JPS6053568A - Colored slaked lime powder for marking use - Google Patents
Colored slaked lime powder for marking useInfo
- Publication number
- JPS6053568A JPS6053568A JP16176483A JP16176483A JPS6053568A JP S6053568 A JPS6053568 A JP S6053568A JP 16176483 A JP16176483 A JP 16176483A JP 16176483 A JP16176483 A JP 16176483A JP S6053568 A JPS6053568 A JP S6053568A
- Authority
- JP
- Japan
- Prior art keywords
- water
- slaked lime
- powder
- colored
- organic solvent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
Abstract
Description
【発明の詳細な説明】
本発明は、標識用着色消石灰粉末に関する。さらに詳し
くは、酸化カルシウム粉末、当Ｉの水、有機顔料、およ
び該顔料を溶解でき、水に可溶な有機溶剤を混合し、′
発熱および乾燥させてなる該粉末に関する。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to colored slaked lime powder for marking purposes. More specifically, calcium oxide powder, water, an organic pigment, and an organic solvent that can dissolve the pigment and are soluble in water are mixed;
The present invention relates to the powder obtained by exothermic and drying.
消石灰粉末は、生石灰すなわち酸化石灰に当量の水を混
合し水和させて製造され、化学工業用。Slaked lime powder is produced by mixing quicklime, or oxidized lime, with an equivalent amount of water and hydrating it, and is used in the chemical industry.
建築用、肥料用、農薬用、製紙用その他に広く用いられ
ている。その他の用途の一つとして例えば、道路、グラ
ンド等に一時的に白線を引く等の狭義の標識用がある。It is widely used for construction, fertilizer, agricultural chemicals, paper manufacturing, and other applications. One of the other uses is, for example, for marking in a narrow sense, such as temporarily drawing white lines on roads, grounds, etc.
従来、標識用の消石灰粉末としては、無着色のすなわち
白色のままのものしか知られていなかりた。その理由の
一つは白色以外の標識形成用消石灰粉末（以下、標識用
消石灰）の需要がなかつたためであり、他の一つは着色
された標識用消石灰を経済的に製造する方法が知られて
いなかったためである。Conventionally, the only known slaked lime powder for marking purposes was one that was uncolored, that is, remained white. One of the reasons for this was that there was no demand for slaked lime powder for marking other than white (hereinafter referred to as slaked lime for marking), and the other reason was that there was no known method to economically produce colored slaked lime for marking. This is because they were not prepared.
本発明者等は、着色された標識用消石灰が経済的に提供
出・来れば、無着色品と併せて、その具体的利用分野は
大幅に拡大出来ると考えた。消石灰粉末は、他の無機顔
料と異り、若干水溶性であシ、顔料で表面処理するには
、相当多量の有機溶剤を要する。また、顔料を消石灰に
直接混合する方法では、例えば顔料の混合比率を混合物
の数十重量％にする必要があり経済的でない。本発明者
等は、以上の問題解決のため、消石灰に代えて、酸化石
灰の粉末を使用し、有機溶剤に代えて酸化石灰と当量の
水および該水とほぼ同量の有機溶剤、および該有機溶剤
に可溶な有機顔料を使用することによシ、酸化石灰から
消石灰への水利反応と同時に、有機顔料による消石灰粉
末の被覆および乾燥が可能となシ、公知の無機充填剤一
般の（有機顔料十有機溶剤）による表面処理による場合
とくらべて、有機溶剤の使用量および回収費が節約出来
、より少ない有機顔料量で効果的な着色が可能であるこ
とを知見した。The inventors of the present invention believed that if colored slaked lime for marking could be provided economically, the specific field of use thereof could be greatly expanded in conjunction with uncolored products. Slaked lime powder, unlike other inorganic pigments, is slightly water-soluble and requires a considerable amount of organic solvent to treat the surface with the pigment. In addition, the method of directly mixing pigments with slaked lime requires, for example, the mixing ratio of pigments to be several tens of weight percent of the mixture, which is not economical. In order to solve the above problems, the present inventors used oxidized lime powder instead of slaked lime, and instead of an organic solvent, used an amount of water equivalent to the amount of lime oxide, an organic solvent approximately the same amount as the water, and an organic solvent. By using an organic pigment that is soluble in an organic solvent, it is possible to cover and dry slaked lime powder with the organic pigment and dry it at the same time as the water utilization reaction from oxidized lime to slaked lime. Compared to surface treatment with organic pigments and organic solvents, the amount of organic solvents used and recovery costs can be saved, and it has been found that effective coloring can be achieved with a smaller amount of organic pigments.
同時に、この着色消石灰粉末は標識用として、色彩が鮮
明であシ、散布性ないし被覆力は無着色品と同等であり
、使用中に着色が剥離しないことを知見して本発明全完
成した。At the same time, this colored slaked lime powder can be used for marking purposes, and the color is clear, the dispersibility and covering power are equivalent to uncolored products, and the coloring does not peel off during use, and the present invention has been completed.
以上の説明から明らかなように、本発明の目的は標識用
着色消石灰粉末を経済的に提供することを目的とする。As is clear from the above description, an object of the present invention is to economically provide colored slaked lime powder for marking.
他の目的は標識用（無着色）消石灰粉末の具体的用塗分
野を拡大することである。Another purpose is to expand the field of specific application of slaked lime powder for marking (uncolored).
本発明は、粒子径４４μ〜５ｆｒａの酸化カルシウム粉
末に０．１〜１０重量％の有機顔料、該酸化カルシウム
と当量の水および前記有機顔料を溶解出来、かつ前記水
とほぼ同量の水溶性有機溶媒を混合し、該酸化カルシウ
ム粉末と水との水利反応により生成した着色物を乾燥せ
しめてなる標識用着色消石灰粉末である。The present invention is capable of dissolving 0.1 to 10% by weight of an organic pigment, an equivalent amount of water to the calcium oxide, and the organic pigment in calcium oxide powder having a particle size of 44 μ to 5 fra, and having a water solubility of approximately the same amount as the water. This is a colored slaked lime powder for labeling, which is made by mixing an organic solvent and drying a colored substance produced by a water utilization reaction between the calcium oxide powder and water.
本発明の構成と効果につき以下に詳述する。The configuration and effects of the present invention will be explained in detail below.
Ａ０着色物製造方法：
酸化カルシウム粉末は、公知方法で焼成された生石灰全
粉砕して、４４μ〜５欄の粒径とする。A0 colored product manufacturing method: Calcium oxide powder is obtained by completely crushing calcined quicklime using a known method to obtain a particle size of 44 μm to 5 columns.
石灰石の焼成方法は限定されないが、好ましくはソフト
な活性度の強い生石灰を得るために、良質の厳選された
石灰石をコークス、石炭等の固形燃料若しくは重油、
ＬＰＧ等の流体燃料を用いて十分に焼成する。生石灰の
粉砕は、レイモノドミル等の公知の粉砕機を使用する。The method of calcining limestone is not limited, but preferably, in order to obtain soft quicklime with strong activity, carefully selected limestone of high quality is heated with solid fuel such as coke, coal, or heavy oil.
Thoroughly fire using a fluid fuel such as LPG. Quicklime is pulverized using a known pulverizer such as a Raymond Mill.
粒度は４４μ〜５＋１１１１好ましくは４４μ〜１ｔｒ
ｒｍである。４４μ未満では水利反応速度が速すぎる部
分と、空気中の炭酸ガスによシ炭酸化され水利反応速度
が遅くなる部分と混合された様になシ有機顔料による被
覆が均一に行なわれない場合があり、５１１ＩＩ＋＋を
超えると、粒子全体から見て水利反応が遅くな多粒子の
表面部分のみ水利され、水利熱の損失が増加し、完全な
着色が出来ない、又、自動的乾燥が不十分となる。Particle size is 44μ to 5+1111 preferably 44μ to 1tr
It is rm. If it is less than 44μ, the coating with the organic pigment may not be uniformly carried out, as parts where the water use reaction rate is too fast are mixed with parts where the water use reaction rate is slow due to carbonation due to carbon dioxide in the air. If it exceeds 511II++, only the surface part of the multi-particles where the water use reaction is slow compared to the whole particle is used, the loss of water use heat increases, complete coloring is not possible, and automatic drying is insufficient. Become.
かくして得られた酸化カルシウム粉末に対して、好まし
くは先ず０．１〜１０重量％（以下、チ）の有機顔料、
好ましくは有機ペイント用顔料粉末を加えて混合する。Based on the calcium oxide powder thus obtained, preferably 0.1 to 10% by weight (hereinafter referred to as H) of an organic pigment,
Preferably, organic paint pigment powder is added and mixed.
有機顔料の使用量は所望の着色濃度により決定する。混
合方法は、公知の粉粒体用混合機例えば、リボン！レン
ダー１Ｖ型混合機。The amount of organic pigment used is determined depending on the desired color density. The mixing method can be carried out using a known mixer for powder or granular materials, such as Ribbon! Render 1V type mixer.
ロータリーミキサー等を用いて室温で１０分〜３時間、
好ましくは３０分〜１時間行なう。かくして得られた酸
化石灰−有機顔料混合物に、好ましくは水と有機溶剤若
しくは水−有機溶剤混合溶液を攪拌下に添加する。水の
使用量は上述の混合物中の酸化石灰と当量もしくは当量
を若干量例えば１〜１０チ上廻る量である当量未満では
、酸化石灰との水利反応が不十分となシ、当量よｐ著る
しく多量に使用すれば最終的製品の自動的乾燥が不十分
となり、また、有機溶剤の必要量も増加し、良質の製品
が得られない。その反面１〜１０％程度の当量よシ過剰
の水分は、後述のペースト状物の攪拌と均一な水利発熱
反応の維持を容易にする有機溶剤としては前述の有機顔
料ｔ−溶解出来、かつ、水と自由な比率で均一に混合出
来るものが望ましい。例えばメタノール、エタノール、
イングロパノール、アセトンなどである。10 minutes to 3 hours at room temperature using a rotary mixer etc.
It is preferably carried out for 30 minutes to 1 hour. To the lime oxide-organic pigment mixture thus obtained, preferably water and an organic solvent or a mixed solution of water and organic solvent are added while stirring. If the amount of water used is less than the equivalent of the oxidized lime in the above-mentioned mixture or slightly more than the equivalent, for example, 1 to 10 times more, the water utilization reaction with the oxidized lime will be insufficient. If too large a quantity is used, the automatic drying of the final product will be insufficient, and the amount of organic solvent required will also increase, making it impossible to obtain a good quality product. On the other hand, an equivalent excess of water of about 1 to 10% can be used as an organic solvent to easily stir the paste-like material described below and maintain a uniform water exothermic reaction, and can dissolve the organic pigments mentioned above. It is desirable to have something that can be mixed uniformly with water in any ratio. For example, methanol, ethanol,
Inglopanol, acetone, etc.
本発明に於て驚くべきことは、上述の水−有機溶剤混合
溶液が直接には、上述の有機顔料を溶解出来なくとも本
発明の実施には差支ないことである（後述説明参照）。What is surprising about the present invention is that even if the above-mentioned water-organic solvent mixed solution cannot directly dissolve the above-mentioned organic pigment, there is no problem in carrying out the present invention (see explanation below).
酸化石灰−有機顔料混合物に水−有機溶剤混合溶液の添
加混合は、公知の混練機又は混和器を用いて、室温〜１
００℃で２０分〜１時間、好ましくは３０〜４０分行な
う。その後、３０分〜３０時間、好ましくは１時間〜１
５時の熟成を製品ホッパーで行なう。水利反応による発
熱は、有機溶剤の蒸発熱によシ除去されるが、危険防止
および環境保全のため混練器等はシャケ、ト等の冷却装
置と有機溶剤の凝縮器（コンデンサー）を備えたものが
良い。該添加混合の終期は、水利反応熱の発生終了を器
内温度を継続的に測定して知シ、器内温度が室温よシや
や高い程度の温度まで十分に低下した時点で終了７する
。The water-organic solvent mixed solution is added to the oxidized lime-organic pigment mixture using a known kneader or mixer at room temperature to 1.
It is carried out at 00°C for 20 minutes to 1 hour, preferably 30 to 40 minutes. After that, 30 minutes to 30 hours, preferably 1 hour to 1 hour.
Aging at 5 o'clock is carried out in the product hopper. The heat generated by the water utilization reaction is removed by the heat of evaporation of the organic solvent, but in order to prevent danger and protect the environment, the kneader, etc. must be equipped with a cooling device such as a salmon and a condenser for the organic solvent. is good. The end of the addition and mixing is determined by continuously measuring the temperature inside the vessel to determine the end of the generation of water utilization reaction heat, and ends when the temperature inside the vessel has sufficiently decreased to a temperature slightly higher than room temperature (7).
かくして、本発明に係わる標識用−着色消石灰粉末が得
られる。Thus, a colored slaked lime powder for marking according to the present invention is obtained.
得られた該粉末を顕微鏡観察すると、消石灰粉末の表面
が有機顔料で均一に被覆され、該粉末を指で摩擦しても
、着色物が簡単に剥離することはない。この理由は、酸
化石灰粉末から水利反応で新たに消石灰の粉末状結晶が
形成される間に一旦有機溶剤溶液として存在した有機顔
料の分子が消石灰粉末の表面に析出して強固に付着し、
有機顔料特有の被覆力を十分に発揮するからであると思
われる。上述の有機溶剤溶液は、当初有機溶剤が水と共
存するため有機顔料の溶解が困難であるが、該水分が酸
化石灰との水利反応で消費されてゆく間に、残った有機
溶剤が、有機顔料を溶解する力を恢復するものと思われ
る。When the obtained powder was observed under a microscope, it was found that the surface of the slaked lime powder was uniformly coated with the organic pigment, and even when the powder was rubbed with a finger, the colored material did not easily peel off. The reason for this is that while new slaked lime powder crystals are formed from oxidized lime powder through a water utilization reaction, organic pigment molecules that once existed as an organic solvent solution precipitate and firmly adhere to the surface of slaked lime powder.
This is thought to be because it sufficiently exhibits the covering power unique to organic pigments. In the above-mentioned organic solvent solution, it is initially difficult to dissolve organic pigments because the organic solvent coexists with water, but as the water is consumed by the water utilization reaction with lime oxide, the remaining organic solvent dissolves into organic pigments. It is thought to restore the power to dissolve pigments.
本発明に係る着色方法に代えて消石灰粉末を直接有機顔
料と有機溶剤を用いて着色被覆することは可能である。Instead of the coloring method according to the present invention, it is possible to directly color coat slaked lime powder using an organic pigment and an organic solvent.
しかしながら有機顔料による消石灰粉末の被覆効果が劣
るため、視覚上、同一着色濃度の着色品を製造するに数
チル数十チ多量の有機顔料を要し、有機溶剤の使用量も
本発明に係る方法よシ約２倍以上必要とし、有機溶剤の
回収と製品の乾燥のために別途加熱を要する。更に決定
的なことは、このような直接着色品に付着している有機
顔料は摩擦等によシ、着色が剥離しやすいことである。However, since the coating effect of the slaked lime powder with the organic pigment is poor, it takes several tens of tons of organic pigment to produce a colored product with the same visual color density, and the amount of organic solvent used is also lower than that of the method according to the present invention. It requires about twice as much water, and additional heating is required to recover the organic solvent and dry the product. What is more decisive is that organic pigments attached to such directly colored products are easily peeled off due to friction or the like.
このことは後述の標識用着色物としての効果を半減させ
るものである。This reduces the effect by half as a colored material for marking, which will be described later.
Ｂ６着色物の標識用としての用途
以上のようにして有機顔料で、完全かつ均一に被覆され
た本発明の標識用着色消石灰粉末（以下、標識用着色粉
末ということがある）が得られる。Use as a marker for B6 colored products As described above, the colored slaked lime powder for markers of the present invention (hereinafter sometimes referred to as colored powder for markers) completely and uniformly coated with an organic pigment is obtained.
本発明において標識用とは単なる目しるしを意味せず、
より広く他の部分若しくは、他の表示部分と区別して表
示出来る用途を意味する。この用途を分野別に説明する
。In the present invention, "for marking" does not mean a mere mark;
It refers to a wider range of uses in which display can be distinguished from other parts or other display parts. This application will be explained by field.
イ、地上表示用：
例えばスポーツグラウンド上の区切シ線は、消石灰粉末
による場合は、白色のみであったので段階的区別が困難
でありた。本発明品は赤色、青色等、自由に着色出来る
ので従来の白線の他に段階別に赤線、青線等を引くこと
が自由に出来る。B. For ground display: For example, when the dividing lines on a sports ground are made of slaked lime powder, they are only white, making it difficult to distinguish them in stages. Since the product of the present invention can be colored freely in red, blue, etc., in addition to the conventional white line, it is also possible to freely draw red lines, blue lines, etc. for each stage.
口１文具用：
本発明の標識用着色粉末に少量の水（及び必要に応じ少
量の糊剤）を加えてペースト状とし、筆等を用いて、壁
面（又は黒板）等に一時的な図形、文章等を表示出来る
。水の代ルに少量の油を加えたペーストとすることも出
来る。For stationery: Add a small amount of water (and a small amount of glue if necessary) to the colored powder for signs of the present invention to make a paste, and use a brush etc. to draw temporary figures on walls (or blackboards), etc. , text, etc. can be displayed. It can also be made into a paste by adding a small amount of oil to the water.
Ｊ＼ 建材用：
消石灰を主原料の一つとするしっくい壁は白色に仕上げ
られる。着色するには、更に別途、表面塗装を要する。J＼ For building materials: Plaster walls made from slaked lime as one of the main raw materials can be finished white. To color it, additional surface painting is required.
消石灰に代えて、本発明品を使用すれば、所望の色調の
着色壁を得ることが出来る。If the product of the present invention is used in place of slaked lime, a colored wall with a desired color tone can be obtained.
ニ、塗装用：
ペイント類は、油性であると、水性であるとを問わず高
価であシ、塗装自体も高度の熟練を要する。本発明品は
ペイント類に較べて、極めて安価であるから、水および
少量の添着剤と混合して懸濁物としブラシ、又はロール
で建築物の内外壁、天井等を一時的に塗装することは、
混合、塗装、およびその後の除去、共に熟練を要しない
から、一時的塗装用として便利である・ホ、肥料用：
消石灰は、作土の−Ｉ調整又は保水力維持等の目的で散
布される。うね状裁培の場合は、作物によシうね毎に消
石灰の散布量を区別したい場合もあシ得る。着色した本
発明の消石灰粉末は、白色の消石灰と散布量を区別し易
い。D. For painting: Paints, whether oil-based or water-based, are expensive, and the painting itself requires a high level of skill. The product of the present invention is extremely inexpensive compared to paints, so it can be mixed with water and a small amount of adhesive to form a suspension, and used to temporarily paint the interior and exterior walls, ceilings, etc. of buildings with a brush or roll. teeth,
Mixing, painting, and subsequent removal do not require any skill, so it is convenient for temporary painting. E. For fertilizer: Slaked lime is sprayed for the purpose of -I adjustment of cultivated soil or maintaining water holding capacity. . In the case of ridge-shaped culturing, it may be possible to differentiate the amount of slaked lime applied to each ridge depending on the crop. The colored slaked lime powder of the present invention can be easily distinguished from white slaked lime in terms of the amount of application.
へ、農薬用：
石灰、硫黄合剤のような水性スラリーを同時に数種類調
合して使用する場合、消石灰の色別に処方を決定してお
けば、散布時に混同するおそれがない。For agricultural chemicals: When preparing several types of aqueous slurry such as lime and sulfur mixtures at the same time, determining the formulation for each color of slaked lime eliminates the risk of confusion during spraying.
ト、製紙用：
着色紙用に消石灰を配合する場合、本発明品を使用すれ
ば、別途添加すべき顔料、または染料を節約し、又は使
用しないですむこととなる。G. For paper manufacturing: When blending slaked lime for colored paper, if the product of the present invention is used, pigments or dyes that should be added separately can be saved or not used.
以上のような用途は、すべて本発明品が無着色の消石灰
に較べて、著るしく高価でない場合に、はじめて経済的
に使用可能となるのである。All of the above uses can only be used economically if the product of the present invention is not significantly more expensive than uncolored slaked lime.
以下、製造例および使用例をもって、本発明を説明する
。The present invention will be explained below with reference to manufacturing examples and usage examples.
製造例１：
１９の布製顔料シアニンブルーＭＳ−４を５０ｄのメタ
ノールに溶解した後、４４μに粉砕した酸化石灰ｌＯＩ
にシアニンブルーの２チメチルアルコール溶液ｌＯｄと
水１０ｍの混合液を加えて混合攪拌し発熱乾燥させて青
色の消石灰粉末とする。Production Example 1: Lime oxide lOI which was prepared by dissolving 19 fabric pigment cyanine blue MS-4 in 50 d of methanol and then pulverizing it to 44μ
A mixture of lOd of 2-thimethyl alcohol solution of cyanine blue and 10m of water was added to the mixture, mixed and stirred, and dried with heat to form a blue slaked lime powder.
製造例２：
４４μに粉砕した酸化カルシウム粉末２０７９に０．２
１１のシアニンブルーＭＳ −４を加え、メタノール６
−を含むメタノール水１２−を加えて混合し、ペースト
状となしたる後、発熱して粉末となる迄攪拌して青色消
石灰粉末をする。Production example 2: Calcium oxide powder 2079 crushed to 44μ and 0.2
Add 11 cyanine blue MS-4 and methanol 6
Methanol water 12- containing - is added and mixed to form a paste, and stirred until it generates heat and becomes powder to form blue slaked lime powder.
製造例３：
５ｍ径に粉砕した酸化カルシウム１０＆に１ｇのシアニ
ンブルーＨａ −４を加えて、メタノール３−を含むメ
タノール水６ｄを加えて混合し、ペースト状となしたる
後発熱して粉末となる迄攪拌して青色消石灰とする。Production Example 3: Add 1 g of cyanine blue Ha-4 to calcium oxide 10& that has been crushed to a diameter of 5 m, add 6 d of methanol water containing methanol 3-, mix, form a paste, and then generate heat to form a powder. Stir until it becomes blue slaked lime.
製造例４：
１４９μに粉砕した酸化カルシウム１０Ｉに０．１Ｆの
シアニングリーン２ＧＮを加え、エタノール３ゴからな
るエタノール水６ｒＩＬｌを加えて混合し、ペースト状
となし、発熱して粉末状となる迄攪拌を続けて、緑色の
消石灰粉末を得る。Production Example 4: Add 0.1F cyanine green 2GN to 10I calcium oxide crushed to 149μ, add 6rILl of ethanol water consisting of 3g of ethanol, mix, form a paste, and stir until it generates heat and becomes a powder. Continue to obtain green slaked lime powder.
製造例５：
１４９μに粉砕した酸化カルシウム２０Ｉｉにセイカフ
ァーストレ、ド４Ｒ４０１６を０．２ ＩＩ加えて６ゴ
のメタノールを含むメタノール水１２−を加えて混合し
ペースト状となし、発熱して粉末状となる迄攪拌を続け
て赤色の消石灰粉末を得る。Production Example 5: To calcium oxide 20Ii ground to 149μ, add 0.2II of Seikafastre, Do 4R4016, add 12I of methanol water containing 6g of methanol, mix to form a paste, and heat to form a powder. Continue stirring until the red slaked lime powder is obtained.
使用例１：
製造例１と同一の方法で製造した着色消石灰粉末に水を
加えて１０％スラリーとし、スポーツ標識用線引き器に
入れ、灰白色のコンクリート床上に仕切シ線を引いた。Use Example 1: Water was added to the colored slaked lime powder produced in the same manner as in Production Example 1 to make a 10% slurry, and the slurry was placed in a sports sign liner to draw partition lines on a gray-white concrete floor.
この仕切線は、無着色の消石灰スラリーで同様に引いた
ものよりも識別性良好であった。This partition line had better distinguishability than one similarly drawn with uncolored slaked lime slurry.
使用例２：
田畑の土壌改良剤として従来よシ消石灰を散布する土の
アルカリ度調節があるが、土地を一定面積に区切りて着
色消石灰の量を調節して散布、すれば赤色の場所、青色
の場所と夫々色別に土壌の声調節が可能である。無着色
の消石灰では散布量を変えても区別かつかづ声調節が困
難であった。Usage example 2: Conventionally, as a soil conditioner for fields, slaked lime is applied to adjust the alkalinity of the soil, but if the land is divided into certain areas and the amount of colored slaked lime is adjusted and sprayed, areas will be red and blue. It is possible to adjust the tone of the soil depending on the location and color. With uncolored slaked lime, it was difficult to differentiate and control the vocalizations even if the amount of spray was changed.
使用例３：
水害後の床下消毒等に消石灰を二・三回散布する際に着
色消石灰粉末であれば色別に散布日時の確認が出来たが
、無着色消石灰では困難であった。Usage Example 3: When spraying slaked lime two or three times for underfloor disinfection after water damage, if colored slaked lime powder was used, the date and time of spraying could be confirmed by color, but this was difficult with uncolored slaked lime.
使用例４：
使用例１と同一の方法で保育園のグラウンドで仕切シ線
を引いたところ園児は無着色のラインよシも着色消石灰
の方を好み従来より活発な動作をする園児が増大した。Usage Example 4: When dividing lines were drawn on the playground of a nursery school using the same method as in Usage Example 1, the children preferred colored slaked lime over uncolored lines, and more children were active than before.
使用例５：
着色消石灰の１０チスラリーに少量の糊剤を加えてスプ
レーでコンクリートモルタル壁面に吹きつけた処、特に
色調に富み彩色性が非常に良好であった。Use Example 5: When a small amount of sizing agent was added to a 10-thi slurry of colored slaked lime and sprayed onto a concrete mortar wall, the color tone was particularly rich and the colorability was very good.
使用例６：
建築物の合壁に用いる時、塗布時に無着色消石灰に顔料
を混合して色合せをするが、本発明の着色消灰は色合せ
の必要がなく、消石灰のアルカリによる褪色もなかった
。Usage Example 6: When used for joint walls of buildings, pigments are mixed with uncolored slaked lime during application to match the color, but the colored slaked ash of the present invention does not require color matching and does not fade due to the alkali of slaked lime. There wasn't.
代理人 弁理士 野 中 克 彦Agent Patent Attorney Katsuhiko Nonaka
Claims (2)
．１〜ｌＯ重量−の有機顔料、該酸化カルシウムと当量
の水および前記有機顔料を溶解出来、かつ、前記水とほ
ぼ同量の水溶性有機溶剤を混合し、該酸化カルシウム粉
末と水との水利反応熱によシ生成した着色物を乾燥せし
めてなる標識用着色消石灰粉末。(1) Calcium oxide powder with a particle size of 44μ~mm
．． 1 to 10% by weight of an organic pigment, water in an equivalent amount to the calcium oxide, and a water-soluble organic solvent that can dissolve the organic pigment and are approximately the same amount as the water, and the calcium oxide powder and water are mixed together. Colored slaked lime powder for labeling, made by drying the colored material produced by reaction heat.
リーン、ファーストレッドおよびモノアゾ系色素ハンプ
から選ばれた一以上のものを使用する特許請求の範囲第
（１）項に記載の消石灰粉末。(2) The slaked lime powder according to claim (1), wherein one or more organic pigments selected from cyanine blue, cyanine green, fast red, and monoazo pigment Hump are used.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP16176483A JPS6053568A (en) | 1983-09-02 | 1983-09-02 | Colored slaked lime powder for marking use |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP16176483A JPS6053568A (en) | 1983-09-02 | 1983-09-02 | Colored slaked lime powder for marking use |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6053568A true JPS6053568A (en) | 1985-03-27 |
| JPS6154825B2 JPS6154825B2 (en) | 1986-11-25 |
Family
ID=15741446
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP16176483A Granted JPS6053568A (en) | 1983-09-02 | 1983-09-02 | Colored slaked lime powder for marking use |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6053568A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2014109330A1 (en) * | 2013-01-10 | 2014-07-17 | 宇部マテリアルズ株式会社 | Water absorbent and method for producing same |
-
1983
- 1983-09-02 JP JP16176483A patent/JPS6053568A/en active Granted
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2014109330A1 (en) * | 2013-01-10 | 2014-07-17 | 宇部マテリアルズ株式会社 | Water absorbent and method for producing same |
| JP2014147927A (en) * | 2013-01-10 | 2014-08-21 | Ube Material Industries Ltd | Moisture adsorbent and method for producing the same |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6154825B2 (en) | 1986-11-25 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN100378177C (en) | Color compositions | |
| JP2009001790A5 (en) | ||
| CA2393425C (en) | Organic pigment dispersion for coloring building materials | |
| JPS6053568A (en) | Colored slaked lime powder for marking use | |
| US6201050B1 (en) | Breakable gel additive carrier for ionic compositions | |
| US2547042A (en) | Coated mineral granule, method of making same, and roofing material surfaced therewith | |
| JP2019038905A (en) | Colored aggregate-containing multicolor coating material | |
| JP2001288415A (en) | Water-based matte coating composition and matte coating method | |
| GB2089827A (en) | Transfer papers | |
| JPH07503038A (en) | Single color or multicolor water-based paint | |
| MX2007009607A (en) | Chromophore coating systems, especially paints and lacquers. | |
| WO2018112753A1 (en) | Multicolor paint composition | |
| JPH0115539B2 (en) | ||
| JP2018193526A (en) | Aqueous multi-color coating composition | |
| US1935769A (en) | Glue or gelatine coating composition | |
| DE543894C (en) | Colored plaster mortar | |
| CN109233485A (en) | A kind of water-soluble colorful coating and preparation method thereof | |
| JPS62100562A (en) | Wall material composition and production thereof | |
| JPS5848592B2 (en) | Method for manufacturing wall covering material with metallic luster | |
| US1106298A (en) | Colored cement structure and process of making same. | |
| NO124212B (en) | ||
| EP1401783B1 (en) | Breakable gel additive carrier for ionic compositions | |
| JPS6022021B2 (en) | Method for manufacturing wall covering material with metallic luster | |
| JPH01104663A (en) | Azo pigment composition for gravure ink | |
| US1145370A (en) | Method for producing manure. |