JPS6063442A - Method for stabilizing calibration gas composition - Google Patents
Method for stabilizing calibration gas compositionInfo
- Publication number
- JPS6063442A JPS6063442A JP3125984A JP3125984A JPS6063442A JP S6063442 A JPS6063442 A JP S6063442A JP 3125984 A JP3125984 A JP 3125984A JP 3125984 A JP3125984 A JP 3125984A JP S6063442 A JPS6063442 A JP S6063442A
- Authority
- JP
- Japan
- Prior art keywords
- aluminum
- gas
- resin
- titanium
- container
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N33/00—Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
- G01N33/0004—Gaseous mixtures, e.g. polluted air
- G01N33/0006—Calibrating gas analysers
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Food Science & Technology (AREA)
- Combustion & Propulsion (AREA)
- Physics & Mathematics (AREA)
- Analytical Chemistry (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Sampling And Sample Adjustment (AREA)
Abstract
Description
【発明の詳細な説明】
詳しく述べればスパッタリング現象を利用して高圧ガス
＃器の内面に金属，その他の＃膜を施こしたものを用い
て、こ、ｒＬに削起標準校正ガスを充填して安定化する
方法をこ関するものである。[Detailed Description of the Invention] To be more specific, a metal or other # film is applied to the inner surface of a high-pressure gas container using sputtering phenomenon, and the rL is filled with a standard calibration gas. This article concerns a method for stabilizing it.
近時公害防止の観点から大気汚染度の一定が問題となり
、各種の微量分析計が盛．に使用されているが、これら
には厳密な定ｊ７選択性を有するものが少ないため、分
析計に供給す６校正ガスを準備する際最適の標準ガスの
組成を決定すると同時に、調製した標準校正ガス組成を
でさる限り変化させことなく安定した状態で分析計に供
給することが望まれる。In recent years, constant air pollution has become a problem from the perspective of pollution prevention, and various microanalyzers have become popular. However, there are few of these that have strict constant j7 selectivity, so when preparing the six calibration gases to be supplied to the analyzer, it is necessary to determine the optimal composition of the standard gas and at the same time use the prepared standard calibration gas. It is desirable to supply the gas to the analyzer in a stable state without changing the gas composition as much as possible.
このような大気汚染の一定に使用されろ標準校正ガスと
しては一酸化窒素．−酸化炭素などをはじめ多くの品種
が用いられているが希薄濃度域におけるこれらの標準ガ
スは、一般に窒素，アルゴンをバランスガスとして希釈
するもので、保存しておくと標準ガス組成に経時変化を
生じ高圧ガス容器自着こおけろ校正ガスの値が安定しな
い場合が多い。 校正ガスの標準値、とくに微量濃度域
校正ガスの標準値が一定しないと測定に正ｍ注を欠き、
標準校正ガスとしてのｉＩＩｂ値を失うことはｄうまで
もない。Nitric oxide is the standard calibration gas used to measure air pollution. -Many types of standard gases are used, including carbon oxide, but these standard gases in dilute concentration ranges are generally diluted with nitrogen or argon as a balance gas, and if stored, the standard gas composition will not change over time. The value of the calibration gas produced by the high-pressure gas container itself is often unstable. If the standard value of the calibration gas, especially the standard value of the calibration gas in the trace concentration range, is not constant, the measurement will not be accurate.
Needless to say, the iIIb value as a standard calibration gas will be lost.
本発明者等は、−酸化窒素あるいは一酸化炭素などの校
正ガスが高圧ガス容器内で経時変化を起こし標準値の不
安定をもたらす要因につい〔凶々検討の結果、高圧容器
材の内面状ｒａ ｓ ことに鉄。The present inventors have investigated the factors that cause the calibration gas such as nitrogen oxide or carbon monoxide to change over time in the high-pressure gas container and cause the standard value to become unstable. s Especially iron.
水酸化鉄，酸化鉄等によるものであ渇との知見を得、−
破イと窒素，あるいは−酸化炭素などの標準組成ガスが
鯛鉄製容器内面と直接接触することを防ぐため充填すべ
き標準校正ガス成分に対し安定な金属または合成樹脂も
しくは無機物質を高圧容器内１逗に被覆することにより
標準校正ガスの経時安定性が長期に亘って保てることを
確認して本発明に至った。It was discovered that iron hydroxide, iron oxide, etc. caused thirst.
In order to prevent the standard composition gas such as nitrogen or carbon oxide from coming into direct contact with the inner surface of the Tai-tetsu container, a metal, synthetic resin, or inorganic substance that is stable against the standard calibration gas components to be filled is placed inside the high-pressure container. The present invention was achieved by confirming that the stability of the standard calibration gas over time can be maintained over a long period of time by coating the standard calibration gas.
本発明の要旨は、経時変化を起しゃすい低濃度諌止ガス
を安定に保存する方法が、ガス容器の上部平端部に配設
したガスケットと、該ガス容器内に延長させた円柱状電
極と、該容器内を真空排気する手段と、該容器内にイオ
ン化可能な気体を導入する手夜と、前記−極に高周波も
しくは直流電圧を印加する手段とから構成されたスパッ
タリング装置により、前記容器内にグロー放電を発生さ
せ、金属，合金，金属化合物．プラスチック及び無機化
合物よりなる群より選ばれた１種を，スパッタリングし
１内壁に形成された被膜を有す゛る高圧ガス容器に、前
記校正ガスを充填すゐことよりなることを特徴とする低
濃度校正ガス組成の安だ化方法である。The gist of the present invention is to provide a method for stably storing low-concentration stop gas that tends to change over time, using a gasket disposed at the upper flat end of a gas container, and a cylindrical electrode extended into the gas container. , a sputtering device comprising means for evacuating the inside of the container, a means for introducing an ionizable gas into the container, and a means for applying a high frequency or DC voltage to the negative electrode. It generates a glow discharge in metals, alloys, and metal compounds. A low-concentration calibration characterized in that a high-pressure gas container having a film formed on the inner wall by sputtering one selected from the group consisting of plastics and inorganic compounds is filled with the calibration gas. This is a method of making the gas composition cheaper.
本発明は、−酸化窒素あるいは一順化炭素などの変化し
やすい低濃度校正ガス組成を安定に保存する方法が金，
ニッケル、アルミ・ニウム、銅，タンタル、銀，鉛，ア
ンチモン、錫，蒼鉛，白金。The present invention provides a method for stably preserving the composition of a low-concentration calibration gas such as nitrogen oxide or monoacclimated carbon.
Nickel, aluminum, copper, tantalum, silver, lead, antimony, tin, blue lead, platinum.
モリブテン、タングステン、カドミウム、クロム。Molybdenum, tungsten, cadmium, chromium.
亜鉛，チタン、パラジウム、ジルコニウム等よりなる群
より選ばれた金属の１種またはこれらの合金、もしくは
窒化アルミニウム、ｔ１！化アルミニウム、酸化タンタ
ル、酸化チタン等の金属窒化物もしくは鍍化響の１１１
１、または四弗化エチレン樹脂。One metal selected from the group consisting of zinc, titanium, palladium, zirconium, etc. or an alloy thereof, or aluminum nitride, t1! Metal nitrides such as aluminum oxide, tantalum oxide, titanium oxide or 111
1, or tetrafluoroethylene resin.
三弗化エチレンｍ脂，ポリアミド１目脂，エポキシ樹脂
，ポリプロピレン４１，Ｊ脂，ポリエチレン樹１屑等の
安定な合成樹脂よりなろ群より選ばれたｌｌ（ｎ。ll (n.
あるいは石英，硝子等の無機物の１稠をスパッタリング
現象を利用して高圧ガス容器内面に薄膜を形成すること
よりなり、これに変化しやすい低濃度標準校正ガスを充
填して貯蔵することを狩徴とする低濃度校正ガスの安定
化方法である。Alternatively, it is possible to form a thin film on the inner surface of a high-pressure gas container using a sputtering phenomenon with a single concentration of inorganic material such as quartz or glass, and then fill this with a easily changeable low-concentration standard calibration gas and store it. This is a method for stabilizing low concentration calibration gas.
本発明の方法を適用でさろ校正ガスは、鉄の存在下に変
化を起しやすい性質を有するガスであればどのようなガ
スでもよいが、ここでは便宜上−酸化窒素および一酸化
炭素を対象として説明する。The calibration gas to which the method of the present invention is applied may be any gas as long as it has the property of easily changing in the presence of iron, but here, for convenience, nitrogen oxide and carbon monoxide are used as the calibration gas. explain.
本発明の方法は出願人がさきに特許出願した特盗器に内
張すする方法として主としてメッキを対象としていたも
のであるが、本発明者等はその後引続いて発明の目的を
より充分に達成すべく検討を重ねた結果本発明を完成し
たものである。Although the method of the present invention was primarily intended for plating as a method for lining a special stealth device for which the applicant previously applied for a patent, the present inventors subsequently continued to pursue the purpose of the invention more fully. The present invention has been completed as a result of repeated studies to achieve this goal.
即ち本発明の目的は一酸化窒素、、−ｗＩ化戻素などの
変化しゃすい低濃度校正ガスの組成を長期に亘り安定に
保存することにあり、もって大気汚染測定用校正ガスを
供給することができるようになしたことをこある。That is, the purpose of the present invention is to stably preserve the composition of a low-concentration calibration gas that easily changes, such as nitrogen monoxide, -wI, and the like, over a long period of time, thereby supplying a calibration gas for air pollution measurement. Here's what I did to make it possible.
従来容器の内張りとして知られているものとしては金属
メッキ及びプラスチックのライニングがある。しかしな
がらこれら′の内張りはいずれも欠点を有し、前者はと
ンホールが生じゃ丁い、水素等のガスが吸蔵される、膜
が厚く従って貴金属の場合材料費が非常に高くつく、膜
があらい、加工に手数を要し時間がかかる、メッキ廃液
の処理が面倒である等、またメッキの１種である溶融メ
ッキにおいては処理温度、高く容器材質に影響を及ぼす
、剥離しやすい等、後者の場合は、隅々まで被覆しにく
い、ピンホールが多い、ガスが１吸着される、剥離しや
すい等の問題が多い。これに反し不発ＩＩにおけるスパ
ッタリング被１良はビンホーｌしが少ない、ガスの吸蔵
が生じない、薄膜で低コストのため高価な材料を使用で
さる、被膜はメッキに比べ非常に緻密である、加工時１
１が短い、低温で処理可能である、付さまわり性がよい
等の従来法の欠点を排除した叡々の長所を−ｗ してい
ろ。Conventional container linings include metal plating and plastic linings. However, all of these linings have drawbacks; the former has poor throughholes and absorbs gases such as hydrogen; the membrane is thick; therefore, the material cost is very high in the case of precious metals; and the membrane is prone to scratches. , processing is laborious and time-consuming, treatment of plating waste liquid is troublesome, and hot-dip plating, which is a type of plating, requires a high processing temperature that affects the container material and is easily peeled off. In this case, there are many problems such as difficulty in covering every corner, many pinholes, adsorption of gas, and easy peeling. On the other hand, the sputtering target in Fudo II has few holes, no gas occlusion, thin film and low cost, so expensive materials can be used, the film is very dense compared to plating, and processing hour 1
Take advantage of the advantages of conventional methods, such as short lengths, the ability to process at low temperatures, and good wraparound properties, which eliminate the drawbacks of conventional methods.
更に従来法ではできなかった石英、硝子４の被膜を内面
に作ることができ、これら無績不苗性祷質によって一層
前記の目的達成に効果あらしめることができる。Furthermore, a coating of quartz or glass 4, which could not be produced by conventional methods, can be formed on the inner surface, and these qualities that prevent seedling failure can be made even more effective in achieving the above-mentioned purpose.
次に本釦明の効果を実施例をあげて説明する。Next, the effect of this button light will be explained by giving an example.
これらは、−１俊化窒素、二酸化窒素、−酸化炭ぶ。These are -1 nitrogen, nitrogen dioxide, and carbon oxide.
硫化水巣、硫化カルボニル、ジメチルサルファイド、ニ
ー比いおう、二酸化いおう、塩化水素、塩素、アンモニ
ア、トリメチルアミン、アクロレイン、メチルメルカプ
タン、塩化ビニル、ボ（水蒸気）オゾンをいずれも窒素
またはアルゴンをバランスガスとしてＦＡＩ表に示す材
料で内面被膜を施こした内容積１０ｊの間圧ガス容器に
、常温で圧力的１００ｋｇ／Ｑｎ’ Ｇで充填Ｌ１充填
後容器内の混合ガ謬を定期的に抜出して校正ガス組成の
経日変化を測定したもので、結果は第１表の１〜１７に
示すとありである。ここをこ−鹸化窒素、二酸化窒素は
ＣＬＤ型窒粱萌化物分析計で、−酸化炭素は非分林型赤
外線号析計で、アンモニア、トツメチルアミン、アクロ
レインはＦＩＬ）型ガマクロマトグラフで、水（＄蒸気
）はガルバニック型微量分析計で、オゾンは化学元光型
オゾン自動分析計で分析し１これ以外のガスは丁べてＦ
ＰＤ型ガマクロマトグラフにより測定した。Water sulfide, carbonyl sulfide, dimethyl sulfide, carbonyl sulfide, sulfur dioxide, hydrogen chloride, chlorine, ammonia, trimethylamine, acrolein, methyl mercaptan, vinyl chloride, water vapor, ozone, and FAI with nitrogen or argon as the balance gas. Fill an intermediate pressure gas container with an inner volume of 10j and an inner surface coated with the material shown in the table with a pressure of 100 kg/Qn'G at room temperature. After filling L1, periodically extract the mixed gas from the container and calculate the calibration gas composition. The results are shown in Table 1, 1 to 17. Here, saponified nitrogen and nitrogen dioxide are measured using a CLD-type nitric oxide analyzer, carbon oxide is measured using a non-branched type infrared analyzer, ammonia, methylamine, and acrolein are measured using a FIL-type gas macromatograph, and water ( $ steam) was analyzed using a galvanic type microanalyzer, and ozone was analyzed using a chemical source ozone automatic analyzer.
It was measured using a PD type Gamacromatograph.
Ｖゞ
この表から明らかなように充填後６４０日あるいはＪｌ
ｔｔ、ｇｓｏｏ日にも亘る経日変化値は従来汎用のマン
ガン鋼の容器（毫印）と比較して非常に変化が少なく格
段の安定さを示した。VゞAs is clear from this table, 640 days after filling or Jl
The changes over time over tt and gsoo days showed very little change and great stability compared to conventional general-purpose manganese steel containers (marked).
実施例 弗 ｌ 衣 １、ＮＯ層 ２、ＮＯ２ハ２ ３．Ｃｏ／Ｎ２ ４ 、 Ｈ２Ｓ／Ｎ２ ５、ｃｏｓハ２ ６、（Ｃｔｉａ ）ｚＳ／Ｎ２ １２、（ＣＭす３Ｎ／Ｎ２ １３．アクロレイン／Ｎ２ １５、ＣＨ２＝ ＣＭＣＩ／Ａｒ １６ ＋ＨｚＯ／Ｈ２Example 弗 L robe 1. NO layer 2.NO2ha2 3. Co/N2 4, H2S/N2 5, cos ha 2 6, (Ctia)zS/N2 12, (CMsu3N/N2 13. Acrolein/N2 15, CH2=CMCI/Ar 16 +HzO/H2
Claims (1)
保存する方法が、ガス容器の上部平端部に配設したガス
グツトと、該ガス容器内に延長させた円柱状電極と、該
容器内を真空排気する手段と、該容器内Ｑこイオン化可
能な気体を尋人する手段と、前記！極に高周波もしくは
直流電圧を印加する手段とから栂成されたスパッタリン
グ装置により、前記容器内にグロー放電を発生させ、金
属１合金。 金属化合物、プラスチック及び無機化合物よりなる群よ
り選ばれた１ｆｉを、スパッタリングし１内壁に形成さ
れた被膜を・汀する高圧ガス容器に、前記校正ガスを光
填することよりなることを待機とする低り度校正ガス組
成の安定化方法。 （２）前記被膜が金、ニッケル、アルミニウム。 銅、タンタル、銀、鉛、アンチモン、錫、蒼鉛。 白金、タングステン、９．力下ミウム、クロム。 モリブデン、亜鉛、チタン、パラジウム、ジルコニウム
よりなん金属の群より一選ばれた少なくとも１種である
特Ｊ「請求／）相聞（１）記載の方法。 （８） Ｉｌｎ記波膜がニッケルー銅、ニッケル−クロ
ム、ニッケルーモリブデン、＠−アルミニウム。 アルミニウムー錫−チタン、チタンーマンガノ。 チタン−アルミニウムーバナジウム、チタン−モリブテ
ン、チタン−ジルコニウム、アルミニウムーマグネシウ
ム、アルミニウムー亜鉛よりな石合金／）群より選ばれ
た１種である特許請求の範囲（１１記載の方法。 （４） 前記被膜が窒化アルミニウム、酸化アルミニウ
ム、酸化タンタル、 ＃Ｉｌ化チクチタンなる群より選
ばれた金属化合物の１種である特許請求の範囲（１）記
載の方法。 （５） 前記被膜が四弗化エチレン樹脂、三弗化塩化エ
チレン樹脂、ポリアミド樹ＩＪｔｊ 、エポキシ樹脂。 ポリプロピレン樹７＋１３１ポリ工チレンｍ ＩＪ目よ
りなる群より選ばれた合成樹脂の１種であゐ待計ｉ１ｊ
求の範囲（１）記載の方法。 （６） 前記被膜が石英、硝子よりなる群より選ばれた
無機化合物のｌ細である特許請求の範囲（１ン記載の方
法。 （７） 前記校正ガスの成分が一酸化窒素、−酸化炭素
、二酸化窒撲、硫化水射、アンモニア、二酸化イオウ、
塩化水素、三酸化イオウ、水（水蒸気９メチルメルカプ
タン ルサルファイド、１帽アクロレイン、塩化ビニール、硫
化カルボニル、オゾンよりなるガスの群より選ばれた少
なくとも１種である特許請求の範囲（１）記載の方法。[Claims] (1) A method for stably storing low-altitude calibration gas that tends to sharpen over time is provided by using a gas gut disposed at the upper flat end of a gas container and extending into the gas container. A cylindrical electrode, means for evacuating the inside of the container, means for removing ionizable gas from inside the container, and the above! A glow discharge is generated in the container by means of a sputtering device consisting of a means for applying a high frequency or direct current voltage to the poles, and a metal 1 alloy is generated in the container. 1fi selected from the group consisting of metal compounds, plastics, and inorganic compounds is sputtered, and the calibration gas is optically filled into a high-pressure gas container in which a coating formed on the inner wall of 1 is left to settle. Method for stabilizing low altitude calibration gas composition. (2) The coating is gold, nickel, or aluminum. Copper, tantalum, silver, lead, antimony, tin, blue lead. Platinum, tungsten, 9. Force Mium, Chromium. (8) The Iln wave recording film is made of at least one metal selected from the group of metals molybdenum, zinc, titanium, palladium, and zirconium. -chromium, nickel-molybdenum, @-aluminum, aluminum-tin-titanium, titanium-mangano, titanium-aluminum-vanadium, titanium-molybdenum, titanium-zirconium, aluminum-magnesium, aluminum-zinc stone alloys. (4) The coating is one of the metal compounds selected from the group consisting of aluminum nitride, aluminum oxide, tantalum oxide, and titanium chloride. The method according to range (1). (5) The coating is selected from the group consisting of tetrafluoroethylene resin, trifluorochloride ethylene resin, polyamide tree IJtj, epoxy resin. Polypropylene tree 7 + 131 polyethylene m IJtj It is a type of synthetic resin.
The method described in scope of request (1). (6) The method according to claim 1, wherein the coating is made of an inorganic compound selected from the group consisting of quartz and glass. (7) The components of the calibration gas are nitrogen monoxide, -carbon oxide. , nitrogen dioxide attack, sulfide water injection, ammonia, sulfur dioxide,
Claim (1) which is at least one gas selected from the group consisting of hydrogen chloride, sulfur trioxide, water (steam 9-methyl mercaptan sulfide, 1-cap acrolein, vinyl chloride, carbonyl sulfide, and ozone) Method.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3125984A JPS6063442A (en) | 1984-02-20 | 1984-02-20 | Method for stabilizing calibration gas composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3125984A JPS6063442A (en) | 1984-02-20 | 1984-02-20 | Method for stabilizing calibration gas composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS6063442A true JPS6063442A (en) | 1985-04-11 |
Family
ID=12326348
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP3125984A Pending JPS6063442A (en) | 1984-02-20 | 1984-02-20 | Method for stabilizing calibration gas composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6063442A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0279454A2 (en) * | 1987-02-20 | 1988-08-24 | Horiba, Ltd. | Assistant combustion agent for the use in a high-frequency combustion furnace |
| JPH05249007A (en) * | 1991-12-27 | 1993-09-28 | Intevep Sa | Method and apparatus for treating and storing sulfurcontaining gas sample for analyzing sulfur |
| CN111725125A (en) * | 2020-06-11 | 2020-09-29 | 深圳市华星光电半导体显示技术有限公司 | Microarray adsorption substrate, driving circuit and display device |
-
1984
- 1984-02-20 JP JP3125984A patent/JPS6063442A/en active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0279454A2 (en) * | 1987-02-20 | 1988-08-24 | Horiba, Ltd. | Assistant combustion agent for the use in a high-frequency combustion furnace |
| JPH05249007A (en) * | 1991-12-27 | 1993-09-28 | Intevep Sa | Method and apparatus for treating and storing sulfurcontaining gas sample for analyzing sulfur |
| CN111725125A (en) * | 2020-06-11 | 2020-09-29 | 深圳市华星光电半导体显示技术有限公司 | Microarray adsorption substrate, driving circuit and display device |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US6805931B2 (en) | Plastic container coated with carbon film | |
| EP0221549A2 (en) | A sealed container comprising a material having a deoxidation function | |
| JPS6063442A (en) | Method for stabilizing calibration gas composition | |
| Stern et al. | Studies of L-DOPA and related compounds adsorbed from aqueous solutions at platinum (100) and platinum (111): electron energy-loss spectroscopy, Auger spectroscopy, and electrochemistry | |
| US7934319B2 (en) | Pencil-sharpening device | |
| KR880001480B1 (en) | Container of prepared nutrient substrate carrier | |
| US2873050A (en) | Measuring and dispensing device | |
| Evans et al. | The growth of silver iodide films | |
| EP0494004B1 (en) | Device for dispensing, under pressure, a product, especially a foaming product, and methods of filling a container for such a device | |
| JPS57198542A (en) | Magnetic recording medium | |
| CA2452466A1 (en) | Addition of odorants to hydrogen by incorporating odorants with hydrogen storage materials | |
| KR20160120437A (en) | Oxygen and carbon dioxide gas real-time detecting sensor and a method of manufacturing the gas sensors and the detection method of the gas composition within the packaging container using the same | |
| Dahiya et al. | Thermodynamics of molecular interactions in aromatic hydrocarbons+ o-chlorotoluene mixtures | |
| JP2007223098A (en) | Plastic container | |
| Kaldor | Absorption Spectrum of Borazine in the Vacuum Ultraviolet | |
| JP2002029581A (en) | Plastic container for aerosol product, and aerosol product using the same | |
| Dehbi-Alaoui et al. | A comparison of the properties of hard carbon films produced by direct gas deposition and plasma-assisted evaporation | |
| US647700A (en) | Metallic receptacle. | |
| JPS62109859A (en) | Material having deoxygenating function | |
| Chua et al. | Microstructural and surface properties of cobalt containing amorphous carbon thin film deposited by a filtered cathodic vacuum arc | |
| Isoyama et al. | Recycling nebulisation system with exchangeable spray chamber for inductively coupled plasma atomic emission spectrometry | |
| JPS6034840A (en) | Abrasion-resistant film forming | |
| JPH08122296A (en) | Ph standard solution stored in small container | |
| Demchishin et al. | Coefficient of Reflection and Corrosion Resistance of Nickel Coatings Produced by Vacuum Deposition | |
| AU5728599A (en) | Plastic container for storing liquid coating materials |