JPS5984801A - Aerosol for expelling injurious insect in space - Google Patents
Aerosol for expelling injurious insect in spaceInfo
- Publication number
- JPS5984801A JPS5984801A JP19662582A JP19662582A JPS5984801A JP S5984801 A JPS5984801 A JP S5984801A JP 19662582 A JP19662582 A JP 19662582A JP 19662582 A JP19662582 A JP 19662582A JP S5984801 A JPS5984801 A JP S5984801A
- Authority
- JP
- Japan
- Prior art keywords
- aerosol
- hole diameter
- volume
- dimethyl ether
- petroleum gas
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Abstract
Description
【発明の詳細な説明】
本発明は空間用害虫駆除エアゾール剤に関し、さらに詳
しくは有好成分としＣ害虫駆除剤またはこれと共力剤と
のＴロジン溶液が４０〜５゜容量％、噴射剤としで２０
’Ｃｌζおける圧力が２．８〜８．５に９／ｃｄｃｎ
液化石油ガスがＯ〜ＳＯ容ｊ１％、液化ジメチルエーテ
？しが２０〜ｂ％からなるエアＩ＋ｌし原液を噴射バル
ブのハウジングの孔径が０．４−１．５３ｆｆ、ペーパ
ータップの孔径、ステムの孔径およびボタンの孔径が、
ｅｔｔぞし０．２５ ” ０．４１’ｌｌ Ｏ） エフ
Ｊ −ｒＩｉ缶＋ｉ！： 充ｊＪｌした爆発性、引火
性の危険がなく、噴射性の良好な、しかも害虫駆除効果
）こ極めで優れた空間用害虫駆除エアゾール剤）こ関す
るものであるっ従来空間用エアゾール殺虫剤の噴射剤と
しては’７０ン類、ジメチルエーテルまたｊま１ｌｌｌ
ガス類あるいはそれらの混合物が用いられできた。フロ
ンガスは爆発性、引火性の危険がなく、噴射性も良好で
あるが大気汚染、オゾン層破壊のおそれがあり、蜆在そ
の使用は規制ないし禁止の方同；こある。またジメチル
エーテルおよび液化石油ガスはいずｎも可燃性ガスであ
ることから、このような噴射剤を使用するときは爆発性
、引火性の危険を低減化せねばならず、例えば特公昭５
７−１６０８１号公報に記載されているよう）と比較的
圧力の低い特定の液化石油ガスを使用するなどの種々の
制約がある。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to an aerosol agent for controlling pests in a space, and more particularly, the present invention relates to an aerosol agent for controlling pests in a space, and more particularly, a C pest control agent or a T rosin solution containing the C pest control agent and a synergist thereof is 40 to 5% by volume of a propellant. Toshide 20
'The pressure in Clζ is 9/cdcn from 2.8 to 8.5
Liquefied petroleum gas is O~SO volume j1%, liquefied dimethyl ether? The undiluted solution is injected with air I + l consisting of 20-b%.The hole diameter of the valve housing is 0.4-1.53ff, the hole diameter of the paper tap, the hole diameter of the stem, and the hole diameter of the button.
ett 0.25"0.41'll O) FJ-rIi can+i!: Fully explosive, no flammable danger, good sprayability, and pest control effect) Excellent and excellent Regarding this topic, the conventional propellants for aerosol insecticides for spaces include '70s, dimethyl ether, and other propellants.
Gases or mixtures thereof could be used. Although fluorocarbon gas is not explosive or flammable and has good jetting properties, it poses a risk of air pollution and destruction of the ozone layer, so its use is regulated or prohibited. Furthermore, since dimethyl ether and liquefied petroleum gas are both flammable gases, when using such propellants, it is necessary to reduce the risk of explosion and flammability.
There are various restrictions such as the use of specific liquefied petroleum gas with relatively low pressure (as described in Japanese Patent No. 7-16081).
このような状況の丁）乙、本発明者らは空間用害虫駆除
エアゾール剤についで、鋭意検討を重ねｔこ結果、エア
ゾール缶の噴射バルブとして、そのハウジング孔径が０
４〜ｌ、 ５ ｕ 、ペーパータップの孔径、ステムの
孔径およびボタンの孔径が、それぞれ０．２５−０．４
ｍのバルブを用いること）こより、噴射剤とじてジメ
チ）レエーテルのみの使用でも、まｔコは、これと比較
的圧力の高い液化石油ガスを併用しでも、爆発性、引火
性に関する高圧ガス引締法に基づくｈ種の規制を満足し
、さら）こはその害虫駆除効果１′Ｃおいでも優れた空
間用エアゾール剤を調製することが可能であることを見
出し、本発明を完成しｔこ。Under these circumstances, the inventors of the present invention have conducted extensive studies regarding space pest control aerosol agents, and as a result, we have found that the housing hole diameter is 0.
4~l, 5u, the hole diameter of the paper tap, the hole diameter of the stem, and the hole diameter of the button are 0.25-0.4, respectively.
Therefore, even if only dimethylene ether is used as a propellant, Matco is able to prevent high-pressure gas with regard to explosiveness and flammability, even if it is used in conjunction with relatively high-pressure liquefied petroleum gas. We have discovered that it is possible to prepare a spatial aerosol agent that satisfies the regulations of Type H based on the Act and also has an excellent pest control effect, and has completed the present invention.
本発明のエアゾール剤シこおいで、有効成分としではピ
レスロイド系殺虫剤、有機リン系殺虫剤等の殺虫剤；よ
か、昆虫、ダニ類；こ対し生理活性を示す物質、例えば
、忌避剤、誘引剤、幼若ホルモン等の害虫駆除剤が使用
でき、これを必要ならば、ビペロニルブトキサイド等の
共力剤とともに、ケロシンシこ溶解しで、ケロシン溶液
とじて用−）る。In the aerosol formulation of the present invention, active ingredients include insecticides such as pyrethroid insecticides and organophosphorus insecticides; A pest control agent such as a kerosene agent or juvenile hormone can be used, and if necessary, it is dissolved in kerosene together with a synergist such as biperonyl butoxide to form a kerosene solution.
また噴射剤としＣはジメチルエーテル単独あるいはこれ
と、２０℃にお（ブる圧力が２．８〜８．５ｋｔｉ／ｄ
の液化石油ガスとの混合物を用いることができる。これ
らの配合割合につＳ）ｒは、ケロシン溶液が４０容量％
未満では、噴射剤が６０容量％を越え、爆発性、引火性
の危険が増大し、前記の高圧ガス取締法の規制を満足し
得す、さら）こ害虫駆除効果も充分ではなく、まｔこケ
ロシン溶液が５０容量％を越すと、引火性の危険の増大
の：ｉか、噴射性）こ関しても、噴震粒子が過大になり
、やはり害虫駆除効果を充分シζ発揮し得ないことから
、ケロシン溶液：噴射剤＝４０〜５０容量％：５０〜６
０容量％である。In addition, the propellant C is dimethyl ether alone or together with it at 20°C (at a pressure of 2.8 to 8.5 kti/d).
A mixture of liquefied petroleum gas and liquefied petroleum gas can be used. These compounding ratios S)r is 40% by volume of kerosene solution.
If the amount of the propellant exceeds 60% by volume, the danger of explosion and flammability increases, and the above-mentioned regulations of the High Pressure Gas Control Act cannot be satisfied. If the kerosene solution exceeds 50% by volume, there is an increased risk of flammability (i.e., ejectability), and the amount of ejected particles becomes too large, making it impossible to exert a sufficient pest control effect. Therefore, kerosene solution: Propellant = 40-50% by volume: 50-6
0% by volume.
また２、噴射剤としＣジメチルエーテルと液化石油ガス
を併用する場合のこれらの配合割合は、エアゾール缶の
噴射バルブのハウジングの孔径、ペーパータップの孔径
、ステムの孔径およびボタンの孔径によっ【も変わり得
るが、爆発性、引火性の危険を低減化するためシとは、
エアゾールを構成する全量中、ジメチルエーテルが２０
容量％以上であり、液化石油ガスが３０容量％以Ｆであ
る。2. When C dimethyl ether and liquefied petroleum gas are used together as propellants, the mixing ratio of these will vary depending on the pore diameter of the housing of the injection valve of the aerosol can, the pore diameter of the paper tap, the pore diameter of the stem, and the pore diameter of the button. However, in order to reduce the risk of explosiveness and flammability,
Dimethyl ether accounts for 20% of the total amount constituting the aerosol.
% by volume or more, and the liquefied petroleum gas is 30% by volume or more F.
前述のような配合割合でケロシン溶液および噴射剤を噴
射バルブのハウジングの孔径が、０．４〜１．５ｍ、、
ペーパータップの孔径、ステムの孔径およびボタンの孔
径が、それぞれ１． ｏ、 ２５〜０．４１１ＩＩＩの
エアゾール缶に充填すること；こより、爆発性、引火性
シこ関する高圧ガス取締法ｊこ基づくｈ種の規制を満足
し、しかも噴射性も良好で従っＣ１有効成分の害虫駆除
効率を充分シこ発揮し得る本発明の空間用害虫駆除エア
ゾール剤が得られる。The kerosene solution and propellant are injected in the mixing ratio as described above.The housing of the valve has a hole diameter of 0.4 to 1.5 m.
The hole diameter of the paper tap, the hole diameter of the stem, and the hole diameter of the button are each 1. o, Filled in an aerosol can of 25 to 0.411III; it satisfies the regulations of class H based on the High Pressure Gas Control Act regarding explosive and flammable substances, has good jetting properties, and contains C1 active ingredients. The spatial pest control aerosol agent of the present invention can be obtained which can sufficiently exhibit pest control efficiency.
次）こ本発明の空間用害虫駆除エアゾール剤Ｓこ関する
実施例を示すが、本発明がそれらりこ限定されるもので
はない。Next) Examples related to the spatial pest control aerosol agent S of the present invention will be shown, but the present invention is not limited thereto.
実施例１
有効成分、とじてフタルスリン０．３％（Ｗ／Ｖ）とｄ
−フェノトリン〔フェノトリンの（＋〉シス、トランス
酸体、以Ｆ同様〕０．２％（Ｗ７Ｖ ＋のケロシン溶液
５０容量％をエアゾール缶に入れ、それ；こ２０ ’Ｃ
ｌこおＧプる圧力が８．０ ｋｇ／−の液化石油ガス２
２゜５容量％と液化ジメチルエーテル２７．５容量９６
ヲ常法）こ従って充填し、第１表：こ示すハウジングの
件径、ベーノｆ−タップの孔径、ステムの孔径およびボ
タンの孔径の噴射バルブの空間用害虫駆除エアゾール剤
を得た。Example 1 Active ingredient, phthalthrin 0.3% (W/V) and d
- Phenothrin [(+> cis, trans acid form of phenothrin, same as F)] 0.2% (W7V Pour 50% by volume of + kerosene solution into an aerosol can;
Liquefied petroleum gas 2 with a pressure of 8.0 kg/-
2.5% by volume and liquefied dimethyl ether 27.5% by volume96
A pest control aerosol agent for the space of an injection valve having the housing diameter, beno F-tap pore diameter, stem pore diameter and button pore diameter shown in Table 1 was obtained.
次薯こ、この空間用害虫駆除エアゾール剤の爆発性、引
火性、噴射性および買出駆除効果を試験した結果を第１
表シこポす。なお爆発性は爆発性試験法による爆発濃度
を、引火性は引火性試験法りこよる火炎長を、噴射性は
肉眼観察の結果を、害虫駆除効果はビートグラディー・
チャンバーを用いたノ１工、力の害虫駆除効力を○、△
、×の３段階に評価し、それぞれ良好なものｔｒ○」で
、使用可能なものを「△」で、使用不可能なものを「×
」で示す。Next, we will present the results of testing the explosiveness, flammability, jetting properties, and commercial extermination effect of this spatial pest control aerosol agent.
The table is posted. Explosiveness is determined by the explosive concentration determined by the explosive test method, flammability is determined by the flame length determined by the flammability test method, sprayability is determined by the result of naked eye observation, and pest control effectiveness is determined by Beat Grady.
No. 1 technique using a chamber, the power pest extermination effect is ○, △
, ×, respectively. Good ones are tr○", usable ones are "△", and unusable ones are "×".
”.
実施例２
有効成分とし℃フタルスリン０．８％（Ｗ７Ｖ ｒとｄ
−フェノトリン０．２％（Ｗ／Ｖｌケロシン）こ溶解し
た原液を２０′ＣにおＣブる圧力が２．４〜４．０ ｋ
（ｊ ／ ｄの液化石油ガスと液化ジメチルエーテルと
を第２表Ｓこ示す各種の客員割合で配合しでエアゾール
缶シこ充填し、ハウジングの孔径が０．８ ｔｍ、ペー
パータップの孔径、ステムの孔径、ボタンの孔径がそれ
ぞれＱ、 ３ ＭＭの噴射バルブのｈ空間用害虫駆除エ
アゾール剤を得ｔこ。Example 2 Active ingredient: °C Phthalthrin 0.8% (W7V r and d
- The pressure at which the stock solution of phenothrin 0.2% (W/Vl kerosene) is heated to 20'C is 2.4 to 4.0 k.
(j / d liquefied petroleum gas and liquefied dimethyl ether were mixed at various ratios shown in Table 2 S and filled into an aerosol can, the pore diameter of the housing was 0.8 tm, the pore diameter of the paper tap, and the diameter of the stem). I obtained a pest control aerosol agent for the h space of the injection valve with hole diameter and button hole diameter of Q and 3 MM, respectively.
次シこ、実施例１と同様の試験を行った結果を第２表に
示す。Next, the same test as in Example 1 was conducted and the results are shown in Table 2.
３−
実施例８
有効成分とじでｄ−アレスリン（７１／スＩＪンの（十
）シス、トランス酸体〕ｏ、４％（ＷＡｉ＞とｄ−レス
メトリン〔レスメトリンの（＋）シス、トランス酸体、
以Ｆ同様） ０．２ ％ （Ｗ／Ｖｌおよび共力剤とじ
てビペロニ）レブトキサイド１．５％（Ｗ／Ｖ）のケロ
シン溶液４ｏ容量％をエアゾール缶）こ入れ、それ）こ
２０ ’ＣＩこおＣブる圧力が２．８ ｋ？ ／ ｄの
液化甲部ガス２ｏ容量％および液化ジメチルエーテル４
ｏ容Ｒ％を充填し、ハウジングの孔径が１．５鮪、ペー
パークップの孔径、ステムの孔径、ボタンの孔径がそれ
ぞれＱ、 ３ ｙｔｗの噴射バルブの空間用害虫駆除エ
アゾール剤を得た。3- Example 8 Active ingredients include d-allethrin ((10) cis, trans acid form of 71/suIJ) o, 4% (WAi>) and d-resmethrin [(+) cis, trans acid form of resmethrin ,
0.2% (W/Vl and synergist as biperoni) levbutoxide 1.5% (W/V) kerosene solution (40% by volume) in an aerosol can) and 20 'CI here. Is the C pressure 2.8 k? / d liquefied upper gas 2o volume % and liquefied dimethyl ether 4
A pest control aerosol agent for the space of an injection valve was obtained by filling the space with a pore size of 1.5 tuna, a pore diameter of a paper cup, a pore diameter of a stem, and a pore diameter of a button of Q and 3 ytw.
次；こ、実施例１と同様の試験ｆｆ−行ったところ爆発
性、引火性、噴射性および害虫駆除効果の何れの面Ｓこ
おいでも使用可能なものであった。Next, the same test as in Example 1 was conducted, and the product was found to be usable in terms of explosiveness, flammability, jetting properties, and pest extermination effect.
実施例４
有効成分としＣフタスリン０．６％（Ｗ／Ｖ）とｄ−フ
ェノトリン０．２％（Ｗ／Ｖ）のケロシン溶液４５容暇
％をエアゾール缶）こ入れ、それに２０℃ｙζお番ブる
圧力が８．２ ｋｇ／ ｃｄの液化石油ガス２０容量％
および液化ジメチルエーテル８５容屋％を充填し、ハウ
ジングの孔径が１．０朋、ステムの孔径が０．８５ ｍ
ｌ、 ／＜ −ハークツブの孔径、ボタンの孔径がそれ
ぞれ０．８閂の噴射バルブの空間用害虫駆除エアゾール
剤を得ｔこ。Example 4 A 45% kerosene solution containing 0.6% (W/V) C-phthalin and 0.2% (W/V) d-phenothrin as active ingredients was added to an aerosol can) and heated at 20°C. 20% by volume of liquefied petroleum gas with a pressure of 8.2 kg/cd
and 85% liquefied dimethyl ether, housing pore diameter 1.0 mm, stem pore diameter 0.85 m.
/< - Obtain an aerosol agent for pest control in a space with an injection valve in which the hole diameter of the knob and the hole diameter of the button are each 0.8 bar.
次シこ、実施例１と同様の試験を行ったところ、爆発性
、引火性、噴射性および害虫駆除効果の何れの面におい
でも使用可能なものであった。Next, the same tests as in Example 1 were conducted, and the result was that the product could be used in terms of explosiveness, flammability, sprayability, and pest control effect.
実施例５
有効ｔｓ分としてフタルスリン０．６％（Ｗ／Ｖ）とｄ
−レスメトリン０，１％（Ｗ／Ｖｌ および共力剤と
しＣオクククロロジブロビルエーテル２％（Ｗ／Ｖ）の
ケロシン溶液５０容ｔ％をエアゾール缶）こ入れ、それ
シこ液化ジメチルエーテルの５０容凰９６ヲ充填し、ハ
ウジングの孔径が１． ｏ闘、ペーパータップの孔径が
０．８５ＭＭ。Example 5 Phthalthrin 0.6% (W/V) and d as effective ts
- Resmethrin 0.1% (W/Vl and as synergist Cocucchlorodibrobyl ether 2% (W/V) kerosene solution in 50 volume t% in an aerosol can) and then 50% of liquefied dimethyl ether. The housing is filled with 96 holes and the hole diameter of the housing is 1. The hole diameter of the paper tap is 0.85MM.
ステムの孔径、ボタンの孔径がそれぞれ０．３闘の噴射
バルブの空間用害虫駆除エアゾール剤を得た。A spatial pest control aerosol agent having an injection valve with a stem pore diameter and a button pore diameter of 0.3 mm was obtained.
次）こ、実施例１と同様の試験を行ツｔこところ、爆発
性、引火性、噴射性および害虫駆除効果の何れの面）こ
お−）でも使用可能なものであっｔこ。Next) The same tests as in Example 1 were conducted, and the product was found to be usable in terms of explosiveness, flammability, jetting properties, and pest extermination effect.
実施例６
有効成分としＣフタルスリン０．２％（Ｗ／白とフェニ
トロチオン０，５％（Ｗ／Ｖ）のケロシン溶液４５容量
％をエアゾール缶；こ入れ、それシｃ２ｏｃ＋こおける
圧力がａ、 ２ ｋｑ ／ ｃｔｊの液化石油ガス２
ｂ 容量％およびジメチルエーテル８０容取％を充填し
、ハウジング径が０．８羽、ペーパータップ径がＱ、
４１１Ｍ 、ステム径、ボタン径がそれぞれ０．８８の
噴射バルブの空間用害虫駆除エアゾール剤を得た。Example 6 A kerosene solution containing 45% by volume of Cphthalthrin 0.2% (W/white) and fenitrothion 0.5% (W/V) as active ingredients was poured into an aerosol can; the pressure at which it was heated was a, 2 kq/ctj liquefied petroleum gas 2
b Filled with volume% and dimethyl ether 80% by volume, housing diameter is 0.8 wings, paper tap diameter is Q,
A spatial pest control aerosol agent having an injection valve having a diameter of 411M, a stem diameter, and a button diameter of 0.88 was obtained.
次シこ、実施例１と同様の試験を行っｔこところ、爆発
性、引火性、噴射性および害虫駆除効果の何れの面シこ
おいでも測用可能なものであった。Next, the same tests as in Example 1 were carried out, and all aspects of explosiveness, flammability, sprayability, and pest control effect were measurable.
手続補正１（自発）
昭和５８年２月７日
１、事件の表示
昭和５７年 特許願第１９６６２５号
２、発明の名称
空間用害虫駆除エアゾール剤
３、補正をする者
事件との関係 特許出願人
住 所 大阪市東区北浜５丁目１５番地名 称 （
２０９）住友化学工業株式会社代表者 土 方
武
４、代理人Procedural amendment 1 (voluntary) February 7, 1980 1, Indication of the case 1988 Patent Application No. 196625 2, Name space of the invention pest control aerosol 3, Person making the amendment Relationship with the case Patent applicant Address 5-15 Kitahama, Higashi-ku, Osaka Name (
209) Sumitomo Chemical Co., Ltd. Representative Hijikata
Takeshi 4, agent
Claims (1)
ジン溶液が４０−５０容量％、噴射剤として２０”Ｃ１
こおける圧力が２．８〜３．５ ｋｑ ／ｉの液化石油
ガスがθ−３０容量％、液化ジメチルエーテルが２０〜
６０容量％からなるエア／−１し原ｆｉを噴射バルブの
ハウジングツ孔径力０．４−１．５＋ｒＭ、ペーパータ
、ブの孔径、ステムの孔径およびボタンの孔径が、それ
ぞれ０．２５〜Ｑ、４１１Ｍのエアゾール缶１ζ充填し
た空間用害虫駆除エアゾール剤。The active ingredient is a pest control agent or a gamma rosin solution of this and a military agent at 40-50% by volume, and the propellant is 20"C1.
Liquefied petroleum gas with a pressure of 2.8 to 3.5 kq/i is θ-30% by volume, and liquefied dimethyl ether is 20 to 30% by volume.
Inject air consisting of 60% by volume / -1 and inject the valve housing hole diameter force 0.4-1.5 + rM, the hole diameter of the paper tab, the hole diameter of the stem, and the hole diameter of the button are 0.25 to Q, respectively. , 411M aerosol can filled with 1ζ space pest control aerosol agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP19662582A JPS5984801A (en) | 1982-11-08 | 1982-11-08 | Aerosol for expelling injurious insect in space |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP19662582A JPS5984801A (en) | 1982-11-08 | 1982-11-08 | Aerosol for expelling injurious insect in space |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS5984801A true JPS5984801A (en) | 1984-05-16 |
Family
ID=16360866
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP19662582A Pending JPS5984801A (en) | 1982-11-08 | 1982-11-08 | Aerosol for expelling injurious insect in space |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5984801A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6824079B2 (en) | 2003-01-24 | 2004-11-30 | S. C. Johnson & Son, Inc. | Aerosol dispenser assembly and method of reducing the particle size of a dispensed product |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5247922A (en) * | 1975-10-13 | 1977-04-16 | Yoshio Katsuta | Aerosol of insecticide |
| JPS5372821A (en) * | 1976-12-09 | 1978-06-28 | Sumitomo Chem Co Ltd | Aerosol insecticides |
| JPS5716081A (en) * | 1975-07-22 | 1982-01-27 | Cpc International Inc | Adhesive composition for producing wavy body |
| JPS5734172A (en) * | 1980-08-07 | 1982-02-24 | Kashiwa Kagaku Kogyo:Kk | Aerosol product |
-
1982
- 1982-11-08 JP JP19662582A patent/JPS5984801A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5716081A (en) * | 1975-07-22 | 1982-01-27 | Cpc International Inc | Adhesive composition for producing wavy body |
| JPS5247922A (en) * | 1975-10-13 | 1977-04-16 | Yoshio Katsuta | Aerosol of insecticide |
| JPS5372821A (en) * | 1976-12-09 | 1978-06-28 | Sumitomo Chem Co Ltd | Aerosol insecticides |
| JPS5734172A (en) * | 1980-08-07 | 1982-02-24 | Kashiwa Kagaku Kogyo:Kk | Aerosol product |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6824079B2 (en) | 2003-01-24 | 2004-11-30 | S. C. Johnson & Son, Inc. | Aerosol dispenser assembly and method of reducing the particle size of a dispensed product |
| US7014127B2 (en) | 2003-01-24 | 2006-03-21 | S.C. Johnson & Son, Inc. | Aerosol dispenser assembly having low volatile organic compound (VOC) content |
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