JPS60150244A - Optical information recording carrier - Google Patents
Optical information recording carrierInfo
- Publication number
- JPS60150244A JPS60150244A JP59005351A JP535184A JPS60150244A JP S60150244 A JPS60150244 A JP S60150244A JP 59005351 A JP59005351 A JP 59005351A JP 535184 A JP535184 A JP 535184A JP S60150244 A JPS60150244 A JP S60150244A
- Authority
- JP
- Japan
- Prior art keywords
- recording layer
- water
- substrate
- insoluble
- cyanine dye
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
- G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
- G11B7/241—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
- G11B7/242—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers
- G11B7/244—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only
- G11B7/246—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only containing dyes
- G11B7/247—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only containing dyes methine or polymethine dyes
- G11B7/2472—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only containing dyes methine or polymethine dyes cyanine
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
- G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
- G11B7/241—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
- G11B7/242—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers
- G11B7/244—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
- G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
- G11B7/241—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
- G11B7/252—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers
- G11B7/253—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of substrates
- G11B7/2531—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of substrates comprising glass
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
- G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
- G11B7/241—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
- G11B7/252—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers
- G11B7/253—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of substrates
- G11B7/2533—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of substrates comprising resins
Abstract
Description
【発明の詳細な説明】 炎順L」 本発明は光学式情報記録担体に関する。[Detailed description of the invention] Enjun L” The present invention relates to an optical information record carrier.
11炎1
光学式情報記録担体は、レーザ光を利用して該担体に設
けられた記録層に情報を記録するものであり例えば円盤
状光ディスクとして実用化されている。11 Flame 1 Optical information recording carriers record information on a recording layer provided on the carrier using laser light, and have been put to practical use, for example, as disc-shaped optical discs.
光ディスクの記録層に有機系色素、特にシアニン色素を
含んだ薄膜を用いる技術的思想が特開昭58−1149
89、特開昭58−112790及び特願昭58−21
0077において提案されている。かかる提案における
光ディスクは第1図及び第2図に示されるものであり、
第3図に示す工程により製造される。すなわち、基盤す
なわちサブストレート1は、PMMA (ポリメチルメ
タクリレート)等のアクリル酸樹脂よりP、P、法又は
インジェクション法を用いて円盤状に成形され、該円盤
上に同心円状又は渦巻状の微細な案内溝(以下ガイドラ
ックと称す)が設けられているものである。サブストレ
ート1をクリーニング工程にて表面の汚れを除去し、シ
アニン色素を溶液にしたものをサブストレート1のガイ
ドラック面上にスピンコード法により均一に被膜する。The technical idea of using a thin film containing an organic dye, especially a cyanine dye, in the recording layer of an optical disk was published in JP-A-58-1149.
89, Japanese Patent Application Publication No. 58-112790 and Japanese Patent Application No. 58-21
0077. The optical disc in this proposal is shown in FIGS. 1 and 2,
It is manufactured by the steps shown in FIG. That is, the base, that is, the substrate 1, is formed into a disk shape from an acrylic acid resin such as PMMA (polymethyl methacrylate) using the P, P, method or injection method, and concentric or spiral fine particles are formed on the disk. A guide groove (hereinafter referred to as a guide rack) is provided. The substrate 1 is subjected to a cleaning process to remove dirt from its surface, and a solution of cyanine dye is uniformly coated on the guide rack surface of the substrate 1 by a spin code method.
その後、ベーキング工程にて被膜面を乾燥させ記録層2
を形成する。形成された記録層2を検査した後、記録層
2を保護するためにパーケージ工程にて記録層2を有し
たサブストレート1上に間隙3を保ってスペーサ6を介
してPMMA製保護板4を貼り合わせ、第1図の如き光
ディスクを得る。また第2図の如き記録層2を有するサ
ブストレート1を2枚用いた両面光ディスクも提案され
ている。After that, the coating surface is dried in a baking process to form the recording layer 2.
form. After inspecting the formed recording layer 2, in order to protect the recording layer 2, a protective plate 4 made of PMMA is placed on the substrate 1 having the recording layer 2 through a spacer 6 while maintaining a gap 3 in a packaging process. By pasting them together, an optical disc as shown in FIG. 1 is obtained. Further, a double-sided optical disk using two substrates 1 having recording layers 2 as shown in FIG. 2 has also been proposed.
なお、゛上記スビンコ゛−゛ト法は、サブストレート1
をその中心口りに例えば2.0 Orpm程度で回転さ
せながら、シアニン色素溶液を緩やかに半径方向に移動
するディスベンザを経てサブストレート1上に滴下せし
め、次いで滴下を止めた後、サブストレート1を例えば
1ooorp+n程度に回転数を上げ余剰溶液分を振り
飛ばし均一なる該溶液の被膜を行う方法である。In addition, the above subincoat method is applied to substrate 1.
The cyanine dye solution is dripped onto the substrate 1 through a dispenser that moves gently in the radial direction while rotating the cyanine dye solution around its center opening at about 2.0 Orpm, and after stopping the dripping, the substrate 1 is For example, the rotation speed is increased to about 1ooorp+n to shake off excess solution and form a uniform coating of the solution.
かかる従来の光ディスクの記録層2はシアニン色素から
なる薄膜であって、その表面はブロンズ光沢若しくは金
属光沢を有し再生時のレーザ光を反射するのに都合が良
い記録層である。また、シアニン色素の薄膜は特定の波
長のレーザ光に対して光を吸収して昇華する故に、記録
時のレーザ光ビームの照射によるビットの形成する記録
層としての機能をも有するものである。さらに、シアニ
ン色素の薄膜は可撓性に優れ、金属膜のように温度変化
によるひびが入りにくいことも確認されている。このよ
うな利点を有する故にシアニン色素単成分による単一薄
膜の記録層が形成されていた。The recording layer 2 of such a conventional optical disk is a thin film made of cyanine dye, and its surface has a bronze luster or a metallic luster, making it a recording layer convenient for reflecting laser light during reproduction. Furthermore, since the cyanine dye thin film absorbs laser light of a specific wavelength and sublimates, it also functions as a recording layer in which bits are formed by irradiation with a laser beam during recording. Furthermore, it has been confirmed that cyanine dye thin films have excellent flexibility and are less prone to cracking due to temperature changes, unlike metal films. Because of these advantages, a single thin film recording layer has been formed using a single cyanine dye component.
しかし乍ら、シアニン色素を溶解せしめる溶剤の多(は
、ケトン系溶剤であり、該溶剤はサブストレートの材質
で広く使用されているPMMA゛(ポリメチルメタクリ
レート)を溶かすものである。すなわち、ケトン系溶剤
を用いたシアニン色素溶液をP’MMAのガイドラック
付サブストレートの表面にスピンツー卜する際に該溶液
がその表面を膨潤又は溶解してしまい、記録層の形成後
、シアニン色素の薄膜が有する金属光沢を損なう結果に
なり、実際の光ディスクの製造に即さないという問題が
あった。However, most of the solvents that dissolve cyanine dyes are ketone-based solvents, and these solvents dissolve PMMA (polymethyl methacrylate), which is widely used as a substrate material. When a cyanine dye solution using a system solvent is spun onto the surface of a P'MMA substrate with a guide rack, the solution swells or dissolves the surface, and after the recording layer is formed, a thin film of cyanine dye is formed. This results in a loss of the metallic luster, which poses a problem in that it is not suitable for actual production of optical discs.
」1列1」
本発明の目的は、上記した問題を解決し金属光沢を維持
しつつ耐湿性及び耐候性に優れた情報記録担体を提供す
ることである。"1 row 1" An object of the present invention is to solve the above-mentioned problems and provide an information recording carrier that maintains metallic luster and has excellent moisture resistance and weather resistance.
本発明は、PMMA等のアクリル酸樹脂からなるサブス
トレー−、!面を保護する水溶性シア0ン色索からなる
第1記録層の上に非水溶性シアニン色素からなる第2記
録層を重ね合わせてなることを特徴として、該記録層の
金属光沢を維持しつつ耐湿性に優れた光学式情報記録担
体である。The present invention provides a substray made of acrylic acid resin such as PMMA. A second recording layer made of a water-insoluble cyanine dye is superimposed on a first recording layer made of a water-soluble cyanine dye that protects the surface, and the metallic luster of the recording layer is maintained. It is an optical information recording carrier with excellent moisture resistance.
1−1−九 ・ 以下、本発明の一実施例を図面によって説明する。1-1-9・ An embodiment of the present invention will be described below with reference to the drawings.
第4図は、本発明の光ディスクの断面を示している。第
1記録層11は水溶性シアニン色素からなるもので、第
2記録層12は非水溶性シアニン色素からなるものであ
る。これら2つのシアニン色素を予め用意する。第1記
録層を形成すべき水溶性シアニン色素としてはインドシ
アニングリーン°(MERCK No 4839 9t
h Ed 、)を用いると良好な結果を得られることが
確認された。インドシアニングリーンはそれ自体が記録
材料の機能を有しかつケトン系溶剤に不溶である。FIG. 4 shows a cross section of the optical disc of the present invention. The first recording layer 11 is made of a water-soluble cyanine dye, and the second recording layer 12 is made of a water-insoluble cyanine dye. These two cyanine dyes are prepared in advance. The water-soluble cyanine dye to form the first recording layer is indocyanine green° (MERCK No. 4839 9t).
It was confirmed that good results could be obtained using h Ed , ). Indocyanine green itself has the function of a recording material and is insoluble in ketone solvents.
本実施例では常温でメタノール中にインドシアニン2〜
5#O/ctで溶解して使用する。第2記録層として形
成すべき非水溶性シアニン色素としては従来からの例え
ば特開昭58−114989、5−
特開昭58−11279に開示される非水溶性シアニン
色素をシクロヘキサンに溶解して使用する。In this example, indocyanine 2 ~
Use by dissolving at 5#O/ct. As the water-insoluble cyanine dye to be formed as the second recording layer, conventional water-insoluble cyanine dyes disclosed in JP-A-58-114989, 5-JP-A-58-11279 are used by dissolving them in cyclohexane. do.
溶剤としては例えば3ペンタン、シア1?トンアルコー
ルを使用しても良い。As a solvent, for example, 3 pentane, 1 shea? Tons of alcohol may also be used.
第5図に示す製造工程によって第4図の如ぎ本発明の光
ディスクが製造される。ガイドラック付PMMAサブス
トレート1を用意してクリーニング工程においてその表
面の汚れを落す。その後、第1スピンコートテイング工
程にて予め用意されたインドシアニングリーンのメタノ
ール溶液を250 rpmで回転中のサブストレート1
の表面に滴下し、回転数を1000 rpn+に上げ余
剰溶液分を振り飛ばし均一なる被膜を行いかつメタノー
ルを充分に揮発させ第1記録層を形成せしめる。引き続
き回転数を250 rpmに下げ第2スピンコーテイン
グ工程として非水溶性シアニン色素のシフ日ヘキサン溶
液を第1記録層上に滴下し、回転数を400〜1000
rl)Illに上げ余剰溶液分を撮り飛ばし第2配録層
になるべき均一なる薄膜を得る。The optical disc of the present invention as shown in FIG. 4 is manufactured by the manufacturing process shown in FIG. A PMMA substrate 1 with a guide rack is prepared and dirt on its surface is removed in a cleaning process. After that, in the first spin coating process, a methanol solution of indocyanine green prepared in advance was applied to the substrate 1 which was rotating at 250 rpm.
, and the rotational speed was increased to 1000 rpm+ to shake off excess solution to form a uniform coating and sufficiently volatilize the methanol to form the first recording layer. Subsequently, the rotation speed was lowered to 250 rpm, and as a second spin coating step, Schiff's hexane solution of water-insoluble cyanine dye was dropped onto the first recording layer, and the rotation speed was increased to 400 to 1000 rpm.
rl) Ill and remove the excess solution to obtain a uniform thin film that will become the second recording layer.
その後ベーキング工程にて乾燥せしめ第1及び第6−
2記録層の積層を完成する。次に検査工程を経た後パッ
ケージエ稈にてスペーサ6及び保護板4によって記録層
を保護し光ディスクを得る。Thereafter, it is dried in a baking process to complete the lamination of the first and 6-2nd recording layers. After passing through an inspection process, the recording layer is protected by a spacer 6 and a protection plate 4 at the package end to obtain an optical disc.
なお、インドシアニングリーン等の水溶性シアニン色素
によってPMMAのサブストレート1の表面をシクロヘ
キサンから保護することにより、非水溶性シアニン色素
の溶液はPMMAのサブストレート1の表面に悪影響を
及ぼずことなく第2記録層を形成でき、インドシアラン
グリーンの記録層をも保護することが出来るのである。Note that by protecting the surface of the PMMA substrate 1 from cyclohexane with a water-soluble cyanine dye such as indocyanine green, the solution of the water-insoluble cyanine dye can be used without adversely affecting the surface of the PMMA substrate 1. 2 recording layers can be formed, and the indosialan green recording layer can also be protected.
また、耐湿性を前轍して第1記録層と第2記録層の厚さ
をスピンコーティング工程にて適宜に調節すべきである
が、非水溶性シアニン色素の第2記録層を厚くすること
が好ましい。In addition, the thickness of the first recording layer and the second recording layer should be adjusted appropriately in the spin coating process in consideration of moisture resistance. is preferred.
更に、本実施例においてPMMAのサブストレートを使
用しているが、ガラス、アクリル樹脂、ビニル樹脂、ポ
リエーテル樹脂、エポキシ樹脂、ポリカーボネート樹脂
、ポリブチラール樹脂、セルロースアセテートブチレー
ト樹脂、ニトロセルロース樹脂などから選ばれる材料に
よって成形されるサブストレートを使用しても良い。
。Furthermore, although a PMMA substrate is used in this example, other materials such as glass, acrylic resin, vinyl resin, polyether resin, epoxy resin, polycarbonate resin, polybutyral resin, cellulose acetate butyrate resin, nitrocellulose resin, etc. Substrates molded from the material of choice may also be used.
.
効 果
本発明によれば、ケトン系溶剤等の有機溶剤に弱いPM
MA等のサブストレートの表面を水溶性シアニン色素の
第1記録層によって保護しつつ第1記録層を非水溶性シ
アニン色素の第2記録層を第1記録層上に積層させるこ
とによって耐湿性に優れかつ長期に亘って安定した記録
層が得られる。Effects According to the present invention, PM, which is sensitive to organic solvents such as ketone solvents,
While protecting the surface of a substrate such as MA with a first recording layer made of a water-soluble cyanine dye, the first recording layer is made moisture resistant by laminating a second recording layer made of a water-insoluble cyanine dye on the first recording layer. An excellent and long-term stable recording layer can be obtained.
第1図は従、来の光ディスクの部分断面拡大図であり、
第2図は従来の両面光ディスクの部分断面拡大図であり
、第3図は従来の光ディスクの製造工程を示す概略図で
あり、第4図は本発明による光ディスクの部分断面拡大
図であり、第5図は本発明による光ディスクの製造工程
を示す概略図である。
主要部分の符号の説明
1・・・・・・ガイドラック付
PMMAサブストレート
2・・・シアニン色素記録層
3・・・・・・間隙
4・・・・・・PMMA保護板
6・・・・・・スペーサ
11・・・・・・第1記録層
12・・・・・・第2記録層
出願人 パイオニア株式会社
代理人 弁理士 藤村元彦
9−
\ 04
− 婦
#5 口
手続ネ…正書(方式)
1、事件の表示
昭和59年特許願第005351号
2、発明の名称
光学式情報記録担体
3、補正をする者
事件との関係 特許出願人
住 所 東京都目黒区目黒1丁目4番1号名 称 (5
01) パイオニア株式会社4、代理人 〒104
住 所 東京都中央区銀座3丁目10番9号6、補正の
対象 図面の浄書 (内容に変更なし)7、補正の内容
別紙添付のとおりFIG. 1 is an enlarged partial cross-sectional view of a conventional optical disc.
FIG. 2 is an enlarged partial sectional view of a conventional double-sided optical disc, FIG. 3 is a schematic diagram showing the manufacturing process of a conventional optical disc, and FIG. 4 is an enlarged partial sectional view of an optical disc according to the present invention. FIG. 5 is a schematic diagram showing the manufacturing process of an optical disc according to the present invention. Explanation of symbols of main parts 1... PMMA substrate with guide rack 2... Cyanine dye recording layer 3... Gap 4... PMMA protective plate 6... ...Spacer 11...First recording layer 12...Second recording layer Applicant Pioneer Co., Ltd. agent Patent attorney Motohiko Fujimura9-\04-Female #5 Oral procedure...Authentic document (Method) 1. Indication of the case Patent Application No. 005351 filed in 1982 2. Name of the invention Optical information recording carrier 3. Person making the amendment Relationship to the case Patent applicant address 1-4 Meguro, Meguro-ku, Tokyo No. 1 name (5
01) Pioneer Co., Ltd. 4, Agent 104 Address: 3-10-9-6, Ginza, Chuo-ku, Tokyo Subject of amendment Engraving of drawings (no change in content) 7. Contents of amendment As attached
Claims (1)
からなる第1記録層を形成し該第1記録層の上に非水溶
性のシアニン色素からなる第2記録層を積層させてなる
ことを特徴とする光学式情報記録担体。A first recording layer made of a water-soluble cyanine dye is formed on a substrate made of acrylic acid resin, and a second recording layer made of a water-insoluble cyanine dye is laminated on the first recording layer. Optical information recording carrier.
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP59005351A JPS60150244A (en) | 1984-01-14 | 1984-01-14 | Optical information recording carrier |
US06/690,200 US4639745A (en) | 1984-01-11 | 1985-01-10 | Optical recording medium |
DE19853500819 DE3500819A1 (en) | 1984-01-11 | 1985-01-11 | OPTICAL INFORMATION RECORDING MEDIUM AND METHOD FOR PRODUCING THE SAME |
GB08500697A GB2152686B (en) | 1984-01-11 | 1985-01-11 | Optical information recording medium |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP59005351A JPS60150244A (en) | 1984-01-14 | 1984-01-14 | Optical information recording carrier |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS60150244A true JPS60150244A (en) | 1985-08-07 |
JPH0447905B2 JPH0447905B2 (en) | 1992-08-05 |
Family
ID=11608770
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP59005351A Granted JPS60150244A (en) | 1984-01-11 | 1984-01-14 | Optical information recording carrier |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS60150244A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS63153192A (en) * | 1986-08-11 | 1988-06-25 | Sumitomo Chem Co Ltd | Optical information recording medium |
KR100763953B1 (en) | 2006-05-17 | 2007-10-05 | 인하대학교 산학협력단 | Colored electornic ink nanoparticles for electronic displays and preparation thereof |
-
1984
- 1984-01-14 JP JP59005351A patent/JPS60150244A/en active Granted
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS63153192A (en) * | 1986-08-11 | 1988-06-25 | Sumitomo Chem Co Ltd | Optical information recording medium |
KR100763953B1 (en) | 2006-05-17 | 2007-10-05 | 인하대학교 산학협력단 | Colored electornic ink nanoparticles for electronic displays and preparation thereof |
Also Published As
Publication number | Publication date |
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JPH0447905B2 (en) | 1992-08-05 |
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