JPS5979965A - Thionyl chloride-lithium cell - Google Patents
Thionyl chloride-lithium cellInfo
- Publication number
- JPS5979965A JPS5979965A JP57190229A JP19022982A JPS5979965A JP S5979965 A JPS5979965 A JP S5979965A JP 57190229 A JP57190229 A JP 57190229A JP 19022982 A JP19022982 A JP 19022982A JP S5979965 A JPS5979965 A JP S5979965A
- Authority
- JP
- Japan
- Prior art keywords
- thin
- groove
- walled
- thionyl chloride
- cover
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/30—Arrangements for facilitating escape of gases
- H01M50/342—Non-re-sealable arrangements
- H01M50/3425—Non-re-sealable arrangements in the form of rupturable membranes or weakened parts, e.g. pierced with the aid of a sharp member
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Abstract
Description
【発明の詳細な説明】
本発明は正肉！お主体、リチウム１１−、ガラスセハレ
”−、、’ｒＥｌｉＱ活物７ｑを兼ねる）１４化チオニ
ル亀解液等より成る塩化チオニル・リチウム電池に関し
、その一部に薄肉溝部を何する電池蓋Ｖはケース中に吻
仮群を収納１市疋して成る電池に１ＳＬ４ｆろものであ
る。[Detailed Description of the Invention] The present invention is true meat! Regarding the thionyl chloride lithium battery made of thionyl 14ide methane solution etc., the battery cover V is the case. It is a 1SL4F battery that houses a proboscis group inside.
近年の著しい電子技術の進歩により、ポータフル機器電
源としてＩｆｌいられている各種−欠″ｊ’ｌ（曲によ
り昼性能、小型、軽爪化が求めら１．ることとなり、正
ｔＩｌＩＩ活物質に ＯＦ ｎ 、Ｍｎ（Ｊ２を用いた
リチウム電池に代表さオ′１．る川く、各種リチウム゛
ｒｌＥ曲がその高性能故に著しい１１１４光を浴びるに
至っている。Due to the remarkable progress in electronic technology in recent years, various types of IflI active materials are required as portable equipment power supplies (depending on the song, daytime performance, small size, and light weight). Various types of lithium batteries, such as lithium batteries using OF n and Mn (J2), are now exposed to remarkable 1114 light due to their high performance.
塩化チオニル・リチウム１攬朋も その非□＾イに茜い
エネルギ゛−１で度、出力密ｊ■、趙７１ｉ； Ｅｌ二
１生目−９を住１丁平担即、ｌ樋Ｄｆなろｌ晶度を牛龍
、貯蔵ＶＩＳ能故に？主目さＡ′１ているＩＫγｍ０）
１つである。Thionyl chloride lithium 1 攬本 also has an extremely bright energy ゛-1 degree, output density j■, Zhao 71i; Uryuu's crystallinity, because of storage VIS ability? IKγm0 with main eye A'1)
There is one.
この°市７１ｊｌは一般には市解欣に比ｉｉＥ抗か約５
（］見・ｃｍの１．５ＭＩノ１Ａｌｃ１４− Ｓす（月
２Ｍ、Ｉｆを用い−Ｃいるので非常に内部抵抗か低く（
数ｎ〜００（１０λ八５中ｎＡ／ｒｍ２以上の大“ｉｉ
Ｅ ７を放電がｉｉＴ ｒｉｇという′ｆ、′Ｆ徴金ｔ
）っている反面、電油温度が１１０”Ｃ以上に至るよう
なＦｔＩｆ；′ｊｔ１．１に亙る大面ｗＦ、牧電、父は
夕）部７（ｊ絡件の’Ｊ’Ｓ ’／ｆｆ ’侍には反応
生Ｉ））シ゛１りであるイオウが沼融してリチウムと接
触し、１ノ１部旬絡を引き起こし著しく発熱、遂にはリ
チウムか浴融して激しく反１＋５、直曲太爆元に至ると
いう危険性を育している。時に塩化チオニルは非常に反
応性が強く、？［ｒｌｕケースとしてステンレス、ニッ
ケル以外Ｉｉとんど便用小町のためこれら金属製ケース
中に活物ｅイか収納さ）］ておＩ）、その剛力は強く、
従って爆発のエネルギーは非常に大きなものとなる。従
ってこス］、ら危１φをＩｔｇ比するため涌′帛はケー
スに安♀弁が、役賄され上述の如き異゛ｊイ時にも比’
Ｉｆｌ旧低い（１ニカで屯ｔＪＬ内１土を１ｊ台放し、
大・Ｕ ニ至らない様対策か１通されていた。This city 71jl is generally about 50% lower than the city's resolution.
(] 1.5 MI of 1.5 cm, Alc14-S (2 M, If-C is used, so the internal resistance is very low (
Number n~00 (large "ii" of nA/rm2 or more in 10λ85
E 7 is discharged iiT rig 'f, 'F charge t
) On the other hand, FtIf; 'jt1.1, where the temperature of the electric oil reaches 110"C or higher, wF, Makiden, father is evening) Part 7 ('J'S' / of j connection) ff 'The samurai saw that the sulfur, which is a reaction product I)), melted in the water and came into contact with the lithium, causing a 1 part 1 part short circuit and a significant heat generation.Finally, the lithium melted in the bath, violently reacting with 1+5, and directly. There is a danger that thionyl chloride is very reactive, and ? When storing living things, their rigidity is strong.
Therefore, the energy of the explosion is extremely large. Therefore, in order to compare the danger 1φ with Itg, the safety valve is attached to the case, and even in the case of the above-mentioned abnormal situation,
Ifl old low (1 ton JL 1 soil for 1 Nika, 1 J unit released,
One letter was sent to ensure that this did not happen.
ｔｊｔ来ではこれら安忙弁として、ステンレス又ハニノ
ケルケースの一部に肉薄の一部を設＋１で破裂１１蝿と
したり又は塩化チオニルに対し抵抗力の・ｂる純α−ア
ルミナより成る士ラミックをメタライシックυ１１工［
７た後ケースに塔接し、円１王上昇に１ｔなうブースの
変形にょｒ）−１！ラミツクをイ呟壊し、ビ」シ１三を
開放する専の手段が採ら１１てきた。Since TJT, as a safety valve, a part of the stainless steel or honey cell case is made with a thin part to make it burst with +1, or metal lamic made of pure α-alumina that is resistant to thionyl chloride is used. υ11 engineering [
After 7 seconds, the booth touches the case and the 1 yen rises to 1 t. Special measures have been taken to destroy Ramitsuku and free the city.
このような方法は、その作動は確実であるが、ケース加
工が非′酵に回倒で高価につくという′に点がある。Although this method works reliably, the problem is that the case processing requires a lot of work without fermentation and is expensive.
本発明はこれら従来の方法に替わり、その一部に同心円
状、半円状、十状、−状＋ＭはＵ字状等の肉薄溝部を何
する′准γｍ蓋、或はケースを用いて゛電池とし、異常
時の１Ｆ３ＥＥの上昇に伴い同品を低匝で破裂させ、安
全弁として用いることを・待機とする電池に関するもの
である。In place of these conventional methods, the present invention uses a 'quasi-γm cover or case which has thin grooves such as concentric, semicircular, ten-shaped, and U-shaped in a part thereof. This relates to a battery that is used as a safety valve by bursting at a low rate when 1F3EE rises during abnormal conditions.
以下本発明の一実施例に付図面と共に説明する。An embodiment of the present invention will be described below with reference to the accompanying drawings.
第１因は本発明に基づくスパイラル構造の１１５化チオ
ニル・リチウム７１Ｊ、 ｒｉｆ＋の縦断面１スであｔ
）、図中＋１１ハス−ｒ ンレス羽より成る負勧端「を
庶ねろケース。The first factor is that the vertical cross section of lithium thionyl 115 71J, rif+, which has a spiral structure based on the present invention, is t.
), +11 hash-r in the figure A case with a negative end made of feathers.
（２）はステ゛ルス鋼より成る電ｒｌＩＩ蓋で本発明に
基づく安全弁の働きをする肉薄溝部（３）が同心円状に
設けてＪ）１′＋１周辺部はケースにＭ接一体化さｔｌ
でいる。（４１はリチウム負ｂｉ１１．（５１はカラス
不織市より成るセパレーター、（６）はアセチレンブラ
ックとテフロンより成る市陣集（ｌＵ体、（７）はテフ
ロン裂の底部絶縁板、（８）はニッケルより成る負１他
リード片で屯ｒ山ケースにスポラＩ−ｒ４ｍされている
。（９）はニッケル片より成る正諭リード片で注欣胃を
兼ねるステンレス剖Ｊ： ’１ 成る正自端子（１ｏ）
にスボ・ノド溶接すｌている。ＬＥ両側子は電解欣注入
妻上端を溶着シールされている。（１１）は上階４子と
負戦端子を絶縁するガラス睡でハーメチックシールされ
ている。(2) is an electric rlII lid made of steel, and a thin groove part (3) that functions as a safety valve based on the present invention is provided concentrically.
I'm here. (41 is a lithium negative bi11. (51 is a separator made of Karasu non-woven fabric, (6) is a separator made of acetylene black and Teflon, (7) is a bottom insulating plate with Teflon cracks, (8) is A negative lead piece made of nickel is connected to a spora I-r4m in the mount case. (9) is a positive lead piece made of nickel, which also serves as a vent, and is made of stainless steel. (1o)
There is sub-groove welding. Both sides of the LE are welded and sealed at the upper ends of the electrolyte injection ends. (11) is hermetically sealed with a glass plate that insulates the upper four terminals and the negative terminal.
（１２）はテフロンより成る上部絶偉仮で・多）ろ。第
２図に°電池蓋（２）の正面図を第３図に同心内状肉ａ
ｑ部の部分拡大断面図を示−ｔｏ本実ｈＩＵ例の肉薄溝
部は電池蓋の加工時に同時にプレス加工により設けたも
ので生則厚Ｑ、 ４ 顛のステンレスにｒｊＪ １１．
２ ＃肩、厚みをＱ、Ｑ２ａ＊に仕−ヒげたものである
。このＪ、うな肉薄溝部は非常にｎｎ Ｉ４ａなプレス
加工で形成することかでき、又同品か肉薄となっている
ため同品の機械的耐力が低く、従って内圧の上昇に伴う
ひずみにより゛容易に同品で破断が起き内王を外部に開
放する。また開放王力の設定は溝巾及び丙薄部の厚み、
或は溝の形状を変えることにより容易に変えることかで
きる。(12) has an upper part made of Teflon. Figure 2 shows the front view of the battery cover (2), and Figure 3 shows the concentric inner wall a.
A partial enlarged cross-sectional view of part q is shown.The thin groove part in this example was created by press working at the same time as the battery cover was manufactured, and the standard thickness was Q.
2 #Shoulder and thickness are adjusted to Q and Q2a*. This J-like thin groove can be formed by a very nnI4a press process, and since it is thin, the mechanical strength of the product is low, and therefore it is easily distorted due to an increase in internal pressure. A rupture occurs in the same item, opening the inner king to the outside. In addition, the setting of the opening force is the groove width and the thickness of the thin part,
Alternatively, it can be easily changed by changing the shape of the groove.
従って肉薄溝部の形状は必ずしも本実施例の如く同心円
状に限定するものではなく、例えば半円状士状、−Ｖ犬
、Ｕ字ｖＫ等ｆ壬意の／１９１犬とすることかできる。Therefore, the shape of the thin groove portion is not necessarily limited to concentric circles as in this embodiment, but may be, for example, a semicircular shape, a -V dog, a U-shape vK, or a /191 dog shape.
又肉薄溝部は電池蓋に設けるだけではなくケース底部、
或いはケース側ＩＩＩＩに１役けても同一効果は得ろこ
とができるし、更に２個所以上に亙６１王力設定を変え
た肉薄溝部を没けることも町１泪である。In addition, the thin groove is not only provided on the battery cover, but also on the bottom of the case,
Alternatively, the same effect can be obtained by using one part on the case side III, and it is also a good idea to submerge the thin groove part where the 61 power setting is changed in two or more places.
つぎに不実１ｆｌ！ｉ例に基づく形状の電池蓋を用い１
用放王を２５＃／ｄＧに設定して作成Ｅ７たＩ１１径８
４φ毘さ６１．５ ａｍの」］サイズ塩化チオニル・リ
チウム電池（Δ）と従来のセラミック製安全弁を設けた
１ｌｊｌ−形状の電池ｔｌＪｌを６２ＯＮずつ作１戊し
た時のｆイ油ｉｆｆのυ１１工費比１咬を第４図に、ケ
ースの下端に卯１モ用Ｓ Ｌｌ ８管を付は内子を加え
た時の安全弁の作剪ｔ−Ｅの比１咬を第５げに示す。こ
ノ１より明らかな如く覗池話の加工費は本発明に基く構
造の方式は従来のセラｊ ツクｉｆ、ｃ １Ｍ’ｉ曲格
（イ料費がこの分安価となり製品のコストダウ゛／に大
きく寄与することとなる。また安全弁の作動匡は各２Ｏ
Ｎ を破裂させた時の上、ト限範囲と平ｂｒ （ｎ’
ｊでホしたがその作動子、バラツキに大差はなく、ｌｉ
′＞同等のｆｑミ能を何するといえろ。Next, unfaithful 1fl! Using a battery lid with a shape based on example i1
I11 diameter 8 was created with E7 set to 25#/dG.
4 φ bis 61.5 am] size thionyl chloride lithium battery (Δ) and 1ljl-shaped battery tljl equipped with a conventional ceramic safety valve were manufactured in units of 62ON, and the construction cost was υ11. Figure 4 shows the ratio 1 stroke, and Figure 5 shows the ratio 1 stroke of the safety valve's operation when the Uchiko is added to the lower end of the case. As is clear from this 1, the processing cost of the Nozoike story is lower than that of the conventional structure method based on the present invention. The operating capacity of the safety valves is 2O each.
When N is ruptured, the upper limit range and flat br (n'
There was no big difference in the variation in the actuator, and li
'> What should we do with the equivalent fq mi function?
従って本発明に基く構造の肉４溝部構造の安全弁を１槓
えｔご…；池は従来品にくらべ同等の作動信頼性＆ （
−１ｆ ロと共に、その材料費は大１１に１１いんする
こととなる。Therefore, when using a safety valve with a four-groove structure based on the present invention, it has the same operational reliability and (
-1f Together with B, the material cost will be 11 in.
以上説明した如く、本発明に基く一部に肉薄溝部を用い
た電池蓋、又はケースを用いたＩＩＩ ７１１Ｊは安全
弁作動信頼性を変えることなく太１［」なコストタウン
かり能となり、その工碗的仙酉１′１−イしく入でｔ）
る。As explained above, the III 711J, which uses a battery cover or case that uses a thin groove in a part based on the present invention, can be cost-effective without changing the reliability of the safety valve operation. matosentori 1'1-i shukuiri de t)
Ru.
第１図は本ｙＩ色明に基づくスパイラル構造、４化チオ
ニル・リチウム電池の＠Ｉｒｙｉｌｉ向図。
第２図面図池蓋のｉＥ而面。第３図は同心因状肉薄部の
部分拡大：ＸＪ（面図。第４図は電池蓋の１１１１工費
叱較クラフ。第５図は安全弁作動Ｕト比軟りラフ。
１・・・・・・ケース、 ２・・・・・・ｉｔ
Ｌ ａ ｓｉｔ 。
８・・・・・・肉薄溝部、 ４・・・・・・リチウ
ム。
５・・・・・・ガラス不織布セパレーター。
６・・・・・・正１０巣’ｒ４ｎ １７＄、 １０
・・−・・止１萌ｙ１＾１子。
１１・・・・・・ガラス。
オ ４．凹
穴 ２ 目
第５図Figure 1 is a diagram of a lithium thionyl tetrachloride battery with a spiral structure based on the present YI color scheme. The second drawing is the iE face of the pond cover. Fig. 3 is a partial enlargement of the concentric thin wall part:・Case, 2...it
La sit. 8...Thin groove part, 4...Lithium. 5...Glass nonwoven fabric separator. 6... Positive 10 nest'r4n 17$, 10
...stop1moey1^1 child. 11...Glass. O 4. Recessed hole 2nd figure 5
Claims (1)
いたことを゛１寺？改とする塩化チオニル・リチウムｒ
ＩＩ池。How to make a straight curved part with a groove part: 1 or case IIJ
What happened to one temple? Lithium thionyl chloride
II Pond.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP57190229A JPS5979965A (en) | 1982-10-28 | 1982-10-28 | Thionyl chloride-lithium cell |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP57190229A JPS5979965A (en) | 1982-10-28 | 1982-10-28 | Thionyl chloride-lithium cell |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS5979965A true JPS5979965A (en) | 1984-05-09 |
Family
ID=16254630
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP57190229A Pending JPS5979965A (en) | 1982-10-28 | 1982-10-28 | Thionyl chloride-lithium cell |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5979965A (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2579833A1 (en) * | 1985-04-01 | 1986-10-03 | Accumulateurs Fixes | Ventilation device acting as valve, in particular for an electrochemical generator |
| JPS6297256A (en) * | 1985-09-30 | 1987-05-06 | エマ−ソン・エレクトリツク・カンパニ− | Manufacture of safe degassing of harmetic container cover and harmetic container cover |
| EP0266541A1 (en) * | 1986-09-27 | 1988-05-11 | Hitachi Maxell Ltd. | Explosion-proof arrangement for a non-aqueous electrochemical cell, and method for the production thereof |
| US4803136A (en) * | 1985-09-30 | 1989-02-07 | Emerson Electric Co. | Method of manufacturing a safety vented container and product |
| FR2627327A1 (en) * | 1988-02-17 | 1989-08-18 | Accumulateurs Fixes | Safety pressure release for battery casing - includes curved groove in base allowing release of pressure build up |
| US6180279B1 (en) | 1996-12-09 | 2001-01-30 | Optnics Precision Co., Ltd. | Method of manufacturing battery explosion prevention safety device |
| WO2012153675A1 (en) | 2011-05-09 | 2012-11-15 | 新日本製鐵株式会社 | Battery can for storage battery |
| US8852797B2 (en) * | 2004-09-22 | 2014-10-07 | Samsung Sdi Co., Ltd. | Lithium ion secondary battery with anti-rotation cap assembly |
-
1982
- 1982-10-28 JP JP57190229A patent/JPS5979965A/en active Pending
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2579833A1 (en) * | 1985-04-01 | 1986-10-03 | Accumulateurs Fixes | Ventilation device acting as valve, in particular for an electrochemical generator |
| JPS6297256A (en) * | 1985-09-30 | 1987-05-06 | エマ−ソン・エレクトリツク・カンパニ− | Manufacture of safe degassing of harmetic container cover and harmetic container cover |
| US4803136A (en) * | 1985-09-30 | 1989-02-07 | Emerson Electric Co. | Method of manufacturing a safety vented container and product |
| EP0266541A1 (en) * | 1986-09-27 | 1988-05-11 | Hitachi Maxell Ltd. | Explosion-proof arrangement for a non-aqueous electrochemical cell, and method for the production thereof |
| US4842965A (en) * | 1986-09-27 | 1989-06-27 | Hitachi Maxell, Ltd. | Non aqueous electrochemical battery with explosion proof arrangement and a method of the production thereof |
| FR2627327A1 (en) * | 1988-02-17 | 1989-08-18 | Accumulateurs Fixes | Safety pressure release for battery casing - includes curved groove in base allowing release of pressure build up |
| US6180279B1 (en) | 1996-12-09 | 2001-01-30 | Optnics Precision Co., Ltd. | Method of manufacturing battery explosion prevention safety device |
| US8852797B2 (en) * | 2004-09-22 | 2014-10-07 | Samsung Sdi Co., Ltd. | Lithium ion secondary battery with anti-rotation cap assembly |
| WO2012153675A1 (en) | 2011-05-09 | 2012-11-15 | 新日本製鐵株式会社 | Battery can for storage battery |
| JP5170352B2 (en) * | 2011-05-09 | 2013-03-27 | 新日鐵住金株式会社 | Battery can for secondary battery |
| US8828569B2 (en) | 2011-05-09 | 2014-09-09 | Nippon Steel & Sumitomo Metal Corporation | Battery can for storage battery |
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