JPS6064693A - Fluidized bed biological oxidation treatment - Google Patents

Fluidized bed biological oxidation treatment

Info

Publication number
JPS6064693A
JPS6064693A JP58172114A JP17211483A JPS6064693A JP S6064693 A JPS6064693 A JP S6064693A JP 58172114 A JP58172114 A JP 58172114A JP 17211483 A JP17211483 A JP 17211483A JP S6064693 A JPS6064693 A JP S6064693A
Authority
JP
Japan
Prior art keywords
fluidized bed
substance
molecular
aforementioned
sludge
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP58172114A
Other languages
Japanese (ja)
Other versions
JPS6234434B2 (en
Inventor
Kozo Konishi
小西 功三
谷口 敬次
水野 金夫
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Denka Consultant and Engineering Co Ltd
Original Assignee
Denka Consultant and Engineering Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Denka Consultant and Engineering Co Ltd filed Critical Denka Consultant and Engineering Co Ltd
Priority to JP58172114A priority Critical patent/JPS6064693A/en
Publication of JPS6064693A publication Critical patent/JPS6064693A/en
Publication of JPS6234434B2 publication Critical patent/JPS6234434B2/ja
Granted legal-status Critical Current

Links

Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/10Biological treatment of water, waste water, or sewage

Landscapes

  • Biological Treatment Of Waste Water (AREA)

Abstract

PURPOSE:To simplify a tank structure, by directly supplying oxygen to a fluidized bed packed with a hydrophilic high-molecular granular substance from the lower part thereof to perform aeration, and discharging released sludge from the surface of the granular substance along with treated water through a reticulated body provided to the fluidized bed. CONSTITUTION:The fluidized bed of a fluidized bed contact oxidation tank is packed with a hydrophilic high-molecular granular substance changed to hydrated high-molecular coarse particulate substnace. Org. substance-containing sewage to be treated is supplied onto the aforementioned fluidized bed while oxygen required in biological oxidation is directly aerated from the lower part of the fluidized bed and released sludge from the surface of the aforementioned coarse particulate substance is discharged along with treated water through the reticulated body provided to the aforementioned fluidized bed. As the aforementioned hydrophilic high-molecular substance, perfectly saponified PVA such as a grafted substance is optimum and the particle size of the PVA granule is pref. adjusted to 8-20mm. in order to prevent the outflow thereof from the reticulated body for discharging released sludge.

Description

【発明の詳細な説明】 この発明は、有機汚泥物質を溶存する汚水(以下中に汚
水という)の生物酸化による処理方法に関するものであ
る。
DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a method for treating wastewater containing dissolved organic sludge substances (hereinafter referred to as wastewater) by biological oxidation.

IQ水の浄化法として現在実施されている方法は、固定
床に微生物を生息させる接触酸化法であって、鼓近にお
いて疎水性高分子発泡体小粒物を微生物の417j 4
ft体とする流動床接触酸化法が研究されるに全っだ。
The method currently being used to purify IQ water is a contact oxidation method in which microorganisms live in a fixed bed.
Fluidized bed catalytic oxidation methods for producing ft bodies are currently being researched.

[7かしながらこの方法は、J(J。[7 However, this method is similar to J(J.

体粒子に過剰に付r1する活性汚泥の処理方法が複雑で
専用の装置を別設する必蟹があり、醇化効イlもよくな
い欠点がある。本発明は、流動床接触酸化法に関するも
のであって、微生物膜の伺着1(1体として水中で不溶
性抱水高分子相粒物となる親木性高分子顆粒物を使用す
ることを特徴とするものであり、1[1体としての抱水
高分子相粒物に微生物)模即ち活性汚泥が強固に付着す
ること、この為汝動床下部に直接曝気が可能になり槽構
造が筒中になること、活性汚泥刺着1目体を容易に流動
化できること、余剰活性汚泥は常時適度に剥離し、これ
を沈降除去したり処理水と共に流動床外に溢流させるこ
とができ余剰活性汚泥除去機構か不要である等の利点が
ある。
The process for treating activated sludge, which is excessively attached to body particles, is complicated and requires a separate dedicated device, and the sludge has poor liquefaction efficiency. The present invention relates to a fluidized bed catalytic oxidation method, and is characterized in that microbial membrane adhesion (1) uses woody polymer granules that become insoluble hydrated polymer phase particles in water. 1. In other words, activated sludge firmly adheres to the hydrated polymer phase particles as a single body, and this allows direct aeration to the lower part of the moving bed, and the tank structure is in the cylinder. The activated sludge sticks can be easily fluidized, and the excess activated sludge can be properly peeled off at all times, and it can be sedimented and removed or flowed out of the fluidized bed together with the treated water, making it possible to remove excess activated sludge. It has the advantage that no mechanism is required.

本発明において、親水性高分子物質としては該物質の抱
水h1が11(体としての機能に余り影響1〜ないこと
、Jlj1体に伺71する微生物ijiにならず、(2
がも微生物耐化に対して難分解性であり、長詩間冷水に
浸♀lc浮遊しても冷水不溶性であること、などの点か
らグラフ)・化物等より完全鹸化PVAが最】とである
In the present invention, as a hydrophilic polymer substance, the hydration h1 of the substance is 11 (1 to 1), which does not have much effect on the body's functions, does not become a microorganism 71 that affects the body, and (2
PVA is resistant to microbial resistance, and is insoluble in cold water even when immersed in cold water. be.

また1、1に物質の顆程物の粒子径は機能−トの条件は
ないが剥14!5泥を容易に排出しうる網目体から流出
しないようにするために長辺2mm程度の不Y形剥離汚
泥が通過するに要する口中5mm乃至7mmの、網口体
より大きい粒度、即ち8mm乃至20mm程度かよい。
In addition, although there are no functional requirements for the particle size of the granules of the substance in 1.1, in order to prevent mud from flowing out from the mesh body that can be easily discharged, the long sides should be approximately 2 mm. The particle size may be 5 mm to 7 mm in the mouth, which is required for the exfoliated sludge to pass through, and is larger than the mesh mouth body, that is, about 8 mm to 20 mm.

史番二、接IIl!l!醇化槽に充填して出来るだけ広
い表面相でJu体の易flf、動性を確保する点から8
 m m 、P)至10mm程度が最も適当で′ある。
History number two, contact IIl! l! From the point of view of filling the solubilization tank and ensuring the ease of flf and mobility of the Ju body with as wide a surface phase as possible.
m m , P) to about 10 mm is most appropriate.

この親水性顆粒物は、親水性高分子粉末をヘンシルミキ
サー内で適当な重敲比の水を添加しつつ加温攪拌するこ
とによって短時間で製造できる。
This hydrophilic granule can be produced in a short time by heating and stirring the hydrophilic polymer powder in a Henshil mixer while adding water at an appropriate ratio.

史にがC動床接触醇化槽への充填率は、槽内の有機IO
濁物質す化に開学する活性汚泥の保持率と、微生物膜を
刺着した111体の適度な流動化と、78体より’JI
I#した余剰汚泥の流動法外溢流の点から20〜55%
(容積)が適当である。
The filling rate of the C moving bed contact solubilization tank is the organic IO in the tank.
The retention rate of activated sludge, which was developed to reduce turbidity, the moderate fluidization of 111 bodies with microbial membranes, and the 'JI' from 78 bodies.
20-55% from the point of excess sludge overflow
(volume) is appropriate.

実 施 例 完全鹸化PVA (重合度170.0.鹸化度99.5
モル%)100部をヘンシルミキサーに投入し、温度6
0°CC1800rpの攪拌ドで木10部を約10分間
スプレーしくイ約10mmの70粒PVAを製造した。
Example Completely saponified PVA (polymerization degree 170.0. saponification degree 99.5
100 parts (mol%) was put into a Henshil mixer, and the temperature was 6.
70 grains of PVA each having a diameter of about 10 mm were produced by spraying 10 parts of wood for about 10 minutes using an agitation machine at 0°C and 1800 rpm.

容積1文の流動床室の上面及び下面に[1巾5mmの合
成繊維製ネットを設け、前記!1lrj粒物を容積比5
0%で充填した。この円筒状流動床試験機の上部液層及
び下部液層は夫ン0.51とし、1一部液層水面から流
動床室を貫通する下降管を設けて自流式とした。
A synthetic fiber net with a width of 5 mm is provided on the upper and lower surfaces of a fluidized bed chamber with a volume of 1 sentence, and the above! 1lrj grains volume ratio 5
Filled with 0%. The upper liquid layer and the lower liquid layer of this cylindrical fluidized bed tester had a ratio of 0.51, and a downcomer pipe was provided that partially penetrated the fluidized bed chamber from the liquid layer water surface to make it a self-flowing type.

流動床下部から水性塗料製造上場廃水(BOD987m
g、/Q、COD665mg/Q) と栄rim(N5
%/BOD、Pi%/BOD)を通油し連続的に生物処
理試験を行なった。
Water-based paint manufacturing listed wastewater from the bottom of the fluidized bed (BOD 987m)
g, /Q, COD665mg/Q) and Sakae rim (N5
%/BOD, Pi%/BOD) were passed through the oil and a biological treatment test was conducted continuously.

流動床担体である顆粒PVAを浮遊させ相体表面に生息
する好気的微生物に必要な酸素として空気2.5mm交
会を下部液層部に設置した多孔質散気管を通して供給し
た。
Granular PVA, which is a fluidized bed carrier, was suspended, and 2.5 mm of air was supplied as oxygen necessary for aerobic microorganisms living on the surface of the phase through a porous air diffuser installed in the lower liquid layer.

なお、L部層液面の水を沈降槽を介して再び流動床室下
部に導入循環させ、沈降槽上部から処理水を1″また。
The water at the liquid level in the L layer is introduced and circulated again into the lower part of the fluidized bed chamber via the settling tank, and the treated water is poured from the upper part of the settling tank by 1 inch.

1記廃水c7) 、a #Xa ヲB OD負荷0 、
5’k g/’IAE動床m′・11とした場合、得ら
れた処理水はBOD20mg/M(BOD除去率98.
0%)C’OD80 m’g/ 9. (COD除去率
88%)であった。
1 Wastewater c7) , a #Xa wo B OD load 0,
When 5'kg/'IAE moving bed m'・11, the obtained treated water has a BOD of 20mg/M (BOD removal rate of 98.
0%) C'OD80 m'g/9. (COD removal rate 88%).

Claims (1)

【特許請求の範囲】[Claims] イ1機吻合有被処理汚水が供給される流動床接触酸化槽
の流動床1−に水中で抱水高分子相粒体となる親水性高
分子1rσ粒物を充填して、該ノAc動床の下部から生
物前(ヒに要する耐票を直接曝気して補給12.11す
記相粒体表面からの711#汚泥を前記流動床に設けた
網11体を通して処理水と共に排出させることを特徴と
する流動床生物酸化処理方法。
B. Hydrophilic polymer 1rσ particles that become hydrated polymer phase particles in water are filled into the fluidized bed 1- of the fluidized bed contact oxidation tank to which wastewater to be treated with anastomosis is supplied. 711 # sludge from the surface of the phase granules is discharged together with the treated water through the net 11 provided in the fluidized bed. Characteristic fluidized bed biological oxidation treatment method.
JP58172114A 1983-09-20 1983-09-20 Fluidized bed biological oxidation treatment Granted JPS6064693A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP58172114A JPS6064693A (en) 1983-09-20 1983-09-20 Fluidized bed biological oxidation treatment

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP58172114A JPS6064693A (en) 1983-09-20 1983-09-20 Fluidized bed biological oxidation treatment

Publications (2)

Publication Number Publication Date
JPS6064693A true JPS6064693A (en) 1985-04-13
JPS6234434B2 JPS6234434B2 (en) 1987-07-27

Family

ID=15935811

Family Applications (1)

Application Number Title Priority Date Filing Date
JP58172114A Granted JPS6064693A (en) 1983-09-20 1983-09-20 Fluidized bed biological oxidation treatment

Country Status (1)

Country Link
JP (1) JPS6064693A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2081768A1 (en) * 1993-06-30 1996-03-01 Denka Consult & Eng Hydrated granular carrier prepared from polyvinyl alcohol and activated charcoal for biological treatment apparatus
JP2014509940A (en) * 2011-04-04 2014-04-24 ヴェオリア・ウォーター・ソリューションズ・アンド・テクノロジーズ・サポート Improved biological wastewater purification reactor and method

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS57207599A (en) * 1981-06-12 1982-12-20 Matsushita Electric Works Ltd Methane fermentation tank

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS57207599A (en) * 1981-06-12 1982-12-20 Matsushita Electric Works Ltd Methane fermentation tank

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2081768A1 (en) * 1993-06-30 1996-03-01 Denka Consult & Eng Hydrated granular carrier prepared from polyvinyl alcohol and activated charcoal for biological treatment apparatus
JP2014509940A (en) * 2011-04-04 2014-04-24 ヴェオリア・ウォーター・ソリューションズ・アンド・テクノロジーズ・サポート Improved biological wastewater purification reactor and method

Also Published As

Publication number Publication date
JPS6234434B2 (en) 1987-07-27

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