JPS605438A - Optical information recording medium - Google Patents

Optical information recording medium

Info

Publication number
JPS605438A
JPS605438A JP58112250A JP11225083A JPS605438A JP S605438 A JPS605438 A JP S605438A JP 58112250 A JP58112250 A JP 58112250A JP 11225083 A JP11225083 A JP 11225083A JP S605438 A JPS605438 A JP S605438A
Authority
JP
Japan
Prior art keywords
layer
recording
light
recording layer
deposited
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP58112250A
Other languages
Japanese (ja)
Other versions
JPH0330216B2 (en
Inventor
Yasushi Miyazono
宮園 泰
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hoya Corp
Original Assignee
Hoya Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hoya Corp filed Critical Hoya Corp
Priority to JP58112250A priority Critical patent/JPS605438A/en
Publication of JPS605438A publication Critical patent/JPS605438A/en
Publication of JPH0330216B2 publication Critical patent/JPH0330216B2/ja
Granted legal-status Critical Current

Links

Classifications

    • GPHYSICS
    • G11INFORMATION STORAGE
    • G11BINFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
    • G11B7/00Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
    • G11B7/24Record carriers characterised by shape, structure or physical properties, or by the selection of the material
    • G11B7/241Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
    • G11B7/252Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers

Landscapes

  • Optical Record Carriers And Manufacture Thereof (AREA)

Abstract

PURPOSE:To improve recording sensitivity, to stabilize a recording layer and to improve signal contrast by depositing successively the 1st layer having light absorptivity and light coherence, a recording layer performing information recording by laser light and the 2nd layer having light absorptivity on a transparent base plate. CONSTITUTION:Soda lime glass subjected to a treatment is used as a discshaped transparent base plate. The 1st layer is deposited on the soda lime glass by glow-discharging gaseous ethylene under the specific gaseous pressure by using high frequency power and depositing at the same time copper phthalocyanine by evaporation as a material having absorptivity with a semiconductor laser on the soda lime glass. The film thickness of the 1st layer 7 is so set that the reflectivity is maximized by light coherence and that the effect of heat insulation is obtd. A recording layer 8 having a specific film thickness is deposited by vacuum deposition using tellurium of high purity on the layer 7. The 2nd layer 9 is deposited on the layer 8 by glow-discharging the gaseous ethylene by and under the method and conditions similar to the layer 1 and depositing at the same time tellurium by evaporation thereon.

Description

【発明の詳細な説明】 本発明は、光学式情報処理装置に使用される記録媒体に
関する。
DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a recording medium used in an optical information processing device.

この記録媒体は、第1図に示すように、レーザ光を円板
状透明基板1側よりレンズで集光、照射し、記録層2を
局部的に溶融、昇華せしめ、約1μmの直径を有する小
孔、いわゆる記録ビットを形成し、その記録ビットの有
無による反射率の変化により情報再生を行うものである
。そして、本例では、記録層2を被着させた円板状透明
基板1を2個用意して、記録層2を相互に対向させて、
透明基板1の内周端及び外周端にスペーサ3,4を挿入
して、中空領域5を設け、透明基板1とスペーサ3.4
との間に接着剤6を塗布して貼り合せ構造にしている。
As shown in FIG. 1, this recording medium has a diameter of approximately 1 μm by condensing and irradiating laser light with a lens from the disk-shaped transparent substrate 1 side to locally melt and sublimate the recording layer 2. Small holes, so-called recording bits, are formed, and information is reproduced by changing the reflectance depending on the presence or absence of the recording bits. In this example, two disc-shaped transparent substrates 1 each having a recording layer 2 thereon are prepared, and the recording layers 2 are made to face each other.
Spacers 3 and 4 are inserted into the inner and outer edges of the transparent substrate 1 to provide a hollow region 5, and the transparent substrate 1 and the spacers 3 and 4 are
An adhesive 6 is applied between the two to create a bonded structure.

このような構造により、記録層2は外気と遮断密閉され
、湿気などの影響による劣化を防止し、また、外気に露
出された記録層2の記録媒体ど対比して、記録再生を透
明基板1側より行う本例は、記録層2の表面に付@する
ごみ、ちり及びキズ等の影響を100万分の1程麿にま
で低減することができ、その結果、記録層2の安定化及
び記録・再生時の誤り率の低減について一応満足してい
る。
With such a structure, the recording layer 2 is sealed and sealed from the outside air, preventing deterioration due to the influence of moisture, etc., and recording and reproduction is performed on the transparent substrate 1, compared to the recording medium with the recording layer 2 exposed to the outside air. In this example, performed from the side, the influence of dirt, dust, scratches, etc. on the surface of the recording layer 2 can be reduced to about 1/1,000,000 times, and as a result, the stabilization of the recording layer 2 and the recording・We are satisfied with the reduction in error rate during playback.

しかし、このような光学式、情報記録媒体は、記録感度
、安定性及び信号コントラストについて次のような欠点
があった。寸なわら、記録感瓜については、レーザ光は
記録時において、そのレーザ光量の20〜30%が記録
層2を透過し、記録ビット形成のために有効利用されて
いないこと、記録層2の劣化防止手段として保護膜を記
録層2上に被着した場合、記録感度が低下することなど
の欠点があり、安定性については、記録層2の表面は遮
断密閉されているとは言え、中空領域5の下にあること
から、酸化による反射率の低下、膜はがれ及びきれつな
どが起きやすいこと、記録層2は透明基板1に直接被着
しているために、基板表面の数μm程度のきず、凹凸な
どの影響を受けやすいことなどの欠点があり、更に、記
録感度及び安定性と信号コントラストとの関係について
は、記録感度を向上させるために記録層2の膜厚を薄く
した場合、(RO−R+ )/ (RO+R+ )(こ
こで、RO及びR1はそれぞれ未記録部分及び記録部分
から得られた反射光信号である。)で表現される信号コ
ントラストが低下し、前述した安定性も著しく劣化する
こと、逆に、信号コントラストを高くし、記録層2の劣
化を防止するために、記録層2の膜厚を厚くした場合、
記録感度が低下するといった相反する性質を持っている
ことがら、両者を共に良好な状態にすることが不可能で
あった。
However, such optical information recording media have the following drawbacks regarding recording sensitivity, stability, and signal contrast. However, regarding the recording process, 20 to 30% of the amount of laser light passes through the recording layer 2 during recording, and is not effectively used for forming recording bits. When a protective film is applied to the recording layer 2 as a means to prevent deterioration, there are drawbacks such as a decrease in recording sensitivity, and stability is affected by the fact that although the surface of the recording layer 2 is sealed and sealed, there are Since the recording layer 2 is located under the area 5, it is susceptible to a decrease in reflectance due to oxidation, peeling and cracking of the film, and since the recording layer 2 is directly adhered to the transparent substrate 1, it is a few μm below the substrate surface. It has drawbacks such as being easily affected by scratches, unevenness, etc. Furthermore, regarding the relationship between recording sensitivity and stability and signal contrast, when the film thickness of the recording layer 2 is made thinner in order to improve recording sensitivity, , (RO-R+)/(RO+R+) (where RO and R1 are the reflected light signals obtained from the unrecorded area and the recorded area, respectively) decreases, and the stability described above decreases. Conversely, if the thickness of the recording layer 2 is increased in order to increase the signal contrast and prevent the recording layer 2 from deteriorating,
Since they have contradictory properties such as a decrease in recording sensitivity, it has been impossible to achieve good conditions for both.

本発明は、上記した欠点を除去するためになされたもの
であり、透明基板上に少なくとも光吸収性及び光干渉性
を右する第1層と、レーザ光により情報記録を行う記録
層と、少なくとも光吸収性を有する第2層とを順次被着
することにより、記録感度を向上させ、記録層を安定化
させ、更に信号コントラストを高くさせた光学式情報記
録媒体を提供することを目的とする。
The present invention has been made in order to eliminate the above-mentioned drawbacks, and includes at least a first layer having light absorption and light interference properties, a recording layer for recording information using a laser beam, and at least a first layer on a transparent substrate. The object of the present invention is to provide an optical information recording medium that improves recording sensitivity, stabilizes the recording layer, and further increases signal contrast by sequentially depositing a second layer having light absorption properties. .

第2図は、本発明による光学式情報記録媒体の主要部を
示し、同図<a >及び(b)はそれぞれレーザ光照射
前及びレーザ光照射後の状態であり、全体構造としては
、同図に示す円板状透明基板1を2個用意して、第1図
に示すように各層を対向さゼて、スペーサを介して接合
した遮断密閉構造になっている。
FIG. 2 shows the main parts of the optical information recording medium according to the present invention, and FIG. Two disk-shaped transparent substrates 1 shown in the figure are prepared, and as shown in FIG. 1, each layer is placed facing each other and joined via a spacer to form a shielding and sealing structure.

円板状透明基板1上には、少なくとも光吸収性及び光干
渉性を有する第1層7と、レーザ光により情報記録を行
う記録層8と、少なくとも光吸収性を有づ−る第2層と
を順次被着している。
On the disc-shaped transparent substrate 1, there are provided a first layer 7 having at least light absorption and light interference, a recording layer 8 for recording information using laser light, and a second layer having at least light absorption. and are applied sequentially.

先ず、第1層7は光吸収性であることから、レーザ光が
円板状透明基板1側より照射したとき、この第1層7に
て熱を発生し、記録層8にお()る記録ビット10の形
成に有効な熱として利用して記録感度を向上させる。ま
た、この第1層7に光干渉性を持たせることにより、第
1層7の内部でレーザ光を伺回か多重反射させ、記録層
8との界面においてその多重反射毎にレーザ光を記録層
8側に誘導させ、記録感度を向上させる。更に、未記録
部分の反射光信号ROが前述した多重反射により増大す
ることから、信号コン1−ラストも高くなる。なお、こ
の第1層7に断熱性ないし比較的厚り膜厚を持たぜた場
合には、レーザ光照射による記録層8で発生した熱の伝
導がこの第1m7にて阻止され、透明基板1側への熱伝
導を防止し、前述した光吸収による第1層7内部で発生
した熱の伝導が記録層8側に一層誘導され、更に、透明
基板1の凹凸などの表面欠陥があったどしても、その影
響を第1層7にて緩和して、記録層8への影響を少なく
づ−る。
First, since the first layer 7 is light-absorbing, when a laser beam is irradiated from the disk-shaped transparent substrate 1 side, heat is generated in the first layer 7 and transferred to the recording layer 8 ( ). The recording sensitivity is improved by using the heat as effective heat for forming recording bits 10. In addition, by giving the first layer 7 optical coherency, the laser beam is circulated or reflected multiple times inside the first layer 7, and the laser beam is recorded at each multiple reflection at the interface with the recording layer 8. It is guided to the layer 8 side to improve recording sensitivity. Furthermore, since the reflected optical signal RO in the unrecorded portion increases due to the multiple reflection described above, the signal contrast also increases. Note that when this first layer 7 has heat insulating properties or a relatively thick film thickness, conduction of heat generated in the recording layer 8 due to laser beam irradiation is blocked by the first layer 7, and the transparent substrate 1 The conduction of heat generated inside the first layer 7 due to the aforementioned light absorption is further guided to the recording layer 8 side, and furthermore, even if there are surface defects such as irregularities on the transparent substrate 1, Even if the recording layer 8 is recorded, the influence on the recording layer 8 is reduced by mitigating the influence in the first layer 7.

次に、第2層9は光吸収性であることから、レーザ光照
射時に熱を発生し、記録層8の記録ビット10の形成に
対しで有効な熱として利用されると共に、この第2層9
を軟化させることから、記録層8に記録ビット10を形
成゛りる際に、この第2層9が容易に取り除かれ、硬化
状態のままであったときと対比しで、記録層8の記録ビ
ット10の形成を促進し、結局、記録感度が向上する。
Next, since the second layer 9 is light-absorbing, it generates heat when irradiated with laser light and is used as effective heat for forming the recording bits 10 of the recording layer 8. 9
Therefore, when forming the recording bits 10 on the recording layer 8, this second layer 9 is easily removed, and the recording layer 8 becomes softer, compared to when the second layer 9 remains in a hardened state. This promotes the formation of bits 10 and ultimately improves recording sensitivity.

また、この第2層9は記録層8の表面を覆うことから、
保護膜としても作用Jる。以下、本発明の具体的実施例
を説明する。
Furthermore, since this second layer 9 covers the surface of the recording layer 8,
It also acts as a protective film. Hereinafter, specific examples of the present invention will be described.

円板状透明基板1として超精密加工、朝磨、洗浄の各工
程を経た板厚1.2mmのソーダライムガラスを使用し
た。
As the disc-shaped transparent substrate 1, soda lime glass with a thickness of 1.2 mm was used, which had undergone ultra-precision processing, polishing, and cleaning steps.

第1層7は、13.54 M+−12、100Wの高周
波電力でエチレンガスを1〜10”” T orrのガ
ス圧でグロー放電させ、同時に波長830 nrnの半
導体レーザに吸収性を持つ材料として銅フタロシアニン
を蒸着してソーダライムガラス[に被着した。エチレン
重合膜中の銅フタロシアニンの含有量は15atomi
c%稈痕である。この含有量は5〜40atomic%
の範囲にあればよく、好ましくは10〜20atomi
c%である。この第1層7の膜厚は、光干渉性により反
射率が最大になり、また断熱効果が得られるように設定
され、本例では約2000人であり、その範囲は100
0人〜3000人であればJ:いが、好ましくは150
0人〜2500人である。ソーダライムガラス基板上に
この第1層7のみを被着させて、同基板側からめた反射
率は約10%であった。
The first layer 7 is made of a material that glow discharges ethylene gas at a gas pressure of 1 to 10" Torr with a high frequency power of 13.54 M+-12 and 100 W, and at the same time absorbs a semiconductor laser having a wavelength of 830 nrn. Copper phthalocyanine was deposited on soda lime glass. The content of copper phthalocyanine in the ethylene polymer film is 15 atoms.
c% culm scar. This content is 5-40 atomic%
It may be within the range of, preferably 10 to 20 atoms
c%. The film thickness of the first layer 7 is set so that the reflectance is maximized due to optical interference and a heat insulation effect is obtained.
J: Yes if there are 0 to 3000 people, but preferably 150
0 to 2500 people. Only this first layer 7 was deposited on a soda lime glass substrate, and the reflectance from the substrate side was about 10%.

次に、99.99%の純度のテルルを1 x 10””
’T or「の真空度で真空蒸着により膜厚100人の
記録層8を先の第1層7上に被着した。この記録層8の
膜厚は20人〜500Aの範囲にあればよく、好ましく
は50人〜150人である。
Next, 1 x 10” of 99.99% pure tellurium
A recording layer 8 having a thickness of 100 Å was deposited on the first layer 7 by vacuum evaporation at a vacuum degree of 'T or'. , preferably 50 to 150 people.

次に、第2層9はエチレンガスを第1層1と同様な方法
及び条件によりグロー放電させ、同時にテルルを蒸着し
て記録層8上に被着した。本例のエチレン重合膜中のテ
ルルの含有量は約10atomic%であるが、その範
囲は5〜40atomic%であればよく、好ましく1
よ10〜20atomic%である。また、エチレン重
合膜の膜厚は、記録感度を低下させずに、記録層8の保
護効果を秦するために、本例では約1ooo人に設定し
たが、その範囲は300人〜3000人であればよく、
好ましくは500人〜2500人である。
Next, the second layer 9 was formed by glow-discharging ethylene gas using the same method and conditions as the first layer 1, and at the same time, tellurium was deposited on the recording layer 8 by vapor deposition. The tellurium content in the ethylene polymer film of this example is about 10 atomic%, but it may range from 5 to 40 atomic%, preferably 1
It is 10 to 20 atomic%. In addition, the film thickness of the ethylene polymer film was set to about 100 people in this example in order to reduce the protective effect of the recording layer 8 without reducing the recording sensitivity, but the range is 300 to 3000 people. Good to have,
Preferably it is 500 to 2,500 people.

記録及び再生+1aのレーザ照射パワーは、記録媒体面
でそれぞれ6mW及び0.6m Wであった。レーザス
ポットの直径は約1.6μmであった。記録感度はレー
ザパルス幅で30nsと高い値が得られた。
The laser irradiation powers for recording and reproduction +1a were 6 mW and 0.6 mW, respectively, on the recording medium surface. The diameter of the laser spot was approximately 1.6 μm. A high recording sensitivity of 30 ns in laser pulse width was obtained.

未記録部及び記録部の反射率は、それぞれ39%及び6
%となって、73%という高い信号コントラストを得た
。記録部分の反射率が10%以下になったのは、第2図
(b)に示すように第1層7中の銅フタロシアニンの一
部においても昇華が行われたためと思われる。
The reflectance of the unrecorded area and the recorded area is 39% and 6, respectively.
%, and a high signal contrast of 73% was obtained. The reason why the reflectance of the recorded portion was 10% or less is considered to be because some of the copper phthalocyanine in the first layer 7 was also sublimated, as shown in FIG. 2(b).

次に、比較例どして第1図に示したような構造、すなわ
ちソーダライムガラス基板(板厚: 1,2mm)上に
1x 10−67 orrの真空度で純度99.99%
のテルルを膜厚約100人で真空蒸着法により被着し、
ソーダライムガラス基板側よりレーザ光をこの記録媒体
に照射し、記録感度及び信号コントラストをそれぞれ測
定した。なお、レーザ光照射パワーは前述しと同様の条
件とした。測定結果によれば、未記録部分及び記録部分
の反射率はそれぞれ30%及び5%であり、信号コント
ラストが10%程度、記録感度がレーザパルス幅で10
 D o sを得て、いずれも本発明と対比して特性が
低下していた。
Next, as a comparative example, the structure shown in Fig. 1 was prepared, that is, the purity was 99.99% on a soda lime glass substrate (thickness: 1.2 mm) at a vacuum level of 1 x 10-67 orr.
of tellurium was deposited by vacuum evaporation method to a film thickness of about 100 mm,
A laser beam was irradiated onto this recording medium from the side of the soda lime glass substrate, and the recording sensitivity and signal contrast were measured. Note that the laser beam irradiation power was set to the same conditions as described above. According to the measurement results, the reflectance of the unrecorded part and the recorded part is 30% and 5%, respectively, the signal contrast is about 10%, and the recording sensitivity is about 10% in laser pulse width.
D o s were obtained, and the characteristics were all lower than those of the present invention.

本発明は以上の実施例に挙げた物質に限定されず、透明
基板として、石英ガラス、塩化ビニール樹脂、酢酸ビニ
ール樹脂、アクリル樹脂、メタクリル樹脂、ポリエステ
ル樹脂、ニトロセルロース、ポリスチレン樹脂、ポリプ
ロピレン樹脂、ポリアミド樹脂、ポリカーボネート樹脂
、エポキシ樹脂等を用いてもよい。次に、光吸収性及び
光干渉性を有する第1層7として、鉛フタロシアニンな
どの金属フタロシアニン、テルル(TO)、セレン(S
e)、及びイオウ(S)のカルコゲン元素又はビスマス
(Bi)、インジウム(In>、鉛(Pb)、、カドミ
ウム(Cd)、ヒ素(As )、スズ(Sn)の単体及
びその化合物又はで−の酸化物をエチレン市合体以外の
オレフィン化合物に混合させるか、ベンピン類、ポリ1
スプル、ポリスチレン、アクリル系ポリマ、酢酸セルロ
ース、硝酸セルロース、臭素化ポリヒト日キシスチレン
、塩化ゴム、Si O及び5i02などを用いてもよい
。次に、記B層8として、カドミウム(Cd)、ビスマ
ス(Bi)、インジウム(In)、鉛(pH)、イAつ
(S)、スズ(Sn)、けレン(Se)の単体、それら
の化合物、それらの酸化物又はフタロシアニン誘導体な
どを用いてもJ、い。光吸収性を有づ゛る第2層つとし
ても第1層7と同様なものが利用でき、更に金(AU 
) 、銀(A(1>、白金(’Pt)、銅(Cu )及
びクロム(CI−)などを用いることができる。また、
実施例の成膜方法として真空蒸着及びグロー放電を挙げ
たが、使用覆る物質によって直流スパッタリング、高周
波スパッタリング、反応性スパッタリング、イオンブレ
ーティング、イオンクラスター、メッキ、CvO1共蒸
着、気相成長、キャスト、ドクターブレード、マグネト
[1ンスパツタ又はスプレー、ローラーコーティング、
ディッピング。スピニング等の塗布法を用いτもJ、い
The present invention is not limited to the materials listed in the above embodiments, but materials such as quartz glass, vinyl chloride resin, vinyl acetate resin, acrylic resin, methacrylic resin, polyester resin, nitrocellulose, polystyrene resin, polypropylene resin, polyamide can be used as the transparent substrate. Resin, polycarbonate resin, epoxy resin, etc. may also be used. Next, as the first layer 7 having light absorption and light interference properties, a metal phthalocyanine such as lead phthalocyanine, tellurium (TO), selenium (S
e), and chalcogen elements of sulfur (S), or simple substances and compounds of bismuth (Bi), indium (In), lead (Pb), cadmium (Cd), arsenic (As), and tin (Sn), or - oxides are mixed with olefin compounds other than ethylene, bempines, poly-1
Sprue, polystyrene, acrylic polymers, cellulose acetate, cellulose nitrate, brominated polyoxystyrene, chlorinated rubber, SiO and 5i02 may also be used. Next, as the B layer 8, simple substances of cadmium (Cd), bismuth (Bi), indium (In), lead (pH), S, tin (Sn), and silicon (Se), It is also possible to use compounds, their oxides, or phthalocyanine derivatives. The second layer having light absorption properties can be made of the same material as the first layer 7, and may also be made of gold (AU
), silver (A(1>), platinum ('Pt), copper (Cu), chromium (CI-), etc. can be used.
Although vacuum evaporation and glow discharge were mentioned as film forming methods in the examples, direct current sputtering, high frequency sputtering, reactive sputtering, ion blating, ion cluster, plating, CvO co-evaporation, vapor phase growth, casting, Doctor blade, magneto [1 inch spatter or spray, roller coating,
Dipping. τ is also J, using a coating method such as spinning.

また、実施例ではレーザ光源に8.30 n mの波長
の半導体レーザを用いたが、使用波長は830 n m
以外のものでもより、(の際、各層の膜厚、光吸収f1
物質の配合割合はその波長により機能的に定めることが
できる。
In addition, in the example, a semiconductor laser with a wavelength of 8.30 nm was used as a laser light source, but the wavelength used was 830 nm.
(In this case, the film thickness of each layer, light absorption f1
The blending ratio of substances can be determined functionally depending on the wavelength.

以上のとJ3す、本発明によれば、記録層8の長期安定
化が得られると共に、第1層7と第2層8によるサンド
インチfil造により信舅コン1−ラストを高くした状
態で、記録感度を向上させることができる。
As described above, according to the present invention, long-term stability of the recording layer 8 can be obtained, and the sand-inch film structure of the first layer 7 and the second layer 8 can increase the optical strength. , recording sensitivity can be improved.

【図面の簡単な説明】[Brief explanation of drawings]

第1図は従来の光学式情報記録媒体の断面図、第2図は
本発明による光学式情報記録媒体の主要部分断面図であ
る。 1・・・円板状透明基板、7・・・第1層、8・・・記
録層、9・・・第2層
FIG. 1 is a sectional view of a conventional optical information recording medium, and FIG. 2 is a sectional view of main parts of an optical information recording medium according to the present invention. DESCRIPTION OF SYMBOLS 1... Disc-shaped transparent substrate, 7... First layer, 8... Recording layer, 9... Second layer

Claims (2)

【特許請求の範囲】[Claims] (1) 透明基板上に少なくとも光吸収性及び光干渉性
を有する第1層と、レーザ光により情報記録を行う記録
層と、少なくとも光吸収性を有する第2層とを順次被着
することを特徴とする光学式%式%
(1) A first layer having at least light absorption and light interference, a recording layer for recording information using a laser beam, and a second layer having at least light absorption are sequentially deposited on a transparent substrate. Features Optical % formula %
(2) 第1層と第2層が金属フタロシアニン、7J 
)tt ml ’7’ > 元素又ハBi 、[、Pb
 、 cd 、 As、Snのうち少なくとも1つを含
有していることを特徴とする特許請求の範囲第1項記載
の光学式情報記録媒体。
(2) The first and second layers are metal phthalocyanine, 7J
)tt ml '7'> Element Mata Bi, [, Pb
, CD, As, and Sn.
JP58112250A 1983-06-22 1983-06-22 Optical information recording medium Granted JPS605438A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP58112250A JPS605438A (en) 1983-06-22 1983-06-22 Optical information recording medium

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP58112250A JPS605438A (en) 1983-06-22 1983-06-22 Optical information recording medium

Publications (2)

Publication Number Publication Date
JPS605438A true JPS605438A (en) 1985-01-12
JPH0330216B2 JPH0330216B2 (en) 1991-04-26

Family

ID=14582000

Family Applications (1)

Application Number Title Priority Date Filing Date
JP58112250A Granted JPS605438A (en) 1983-06-22 1983-06-22 Optical information recording medium

Country Status (1)

Country Link
JP (1) JPS605438A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6163940A (en) * 1984-09-05 1986-04-02 Hitachi Ltd Information recording medium
JP2004504633A (en) * 2000-07-17 2004-02-12 チャップマン テクノロジーズ インコーポレイテッド Dry multilayer inorganic alloy thermal resist for lithographic processing and imaging

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8972409B2 (en) 2011-07-27 2015-03-03 Google Inc. Enabling search for conversations with two messages each having a query team

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5174632A (en) * 1974-12-24 1976-06-28 Canon Kk

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5174632A (en) * 1974-12-24 1976-06-28 Canon Kk

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6163940A (en) * 1984-09-05 1986-04-02 Hitachi Ltd Information recording medium
JPH0473226B2 (en) * 1984-09-05 1992-11-20 Hitachi Ltd
JP2004504633A (en) * 2000-07-17 2004-02-12 チャップマン テクノロジーズ インコーポレイテッド Dry multilayer inorganic alloy thermal resist for lithographic processing and imaging

Also Published As

Publication number Publication date
JPH0330216B2 (en) 1991-04-26

Similar Documents

Publication Publication Date Title
CA1220552A (en) Information recording medium
EP0978831B1 (en) Optical information recording medium and method for producing the same, method for recording and reproducing information thereon and recording/reproducing apparatus
KR20000062984A (en) Information recording medium, manufacturing method of the medium and recording method of the medium
KR20000064351A (en) Optical information recording medium and manufacturing method thereof, optical information recording and reproducing method, and optical information recording and reproducing apparatus
EP1052632A2 (en) Optical information recording medium
EP1414029A2 (en) Optical recording medium and method for manufacturing the same
JP3666854B2 (en) Information recording medium and manufacturing method thereof
US6432502B1 (en) Optical recording medium and method of manufacturing the same
EP0099208B1 (en) An information recording material
EP1052631A2 (en) Optical information recording medium, method for producing the same, and method and apparatus for recording/reproducing information thereon
US4385305A (en) Recording member
JPS605438A (en) Optical information recording medium
JP2004082406A (en) Optical recording medium
US20020110069A1 (en) Initialization method for phase change type optical disc
JPH0575595B2 (en)
JPS6118262B2 (en)
JPH0252330B2 (en)
US5006387A (en) Information recording medium
JPH042436B2 (en)
JPH0822614B2 (en) Optical recording medium
JP2001028148A (en) Optical information recording medium, its manufacture, recording/reproducing method and recording/ reproducing device
JPS61272190A (en) Optical recording medium
KR100258938B1 (en) Phase changing type optical disk
JP2003085838A (en) Method of manufacturing optical recording medium
JPS62127287A (en) Optical recording material