JPS6024874B2 - Method for forming resist dyeing paste on fabric - Google Patents

Description

【発明の詳細な説明】 本発明は、布高上にて防梁剤含有のゲル粒子からなる防
染糊を形成する方法に関し、その主なる目的は、防梁糊
の防梁効果の大幅な改善並びに防梁加工工程の経済性の
飛躍的向上にある。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a method of forming a resist dyeing paste made of gel particles containing a beam-proofing agent on a fabric. Improvements and dramatic improvements in the economic efficiency of the beam guard processing process.

従来、防梁法は物理防梁法と化学防染法とに類別される
が、いずれも物理的又は化学的作用を示す防梁剤を元糊
中に均一に溶解または分散させて防梁糊を製し、次いで
布再上に施こすものである。Conventionally, beam-proofing methods are classified into physical beam-proofing methods and chemical resisting methods, but both methods involve uniformly dissolving or dispersing a beam-proofing agent that has a physical or chemical effect into the base glue. It is then applied onto the fabric.

しかし、このように防梁剤を単に元糊中に配合して用い
ることは、以下の問題点を有する。However, simply blending the beam preventive agent into the base glue and using it as described above has the following problems.

【１）該防梁剤が印綬部分以外に鯵出して周囲の輪郭を
不鮮競にする。‘２１ 防染処理中に防染剤が防染糊層
から布内部へ移行し、防染糊層表面の防染力を低下させ
る。｛３１ 防梁処理後に水洗、脱糊しても布中に防梁
剤が残留、付着して布の防梁部分に汚染、やけ、劣化な
どを起し防染効果を低下させる。斯かる従釆法の欠点の
解決のため、本発明者等は先に出願せる特願昭４９−５
２５９９及び特蟻昭４９一５２６００において、ゲル化
しうる糊料水溶液又は逆イオン性物質の添加により凝結
しうるイオン性物質水溶液に防梁剤を混合、分散させ、
これにゲル化剤又は逆イオン性物質をそれぞれ添加、混
合して防梁剤含有のゲル粒子又は凝結粒子を製し、これ
らをそれぞれ防梁用元糊中に分散させて防染糊を得るこ
とにより、防梁糊中の防梁剤が適当なる大きさに凝結し
ているので、防梁剤が防梁処理中に印孫部分以外への鯵
出が防止されること、防染処理中における防染剤の布内
部への移行が妨げられること、防梁処理後の水性、脱糊
時に防梁剤の防梁部分への強固な付着を防止できること
等の特徴の効果がある事を開示した。[1] The beam-preventing agent oozes out in areas other than the insole area, making the surrounding outline look unsightly. '21 During the resist dyeing process, the resist dye migrates from the resist dye paste layer to the inside of the fabric, reducing the resist dyeing power on the surface of the resist dye glue layer. {31 Even after washing with water and descaling after beam-proofing treatment, the beam-proofing agent remains in the fabric and adheres to it, causing contamination, tanning, deterioration, etc. on the beam-proofing part of the cloth, reducing the anti-dyeing effect. In order to solve the drawbacks of such a dependent method, the present inventors have filed a patent application filed in 1973-5, which can be filed earlier.
2599 and Tokusho 49-52600, a beam preventive agent is mixed and dispersed in an aqueous paste solution that can be gelled or an aqueous solution of an ionic substance that can be coagulated by adding a reverse ionic substance,
By adding and mixing a gelling agent or a reverse ionic substance to this, respectively, to produce gel particles or coagulated particles containing a beam-proofing agent, and dispersing these in the base glue for beam-proofing to obtain a resisting paste, Since the beam-proofing agent in the beam-proofing paste is condensed to an appropriate size, the beam-proofing agent is prevented from seeping out to areas other than the embossed area during beam-proofing treatment, and the beam-proofing agent is prevented from flowing out to areas other than the embossed area during the beam-proofing process. It was disclosed that it has the following characteristics: it prevents the agent from migrating into the fabric, it is water-based after beam-proofing treatment, and it prevents the beam-proofing agent from firmly adhering to the beam-proofing part during desizing.

然しながら該防梁糊は、あらかじめ防梁剤をゲル粒子と
なす処理操作及び印捺作業を要するが、該処理操作がや
や煩雑であり、また防梁剤たるゲル粒子又は凝結粒子を
高濃度に含有する防梁糊の調製が難かしく、加うるにか
かる防梁糊は、凹凸の著しい布への均一な印漆作業を害
する憾がある。However, the beam-proofing paste requires a processing operation to form the beam-proofing agent into gel particles and a printing operation, which is somewhat complicated, and also contains a high concentration of gel particles or coagulated particles as the beam-proofing agent. It is difficult to prepare a beam-proofing paste, and in addition, such a beam-proofing paste has the disadvantage of impairing the ability to uniformly apply lacquer to fabrics with significant irregularities.

本発明者は、斯かる欠点を鍵決すべく種々検討の結果、
通常の染色工程において布上で一挙に防染剤たるゲル粒
子又は凝結粒子を含む防染糊が形成可能なる本発明方法
を完成し、その結果、防梁効果を布の種類に無関係に発
揮し得、且つ特別のゲル化処理又は凝結処理を要せずし
て経済的な防梁加工を施すことに成功したのである。As a result of various studies in order to solve these drawbacks, the inventor of the present invention found that
We have completed the method of the present invention, which enables the formation of a resist dyeing paste containing gel particles or coagulated particles, which are resist dyes, all at once on cloth in a normal dyeing process, and as a result, the beam-proofing effect can be exhibited regardless of the type of cloth. They succeeded in applying an economical beam-proofing process without requiring any special gelling or coagulation treatment.

次に本発明の構成について詳述する。Next, the configuration of the present invention will be explained in detail.

本発明は、ゲル化しうる糊料水溶液及びゲル化剤たる元
糊のうち、何れか一方の防梁糊及び他方に防染剤を配合
して成る捺染糊の２種の捺染糊を用いて、布尾上に両者
を部分模様乃至全面状に相前後して印捺し、該布尾上に
おいて２種の捺染糊が重複する部分に防染剤含有のゲル
粒子から成る防染糊を生成することを特徴とする布畠上
防梁糊形成方法である。The present invention uses two types of printing pastes, one of which is an anti-beam paste and the other is a printing paste made of a gelatinable paste aqueous solution and a base paste which is a gelling agent. The method is characterized in that both are printed one after the other in a partial pattern or over the entire surface on the fabric tail, and a resist dyeing paste consisting of gel particles containing a resist dye is produced in the area where the two types of printing paste overlap on the fabric tail. This is a method for forming girder paste on cloth fields.

本発明に用いられるゲル化し得る糊料水溶液の糊料とし
ては、アルギン酸ソーダ、ローカストビンゴム、ペクチ
ン等の天然糊料、メチルセルロース、力ルボキシメチル
セルロース、ヒドロキシエチルセルロース等の如きセル
ロース誘導体、ナフカクリスタルゴム、エーテル化グア
ゴム、カゼイン等の如き加工糊料、ポリピニルアルコー
ル、ポリアクリル酸ソーダ、マレィン酸共重合体等の如
き合成糊料が挙げられ、これらの糊料の単独又は２種以
上の混合物を水に混合して糊化し、更に必要ならば通常
の染色用薬剤、例えば、還元防止剤、防腐剤、白色顔料
、ｐＨ調節剤、鉱物油、増量剤、乾燥防止剤等及び蟹光
増白剤、色素等が配合さ・れて、捺染糊が調合される。Examples of the thickening agent of the aqueous gelatable thickening solution used in the present invention include natural thickening agents such as sodium alginate, locust alcohol gum, and pectin, cellulose derivatives such as methyl cellulose, hydroxymethyl cellulose, and hydroxyethyl cellulose, naphka crystal rubber, Examples include processed thickeners such as etherified guar gum and casein, and synthetic thickeners such as polypinyl alcohol, sodium polyacrylate, maleic acid copolymers, etc. These thickeners may be used alone or in combination of two or more. Mix with water to gelatinize, and if necessary, use conventional dyeing agents such as reducing inhibitors, preservatives, white pigments, pH regulators, mineral oil, fillers, anti-drying agents, etc. and light brighteners. , pigments, etc. are added to prepare the printing paste.

本発明に用いられるゲル化剤としては、前記のゲル化し
得る糊料と相溶せず二相分離する糊料が挙げられる。即
ち、例えば、アルギン酸ソーダ、メチルセルロース、力
ルポキシメチルセルロース、ヒドロキシェチルセルロー
ス及びローカストビンゴムの各水溶液に対して相溶せず
二相分離する糊料としてナフカクリスタルゴム、アラビ
アゴム及びポリビニルアルコールが挙げられ、ナフカク
リスタルゴム、アラビアゴムの各水溶液に対して相溶せ
ず二相分離する糊料として、アルギン酸ソーダ、メチル
セルロース、力ルボキシメチルセルロース、ヒドロキシ
ェチルセルロース及びローカストビンゴムが挙げられ、
ポリビニルアルコール水溶液に対して相綾せず二相分離
する糊料として、アルギン酸ソーダ、メチルセルロース
、カルボキシメチルセルロース、ヒドロキシエチルセル
ロース、澱粉類、プリテシュゴム及びローカストビンゴ
ム等が挙げられ、このように、前記のゲル化し得る糊料
水溶液も場合によってはゲル化剤となり得るものである
。本発明におけるゲル化剤たる元糊中には、必要に応じ
て通常の染色用薬剤、例えば、還元防止剤、乳化剤、鉱
物油、ｐＨ調節剤、乾燥調節剤など及び色素顔料等を配
合することもできる。Examples of the gelling agent used in the present invention include a paste that is incompatible with the above-mentioned gelatable paste and separates into two phases. That is, for example, naphka crystal rubber, gum arabic, and polyvinyl alcohol are listed as adhesives that are incompatible and separate into two phases in aqueous solutions of sodium alginate, methylcellulose, hydroxymethylcellulose, hydroxyethylcellulose, and locust alcohol. Examples of glues that are incompatible and separate into two phases from aqueous solutions of naphka crystal rubber and gum arabic include sodium alginate, methyl cellulose, hydroxymethyl cellulose, hydroxyethyl cellulose, and locust alcohol gum.
Thickeners that do not phase and separate into two phases in a polyvinyl alcohol aqueous solution include sodium alginate, methyl cellulose, carboxymethyl cellulose, hydroxyethyl cellulose, starches, pretesh gum, and locust bottle gum. The obtained thickening aqueous solution can also be used as a gelling agent depending on the case. In the base paste, which is a gelling agent in the present invention, ordinary dyeing agents such as reduction inhibitors, emulsifiers, mineral oils, pH regulators, drying regulators, color pigments, etc. may be blended as necessary. You can also do it.

本発明において、防梁剤は、前述のゲル化し得る糊料水
溶液又はゲル化剤たる元糊のうちのどちらか一方の捺染
糊中に配合されるが、その防梁剤としては、活性炭素、
シリカゲル、酸性白土、活性白土、桂藤士、ナイロンオ
リゴマー、ポリエステル樹脂粉末、羊毛紬粉、ポリビニ
ルピロリドンなどの如き色素の吸収染着物質、塩化バリ
ウム、錆酸鉛、塩化第二錫、塩化亜鉛、蟻酸第二銅、硫
酸アルミニウム、モリブデン酸アンモニウム、ジシアン
ジアミジン塩、ジフェニル尿素塩、タンニン酸、合成タ
ンニン類似物、ピロガロール、イオン交換性樹脂などの
如き色素の不溶化又はキレート化物質、鉄粉、亜鉛末、
硫化カルシウム、硫黄末、亜硫酸ソーダ、ロンガリッド
、亜燐酸ナトリウム、塩化第一錫、燐酸第一錫、修酸（
ｍ）チタン、塩化第一クロム、二酸化マンガン、次亜塩
素酸カルシウム、二酸化鉛、クロム酸亜鉛、修酸ビドラ
ジン、グルコース、澱粉、ハイド。In the present invention, the beam-proofing agent is blended into the printing paste, which is either the above-mentioned aqueous size solution capable of gelatinization or the base paste as a gelling agent, and the beam-proofing agent includes activated carbon,
Pigment absorbing dyeing substances such as silica gel, acid clay, activated clay, Katsura Fujishi, nylon oligomer, polyester resin powder, wool pongee powder, polyvinylpyrrolidone, barium chloride, lead rust acid, tin chloride, zinc chloride, Pigment insolubilizing or chelating substances such as cupric formate, aluminum sulfate, ammonium molybdate, dicyandiamidine salts, diphenyl urea salts, tannic acid, synthetic tannin analogs, pyrogallol, ion exchange resins, etc., iron powder, zinc. At the end,
Calcium sulfide, sulfur powder, sodium sulfite, Rongarid, sodium phosphite, stannous chloride, stannous phosphate, oxalic acid (
m) Titanium, chromium chloride, manganese dioxide, calcium hypochlorite, lead dioxide, zinc chromate, hydrazine oxalate, glucose, starch, hyde.

キノンなどの如き色素の分解怪物質、炭酸バリウム、水
酸化ナトリウム、メタ桂酸ナトリウム、硫酸マグネシウ
ム、硫酸ナトリウム、塩化カリウム、スルフアミン酸な
どの如き色素の塩析乃至加水分解性物質、炭酸カルシウ
ム、硫酸バリウム、桂砂、タルク、アルミナ、カオリン
、火山灰、粘度などの如き吸水性物質、ダンマルゴム、
シリコン樹脂、弗素樹脂、ステアリン酸、木ロウの如き
溌水防水性物質、卵白、ゼラチン、界面活性剤、乳酸な
どの如き色素の緩梁性物質などが挙げられ、これらは単
独あるいは混合して捺染糊が調合される。本発明におい
ては、ゲル化し得る湖料水溶液及びゲル化剤たる元糊の
うちの何れか一方の捺染糊中に前述の防梁剤を混合、分
散させたるものを第一の捺染糊とし、該防梁剤を含まな
い他方の捺染糊を第二の捺染糊となし、布常上に両者の
部分模様乃至全面状に相前後して印捺することにより、
対象布畠上で２種の捺染糊が童積せる部分に、防染剤を
含有するゲル粒子が適当なる大きさに凝結・生成した防
梁糊が得られ、従って防築剤が該防梁糊中から布の繊維
組織中へ移行することを防止するのである。尚、前記の
防染剤中には、それ自体がゲル化剤たり得るもの、或は
色素の塩析性及び分解性を併有し、加えてゲル化能を示
す塩化第一錫、塩化第一鉄、硫酸第一鉄の如きものも含
まれている事は注目さるべきであり、これらの防梁剤就
中後者の防染剤を使用すれば、本発明の構成よりして極
めて効果的である。斯くして、本発明を実施するに際し
ては、防梁剤を配合せるゲル化しうる糊料水溶液からな
る捺染湖とゲル化剤たる元糊からなる捺染糊或し、は防
染剤を配合せるゲル化剤たる元糊からなる捺染糊とゲル
化しうる糊料水溶液からなる捺染糊の２種の組合せが得
られ、従って、各組合せにおける２つの捺染糊の布上の
印榛操作の時間的前後関係を加えて、合計４通りの防染
糊の形成方法が成立する。即ち、例えば、１つの具体的
方法として、布尾上に防梁剤を配合せるゲル化しうる糊
料水溶液からなる捺染糊にて任意の模様を印捺し、次い
で、ゲル化剤たる元糊からなる捺染糊を該模様に一致し
て重積する如く印捺するか、又は該模様部分のみならず
布全面に亘り被覆して、両捺染糊の相接する部分に防梁
糊を形成させることができるが、譲列頂序を逆にするこ
とによって、都合２通りの組合せが得られ、更に、ゲル
化剤たる元糊に防梁剤を配合する組合せにおいても、ま
た布上の印漆操作の時間的前後関係により２通りの組合
せが得られる。Substances that decompose pigments such as quinone, salting-out or hydrolyzable substances of pigments such as barium carbonate, sodium hydroxide, sodium metacitate, magnesium sulfate, sodium sulfate, potassium chloride, sulfamic acid, calcium carbonate, sulfuric acid, etc. Water-absorbing substances such as barium, cinnabar sand, talc, alumina, kaolin, volcanic ash, viscosity, etc., dammar gum,
Examples include silicone resin, fluororesin, stearic acid, water-repellent waterproof substances such as wood wax, and slowly pigmented substances such as egg white, gelatin, surfactants, and lactic acid, which can be used alone or in combination for printing. The glue is mixed. In the present invention, the first printing paste is prepared by mixing and dispersing the above-mentioned beam-proofing agent in the printing paste, which is either one of the aqueous solution that can be gelatinized and the base paste as the gelling agent. By using the other printing paste that does not contain the beam-proofing agent as the second printing paste, and printing both partial patterns or the entire surface of the fabric one after another,
On the area where two types of printing pastes are deposited on the target fabric field, a beam-proofing paste in which gel particles containing a resisting agent are coagulated and formed to an appropriate size is obtained. This prevents migration from the glue into the fiber structure of the fabric. In addition, among the above-mentioned resist dyes, there are those that can themselves act as gelling agents, or those that have salting-out and decomposition properties for dyes, as well as stannous chloride and stannous chloride that exhibit gelling ability. It should be noted that it also contains substances such as ferrous iron and ferrous sulfate, and if the latter of these anti-beam resisting agents is used, it will be extremely effective compared to the structure of the present invention. It is. Thus, when carrying out the present invention, a printing lake consisting of a gelatinable paste aqueous solution in which a resisting agent is mixed and a printing paste consisting of a base paste as a gelling agent, or a gel in which a resisting agent is blended. Two types of combinations are obtained: a printing paste consisting of a base paste as a curing agent and a printing paste consisting of an aqueous paste solution capable of gelatinization. Therefore, the temporal relationship between the printing operations of the two printing pastes on cloth in each combination is In addition, a total of four methods of forming resist dyeing paste are established. That is, for example, one specific method is to print an arbitrary pattern with a printing paste made of a gelatinable paste aqueous solution containing a beam-proofing agent on the fabric tail, and then print with a printing paste made of a base paste as a gelling agent. The paste can be printed so as to overlap the pattern, or it can be applied not only to the pattern but also to the entire surface of the cloth, to form a beam-proofing paste in the area where the two printing pastes meet. However, by reversing the top and bottom order, two convenient combinations can be obtained.Furthermore, in the combination of adding a beam-proofing agent to the base glue, which is a gelling agent, the time required for stamping and lacquering on cloth can also be reduced. Two combinations can be obtained depending on the context of the target.

本発明では、以上４通りの形成方法のいずれを採用して
も良く、防染剤濃度、防梁剤の水溶解度、防梁剤の安定
性、捺染糊の皮腹強度、捺染糊の水洗性、防梁効果、捺
染柄面積等により自由に選択する。In the present invention, any of the above four forming methods may be adopted, including the concentration of the resisting agent, the water solubility of the beam resisting agent, the stability of the beam resisting agent, the skin strength of the printing paste, and the water washability of the printing paste. , freely selected depending on beam-proofing effect, printing pattern area, etc.

本発明において、２種の捺染糊は、公知の捺染方法、例
えば、ローラープリント、フラットベッドオートマチッ
クスクリンプリント、ロータリンスクリンプリント、ハ
ンドプリント等により布に印捺し防梁糊が形成されるが
、一方がパディング、あるいはコーティングによっても
良く次いで必要ならば乾燥し、つづいて、地梁用染料を
含む公知の地梁糊または染色液をもって目的部分を被覆
する。In the present invention, two types of printing pastes are printed on cloth by known printing methods, such as roller printing, flatbed automatic screen printing, rotary screen printing, hand printing, etc., to form a beam-proofing paste. This may be padded or coated, then dried if necessary, and the desired area is then coated with a known base glue or stain containing a base dye.

この場合地梁用染料としては、直接染料、酸性染料、鍔
塩染料、反応性染料、建築染料、ナフトール染料、分散
性染料、カチオン性染料、フタロゲン染料等が挙げられ
る。地梁糊または染色液を施してのち、通常の乾燥を行
ない、次に蒸熱・乾燥処理等を行なうが、これらの熱処
理条件は、布を構成する繊維の種類により異なるものの
、既知の如く、１００ｑｏ乃至２１５ｏｏの範囲である
。尚、本発明で地染用染料が昇華転写捺染紙の如き担体
シート状の場合も同一の適用が可能なることは、云う迄
もない。熱処理後、印榛層の糊料残澄及び未染着染料等
を水洗及びソーピングで洗浄、除去するが、必要に応じ
て還元洗浄を行なう。In this case, examples of the base beam dye include direct dyes, acid dyes, salt dyes, reactive dyes, architectural dyes, naphthol dyes, disperse dyes, cationic dyes, and phthalogen dyes. After applying base glue or dyeing solution, normal drying is performed, and then steaming and drying treatments are performed.These heat treatment conditions vary depending on the type of fibers that make up the cloth, but as is known, 100 qo The range is from 215oo to 215oo. It goes without saying that the same application is possible in the present invention when the ground dyeing dye is in the form of a carrier sheet such as sublimation transfer printing paper. After the heat treatment, the paste residue and undyed dye in the printing layer are washed and removed by washing with water and soaping, and if necessary, reduction washing is performed.

斯くして、本発明の防梁糊を施した布には著しく鮮説な
防染模様が顕出する。In this way, the cloth coated with the anti-beam paste of the present invention exhibits an extremely vivid resist dyeing pattern.

尚、本発明において対象とする布常には、木綿、絹、羊
毛、麻等の天然繊維、レーヨン、キュプラ、ポリノジツ
ク、アセテート等の再生または半合成繊維並びにナイロ
ン，ポリエステル，ポリオレフィン等の合成繊維の織物
、編物及びそれらの混合物が挙げられる。The fabrics covered by the present invention include natural fibers such as cotton, silk, wool, and linen, recycled or semi-synthetic fibers such as rayon, cupro, polynosic, and acetate, and synthetic fibers such as nylon, polyester, and polyolefin. , knitted fabrics and mixtures thereof.

また、本発明の防梁糊を形成する２種の捺染糊のいずれ
か一方の中に着色用色素を配合して同様の防梁方法を行
なえば、優れた着色防染布を得る。Further, if a similar beam-proofing method is carried out by incorporating a coloring dye into either one of the two types of printing pastes forming the beam-proofing paste of the present invention, an excellent colored resist-dyed fabric can be obtained.

次に、本発明の効果を列挙する。Next, the effects of the present invention will be listed.

｛１’ 本発明の防染糊は、通常の印漆工程中に形成す
ることが特徴であり、防梁糊の製造に当たり特別な装置
、工程を要せず、極めて経済的である。{1' The resist dyeing paste of the present invention is characterized in that it is formed during the normal sealing and lacquer process, and it is extremely economical since no special equipment or process is required for producing the resisting paste.

‘２） 本発明の防梁糊は、捺染糊中の防梁剤がゲル状
に凝結しており、防染処理後中に印孫部分以外に惨出す
ることがなく、従って鮮明な模様の郡が得られ、また防
染剤の防染剤の防梁糊層から布内部への移行が防止され
るため、比較的薄い防梁糊層の形成によって従来法より
特段に優れた防梁効果が得られる。'2) In the beam-proofing paste of the present invention, the beam-proofing agent in the printing paste is condensed in a gel-like form, and does not come out other than in the print area after the resist dyeing process, so that a clear pattern can be created. In addition, the migration of the dye resist agent from the beam-proof glue layer to the interior of the fabric is prevented, resulting in a beam-proofing effect that is particularly superior to that of conventional methods due to the formation of a relatively thin beam-proof glue layer. is obtained.

脚 本発明の防梁糊は、防梁剤がゲル中に封入されてお
り安定であり、防染処理中に防梁力を発揮し、またゲル
化せる防梁剤が水洗脱糊中に布へ再付着せず・防梁部分
の汚染・やけ・餅ヒを起こすことがない。Legs The beam-proofing paste of the present invention is stable because the beam-proofing agent is encapsulated in the gel, and exhibits beam-proofing power during the resist dyeing process. It does not re-adhere to the fabric and does not cause contamination, burns, or sticky spots on the beam guard.

■ 本発明においては、２種類の捺染糊にて高濃度の防
染糊を形成させることができ、各々の捺染糊はいかなる
組織の布常上へも容易に印漆することが可能であり、従
釆の単独の防染糊のみにて印漆する方法による布の選択
性が不要である。■ In the present invention, a highly concentrated resist dyeing paste can be formed using two types of printing pastes, and each printing paste can be easily imprinted onto fabrics of any structure; There is no need for the selectivity of the fabric due to the method of lacquering with only a single resist dyeing paste.

‘５１本発明の防染織は、布上で形成されるため、従来
の防染糊の如く保管中に変質、劣化を起すことなく安全
である。'51 Since the resist dyeing fabric of the present invention is formed on cloth, it is safe and does not undergo deterioration or deterioration during storage unlike conventional resist dyeing pastes.

実施例 １ カルボキシメチルセルロース５重量部（以下「重量部」
を「部」と略す）、ペクチン５部、尿素２部及び水織部
にてゲル化しうる捺染糊（粘度８００比．ｐ．ｓ）を調
製し、オートマックスクリン捺染機により、ポリエステ
ルニット布上、直径５肌間隔の水玉模様スクリン型（９
００メッシュ）にて印捺した。Example 1 5 parts by weight of carboxymethylcellulose (hereinafter "parts by weight")
(abbreviated as "part"), 5 parts of pectin, 2 parts of urea, and a printing paste (viscosity 800 ratio p.s) that can be gelatinized with water are prepared, and printed on polyester knit cloth using an automaxklin printing machine. Polka dot screen type with diameter of 5 skins apart (9
00 mesh).

次いで、燐酸第一錫５部、塩化第一錫２部、酒石酸０．
５部、グリセリン２部、ヒマシ油０．５部、ナフカクリ
スタルゴム２碇郡及び水７碇都からなる防染剤を含みゲ
ル化館を有する捺染糊を用いて、同一模様スペアにて同
一個所に一致させて重ねて、印捺し、１２０℃、１分間
の熱風乾燥を施し、水玉模様の防梁糊を形成させた。該
防梁糊形成布に対して、グラビアコーティングマシンに
て、分散染料たるミケトンポリェステルジスチヤージブ
ルーＲ（商品名）１礎部、尿素２部、酒石酸１部及びメ
ープロガムＮＰ（商品名）６％水溶液８７部からなる地
梁糊を全面印捺した。Next, 5 parts of stannous phosphate, 2 parts of stannous chloride, and 0.0 parts of tartaric acid were added.
5 parts of glycerin, 0.5 parts of castor oil, 2 parts of naphka crystal rubber, 7 parts of water, and a gelatinized printing paste containing a resisting agent. The sheets were overlapped in the same manner as above, printed, and dried with hot air at 120° C. for 1 minute to form a polka dot pattern of beam-proofing paste. Using a gravure coating machine, 1 part of the disperse dye Miketon Polyester Discharge Blue R (trade name), 2 parts of urea, 1 part of tartaric acid, and Mapro Gum NP (trade name) were applied to the beam-proofing paste-forming fabric. ) A paste made of 87 parts of a 6% aqueous solution was printed on the entire surface.

その後、１２０℃、１分間乾燥し、高圧スチーマ−によ
り１３０ｑｏにて２０分蒸熱処理を行ない、水洗、ソー
ピングを行ない、更にリダクションクリニングを施し乾
燥した。かくして、濃紺地上に鮮明な白色防染水玉模様
を有するポリエステルニット布が得られた。比較例とし
て、本実施例に用いた２種の捺染糊を高速度縄梓下に混
合し、次いで３本ローフーミルを３回通過させて防染糊
を製し、本実施例同様に印漆（但し、１回のみ）し、防
染処理するに、かなり良好な防染効果を示したが、水玉
模様中に若干の不防染部分たるピンホール状の青色班点
が生じ不十分であった。Thereafter, it was dried at 120 DEG C. for 1 minute, steamed for 20 minutes at 130 qo using a high-pressure steamer, washed with water, soaped, and further subjected to reduction cleaning and dried. In this way, a polyester knit cloth having a clear white resist-dyed polka dot pattern on a dark blue ground was obtained. As a comparative example, the two types of printing pastes used in this example were mixed under a high-speed rope and then passed through a 3-loaf mill three times to produce a resist dyeing paste. However, when resist dyeing was applied (only once), it showed a fairly good resist dyeing effect, but it was insufficient as some pinhole-like blue spots, which were unresist dyed areas, appeared in the polka dot pattern. .

また、実施例中の防染剤含有捺染糊にて同一型で２回印
捺し同様の防染処理を施したが、著しくピンホールの多
い水玉模様となり、また非防梁部周辺が変色すると共に
防梁部分が褐変せる結果が得られ、本発明とは歴然たる
差があった。In addition, although the same mold was printed twice using the printing paste containing the resisting agent in the example and the same resisting treatment was applied, the result was a polka dot pattern with many pinholes, and the area around the non-resistance part was discolored. The result was that the girder part turned brown, which was a clear difference from the present invention.

実施例 ２ アルギン酸ソーダ４％水溶液８３部、微粉末状の水蒸気
賦活炭８部、酸性白土５部、ジェチレングリコール２部
及びアシッドローダミンＢ（商品名、酸性染料）２部を
均一に′混合して、防染剤を含むゲル化しうる糊料から
なる捺染糊（粘度８５０比．ｐ．ｓ）を調製し、ロータ
リィスクリソ捺染機により、ナイロンちりめんジョーゼ
ット布上、大きさ１〜５肋の乱性模様ニッケル円筒砂（
８００メッシュ）にて印捺した。Example 2 83 parts of a 4% aqueous solution of sodium alginate, 8 parts of finely powdered steam-activated carbon, 5 parts of acid clay, 2 parts of diethylene glycol, and 2 parts of acid rhodamine B (trade name, acid dye) were uniformly mixed. Then, a printing paste (viscosity 850 ratio.ps) consisting of a gelatinable paste containing a dye resisting agent was prepared, and printed on a nylon crepe georgette cloth with a size of 1 to 5 ribs using a rotary screen printing machine. Random pattern nickel cylindrical sand (
800 mesh).

次いでゲル化剤たるアラビアゴム５碇郭及び水５の部か
らなる捺染湖を用いて、該布全面を同円筒紗（８００メ
ッシュ）全面型で均一に被覆し、１００００、２分間の
乾燥を施し、乱星模様部分には防梁糊を形成させた。次
に、該防染糊形成布に対して、ローラー捺染機を使用し
て、アイゼンオパールブラックニューコンク（商品名）
５部、グリェシンＡ（商品名）５部、インダルカＰＡ−
３（商品名）６部及び水８４部からなる地梁糊を全面無
地調刻版（ローレツト＃２０）にて全面被覆し、常圧蒸
熱１０ぴ０、３０分間処理し、水洗、乾燥した。斯くし
て、黒地上に鮮桃色の鮮鋭な着色防梁乱星模様を有する
ナイロン布が得られた。比較例として、本実施例に使用
した防梁剤を含むゲル化しうる糊料からなる捺染湖のみ
を用いて乱星模様を同機印捺し、同一処理を施すに、防
梁効果は良好なるも、活性炭が布組織中に固着し脂赤色
となった。Next, the entire surface of the fabric was uniformly coated with the same cylindrical gauze (800 mesh) using a printing lake consisting of 5 parts of gum arabic as a gelling agent and 5 parts of water, and dried for 2 minutes at 10,000 ml. , A barrier glue was formed on the random star pattern part. Next, using a roller printing machine, the resist-dyed paste-formed fabric was coated with Eisen Opal Black New Conc (trade name).
5 parts, Gliescin A (product name) 5 parts, Indaruka PA-
The entire surface was coated with a base glue consisting of 6 parts of 3 (trade name) and 84 parts of water using a plain color control plate (Knurling #20), steamed at 10 pm for 30 minutes, washed with water, and dried. In this way, a nylon cloth having a sharply colored bright pink star pattern on a black background was obtained. As a comparative example, a random star pattern was printed on the same machine using only the printing lake made of a gelatinable paste containing the beam-proofing agent used in this example, and when the same treatment was applied, the beam-proofing effect was good. Activated carbon stuck to the fabric and turned a greasy red color.

之をソーピング溶中にて１時間水洗して脱糊するに、や
や明るくなったものの殆んど効果が無く、また、地染め
黒色が灰化する程になつた。実施例 ３ 実施例２の捺染糊を前後逆にて同一防染処理を施し、即
ち全面印漆後に模様を印捺したが、殆んど同等の防梁効
果が得られた。When I washed it with water in a soaping solution for 1 hour to remove the size, it became a little brighter, but there was almost no effect, and the black color of the dyed base turned to ash. Example 3 The printing paste of Example 2 was subjected to the same resist dyeing treatment with the front and back reversed, that is, the pattern was printed after the entire surface was lacquered, but almost the same beam resisting effect was obtained.

尤も、印漆作業能率は、実施例２より型踏み等において
やや劣る傾向を示した。実施例 ４ 実施例２の防染剤を含むゲル化しうる糊料からなる捺染
級中のアシツドローダミンＢ（商品名）を除きたるもの
からなる捺染糊を、ナイロン布に替えてポリエステルジ
ョーゼット布上にに施し、次いでアラビアゴム糊を全面
印捺して得た防梁糊形成布を用い、あらかじめ準備せる
ところの、マッミロンブラックＫＳＰ（商品名、昇華転
写捺染用分散染料の印刷インキ）５礎部、エチルセルロ
ース５部、ィソプチルアルコール４５部にてコート紙上
に全面グラビア版（８５仏，６０ム）を用いて印刷せる
マッミロン転写紙（商品名）と共に重ねて、カレンダー
式熱転写機にて２０５ｑ０、２５秒間熱処理を施した。However, the lacquer work efficiency tended to be slightly inferior to that of Example 2 in stamping and the like. Example 4 A printing paste consisting of a gelatinable paste containing a dye resisting agent in Example 2 except Ashitsurhodamin B (trade name) was replaced with nylon cloth and a polyester georgette cloth was used. Mamilon Black KSP (trade name, disperse dye printing ink for sublimation transfer printing) 5 bases, which can be prepared in advance using a beam-proofing paste-forming fabric obtained by applying gum arabic paste on the top and then printing gum arabic paste on the entire surface. Coated paper with 5 parts of ethyl cellulose and 45 parts of isoptyl alcohol was layered with Mamillon transfer paper (trade name), which can be printed using a full-surface gravure plate (85 mm, 60 mm), and 205 q0 was coated with a calendar-type thermal transfer machine. , heat treatment was performed for 25 seconds.

斯くして黒地上に鮮鋭なる白色乱星防梁模様を有するポ
リエステルジョーゼット布が得られた。実施例 ５ ポリビニルアルコール５％水溶液８礎都及びアニオン交
≠剣樹脂粉末２＄部をコロイドミルにて混合分散させ、
防梁剤を含むゲル化しうる糊料からなる捺染湖を調製し
、ハンドプリントにて絹一越布上、幅０．５側〜１．５
側の線柄乱格子模様のスクリン版（１０００メッシュ）
を用いて印捺した。In this way, a polyester georgette cloth having a sharp white random star beam pattern on a black background was obtained. Example 5 2 parts of 5% polyvinyl alcohol aqueous solution 8 bases and anionic resin powder were mixed and dispersed in a colloid mill,
A printing lake made of a gelatinable paste containing a beam-proofing agent was prepared, and hand-printed onto a silk cloth with a width of 0.5 to 1.5 mm.
Screen version with random grid pattern on the side (1000 mesh)
It was printed using.

次いでポリビニルアルコールのゲル化剤たるカルボキシ
メチルセルロース５部、更に同じくゲル化剤兼元糊たる
ナフカクリスタルゴム１の郡及び水８５部からなる捺染
糊を用いて、同一模様スペア型にて同一個所に一致させ
て重ねて印捺し、引続き乾燥せずに実施例２に用いた黒
色地染色棚を同じく全面スクリン版（１２００メッシュ
）を用いて布全面に印捺し、８０００、３分間乾燥し常
圧蒸熱４５分間を施し、水洗、乾燥した。斯くして、黒
地上に鮮鉄なる白色乱格子防梁模様の優れた正絹捺染布
が得られた。尚、比較例として、本実施例の防梁剤を含
むゲル化し得る糊料からなる捺染糊のみにて印捺し、同
様の防染処理を施すに、防梁効果がかなり劣り、且つ、
水洗脱糊中に未染着の染料が防梁部分を著しく汚染した
。Next, using a printing paste consisting of 5 parts of carboxymethyl cellulose, which is a gelling agent for polyvinyl alcohol, and 1 part of naphka crystal rubber, which is also a gelling agent and base paste, and 85 parts of water, a spare mold with the same pattern was applied to the same place. Then, without drying, the black background dyeing shelf used in Example 2 was used to print on the entire surface of the cloth using the same screen plate (1200 mesh), dried at 8000 ℃ for 3 minutes, and then steamed under normal pressure at 45 ℃. It was washed with water and dried. In this way, an excellent pure silk printed fabric with a bright white irregular lattice beam pattern on a black background was obtained. As a comparative example, printing was carried out only with a printing paste made of a gelatinable paste containing the beam-proofing agent of this example, and when the same resisting treatment was applied, the beam-proofing effect was considerably inferior, and
During washing and descaling, the undyed dye significantly contaminated the girders.

之は、恐らくイオン交換樹脂が組織中に固着せる結果と
考えられる。実施例 ６
、実施例５の捺染糊２種を逆の順序に印捺し、同一
の防染処理を施したところ、全く同一の鮮明なる防染模
様が得られた。This is probably a result of the ion exchange resin being fixed in the tissue. Example 6
When the two printing pastes of Example 5 were printed in the reverse order and subjected to the same resist dyeing treatment, exactly the same clear resist dyeing pattern was obtained.

実施例 ７ 実施例５のゲル化剤を含む捺染糊を水にて５０％に稀釈
させたる水溶液中に絹布を浸潰して絞り乾燥せるものに
、同実施例の防梁剤を含むゲル化しうる捺染糊を同模様
で印捺し、同様の防梁処理を施したところ、殆んど同じ
く良好な防梁効果を示した。Example 7 A silk cloth is immersed in an aqueous solution prepared by diluting the printing paste containing the gelling agent of Example 5 to 50% with water and then squeezed to dry. When printing paste was printed with the same pattern and the same beam-proofing treatment was applied, almost the same good beam-proofing effect was obtained.

Claims (1)

【特許請求の範囲】 １ ゲル化しうる糊料水溶液及びゲル化剤たる元糊のう
ちの何れか一方の捺染糊及び他方に防染剤を配合して成
る捺染糊の２種の捺染糊を用いて、布帛上に両者を相前
後して部分模様乃至は全面状に印捺し、該布帛上におい
て前記２種の捺染糊が重積する部分に防梁剤含有のゲル
粒子から成る防染糊を形成することを特徴とする、布帛
上防染糊形成方法。 ２ 防染剤がゲル化能を有する、特許請求の範囲第１項
記載の布帛上防染糊形成方法。 ３ 防染剤が色素の塩析性及び分解性を併用すると共に
ゲル化能をも有する、特許請求の範囲第１項記載の布帛
上防染糊形成方法。[Scope of Claims] 1. Two types of printing pastes are used: one consisting of a gelatinable paste aqueous solution and a base paste serving as a gelling agent, and the other containing a resisting agent. Then, both are printed one after another on a partial pattern or the entire surface of the fabric, and a resist dyeing paste made of gel particles containing a beam preventive agent is applied to the part of the fabric where the two types of printing pastes are superimposed. 1. A method for forming resist dyeing paste on fabric, characterized by forming. 2. The method for forming resist dyeing paste on fabric according to claim 1, wherein the resist dyeing agent has a gelling ability. 3. The method for forming a resist dyeing paste on fabric according to claim 1, wherein the resist dye has both salting-out and decomposition properties of the dye and also has a gelling ability.