JPS5984202A - Infrared optical fiber and its manufacture - Google Patents
Infrared optical fiber and its manufactureInfo
- Publication number
- JPS5984202A JPS5984202A JP57195661A JP19566182A JPS5984202A JP S5984202 A JPS5984202 A JP S5984202A JP 57195661 A JP57195661 A JP 57195661A JP 19566182 A JP19566182 A JP 19566182A JP S5984202 A JPS5984202 A JP S5984202A
- Authority
- JP
- Japan
- Prior art keywords
- core
- optical fiber
- compd
- infrared fiber
- chalcogenide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 12
- 239000013307 optical fiber Substances 0.000 title abstract 4
- 238000001125 extrusion Methods 0.000 claims abstract description 5
- 239000011248 coating agent Substances 0.000 claims abstract 5
- 238000000576 coating method Methods 0.000 claims abstract 5
- 239000000835 fiber Substances 0.000 claims description 19
- -1 metal halide compound Chemical class 0.000 claims description 17
- 229910001507 metal halide Inorganic materials 0.000 claims description 10
- 238000005253 cladding Methods 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 8
- 238000010438 heat treatment Methods 0.000 claims description 5
- 238000007740 vapor deposition Methods 0.000 claims description 2
- 150000004770 chalcogenides Chemical class 0.000 abstract description 4
- 229920002472 Starch Polymers 0.000 abstract description 2
- 238000001816 cooling Methods 0.000 abstract description 2
- ADZWSOLPGZMUMY-UHFFFAOYSA-M silver bromide Chemical compound [Ag]Br ADZWSOLPGZMUMY-UHFFFAOYSA-M 0.000 abstract description 2
- 235000019698 starch Nutrition 0.000 abstract description 2
- 239000008107 starch Substances 0.000 abstract description 2
- 150000004820 halides Chemical class 0.000 abstract 2
- 230000035699 permeability Effects 0.000 abstract 1
- 239000006188 syrup Substances 0.000 abstract 1
- 235000020357 syrup Nutrition 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 description 3
- 238000002834 transmittance Methods 0.000 description 2
- QFLWZFQWSBQYPS-AWRAUJHKSA-N (3S)-3-[[(2S)-2-[[(2S)-2-[5-[(3aS,6aR)-2-oxo-1,3,3a,4,6,6a-hexahydrothieno[3,4-d]imidazol-4-yl]pentanoylamino]-3-methylbutanoyl]amino]-3-(4-hydroxyphenyl)propanoyl]amino]-4-[1-bis(4-chlorophenoxy)phosphorylbutylamino]-4-oxobutanoic acid Chemical compound CCCC(NC(=O)[C@H](CC(O)=O)NC(=O)[C@H](Cc1ccc(O)cc1)NC(=O)[C@@H](NC(=O)CCCCC1SC[C@@H]2NC(=O)N[C@H]12)C(C)C)P(=O)(Oc1ccc(Cl)cc1)Oc1ccc(Cl)cc1 QFLWZFQWSBQYPS-AWRAUJHKSA-N 0.000 description 1
- 229940126062 Compound A Drugs 0.000 description 1
- NLDMNSXOCDLTTB-UHFFFAOYSA-N Heterophylliin A Natural products O1C2COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC2C(OC(=O)C=2C=C(O)C(O)=C(O)C=2)C(O)C1OC(=O)C1=CC(O)=C(O)C(O)=C1 NLDMNSXOCDLTTB-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000005309 metal halides Chemical class 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
- 238000005491 wire drawing Methods 0.000 description 1
Classifications
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B6/00—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
- G02B6/10—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings of the optical waveguide type
- G02B6/102—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings of the optical waveguide type for infrared and ultraviolet radiation
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B37/00—Manufacture or treatment of flakes, fibres, or filaments from softened glass, minerals, or slags
- C03B37/01—Manufacture of glass fibres or filaments
- C03B37/02—Manufacture of glass fibres or filaments by drawing or extruding, e.g. direct drawing of molten glass from nozzles; Cooling fins therefor
- C03B37/022—Manufacture of glass fibres or filaments by drawing or extruding, e.g. direct drawing of molten glass from nozzles; Cooling fins therefor from molten glass in which the resultant product consists of different sorts of glass or is characterised by shape, e.g. hollow fibres, undulated fibres, fibres presenting a rough surface
- C03B37/023—Fibres composed of different sorts of glass, e.g. glass optical fibres, made by the double crucible technique
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B2201/00—Type of glass produced
- C03B2201/80—Non-oxide glasses or glass-type compositions
- C03B2201/84—Halide glasses other than fluoride glasses, i.e. Cl, Br or I glasses, e.g. AgCl-AgBr "glass"
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B2201/00—Type of glass produced
- C03B2201/80—Non-oxide glasses or glass-type compositions
- C03B2201/86—Chalcogenide glasses, i.e. S, Se or Te glasses
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Manufacturing & Machinery (AREA)
- Toxicology (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Optical Fibers, Optical Fiber Cores, And Optical Fiber Bundles (AREA)
Abstract
Description
【発明の詳細な説明】
本発明は、金属ハライド系化合物をコア部とする赤外フ
ァイバ及びその製造方法に関する。従来この種赤外ファ
イバ（コア部が金属ハライド系化合物で形成されている
赤外ファイバ）としては、クラッド部にＡｇＣ１を用い
たものがあるが、ＡｇＣｆ自身柔かいため機械強度、耐
久性が不充分であり、又、その製造方法の一つ１よ竹状
のＡｇＣ１！内に棒状の金属ハライド系化合物を挿入し
たものをアルミパイプ内に入れて引き抜き、線引加工を
行なうというものであり、この方法ではコア部とクラッ
ド部とのＷ而に一様な応力で変形を加えることが困・碓
なため前記界面が凹凸状となり、製造された赤外ブｒイ
バーの透過性が悪いという欠点があった。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to an infrared fiber having a core made of a metal halide compound and a method for manufacturing the same. Conventional infrared fibers of this type (infrared fibers whose core is made of a metal halide compound) use AgC1 for the cladding, but because AgCf itself is soft, its mechanical strength and durability are insufficient. And, one of the manufacturing methods is bamboo-like AgC1! A rod-shaped metal halide compound is inserted inside the aluminum pipe and pulled out to perform the wire drawing process.In this method, the core and cladding parts are deformed by uniform stress. Since it is difficult and difficult to add the above-mentioned infrared rays, the interface becomes uneven, resulting in the disadvantage that the produced infrared breaker has poor transmittance.
本発明は、これらの従来欠点に鑑み、機械強度、耐久性
及び透過性のいずれにおいても優れ、目、つ製造が容易
である７、金属ハライド系化合物をコア部とする赤外フ
ァイバ及びその製造方法を提供することを目的とする。In view of these conventional drawbacks, the present invention provides an infrared fiber having a core made of a metal halide compound, which has excellent mechanical strength, durability, and transparency, and is easy to manufacture. The purpose is to provide a method.
以下、本発明の実施例を図面に基いて説明する。Embodiments of the present invention will be described below with reference to the drawings.
第１図、ｖ；２図は本発明の一実施例を示し、同図にお
いて、ｌは押出し成形機のコンテナ、２はグイ、３はス
テムであって、コンテナ１内に収容された金属ハライド
系化合物Ａ （ＡｇＢｒ又はＴＶ−Ｘ。Ｘは、Ｃ／’
＋ Ｂｒｚ （Ｃ１＋ Ｂｒ ） ＋ （Ｂｒ＋
Ｉ ）、 （Ｃ１＋Ｂｒ −１−Ｉ ）などである。Figures 1 and 2 show an embodiment of the present invention, in which 1 is a container of an extrusion molding machine, 2 is a guide, 3 is a stem, and metal halide is housed in the container 1. Compound A (AgBr or TV-X. X is C/'
+ Brz (C1+ Br) + (Br+
I), (C1+Br-1-I), etc.
）はステム３に抑圧されてダイ２の開口４より押出し成
形され、赤外ファイバ５のコア部６が形成される。次に
、７は軟化用コンテナ、８は加熱用ヒータ、９は雰囲気
調整用カバーであって、投入口１０からコンテナ７内に
投入されたカルコゲナイド化合部１１（後述）はヒータ
８により加熱されて軟化し且つ水あめ状となり、押出し
成形中のコア部６外周に被覆され、爾後冷却されてクラ
ッド部１２が形成され、ステップインデックス型の赤外
ファイバ５が製造される。このとき入口１３から導入さ
れ出口１４から排出されるＡｒガスによって赤外ファイ
バ５成形時の雰囲気が調整される。句１５は空気ぬき孔
、１６は栓である。) is pressed by the stem 3 and extruded from the opening 4 of the die 2 to form the core portion 6 of the infrared fiber 5. Next, 7 is a container for softening, 8 is a heater for heating, and 9 is a cover for atmosphere adjustment, and a chalcogenide compound 11 (described later) that is introduced into the container 7 from an input port 10 is heated by the heater 8. It softens and becomes syrup-like, coats the outer periphery of the core part 6 which is being extruded, and is then cooled to form a clad part 12, thereby producing a step index type infrared fiber 5. At this time, the atmosphere during molding of the infrared fiber 5 is adjusted by Ar gas introduced from the inlet 13 and discharged from the outlet 14. Numeral 15 is an air vent, and 16 is a plug.
６１１記力ルコゲナイド化合物としては、たとえば、■
Ｇｅ＊Ｓ、■Ａｓ１１Ｓ、あるいは■Ａｓ＠ＳにＴｌ＋
Ｃ１，Ｂｒ、Ｉ、Ｆ、Ｓｅｔ Ｔｅ、Ｓｂ。Examples of the 611-dyelucogenide compounds include ■
Tl+ for Ge*S, ■As11S, or ■As@S
C1, Br, I, F, Set Te, Sb.
Ｇｅのうち一以上を適当用ブレンドしたものなどが用い
られ加熱により容易に軟化してあめ状となる。（たとえ
ばＧｅ ｍ Ｓの場合、軟化点３８０°Ｃ）次に、第３
図は、本発明の別実施例を示す。この実施例では、予じ
め押出し成形により製作した、金属ハライド系化合物よ
りなる長尺状のコア部６を巻取りボビン１７に巻取って
おき、次にこれを順次矢印方法に操り出して、その外局
にヒータ１８により加熱され軟化して水あめ状となった
カルコゲナイド化合物（前述）１１を被゛ｒυし爾後冷
却してステップインデックス型の赤外ファイバ５を製造
するものである。A suitable blend of one or more of Ge is used, and it is easily softened by heating to become candy-like. (For example, in the case of Ge m S, the softening point is 380°C) Next, the third
The figure shows another embodiment of the invention. In this embodiment, an elongated core part 6 made of a metal halide compound, manufactured in advance by extrusion molding, is wound up on a winding bobbin 17, and then the core part 6 is sequentially rolled out in the direction of the arrow. The step index type infrared fiber 5 is manufactured by heating the chalcogenide compound (described above) 11, which has been softened and becomes starch syrup-like by being heated by the heater 18, and then cooling it.
尚、図中１９は加熱るつぼである。この他に予じめ成形
したコア部の外周に、蒸着法を用いてカルコゲナイド化
合物を蒸着して赤外ファイバを製造してもよい。前記三
つの製造方法のいずれによっても、冒頭に記載した従来
方法のようにコア部−クラッド部の界面が凹凸状になる
ようなことがなく、従って赤外ファイバの透過性が向上
する。In addition, 19 in the figure is a heating crucible. Alternatively, an infrared fiber may be manufactured by depositing a chalcogenide compound on the outer periphery of a pre-formed core using a vapor deposition method. In any of the three manufacturing methods described above, unlike the conventional method described at the beginning, the interface between the core part and the cladding part does not become uneven, and therefore the transmittance of the infrared fiber is improved.
又、製作された赤外ファイバは、カルコゲナイド化合物
の物性に基き、機械強度、耐久性において、従来のＡｇ
Ｃｌ！をクラッド部とするものに比較しはるかに優れて
いる。In addition, the manufactured infrared fiber has mechanical strength and durability superior to that of conventional Ag based on the physical properties of the chalcogenide compound.
Cl! This is far superior to those with a cladding part.
以上説明したように、本発明によれば透過性、機械強度
、ｉ＠久住の点で優れた、金属ハライド系化合物をコア
部とする赤外ファイバを得られ、その製造もクラッド部
となるカルコゲナイド化合物の特性である軟化しやすい
点、蒸着しやすい点を利用し容易に行なうことができる
。As explained above, according to the present invention, it is possible to obtain an infrared fiber having a metal halide compound as the core part, which is excellent in terms of transparency, mechanical strength, and i@kusumi, and its production is also possible using chalcogenide as the cladding part. This can be easily carried out by taking advantage of the characteristics of the compound, which are that it is easy to soften and that it is easy to vapor deposit.
第４図は本発明の赤外ファイバの製造方法を示す縦断面
図、第２図は赤外ファイバの縦断面図、第３図は本発明
にかかる製造方法の別実施例を示す説明図である。
５・・・赤外ファイバ、６・・・コア部、１１・・カル
コゲナイド化合物、１２・・・クラッド部、Ａ・・金属
ノＸライド系化合物。FIG. 4 is a longitudinal cross-sectional view showing the infrared fiber manufacturing method of the present invention, FIG. 2 is a vertical cross-sectional view of the infrared fiber, and FIG. 3 is an explanatory diagram showing another embodiment of the manufacturing method according to the present invention. be. 5... Infrared fiber, 6... Core part, 11... Chalcogenide compound, 12... Clad part, A... Metal no Xride based compound.
Claims (1)
クラッド部がカルコゲナイド化合物で構成されている赤
外ファイバ （ｚ）金属ハライド系化合物よりなりコア部の外周を、
加熱により軟化した状態のカルコゲナイド化合物で被覆
してクラッド部を形成することを特徴とする赤外ファイ
バの製造方法 （３） コア部の押出し成形時に前記被覆を行なう特
許請求の範囲第（２）項に記載の赤外ファイバの製造方
法 （４）予じめ成形したコア部を移送しつつ前記被覆を行
なう特許請求の範囲第（２）項に記載の赤外ファイバの
製造方法 （５）予じめ成形した金属ハライド系化合物よりなるコ
ア部を蒸着法によりカルコゲナイド化合物で被覆しそク
ラッド部を形成することを特徴とする赤外ファイバの製
造方法[Claims] (1) The core portion is composed of a metal halide compound,
Infrared fiber (z) whose cladding part is made of a chalcogenide compound.The outer circumference of the core part is made of a metal halide compound.
A method for manufacturing an infrared fiber (3), characterized in that the cladding portion is formed by coating with a chalcogenide compound softened by heating. Claim (2), wherein the coating is performed during extrusion molding of the core portion. (4) The method for manufacturing an infrared fiber according to claim (2), in which the coating is carried out while transferring the preformed core part. A method for producing an infrared fiber, which comprises forming a core made of a metal halide compound and forming a cladding part by coating the core part with a chalcogenide compound by a vapor deposition method.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP57195661A JPS5984202A (en) | 1982-11-06 | 1982-11-06 | Infrared optical fiber and its manufacture |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP57195661A JPS5984202A (en) | 1982-11-06 | 1982-11-06 | Infrared optical fiber and its manufacture |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS5984202A true JPS5984202A (en) | 1984-05-15 |
Family
ID=16344882
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP57195661A Pending JPS5984202A (en) | 1982-11-06 | 1982-11-06 | Infrared optical fiber and its manufacture |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5984202A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6564587B2 (en) * | 2000-09-01 | 2003-05-20 | Viatcheslav Artiouchenko | Method of producing an optical fiber by gathering material from a molten bath |
-
1982
- 1982-11-06 JP JP57195661A patent/JPS5984202A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6564587B2 (en) * | 2000-09-01 | 2003-05-20 | Viatcheslav Artiouchenko | Method of producing an optical fiber by gathering material from a molten bath |
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