JPS59212846A - Electrophotographic transfer paper - Google Patents
Electrophotographic transfer paperInfo
- Publication number
- JPS59212846A JPS59212846A JP8583183A JP8583183A JPS59212846A JP S59212846 A JPS59212846 A JP S59212846A JP 8583183 A JP8583183 A JP 8583183A JP 8583183 A JP8583183 A JP 8583183A JP S59212846 A JPS59212846 A JP S59212846A
- Authority
- JP
- Japan
- Prior art keywords
- paper
- transfer paper
- transfer
- styrene
- copolymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G7/00—Selection of materials for use in image-receiving members, i.e. for reversal by physical contact; Manufacture thereof
- G03G7/0006—Cover layers for image-receiving members; Strippable coversheets
- G03G7/002—Organic components thereof
- G03G7/0026—Organic components thereof being macromolecular
- G03G7/004—Organic components thereof being macromolecular obtained by reactions only involving carbon-to-carbon unsaturated bonds
Landscapes
- Physics & Mathematics (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Spectroscopy & Molecular Physics (AREA)
- General Physics & Mathematics (AREA)
- Paper (AREA)
Abstract
Description
【発明の詳細な説明】
〔発明の利用分野〕
本発明ｎ、」ｄ子写は／ｆ＆光体も−しくは静゛屯０１
録体上に形成さｔしたトナー像が鴨写さｔ′シ、そり転
写さτ［だトナー１球−ｆ：熱又に１、圧力により定肩
せしめることが出来る電子写真用転写紙に関する。[Detailed Description of the Invention] [Field of Application of the Invention] The present invention is based on the n, d copy, /f & light body, or still unit 01
This invention relates to an electrophotographic transfer paper in which a toner image formed on a recording medium can be transferred to a fixed position by heat or pressure.
〔）１蓉」の背却〕
匝米よシ、トナーの転写紙としては、紙支持体上にゴム
示うテックスケ塗布したもの、またゴム糸ラテックスに
顔料を加えて塗δｔしたものが知られている。これらの
転写紙の六回）曽にゴム系ラテックスが使用されている
ことから定着性に優扛ている。しかし、これらの転写紙
ではゴム系ラテックスの有する粘漸性のために転写紙同
志のブロンキングが起シ易く、形成された塗１換の光沢
が強いため晋ＪＪＩｉ凪の感触が得られず、さらに鉛筆
による筆記性、インク筆記性も恋いなどυ欠点に’ＭＬ
、ている。[) 1 蓉” Rejection] As toner transfer paper, there are two known types of toner transfer paper: those coated with rubber on a paper support, and those coated with pigments added to rubber thread latex. ing. Since rubber-based latex is used in the layer of these transfer papers, they have excellent fixing properties. However, with these transfer papers, due to the viscosity of the rubber-based latex, bronzing between the transfer papers tends to occur, and the gloss of the first coat formed is strong, making it impossible to obtain a calm feel. Furthermore, there are υ drawbacks such as poor writing performance with pencil and ink.
,ing.
本発明の目的は、便米の欠点がなく、特に定着性に優れ
、ペーパーライク性及び筆記性、さらには尚湿時の転写
性にも優ｆＬ、答易に製造出来る゛東子写四用転写紙ゲ
提供することにある。The purpose of the present invention is to provide a transfer for Toko Shashi 4 that does not have the drawbacks of regular rice, has excellent fixing properties, has excellent paper-like properties and writing properties, and is also excellent in transfer properties even when wet, and can be easily produced. The goal is to provide paper games.
本発明ｃノミ子写闘用転写紙は、紙支持体の片方（１）
曲にスチレンとアクリル酸及び（又は）メタクリル酸と
メタクリル１波アルキルエステル（但シ、アルキル基は
炭素数ｌ〜１２の直鎖又は分岐鎖アルキル基である。）
の共垂酋体を用いて塗布し転写層？形成せしめてなるこ
とケ特徴とするものである。The transfer paper for Nomiko photography of the present invention has one side (1) of the paper support.
Styrene and acrylic acid and/or methacrylic acid and methacrylic single wave alkyl ester (However, the alkyl group is a straight or branched alkyl group having 1 to 12 carbon atoms.)
Is the transfer layer applied using a synergist? It is characterized by the fact that it is formed.
本発明勿さらｌこ詳細に脱明すると、不発明転写紙は紙
の一方の面に時短の樹脂ケ主成分とする塗散伊ｆｒ布乾
煉して獣写層が形成されたものである。To clarify the details of the present invention, the uninvented transfer paper is one in which an animal copying layer is formed on one side of the paper by coating and drying a cloth containing a time-saving resin as the main component. .
この→ｉ’Ｍ（ｌ）樹脂とは、前述のとおりスチレン（
ＡｈＪ、分）と、アクリルば及び（又は）メタクリル酸
（Ｂｌ戊分ンと、ツタクリル扉アルキルエステル（Ｃｌ
戎分ンとから（祷Ｉズさ往でおり、とｆＬらの共重合体
は約１００００〜１２υυＱ０９＞分子にヶ有するもの
てあ一す、これらの１４ト駐体は通常用いられる浴液重
合、懸濁重置及び乳１ヒ市合寺の手段で共重合させろこ
とに工シイｑらｆＬる。これらの共重合体は、へ成分Ｊ
ｆ：２０〜６０モルチ、Ｂ成分ケ５〜２０モル％、ぞし
てＣｒｆ：分ケ２０〜７５モルチの・氾し召で才４・Ｊ
するものである。Δ成分か５モル係以下であめと軟かく
なり１湿性が悪くなる。６０モルチ以上ＶＣなるとイ便
いｊ俣′／′Ｃなりもろくなる。Ｂ成分か５モル％以−
トであると、軟かくなり、筆記性か恋くなる。２０モル
係以上ではｉ４３１漠がもろくなる。さ１、）ンこＣ成
分が２０モル饅以下であれ（・ｆ２かなり硬い甲ｆｆｉ
１１一本が得られ、室ｊ１檗かもろく７２：め。７５七
ル係以上であると軟か過ぎて声ｊい硬膜が４４４られな
くなり、６らＶＣＣ温湿の転写１４トが悪くなる。この
重合体の分子祈は重眞平均分子社で１００００〜１２０
０００が適当である。１００００ 以下では堂肛強度
が弱くなりブロッキングが生じ、１２００００以上にな
ると定着性が劣る。しかしながら、不発明転写紙は紙の
一方に上記α〕樹脂ｒ塗１１ｊして倚しれるものである
が、さらにペーパーライク性ケ出すために、平均粒径０
．５〜３μｍの如料ｒ混会する。ここでの無蘭顔料とし
ては、炭駁カルシウム、数比亜鉛酸化チタン、シリカ、
メルク、クレー、硫畝バソクムなどがあげらｔ″Ｌる。As mentioned above, this →i'M(l) resin is styrene (
AhJ, min), acrylic and/or methacrylic acid (Bl), ivy alkyl ester (Cl
The copolymer of FL et al. has a molecular weight of about 10,000 to 12υυQ09. The copolymerization was carried out by means of suspension superimposition and lactation.These copolymers were prepared by adding component J to
f: 20 to 60 mol%, B component 5 to 20 mol%, and Crf: 20 to 75 mol%, 4 J
It is something to do. If the Δ component is less than 5 molar ratio, it will become amber and soft, and its wettability will deteriorate. If the VC is more than 60 molti, it becomes brittle. 5 mol% or more of component B
If it is soft, it will be soft and the writing quality will be poor. Above 20 moles, i431 becomes brittle. 1,) If the Nko C component is less than 20 moles (・f2 is quite hard)
11 one book was obtained, and the room was 72: me. If it is above 75%, it will be too soft and the dura mater will not be able to be transferred properly, and the transfer of VCC temperature and humidity will be poor. The molecular weight of this polymer is 10,000 to 120 at Shigeshin Keizai Shonensha.
000 is appropriate. If it is less than 10,000, the hole strength becomes weak and blocking occurs, and if it is more than 120,000, the fixing property is poor. However, the non-inventive transfer paper is coated with the above-mentioned [alpha] resin r on one side of the paper, but in order to obtain a paper-like property, it is coated with an average particle size of 0.
．． Mix 5 to 3 μm of material. The non-random pigments used here include calcium charcoal, zinc titanium oxide, silica,
Examples include Merck, Klee, and Sulfur Bathokum.
槌科等の１光合験に、顔料／樹脂二０． ５〜１．５／
ｌ（飛Ｉｆｔ比）が適へｊて′ある。こうした転写ｌ曽
忙形，ト戊ｆるために塗液（ｌｒ乾燥後塗亜量は２〜ｌ
（Ｊｇ／ｒｒｌ′である。紙の両口１１に塗布してもよ
い。塗布方法としては公＞、−１１のエアーブーイフコ
ーティング、ワイヤバーコーティング、ロントコ−ティ
ングなど〃朝Ｊいら（Ｌる。こ（１．ｒ（−うｆニして
作らｔした転写紙ｒノＩＪいて１１シ坤画像紫・１寄る
定☆プロセスは、りｑえば特公昭４Ｇ−１５８７６＋５
公１服にもｄ己１成されておシ、それ自体〕出常（１）
ものであゐ。又、ギ元明（／−ｒ Ｑ広写紙に用いられ
ろトナーとしでは、辿゛吊、熱定右や圧力定地に用い６
ｔｔているトナーが適用できる。かかる本発明の・１ム
写紙Ｐｉ懐めて蛤−えしいものである。Ｔ′なわち、こ
Ｃ／Ｊ帖写俄汀、矩層注も従来の電子３九に比べてハｅ
凍（１」竹−でりシ、ての他はすべての点で侵っている
。レリえは形成さｔ“した粂１戻の衣ｍＩは細かなアン
カ／／ＪＪ米（凸凹）Ｖ−なっており、定オ〕性及びペ
ーパライク性及び５団占ａ １ａｔが良好で必ろ。また
ゴム系うｆンクスのものよりも硬い塗膜であシ、鉛筆１
／Ｃよろ；、ｒｌｌに１′１ミか同上している。さらＹ
ＣＣ温湿良好な共１涯Ｍ Ｋ ｉ口も゛しいたりて、υ
Ｅ米尚湿時に極端ＶＣ黴写ｉ′：＋：が洛ちめ火照も１
２良さｔした。こ／″Ｌは、湿屁に肘して、（・まとん
ど形成塗膜り屯気抵抗がドがらないためと力えもｔし心
。Pigment/resin 20. 5-1.5/
l (flying Ift ratio) is suitable. In order to remove these transfer patterns, the coating liquid (lr coating weight after drying is 2 to 1 l)
(Jg/rrl'. It may be coated on both sides 11 of the paper. Application methods include public>, -11 airbuoy coating, wire bar coating, and front coating. .This (1.r(-Ufni) was made with transfer paper r no IJ and 11 pieces of image purple, 1 layered ☆ process, if requested, special public show 4G-15876+5
Even in public affairs, oneself is created, itself] appearance (1)
It's something. In addition, as a toner used for Q wide paper, it is also used for hanging, heat setting, and pressure setting.
tt toner can be applied. The 1-mm photo paper Pi of the present invention is very appealing. T', that is, this C/J chapter copy, rectangular layer note is also more expensive than the conventional electron 39.
Frozen (1) Bamboo - Derishi, and all other points are damaged. The reel is formed and the kiln 1 is returned to the clothes with fine anchors//JJ rice (uneven) V- It must have good constant strength, paper-like properties, and 5-group a 1at.Also, it has a hard coating film than that of rubber-based adhesives, and the pencil 1
/C wobble;, rll is 1'1 mi or same as above. Sara Y
CC has good temperature and humidity for one year.
When E rice is humid, extreme VC mold copy i′:+: is Rakuchime hotsho is also 1
It was 2 good. This/"L, elbowed his elbow in the wet fart (・I tried not to force it because the coating film formed in the middle of the day did not reduce the air resistance.
〔発明（／Ｊ＊弛し１」〕 次に実軸り１」及び比較例ｒ示す。[Invention (/J*Relaxation 1”) Next, real axis 1'' and comparative example r are shown.
笑祖列 １
スチレン：メタクリルｉ我： １１−プチルアクリレ−
トコ４０：１０：５０のモル％て共Ｍ付さぞ罠。Smiling family 1 Styrene: Methacrylic: 11-butyl acrylate
The mole percentage of 40:10:50 is a trap with M included.
共重合体 ｉｏｏｇ
−塩１眞炭酸カルシウム ２０ｇｔ４０寂倉％ト
ルエ浴液に祠節し、この浴液は、塗工４：が約３ｇ／ｍ
２になるよう′Ｌ塗布し乾燥して転写紙ケ製造した。−
万有機７１＆光体又は無（涜感光不忙コロナチャージャ
ーで荷由比画稼１４光後、低注−１戊分トナーで磁気ブ
ラシ決球した。次いで、コロナチャージ転写法で／ｆＮ
，光体のトナ−画像４転写紙に転写させ定地δせた。Copolymer ioog - Salt 1 Calcium carbonate 20gt40 Jakukura% Torue bath liquid, this bath liquid has coating 4: about 3g/m
2'L was coated and dried to produce a transfer paper. −
After 14 rays of light using a corona charger, I applied a magnetic brush to a low injection-1 toner. Next, I used a corona charge transfer method to /fN
, the toner image 4 of the light body was transferred to the transfer paper and the fixed position δ was set.
日ギスクリーンの反射炭＃肘で画１原ｒ測ボしたところ
１．５であった。この部分ケ市販の３Ｍ製のスコンチテ
ープで剥離テストヶし定）、ｊ性忙御］定し／こところ
８０％であった。父、ペーパライク性及びＷｌｉ４ｅ性
、プロンキングも無かった。次ＹＣ２５ｃ。When I measured the radiance of each image using the reflective charcoal #elbow of a Japanese screen, it was 1.5. A peel test of this part was carried out using commercially available 3M Sconti tape, and the result was 80%. My father had no paper-like or Wli4e characteristics, and no pronking. Next YC25c.
８５慢Ｒ）（の雰囲気で上記の方法で転写紙に画像？形
成したところ、画像鍮度１．２と高惺栄件にもかかわら
す．￥娘、ば倉示した。When an image was formed on the transfer paper using the above method in an atmosphere of 85 R), the image brassiness was 1.2 and despite the high quality.
実施例
スチレン゛アクリルば二メタクリル飯アルキルエステル
＝３０：２０＋５０モル嘱で共重合烙せた。Example: Copolymerization of styrene, acrylic, dimethacrylic, and alkyl esters was carried out in a ratio of 30:20+50 moles.
共重合体 ＩＵＯｇ
クレー ２０ｇ
ｆ ４ Ｕ ’ｒＪ（ｉｑ、ｊ ％ ｌ’ルエン：Ｉｖ
Ｅ Ｋ （メチルエチルケトン５０１５０ ）浴液に
読Ｙ拍した。この溶液は実施例１と同僚にして転写紙ｒ
製造し定盾性を測定したところ７０チであった。又ペー
パーライク性、−〇ｄじ性、ブロッキングも無かった。Copolymer IUOg Clay 20g f 4 U 'rJ (iq, j % l' Luene: Iv
E K (methyl ethyl ketone 50150) was added to the bath solution. This solution was applied to the transfer paper r as in Example 1.
When manufactured and measured for constant shielding property, it was 70 degrees. Also, there was no paper-like property, -〇d-like property, or blocking.
次に２５Ｃ１８５％凡Ｈの雰囲気で実施例１と同様に画
像ｒ出したところ画像浜度は１．２であった。Next, an image was taken out in the same manner as in Example 1 in an atmosphere of 25C185% H, and the image hardness was 1.2.
実施例
スチレン：アクリルｃｍ：ｎ−ブチルアクリレート＝４
０：１５ニア５モル係で共重合させた。Example styrene: acrylic cm: n-butyl acrylate = 4
Copolymerization was carried out at a ratio of 0:15 to 5 moles.
共重合体 ｉｏｏｇ
炭酸カルシウム ２０ｇ
ｐ ４０ 項ｌ；、’（、’ｊ°％Ｃノトルエン’ＭＥ
Ｋ＠液に調節した。Copolymer ioog Calcium carbonate 20g p 40 term l;,'(,'j°%C-notluene'ME
Adjusted to K@ solution.
このＭ液は実施例１と同様にして転写紙ｒ製造し実施例
１と同様に軍者性τ測矩したところ８０−であった。又
ペーパーライク性、筆記性、グロンキングも無かった。This M liquid was prepared as a transfer paper in the same manner as in Example 1, and measured for military strength τ in the same manner as in Example 1, and found to be 80-. Also, there was no paper-like property, no writability, and no grongking.
又２５ｃ、８５ＳＲ，Ｈの雰囲気で夾姻ｙＮｌと同様に
画像ｒ出したところ画像開度は１．２であった。In addition, when an image r was taken out in the atmosphere of 25c, 85SR, and H in the same manner as for the concomitant YNl, the image opening was 1.2.
冥Ｍ！１例 ４
スチレン：アクリルは：ｎ−ブチルアクリレ−）＝４（
１１０： ５０モル褒で共電台させた。Mei M! 1 Example 4 Styrene: Acrylic: n-butyl acrylate) = 4 (
110: I got a power station for 50 moles.
共重合体 １００ｇ
炭酸カルシウム ３０ｇ
？４０歌１、ｉ：係トルエン：Δ４ ’Ｅ ｉ（溶液に
調節した。Copolymer 100g Calcium carbonate 30g? 40 Song 1, i: Toluene: Δ4'E i (adjusted to solution.
この６液は実施例１と―Ｊ様にして転写紙ケ製造し定渚
性勿ｄ１（］定したところ７５襲であった。又、ペーパ
ーライク性、筆記性、ブロッキング性も無かった。次Ｖ
Ｃ２５Ｃ，８５％Ｒ，Ｈの８囲気で実施例１と同様１／
（画像ｒ田したところ（υ〕１像峡度は１．３であった
。These 6 liquids were made into transfer paper in the same manner as in Example 1 and -J, and the stability of the paper was determined to be 75%.Also, there was no paper-like property, no writing property, and no blocking property.Next V
Same as Example 1 in 8 atmospheres of C25C, 85% R, H.
(When I looked at the image (υ), the 1-image isthmus was 1.3.
比Ｃ咬例 １
ＳＢＲ（スチレンブタジェンツバ−） ｉｏｏｇ炭
レカルしウム ４０ｇ水
５０’Ｏｇ上記溶液
？笑′ＭＭ例１と同僚にして転写紙ケ作成した。この足
元性ｉ″；ｉ７５％であった。しかしながら光沢は３０
％でギラギラした感じであり、筆記性も文字がカスして
おシ、１分１ｆｊコ放置してもペンに工ゐインクが乾か
なかった。さらに圧力定后ではロールヶフＪ０ずときブ
ロンキングが発生した。Ratio C bite example 1 SBR (styrene butadiene tuber) ioog charcoal calcium 40g water
50'Og above solution? Lol' MM Example 1 and a colleague made a transcription paper. This foot property i″; i was 75%. However, the gloss was 30%.
%, it had a glaring feel, the writing quality was poor, the letters were smudged, and the ink did not dry on the pen even if I left it for 1 minute. Furthermore, after the pressure had stabilized, bronking occurred when the roll gap reached J0.
〔う１ｚ明Ｖ）４レリ釆〕 ８以上の如く、
本元明転写紙は定宿性は市販転写紙と同等であるがペー
パーライク性、筆記性、ブロッキング性も良好であシさ
らｖｃ２５ｔｌ：’、８５％１４ Ｈと尚湿における画
像Ｑ度が菌く、湿度にあ・け／）弛Ｐｊ・ｌ、（（１）
少ない転写紙である。又、この転写紙は、熱定光１゛、
圧力定ン告に１史用できる。[U1z Akira V) 4reli pot] As above 8,
Hongen Akira transfer paper has the same retention properties as commercially available transfer paper, but also has good paper-like properties, writing properties, and blocking properties. , Humidity /) Relaxation Pj・l, ((1)
There is less transfer paper. Also, this transfer paper has a thermal constant of 1゛,
One history can be used for pressure determination.
代理人 弁理士 高橋明夫Agent: Patent Attorney Akio Takahashi
Claims (1)
レンと、アクリル酸及び（又は）メタクリル酸とメタク
リル眩アルキルエステルとｒ構成単位として含−む共屯
６・体φ〕イケ液ケ塗布し転写層音形成ぜしめてなるこ
とケ特似とする電子写真用転写紙。1. On at least the toner image-receiving surface of the paper support, a liquid solution containing styrene, acrylic acid and/or methacrylic acid, methacrylic alkyl ester, and a conjugate unit φ] is applied. An electrophotographic transfer paper with a transfer layer that is unique in its sound formation.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP8583183A JPS59212846A (en) | 1983-05-18 | 1983-05-18 | Electrophotographic transfer paper |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP8583183A JPS59212846A (en) | 1983-05-18 | 1983-05-18 | Electrophotographic transfer paper |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS59212846A true JPS59212846A (en) | 1984-12-01 |
Family
ID=13869792
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP8583183A Pending JPS59212846A (en) | 1983-05-18 | 1983-05-18 | Electrophotographic transfer paper |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS59212846A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6032059A (en) * | 1983-08-02 | 1985-02-19 | Ricoh Co Ltd | Transfer sheet |
| JPS62198876A (en) * | 1986-02-26 | 1987-09-02 | Fuji Xerox Co Ltd | Electrophotographic transfer paper |
| JPS62198875A (en) * | 1986-02-26 | 1987-09-02 | Fuji Xerox Co Ltd | Transfer paper for electrophotography |
| EP0433949A2 (en) * | 1989-12-22 | 1991-06-26 | Eastman Kodak Company | Thermally assisted transfer of electrostatographic toner particles to a thermoplastic bearing receiver |
| WO2007129400A1 (en) * | 2006-05-08 | 2007-11-15 | Pt. Pabrik Kertas Tjiwi Kimia Tbk. | Electrophotographic paper |
-
1983
- 1983-05-18 JP JP8583183A patent/JPS59212846A/en active Pending
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6032059A (en) * | 1983-08-02 | 1985-02-19 | Ricoh Co Ltd | Transfer sheet |
| JPS62198876A (en) * | 1986-02-26 | 1987-09-02 | Fuji Xerox Co Ltd | Electrophotographic transfer paper |
| JPS62198875A (en) * | 1986-02-26 | 1987-09-02 | Fuji Xerox Co Ltd | Transfer paper for electrophotography |
| JPH0582939B2 (en) * | 1986-02-26 | 1993-11-24 | Fuji Zerotsukusu Kk | |
| JPH0582940B2 (en) * | 1986-02-26 | 1993-11-24 | Fuji Zerotsukusu Kk | |
| EP0433949A2 (en) * | 1989-12-22 | 1991-06-26 | Eastman Kodak Company | Thermally assisted transfer of electrostatographic toner particles to a thermoplastic bearing receiver |
| WO2007129400A1 (en) * | 2006-05-08 | 2007-11-15 | Pt. Pabrik Kertas Tjiwi Kimia Tbk. | Electrophotographic paper |
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