When the above three components are mixed, the pyridazine derivative and the arylsulfonic acid react to form a salt.

この塩は、蛇が嫌忌するピリダジン誘導体のII)異な
悪臭および/または刺激臭を保持しており□、かつ水に
不溶性であるため、この組成物を適当:な布または合成
樹脂テープに担持させて電柱に巻1き付ければ、電柱へ
の蛇の接近を半永久的((避け:るこ□、。。3、えケ
ア15.ユ、えゆ、よ、4ッ、1ワ。
This salt retains the different malodor and/or pungent odor of pyridazine derivatives, which are repellent to snakes, and is insoluble in water, so the composition is carried on a suitable cloth or synthetic resin tape. If you wrap it around a telephone pole, it will semi-permanently prevent snakes from approaching the pole ((Avoid: Ruko□,... 3, Care 15. Yu, Eyu, Yo, 4, 1 Wa.

目的を十分達成することができるが、本発明に係る組成
物は、その他の類似の忌避作用および1/またはその他
の作用を持った各種成分を含有し1でいてもよい。所望
により添加されるその他の吠□分と14+、J、4+7
−k l 〕I誹−J/ ty襲諒礒J+ r+τ油小
語前方1この様な、所望により添加されるその他の成分
の具体例は、例えばゲルタールアルデヒド、チオフェノ
ール、メルカプタール類、例えばゲルタールアルデヒド
ビス−(ジフェニルメルカプタール)、0−7タールア
ルデヒドビスー(ジフェニルメルカプタール)など、3
,3−ジピリジル、硫黄、フタール酸ジメチルエステル
、ナフタレン、シクロヘキサノール、チオフェノールス
ルホン酸などである・・ 上記の所望により添加されるその他の成分は、水に不溶
または難溶であるが、本発明((係る組成物の必須成分
であるピリダジン誘導体とアリールスルホン酸との塩、
および塗料基剤またをよ粘lγぼ1゜基剤の混合物が著
しい粘稠11をイ」゛する為、これらの成分は保留性が
高められ、半永久的Qてその効力が保持される。
Although the purpose can be fully achieved, the composition according to the present invention may contain various other components having similar repellent and/or other effects. Other ingredients added as desired and 14+, J, 4+7
-k l]I 诹-J/ty 对礒J+r+τoil小子forward 1 Specific examples of such other components that may be added as desired include gel tar aldehyde, thiophenol, mercaptals, such as gel Taraldehyde bis(diphenylmercaptal), 0-7 taraldehyde bis(diphenylmercaptal), etc.
, 3-dipyridyl, sulfur, phthalic acid dimethyl ester, naphthalene, cyclohexanol, thiophenolsulfonic acid, etc. The other components added as desired above are insoluble or sparingly soluble in water, but the present invention ((A salt of a pyridazine derivative and an arylsulfonic acid, which are essential components of such a composition,
Since the mixture of the paint base and the paint base has a remarkable viscosity, the retention of these components is enhanced and their effectiveness is retained with a semi-permanent quality.

上記の所望により添加されるその他の成分の内、防虫効
果を有する物質、例えばフタール酸ジメチルエステルを
含有する本発明組成物O」、蛇忌避剤として有効で多る
ばかシでなく、樹木を有害生物(例えば、病菌、害虫、
ネズミなどの小動物)から保護J−るのにも有効である
。。
Among the other ingredients added as desired, the composition of the present invention contains a substance having an insect repellent effect, such as dimethyl phthalate, which is effective as a snake repellent, but is not harmful to trees. Organisms (e.g., pathogens, pests,
It is also effective for protecting against small animals such as rats. .

従って本発明はまた、ピリダジン誘導体、アリールスル
ホン酸、フクール酸シメチルエステルオよび塗料基剤ま
たは粘着性基剤を必須成分とする樹木有害生物忌避組成
物を提供するものである。
Accordingly, the present invention also provides a tree pest repellent composition containing a pyridazine derivative, an arylsulfonic acid, a dimethyl fucuric acid ester, and a paint base or adhesive base as essential components.

本発明に係る組成物を構成する各種1戊分はいづれも既
知物質であり、市販されているかあるいは既知の方法で
簡単に製造することができる。
All of the various substances constituting the composition according to the present invention are known substances, and are either commercially available or can be easily produced by known methods.

例えば式(りのピリダジン誘導体1は薬学雑誌、二11
59頁(1974年)に記載されており、式(11)の
ピリダジン誘導体はクロロ−ジメチルフェノラートの水
溶液VC9拌下、当量の3.6−ジクロロピリダジンを
加えて加温し、反応を完結する事によシ製造できる。
For example, the pyridazine derivative 1 of the formula (Pharmaceutical Journal, 211
59 (1974), the pyridazine derivative of formula (11) is prepared by adding an equivalent amount of 3,6-dichloropyridazine to an aqueous solution of chloro-dimethylphenolate under stirring at VC9 and heating to complete the reaction. In fact, it can be manufactured.

式(I)または式(U)で示されるピリダジン誘導体と
ドデシルベンゼンスルホン酸またはポリスチレンスルホ
ン酸との塩はそれぞれ融点300°C以上の、水に極め
て難溶な安定な化合物である。
The salts of the pyridazine derivatives represented by the formula (I) or the formula (U) and dodecylbenzenesulfonic acid or polystyrenesulfonic acid are respectively stable compounds having a melting point of 300°C or higher and extremely sparingly soluble in water.

本発明に係る蛇忌避組1戊物νよび樹木有害生物忌避組
成物(咀、第3の必須成分が塗料基剤である場合には直
接電柱または剛木の基部(通常、地上から約50cm〜
100(Jの部分)に塗布あるい(d噴霧するか、1だ
にこれを適当な合;戎樹脂テープ、例えばポリエーテル
あるいはポリエステル樹脂テープに塗布したものを該基
部に巻き伺けて使用ノーるのが好ましい。一方、第3の
必須成分が粘着性基剤である場合は、本発明組[戊物を
塗布、含浸せしめた布を該基部に巻き付けて使用するの
が好ましい。これにより、蛇および樹木有害生物が電柱
や樹木に接近し、既述した如き配線小数を起したり、樹
木に著しい損傷を与えたりするのを防止することができ
る。
The snake repellent set 1 according to the present invention and the tree pest repellent composition (snake), when the third essential component is a paint base, are placed directly on the base of a telephone pole or hardwood (usually about 50 cm to 50 cm above the ground).
100 (part J) or spray it, or simply apply it in an appropriate manner; wrap a resin tape, such as a polyether or polyester resin tape, around the base and use no. On the other hand, when the third essential component is an adhesive base, it is preferable to use the present invention by wrapping a cloth coated with and impregnated with the base. It is possible to prevent snakes and tree pests from approaching utility poles and trees, causing the above-mentioned wiring problems and causing significant damage to trees.

以下に本発明に係る忌避組成物の実施例を挙げる。Examples of the repellent composition according to the present invention are listed below.

実施例1 成分 重量部 3−クロロ−6−フェニルチオ 5 ピリダジン 3−クロロ−6−(ジメチルーク 5 0口)フェノキシピリダジン ドデシルベンゼンスルホン酸12 ダイヤナールL IL 36 8 上記各成分を室温でよく混合し、蛇忌避、姐I戊物全得
る。
Example 1 Ingredients Parts by weight 3-Chloro-6-phenylthio 5 Pyridazine 3-chloro-6-(dimethyl chloride 50) Phenoxypyridazine Dodecylbenzenesulfonic acid 12 Dianal L IL 36 8 The above components were mixed well at room temperature, Snake repellent, get all the benefits.

実施例2 1戊分 重量部 3−クロロ−6−フェニルチオ ピリダジン 3−クロロ〜6−(ジメテル−り 。o)7x)ヤ、、、、、、2.225ポリスチレンス
ルホン酸水溶液(204%)32ダイヤナールIノ■L
30 2 上記各成分を室温でよく混合し、樹木有害生物忌避組成
物を得る。
Example 2 1 part by weight 3-Chloro-6-phenylthiopyridazine 3-chloro-6-(dimeteri.o)7x) 2.225 Polystyrene sulfonic acid aqueous solution (204%) 32 Dial I No L
30 2 The above components are thoroughly mixed at room temperature to obtain a tree pest repellent composition.

実施例3 」成分 重量部 グルクールアルデヒド 2 チオフエノール 1 3−クロロ−6−フェニルチオ ピリダジン 3−クロロ−6−(ジメチルーク 0口)フェノキシピリダジン 3.3−ジピリジル 1 硫黄 18 フタール酸ジメチルエステル 25 ナフタレン 5 シクロヘキザノ−ル 2 ドテシルベンゼンスルホン酸12 ナオフェノールスルポン酸2 ダイヤナールL It 7.0 [48 上記各成分全室i鼎でよく混合する。 ?!)らI′シ
だ組成物は蛇忌避剤としても樹木有害生物忌避剤としで
も有効である。
Example 3 Ingredients Parts by weight Glucuraldehyde 2 Thiophenol 1 3-chloro-6-phenylthiopyridazine 3-chloro-6-(dimethyl chloride 0) phenoxypyridazine 3.3-dipyridyl 1 Sulfur 18 Dimethyl phthalate 25 Naphthalene 5 Cyclohexanol 2 Dotecylbenzenesulfonic acid 12 Naophenol sulfonic acid 2 Dianal L It 7.0 [48] Mix all of the above ingredients well in a bowl. ? ! ) Radica compositions are effective both as snake repellents and as tree pest repellents.

実施例4 成分 市−「It部 ゲルタールアルデヒドビス− 3 (ジフェニルメルカプタール) 0−ノクールアルデヒドビスー (ジフェニルメルカプタール) P−ジクロロベンゼン 10 3−クロロ−6−フエニルチ第 ピリダジン 3.3−ジピリジル 1 硫黄 8 フタール酸ジメチルエステル 15 ナフタレン 5 シクロヘキサノール 2 ドデシルベンゼンスルホン酸12 ダイヤナールLR80 49 上記各成分を室温でよく混合する。得られた組成物は、
蛇忌避剤さしても樹木有害生物忌避剤としても有効であ
る。
Example 4 Ingredients - It gel tar aldehyde bis-3 (diphenyl mercaptal) 0-nocuraldehyde bis (diphenyl mercaptal) P-dichlorobenzene 10 3-chloro-6-phenylthi-pyridazine 3.3 -Dipyridyl 1 Sulfur 8 Dimethyl phthalate 15 Naphthalene 5 Cyclohexanol 2 Dodecylbenzenesulfonic acid 12 Dianaru LR80 49 The above components are mixed well at room temperature.The resulting composition is as follows:
It is effective both as a snake repellent and as a tree pest repellent.

実施例5 成分 重厭部 ゲルタールアルデヒドビス− (ジフェニルメルカプタール) P−ジクロロベンゼン 10 3−クロロ−6−フエニルチ第 ピリダジン 3−クロロ−6−(ジメチルーク 0口)フェノキシピリダジン 3.3−ジピリジル 1 硫黄 8 フタール酸ジメチルエステル 15 ナフタレン 5 シクロヘキサノール 2 ポリスチレンスルホン酸水溶液(20,4%)16ドデ
シルベンゼンスルホン酸6 ダイヤナールL R70 46 上記各1戎分を室温でよく混合し、蛇忌避剤Jill我
物を得る。
Example 5 Ingredients Geltar aldehyde bis- (diphenyl mercaptal) P-dichlorobenzene 10 3-chloro-6-phenylthipyridazine 3-chloro-6-(dimethyl chloride 0) phenoxypyridazine 3,3-dipyridyl 1 Sulfur 8 Phthalic acid dimethyl ester 15 Naphthalene 5 Cyclohexanol 2 Polystyrene sulfonic acid aqueous solution (20.4%) 16 Dodecylbenzenesulfonic acid 6 Dianal L R70 46 Mix 1 scoop of each of the above at room temperature and use the snake repellent Jill. Get what's yours.

実施例6 グルタールアルデヒドビス− (ジフェニルメルカプタール) O−フタールアルデヒドビスー (ジフェニルメルカプタール) P−ジクロロベンゼン 10 3−クロロ−6−フエニルチ第 ピリダジン 3−クロロ−6−(ジメチルーク 0口)フェノキシピリダジン 3.3′−ジピリジル 1 硫黄 8 フタール酸ジメチルエステル 15 ナフタレン 5 シクロヘキサノール 2 ドデンルベンゼンスルホン酸 12 9 上記成分を室温で混合してA剤とする。Example 6 Glutaraldehyde bis- (diphenylmercaptal) O-phthalaldehyde bissu (diphenylmercaptal) P-dichlorobenzene 10 3-chloro-6-phenylthi pyridazine 3-chloro-6-(dimethylchloride) 0 mouth) Phenoxypyridazine 3.3'-dipyridyl 1 Sulfur 8 Phthalic acid dimethyl ester 15 Naphthalene 5 Cyclohexanol 2 Dodenlebenzenesulfonic acid 12 9 The above components are mixed at room temperature to form Part A.

ヒマシ油 1,500 牛 脂 770 鉛 丹 615 2.885 上記成分を、250’0〜270°Cで混合して粘着性
基剤を製しB剤とする。
Castor oil 1,500 Beef tallow 770 Red lead 615 2.885 The above ingredients are mixed at 250'0 to 270°C to prepare a sticky base and use it as agent B.

A剤40部、B剤60部を50°C以下で練合して忌避
組成物を得る。
A repellent composition is obtained by kneading 40 parts of agent A and 60 parts of agent B at 50°C or less.

実施例7 グルタールアルデヒドビス− (ジフェニルメルカプタール) P−ジクロロベンゼン 10 3−クロロ−6−フエニルチ第 ピリダジン 3−クロロ−6−(ジメチルーク 0口)フェノキシピリダジン 3.3−ジピリジル 1 硫黄 8 フタール酸ジメチルエステル 15 ナフタレン 5 シクロヘキサノール 2 ボリスチレシスルホン酸水溶液(20,4%)16トテ
シルベンゼンスルホン酸6 6 上記1戊分を室温で混合してA剤とする。
Example 7 Glutaraldehyde bis- (diphenylmercaptal) P-dichlorobenzene 10 3-chloro-6-phenylthiarypyridazine 3-chloro-6-(dimethylchloride)phenoxypyridazine 3.3-dipyridyl 1 Sulfur 8 Phthal Acid dimethyl ester 15 Naphthalene 5 Cyclohexanol 2 Aqueous solution of boristyrethysulfonic acid (20.4%) 16 Totecylbenzenesulfonic acid 6 6 The above 1 portions were mixed at room temperature to prepare Part A.

A剤40部を実施例6のB剤60部と50°C以下で煉
きして忌避組成物を得る。。
A repellent composition is obtained by blending 40 parts of Agent A with 60 parts of Agent B of Example 6 at 50°C or below. .

試験■ 頂上に生きた蛙を固定した高さ2m、直圧006mの鉄
柱2本を蛇を投入した密閉室内に置き、その一方にのみ
厚さ1.5mmの布地に実施例6で製造した忌避剤を塗
布した布(巾30C7n)を巻きつける。加工布地を巻
きつけてない方の蛙は、−夜にして消失したが、他方1
ri蛙の生存中そのまま放置したにもかかわらず変化を
受けなかった。
Test ■ Two steel poles with a height of 2 m and a direct pressure of 0.06 m with a live frog fixed to the top were placed in a sealed chamber into which a snake was placed, and only one of them was covered with a repellent fabric made in Example 6 made of cloth with a thickness of 1.5 mm. Wrap a cloth (width 30C7n) coated with the agent. The frog that was not wrapped in treated fabric disappeared overnight, but the other one
Despite being left alone during the life of the ri frog, no changes were observed.

試験II 頂上に、糖蜜および砂糖の混合物10gを置いた高さ1
.5m、直径0.06 fiの鉄柱2本を約5m以上の
間隔を置いて蟻の生息する地上に立て、一方に実施例;
5で製造した忌避剤を塗布(11] 20 C1n、厚
さ70 tt )する。塗布しない鉄柱上には約2 (
147間で頂上に蟻が集まり始め、1週間以内に砂糖分
に全部消失したが、塗布した方の砂糖は3ケ月を経ても
全く変化はなく鉄柱を登る蟻も認められなかった。
Test II Height 1 with 10 g of molasses and sugar mixture placed on top
.. Two steel poles with a diameter of 5 m and a diameter of 0.06 fi were erected on the ground where ants live, with an interval of about 5 m or more, and one of them was placed in the example;
The repellent prepared in step 5 is applied (11] 20 C1n, thickness 70 tt). Approximately 2 (
After 147 days, ants began to gather on the top, and within a week they had all disappeared into the sugar, but the sugar on the side where it was applied had not changed at all even after 3 months, and no ants were observed climbing the iron pillar.

試験■ 寒地性の白樺、ベニイタヤ、ナナカマド等或は梅、ミカ
ン、桃、梨、サツキ等の果樹本の基部に害虫が巣喰う事
がしばしばあるが、実施例3で製造した忌避剤を基部に
直接塗布(中10〜2Qc+++)したところ、数日後
に樹液の分泌、木屑が観察されなくなった。これは、こ
れらの樹木が害虫の侵害力・ら保護されたこ吉を示すも
のである。
Test ■ Insects often nest at the base of cold-region birches, safflower trees, rowan trees, etc., or fruit trees such as plums, mandarin oranges, peaches, pears, and azaleas. When directly applied (10 to 2Qc+++) to the tree, sap secretion and wood chips were no longer observed after a few days. This shows that these trees are protected from the encroaching power of pests.

Claims (1)

【特許請求の範囲】 1、ピリダジン誘導体、アリールスルホン酸、および塗
H基剤または粘沼性ノ、1剤1(必須成分とする蛇忌避
、姐我物。 2ピリダジン誘導体が3−クロロ−6−フェニルチオピ
リダジンおよび/または3−クロロ−6−(ジメチル−
クロロ)フェノキシピリダジンであり、アリールスルホ
ン酸がドブフルベンゼンスルホン酸またはポリスチレン
スルホン酸であルff51項に記載の組成物、。 3ピリダジン誘導体、アリールスルホン酸、フタール酸
ジメチルエステル、および塗料基剤または活着性基剤を
必須成分とする樹木有害生物忌避用代物。 4ピリダジン誘導f4jが3−クロロ−6−フェニルチ
オピリダジンおよび/また&−13−クロロ−6−/ 
、J J a−ルー//rコr−1)7丁ノル・ソl−
’lIカゝ、・ン・7で6Lアリールスルポン酸がドブ
フルベンゼンスルホン酸ま1にはポリステレジスルポン
酸で心る第3項に記載の組成物。
[Scope of Claims] 1. A pyridazine derivative, an arylsulfonic acid, and a coating base or a viscous substance. -phenylthiopyridazine and/or 3-chloro-6-(dimethyl-
The composition according to item ff51, wherein the aryl sulfonic acid is dobuflubenzenesulfonic acid or polystyrene sulfonic acid. A substitute for repelling tree pests, which contains a 3-pyridazine derivative, arylsulfonic acid, dimethyl phthalate, and a paint base or adhesive base as essential ingredients. 4-pyridazine-derived f4j is 3-chloro-6-phenylthiopyridazine and/or &-13-chloro-6-/
, J J a-ru//r-ko r-1)
3. The composition according to item 3, wherein 6L aryl sulfonic acid is used as dobuflubenzenesulfonic acid or polysteredysulfonic acid as 1.
JP18723383A 1983-10-05 1983-10-05 Snake repellent composition and composition for repelling noxious life of tree Granted JPS6078903A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP18723383A JPS6078903A (en) 1983-10-05 1983-10-05 Snake repellent composition and composition for repelling noxious life of tree

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP18723383A JPS6078903A (en) 1983-10-05 1983-10-05 Snake repellent composition and composition for repelling noxious life of tree

Publications (2)

Publication Number Publication Date
JPS6078903A true JPS6078903A (en) 1985-05-04
JPS624361B2 JPS624361B2 (en) 1987-01-30

Family

ID=16202382

Family Applications (1)

Application Number Title Priority Date Filing Date
JP18723383A Granted JPS6078903A (en) 1983-10-05 1983-10-05 Snake repellent composition and composition for repelling noxious life of tree

Country Status (1)

Country Link
JP (1) JPS6078903A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS63101303A (en) * 1986-10-16 1988-05-06 Tokuo Saito Composition for protecting fruit tree
JPS63101304A (en) * 1986-10-16 1988-05-06 Tokuo Saito Termite-preventive composition
EP0624455A2 (en) * 1993-05-14 1994-11-17 Albin Alexander Wladyslaw Baecker Flexible synthetic plastic sheeting
US5733613A (en) * 1993-05-14 1998-03-31 Baecker; Albin Alexander Wladyslaw Synthetic plastic sleeve having a dry film biocide incorporated therein and method for treating a timber pole to inhibit sub-soil bio-deterioration of the pole

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS63101303A (en) * 1986-10-16 1988-05-06 Tokuo Saito Composition for protecting fruit tree
JPS63101304A (en) * 1986-10-16 1988-05-06 Tokuo Saito Termite-preventive composition
EP0624455A2 (en) * 1993-05-14 1994-11-17 Albin Alexander Wladyslaw Baecker Flexible synthetic plastic sheeting
EP0624455A3 (en) * 1993-05-14 1994-12-28 Albin Alexander Wladys Baecker Flexible synthetic plastic sheeting.
US5733613A (en) * 1993-05-14 1998-03-31 Baecker; Albin Alexander Wladyslaw Synthetic plastic sleeve having a dry film biocide incorporated therein and method for treating a timber pole to inhibit sub-soil bio-deterioration of the pole

Also Published As

Publication number Publication date
JPS624361B2 (en) 1987-01-30

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