JPS60231868A - Aqueous composition for softening fiber product - Google Patents
Aqueous composition for softening fiber productInfo
- Publication number
- JPS60231868A JPS60231868A JP60081217A JP8121785A JPS60231868A JP S60231868 A JPS60231868 A JP S60231868A JP 60081217 A JP60081217 A JP 60081217A JP 8121785 A JP8121785 A JP 8121785A JP S60231868 A JPS60231868 A JP S60231868A
- Authority
- JP
- Japan
- Prior art keywords
- weight
- composition
- softener
- cationic
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/645—Mixtures of compounds all of which are cationic
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/001—Softening compositions
- C11D3/0015—Softening compositions liquid
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
- C11D1/523—Carboxylic alkylolamides, or dialkylolamides, or hydroxycarboxylic amides (R1-CO-NR2R3), where R1, R2 or R3 contain one hydroxy group per alkyl group
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
- C11D1/526—Carboxylic amides (R1-CO-NR2R3), where R1, R2 or R3 are polyalkoxylated
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/62—Quaternary ammonium compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.
Description
【発明の詳細な説明】
本発明はａｍ製品柔軟用水性組成物に係り、特に水不溶
性カチオン性の繊維製品柔軟剤を含む組成物に係る。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to aqueous compositions for softening am products, and more particularly to compositions containing water-insoluble cationic textile softeners.
英国特許公開箱１，１０４．４４１号明細書（ＵＮＩＬ
ＥＶＥＲ／ＴｔｌＮＥ）は、最高１０重量％の水不溶性
カチオン性のｍＨ製品柔軟剤と、柔軟作用を増強しかつ
処置した繊維製品に対して帯電防止性仕上がりを与える
べく添加される脂肪酸エタノールアミドとを含む繊維製
品柔軟用水性組成物を開示している。上記組成物に、製
品の稠度（ｔｈｔｃｋｎｅｓｓ）を調整するために炭酸
ナトリウムを添加することもあるとされているが、カチ
オン性柔軟剤が水不溶性であるために、特に貯蔵時に製
品の粘度が増大する欠点があった。British Patent Publication Box 1,104.441 (UNIL
EVER/TtlNE) contains up to 10% by weight of water-insoluble cationic mH product softeners and fatty acid ethanolamides which are added to enhance the softening action and provide an antistatic finish to the treated textiles. Discloses an aqueous composition for softening textile products comprising: It is said that sodium carbonate is sometimes added to the above composition to adjust the consistency of the product, but since the cationic softener is water-insoluble, the viscosity of the product increases, especially during storage. There was a drawback.
本出願人は、製品に特殊な電解質を含めることにより、
貯蔵時の安定性に優れている粘度のより低い製品が得ら
れるという驚くべき知見を得た。By including special electrolytes in the product, the applicant
The surprising finding was that a lower viscosity product with excellent storage stability was obtained.
本発明により提供される繊維製品柔軟用水性組成物は、
ｉ）水性ベース；
ｉｉ）水不溶性カチオン性のＩｌ雑製品柔軟剤少なくと
も１重量％〜１０重間％未満；
１ｉｉ）少なくとも１０個の炭素原子を含む脂肪酸アミ
ドのアルキレンオキサイド付加物であって、前記付加物
中に含まれるアルキレンオキサイド基が平均５個未満で
ある非イオン性物質少なくとも１重量％、ただしカチオ
ン性柔軟剤と非イオン性物質との総量が３６重量％以下
、好ましくは約２５重量％以下である；および
ｉｖ）リチウム、マグネシウム、カルシウムおよびアル
ミニウムのイオン性塩およびその混合物から選択される
電解質；
からなる。The aqueous textile softening composition provided by the present invention comprises: i) an aqueous base; ii) a water-insoluble cationic Il miscellaneous fabric softener from at least 1% by weight to less than 10% by weight; 1ii) at least 10 carbon atoms. an alkylene oxide adduct of a fatty acid amide containing atoms, said adduct containing on average less than 5 alkylene oxide groups, at least 1% by weight of a nonionic substance, provided that the cationic softener and the nonionic substance and iv) an electrolyte selected from ionic salts of lithium, magnesium, calcium and aluminum and mixtures thereof;
組成物中のカチオン性柔軟剤の聞は、６重量％以上〜１
０［１％未満が好ましく、より好ましくは約７重量％〜
約９重問％である。組成物中の非イオン性物質は１０重
量％未満が好ましく、より好ましくは約２重量％〜約８
重量％である。カチオン性柔軟剤と非イオン性物質の総
量は少なくとも１２重量％未満であるのが好ましい。非
イオン性物質に対するカチオン性柔軟剤の重量比は、少
なくとも１：１、例えば約１．５：１〜約５：１が好ま
しい。The content of the cationic softener in the composition is 6% by weight or more to 1% by weight.
0 [preferably less than 1%, more preferably from about 7% by weight
Approximately 9% of questions were asked. Preferably, the non-ionic material in the composition is less than 10% by weight, more preferably from about 2% to about 8% by weight.
Weight%. Preferably, the total amount of cationic softener and nonionic material is at least less than 12% by weight. Preferably, the weight ratio of cationic softener to nonionic material is at least 1:1, such as from about 1.5:1 to about 5:1.
水不溶性カチオン性の１１Ｉｆｆ製品柔軟剤としては、
ｐＨ２，５および２０℃での水溶解度が１０９／ρ未満
の繊維製品−実質的にカチオン性（ｆａｂｒｉｃ−ｓｕ
ｂｓｔａｎｔｉｖｅ ｃａＮｏｎｉｃ）化合物であれば
よく、最も好ましい物質は、２本の０１２−０２４アル
キル又はアルケニル鎖を有し、任意に−ＯＨ，−０−。Water-insoluble cationic 11Iff product softeners include:
Textile products with a water solubility of less than 109/ρ at pH 2,5 and 20°C - substantially cationic (fabric-su
The most preferred materials have two 012-024 alkyl or alkenyl chains, optionally -OH, -0-.
−ＣＯＮＨ，−ＣＯＯ−等の官能基で置換もしくは中断
された第４級アンモニウム塩である。It is a quaternary ammonium salt substituted or interrupted with a functional group such as -CONH or -COO-.
実質的に水不溶性の第４級アンモニウム化合物は式
（式中、ＲおＪ：びＲ２は炭素数約１２〜約２４のハイ
ドロカルビル基を表わし、Ｒ３およびＲ４は炭素数１〜
約４のハイドロカルビル基を表わし、Ｘは陰イオン好ま
しくはハロゲン化物、メチル或いはエチルサルフェート
から誘導される陰イオンである）を有する。これら第４
級柔軟剤の代表例としては、シタロウ（ｄｉｔａｌｌｏ
ｗ）ジメチルアンモニウムクロライド−ジタロウジメチ
ルアンモニウムメチルサルフェート；ジオクタデシルジ
メチルアンモニウムクロライド；ジ（水素化タロウアル
キル）ジメチルアンモニウムクロライド；ジオクタデシ
ルジメチルアンモニウムクロライド；ジエイコシルジメ
チルアンモニウムクロライド：ジドコシルジメチルアン
モニウムクロライド；ジ（水素化タロウ）ジメチルアン
モニウムメチルサルフェート；ジヘキサデシルジエチル
アンモニウムクロライド；ジ（ココナツトアルキル）ジ
メチルアンモニウムクロライドニジ（ココナツトアルキ
ル）ジメチルアンモニウムメトサルフェートが挙げられ
る。シタロウジメチルアンモニウムクロライド。Substantially water-insoluble quaternary ammonium compounds have the formula
It represents about 4 hydrocarbyl groups, with X having an anion, preferably an anion derived from halide, methyl or ethyl sulfate. The fourth of these
A typical example of grade fabric softener is ditallo.
w) Dimethylammonium chloride - ditallow dimethyl ammonium methyl sulfate; dioctadecyl dimethyl ammonium chloride; di(hydrogenated tallowalkyl) dimethyl ammonium chloride; dioctadecyl dimethyl ammonium chloride; dieicosyl dimethyl ammonium chloride: didocosyl dimethyl ammonium chloride; Di(hydrogenated tallow)dimethylammonium methylsulfate; dihexadecyldiethylammonium chloride; di(coconut alkyl)dimethylammonium chloride di(coconut alkyl)dimethylammonium methosulfate. Shitarou dimethyl ammonium chloride.
ジ（水素化タロウアルキル）ジメチルアンモニウムクロ
ライド、ジ（ココナツトアルキル）ジメチルアンモニウ
ムクロライドやジ（ココナツトアルキル）ジメチルアン
モニウムメトサルフェートがより好ましい。Di(hydrogenated tallowalkyl)dimethylammonium chloride, di(coconut alkyl)dimethylammonium chloride and di(coconut alkyl)dimethylammonium methosulfate are more preferred.
別の群の水不溶性カチオン性物質としては式（式中、Ｒ
６は炭素数１〜４．好ましくは１γ２のアルキルまたは
ヒドロキシアルキル基であり、Ｒ７は炭素数８〜２５の
アルキルまたはアルケニル基であり、Ｒ８は炭素数８〜
２５のアルキルまたはアルケニル基であり、Ｒ９は水素
または炭素数１〜４のアルキル基であり、八−は陰イオ
ン好ましくはハロゲン化物、メトサルフェート或いはエ
トサルフェートから誘導される陰イオンである）を有す
ると考えられているアルキルイミダゾリニウム塩が好ま
しい。好ましいイミダゾリニウム塩は、１−メチル−１
−（タロウィルアミド−）ニブル−２−タロウィル−４
，５−ジヒドロイミダゾリニウムメトサルフェートおよ
び１−メチル−１−（パルミトイルアミド゛）エチル−
２−オクタデシル−４，５−ジヒドロ−イミダゾリニウ
ムクロライドである。他の有用なイミダゾリニウム物質
は、２−ヘプタデシル−１−メチル−１−（２−ステア
リルアミド）−エチル−イミダゾリニウムクロライドお
よび２−ラウリル−１−ヒドロキシエチル−１−オレイ
ル−イミダゾリニウムクロライドである。米国特許第４
．１２７．４８９号明細書に記載されているイミダゾリ
ニウム繊ＩＩ製品柔軟化成分も適当である。Another group of water-insoluble cationic substances includes the formula (wherein R
6 is carbon number 1-4. Preferably it is a 1γ2 alkyl or hydroxyalkyl group, R7 is an alkyl or alkenyl group having 8 to 25 carbon atoms, and R8 is an alkyl or alkenyl group having 8 to 25 carbon atoms.
25 alkyl or alkenyl group, R9 is hydrogen or an alkyl group having 1 to 4 carbon atoms, and 8- is an anion (preferably an anion derived from a halide, methosulfate or ethosulfate). Preferred are alkylimidazolinium salts which are believed to have the following properties. A preferred imidazolinium salt is 1-methyl-1
-(Taroviramide-)Nibble-2-Tarovir-4
, 5-dihydroimidazolinium methosulfate and 1-methyl-1-(palmitoylamido)ethyl-
2-octadecyl-4,5-dihydro-imidazolinium chloride. Other useful imidazolinium materials are 2-heptadecyl-1-methyl-1-(2-stearylamido)-ethyl-imidazolinium chloride and 2-lauryl-1-hydroxyethyl-1-oleyl-imidazolinium It is chloride. US Patent No. 4
．． Also suitable are the imidazolinium fiber II product softening components described in US Pat. No. 127.489.
上記種類の代表的な市販物質は、第４級アンモニウム化
合物としてはＡｒＱｕａｃｌ ２ＨＴ （アクツオ製）
：Ｎｏｒａｍｉｕｍ Ｈ２ＳＨ（ＣＥＫＡ製）；Ａｌ
１ｑｕａｔ−２ＨＴ（ゼネラル・ミルズ（株）の商標）
であり、イミダゾリニウム化合物としてはＶａｒｉｓｏ
ｆｔ ４７５（Ｓｈｅｒｅｘ Ｃｏｍｐａｎｙ；コロン
ブス、オハイオの商標）およびｔｔｅｗｏｑｕａｔ縁７
５０＜１ （ＲＥ紳Ｏの商標）である。Typical commercially available substances of the above type include ArQuacl 2HT (manufactured by Akutsuo) as a quaternary ammonium compound.
:Noramium H2SH (manufactured by CEKA); Al
1quat-2HT (trademark of General Mills Co., Ltd.)
As an imidazolinium compound, Variso
ft 475 (trademark of Sherex Company; Columbus, Ohio) and ttewoquat rim 7
50<1 (RE Gen O's trademark).
非イオン性物質は少なくとも上記した各種脂肪酸アミド
のアルキレンオキサイド付加物を含み、他のアルコキシ
化もしくは非アルコキシ化非イオン性物質を含んでいて
もよい。The nonionic substance includes at least the alkylene oxide adducts of the various fatty acid amides described above, and may also include other alkoxylated or non-alkoxylated nonionic substances.
本発明で使用される脂肪酸アミドのアルキレンオキサイ
ド付加物は好ましくは、一般式（式中、Ｒ１０は炭素数
が少なくとも１０．より好ましくは１０〜２２のアルキ
ルもしくはアルケニル基であり、ｎは２または３であり
、ＸおよびＺは合計４．０以下好ましくは約０．５〜約
３．５であり、Ｘおよび２の一方が０であってもよい）
を有する。前記物質として、りＯつ七ノエタノールアミ
ドおよびジェタノールアミド、並びに対応するココナツ
ト化合物およびツヤ化合物（ｓｏｙａｃｏｍｐｏｕｎｄ
）が例示される。The alkylene oxide adduct of fatty acid amide used in the present invention preferably has the general formula and the total of X and Z is 4.0 or less, preferably about 0.5 to about 3.5, and one of X and 2 may be 0)
has. Said substances include ethanolamide and jetanolamide, and the corresponding coconut compounds and soya compounds.
) is exemplified.
１１０ ｓｅｃ”せん断速度で測定した生成物の粘度は
、約１５０ＣＰ未満好ましくは約２０〜約１００ＣＰで
あり、生成物をそのまま繊維製品リンス液に添加しても
、また水で予め希釈してもよい。The viscosity of the product, measured at a 110 sec" shear rate, is less than about 150 CP, preferably from about 20 to about 100 CP, and the product can be added neat to the textile rinse solution or pre-diluted with water. .
本発明組成物は実質的にアニオン性物質を、特にアニオ
ン性界面活性物質を含まないことが好ましい。そのよう
な物質が存在する場合、アニオン性物質に対するカチオ
ン性物質の重量比は１０：１以上例えば１００：１以上
が好ましい。Preferably, the composition according to the invention is substantially free of anionic substances, in particular free of anionic surfactants. If such substances are present, the weight ratio of cationic to anionic substances is preferably 10:1 or more, for example 100:1 or more.
組成物は生成物の粘度調整を補助する目的で特殊な電解
質を含む。組成物中の電解質量は、無水塩で換算して約
０．０１〜約０．５＠量％が適当であり、より好ましく
は約０．０２〜約０．２％である。適当な電解質として
は、塩化リチウム。The composition contains special electrolytes to help control the viscosity of the product. The amount of electrolyte in the composition is suitably about 0.01 to about 0.5% by weight, more preferably about 0.02 to about 0.2% in terms of anhydrous salt. A suitable electrolyte is lithium chloride.
塩化カルシウム、塩化マグネシウムや塩化アルミニウム
が例示される。これら電解質を２種またはそれ以上含む
混合物や前記電解質とナトリウム或いはカリウム塩との
混合物を使用してもよい。Examples include calcium chloride, magnesium chloride and aluminum chloride. A mixture containing two or more of these electrolytes or a mixture of the electrolyte and a sodium or potassium salt may be used.
組成物が、カチオン性繊維製品柔軟剤用溶媒を少量含ん
でいてもよい。事実、カチオン性原料にはしばしば溶媒
としてイソプロパツールが含まれている。イソプロパツ
ールあるいは他の０１−０４の１価アルコールが組成物
中に約５重量％未満含まれているのが好ましく、より好
ましくは約２．５重量％未満である。The composition may also include a small amount of a cationic textile softener solvent. In fact, cationic raw materials often contain isopropanol as a solvent. Preferably, less than about 5% by weight of isopropanol or other 01-04 monohydric alcohol is present in the composition, more preferably less than about 2.5% by weight.
組成物が更に、冷所貯蔵時の生成物の安定性を維持する
だめの物質を含んでいてもよい。前記物質としては、エ
チレングリコール、プロピレングリコール、グリセロー
ルやポリエチレングリコールの如き多価アルコールが例
示される。前記物質量は約０．５〜約５重１％が適当で
あり、約１．０〜２．０重量％が好ましい。The composition may further include substances that maintain the stability of the product during cold storage. Examples of the substance include polyhydric alcohols such as ethylene glycol, propylene glycol, glycerol, and polyethylene glycol. The amount of said material is suitably about 0.5 to about 5% by weight, preferably about 1.0 to 2.0% by weight.
更に本発明組成物は、着色剤、香料、保存料。Furthermore, the composition of the present invention contains coloring agents, fragrances, and preservatives.
消泡剤、光沢剤、乳白剤、’ＤＨ緩衝剤（組成物の１）
Ｈは約３〜約８例えば約４〜約６が好ましい）。Defoamers, brighteners, opacifiers, 'DH buffers (composition 1)
H is preferably about 3 to about 8, for example about 4 to about 6).
別の粘度調整剤、非カチオン性繊維製品コンディショニ
ング剤、収縮防止剤、しり防止剤、繊維製品縮み防止剤
、しみ抜き剤、防汚加工剤、殺菌剤。Separate viscosity modifiers, non-cationic textile conditioning agents, anti-shrink agents, anti-shrink agents, anti-shrink agents, stain removers, anti-fouling agents, bactericidal agents.
酸化防止剤や防腐剤等の他の任意成分を含んでもよい。Other optional ingredients such as antioxidants and preservatives may also be included.
本発明組成物は種々の方法で調製され得る。適当な方法
の一つは、カチオン性繊維製品梁軟剤と非イオン性物質
との溶融混合物を作り、この混合物を水に撹拌しながら
添加して分散液を作り、次いで電解質（例えば濃縮溶液
の形態で）と他の任意成分を添加する方法である。Compositions of the invention can be prepared in a variety of ways. One suitable method is to make a molten mixture of the cationic fiber beam softener and the nonionic material, add this mixture to water with stirring to form a dispersion, and then add the electrolyte (e.g. in concentrated solution). (form) and other optional ingredients.
本発明を実施例を参照しながら更に説明する。The present invention will be further explained with reference to Examples.
実施例中、部およびパーセントは全て重量部および重量
パーセントである。市販製品を使用した場合には、製品
中に含まれる活性物質の量で表示した。粘度は、１１０
５ｅｃ−１，２５℃でＨａａｋｅ回転粘度計（モデルＲ
Ｖ２）を用いて測定した。In the examples, all parts and percentages are by weight. When commercially available products were used, the amount of active substance contained in the product was indicated. The viscosity is 110
Haake rotational viscometer (model R) at 5ec-1,25℃
V2).
実施例１〜１２ 次表に示した処方に従って、組成物を調製した。Examples 1-12 Compositions were prepared according to the formulations shown in the table below.
まず、６５℃でカチオン性成分と非イオン性成分との溶
融混合物を作り、同じ温度で前記混合物を水に添加し、
撹拌して分散液を作り、飽和溶液の形態で電解質を添加
し、冷却し、次いで香料を添加して組成物を調製した。First, make a molten mixture of cationic and nonionic components at 65°C and add said mixture to water at the same temperature,
The composition was prepared by stirring to form a dispersion, adding the electrolyte in the form of a saturated solution, cooling, and then adding the perfume.
１００ｇ単位で組成物を調製した。撹拌は５００ ｒｐ
ＩＩｌで７分間行なった。Compositions were prepared in 100 g units. Stirring is 500 rp.
IIl for 7 minutes.
（注）
１）市販製品ニジ−硬化タロウジメチルアンモニウムク
ロライド〈約８２％−活性物質、残部−水およびイソプ
ロパツール）１１％タロウ モノエタノールアミドを１
％硬化タロウ脂肪酸で置ＩＩＡすることも可能である。(Note) 1) Commercially available product - hardened tallow dimethyl ammonium chloride (approximately 82% - active substance, balance - water and isopropanol) 11% tallow monoethanolamide 1
% hydrogenated tallow fatty acid is also possible.
（注）
２）ツヤ ジェタノールアミド
（Ｈａｃｋａｍｉｄｅ Ｓ ｅｘ Ｈｃ Ｉｎｔｙｒｅ
Ｃｏ）実施例１３および１４
非イオン性付加物中のアルキレンオキサイド基の数の影
響を調べるために、下記組成物を実施例１と同様にして
調製し、その粘度を測定した。(Note) 2) Gloss Jetanolamide (Hackamide S ex Hc Intyre)
Co) Examples 13 and 14 To investigate the influence of the number of alkylene oxide groups in the nonionic adduct, the following compositions were prepared in the same manner as in Example 1 and their viscosity was measured.
（注）
３ ） ＨＯＥＣＩＩＳＴ＾Ｇの市販製品（ココナツト
脂肪族モノエタノールアミドとエチレンオキサイド５モ
ルとの付加生成物）上記実施例から、分子中のエチレン
オキサイド基の数が５未満のエトキシ化アミドを使用し
て得られた製品の初期粘度は許容され得る程度に低く、
一方エチレンオキサイド基の数が５以上の場合には製品
の粘度が高く許容し得ない。(Note) 3) Commercial product of HOECIIST^G (addition product of coconut aliphatic monoethanolamide and 5 moles of ethylene oxide) From the above example, it is clear that an ethoxylated amide with less than 5 ethylene oxide groups in the molecule The initial viscosity of the product obtained using the product is acceptably low;
On the other hand, when the number of ethylene oxide groups is 5 or more, the viscosity of the product is unacceptably high.
出１１１人 ユニ９−バー た４０−ｔ″へンノートシ
τ−７′代理人 ｔＰ１！±川 口 義 雄
第１頁の続き
０発 明 者 ニドウィン・ライリス イギー、１
ス１１１Output 111 people Uni9-bar T40-t''hennotes τ-7' Agent tP1!± Yoshio Kawaguchi Continued from page 1 0 Inventor Nidwin Rylis Iggy, 1 S111
Claims (1)
なくとも１重量％〜１０＠量％未満： １ｉｉ）少なくとも１０個の炭素原子を含む脂肪酸アミ
ドのフルキレンオキサイド付加物であって、前記付加物
中に含まれるアルキレンオキサイド基は１分子あたり平
均５個未満である非イオン性物質少なくとも１重量％、
ただしカチオン性柔軟剤と非イオン性物質との総量は３
６重量％以下である：およびｉｖ）リチウム、マグネシ
ウム、カルシウムおよびアルミニウムのイオン性塩およ
びその混合物から選択される電解質： からなる繊維製品柔軟用水性組成物。 （２） 組成物中の水不溶性カチオン性の繊維製品柔軟
剤の量が６重量％以上である特許請求の範囲第１項に記
載の組成物。 （３） 組成物中の非イオン性物質の量が１０重量％未
満である特許請求の範囲第１項に記載の組成物。 （４） 水不溶性カチオン性の繊維製品柔軟剤と非イオ
ン性物質との重量比が少なくとも１：１である特許請求
の範囲第１項に記載の組成物。 （５〉 組成物中の電解質量が無水塩として換飾して０
．０１〜０．５重量％である特許請求の範囲第１項に記
載の組成物。 （６） カチオン性柔軟剤と非イオン性物質との溶融混
合物を水に撹拌しながら添加して分散液を作り、その後
電解質を添加することからなる特許請求の範囲第１項に
記載の繊維製品柔軟用水性組成物の製造方法。Claims: (1) i) Aqueous based: 11) Water-insoluble cationic 1iilft product softener from at least 1% by weight to less than 10% by weight: 1ii) Fulfillment of fatty acid amide containing at least 10 carbon atoms. at least 1% by weight of a nonionic substance, which is a lene oxide adduct, and the adduct contains on average less than 5 alkylene oxide groups per molecule;
However, the total amount of cationic softener and nonionic substance is 3
and iv) an electrolyte selected from ionic salts of lithium, magnesium, calcium and aluminum and mixtures thereof. (2) The composition according to claim 1, wherein the amount of water-insoluble cationic textile softener in the composition is 6% by weight or more. (3) The composition according to claim 1, wherein the amount of nonionic material in the composition is less than 10% by weight. (4) The composition of claim 1, wherein the weight ratio of water-insoluble cationic textile softener to nonionic material is at least 1:1. (5) The amount of electrolyte in the composition is reduced to 0 after being modified as an anhydrous salt.
．． 2. A composition according to claim 1, wherein the amount is 0.01 to 0.5% by weight. (6) A textile product according to claim 1, comprising adding a molten mixture of a cationic softener and a nonionic substance to water with stirring to form a dispersion, and then adding an electrolyte. A method for producing an aqueous composition for softening.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB8410319 | 1984-04-19 | ||
| GB848410319A GB8410319D0 (en) | 1984-04-19 | 1984-04-19 | Aqueous fabric softening composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS60231868A true JPS60231868A (en) | 1985-11-18 |
Family
ID=10559919
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP60081217A Pending JPS60231868A (en) | 1984-04-19 | 1985-04-16 | Aqueous composition for softening fiber product |
Country Status (7)
| Country | Link |
|---|---|
| EP (1) | EP0159922A3 (en) |
| JP (1) | JPS60231868A (en) |
| AU (1) | AU560746B2 (en) |
| CA (1) | CA1226407A (en) |
| ES (1) | ES8706195A1 (en) |
| GB (1) | GB8410319D0 (en) |
| ZA (1) | ZA852865B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2016011469A (en) * | 2014-06-27 | 2016-01-21 | 花王株式会社 | Method for producing emulsion composition |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1104441A (en) * | 1964-07-08 | 1968-02-28 | Unilever Ltd | Fabric conditioner |
| JPS50105997A (en) * | 1974-01-11 | 1975-08-21 | ||
| JPS58132173A (en) * | 1981-11-17 | 1983-08-06 | ザ・プロクタ−・エンド・ギヤンブル・カンパニ− | Softener composition for thick fabric |
| JPS58186673A (en) * | 1982-04-23 | 1983-10-31 | 三洋化成工業株式会社 | Softener composition for fiber product |
| JPS58186674A (en) * | 1982-04-23 | 1983-10-31 | 三洋化成工業株式会社 | Softening finish composition |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2605502A1 (en) * | 1976-02-12 | 1977-08-18 | Exquisit Kosmetik Gmbh | Washing and rinsing composition for softening textiles - nonionic surfactant, softening agent and polyglycol difatty acid ester |
| DE2930061A1 (en) * | 1979-07-25 | 1981-02-19 | Hoechst Ag | SOFT SOFTENER |
-
1984
- 1984-04-19 GB GB848410319A patent/GB8410319D0/en active Pending
-
1985
- 1985-04-15 AU AU41252/85A patent/AU560746B2/en not_active Ceased
- 1985-04-15 CA CA000479169A patent/CA1226407A/en not_active Expired
- 1985-04-16 JP JP60081217A patent/JPS60231868A/en active Pending
- 1985-04-17 EP EP85302717A patent/EP0159922A3/en not_active Withdrawn
- 1985-04-17 ZA ZA852865A patent/ZA852865B/en unknown
- 1985-04-17 ES ES542352A patent/ES8706195A1/en not_active Expired
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1104441A (en) * | 1964-07-08 | 1968-02-28 | Unilever Ltd | Fabric conditioner |
| JPS50105997A (en) * | 1974-01-11 | 1975-08-21 | ||
| JPS58132173A (en) * | 1981-11-17 | 1983-08-06 | ザ・プロクタ−・エンド・ギヤンブル・カンパニ− | Softener composition for thick fabric |
| JPS58186673A (en) * | 1982-04-23 | 1983-10-31 | 三洋化成工業株式会社 | Softener composition for fiber product |
| JPS58186674A (en) * | 1982-04-23 | 1983-10-31 | 三洋化成工業株式会社 | Softening finish composition |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2016011469A (en) * | 2014-06-27 | 2016-01-21 | 花王株式会社 | Method for producing emulsion composition |
Also Published As
| Publication number | Publication date |
|---|---|
| ES542352A0 (en) | 1987-06-01 |
| CA1226407A (en) | 1987-09-08 |
| ZA852865B (en) | 1986-12-30 |
| AU4125285A (en) | 1985-10-24 |
| ES8706195A1 (en) | 1987-06-01 |
| EP0159922A2 (en) | 1985-10-30 |
| GB8410319D0 (en) | 1984-05-31 |
| AU560746B2 (en) | 1987-04-16 |
| EP0159922A3 (en) | 1987-03-25 |
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