JPS60166394A - Waste oil fuel composition - Google Patents
Waste oil fuel compositionInfo
- Publication number
- JPS60166394A JPS60166394A JP2001884A JP2001884A JPS60166394A JP S60166394 A JPS60166394 A JP S60166394A JP 2001884 A JP2001884 A JP 2001884A JP 2001884 A JP2001884 A JP 2001884A JP S60166394 A JPS60166394 A JP S60166394A
- Authority
- JP
- Japan
- Prior art keywords
- waste
- fuel composition
- composition
- oil
- fuel
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/10—Biofuels, e.g. bio-diesel
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/30—Fuel from waste, e.g. synthetic alcohol or diesel
Landscapes
- Solid Fuels And Fuel-Associated Substances (AREA)
Abstract
Description
【発明の詳細な説明】
この発明は、重油スラッジまたは廃潤滑油(以下、両者
を含めて車に「廃油」という)を主成分とする燃料組成
物に関するもので、現状ではほとんどが廃棄の対象とさ
れているこれらの廃油を容易かつ低コストにおいて、日
常単独に使用できる完全な燃料に再生させる手段を提供
することを目的とする。[Detailed Description of the Invention] This invention relates to a fuel composition whose main components are heavy oil sludge or waste lubricating oil (hereinafter both are referred to as "waste oil" for cars), and currently most of them are subject to disposal. The purpose of the present invention is to provide a means to easily and at low cost regenerate these waste oils into a complete fuel that can be used independently on a daily basis.
ここにいう重油スラ・ンジとは、主として海上輸送用重
油タンカーの船底の沈澱物を洗浄水とともに汲み揚げた
、いわゆるプロースラッジを指すが、また、各所に建設
されている石油基地の重油貯蔵タンクの槽底沈澱物につ
いても同然である。The heavy oil sludge referred to here mainly refers to the so-called Pruss sludge, which is obtained by pumping up sediment from the bottom of heavy oil tankers used for maritime transport along with washing water, but it also refers to the heavy oil storage tanks constructed at various oil terminals. The same holds true for tank bottom sediment.
この発明者の研究によれば、このようなプロースラッジ
を蒸餡して完全に本分を除去したものは40重煮%以上
の可燃性油分を含んでおり、従って燃料として使用する
ことが充分にできるのであるが、蒸留に要するコストが
過大で実用できない。 。According to the inventor's research, such Pross sludge, which has been steamed to completely remove its main components, contains a flammable oil content of 40% or more, and is therefore sufficient to be used as fuel. However, the cost required for distillation is too high to be practical. .
従って、きわめて多量に発生するプロースラッジは現状
では用途がなく、然るべき地点まで陸上輸送した上、土
中に吸取させるなど、公害防止のため多額の経費をかけ
て処分されている。Therefore, the extremely large amount of Prose sludge that is generated currently has no use, and is disposed of by transporting it overland to an appropriate location and absorbing it into the soil, at great expense, in order to prevent pollution.
この発明によれば、上記したような重油スラッジにつき
、水分を30重量%以下に調整したものを主たる組成分
とするのであるが、上記した重油スラッジにかえ、廃潤
滑油を主たる組成物とすることができる。また、前記重
油スラッジと廃潤滑油の混合物がこの発明の燃料組成物
となりうろことも当然である。According to this invention, the main composition of heavy oil sludge as described above is one in which the water content is adjusted to 30% by weight or less, but instead of the above-mentioned heavy oil sludge, waste lubricating oil is used as the main composition. be able to. It is also natural that a mixture of the heavy oil sludge and waste lubricating oil can be used as the fuel composition of the present invention.
廃潤滑油は、主として自動車用エンジン、航空エンジン
等のガソリンエンジンや船舶用、発電用等のディーゼル
エンジンなどの内燃機関から発生放出されるもので、原
組成物である潤滑油そのものは重油の分溜加工物である
1石油系潤滑油、有機合成法により製造した合成潤滑油
などがあり、個々の銘柄については、その成分はきわめ
て区々である上、その発生地点がきオつめて多岐にわた
っているため、無価値物としてほとんど回収されること
もなく廃棄されているのが実情である。重油に較べて一
般に引火点が高いとはいうものの、その大部分は重油と
同様に可燃物である。Waste lubricating oil is mainly generated and released from internal combustion engines such as gasoline engines such as automobile engines and aircraft engines, and diesel engines for ships and power generation. There are 1 petroleum-based lubricating oils that are processed by distillation, and synthetic lubricating oils that are manufactured using organic synthesis methods.Individual brands have extremely different ingredients, and the points of origin are extremely diverse. Therefore, the reality is that they are considered worthless and are discarded without being recovered. Although it generally has a higher flash point than heavy oil, most of it is flammable like heavy oil.
前記したように、この発明によれば、前記した廃油を主
たる組成分とするが、これらの廃油は水分の含料が30
重量%以下でなければならない。30ホ量%を超えると
燃料組成物の燃焼性が急激に劣化するからである。前記
したプロースラッジは、前記したように、きわめて多量
の水を含むのであるが、静置および遠心分離等の機械的
操作により、水分含を率を30〜20%に低下させるの
は非常に間車であり、作業コストも名目的である。廃潤
滑油についても取扱不良のため水が混入している場合が
あるが、その場合前記した機械的操作が必要であっても
、普通は含水率が低いのでそのまま生成分として採用で
きる。As described above, according to the present invention, the main composition is the above-mentioned waste oil, but the water content of these waste oils is 30%.
Must be less than % by weight. This is because if the amount exceeds 30% by volume, the combustibility of the fuel composition will deteriorate rapidly. As mentioned above, the Prose sludge contains an extremely large amount of water, but it takes a very long time to reduce the water content to 30-20% by standing still and mechanical operations such as centrifugation. It's a car, and the work costs are nominal. Waste lubricating oil may also be contaminated with water due to poor handling, but in that case, even if the mechanical operations described above are required, it usually has a low water content and can be used as a product as is.
さて、この発明にかかる組成物の主成分は上記の通りで
あるが、この発明にかかる燃料組成物には製材等の廃羽
であるオガくず、および硝石またはセルロイドの粉砕物
が副成分として必要である。Now, the main components of the composition according to the present invention are as described above, but the fuel composition according to the present invention requires sawdust, which is waste feathers from sawn timber, and crushed saltpeter or celluloid as subcomponents. It is.
つぎに、この発明にかかる燃料組成物の組成割合はつぎ
の通りである。すなわち、主成分である水分調整ずみの
重油スラッジまたは廃潤滑油は60〜80重量%、副成
分であるオかくずは18.5〜34.5重量%、同じく
副成分である硝石またはセルロイドの粉砕物は0.5〜
1.5重重%である。Next, the composition ratio of the fuel composition according to the present invention is as follows. That is, the main component, moisture-adjusted heavy oil sludge or waste lubricating oil, is 60 to 80% by weight, the subcomponent is 18.5 to 34.5% by weight, and the subcomponent is pulverized saltpeter or celluloid. Things are 0.5~
It is 1.5% by weight.
重油スラッジや廃潤滑油は、それ自身油分をかなりの量
含むので、吸熱性である水分を20%程度になるまで除
去したうえ、石炭その他の固形燃料、灯油その他の液体
燃料、あるいは天然ガス等の気体燃料等、高熱量燃料の
火熱によって燃焼を援ければ焼却もでき、その熱量も利
用できるが、なによりも独立の燃料として使用できない
うえ、パイ煙が多く、不潔感をともなう欠点がある。こ
の発明はこのような廃油を日常使用する燃料としてfa
t独使用に耐えるようなものに転化することを可能にし
、経済測置を著しく高めたものである。Heavy oil sludge and waste lubricating oil themselves contain a considerable amount of oil, so after removing the endothermic moisture to about 20%, they can be used as coal or other solid fuels, kerosene or other liquid fuels, or natural gas, etc. Incineration is possible if the combustion is assisted by the heat of a high calorific value fuel such as gaseous fuel, and the calorific value can be used, but above all, it cannot be used as an independent fuel and has the disadvantage of producing a lot of smoke and making it feel unclean. . This invention aims to utilize such waste oil as a fuel for daily use.
This made it possible to convert it into something that could withstand German use, and significantly improved its economical design.
この発明にかかる燃料組成物における廃油は、水分を3
0iii1t96以下に調整したものであり、この水分
調整がきわめて容易であることは既に述べた。The waste oil in the fuel composition according to this invention has a moisture content of 3
It has already been mentioned that this moisture adjustment is extremely easy.
この発明における副成物の一つであるオガクズは、もち
ろん水分の少ないものであることがのぞましいが、普通
は特に人工乾燥する必要はない。オガクズは前記した廃
油を吸収するとともに、廃油が空気酸化により燃焼する
際の表面積を著しく拡大する。この場合、組成物中、前
記した廃油60〜80重量%に対応するオガクズの適量
は18.5〜34.5重量%であることが実験により見
出された。これらの組成割合を逸脱すれば、廃油が多過
ぎても、オかクズが多過きても組成物の燃焼性が阻害さ
れる。Sawdust, which is one of the by-products in this invention, preferably has a low moisture content, but normally there is no need to artificially dry it. Sawdust not only absorbs the waste oil mentioned above, but also significantly expands the surface area when the waste oil is combusted by air oxidation. In this case, it has been experimentally found that the appropriate amount of sawdust in the composition is 18.5 to 34.5% by weight, corresponding to the above-mentioned 60 to 80% by weight of waste oil. If these composition ratios are exceeded, the combustibility of the composition will be inhibited even if there is too much waste oil or too much sawdust.
その」二、廃油が多過ぎれば、組成物が包装および使用
に不便なベタベタの状態を呈するし、オガクズが過多で
あれば、燃料としての熱量が不足する欠点がある。Second, if there is too much waste oil, the composition will be sticky which is inconvenient for packaging and use, and if there is too much sawdust, there will be insufficient heat as a fuel.
この発明において硝石またはセルロイドの粉砕物を配合
したのは、その爆発的燃焼性を利用し、着火促進を行う
ためである。これらの粉末は多塩の水の存在下において
引火性はないのであるが、オかクズに吸着された前記廃
油を多量に含む組成物において、硝石、セルロイドの粉
砕物は0.5〜1.5重量%の割合において充分な引火
性がある。The reason why crushed saltpeter or celluloid is blended in this invention is to utilize its explosive combustibility to promote ignition. These powders are not flammable in the presence of polysalt water, but in a composition containing a large amount of the waste oil adsorbed on sawdust, crushed saltpeter and celluloid are 0.5 to 1. It is sufficiently flammable at a proportion of 5% by weight.
1.5重量%以上においては着火促進性はもちろん増大
するが、燃料組成物のコストが高くなるばかりでなく、
燃焼速度が過敏になるため、熱量利用の見地から損失を
まねく。また、o、5%未満の配合量では着火性が不良
となり、日常利用する燃料として不適当になる。If it exceeds 1.5% by weight, the ignition promoting ability will of course increase, but not only will the cost of the fuel composition increase;
The burning rate becomes sensitive, resulting in loss from the standpoint of heat utilization. Furthermore, if the blending amount is less than 5%, the ignitability will be poor, making it unsuitable as a fuel for daily use.
前記した組成割合をもっこの発明の燃料組成物。A fuel composition of the invention having the composition ratio described above.
は、油分の多い果粒状を呈するので、包装、取扱いとも
に便利であり、マツチ一本で着火するすぐれた着火性を
有し、着火後は燃えつきるまで自然消火しない燃焼持続
性を有する。また、燃焼状態は自然放置でもパイ煙を発
生せずに完全燃焼するので、公害発生原因とならない。Because it has the shape of a fruit with a high oil content, it is convenient to package and handle, has excellent ignition properties that can be ignited by a single pine tree, and has long-lasting combustion that does not spontaneously extinguish until it burns out after ignition. In addition, even when left to burn naturally, it burns completely without producing pie smoke, so it does not cause pollution.
すなわち、この発明によれば、独立して使用できる固形
燃料の−種であるが、アルコール、灯油などの液体燃料
などと同様、簡単に着火するので、木炭やコークスより
も使用しやすく、石炭のようにパイ煙を発しないので、
ボイラーはもちろん、いかなる燃焼器具でも使用できる
し、燃焼持続性に優れた燃料を提供することができる。That is, according to the present invention, although it is a type of solid fuel that can be used independently, it ignites easily like liquid fuels such as alcohol and kerosene, so it is easier to use than charcoal or coke, and it is a type of solid fuel that can be used independently. Because it does not emit pie smoke,
It can be used not only in boilers but also in any combustion equipment, and can provide fuel with excellent combustion sustainability.
のみならず、この燃料組成物の生産過程は前記のように
簡単であり、主原料は元来廃棄物とされているものであ
るから、低価格の燃料が多量に提供されるし、放棄され
るエネルギー資源が有用物として再生されるので、産業
および経済社会に多大の寄与をすることができる。Not only that, the production process for this fuel composition is simple as mentioned above, and the main raw material is originally waste, so it provides a large amount of low-cost fuel and eliminates waste. Since the energy resources that are used are recycled as useful products, they can make a significant contribution to industry and economic society.
なお、この発明にかかる燃料組成物における各組成分お
よび組成割合の範囲は前記した通りであるが、この発明
者による実験においてもつとも好ましい組成割合はつぎ
の通りであった。Although the various components and ranges of composition ratios in the fuel composition according to the present invention are as described above, the most preferred composition ratios in experiments conducted by the inventor were as follows.
(重油スラッジ燃料組成物)
重油スラ・lジ 75kfA量%
おがくず 24〃
硝石 1 //
(廃潤滑油燃料組成物)
廃潤滑油、70重態形
おがくず 29〃
硝石 】〃
ただし、上掲各例につき、硝石に代えてセルロイド粉砕
物を配合した場合も配合割合はかわらない。(Heavy oil sludge fuel composition) Heavy oil sludge 75kfA amount % Sawdust 24〃 Saltpeter 1 // (Waste lubricating oil fuel composition) Waste lubricating oil, 70 heavy form sawdust 29〃 Saltpeter ]〃 However, for each of the above examples The blending ratio remains the same even when crushed celluloid is blended in place of saltpeter.
以下、第1表の組成物を用いた燃焼実験成績を第2表に
掲げる。ただし、この燃焼実数は図示した装置により、
検体の燃料組成物aを10〃蒸発皿すにたいらに入れ、
着火後燃えつきSまでの時間と、ビーカーC中に入れた
50 ccの水の温度」二昇を測定して石なった。各表
中「Ex、 AI Jおよび「Ex−BI Jは、それ
ぞれ曲射の「重油スラッジ燃料組成物」および「廃潤滑
油燃料組成物」の実施例と同一物である。各表中「co
nt、 AI J〜「Cant、 A4 Jは、「重油
スラッジ燃料組成物Jであるが、この発明で限定した組
成割合から逸脱した割合の対照例を意味する。また、r
cont、 BI J〜JCont−B4 Jは「廃潤
滑油燃料組成物」であるが、この発明で限定した組成割
合から逸脱した ”割合の対照例を意味する。The results of combustion experiments using the compositions in Table 1 are listed in Table 2 below. However, this actual combustion number can be calculated using the device shown in the diagram.
Put the sample fuel composition a into a 10 liter evaporating dish,
The time from ignition to burnout S and the temperature of 50 cc of water placed in beaker C were measured. In each table, "Ex, AI J" and "Ex-BI J" are the same as in the examples of "heavy oil sludge fuel composition" and "waste lubricating oil fuel composition", respectively. In each table “co”
nt, AI J ~ "Cant, A4 J" means a comparative example of "heavy oil sludge fuel composition J, but with a ratio deviating from the composition ratio limited in this invention."
Cont, BI J to JCont-B4 J are "waste lubricating oil fuel compositions," but they mean comparative examples of composition ratios that deviate from the composition ratios defined in this invention.
第1表
第2表
ただし、表中、
(1)「状態」は指触の状態をいい、「良好」とは日常
使用に好適な果駈状であることをいう。Table 1 Table 2 However, in the table, (1) ``Condition'' refers to the condition to the touch, and ``Good'' refers to the condition of the product being suitable for daily use.
(2)「着火性」はマツチ一本で直ちに着火するものを
「良好」とし、着火試験を繰返したとき、ときどきマツ
チ一本で着火しないこ 8とがある場合、「やや不良」
という。(2) "Ignitability" is considered "good" if it ignites immediately with a single pine, and "slightly poor" if it sometimes fails to ignite even with a single pine when repeated ignition tests8.
That's what it means.
(3)「持続性」は着火後、もえつきるまで自然消火し
ない場合「良好」という。(3) "Sustainability" is said to be "good" if the fire does not extinguish naturally until it burns after ignition.
(4)「温度」および「時間」はそれぞれ、着火後もえ
つきるまでに上昇した水温および経過時間である。(4) "Temperature" and "time" are the temperature of the water that rose until it became hot after ignition and the elapsed time, respectively.
(5)※1:燃焼時間中2〜3回自然消火した。(5) *1: Natural extinguishment occurred 2 to 3 times during the combustion time.
×2°燃焼時間中3〜4回自然消火した。×2° Natural extinguishment occurred 3 to 4 times during the combustion time.
※3:マッチ一本では着火せず、喫煙ライターでは着火
する。*3: A single match will not ignite it, but a smoking lighter will.
X4:燃焼時間中2〜3回自然消火した。X4: Natural extinguishment occurred 2 to 3 times during the combustion time.
※5:サラサラし過ぎ、吹くと飛散するので使用しにく
い。*5: It is difficult to use because it is too smooth and scatters when you blow it.
※6:燃焼時間中2〜3回自然消火した。*6: Natural extinguishment occurred 2 to 3 times during the combustion time.
図面は燃焼実験に使用した装置の概観側面図である。
八は燃料組成物、Bは蒸発皿、Cはビーカー、Dは水、
Eは架台、Fは金網、a=8 am % b=5 cm
c=7cmである。
← c −HThe drawing is a schematic side view of the apparatus used in the combustion experiment. 8 is the fuel composition, B is the evaporation dish, C is the beaker, D is water,
E is the frame, F is the wire mesh, a=8 am % b=5 cm
c=7cm. ← c −H
Claims (1)
m滑油60〜80重量%と、オガくず18.5〜34.
1Mk%と、硝石またはセルロイドの粉砕物0.5〜1
.5%とを混和してなる廃油燃料組成物。Heavy oil sludge with a moisture content of 30% or less or *
60-80% by weight of lubricating oil and 18.5-34% sawdust.
1 Mk% and crushed saltpeter or celluloid 0.5-1
.. A waste oil fuel composition obtained by mixing 5% of
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2001884A JPS60166394A (en) | 1984-02-08 | 1984-02-08 | Waste oil fuel composition |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2001884A JPS60166394A (en) | 1984-02-08 | 1984-02-08 | Waste oil fuel composition |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS60166394A true JPS60166394A (en) | 1985-08-29 |
JPH0419280B2 JPH0419280B2 (en) | 1992-03-30 |
Family
ID=12015355
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2001884A Granted JPS60166394A (en) | 1984-02-08 | 1984-02-08 | Waste oil fuel composition |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS60166394A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2008169358A (en) * | 2007-01-15 | 2008-07-24 | Taiheiyo Cement Corp | Solid fuel |
JP2009197204A (en) * | 2008-02-25 | 2009-09-03 | Fuji Energy Co Ltd | Method for producing solid fuel using organic waste liquid and production system thereof |
JP2010227882A (en) * | 2009-03-27 | 2010-10-14 | Taiheiyo Cement Corp | Method for treating hydrogen generating oil sludge and method for using hydrogen generating oil sludge |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS4935401A (en) * | 1972-08-08 | 1974-04-02 | ||
JPS54161746A (en) * | 1978-06-13 | 1979-12-21 | Sanritsu Shiyori Kougiyou Kk | Waste oilssanddfats disposal method |
-
1984
- 1984-02-08 JP JP2001884A patent/JPS60166394A/en active Granted
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS4935401A (en) * | 1972-08-08 | 1974-04-02 | ||
JPS54161746A (en) * | 1978-06-13 | 1979-12-21 | Sanritsu Shiyori Kougiyou Kk | Waste oilssanddfats disposal method |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2008169358A (en) * | 2007-01-15 | 2008-07-24 | Taiheiyo Cement Corp | Solid fuel |
JP2009197204A (en) * | 2008-02-25 | 2009-09-03 | Fuji Energy Co Ltd | Method for producing solid fuel using organic waste liquid and production system thereof |
JP2010227882A (en) * | 2009-03-27 | 2010-10-14 | Taiheiyo Cement Corp | Method for treating hydrogen generating oil sludge and method for using hydrogen generating oil sludge |
Also Published As
Publication number | Publication date |
---|---|
JPH0419280B2 (en) | 1992-03-30 |
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