JPS6029402A - Manufacture of colored aluminum powder - Google Patents
Manufacture of colored aluminum powderInfo
- Publication number
- JPS6029402A JPS6029402A JP58137313A JP13731383A JPS6029402A JP S6029402 A JPS6029402 A JP S6029402A JP 58137313 A JP58137313 A JP 58137313A JP 13731383 A JP13731383 A JP 13731383A JP S6029402 A JPS6029402 A JP S6029402A
- Authority
- JP
- Japan
- Prior art keywords
- same
- hydroxide
- aluminum powder
- parts
- dye
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 title claims description 37
- 238000004519 manufacturing process Methods 0.000 title claims description 7
- 239000000975 dye Substances 0.000 claims abstract description 14
- 125000000129 anionic group Chemical group 0.000 claims abstract description 9
- 238000004043 dyeing Methods 0.000 claims abstract description 9
- RQPZNWPYLFFXCP-UHFFFAOYSA-L barium dihydroxide Chemical compound [OH-].[OH-].[Ba+2] RQPZNWPYLFFXCP-UHFFFAOYSA-L 0.000 claims abstract description 6
- 229910001863 barium hydroxide Inorganic materials 0.000 claims abstract description 6
- IVORCBKUUYGUOL-UHFFFAOYSA-N 1-ethynyl-2,4-dimethoxybenzene Chemical compound COC1=CC=C(C#C)C(OC)=C1 IVORCBKUUYGUOL-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000000980 acid dye Substances 0.000 claims abstract description 4
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims abstract description 4
- 239000000982 direct dye Substances 0.000 claims abstract description 4
- 239000000983 mordant dye Substances 0.000 claims abstract description 4
- 229940049676 bismuth hydroxide Drugs 0.000 claims abstract description 3
- TZSXPYWRDWEXHG-UHFFFAOYSA-K bismuth;trihydroxide Chemical compound [OH-].[OH-].[OH-].[Bi+3] TZSXPYWRDWEXHG-UHFFFAOYSA-K 0.000 claims abstract description 3
- PLLZRTNVEXYBNA-UHFFFAOYSA-L cadmium hydroxide Chemical compound [OH-].[OH-].[Cd+2] PLLZRTNVEXYBNA-UHFFFAOYSA-L 0.000 claims abstract description 3
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims abstract description 3
- 239000000347 magnesium hydroxide Substances 0.000 claims abstract description 3
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims abstract description 3
- UGZADUVQMDAIAO-UHFFFAOYSA-L zinc hydroxide Chemical compound [OH-].[OH-].[Zn+2] UGZADUVQMDAIAO-UHFFFAOYSA-L 0.000 claims abstract description 3
- 229910021511 zinc hydroxide Inorganic materials 0.000 claims abstract description 3
- 229940007718 zinc hydroxide Drugs 0.000 claims abstract description 3
- 229910000000 metal hydroxide Inorganic materials 0.000 claims description 6
- 150000004692 metal hydroxides Chemical class 0.000 claims description 6
- 239000000049 pigment Substances 0.000 claims description 5
- 230000002378 acidificating effect Effects 0.000 claims description 3
- SJEYSFABYSGQBG-UHFFFAOYSA-M Patent blue Chemical compound [Na+].C1=CC(N(CC)CC)=CC=C1C(C=1C(=CC(=CC=1)S([O-])(=O)=O)S([O-])(=O)=O)=C1C=CC(=[N+](CC)CC)C=C1 SJEYSFABYSGQBG-UHFFFAOYSA-M 0.000 claims description 2
- 229910052751 metal Inorganic materials 0.000 abstract description 8
- 239000002184 metal Substances 0.000 abstract description 8
- 239000000843 powder Substances 0.000 abstract description 6
- 239000002253 acid Substances 0.000 abstract description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 abstract description 5
- 238000000034 method Methods 0.000 abstract description 4
- 238000000151 deposition Methods 0.000 abstract description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 15
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 12
- 239000002932 luster Substances 0.000 description 7
- 235000019646 color tone Nutrition 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- 239000007864 aqueous solution Substances 0.000 description 5
- 150000003839 salts Chemical class 0.000 description 5
- 229910052782 aluminium Inorganic materials 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 235000011121 sodium hydroxide Nutrition 0.000 description 4
- 239000000126 substance Substances 0.000 description 3
- STOOUUMSJPLRNI-UHFFFAOYSA-N 5-amino-4-hydroxy-3-[[4-[4-[(4-hydroxyphenyl)diazenyl]phenyl]phenyl]diazenyl]-6-[(4-nitrophenyl)diazenyl]naphthalene-2,7-disulfonic acid Chemical compound OS(=O)(=O)C1=CC2=CC(S(O)(=O)=O)=C(N=NC=3C=CC(=CC=3)C=3C=CC(=CC=3)N=NC=3C=CC(O)=CC=3)C(O)=C2C(N)=C1N=NC1=CC=C([N+]([O-])=O)C=C1 STOOUUMSJPLRNI-UHFFFAOYSA-N 0.000 description 2
- RGCKGOZRHPZPFP-UHFFFAOYSA-N Alizarin Natural products C1=CC=C2C(=O)C3=C(O)C(O)=CC=C3C(=O)C2=C1 RGCKGOZRHPZPFP-UHFFFAOYSA-N 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 2
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- HFVAFDPGUJEFBQ-UHFFFAOYSA-M alizarin red S Chemical compound [Na+].O=C1C2=CC=CC=C2C(=O)C2=C1C=C(S([O-])(=O)=O)C(O)=C2O HFVAFDPGUJEFBQ-UHFFFAOYSA-M 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 239000012670 alkaline solution Substances 0.000 description 2
- MWPLVEDNUUSJAV-UHFFFAOYSA-N anthracene Chemical compound C1=CC=CC2=CC3=CC=CC=C3C=C21 MWPLVEDNUUSJAV-UHFFFAOYSA-N 0.000 description 2
- PWHCIQQGOQTFAE-UHFFFAOYSA-L barium chloride dihydrate Chemical compound O.O.[Cl-].[Cl-].[Ba+2] PWHCIQQGOQTFAE-UHFFFAOYSA-L 0.000 description 2
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 2
- 239000000920 calcium hydroxide Substances 0.000 description 2
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 2
- 230000008878 coupling Effects 0.000 description 2
- 238000010168 coupling process Methods 0.000 description 2
- 238000005859 coupling reaction Methods 0.000 description 2
- 150000002894 organic compounds Chemical class 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- 238000010298 pulverizing process Methods 0.000 description 2
- 239000001054 red pigment Substances 0.000 description 2
- 229920003002 synthetic resin Polymers 0.000 description 2
- 239000000057 synthetic resin Substances 0.000 description 2
- 235000012756 tartrazine Nutrition 0.000 description 2
- UJMBCXLDXJUMFB-GLCFPVLVSA-K tartrazine Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)C1=NN(C=2C=CC(=CC=2)S([O-])(=O)=O)C(=O)C1\N=N\C1=CC=C(S([O-])(=O)=O)C=C1 UJMBCXLDXJUMFB-GLCFPVLVSA-K 0.000 description 2
- 239000004149 tartrazine Substances 0.000 description 2
- FFRBMBIXVSCUFS-UHFFFAOYSA-N 2,4-dinitro-1-naphthol Chemical compound C1=CC=C2C(O)=C([N+]([O-])=O)C=C([N+]([O-])=O)C2=C1 FFRBMBIXVSCUFS-UHFFFAOYSA-N 0.000 description 1
- XNDZQQSKSQTQQD-UHFFFAOYSA-N 3-methylcyclohex-2-en-1-ol Chemical compound CC1=CC(O)CCC1 XNDZQQSKSQTQQD-UHFFFAOYSA-N 0.000 description 1
- AOMZHDJXSYHPKS-DROYEMJCSA-L Amido Black 10B Chemical compound [Na+].[Na+].[O-]S(=O)(=O)C1=CC2=CC(S([O-])(=O)=O)=C(\N=N\C=3C=CC=CC=3)C(O)=C2C(N)=C1\N=N\C1=CC=C(N(=O)=O)C=C1 AOMZHDJXSYHPKS-DROYEMJCSA-L 0.000 description 1
- 229910001369 Brass Inorganic materials 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- FOGVNFMUZXDMTR-UHFFFAOYSA-N [Mg].Cl Chemical compound [Mg].Cl FOGVNFMUZXDMTR-UHFFFAOYSA-N 0.000 description 1
- DGOBMKYRQHEFGQ-UHFFFAOYSA-L acid green 5 Chemical compound [Na+].[Na+].C=1C=C(C(=C2C=CC(C=C2)=[N+](CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C=2C=CC(=CC=2)S([O-])(=O)=O)C=CC=1N(CC)CC1=CC=CC(S([O-])(=O)=O)=C1 DGOBMKYRQHEFGQ-UHFFFAOYSA-L 0.000 description 1
- 229910001854 alkali hydroxide Inorganic materials 0.000 description 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- WXLFIFHRGFOVCD-UHFFFAOYSA-L azophloxine Chemical compound [Na+].[Na+].OC1=C2C(NC(=O)C)=CC(S([O-])(=O)=O)=CC2=CC(S([O-])(=O)=O)=C1N=NC1=CC=CC=C1 WXLFIFHRGFOVCD-UHFFFAOYSA-L 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 1
- 239000001055 blue pigment Substances 0.000 description 1
- 239000010951 brass Substances 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- QHFQAJHNDKBRBO-UHFFFAOYSA-L calcium chloride hexahydrate Chemical compound O.O.O.O.O.O.[Cl-].[Cl-].[Ca+2] QHFQAJHNDKBRBO-UHFFFAOYSA-L 0.000 description 1
- 239000003518 caustics Substances 0.000 description 1
- 239000013522 chelant Substances 0.000 description 1
- DXRWYIKGBIPGAG-UHFFFAOYSA-M chembl2028375 Chemical compound [Na+].[O-][N+](=O)C1=CC=C2C(N=NC3=C4C=CC=CC4=CC=C3O)=C(O)C=C(S([O-])(=O)=O)C2=C1 DXRWYIKGBIPGAG-UHFFFAOYSA-M 0.000 description 1
- BPHHNXJPFPEJOF-UHFFFAOYSA-J chembl296966 Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]S(=O)(=O)C1=CC(S([O-])(=O)=O)=C(N)C2=C(O)C(N=NC3=CC=C(C=C3OC)C=3C=C(C(=CC=3)N=NC=3C(=C4C(N)=C(C=C(C4=CC=3)S([O-])(=O)=O)S([O-])(=O)=O)O)OC)=CC=C21 BPHHNXJPFPEJOF-UHFFFAOYSA-J 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- SJHUQGQHKBUYQV-UHFFFAOYSA-L dichlorocadmium;dihydrate Chemical compound O.O.Cl[Cd]Cl SJHUQGQHKBUYQV-UHFFFAOYSA-L 0.000 description 1
- VHGDEGWDHMWQLR-UHFFFAOYSA-L disodium 5-[[4-[4-[(2,6-diamino-3-methyl-5-sulfophenyl)diazenyl]-3-methylphenyl]-2-methylphenyl]diazenyl]-2-oxidobenzoate Chemical compound CC1=CC(=C(C(=C1N)N=NC2=C(C=C(C=C2)C3=CC(=C(C=C3)N=NC4=CC(=C(C=C4)[O-])C(=O)[O-])C)C)N)S(=O)(=O)O.[Na+].[Na+] VHGDEGWDHMWQLR-UHFFFAOYSA-L 0.000 description 1
- HRMOLDWRTCFZRP-UHFFFAOYSA-L disodium 5-acetamido-3-[(4-acetamidophenyl)diazenyl]-4-hydroxynaphthalene-2,7-disulfonate Chemical compound [Na+].OC1=C(C(=CC2=CC(=CC(=C12)NC(C)=O)S(=O)(=O)[O-])S(=O)(=O)[O-])N=NC1=CC=C(C=C1)NC(C)=O.[Na+] HRMOLDWRTCFZRP-UHFFFAOYSA-L 0.000 description 1
- NJPXFJXCALXJCX-UHFFFAOYSA-L disodium 7-anilino-3-[[4-[(2,4-dimethyl-6-sulfonatophenyl)diazenyl]-2,5-dimethylphenyl]diazenyl]-4-hydroxynaphthalene-2-sulfonate Chemical compound [Na+].[Na+].Cc1cc(C)c(N=Nc2cc(C)c(cc2C)N=Nc2c(O)c3ccc(Nc4ccccc4)cc3cc2S([O-])(=O)=O)c(c1)S([O-])(=O)=O NJPXFJXCALXJCX-UHFFFAOYSA-L 0.000 description 1
- NJDNXYGOVLYJHP-UHFFFAOYSA-L disodium;2-(3-oxido-6-oxoxanthen-9-yl)benzoate Chemical compound [Na+].[Na+].[O-]C(=O)C1=CC=CC=C1C1=C2C=CC(=O)C=C2OC2=CC([O-])=CC=C21 NJDNXYGOVLYJHP-UHFFFAOYSA-L 0.000 description 1
- VTEBSADXXKSKOE-UHFFFAOYSA-L disodium;4-[[2,4-diamino-5-[[3-[[2,4-diamino-5-[(4-sulfonatophenyl)diazenyl]phenyl]diazenyl]phenyl]diazenyl]phenyl]diazenyl]benzenesulfonate Chemical compound [Na+].[Na+].NC1=CC(N)=C(N=NC=2C=C(C=CC=2)N=NC=2C(=CC(N)=C(N=NC=3C=CC(=CC=3)S([O-])(=O)=O)C=2)N)C=C1N=NC1=CC=C(S([O-])(=O)=O)C=C1 VTEBSADXXKSKOE-UHFFFAOYSA-L 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 239000001056 green pigment Substances 0.000 description 1
- 239000000976 ink Substances 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- CTIQLGJVGNGFEW-UHFFFAOYSA-L naphthol yellow S Chemical compound [Na+].[Na+].C1=C(S([O-])(=O)=O)C=C2C([O-])=C([N+]([O-])=O)C=C([N+]([O-])=O)C2=C1 CTIQLGJVGNGFEW-UHFFFAOYSA-L 0.000 description 1
- IZMJMCDDWKSTTK-UHFFFAOYSA-N quinoline yellow Chemical compound C1=CC=CC2=NC(C3C(C4=CC=CC=C4C3=O)=O)=CC=C21 IZMJMCDDWKSTTK-UHFFFAOYSA-N 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- WPPDXAHGCGPUPK-UHFFFAOYSA-N red 2 Chemical compound C1=CC=CC=C1C(C1=CC=CC=C11)=C(C=2C=3C4=CC=C5C6=CC=C7C8=C(C=9C=CC=CC=9)C9=CC=CC=C9C(C=9C=CC=CC=9)=C8C8=CC=C(C6=C87)C(C=35)=CC=2)C4=C1C1=CC=CC=C1 WPPDXAHGCGPUPK-UHFFFAOYSA-N 0.000 description 1
- 235000012739 red 2G Nutrition 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- ZHFPEICFUVWJIS-UHFFFAOYSA-M sodium 2-hydroxy-5-[(3-nitrophenyl)diazenyl]benzoate Chemical compound [Na+].Oc1ccc(cc1C([O-])=O)N=Nc1cccc(c1)[N+]([O-])=O ZHFPEICFUVWJIS-UHFFFAOYSA-M 0.000 description 1
- BQHRKYUXVHKLLZ-UHFFFAOYSA-M sodium 7-amino-2-[[4-[(4-aminophenyl)diazenyl]-2-methoxy-5-methylphenyl]diazenyl]-3-sulfonaphthalen-1-olate Chemical compound [Na+].COc1cc(N=Nc2ccc(N)cc2)c(C)cc1N=Nc1c(O)c2cc(N)ccc2cc1S([O-])(=O)=O BQHRKYUXVHKLLZ-UHFFFAOYSA-M 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- -1 sulfate Chemical class 0.000 description 1
- 229960000943 tartrazine Drugs 0.000 description 1
- UJMBCXLDXJUMFB-UHFFFAOYSA-K trisodium;5-oxo-1-(4-sulfonatophenyl)-4-[(4-sulfonatophenyl)diazenyl]-4h-pyrazole-3-carboxylate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)C1=NN(C=2C=CC(=CC=2)S([O-])(=O)=O)C(=O)C1N=NC1=CC=C(S([O-])(=O)=O)C=C1 UJMBCXLDXJUMFB-UHFFFAOYSA-K 0.000 description 1
- 238000001771 vacuum deposition Methods 0.000 description 1
- 239000001052 yellow pigment Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Landscapes
- Powder Metallurgy (AREA)
Abstract
Description
【発明の詳細な説明】
本発明は種々の色調を有する着色アルミニウム粉、特に
メタリック・カラーとして塗料やインキに有用な着色ア
ルミニウム粉の製造方法に関する。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a method for producing colored aluminum powder having various tones, particularly colored aluminum powder useful as a metallic color in paints and inks.
従来からメタリックカラーとして、銀色用としてはアル
ミニウム粉が使用されてきた。更に種々の色調を出すた
めに、金色としては真情物を、他の色調には、アルミニ
ウム粉表面に酸化皮膜を形成せしめ１次いで染料にて染
色せしめるか１着色合成樹脂フィルムにアルミニウムを
真空蒸着してこれを粉砕する方法およびアルミニウム粉
を金属塩とキレート能を有する有機化合物とを含む弱ア
ルカリ溶液に浸漬処理することにより着色アルミニウム
粉が得られるが、いずれも次のような理由により実用化
するには満足すべきものとはいえなかった。Aluminum powder has traditionally been used as a metallic color and as a silver color. Furthermore, in order to produce a variety of color tones, the gold color can be obtained by using Shinjou, and other color tones can be obtained by forming an oxide film on the surface of the aluminum powder and then dyeing it with a dye, or by vacuum evaporating aluminum onto a colored synthetic resin film. Colored aluminum powder can be obtained by pulverizing it with a hand or by immersing the aluminum powder in a weak alkaline solution containing a metal salt and an organic compound with chelating ability, but both methods are not practical for the following reasons. could not be said to be satisfactory.
即ち
■ 金色としての真鍮粉は、原料が高価であること、環
境によって変色し易いこと、光沢が劣化し易いこと。Namely, ■ Brass powder, which has a golden color, is an expensive raw material, easily changes color depending on the environment, and easily loses its luster.
■ アルミニウム粉表面に酸化皮膜を形成せしめて１次
いで染料で染色する方法は、酸化皮膜を均一にアルミニ
ウム粉の表面に形成せしめることは、その条件設定が非
常に困難の為に、後で染料で染色すると、不均一な染色
結果金得ることが多い。■ The method of first forming an oxide film on the surface of the aluminum powder and then dyeing it with a dye is very difficult to set the conditions to uniformly form an oxide film on the surface of the aluminum powder, so it is necessary to dye it later with a dye. When dyeing, you often get uneven dyeing results.
■ 着色合成樹脂フィルムにアルミニウムを蒸着して、
これを粉砕する方法は真空蒸着装置が非常に高いために
、安価なメクリック塗料には使用できない。■ By vapor-depositing aluminum on colored synthetic resin film,
The method of pulverizing this requires very expensive vacuum deposition equipment, so it cannot be used for inexpensive Meklic paints.
■ アルミニウム粉を金属塩とキレート能を有する有機
化合物とを含む弱アルカリ溶液に浸漬処理することによ
る着色アルミニウム粉は着色される色が限定される上に
着色される色調も濃度かうすく、釜属キレートｑ−＋有
のくすんだ色調が得られない。■ Colored aluminum powder produced by immersing aluminum powder in a weak alkaline solution containing a metal salt and an organic compound with chelating ability has a limited range of colors, and the color tone is faint, making it difficult to use in a pot. A dull color tone cannot be obtained with chelate q-+.
等の不利益を有していた。They had disadvantages such as:
本発明者等は上記諸問題を解決するだめに気量研究した
結果２アルミニウム粉に多価金属の水酸化物を付着せし
めて後、アニオン性の染料で染色することにより、容易
に望む色調に着色したアルミニウム粉が得られることを
見出したのである。In order to solve the above-mentioned problems, the present inventors conducted a quantitative research and found that it was possible to easily obtain the desired color tone by attaching polyvalent metal hydroxide to aluminum powder and then dyeing it with an anionic dye. They discovered that colored aluminum powder could be obtained.
即ちアルミニウム粉を多価金属塩６水溶液に分散し、炭
酸アルカ’Ｊ ｔたは水酸化アルカリの水溶液を添加し
て、アルミニウム粉の表面に、該多価金属の水酸化物を
析出せしめ２次にアニオン性染料２例えば酸性染料など
により染色することにより２着色したアルミニウム塩を
得る。That is, aluminum powder is dispersed in an aqueous solution of polyvalent metal salt 6, and an aqueous solution of alkali carbonate or alkali hydroxide is added to precipitate the hydroxide of the polyvalent metal on the surface of the aluminum powder. A 2-colored aluminum salt is obtained by dyeing with an anionic dye 2, such as an acid dye.
前記多価金属の水酸化物を形成する多価金属の塩として
は、亜鉛、アルミニウム、カドミウム、ジルコニウム、
バリウム、ビスマス、マグネシウムの塩酸塩、硝酸塩、
硫酸塩などの水溶性塩であり、前述したように苛性アル
カリまたは炭酸アルカリの水溶液によって、水酸化亜鉛
。The polyvalent metal salts forming the polyvalent metal hydroxide include zinc, aluminum, cadmium, zirconium,
barium, bismuth, magnesium hydrochloride, nitrate,
Zinc hydroxide is a water-soluble salt such as sulfate, and as mentioned above, by an aqueous solution of caustic or alkali carbonate.
水酸化アルミニウム、水酸化カドミウム、水酸化カルシ
ウム、水酸化ジルコニウム、水酸化バリウム、水酸化ビ
スマス、水酸化マグネシウムなどの白色で安定な多価金
属の水酸化物としてアルミニウム粉に付着せしめるが、
多価金属の水酸化物の量は、アルミニウム粉の５〜５０
重量％が好ましく、５重量％以下では、アニオン性染料
の染色効果が少なく、５０重量％以上ではアニオン性染
料の濃度に関係なく、アルミニウム粉の金属光沢が失な
われることがある。It is attached to aluminum powder as a white and stable polyvalent metal hydroxide such as aluminum hydroxide, cadmium hydroxide, calcium hydroxide, zirconium hydroxide, barium hydroxide, bismuth hydroxide, and magnesium hydroxide.
The amount of polyvalent metal hydroxide is 5 to 50% of the aluminum powder.
The amount is preferably 5% by weight or less, the dyeing effect of the anionic dye is small, and if it is more than 50% by weight, the metallic luster of the aluminum powder may be lost regardless of the concentration of the anionic dye.
価金属の水酸化物を付着したアルミニウム粉を分散する
ことにより容易に実施できるものである。This can be easily carried out by dispersing aluminum powder to which a hydroxide of a valent metal is attached.
アニオン性染料としては、直接染料、酸性染料、酸性媒
染染料が挙げられ、直接染料としては、 Ｃ，１，ダイ
レクト・エロー８．同１１．同１２゜同２６．同２７．
同２８．同３３．同３９．同４４、同５０．Ｃ，１，ダ
イレクト・オレンジ６゜同１０．同２６．同２９．同６
９．同４１．同４９、同１ｏ ２． Ｏ，１，ダイレク
ト・レッド２゜同４．同２０．同２３．同２４．同３１
．同３９゜同４６．同６２．同６３．同７５．同７９．
同８０、同８１．同８３．同８４．同１１３１．０．１
．ダイレクト・バイオレット７、同９．同３５゜同４７
．同４８．同ｓ１．Ｃ，１，ダイレクト・ブルー１．同
１５．同２２．同２５．同４１．同７１、同７６、同７
８．同８６．同９０．同９８゜同１０６．同１０８．同
１２ｏ、同１２３．同１５８、同１６６、同１６５．同
１６８．同２２６゜０．１．ダイレクト・グリーン２８
．同３３．同５９゜０．１．ダイレクト・ブラウン４４
．同ｉｏｏ、同１０６、同ｔ １’ ２ 、 Ｃ，１，
ダイレクト・ブラック１７、同１９．同２２．同３２．
同５１．同５６゜同７１．同７４．同７５．同７７など
があり。Examples of anionic dyes include direct dyes, acid dyes, and acid mordant dyes. Examples of direct dyes include C, 1, Direct Yellow 8. Same 11. Same 12゜ Same 26. Same 27.
Same 28. Same 33. 39. 44, 50. C, 1, Direct Orange 6° Same 10. 26. 29. Same 6
9. 41. 49, 1o 2. O, 1, Direct Red 2° Same 4. 20. Same 23. Same 24. 31
．． 39° 46. Same 62. Same 63. 75. Same 79.
80, 81. Same 83. Same 84. 1131.0.1
．． Direct Violet 7, same 9. Same 35° Same 47
．． 48. Same s1. C, 1, Direct Blue 1. Same 15. Same 22. 25. 41. 71, 76, 7
8. 86. 90. Same 98° Same 106. Same 108. 12o, 123. 158, 166, 165. Same 168. 226°0.1. direct green 28
．． Same 33. 59°0.1. direct brown 44
．． Same ioo, same 106, same t 1' 2, C,1,
Direct Black 17, same 19. Same 22. 32.
Same 51. 56゜71. Same 74. 75. There are 77 etc.
酸性染料としては、 Ｏ，１，アシッド・エロー１゜同
６．同７．同１１．同１７．同２６．同２５゜同２９．
同３６．同５Ｂ、Ｉｏ１４０．同４２．同４４、同７６
、同９８．同ｑｑ、Ｏ，１，アンツド・オレンジ１．同
７．同８．同１０．同１９゜同２０．同２４．同２８．
同３３．同４１．同５１、同５６．同７４．Ｏ，１，ア
シツド・レッド１、同６．同８．同９．同１３．同１４
．同１８、同２６．同２７．同３２．同３５．同３７、
同４２．同５１．同５２．同８０．同８２、同８３．同
８７．同８８．同８９．同９２、同９４．同９７．同１
０６．同１１１゜同１１４．同１１５．同１３３．同１
３４．同１４５、同１５４．同１５５．同１５８．同１
８０、同１８３．同１８４．同１８６．同１９８、同２
４９．同２６ ｓ、 ０．１．アシッド・バイオレット
７、同１１．同１５．同３４．同４１、同４３．同４９
．同５１．同６３．Ｃ，Ｉ。As acidic dyes, O, 1, Acid Yellow 1° and 6. Same 7. Same 11. Same 17. 26. Same 25° Same 29.
36. Same 5B, Io140. Same 42. Same 44, Same 76
, 98. Same qq, O, 1, Untud Orange 1. Same 7. Same 8. Same 10. Same 19゜ Same 20. Same 24. Same 28.
Same 33. 41. 51, 56. Same 74. O, 1, acid red 1, same 6. Same 8. Same 9. Same 13. Same 14th
．． 18th, 26th. Same 27. 32. 35. Same 37,
Same 42. Same 51. Same 52. 80. 82, 83. Same 87. 88. 89. 92, 94. 97. Same 1
06. Same 111゜ Same 114. 115. 133. Same 1
34. 145, 154. 155. Same 158. Same 1
80, 183. Same 184. 186. 198, 2
49. 26 s, 0.1. Acid Violet 7, 11. Same 15. 34. 41, 43. Same 49
．． Same 51. Same 63. C.I.
アシッド・ブルー１１同７．同９．同１５．同２２、同
２３．同２５．同２７．同２９．同４０、同４１．同４
３．同４５．同５９．同６２、同７４．同７８．同８０
．同８３．同９０、同９２．同９３．同１００．同１０
２゜同１０６．同１０４．同１１３．同１１７．同１２
０、同１２７．同１３８．同１５８．同＋ ６１．０．
１．アシッド・グリーン６、同９．同１２、同１６．同
１９．同２０．同２５．同２７、同３５．同３６．同４
１．同４４．Ｃ！、Ｉ。Acid Blue 11 7. Same 9. Same 15. Same 22, same 23. 25. Same 27. 29. 40, 41. Same 4
3. 45. 59. 62, 74. 78. Same 80
．． Same 83. 90, 92. Same 93. Same 100. Same 10
2゜same 106. Same 104. Same 113. 117. Same 12th
0, 127. 138. Same 158. Same + 61.0.
1. Acid Green 6, same 9. Same 12, same 16. Same 19. 20. 25. 27, 35. 36. Same 4
1. 44. C! ,I.
アシッド・ブラウン２．同４．同１′５．同１４゜同２
０．同２７．同＋ ０３． Ｏ，１，アシッド・ブラッ
ク１．同２．同７．同２４．同２６．同３１、同４８．
同５１．同５２ｆｘどがあり、酸性媒染染料としては、
Ｏ，１，モルダント・エロー１、同３．同５．同２６
．同３０．同３８゜０．１．モルダン）−オレンジ１．
同４．同６．同２９、同３７．Ｏ，１，モルダント・レ
ッド３．同７、同９．同１５．同１７．同１９．同２１
゜同２６．同２７．同３０．Ｏ，１，モルダント・バイ
オレット１．同５．同４４．Ｏ，１，モルダント・ブル
ー１．同７．同８−同１６．同２９．同４４、同４７．
同４８．Ｏ，１，モルダント・グリーン１１．同１５．
同１７．Ｏ，１，モルダント・ブラウン１．同１４．同
１５．同１９．同２１゜同３６．同４０．Ｏ，１，モル
ダント俸ブラック１゜同３．同９．同１１．同１３．同
１７．同３８゜同５１．同５４などがあり、単独もしく
は混合して使用可能である。Acid Brown 2. Same 4. Same 1'5. Same 14゜ Same 2
0. Same 27. Same + 03. O, 1, acid black 1. Same 2. Same 7. Same 24. 26. 31, 48.
Same 51. 52fx etc., and as an acidic mordant dye,
O, 1, Mordant Yellow 1, same 3. Same 5. Same 26th
．． 30. 38°0.1. Mordan) - Orange 1.
Same 4. Same 6. 29, 37. O, 1, Mordant Red 3. 7, 9. Same 15. Same 17. Same 19. Same 21
゜Same 26. Same 27. 30. O, 1, Mordant Violet 1. Same 5. 44. O, 1, Mordant Blue 1. Same 7. Same 8-16. 29. 44, 47.
48. O, 1, Mordant Green 11. Same 15.
Same 17. O, 1, Mordaunt Brown 1. Same 14. Same 15. Same 19. 21゜36. 40. O, 1, mordant black 1° same 3. Same 9. Same 11. Same 13. Same 17. 38° 51. 54, etc., and can be used alone or in combination.
以下、実施例を用いて具体的に説明するが。Hereinafter, this will be explained in detail using examples.
実施例中１部」とあるのは「重量部」を示すものである
一０′
実施例１
アルミニウム粉 １０部
水 １００部
硝酸アルミニウム・９水和物 ７部
上記組成物を常温で２０分間攪拌し、５％水酸化ナトリ
ウム水溶液を滴下し、ＰＨｓ、ｏとして、その後濾過、
水洗、乾燥させて１３５部の水酸化アルミニウムの付着
したアルミニウム粉を得だ。In the examples, "1 part" indicates "parts by weight." Example 1 Aluminum powder 10 parts Water 100 parts Aluminum nitrate nonahydrate 7 parts The above composition was stirred at room temperature for 20 minutes. Then, 5% aqueous sodium hydroxide solution was added dropwise to adjust the pH to 0, and then filtered.
It was washed with water and dried to obtain aluminum powder to which 135 parts of aluminum hydroxide was attached.
上記で得られたアルミニウム粉１３５部を。135 parts of the aluminum powder obtained above.
カヤク・タートラジン・コンク（０，１，アシッド・エ
ロー２３日本化薬■製）０７部、水５００部からなる溶
液に加えＰ ｆ（５に調整し７て常温で３０分間攪拌し
、濾過、水洗、乾燥させて。Kayaku Tartrazine Conch (0,1, Acid Yellow 23 manufactured by Nippon Kayaku ■) was added to a solution consisting of 07 parts of Pf (adjusted to 5 and 7, stirred at room temperature for 30 minutes, filtered, and washed with water. , let it dry.
メタリック調光沢を有する黄金色の顔料１３５部が得ら
れた。135 parts of a golden pigment with metallic luster were obtained.
実施例２
実施例１で使用しだカヤク・タートラジン・コンク０７
部の代わりにナンカイ・ダイレクト・ファースト・エロ
ーＡコンク（０，Ｉ・タイレフトエロー１１．南海染料
■製）を０７部使用しても実施例１と同様な黄金色の顔
料が得られた。Example 2 Shida Kayak Tartrazine Conch 07 used in Example 1
A golden yellow pigment similar to that of Example 1 was obtained even when 0.7 parts of Nankai Direct First Yellow A Conc (0.I.Tyre Left Yellow 11. manufactured by Nankai Dye ■) was used instead of 0.7 parts.
実施例３
アルミニウム粉 １０部
塩化カルシウム・６水和物 ２部
水 １００部
上記組成を常温で１時間攪拌し、５％苛性ソーダ水溶液
で中オロしてＰ Ｈａとし、濾過、水洗。Example 3 Aluminum powder 10 parts Calcium chloride hexahydrate 2 parts Water 100 parts The above composition was stirred at room temperature for 1 hour, diluted with 5% caustic soda aqueous solution to obtain P Ha, filtered, and washed with water.
５０Ｃで乾燥させて１１部の水酸化カルシウムの付着し
たアルミニウム粉を得た。It was dried at 50C to obtain aluminum powder to which 11 parts of calcium hydroxide was attached.
上記で得られたアルミニウム粉１１部をジャパノール・
カップリング・オレンジコンク（Ｃ，１，ダイレクト・
オレンジ１０．住友化学■製）０５５部、水２００部か
らなる溶液に力Ｕえ、常温で６０分間攪拌し、濾過、水
洗、５０Ｃで乾燥させてメタリック調光沢を有する赤味
かかった黄金色の顔料１１部が得られた。11 parts of the aluminum powder obtained above was mixed with Japanol.
Coupling Orange Conch (C, 1, Direct
Orange 10. A solution consisting of 055 parts (manufactured by Sumitomo Chemical) and 200 parts of water was heated, stirred at room temperature for 60 minutes, filtered, washed with water, and dried at 50C to obtain 11 parts of a reddish golden pigment with metallic luster. was gotten.
実施例４
実施例３で使用したジャパノール・カップリング・オレ
ンジ・コンク０５５部の代わりにスミクローム・ファー
スト・エローに、Ｅコンク（Ｃ，１，モルダント・エロ
ー６０．住友化学■製）０５５部を使用しても実施例３
と同様な赤味がかった黄金色の顔料を得た。Example 4 Instead of 055 parts of Japanol Coupling Orange Conc used in Example 3, 055 parts of E Conc (C, 1, Mordant Yellow 60, manufactured by Sumitomo Chemical ■) was added to Sumichrome First Yellow. Example 3 even if used
A reddish golden pigment similar to that obtained was obtained.
実施例５
アルミニウム粉 １０部
塩化バリウム・２水和物 ２．５部
水 １００部
上記組成を常温で１時間攪拌し、５％苛性ソーダ水溶液
をＰ Ｈ８となるように滴下し、濾過。Example 5 Aluminum powder 10 parts Barium chloride dihydrate 2.5 parts Water 100 parts The above composition was stirred at room temperature for 1 hour, 5% aqueous sodium hydroxide solution was added dropwise to pH 8, and filtered.
水洗、乾燥させて、１１部の水酸化バリウムの付着した
アルミニウム粉を得だ。It was washed with water and dried to obtain aluminum powder with 11 parts of barium hydroxide attached.
上記で得られたアルミニウム粉１１部をアシッド・アン
トラセン・レッド３Ｂ（０，１，７シノドレソド８９日
本色素製造■製）０２８部；水２００部からなる溶液に
加え、常温で３０分間攪拌し、濾過、水洗、５０Ｃ乾燥
させて、メタリック調光沢を有する青味の赤色の顔料１
１部が得られた。11 parts of the aluminum powder obtained above was added to a solution consisting of 028 parts of Acid Anthracene Red 3B (manufactured by 0,1,7 Synodresod 89 Nippon Shiki Seizo Co., Ltd.) and 200 parts of water, stirred at room temperature for 30 minutes, and filtered. , washed with water, dried at 50C, bluish red pigment 1 with metallic luster
One part was obtained.
実施例６
実施例５で使用した塩化バリウム・２水和物２．５部の
代りに塩化カドミウム・２．５水和物を同量使用して、
実施例５と同様な青味の赤色の顔料が得られた。Example 6 Instead of 2.5 parts of barium chloride dihydrate used in Example 5, the same amount of cadmium chloride dihydrate was used,
A bluish red pigment similar to Example 5 was obtained.
叉１ｊ己
アルミニウム粉 １０部
塩化マグネシウム・ろ水和物 ６部
水 １００部
上記組成を常温で１時間攪拌し、５％苛性ソーダ水溶液
で中和して、濾過、水洗、５０Ｃ乾燥することにより１
４部の水酸化バリウムの伺着したアルミニウム粉を得た
。Aluminum powder 10 parts Magnesium chloride filtrate 6 parts Water 100 parts The above composition was stirred at room temperature for 1 hour, neutralized with 5% caustic soda aqueous solution, filtered, washed with water, and dried at 50C to obtain 1
An aluminum powder adhering to 4 parts of barium hydroxide was obtained.
上記で得られたアルミニウム粉１４部をミツイ・アリザ
リン・フォースドブルー４ＧＬ（０，１，アンノドブル
ー２３．三井東圧化学■製）０７部、水２００部からな
る溶液に加え。14 parts of the aluminum powder obtained above was added to a solution consisting of 0.7 parts of Mitsui Alizarin Forced Blue 4GL (0.1, Annod Blue 23. manufactured by Mitsui Toatsu Chemical ■) and 200 parts of water.
Ｐ Ｈｓで常温にて５０分間攪拌し、濾過、水洗。Stir with PHS at room temperature for 50 minutes, filter, and wash with water.
５０Ｃ乾燥させて、メタリック調光沢を有する青色の顔
料１４．１部が得られた。After drying at 50C, 14.1 parts of a blue pigment with metallic luster was obtained.
実施例８
実施例７で使用したミツイ・アリザリン・ファースト・
ブルー４ Ｇ Ｌ ｏ７部の代わりにアイゼン・プリム
ラキュプロ・グリーンＧＨ（、Ｏ，Ｉ。Example 8 Mitsui Alizarin First used in Example 7
Blue 4 G Lo Instead of part 7, Eisen Primula Cupro Green GH (, O, I.
ダイレクト・グリーン５９．保土谷化学■製）０７部を
使用するとメタリック調光沢を有する緑色の顔料を得た
。Direct Green 59. When 07 parts (manufactured by Hodogaya Kagaku ■) were used, a green pigment with metallic luster was obtained.
以上のように本発明の着色アルミニウムの製造方法は従
来の製造方法とは異なり、容易に望む色調のものが得ら
れるメリットがある。As described above, the method for producing colored aluminum of the present invention is different from conventional production methods, and has the advantage that a desired color tone can be easily obtained.
特許出ｉＦ１人 ぺんてる株式会社Patented iF 1 person Pentel Co., Ltd.
Claims (1)
しめて後、アニオン性の染料にて染色せしめてなる顔料
の製造方法。 （２） 多価金属の水酸化物が、水酸化亜鉛、水酸化ア
ルミニウム、水酸化カドミウム、水酸化ジルコニウム、
水酸化バリウム、水酸化ジルコニウム、水酸化バリウム
、水酸化ビスマス。 水酸化マグネシウムである特許請求の範囲第１項記載の
着色アルミニウム粉の製造方法。 （５） アニオン性の染料が直接染料、酸性染料。 酸性媒染染料である特許請求の範囲第１項乃至第２項記
載の顔料の製造方法。[Scope of Claims] (1) A method for producing a pigment by attaching polyvalent metal hydroxide to aluminum powder and then dyeing it with an anionic dye. (2) Polyvalent metal hydroxides include zinc hydroxide, aluminum hydroxide, cadmium hydroxide, zirconium hydroxide,
Barium hydroxide, zirconium hydroxide, barium hydroxide, bismuth hydroxide. The method for producing colored aluminum powder according to claim 1, which is magnesium hydroxide. (5) Anionic dyes are direct dyes and acid dyes. A method for producing a pigment according to claims 1 and 2, which is an acidic mordant dye.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP58137313A JPS6029402A (en) | 1983-07-26 | 1983-07-26 | Manufacture of colored aluminum powder |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP58137313A JPS6029402A (en) | 1983-07-26 | 1983-07-26 | Manufacture of colored aluminum powder |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS6029402A true JPS6029402A (en) | 1985-02-14 |
Family
ID=15195764
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP58137313A Pending JPS6029402A (en) | 1983-07-26 | 1983-07-26 | Manufacture of colored aluminum powder |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6029402A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5031106A (en) * | 1988-06-30 | 1991-07-09 | Brother Kogyo Kabushiki Kaisha | Machine tool |
| WO1996022336A1 (en) * | 1995-01-18 | 1996-07-25 | Eckart-Werke Standard Bronzepulver Werke Carl Eckart Gmbh & Co. | Coloured aluminium pigments, process for producing them and their use |
| EP0769535A3 (en) * | 1995-10-20 | 1997-09-17 | Japat Ltd | Colored metallic pigment and preparation thereof |
| US5718753A (en) * | 1995-10-20 | 1998-02-17 | Ciba Specialty Chemicals Holding, Inc. | Colored metallic pigment and preparation thereof |
-
1983
- 1983-07-26 JP JP58137313A patent/JPS6029402A/en active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5031106A (en) * | 1988-06-30 | 1991-07-09 | Brother Kogyo Kabushiki Kaisha | Machine tool |
| WO1996022336A1 (en) * | 1995-01-18 | 1996-07-25 | Eckart-Werke Standard Bronzepulver Werke Carl Eckart Gmbh & Co. | Coloured aluminium pigments, process for producing them and their use |
| EP0769535A3 (en) * | 1995-10-20 | 1997-09-17 | Japat Ltd | Colored metallic pigment and preparation thereof |
| US5718753A (en) * | 1995-10-20 | 1998-02-17 | Ciba Specialty Chemicals Holding, Inc. | Colored metallic pigment and preparation thereof |
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