JPS5921789A - Colored fiber rope - Google Patents

Colored fiber rope

Info

Publication number
JPS5921789A
JPS5921789A JP13099882A JP13099882A JPS5921789A JP S5921789 A JPS5921789 A JP S5921789A JP 13099882 A JP13099882 A JP 13099882A JP 13099882 A JP13099882 A JP 13099882A JP S5921789 A JPS5921789 A JP S5921789A
Authority
JP
Japan
Prior art keywords
colored
resins
rope
flame
resistant
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP13099882A
Other languages
Japanese (ja)
Inventor
伊藤 正延
片ノ坂 明郷
興一 伊藤
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Teijin Ltd
Original Assignee
Toho Rayon Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toho Rayon Co Ltd filed Critical Toho Rayon Co Ltd
Priority to JP13099882A priority Critical patent/JPS5921789A/en
Publication of JPS5921789A publication Critical patent/JPS5921789A/en
Pending legal-status Critical Current

Links

Landscapes

  • Decoration Of Textiles (AREA)
  • Emergency Lowering Means (AREA)
  • Ropes Or Cables (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)

Abstract

(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。
(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.

Description

【発明の詳細な説明】 本発明は彩度の高い着色繊維ローブに関づる。[Detailed description of the invention] The present invention relates to highly saturated colored fiber robes.

耐炎m維又は(及び)炭素繊維からなるローブは不燃性
で耐熱強度も高く、しかも軽量で取扱いが容易であるこ
とから、特に火災時の避II用ロープ又は消火活動時の
命づなとして適している。しかし、耐炎繊維、炭素繊維
は木質的に黒色であるため、特に夜間の使用にd3いて
ローブの目視確認が困難であり支障をきたづ。
Robes made of flame-resistant m-fiber or (and) carbon fiber are nonflammable and have high heat-resistant strength, as well as being lightweight and easy to handle, making them particularly suitable as evacuation ropes during fires or as a lifeline during firefighting activities. There is. However, since flame-resistant fibers and carbon fibers are black in wood, it is difficult to visually check the robes, especially when used at night, which poses a problem.

本発明者らは、目視確認の容易な着色繊組「1−プにつ
いて検討した結果、耐炎繊維又はく及び)炭素繊維から
作られたローブを通常の塗料で着色すると、着色材が容
易に内部に浸透してローブ表面を有効に着色することが
困帥であること、しかし−、44μ以上の粒径が比較的
太で、かつ反射光を与える着色材を含む塗装材で]」−
プを着色すると、彩度の高い表面着色が達成でき使用時
の目視確認が極めて容易であること、しかもこの場合ロ
ープは着色材の内部浸透がなく本来の柔軟性を保持して
いることを見出し、本発明に至った。
As a result of studying colored fibers that are easy to visually check, the inventors found that when a robe made of flame-resistant fiber or carbon fiber is colored with ordinary paint, the coloring material can easily be absorbed inside the robe. However, it is difficult to effectively color the surface of the lobes by penetrating the surface of the lobes.
It was discovered that by coloring the rope, highly saturated surface coloring can be achieved and visual confirmation during use is extremely easy, and in this case, the rope retains its original flexibility without the colorant penetrating inside. , led to the present invention.

4なわち、本発明は、耐炎繊維又は(及び)炭素繊維か
らなるロープの表面に粒径44μ以上の反射光着色材を
含む塗装材を塗布してなる彩度の高い着色繊維ロープで
ある。
4. That is, the present invention is a colored fiber rope with high chroma, which is obtained by coating the surface of a rope made of flame-resistant fibers and/or carbon fibers with a coating material containing a reflective coloring material with a particle size of 44 μm or more.

本発明の着色繊維ローブは、鮮明に着色され彩度が高く
、使用時の目視確認が容易であり、しかも不燃、耐熱、
軽量の特性を兼ね備えており、非常用ロープとして極め
て有用なものである。
The colored fiber robe of the present invention is vividly colored and has high saturation, and is easy to visually check when in use, and is nonflammable, heat resistant, and
It has the characteristics of being lightweight, making it extremely useful as an emergency rope.

本発明のロープは耐炎繊維又は(及び)炭素繊維からな
るものである。耐炎繊維はセルロース繊維、フェノール
ノボラック系繊維、アクリロ二1−リル系繊維等を酸化
性雰囲気巾約200〜300℃で熱処理したものである
The rope of the present invention is made of flame-resistant fibers and/or carbon fibers. The flame-resistant fibers are those obtained by heat-treating cellulose fibers, phenol novolak fibers, acryloni-l-lyl fibers, etc. in an oxidizing atmosphere at about 200 to 300°C.

炭素繊維はこの耐炎繊維を不活性ガス雰囲気巾約600
〜1500℃で熱処理して得られるものである。炭素繊
維には、前記の炭素繊維を更に高温焼成して得られる黒
ε))繊維も包含される。本発明においては特にノノク
リロニI〜リル系繊維を原料とするものが好適である。
Carbon fiber is made of flame-resistant fiber in an inert gas atmosphere of about 600 ml.
It is obtained by heat treatment at ~1500°C. The carbon fibers also include black ε)) fibers obtained by firing the above-mentioned carbon fibers at a higher temperature. In the present invention, those made from nonocryloni I to lylu type fibers are particularly suitable.

本発明のロープは、例えば耐炎繊維又は炭素#1i紺の
紡績糸、フィラメント、あるいは、耐炎$1i維と炭素
繊維の混紡糸、更に耐炎繊維又は炭素繊維と伯の耐熱繊
維との混紡糸、合撚糸から作られたものである。そして
、これらを混用して作られたものでもよい。本発明のロ
ープは形態に制限がなく、目的の太さ、強さ等に応じて
合糸製造して任意の形態にすることができる。
The rope of the present invention may be made of, for example, flame-resistant fibers or carbon #1i navy blue spun yarn, filaments, flame-resistant $1i fibers and carbon fiber blended yarns, flame-resistant fibers or carbon fibers, and black heat-resistant fibers blended or composite yarns. It is made from twisted yarn. A product made by using a mixture of these may also be used. The rope of the present invention is not limited in shape, and can be made into any shape by doubling according to the desired thickness, strength, etc.

本発明の耐炎繊維又は(及び)炭素繊維からなるロープ
の表面に塗布り−る反則光着色材は、粒径44μ以上の
ものである。44μより微細になると着色材が耐炎繊維
等からなる糸の組織(編目)を通過してロープの内部に
浸透し、このため有効な表面着色が達成できず、また【
コープの柔軟性がそこなわれる。
The anti-fouling colorant applied to the surface of the rope made of flame-resistant fibers and/or carbon fibers of the present invention has a particle size of 44 microns or more. If the coloring material is finer than 44μ, the coloring material will pass through the structure (knits) of the thread made of flame-resistant fibers and penetrate into the rope, making it impossible to achieve effective surface coloring.
Co-op flexibility is impaired.

着色材は反射光を与えるものでな()ればならない。か
かるものとしては、アルミ蒸着フィルムの粉砕化物やア
ルミ蒸着フィルム上に透明着色保護コートを施したもの
の粉砕化物が挙げられ、前者はロープ面に鮮かなシルバ
ー色を付与し、また、後右はロープ面に所望の@色でメ
タリックな鮮かな色彩を与える。
The colorant must provide reflected light. Such materials include pulverized products of aluminum vapor-deposited film and pulverized products of aluminum vapor-deposited film coated with a transparent colored protective coating.The former gives a bright silver color to the rope surface, and the back right Gives a bright metallic color to the surface with the desired @ color.

これら2種の粉砕化物は単独又は混合して使用す゛るこ
とができる。更に、反射用ガラスピーズをこれらに混入
してもよく、この場合には反射光を一層強めることがで
きる。このほか、着色バインダー(極微粒子の有機顔料
を樹脂中に含lυだもの)をアルミ蒸着粉砕化物とイタ
1用すると着色メタリックの良好な彩色を得ることがで
きる。
These two types of pulverized products can be used alone or in combination. Furthermore, reflective glass beads may be mixed into these, and in this case, the reflected light can be further strengthened. In addition, good colored metallic coloring can be obtained by using a colored binder (a resin containing ultrafine organic pigment particles) with the aluminum vapor-deposited and pulverized product.

塗装材には、着色材をロープ表面に固定4るためバイン
ダーとして樹脂が含まれており、樹脂としてはロープの
特性をそこなわないため柔軟性のあるものが選ばれ、ま
た耐熱性の優れたものが使用される。具体的には、シリ
コン樹脂、ゴム系樹脂、アクリル系樹脂、ウレタン系樹
脂、テフロン系樹脂の群から選ばれた1種又は2種以上
が使用される。塗装材にお゛いて前ム【1樹脂(固形)
に対し着色材を1〜50重川%分用させたものを塗布す
ると、本発明のロープに彩度の高い鮮かな反射光をもつ
着色を与えることができる。ガラスピーズを4jf用す
る場合には、着色材とガラスピーズを合算して樹脂に対
し1〜60重量%混入すると反射光を一層強めることが
できる。塗装材には、所望により添加物例えばレベリン
グ剤、他の顔料等を加えてもよい。
The coating material contains a resin as a binder to fix the coloring material to the rope surface, and the resin is selected from a flexible material so as not to damage the rope's properties, and a material with excellent heat resistance. things are used. Specifically, one or more selected from the group of silicone resins, rubber resins, acrylic resins, urethane resins, and Teflon resins are used. The first resin (solid) is used as a coating material.
When a colorant is applied in an amount of 1 to 50% to the rope of the present invention, the rope of the present invention can be colored with highly saturated and vivid reflected light. When glass beads are used for 4JF, reflected light can be further strengthened by mixing the colorant and glass beads in a total amount of 1 to 60% by weight based on the resin. If desired, additives such as leveling agents, other pigments, etc. may be added to the coating material.

本発明において塗布の方法には制限はなく、通常の方法
で塗装材をロープ上に塗イl1−L、常温放置又は加熱
焼付により乾燥、硬化を行う。ガラスピーズは塗装材に
含ま゛せて塗布により0−プ表面に付与するのが普通で
あるが、塗イ11の後にガラスピーズを散布し固着さけ
てもよい。本発明の着色繊維ローブを作る際には、所望
により更に塗料を上塗りする仁とにより彩度を高めると
ともに着色材を一層強く固着させることができる。
In the present invention, there are no restrictions on the method of application, and the coating material is applied onto the rope in a conventional manner, and is dried and hardened by leaving it at room temperature or baking with heat. The glass beads are usually incorporated into a coating material and applied to the surface of the coating by coating, but the glass beads may also be scattered after coating 11 to avoid sticking. When making the colored fiber robe of the present invention, it is possible to further increase the color saturation and make the coloring agent adhere more strongly by further applying a layer of paint if desired.

以下、本発明を実施例によって説明丈る。The present invention will be explained below with reference to Examples.

実施例1 下記組成の配合物を高速で攪拌し分散液を作つ Iこ 
Example 1 A dispersion liquid was prepared by stirring the following composition at high speed.
.

エルジ−シルバー#150 この分散液にハードナー(硬化や触媒>Yca1編糸か
らなるロープの上へ、スプレーガン(口1! 1.2m
mΦ)  3.0kg/ Cm’の圧力で20cmの距
離からエアスプレー塗布した。次いで10分風乾したの
も150℃、20分焼付を行い製品を得た。製品はシル
バー色の鮮明な彩度の高い着色炭素繊組ロープであった
Elgi Silver #150 Spray this dispersion liquid onto a rope made of hardener (hardening and catalyst > Yca1 knitting yarn) using a spray gun (mouth 1! 1.2m).
mΦ) Air spray coating was applied from a distance of 20 cm at a pressure of 3.0 kg/cm'. Next, the product was air-dried for 10 minutes and then baked at 150° C. for 20 minutes to obtain a product. The product was a highly saturated colored carbon fiber braided rope with a vivid silver color.

上記配合物中(b )のエルジ−シルバー# 150を
エルジ−シルバー#200(粒径74μ)(こ代えたば
かは上記と同様にしC@色炭素繊維II −ブを得た。
Elgie Silver #200 (particle size: 74 μm) (particle size: 74 μm) was substituted for Elgee Silver #150 in the above formulation (b). C@ color carbon fiber II-b was obtained in the same manner as above.

このものも高い鮮明な彩度を示した。This one also showed high vivid color saturation.

実施例2゜ 前記実施例1と同様にして着色炭素繊1f、 +::+
 −ブを作った。このロープを下記組成の配合物で一1
ニ づト リ し 1こ 。
Example 2゜ Colored carbon fiber 1f in the same manner as in Example 1, +::+
-I made a book. This rope was mixed with a compound of the following composition.
1 piece.

シリコン樹脂−r S R1122100重量部レベリ
ング剤BYKE王OL3  5型開部キシレン    
      ioo重串部10分風乾したのも 150
°Cl2O分焼イ]を行って製品を得た。このロープは
表面に着色材が充分に固着し彩度も高いものであつ/j
 0 実施例3゜ 下記の材料を準備した。
Silicone resin-r S R1122100 parts by weight Leveling agent BYKE King OL3 5 type opening xylene
ioo heavy skewer part air-dried for 10 minutes 150
A product was obtained by calcining in °C12O. The coloring material of this rope is sufficiently adhered to the surface and the color saturation is high.
0 Example 3゜The following materials were prepared.

1ルジーシルバー#150 」ニ記材旧(a)、(c )及び([)をあらかじめ混
合し、混合物を3本ロールに/)I Cjて充分に分散
さけた。次いで、他の月1’il全部を加えて混合物を
攪拌混合した。得られた塗装材を炭素繊維編糸からなる
ローブ上に塗布し10分風乾後、150℃、20分焼付
を行って製品を得た。1りられ1、:@色炭素械維「J
−ブは、黄色の表面で反射光@色材とガラスピーズが光
反射し高度に鮮明な着色を示した。
The materials (a), (c) and ([) were mixed in advance and the mixture was rolled into three rolls to ensure thorough dispersion. Then, the other 1'il was added and the mixture was stirred to mix. The obtained coating material was applied onto a lobe made of carbon fiber knitted yarn, air-dried for 10 minutes, and then baked at 150° C. for 20 minutes to obtain a product. 1 Rirare 1: @ color carbon machine fiber “J
-B showed highly vivid coloring due to the reflected light on the yellow surface of the coloring material and the glass beads.

実施例4 前記実施例3において炭素繊N編糸からな−るU−プに
代えて耐炎繊維編糸からなるロープを用いたほかは実施
例3と同様にして酒色耐炎キ観維ローブを得た。このも
のも黄色の表面で厄介1光着色材による反射光に更にカ
ラスピース【こよる反射光が加わり高い彩度の着色を示
し1.:、。
Example 4 A liquor-colored flame-resistant fiber robe was obtained in the same manner as in Example 3, except that a rope made of flame-resistant fiber knitted yarn was used in place of the U-loop made of carbon fiber N knitted yarn in Example 3. Ta. This one also has a yellow surface, and in addition to the reflected light from the troublesome 1-light coloring material, the reflected light from the crow piece also adds to the coloring with high saturation.1. :,.

比較例 前記実施例1においてエルジーシルl\−のイ(りに、
顔料ファストイエo−3RN(粒を子0.05μ〉、ル
チル型酸化チタン(粒径0.5μ)、アルミペースト(
粒径40μ)をそれぞれ使用し/JIIかは実施例1と
同様にして1」−ブを4’1 /こ。
Comparative Example In Example 1, L.G.
Pigment Fast Ye o-3RN (particle size 0.05μ), rutile type titanium oxide (particle size 0.5μ), aluminum paste (
Particle size: 40μ) was used, and JII and JII were prepared in the same manner as in Example 1.

いずれの場合も、1呼られた[1−ブは着色材1fi 
I)4部に浸透して表面゛に(=J ’i!IせずIi
l′i期のれ色目−ブを得ることができなかった。
In either case, 1 called [1-bu is the colorant 1fi
I) Penetrates into the 4th part and reaches the surface (=J 'i!I without Ii
It was not possible to obtain a clear color during the l'i period.

【図面の簡単な説明】[Brief explanation of drawings]

第1図は実施例1で得られにロープブの外観図、第2図
は実施例3で得られたロープの外観図である。 1:ロープ、2二反制光着色刊
FIG. 1 is an external view of the rope obtained in Example 1, and FIG. 2 is an external view of the rope obtained in Example 3. 1: Rope, 2 anti-light coloring publication

Claims (3)

【特許請求の範囲】[Claims] (1)耐炎11i軸又は(及び)炭素1iftからなる
ローブの表面に粒t¥44μ以上の反射光着色材を含む
塗装材を塗布してなる彩度の高い着色繊維ロープ。
(1) A highly saturated colored fiber rope made by coating the surface of a flame-resistant 11i shaft or (and) a lobe made of carbon 1ift with a coating material containing a reflective coloring material with a grain size of ¥44μ or more.
(2)反射光着色材が、アルミ蒸着フィルムの粉咋化物
又はく及び)アルミ蒸着フィルム上に透明着色保護コー
トを施したものの粉砕化物であるか、あるいは、これら
の単独物又は混合物に反射用ガラスピース゛を混入した
ものである特許請求の範囲(1)の着色m刺自」−プ。
(2) The reflective light coloring material is a pulverized product of an aluminum vapor-deposited film or a pulverized product of a transparent colored protective coat applied on an aluminum vapor-deposited film, or a reflective coloring material is used alone or in a mixture thereof. The colored embroidery plate according to claim (1), which contains a glass piece.
(3)塗装材が、バインダーとして柔軟性あるシリコン
樹脂、ゴム系樹脂、アクリル系樹脂、ウレタン樹脂、テ
フロン系樹脂の群から選ばれた1種又は2種以上を含ん
だものである特許請求の範囲(1)の着色繊維ローブ。
(3) A patent claim in which the coating material contains one or more binders selected from the group of flexible silicone resins, rubber resins, acrylic resins, urethane resins, and Teflon resins. Colored fiber robe of range (1).
JP13099882A 1982-07-27 1982-07-27 Colored fiber rope Pending JPS5921789A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP13099882A JPS5921789A (en) 1982-07-27 1982-07-27 Colored fiber rope

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP13099882A JPS5921789A (en) 1982-07-27 1982-07-27 Colored fiber rope

Publications (1)

Publication Number Publication Date
JPS5921789A true JPS5921789A (en) 1984-02-03

Family

ID=15047545

Family Applications (1)

Application Number Title Priority Date Filing Date
JP13099882A Pending JPS5921789A (en) 1982-07-27 1982-07-27 Colored fiber rope

Country Status (1)

Country Link
JP (1) JPS5921789A (en)

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS4118127Y1 (en) * 1964-09-02 1966-08-23
JPS4969954A (en) * 1972-11-13 1974-07-06
JPS4976395A (en) * 1972-10-04 1974-07-23
JPS5118250A (en) * 1974-08-06 1976-02-13 Nippon Steel Corp ATSUENKI
JPS5658677A (en) * 1980-10-07 1981-05-21 Seiko Instr & Electronics Ltd Dial plate applied metallic powder paint

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS4118127Y1 (en) * 1964-09-02 1966-08-23
JPS4976395A (en) * 1972-10-04 1974-07-23
JPS4969954A (en) * 1972-11-13 1974-07-06
JPS5118250A (en) * 1974-08-06 1976-02-13 Nippon Steel Corp ATSUENKI
JPS5658677A (en) * 1980-10-07 1981-05-21 Seiko Instr & Electronics Ltd Dial plate applied metallic powder paint

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