JPS60152551A - Tacky water-containing gel - Google Patents
Tacky water-containing gelInfo
- Publication number
- JPS60152551A JPS60152551A JP814884A JP814884A JPS60152551A JP S60152551 A JPS60152551 A JP S60152551A JP 814884 A JP814884 A JP 814884A JP 814884 A JP814884 A JP 814884A JP S60152551 A JPS60152551 A JP S60152551A
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- water
- gel
- polyacrylic acid
- hydrogel
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Abstract
Description
【発明の詳細な説明】
本発明は保水性、粘着性及び保形性にすぐれる粘着タイ
プの含水ゲルに関するものである。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to an adhesive type hydrogel having excellent water retention, adhesiveness and shape retention.
含水ゲルとしては、寒天、仁んにやく一マンナンの如き
天然系高分子材料と水とからなるタイプと、ポリビニル
アルコール、ポリアクリル酸及びそれらの塩、カルボキ
シメチルセルロースの如キ合成系高分子材料と水との混
合物に、２価以上の金属塩ｔエポキシ化合物、ホウ酸、
アルデヒド化合物、ケトン類の如きゲル化成分を配合し
て反応させてなるタイプとが知られている。Hydrogels include types made of natural polymer materials such as agar and mannan and water, and synthetic polymer materials such as polyvinyl alcohol, polyacrylic acid and their salts, and carboxymethyl cellulose. In the mixture with water, divalent or higher metal salt t-epoxy compound, boric acid,
A type in which gelling components such as aldehyde compounds and ketones are mixed and reacted is known.
しかして、前記天然系高分子材料を主体とする含水ゲル
社、その主材の組成に起因して腐食したり、加熱下でゲ
ル構造が喪失したシするといった欠点があり、また合成
系高分子材料を主体とする含水ゲルは、＠えばゲル化成
分が塩化マグネシウム、塩化カルシウムの如き２価以上
の金属塩であるときは、主材とのゲル化速度が早すぎて
所望の・形状に成形できなかったり、ゲル中に充分な水
分を保有させることができなかったシするという欠点が
６９．またゲル化成分としてトリグリシジノンイソシア
ヌレートの如き工ｇキシ化合物を使用すると、含水ゲル
としては過度な保水性及び保形性を有するが、粘着性に
欠けるために多価アルコールの如き粘性剤を添加すると
いった煩雑な作業を必要とする欠点がある。However, hydrogels made mainly from natural polymer materials have disadvantages such as corrosion due to the composition of the main material, loss of gel structure under heating, and synthetic polymers. For example, when the gelling component is a divalent or higher metal salt such as magnesium chloride or calcium chloride, the gelation rate with the main material is too fast, making it difficult to form the gel into the desired shape. 69. Furthermore, when a synthetic compound such as triglycidinone isocyanurate is used as a gelling component, it has excessive water retention and shape retention properties as a hydrogel, but it lacks tackiness, so a viscous agent such as polyhydric alcohol is used. It has the disadvantage of requiring complicated operations such as addition.
本発明者達は刀・かる従来技術の情況に鑑み鋭意研究を
重ねた結果、驚くべきことに、ポリアクリル酸及びン又
はプリアクリル酸塩を多価金属酸化物でゲル化すると、
保水性及び保形性が良好で、多くの実質的に平滑な適用
体面に接着し且つ残留物なく剥がすことができる粘着性
含水ゲルが得られることを見い出し、本発明に至ったも
のである。The inventors of the present invention have conducted extensive research in view of the state of the art of swords and swords, and have surprisingly found that when polyacrylic acid and polyacrylic acid salts are gelled with polyvalent metal oxides,
The present invention has been based on the discovery that an adhesive hydrogel can be obtained that has good water retention and shape retention properties, can adhere to many substantially smooth application surfaces, and can be peeled off without leaving any residue.
即ち本発明は、少なくとも１重証％のテリアクリル酸及
び／′又はがリアクリル酸塩と、少なくともｏ、ｏｚｉ
ｉ％のゲル化剤と、少なくとも１５重量％の水とを含む
実質的に平滑な適用体面に粘着する含水ゲルであって、
前記ゲル化剤として多価金属酸化物を用いたことを特徴
とする粘着性含水ゲルを提供するものである。That is, the present invention provides at least 1% teriacrylic acid and/or lyacrylate;
A hydrogel that adheres to a substantially smooth application surface, the gel comprising: i% gelling agent and at least 15% water by weight;
The present invention provides an adhesive hydrogel characterized in that a polyvalent metal oxide is used as the gelling agent.
本発明の粘着性含水ゲルによれば、良好な保水性及び保
形性を有すると共に、例えば皮膚面の如き実質的に平滑
な適用体向に適度に接着し、少なくとも自重では特別な
固着補助手段を用いなくても剥離することがないという
特徴を有する。According to the adhesive hydrogel of the present invention, it has good water retention and shape retention properties, and also properly adheres to a substantially smooth application surface such as the skin surface, and at least under its own weight, special adhesion auxiliary means are used. It has the characteristic that it does not peel off even if it is not used.
従って、例えば単独で身体の保冷基剤として１また薬物
の如き活性物質と混合系で用いることによって、冷却効
果を有する消炎剤の如き治療基剤として用いることがで
きるものでめる。Therefore, it can be used, for example, alone as a cooling base for the body, or as a therapeutic base such as an anti-inflammatory agent having a cooling effect by being used in a mixture with an active substance such as a drug.
本発明の実施に当って用いられるポリアクリル酸及び／
又は、ｈ、ｐ ＩＪアクリル酸塩として幻１、重合度か
１．０００−６０．０００のものが望ましいものでをノ
って。Polyacrylic acid and/or used in carrying out the present invention
Alternatively, h,p IJ acrylates with a phantom level of 1 and a degree of polymerization of 1.000-60.000 are desirable.
１．０００以下では得られる含水ケルの物理的強度がｍ
５ ＜ 、 ６０．０（１０以上では均一なマトリック
ス構造を有するゲルか得らり、、 ｔｔ二＜いので好ま
しくないものである。丑だ目′リアクリル酸塩は、ポリ
アクリル酸ナトリウム、ポリアクリル酸アシ−Ｅニウム
、４？リアクリル酸カリウムの如き一価のものがよい、
かかるぼりアクリル酸及び／又は？リアクリル酸塩は、
含水ゲル組成体中に少々くとも１重量％含むように調整
さ才１ていることか、目的とする物理的強度と粘着性を
得るうえで必要である。ポリアクリル酸及び／又は−リ
アクリル酸塩の含水ゲル組成体中に漬−りる含有量の上
限は、グリセリンの如き粘性剤を特に用いることなく、
含水ゲルに目的とする粘着性が得られるか否かによって
決められるものであって、多くて（，６０重型外を超え
ないことが望ましいものである。If it is less than 1.000, the physical strength of the obtained water-containing Kel is m
5 <, 60.0 (If it is 10 or more, a gel with a uniform matrix structure will not be obtained, which is undesirable.) Monovalent ones such as acid ace-E-nium and potassium 4?reacrylate are preferable.
Acrylic acid and/or? Lyacrylate is
It is necessary to adjust the content of at least 1% by weight in the hydrogel composition in order to obtain the desired physical strength and adhesiveness. The upper limit of the content of polyacrylic acid and/or lyacrylate in the hydrogel composition can be set without using a viscous agent such as glycerin.
It is determined by whether or not the desired adhesiveness can be obtained for the hydrogel, and it is preferable that the adhesiveness does not exceed .60 mm at most.
本発明においてポリアクリル酸及び／又はポリアクＱ
）し酸塩のケル化剤と【７て用いる多価金属酸化物と１
−では、酸化チタン、酸化亜鉛、酸化マグネシウム、酸
化アルミニウム、Ｍ北方ルシウム、酸化鉄の如き多価の
酸化金属が挙けられる。In the present invention, polyacrylic acid and/or polyac Q
) A kelizing agent for oxalate, a polyvalent metal oxide used in [7], and a
- includes polyvalent metal oxides such as titanium oxide, zinc oxide, magnesium oxide, aluminum oxide, M lucium, and iron oxide.
かかる多価金属酸化物は、含水ゲル組成体中に少なくと
も０．０２重型外２、好ましくは０．０４重量％以上％
実用的にＦｉ１０重量％以、に含むようｌ’４調整され
ていることがゲル化及び増粘効果を得るうえで必要であ
る。０．０２重量％以干ではポリアクリル酸及び／又は
ポリアクリル酸塩を充分にゲル化させて増粘させること
ができないものである。しかして、該酸化物は多くても
含水ゲル組成体中の７３重量％を超えないことが望まし
いものであ＃）、７３重量％以上では含水ゲルの粘着性
が低下するばかりか、粘弾性に欠けるものである。Such a polyvalent metal oxide is present in the hydrogel composition in an amount of at least 0.02% by weight or more, preferably 0.04% by weight or more.
Practically speaking, it is necessary to adjust l'4 to include 10% by weight or more of Fi in order to obtain gelling and thickening effects. If the amount is less than 0.02% by weight, the polyacrylic acid and/or polyacrylate cannot be sufficiently gelled and thickened. However, it is desirable that the amount of the oxide does not exceed 73% by weight of the hydrogel composition at most; if it exceeds 73% by weight, the adhesiveness of the hydrogel will not only decrease, but also the viscoelasticity will decrease. It is something that is lacking.
これらのポリアクリル酸及び／又はポリアクリル酸塩と
水と多価金属酸化物とから粘着性含水ゲルが構成される
ものであるが、ゲル中の水分量は少なくとも１５ｉｉｉ
１％、好ましくはｚｏｉｉｉ％以上であることが必要で
ある。水分量が１５重蓋％以下ではゲル体が硬く、シか
も粘着性に劣るために好謙しくないものである。しかし
て、水の含有量は多くても含水ゲル組成体中の９５重量
％を超えないことが望ｌしいものであり、９５重量％以
上では保形性に欠けるものである。A sticky hydrogel is composed of these polyacrylic acids and/or polyacrylates, water, and a polyvalent metal oxide, and the water content in the gel is at least 15iii.
It is necessary that the content is 1%, preferably zoiii% or more. If the water content is less than 15%, the gel body will be hard and have poor adhesive properties, making it undesirable. Therefore, it is preferable that the water content does not exceed 95% by weight of the hydrogel composition at most, and if it is more than 95% by weight, shape retention will be poor.
このように構成し、てなる粘着性含水ゲルには、必要に
応じてゲリー♂リシ、プロピレングリコールの如き多価
アルコール、カオリシ、タルク、クレーの如き補強充填
剤、その他繊維糸、ガラスピーズ、着色剤、香料、抗炎
症剤、防腐剤の如き通常の添加剤を含有させてもよい。The adhesive water-containing gel thus constituted may contain, if necessary, polyhydric alcohols such as gelatin, propylene glycol, reinforcing fillers such as kaorishi, talc, and clay, other fiber threads, glass beads, and coloring. It may also contain conventional additives such as agents, fragrances, anti-inflammatory agents, and preservatives.
またシート状とする場合には多孔質基材からなる芯材を
内在させるか或いはその一方の表面に薄葉材料を貼着し
てもよいものである。In the case of forming a sheet, a core material made of a porous base material may be included, or a thin sheet material may be attached to one surface of the core material.
本発明の粘着性含水ゲルは、以下の実施例にて具体的に
例証される如＜、＊れた保水性、保形性及び粘着性を有
するものであシ、従って冷感のみ或いは冷静と配合活性
物質の添加効果とを得る基剤として有用である。The adhesive water-containing gel of the present invention has excellent water retention, shape retention, and adhesive properties as specifically illustrated in the following examples, and therefore has only a cooling sensation or a calming sensation. It is useful as a base to obtain the effect of adding active substances.
以下本発明の実施例を示す。Examples of the present invention will be shown below.
実施例１
ポリアクリル酸（重合度２０００ ）の水溶液（２０重
蓋％ベース）３０ｇと酸化チタン５４．９とを均一に混
合し、深さ７朋の型内に流延して粘着性含水ゲルを得た
。Example 1 30 g of an aqueous solution (20% base) of polyacrylic acid (degree of polymerization 2000) and 54.9 g of titanium oxide were uniformly mixed and cast into a mold with a depth of 7 mm to form a sticky hydrogel. I got it.
実施５ＩＪ２
ポリアクリル酸（重合度６０００ ）の水溶液（２０重
に％ベース）３０，９と酸化チタン５４ｇと水３６ｇと
を均一に混合し、深さｌＯ朋の型内に流延して粘着性含
水ゲルを得た。Implementation 5IJ2 Aqueous solution (20% basis) of polyacrylic acid (degree of polymerization 6000), 54 g of titanium oxide, and 36 g of water were uniformly mixed and cast into a mold with a depth of 10 mm to make it sticky. A hydrogel was obtained.
実施例３
ｄ？ ＋Ｊアクリル酸（重合度６０００ ）の水溶液（
２０重亀％ベース）３０Ｉに水酸化ナトリウム３．３ｙ
を添加して均一に混合して水ａｎ（ｐＨ７）とし、これ
に酸化チタン５４ｇと水２４７ｇとを加えて均一に混合
し、深さ１０ｍｍの型内に流延しゼ粘着性含水ゲルを得
た。Example 3 d? +J Aqueous solution of acrylic acid (degree of polymerization 6000) (
20 weight turtle% base) 30I and 3.3y of sodium hydroxide
was added and mixed uniformly to make water an (pH 7), 54 g of titanium oxide and 247 g of water were added and mixed uniformly, and cast into a mold with a depth of 10 mm to obtain a sticky hydrogel. Ta.
実施例４
ポリアクリル酸ナトリウム（重合度２０００ ）６，９
と水５ｇと酸化チタン６９とを均一に混合し、深さ３
ｍｗ、の型内に流延して粘着性含水ゲルを得た。Example 4 Sodium polyacrylate (degree of polymerization 2000) 6,9
, 5 g of water, and 69 titanium oxide were mixed uniformly, and
mw, to obtain a sticky hydrogel.
実施例５
ポリアクリル酸（重合度６０００ ）の水溶液（２０重
量％ベース）３０ｇに水酸化ナトリウム２．４ｇを添加
して均一に混合して水溶液（ｐＨ５）とし、これに酸化
チタン６ｇを加えて均一に混合し、深さ１０にの型内に
流延］〜て粘着性含水ゲルを得た。Example 5 2.4 g of sodium hydroxide was added to 30 g of an aqueous solution (20% by weight base) of polyacrylic acid (degree of polymerization 6000) and mixed uniformly to form an aqueous solution (pH 5), and 6 g of titanium oxide was added to this. The mixture was mixed uniformly and cast into a mold with a depth of 10 mm to obtain a sticky hydrogel.
実施例６
ポリアクリル酸（重合度６０００ ）の水溶液（２０重
社％ベース）３０ｇに水酸化すトリウム２，４ｇを添加
して均一に混合して水浴液（ｐＨ５）とし、これに水５
０９と酸化チタン６ｇとを加えて均一に混合し、深さｌ
Ｏ、ｍｍの型内に流延して粘着性含水ゲルを得た。Example 6 2.4 g of thorium hydroxide was added to 30 g of an aqueous solution (based on 20 Jyusha %) of polyacrylic acid (degree of polymerization 6000) and mixed uniformly to prepare a water bath solution (pH 5).
Add 09 and 6 g of titanium oxide, mix uniformly, and mix to a depth of l.
A sticky hydrogel was obtained by casting into a mold of 0.0 mm.
実施例７
ポリアクリル酸ナトリウム（重合度２０００ ）６．９
と水３．１ｇと酸化チタン１．２ｇとを均一に混合し。Example 7 Sodium polyacrylate (degree of polymerization 2000) 6.9
3.1 g of water and 1.2 g of titanium oxide were mixed uniformly.
深さ５ ｍｍの型内に流延して粘着性含水ゲルを得た。A sticky hydrogel was obtained by casting into a mold with a depth of 5 mm.
実施例８
ポリアクリル酸ナトリウム（重合度３０００）６．ｐと
水７６２ｇと酸化チタン１．２ｇとを均一に混合し、深
さ１０關の型内に流延して粘着性含水ゲルを得た。Example 8 Sodium polyacrylate (degree of polymerization 3000) 6. P, 762 g of water, and 1.2 g of titanium oxide were uniformly mixed and cast into a mold with a depth of 10 mm to obtain a sticky hydrogel.
実施例９
ｄＰリアクリル酸（重合度６０００ ）の水浴液（２０
Ｍ量％ベース）３０ｇに水酸化すトリウノ−３，３ｐを
添加して均一に混合して水溶液（［１）ｉ７）とし、こ
れに酸化チタン１．２ｇを加えて均一に混合し、深さｌ
Ｏｍの型内に流延して粘着性含水ケルを得た。Example 9 Water bath solution (20
Add triuno-3,3p hydroxide to 30 g (M amount% base) and mix uniformly to obtain an aqueous solution ([1) i7). Add 1.2 g of titanium oxide to this and mix uniformly. l
A sticky water-containing gel was obtained by casting into a mold of Om.
実施例１０
ポリアクリル酸（重合度６（１００）の水浴液（２０Ｍ
ｍ％ベース） 、３０９に水酸化すトリウム２．４ｇを
添加して均一に混合して水溶液ＣｐＨ５）とし、これに
酸化亜鉛６１１を加えて均一に混合し、深さ１゜龍の型
内に流延して粘着性含水ゲルを得た。Example 10 Polyacrylic acid (polymerization degree 6 (100) water bath solution (20M
2.4 g of thorium hydroxide was added to 309 and mixed uniformly to form an aqueous solution CpH 5), and zinc oxide 611 was added to this, mixed uniformly, and placed in a dragon mold with a depth of 1°. A sticky hydrogel was obtained by casting.
実施例１１
？リアクリル酸（重合度６０００）の水浴液（２０重量
％ベース）３０ｙに水酸化す＋−’）ラム３．３ｇを添
加して均一に混合して水浴液（ｐＨ７；どし、これに酸
化マグネシウム６ｇを加えて均一に混合し、深さ１０
ｒｔｒｍの型内に流延して粘着性含水ゲルを得た０
第１表に実施例１〜１１の特性評価結果を示す。Example 11? To 30y of a water bath solution (20% by weight base) of lyacrylic acid (degree of polymerization 6000) was added 3.3g of hydroxide +-') and mixed uniformly. Add 6g and mix evenly to a depth of 10
A sticky hydrogel was obtained by casting into a mold of rtrm. Table 1 shows the characteristics evaluation results of Examples 1 to 11.
第 １ 表
第１表中の試り法
粘着性：Ｊ、Ｄｏｗの玉ころかし、法（３０度の角度を
持った斜面に一定長さの粘着性含水ゲルシートを止め、
一定高さよジ１／３２インチから１インチまでの３２種
類の大きさの鍋球をころがし、ゲルシート上でとまる最
大径の鷹で粘着性を示す。）に準じて測定した。Table 1 Trial method in Table 1 Adhesion: J, Dow's ball rolling method (fixed a fixed length of adhesive hydrogel sheet on a slope with an angle of 30 degrees,
Pot balls of 32 sizes from 1/32 inch to 1 inch are rolled at a constant height, and the stickiness is indicated by the largest diameter ball that stops on the gel sheet. ).
ゲル保形性：３Ｃ＋ｎＸ３鎖に切断した含水ゲルをアル
ミ製袋内に密封保存して４０℃±２℃の乾燥機内に２４
時間保存する。次に室温に冷却後、アルミ袋内よりゲル
を取シ用シフ、その寸法を測定する。Gel shape retention: The hydrous gel cut into 3C + n
Save time. Next, after cooling to room temperature, remove the gel from the aluminum bag using a sifter and measure its dimensions.
保存時の下側のゲル平面積の増加率が１０％以内は良、
１０〜２０％を可、２０％以上を不可と判定１７た。If the increase rate of the lower gel plane area during storage is within 10%, it is considered good.
10 to 20% was judged to be acceptable, and 20% or more was judged to be unacceptable17.
上記実施例からも明らかな如く、本発明の粘着性含水ゲ
ルは、保水性、粘着性及び保形性にすぐれるものである
ことが明らかである。As is clear from the above examples, it is clear that the adhesive hydrogel of the present invention has excellent water retention, adhesiveness, and shape retention.
特許出願人 日東電気工業株式会社 代表者土方三部patent applicant Nitto Electric Industry Co., Ltd. Representative Sanbe Hijikata
Claims (1)
リアクリル酸塩と、少なくとも０．０２重量％のゲル化
剤と、少なくとも１５重量％の水とを含む実質的に平滑
な適用体面に接着する含水ケルであって、前記ゲル化剤
として多価金属酸化物を用いたと・とを特徴とする粘着
性含水ゲル。 ２）多価金属酸化物が酸化チタン、酸化亜鉛、酸化マグ
ネシウムの群から選ｄれだ少なくとも一つである特許請
求の範囲第１項記載の粘着性含水ゲル０Claims: l) A substantially smooth material comprising at least 1% by weight of polyacrylic acid and/or polyacrylate, at least 0.02% by weight of a gelling agent, and at least 15% by weight of water. 1. An adhesive hydrogel that adheres to a surface to which it is applied, characterized in that a polyvalent metal oxide is used as the gelling agent. 2) The adhesive hydrous gel 0 according to claim 1, wherein the polyvalent metal oxide is at least one selected from the group of titanium oxide, zinc oxide, and magnesium oxide.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP814884A JPS60152551A (en) | 1984-01-19 | 1984-01-19 | Tacky water-containing gel |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP814884A JPS60152551A (en) | 1984-01-19 | 1984-01-19 | Tacky water-containing gel |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS60152551A true JPS60152551A (en) | 1985-08-10 |
| JPS6313452B2 JPS6313452B2 (en) | 1988-03-25 |
Family
ID=11685225
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP814884A Granted JPS60152551A (en) | 1984-01-19 | 1984-01-19 | Tacky water-containing gel |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS60152551A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5204109A (en) * | 1989-12-28 | 1993-04-20 | Nitto Denko Corporation | Percutaneous gel preparation |
| GR1001334B (en) * | 1992-05-29 | 1993-08-31 | Colgate Palmolive Co | Linear viscoelastic aqueous liquid automatic dishwasher detergent composition. |
| EP0574236A2 (en) * | 1992-06-08 | 1993-12-15 | Colgate-Palmolive Company | Aqueous composition containing a non-crosslinked polymer for augmenting viscosity |
| US5845954A (en) * | 1996-06-25 | 1998-12-08 | Toyota Technical Center, U.S.A., Inc. | Glove box assembly including glove box that is positionable in a partially open position |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5315413A (en) * | 1976-07-28 | 1978-02-13 | Daikiyou Yakuhin Kougiyou Kk | Pap agent |
| JPS55116777A (en) * | 1979-02-28 | 1980-09-08 | Nitto Electric Ind Co Ltd | Method of modifying coating film of pressure-sensitive adhesive |
| JPS5980459A (en) * | 1982-10-29 | 1984-05-09 | Arakawa Chem Ind Co Ltd | Water-absorbing powdery resin composition |
-
1984
- 1984-01-19 JP JP814884A patent/JPS60152551A/en active Granted
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5315413A (en) * | 1976-07-28 | 1978-02-13 | Daikiyou Yakuhin Kougiyou Kk | Pap agent |
| JPS55116777A (en) * | 1979-02-28 | 1980-09-08 | Nitto Electric Ind Co Ltd | Method of modifying coating film of pressure-sensitive adhesive |
| JPS5980459A (en) * | 1982-10-29 | 1984-05-09 | Arakawa Chem Ind Co Ltd | Water-absorbing powdery resin composition |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5204109A (en) * | 1989-12-28 | 1993-04-20 | Nitto Denko Corporation | Percutaneous gel preparation |
| GR1001334B (en) * | 1992-05-29 | 1993-08-31 | Colgate Palmolive Co | Linear viscoelastic aqueous liquid automatic dishwasher detergent composition. |
| EP0574236A2 (en) * | 1992-06-08 | 1993-12-15 | Colgate-Palmolive Company | Aqueous composition containing a non-crosslinked polymer for augmenting viscosity |
| EP0574236A3 (en) * | 1992-06-08 | 1994-08-31 | Colgate Palmolive Co | |
| US5845954A (en) * | 1996-06-25 | 1998-12-08 | Toyota Technical Center, U.S.A., Inc. | Glove box assembly including glove box that is positionable in a partially open position |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6313452B2 (en) | 1988-03-25 |
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