JPS60250056A - Antistatic transparent resin composition - Google Patents
Antistatic transparent resin compositionInfo
- Publication number
- JPS60250056A JPS60250056A JP10683584A JP10683584A JPS60250056A JP S60250056 A JPS60250056 A JP S60250056A JP 10683584 A JP10683584 A JP 10683584A JP 10683584 A JP10683584 A JP 10683584A JP S60250056 A JPS60250056 A JP S60250056A
- Authority
- JP
- Japan
- Prior art keywords
- polymethyl methacrylate
- lithium perchlorate
- resin
- antistatic
- solvent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Abstract
Description
【発明の詳細な説明】
〔発明の技術分野〕
この発明はポリメタクリル酸メチルに過塩素酸リチウム
を加えた、帯電防１効果を持つ透明な樹脂組成物に関す
るものである。DETAILED DESCRIPTION OF THE INVENTION [Technical Field of the Invention] The present invention relates to a transparent resin composition having an antistatic effect, which is made by adding lithium perchlorate to polymethyl methacrylate.
従来、透明性を保持したまま帯電性を小さくするために
は帯電防止剤を塗布したり練り込んだりする方法が知ら
れており、帯電防止剤としては通常、界面活性剤または
それに類するものが用いられる。そのような帯電防止剤
は同一分子内に親水基と疎水基を有しているため、樹脂
に対して適度の相溶性を持ち、かつ空気中の水分を吸湿
することにより樹脂表面のイオン伝導性が大きくなり帯
電防止性を示す。Conventionally, methods of coating or kneading an antistatic agent have been known in order to reduce electrostatic properties while maintaining transparency, and surfactants or similar substances are usually used as the antistatic agent. It will be done. Since such antistatic agents have a hydrophilic group and a hydrophobic group in the same molecule, they have moderate compatibility with resins, and improve the ionic conductivity of the resin surface by absorbing moisture in the air. increases, indicating antistatic properties.
従来の帯電防止剤は以上のような作用機構で帯電防止効
果が発現するため水の存在は不可欠であり、低湿度の環
境では帯電防止効果は小さくなる等の欠点がある。さら
に、帯電防止剤を塗布する方法は、塗布した帯電防止剤
が取れやすく、塗布するためのコストも大きい等の欠点
があり、また帯電防止剤を練り込む方法は、練り込んだ
帯電防止剤が樹脂表面に移行してこなければ大きな帯電
防止効果を発揮せず、樹脂との完全な相溶性はないため
良好な透明性を維持することは困難である等の欠点があ
る。Conventional antistatic agents exhibit their antistatic effect through the mechanism described above, so the presence of water is essential, and they have drawbacks such as their antistatic effect being reduced in low humidity environments. Furthermore, the method of applying an antistatic agent has disadvantages such as the applied antistatic agent is easy to remove and the cost of applying it is high. If it does not migrate to the resin surface, it will not exhibit a large antistatic effect, and since it is not completely compatible with the resin, it has drawbacks such as difficulty in maintaining good transparency.
この発明は上記従来のものの欠点を除去するためになさ
れたもので、ポリメタクリル酸メチル１００重量部およ
び過塩素酸グチ１クム８５重量％以下を含有する組成物
を用いることにより、導電性が比較的高く、低湿度の環
境中においても良好な帯電防止効果を示し、かつ透明性
に優れた透明帯電防止樹脂組成物を提供することを目的
とするものである。This invention was made in order to eliminate the drawbacks of the above-mentioned conventional products, and by using a composition containing 100 parts by weight of polymethyl methacrylate and 85% by weight or less of 1 cum of perchlorate, the conductivity was improved compared to that of the conventional one. The object of the present invention is to provide a transparent antistatic resin composition that exhibits a good antistatic effect even in a low-humidity environment and has excellent transparency.
この発明に係わるポリメタクリル酸メチル樹脂および過
塩素酸リチウムは、過塩素酸リチウムがポリメタクリル
酸メチル樹脂中に固溶体的に溶解してイオンに解離した
状態であり、電界が印加されればこのイオンがポリメタ
クリル酸メチルｍＢＷ中を移動して電荷を中和しようと
することにより帯電防止効果を示す。才だ、イオンのＡ
ＩＭはポリメタクリル酸メ≠ル樹脂自体の中で起こり、
水分を必要としないため乾燥することをζよる帯電防止
効果の低下はなく、過塩素酸リチウムはポリメタクリル
酸メチル樹脂に完全に溶解しているためポリメタクリル
酸メチル樹脂の良好な透明性をそこなうことはない。The polymethyl methacrylate resin and lithium perchlorate according to the present invention are in a state in which lithium perchlorate is dissolved as a solid solution in the polymethyl methacrylate resin and dissociated into ions, and when an electric field is applied, the ions moves in polymethyl methacrylate mBW and attempts to neutralize the charge, thereby exhibiting an antistatic effect. Great talent, Aeon's A.
IM occurs within the polymethacrylate methyl resin itself,
Since no moisture is required, there is no reduction in antistatic effect due to drying, and since lithium perchlorate is completely dissolved in polymethyl methacrylate resin, it does not impair the good transparency of polymethyl methacrylate resin. Never.
ポリメタクリル酸メチル樹脂と過塩素酸リチウムの量的
割合は適当な範囲がある。即ち、ポリメタクリル酸メチ
ル樹脂１００重量部に対し過塩素酸リチウムの配合割合
は８５重量部以下でなければならない。過塩素酸リチウ
ムが８６重量部を越える場合には通常の室温での配合に
おいて過塩素酸リチウムの結晶が析出し、透明性が悪く
なる場合がある。The quantitative ratio of polymethyl methacrylate resin and lithium perchlorate has an appropriate range. That is, the blending ratio of lithium perchlorate to 100 parts by weight of polymethyl methacrylate resin must be 85 parts by weight or less. If the amount of lithium perchlorate exceeds 86 parts by weight, crystals of lithium perchlorate may precipitate when blended at normal room temperature, resulting in poor transparency.
ポリメタクリル酸メチルと過塩素酸リチウムの配合は公
知の方法１例えば溶剤キャスト法または溶剤を用いずそ
のまま溶融混合する方法で行なわれ、得られた組成物は
常法にて１例えば射出成形法により成形することが可能
である。The blending of polymethyl methacrylate and lithium perchlorate is carried out by a known method 1, such as a solvent casting method or a method of melt-mixing without using a solvent, and the resulting composition is mixed by a conventional method 1, such as an injection molding method. It is possible to mold it.
なお、この発明の一実施例の透明帯電防止樹脂組成物が
、導電性を上げるために１組成物と相溶性のある化合物
を含有しても良い。The transparent antistatic resin composition of one embodiment of the present invention may contain a compound compatible with the other composition in order to increase the conductivity.
次にこの発明を実施例にて具体的に説明するが。Next, this invention will be specifically explained with reference to Examples.
これに限定されるものではない。It is not limited to this.
実施例
テトラヒドロフランに過塩素酸リチウムを所定量溶解し
、さらにポリメタクリル酸メチル樹脂を所定量溶解し、
ガラス板１にその溶液を流し込み。Example: Dissolve a predetermined amount of lithium perchlorate in tetrahydrofuran, further dissolve a predetermined amount of polymethyl methacrylate resin,
Pour the solution onto glass plate 1.
その後テトラヒドロフランを蒸発させ、過塩素酸リチウ
ムの割合が８６重量部以下の１１１１１？組成物のフィ
ルムを作成する。得られたフィルムの透明性。After that, tetrahydrofuran is evaporated, and the proportion of lithium perchlorate is 86 parts by weight or less. Create a film of the composition. Transparency of the resulting film.
導電性および帯電性をそれぞれＡＳＴＭ ０１００Ｂ
の方法による光の透過率（■）の測定、２５℃の不活性
ガス雰囲気中（湿間０％）で２ＫＶ／ｃｍの電界を印加
した場合の体積抵抗率（！と・ｃｍ）の測定および室温
２０℃湿度聞％の雰囲気中でポリエステル布片で１０回
摩擦した試料フィルムが新鮮な煙草の灰を吸引し始める
距Ｊｉｍ！（ｃｍ）の測定（アッシュテスト月こより評
価した。ASTM 0100B conductivity and chargeability respectively
Measurement of light transmittance (■) using the method described above, measurement of volume resistivity (! and cm) when applying an electric field of 2 KV/cm in an inert gas atmosphere at 25°C (humidity 0%), and A sample film rubbed 10 times with a piece of polyester cloth in an atmosphere with room temperature and humidity of 20°C and 20% humidity begins to attract fresh cigarette ash! (cm) measurement (evaluated from ash test month).
比較例
テトラヒドロフランにポリメタクリル酸メチル樹脂を溶
解し、ガラス板上にその溶液を流し込み。Comparative Example Polymethyl methacrylate resin was dissolved in tetrahydrofuran and the solution was poured onto a glass plate.
その後テトラヒドロフランを蒸発させポリメタクリル酸
メチル樹脂のみのフィルムを作成する。得られたフィル
ムについて、実施例と同様な測定により評価し結果を表
に示す。Thereafter, the tetrahydrofuran is evaporated to create a film made only of polymethyl methacrylate resin. The obtained film was evaluated by the same measurements as in the examples, and the results are shown in the table.
＊）０はほとんど吸引しないことを表わす。*) 0 represents almost no suction.
以との測定結果から、この発明の実施例の組成物は導電
性が比較的高く、低湿度の環境中においても良好な帯電
防止効果を示し、かつ透明性が従前と同様優れているこ
とが解る。From the following measurement results, it was found that the compositions of Examples of the present invention have relatively high conductivity, exhibit good antistatic effects even in low humidity environments, and have excellent transparency as before. I understand.
（発明の効果〕
以上説明したとおり、この発明は、ポリメタクリル酸メ
チル１００重量部および過塩素酸リチウム８６重量％以
下を含有する組成物を用いることにより、導電性が比較
的高く、低湿度の環境中においても良好な帯電防止効果
を示し、かつ透明性において従前と同様に優れた透明帯
電防止栃脂組成物を得ることができる。(Effects of the Invention) As explained above, the present invention has relatively high conductivity and low humidity by using a composition containing 100 parts by weight of polymethyl methacrylate and 86% by weight or less of lithium perchlorate. It is possible to obtain a transparent antistatic horse chestnut resin composition that exhibits a good antistatic effect even in the environment and has excellent transparency as before.
代理人 大岩増雄Agent Masuo Oiwa
Claims (1)
酸リチウム８５重量部以下を含有する透明帯電防止樹脂
組成物。A transparent antistatic resin composition containing 100 parts by weight of polymethyl methacrylate resin and 85 parts by weight or less of lithium perchlorate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10683584A JPS60250056A (en) | 1984-05-25 | 1984-05-25 | Antistatic transparent resin composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10683584A JPS60250056A (en) | 1984-05-25 | 1984-05-25 | Antistatic transparent resin composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS60250056A true JPS60250056A (en) | 1985-12-10 |
Family
ID=14443772
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP10683584A Pending JPS60250056A (en) | 1984-05-25 | 1984-05-25 | Antistatic transparent resin composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS60250056A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6114257A (en) * | 1984-06-29 | 1986-01-22 | Mitsubishi Rayon Co Ltd | Lithium-containing resin composition and production thereof |
| JPS6445483A (en) * | 1987-08-14 | 1989-02-17 | Sansui Kk | Coating composition having antistatic effect |
| WO1990005171A1 (en) * | 1988-11-10 | 1990-05-17 | Sekisui Kagaku Kogyo Kabushiki Kaisha | Antistatic composition and antistatic chlorinated resin composition comprising said antistatic composition and process for preparing the same |
-
1984
- 1984-05-25 JP JP10683584A patent/JPS60250056A/en active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6114257A (en) * | 1984-06-29 | 1986-01-22 | Mitsubishi Rayon Co Ltd | Lithium-containing resin composition and production thereof |
| JPH0588272B2 (en) * | 1984-06-29 | 1993-12-21 | Mitsubishi Rayon Co | |
| JPS6445483A (en) * | 1987-08-14 | 1989-02-17 | Sansui Kk | Coating composition having antistatic effect |
| WO1990005171A1 (en) * | 1988-11-10 | 1990-05-17 | Sekisui Kagaku Kogyo Kabushiki Kaisha | Antistatic composition and antistatic chlorinated resin composition comprising said antistatic composition and process for preparing the same |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JPH04218537A (en) | Antistatic sheet or web material | |
| KR970028883A (en) | Electrostatic Image Toner | |
| JPS60250056A (en) | Antistatic transparent resin composition | |
| JP2000178540A (en) | Antistatic agent for inorganic substance | |
| JPH07305000A (en) | Antistatic coating composition | |
| US5910400A (en) | Antistatic composition and photographic element containing a layer of this composition | |
| JP2944504B2 (en) | Insulating paint and printed wiring board having coating film of the paint | |
| JPS6043874B2 (en) | Conductive resin composition | |
| JPS58102944A (en) | Electrostatic recording body | |
| US3525780A (en) | Method of manufacturing polymer materials having limited electrostatic chargeability | |
| JP3300475B2 (en) | Resin magnet composition and molded product thereof | |
| JP3233742B2 (en) | Antistatic coating composition for plastics | |
| JPS6172061A (en) | Resin composition | |
| JPS61176651A (en) | Resin composition | |
| CN1352798A (en) | Conductive or static dissipative coating | |
| US1405491A (en) | Cellulose-ether composition | |
| US3407093A (en) | Electronic recording film | |
| JPS61162545A (en) | Resin composition | |
| CN115650887A (en) | Optically transparent temperature-resistant long-acting small-molecule antistatic agent and preparation method and application thereof | |
| JPS593809A (en) | Ion conductive composition | |
| KR100229347B1 (en) | Method for the preparation of photographic film with excellent antistatic property | |
| JPS62112803A (en) | Antistatic artificial turf | |
| KR940010314B1 (en) | Method of making other than silver salt diazo type reproduction film | |
| JP2006328186A (en) | Coating material and molded article using it | |
| SU686004A1 (en) | Antistatic laquer coating for cine and photo materials |