JPS6053525A - Resin composition for impregnation of motor coil for freezer - Google Patents
Resin composition for impregnation of motor coil for freezerInfo
- Publication number
- JPS6053525A JPS6053525A JP16218783A JP16218783A JPS6053525A JP S6053525 A JPS6053525 A JP S6053525A JP 16218783 A JP16218783 A JP 16218783A JP 16218783 A JP16218783 A JP 16218783A JP S6053525 A JPS6053525 A JP S6053525A
- Authority
- JP
- Japan
- Prior art keywords
- resin
- weight
- parts
- resin composition
- epoxy resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Manufacture Of Motors, Generators (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Epoxy Resins (AREA)
- Paints Or Removers (AREA)
- Organic Insulating Materials (AREA)
Abstract
Description
【発明の詳細な説明】
本発明は、冷凍機用モードルコイル含浸用樹脂組成物Ｃ
以下ワニスと略す）に関する。DETAILED DESCRIPTION OF THE INVENTION The present invention provides a resin composition C for impregnating modele coils for refrigerators.
(hereinafter abbreviated as varnish).
ビスフェノールＡとエピクロルヒドリンから得られる分
子内に少なくとも１個のエポキシ基を有するエポキシ樹
脂（以下エポキシ樹脂と略す。）とレゾール型フェノー
ル樹脂（以下フェノール樹脂と略す。）をキシレン、第
１級アルコール及び第２級アルコールの混合溶媒に溶解
したワニスは耐冷媒性に優れているため、冷凍機用モー
ドルのコイル含浸用ワニスとして使用されているが、優
れた耐冷媒性を得るためにはワニス（ｚ １３０〜１４
０Ｃで約１０〜１５時間乾燥させる必要があり、生産性
、省エネルギー化の点から、ワニスの乾燥時間の短縮化
が望まれていた。An epoxy resin having at least one epoxy group in the molecule obtained from bisphenol A and epichlorohydrin (hereinafter referred to as epoxy resin) and a resol type phenol resin (hereinafter referred to as phenol resin) are combined with xylene, a primary alcohol and a Varnish dissolved in a mixed solvent of secondary alcohol has excellent refrigerant resistance, so it is used as a varnish for impregnating the coils of refrigerator molds. ~14
It is necessary to dry the varnish for about 10 to 15 hours at 0C, and from the viewpoint of productivity and energy saving, it has been desired to shorten the drying time of the varnish.
本発明者はエポキシ樹脂、フェノール樹脂及び有機溶剤
からなるワニスの乾轡賄間の短縮化を目的に種々検討し
た結果、イミダゾール化片物を添加することにより、ワ
ニスの乾燥時間ｔｌ／３〜１／４に短縮化することを見
出した。As a result of various studies aimed at shortening the drying time of varnishes made of epoxy resins, phenolic resins, and organic solvents, the present inventor found that by adding imidazolized flakes, the drying time of varnishes ranged from tl/3 to 1. It was found that the time can be shortened to /4.
木兄ＥＪ４は、エポキシ樹脂１００重量部、フェノール
樹脂１０〜７０重量部及び一般式
ｎｃ＝ｃ ｎ、１
１１
２
（Ｒ１はＨまたは炭素数１〜３のアルキル基でありＲ２
は炭素数１〜１１のアルキル基またはＣ６１−ＩＳ基で
ある）で示されるイミダゾール化合物０，３〜１０重量
部を含有してなる冷凍機用モードルコイル含浸用ワニス
に関する。Kinoe EJ4 contains 100 parts by weight of epoxy resin, 10 to 70 parts by weight of phenol resin, and the general formula nc=c n, 1 11 2 (R1 is H or an alkyl group having 1 to 3 carbon atoms, and R2
is an alkyl group having 1 to 11 carbon atoms or a C61-IS group.
本発明においてビスフェノールＡとエピクロルヒドリン
から得られる分子内に少なくともｌ 蘭のエポキシ基を
有するエポキシ樹脂としてはエピコート８２８，１００
１．１００４．１００７（いずれもシェル化学社製）等
が用いられる。In the present invention, the epoxy resin having at least 1 epoxy group in the molecule obtained from bisphenol A and epichlorohydrin is Epicote 828,100.
1.1004.1007 (all manufactured by Shell Chemical Co., Ltd.), etc. are used.
フェノール樹脂としてはＰＲ−４０１０，ＰＲ−４０２
０、ＰＲ−５２０，ＰＲ−３３０５（日立化成工業株式
会社製）ｉが用いられる。上記の一般式で示されるイミ
ダゾール化合物としては、ギコーアゾール２ＭＺ−ＣＮ
、２Ｅ４ＭＺ−ＣＮ、２ＩＺ−ＣＮ、２ＰＺ−ＣＮ（い
ずれも四国化成工業株式会社製）等が用いられる。また
、これらを溶解する有機溶剤としてはエポキシ樹脂とフ
ェノール樹脂の双方を溶解しやすいことが必要なため、
好ましくは、キシレン、トルエン、ｎ−ブタノール、ニ
ーブタノール、を−ブタノール等が混合されて用いられ
る。PR-4010, PR-402 as phenolic resin
0, PR-520, PR-3305 (manufactured by Hitachi Chemical Co., Ltd.) i are used. As the imidazole compound represented by the above general formula, gycoazole 2MZ-CN
, 2E4MZ-CN, 2IZ-CN, 2PZ-CN (all manufactured by Shikoku Kasei Kogyo Co., Ltd.), etc. are used. In addition, the organic solvent that dissolves these needs to be able to easily dissolve both epoxy resin and phenol resin.
Preferably, a mixture of xylene, toluene, n-butanol, n-butanol, n-butanol, etc. is used.
本発明においてはエポキシ樹脂１００重量部に対してフ
ェノール樹脂を１０〜７０重量部、上記の一般式で示さ
れるイミダゾール化合物を０，３〜ｚＯｆｆｉ量部の範
囲で用いることが必要である。フェノール樹脂が１０重
量部未満ではワニスの接着力が劣り、７０重量部を越え
るとワニスの耐冷媒性が劣りまた、イミダゾール化合物
’ｌ： ０．３重量部未満とした場合や１０重量部を越
える量とした場合には乾燥時間の短縮化の効果が小さい
からである。本発明の詳細な説明する。In the present invention, it is necessary to use 10 to 70 parts by weight of the phenol resin and 0.3 to zOffi parts of the imidazole compound represented by the above general formula to 100 parts by weight of the epoxy resin. If the phenolic resin is less than 10 parts by weight, the adhesive strength of the varnish will be poor; if it exceeds 70 parts by weight, the varnish will have poor refrigerant resistance; and if the imidazole compound is less than 0.3 parts by weight or if it exceeds 10 parts by weight This is because the effect of shortening the drying time is small when it is expressed as a quantity. The present invention will be described in detail.
実施例１〜６
エビコー） １００１ （エポキシ樹脂）、ＰＲ−４０
２０（フェノール樹脂）、キュアゾール２Ｅ４ＭＺ−Ｃ
Ｎ （イミダゾール化合物）、キシレン、ｎ−フリノー
ルを表１に示す割合で配合した樹脂組成物の（１）粘度
、（２）塗膜の乾燥性及び乾燥時間を変えて、（３）接
着力、（４）耐冷媒性を評価した。Examples 1 to 6 Ebiko) 1001 (epoxy resin), PR-40
20 (phenol resin), Curesol 2E4MZ-C
By changing (1) viscosity, (2) drying properties and drying time of the coating film, (3) adhesive strength, (4) Refrigerant resistance was evaluated.
結果を表１に示す。The results are shown in Table 1.
実施例７〜８
エピコート１００１１Ｐ几−４０２０、キュアゾール（
イミダゾール化合物）２ＰＺ−ＣＮ、キシレン、ｎ−ブ
タノールを表１に示す割合で配合し、実施例１〜６と同
様にして評価した。Examples 7-8 Epicote 10011P-4020, Curezol (
Imidazole compound) 2PZ-CN, xylene, and n-butanol were blended in the proportions shown in Table 1, and evaluated in the same manner as in Examples 1 to 6.
比較例
エピコート１００１．ＰＲ−４０２０、キシレン、ｎ−
ブタノールを表１に示す割合で配合し上記の実施例と同
様にして評価した。Comparative Example Epicoat 1001. PR-4020, xylene, n-
Butanol was blended in the proportions shown in Table 1 and evaluated in the same manner as in the above examples.
ム
（試験方法）
（］） 粘度
東京計器製ＢＬ型回転粘度計を用いて、２５Ｃで測定し
た。(Test method) (]) Viscosity Measured at 25C using a BL type rotational viscometer manufactured by Tokyo Keiki.
（２） 塗膜の乾燥性
５０Ｘ１００Ｘ０．３ ｔｍ＋ｎ のステンレス板にワ
ニスを塗布したあと、１２０ｃに放置し、乾燥時間を指
触によって測定した。(2) Drying property of coating film After applying varnish to a stainless steel plate of 50 x 100 x 0.3 tm+n, the plate was left at 120°C and the drying time was measured by touch.
（３） 接着力
直径１．０胴のホルマール線でＪＩＳＣ２１０３に準じ
て、ヘリカルコイルを作成し、ワニス′ｆ：２回処理（
１回目：１３５０／１時間、２回目：１３５Ｃ／２〜１
５時間）したあと、島津製作所製オートグラフＩＭ−１
０Ｑ型を用いて、２３Ｃの雰囲気での接着力を測定した
。(3) Adhesive strength A helical coil was made using a formal wire with a diameter of 1.0 in accordance with JISC2103, and treated with varnish 'f: 2 times (
1st time: 1350/1 hour, 2nd time: 135C/2~1
After 5 hours), use the Shimadzu Autograph IM-1
Adhesive strength was measured in a 23C atmosphere using a 0Q type.
（４）耐冷媒性
５０Ｘ１００Ｘ０．３Ｌｍ のステンレス板にワニスを
２回処理（１回目＋１３５Ｃ／１時間、２回目：１３５
Ｃ／２〜１５時間）したものを試験片とした。(4) Refrigerant resistance 50x100x0.3Lm stainless steel plate is treated with varnish twice (first time +135C/1 hour, second time: 135C/1 hour)
C/2 to 15 hours) was used as a test piece.
この試験片を内容積１ｔのステンレス製耐圧容器（以下
オートクレーブと略す。）に入れ、冷凍機油（昭和石油
製、ナ１５０）３００ｇを加え、オートクレーブを密封
し、冷凍機油に含まれる水分を真空脱水（１０−ＯＣ，
ｌ咽Ｈｇ；１時間計し冷却後さらに７レオンガスＲ，−
２２（アサヒフロン製）３００ｇを加えて密封した。密
封したオートクレーブを１１０Ｃで１２０時間放置後、
尾部まで冷却したあと開封し、試験片を取出して、付着
した冷凍機油をガソリンで５回洗浄した。洗浄した試験
片を１３０７：で３０分加熱後、試験片の重量を測定し
、抽出率を算出した。This test piece was placed in a stainless steel pressure-resistant container (hereinafter referred to as an autoclave) with an internal volume of 1 ton, 300 g of refrigeration oil (Na150, manufactured by Showa Sekiyu) was added, the autoclave was sealed, and the moisture contained in the refrigeration oil was vacuum dehydrated. (10-OC,
l Throat Hg; Measured for 1 hour, cooled, and then added 7 Leon gas R, -
300 g of No. 22 (manufactured by Asahi Flon) was added and sealed. After leaving the sealed autoclave at 110C for 120 hours,
After cooling down to the tail, the test piece was opened, the test piece was taken out, and the attached refrigerating machine oil was washed five times with gasoline. After heating the washed test piece at 1307: for 30 minutes, the weight of the test piece was measured and the extraction rate was calculated.
表１に示されるように、本発明になるコイル含浸用樹脂
組成物を用いることにより、従来の樹脂組成物に比収し
て約１／３の時間でワニス乾燥させることが可能である
。As shown in Table 1, by using the resin composition for coil impregnation according to the present invention, it is possible to dry a varnish in about 1/3 of the time compared to conventional resin compositions.
代理人 弁理士 若林邦彦Agent Patent Attorney Kunihiko Wakabayashi
Claims (1)
分子内に少なくとも１個のエポキシ基を有するエポキシ
樹脂１００重量部、レゾール型ノエノール栃脂ｌＯ〜７
０重量部、および一般式（几ｌは１１または炭素数１〜
３のアルキル基でるり几２は炭素数１〜１１のアルキル
基またはＣ６１１５基である）で示されるイミダゾール
化合物０．３〜１０重量部を含有してなる冷凍機用モー
ドルフィル含浸用樹脂組成物。/ 100 parts by weight of an epoxy resin containing at least one epoxy group in the molecule containing bisphenol A and epichlorohydrin, resol type Noenol Tochi resin lO~7
0 parts by weight, and the general formula (⇠l is 11 or carbon number 1 to
A resin composition for impregnating a mold fill for a refrigerator containing 0.3 to 10 parts by weight of an imidazole compound represented by the alkyl group of 3 and 2 being an alkyl group having 1 to 11 carbon atoms or a C6115 group. thing.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP16218783A JPS6053525A (en) | 1983-09-02 | 1983-09-02 | Resin composition for impregnation of motor coil for freezer |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP16218783A JPS6053525A (en) | 1983-09-02 | 1983-09-02 | Resin composition for impregnation of motor coil for freezer |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6053525A true JPS6053525A (en) | 1985-03-27 |
| JPS6348909B2 JPS6348909B2 (en) | 1988-10-03 |
Family
ID=15749656
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP16218783A Granted JPS6053525A (en) | 1983-09-02 | 1983-09-02 | Resin composition for impregnation of motor coil for freezer |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6053525A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60228529A (en) * | 1984-03-31 | 1985-11-13 | ヘキスト・アクチエンゲゼルシヤフト | Mixture for manufacturing acid-resistant filler or impregnating agent, manufacture and use |
| JPH01266127A (en) * | 1988-04-18 | 1989-10-24 | Hitachi Chem Co Ltd | Electrical insulating resin composition |
| US5017258A (en) * | 1986-06-20 | 1991-05-21 | Shell Oil Company | Pipe rehabilitation using epoxy resin composition |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5313239A (en) * | 1976-07-22 | 1978-02-06 | Furukawa Electric Co Ltd:The | Manufacturing process of laminated electrical heat plate |
| JPS6051716A (en) * | 1983-08-31 | 1985-03-23 | Hitachi Chem Co Ltd | Resin composition for use in refrigerator motor coil |
-
1983
- 1983-09-02 JP JP16218783A patent/JPS6053525A/en active Granted
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5313239A (en) * | 1976-07-22 | 1978-02-06 | Furukawa Electric Co Ltd:The | Manufacturing process of laminated electrical heat plate |
| JPS6051716A (en) * | 1983-08-31 | 1985-03-23 | Hitachi Chem Co Ltd | Resin composition for use in refrigerator motor coil |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60228529A (en) * | 1984-03-31 | 1985-11-13 | ヘキスト・アクチエンゲゼルシヤフト | Mixture for manufacturing acid-resistant filler or impregnating agent, manufacture and use |
| US5017258A (en) * | 1986-06-20 | 1991-05-21 | Shell Oil Company | Pipe rehabilitation using epoxy resin composition |
| JPH01266127A (en) * | 1988-04-18 | 1989-10-24 | Hitachi Chem Co Ltd | Electrical insulating resin composition |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6348909B2 (en) | 1988-10-03 |
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