JPS6075256A - Production of oil-soluble dyestuff - Google Patents

Production of oil-soluble dyestuff

Info

Publication number
JPS6075256A
JPS6075256A JP58099062A JP9906283A JPS6075256A JP S6075256 A JPS6075256 A JP S6075256A JP 58099062 A JP58099062 A JP 58099062A JP 9906283 A JP9906283 A JP 9906283A JP S6075256 A JPS6075256 A JP S6075256A
Authority
JP
Japan
Prior art keywords
oil
dyestuff
soluble
water
pigment
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP58099062A
Other languages
Japanese (ja)
Inventor
Masami Shibata
柴田 正美
Akira Yasuda
侃 安田
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
San Ei Kagaku Co Ltd
Sanei Kagaku Kogyo KK
Original Assignee
San Ei Kagaku Co Ltd
Sanei Kagaku Kogyo KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by San Ei Kagaku Co Ltd, Sanei Kagaku Kogyo KK filed Critical San Ei Kagaku Co Ltd
Priority to JP58099062A priority Critical patent/JPS6075256A/en
Publication of JPS6075256A publication Critical patent/JPS6075256A/en
Pending legal-status Critical Current

Links

Landscapes

  • Coloring Foods And Improving Nutritive Qualities (AREA)

Abstract

PURPOSE:To obtain a homogeneous oil-soluble dyestuff having a uniform quality, by adding a surfactant having high hydrophilicity, a solvent and if necessary a stabilizer to a starting material water-soluble dyestuff. CONSTITUTION:A dyestuff such as red anthocyanin dyestuff, e.g. purple corn dyestuff, yellow carotenoid dyestuff, yellow Gardenia jasminoides Ellis dyestuff, etc. is prepared. The water-soluble dyestuff is mixed with water or another solvent, e.g. propylene glycol, to prepare a mixed system thereof. A stabilizer, e.g. xanthan gum, is if necessary added to the mixed system to homogenize the system, and a fat or oil, e.g. soybean oil, is then added to homogenize the system. Thus, the aimed oil-soluble dyestuff consisting of a stable water-in-oil type emulsion system is obtained from the water-soluble dyestuff.

Description

【発明の詳細な説明】 この究明は、食品に使用する色素に係るものであって、
水溶性色素を原料とし品質に優れた油溶性色素全工業的
に有利に製造することを目的とする。
[Detailed Description of the Invention] This investigation relates to pigments used in foods,
The purpose is to produce oil-soluble pigments of excellent quality industrially advantageously using water-soluble pigments as raw materials.

公り.llの食品用油溶性色素は、天然系では黄橙〜橙
色系のものとして、カロチノイド系色素が、緑色系のも
のとしてクロロフィル系色素があるだけであって、赤色
、黄色、青色のものは知られていない。
Public. The natural oil-soluble food pigments are yellow-orange to orange, carotenoid pigments are green, and chlorophyll pigments are green, and red, yellow, and blue pigments are well known. It has not been done.

また、公知の油溶性色素中、カロチノイド系のdlのH
−tリ−A.):仝で力;光f不安宇でありークロロフ
ィル系のものは、光にはもちろんのこと、酸にも熱にも
不安定である。合成系のものでは現在食品に使用が認め
られた油溶性色素は存在しない。
In addition, among known oil-soluble pigments, carotenoid dl H
-t Lee A. ): It is unstable to light; chlorophyll-based substances are unstable not only to light but also to acids and heat. There are currently no synthetic oil-soluble pigments approved for use in foods.

アルミニウム系のものがあるが、レーキ質のものであシ
、着色物が不透明になシ、かつ、経時的に色の分離が起
こる等の欠点かある。
Aluminum-based materials are available, but they have drawbacks such as being lake-like, making the colored material opaque, and causing color separation over time.

この発明は、このような課題ケ同時並行的に解決しよう
とするものである。その詳A:lH ’fc以下に説明
する。
This invention attempts to solve these problems concurrently. The details A:lH'fc will be explained below.

この究明のlWj成要件は、出発原料の水溶性色素、親
油性の高い界面活性剤、溶剤、油脂、要すれば安定剤で
ある。
The requirements for IWj in this investigation are a water-soluble dye as a starting material, a highly lipophilic surfactant, a solvent, an oil, and, if necessary, a stabilizer.

水溶性色素としては、赤色糸のものとして、アントシア
ニン糸(例えは、紫’1.ウモロコシ色素、ブドウ果皮
色素、ブドウ果汁色票、ベリー類色素、赤キヤベツ色素
、その他のもの)、アン{・ラキノン系(コチニール色
素、ランク色素、その他のもの)、黄色系のものとして
、カロチノイド系(例えは、クチナシ黄色素、その他の
もの)青色糸のものとして、クチナシ青色素その他があ
る。
Water-soluble pigments include red threads, anthocyanin threads (for example, purple'1, corn pigment, grape skin pigment, grape juice color chart, berry pigment, red cabbage pigment, and others), Laquinone type (cochineal pigment, rank pigment, etc.), carotenoid type (e.g. gardenia yellow pigment, etc.) as yellow type, and gardenia blue pigment and others as blue type.

親油性の高い界面活性剤としては、クリセリン、ソルビ
タン等の脂肪酸エステルが挙けられる。このものの脂I
J/j酸は、炭素数が18ないし8個のもノ、mltは
、ステアリン酸、ミリスチン酸、オレイン酸、バルミチ
ン酸、リシノー/I/酸、リノール酸等が好〕凶である
Examples of highly lipophilic surfactants include fatty acid esters such as chrycerin and sorbitan. This fat I
The J/j acid is preferably one having 18 to 8 carbon atoms, and the mlt is preferably stearic acid, myristic acid, oleic acid, valmitic acid, ricino/I/acid, linoleic acid, etc.

安定剤としては、天然系糊料として一般に知られでいる
もの、例えに、ギザンタンヵム、アラビア力11、カラ
へ1ガム、カラギーナン、グアーガム、ファーセレラン
、マツA′二、その他の1棟以上が?トリしれる。
As stabilizers, there are generally known natural thickeners, such as Gizantancum, Arabian Power 11, Karahe 1 Gum, Carrageenan, Guar Gum, Furseleran, Pine A'2, and one or more others. I can do it.

油1j11としては、例えは、大豆油、ゴマ油、米ヌカ
油、その他の141+以」二が挙けられる。
Examples of the oil 1j11 include soybean oil, sesame oil, rice bran oil, and other oils 141+ and above.

溶/11]としては、水、プロピレングリコール、グリ
セリン、エタノール、その他のものが挙けられる。この
ものも2伸以」二のイノ1用かif fluである。
Solvents/11] include water, propylene glycol, glycerin, ethanol, and others. This one is also for 2nd and 2nd inno 1 or if flu.

次に、製造工程全説明する。+f、ず、水溶性色素と水
、その他の溶剤との混合系を用意する。混合割合は任、
0、であるか、前者1重Iiに対し、後者等Jjiない
し10重量倍とし、これを均質になるように撹拌する。
Next, the entire manufacturing process will be explained. +f. Prepare a mixed system of water-soluble dye, water, and other solvents. The mixing ratio is up to you.
0, or 1 weight of the former Ii to 10 times the weight of the latter, etc., and stirred to make it homogeneous.

この混合系に要すれば安定剤を添加し均質にする。安定
剤が必要であるかいなかは、水溶性色素の性質あるいは
溶剤との混合割合の如何によって相異し、一義的には決
められない。水溶性色素と溶剤との比重差が大きいもの
については、安定剤を必要とし多くの場合、相手色素に
苅する等車量以下の量での使用でたやる。
If necessary, stabilizers are added to this mixed system to make it homogeneous. Whether a stabilizer is necessary or not depends on the nature of the water-soluble dye or the mixing ratio with the solvent, and cannot be determined uniquely. For those with a large difference in specific gravity between the water-soluble dye and the solvent, a stabilizer is required, and in most cases, the amount used is less than that of the other dye.

この系に、親油性の界面活性剤を添加し、均質にする。A lipophilic surfactant is added to this system to homogenize it.

使用量は、(・1手色素の重量に文1し重量ないし10
倍量でよい。
The amount to be used is (・1 to 10 to 100 grams per weight of pigment)
Double the amount.

欠に、この糸に対し、油脂を添加し均質にする。In some cases, oil is added to the thread to make it homogeneous.

その添加量は、ID0手色素対し1/10爪以上であっ
て、かつ溶剤使用量に苅しl/10量以」重量とすれは
よい。
The amount added should be 1/10 or more of the ID0 hand dye and at least 1/10 of the weight of the solvent used.

以上のようにすると、色素は安定にνV10型の乳化系
を形成する。。
In the above manner, the dye stably forms a vV10 type emulsion system. .

生成したものが目的の食品用油溶性色素であり、ここに
この発明はその目的を達しおえる。
The product produced is the desired food-use oil-soluble dye, and the present invention has achieved that object.

念のだめに記すと、赤系、黄色系、へ色系の各色素を適
宜混合しこの究明の工程を加えることによって紫色、緑
色その他の任意の色41」のものを収得することができ
る。
As a reminder, purple, green, or any other color 41'' can be obtained by appropriately mixing red, yellow, and dark brown pigments and adding this process of investigation.

との究明の油溶性色素は発色かよく、色相がちさやかで
退色かほとんどない。また、使用方法がl111易であ
る。
The oil-soluble pigments that were discovered have good color development, a distinct hue, and almost no fading. Also, it is very easy to use.

次に、この究明を実施例によシ史に詳しく説明する。Next, this investigation will be explained in detail using examples.

実 施 例 I 制麹邑素の油溶性色素は、紅麹色素抽出液35?、il
(、プロピレングリコール5部、クリセリン脂肪1惰エ
ステル60部、食用油脂30部を混合することにより拐
ら〕tた。
Example I Is the oil-soluble pigment of Kojibu Soto the red malt pigment extract 35? ,il
(It was prepared by mixing 5 parts of propylene glycol, 60 parts of chrycerin fat 1 inert ester, and 30 parts of edible fat and oil).

水晶はサラダ油にtex]、g=に溶は透明な赤色に着
色できた。
The crystals were dissolved in salad oil and colored transparent red.

実 カル 例 2 天然の緑色油、容性色素は、紅花黄色素抽出液80部、
クチナシ青巴素抽出故20部、グリセリン脂肪酸エステ
ル150部、食用lu+脂30部の混ばにより得られた
。このものをカマボコのすシ身に1〜3%添加して、常
法によりカマボコを着色したところ、カマボコの白い部
分への色素の移行が認められなかった。
Example 2 Natural green oil, soluble pigment is 80 parts of safflower yellow pigment extract,
It was obtained by mixing 20 parts of gardenia blueberry extract, 150 parts of glycerin fatty acid ester, and 30 parts of edible lu+fat. When 1 to 3% of this product was added to the fish paste meat and the fish paste was colored by a conventional method, no transfer of the pigment to the white parts of the fish cake was observed.

しかしなから紅花黄色素とクチナシ青色素の(11−用
だけでは着色した場合、カマボコの白い部分にかなりの
色の移行が認められた。
However, when colored with only safflower yellow pigment and gardenia blue pigment (11-), a considerable color shift was observed in the white part of the kamaboko.

実 施 例 3 赤キヤベツ色素の油溶性色素は、亦キャベツ色素抽出液
100部、グリセリン脂肪酸エステル180部、食用油
脂30部を混合することにより得られた。得られた油溶
性色素30部を70部の30%アラビアガム水溶液と混
合乳化させることにより、赤キヤベツ色素の油溶性色素
の水分散物か得られた。このもの食用いて2層セリ−1
粒セリ−を着色したところ、色素の水性部分への移イー
1が認められなかった。
Example 3 An oil-soluble red cabbage pigment was obtained by mixing 100 parts of cabbage pigment extract, 180 parts of glycerin fatty acid ester, and 30 parts of edible fat. By mixing and emulsifying 30 parts of the obtained oil-soluble pigment with 70 parts of a 30% aqueous gum arabic solution, an aqueous dispersion of an oil-soluble pigment of red cabbage pigment was obtained. Edible 2-layer serie-1
When the celery grains were colored, no transfer of the pigment to the aqueous portion was observed.

実 施 例 4 食用赤色102号のlO%水溶故100部に対し、グリ
セリン脂肪酸エステ/L/ 200部食用油脂20部を
混合した。
Example 4 To 100 parts of 10% water-soluble food red No. 102, 200 parts of glycerin fatty acid ester/L/20 parts of edible oil and fat were mixed.

水晶はサラダ油、ショートニングに+lIJ単に溶けて
赤色の色調にia色することができた。
The crystals were simply dissolved in salad oil and shortening to give them a reddish tint.

特許出願人 三栄化年二上条株式会佳patent applicant Sanei Chemical Year Nikamijo Co., Ltd.

Claims (1)

【特許請求の範囲】[Claims] 水溶性色素と溶剤と要すれば安定剤との混合系に、界面
活性剤を添加して均質系にし、これに油脂を添加するこ
とを特徴とする食品用油溶性色素の製法。
A method for producing an oil-soluble colorant for food, which comprises adding a surfactant to a mixed system of a water-soluble colorant, a solvent, and, if necessary, a stabilizer to form a homogeneous system, and adding fat or oil to the mixture.
JP58099062A 1983-06-02 1983-06-02 Production of oil-soluble dyestuff Pending JPS6075256A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP58099062A JPS6075256A (en) 1983-06-02 1983-06-02 Production of oil-soluble dyestuff

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP58099062A JPS6075256A (en) 1983-06-02 1983-06-02 Production of oil-soluble dyestuff

Publications (1)

Publication Number Publication Date
JPS6075256A true JPS6075256A (en) 1985-04-27

Family

ID=14237253

Family Applications (1)

Application Number Title Priority Date Filing Date
JP58099062A Pending JPS6075256A (en) 1983-06-02 1983-06-02 Production of oil-soluble dyestuff

Country Status (1)

Country Link
JP (1) JPS6075256A (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009207403A (en) * 2008-03-04 2009-09-17 Riken Vitamin Co Ltd Monuscus color-solubilized preparation
JP2009263650A (en) * 2008-03-31 2009-11-12 Riken Vitamin Co Ltd Monascus pigment preparation and its production method
JP2013165697A (en) * 2012-02-17 2013-08-29 S & B Foods Inc Caramel-containing heat-sterilized food and method for production of the same
JP2015180719A (en) * 2014-03-04 2015-10-15 三栄源エフ・エフ・アイ株式会社 Non-emulsifiable color formulation comprising monascus color and/or monascus yellow color
WO2016182023A1 (en) * 2015-05-12 2016-11-17 三栄源エフ・エフ・アイ株式会社 Anthocyanin dye preparation
WO2017057187A1 (en) * 2015-09-29 2017-04-06 理研ビタミン株式会社 Gardenia pigment preparation

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009207403A (en) * 2008-03-04 2009-09-17 Riken Vitamin Co Ltd Monuscus color-solubilized preparation
JP2009263650A (en) * 2008-03-31 2009-11-12 Riken Vitamin Co Ltd Monascus pigment preparation and its production method
JP2013165697A (en) * 2012-02-17 2013-08-29 S & B Foods Inc Caramel-containing heat-sterilized food and method for production of the same
JP2015180719A (en) * 2014-03-04 2015-10-15 三栄源エフ・エフ・アイ株式会社 Non-emulsifiable color formulation comprising monascus color and/or monascus yellow color
WO2016182023A1 (en) * 2015-05-12 2016-11-17 三栄源エフ・エフ・アイ株式会社 Anthocyanin dye preparation
JPWO2016182023A1 (en) * 2015-05-12 2018-03-01 三栄源エフ・エフ・アイ株式会社 Anthocyanin pigment preparation
US10827769B2 (en) 2015-05-12 2020-11-10 San-Ei Gen F.F.I., Inc. Anthocyanin dye preparation
WO2017057187A1 (en) * 2015-09-29 2017-04-06 理研ビタミン株式会社 Gardenia pigment preparation
JPWO2017057187A1 (en) * 2015-09-29 2018-07-19 理研ビタミン株式会社 Gardenia pigment preparation
US11174390B2 (en) 2015-09-29 2021-11-16 Riken Vitamin Co., Ltd. Gardenia pigment preparation

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